qu Qs Qa 26 He Chemistry (Compulsory) Q.1-Q. 6 carry one mark each. Which one of the following is not a state function? {A)Enthalpy (H) — (B) Internal energy (U) (C) Work done () (D) Entropy (S) Specify which among the following statements describe uncertainty principle (A) No two electrons. in an atom can have the same set of four quantum numbers (B) Itis impossible to determine simultaneously the velocity and momentum of a object with certainty (C) Matter like radiation exhibit a dual behavior (D) Iris impossible to simultaneously determine the position and momentum of an ‘object with certainty Among the given compounds, the most stable halogen containing compound of sulfur A)SFe (B)S.Cl: © SF ©) soc: The nucleophile among the following is (ABR (B) So; © (HN (B) Noe In the reaction ASB Products, If the concentration of A is doubled, the rate of the reaction increases by a factor of 4, However, ifthe concentration of B is doubled, the rate remains unaltered. The order of the reaction with respect to A and B will be respectively (A)2and | (B)2 and 0 (©) Land 0 () Land 1 The major product (X) of the reaction Zine dus BrCHy-CH,-CH,Br —“"" gy a) (B) CH; =CH. CH, Br Het. SN Hy Hae (©) BrCH,- CH=CH,Q7 as Qs Quo Qui Qu Qn Q.7-Q. 24 carry two marks each. ‘Which among the following steps is NOT present in the determination of lattice centhalpy of Nal using the Bom- Haber eycle (A) %h6)—*_ *&h@) @) Na) —* Nat ©) 2b@ —+1@ ©) Ig + —*>T@ ‘The boiling point of pure benzene is 80.0 °C. When a certain amount of benzoic acid ‘was added (0 it, the boiling point increased to 82.5 °C. Ifthe ebullioscopie constant (K,) is 25 K kg mor", the molality of the solution will be (a) 0.02 (B)0.25 ©1009 (D) 6.25 ‘The structure of XeO,F; based on VSEPR theory is best described as (A) See-saw structure with the O-Xe-O angle close 10 120° (B) See-saw structure with F-Xe-F angle close to 120° (C) A perfect tetrahedral arrangement of substituents around Xe (D) A square planar structure with the fluorines trans to each other ‘The hydrolysis of which of the following compounds would yield phosphorous acid (H:PO,)? (APs (B) POC; © POw (D) Pols ‘The type of hybridization that chromium show in Cr(CO)¢ and [CrP]? are respeetively [atomic number of chromium is 24] (A) sp°d® and (B) spa? and 5 (©) sp! and oy (yal sp? and spr Which among the following molecules has the lowest bond dissociation energy? (a) NO (B) NO* (©) NO™ @) N: A transition metal ion in its #3 oxidation tute forms complexes with excess of F™ as well as CI”. Given that the ionic radi ofthe metal jon, F~ and C1 are 0.64, 1.34 and LSI A respectively, the geometries ofthe metal complexes formed will be octahedral AND. [MCI4]°. tetrahedral ectahedral AND [MClcJ* , octahedral (C) [MPiJ"- tetrahedral AND (MCLJ", tetrahedral (D) [MF,]~ tetrahedral AND [MCl]'~ octahedralQ.14 The reagent required for the conversion (A) Nain tigiid ammonia (B) LiAIHy (©) swe (D) Pui BaSO4/ Quinoline QS For the synthesis of ‘cocHs using Diels -Alder reaction, the reactants required are a B) © Q16 Match the values of K, (given in column 2) with the substituted benzoic acids (given in column 1) Column 1 Column 2 IP] p-No» [x] 36x 10° [Q] p-OH WY] 10x 10% IR] p-Cl [Zl 26x 10%Quis Qus ‘The major products (X) ana (Y) of the reactions HBr /peroxide aa 78°C CH; CH= CHy HCI (peroxide ee YT “78°C (A) X=CH;CHBICH; ; Y= CH,CHCICH; B) Y= CH;CHCICH; «© Y= CHsCH:CHCI (D) X=CHSCHBrCHs ; Y= CH:CH:CH:Cl Nitration of p-nitrobipheny! is carried out, The new nitro group would introduce at “OO nt (A) PandT (B) only Q Sparive cry, cr-cH, POCHYCHSON, x If X= Fin the first case and X = Brin the second case, the major product formed will be respectively (A) I-Hexene and 1+ Hexene (B) —I-Hexene and 2-Hexene (©) 2-Hexene and 2. Hexene (D) —-2-Hexene and 1-Hexene920 Qa Q22 Henderson's equation can be represented as “@ pit = pk, loa) (®) pH= og (©) pk, = pa tog al ) pK, = pH oa A concentrated solution of NaCl is diluted ten times, The specific conductance (x) and molar conductance (qy) will show the following behavior (A) decrease in i¢ and increase in Ay (B) increase in «and decrease in Amy (C) no change in both () increase in both Inthe reaction 2805 (g) == 280:(9) +0212) taking place at 27 °C, Kp is 3.0 x 10° atm. The value of K. (in mol dm™) for the {Given R= 0.0821 dn aun K* mot" 7x to @) 22 x10 (© 5 x10 (D) 2x10" Common Data Questions ‘Common Data for Questions 23, 24: KMnO4 reacts with oxalic acid in the presence of excess H:SO. to yield a manganese complex X. which is colorless in dilute solutions and pale pink in the crystalline form [atoraic number of manganese is 25}, Qa Qu ‘The number of unpaired electrons present in the complex X is al (B)3 oF ) 5 ‘The calculated spin only magnetic moment for the compound X is (A)5.92 BM (B) 4.90 BM (© 387BM () 1.73 BMLinked Answer Question ). 25 10 Q. 28 carry two marks each, Statement for Linked Answer Questions 25 & 26: Benzene reacts with I-chloro-2-methylpropane in presence of anhydrous AICIsat 20°C 10 give major product (X). Q25 The product (X)is ®) a ar ore © o on chic! ong om LAH gives (Y). Compound (¥) is ® - .CHgOH oO” on ee Consider ace " Zas)| Zag) || Cuan) | Cols) operating at 298 K [Given E%(2n"* /2n)=-0.763V and B(Ca/Cu°*) =-0.337V] Q.27 The emf of the cell (E*.u) will be (a) L100) (80.426 v © -1.10v (D)-0.426V Q28 The value of log K for the cell eaction: Za (s) + Cu” (aq) === Zn** (aq) + Cu (9) where K is the equilibrium constant will be f (a) 1861 ua ©-1441 0) 37.22 sn R = 8.314 JK“ mol ~!, F= 96,500 C mol] END OF THE SECTION