Professional Documents
Culture Documents
TECHNOLOGY
By Charles L. Riggs,'Ph.D.
and Joseph C. Sherrill, Ph.D.
TEXTILE RENTAL
SERVICES
ASSOCIATION
O F AMERICA
The authors dedicate this edition of Textile Laundering Technology to LIST O F TABLES AND FIGURES ........................................... 5
Everett E . Harris in appreciation for his guidance and assistance not only
during the preparation of this edition but also the first edition in 1979. Ev ACKNOWLEDGMENTS ...................................................... 7
has been a constant source of enthusiasm. inspiration. and personal INTRODlJCTION .............................................................. 9
assurance for both of the authors during these and other TRSA-sponsored l/LAUNDRY CHEMISTRY
projects for many years . Thanks Ev!! An Introduction to Basic Chemistry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Chemical Processes in Laundering . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Tests of Chemical Concentrations in Laundering Operations . . . . . . . . . . . . 15
The Decergency Function . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16
Washroom Test Kit . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19
Washreom Tests . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19
Wash Test Piece Services . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
P/WATER
Source? of Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .25.
Water Impurities . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26
Water Softening for Laundering . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
3/WASHING CHEMICALS
Surfactants ..................................................................35
Alkalies ..................................................................... 42
Other Washing Chemicals .................................................50
4/BLEACHES
Stain Removal .............................................................. 53
Bleach Types and How They Remove Stains .............................. 54
Sterilizing with Bleach ..................................................... 54
How Chlorine Bleach Affects Textile Strength Loss in Cotton ........... 55
Recommended Use of Liquid Chlorine Bleach ............................. 55
Bleach Management in the Laundry ...................................... 57
5/FINISHING CHEMICALS
Antichlor . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61 .
Sours . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .61
.
Fabric Softeners . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 .
Chemicals T h a t Control Mildew and Bacteria .......................... 65
Sizing ...................................................................... 68
Soil-release Finishes ......................................................70
Proprietary Finishing Chemicals ........................................ 70
G/TEXTILE FIBERS. FABRICS. AND FINISHERS
Classification of Textile Fibers ...........................................71
Fiber Names .............................................................. 71
Natural Fibers ............................................................ 72
Textile Labels ............................................................. 73
Common Fibers Encountered in Professional Laundries ................73 LIST OF TABLES AND FIGURES
Structure of Fibers. Yarns. a n d Fabrics ................................. 81
Textile Dyeing. Printing. and Finishing ................................. 86
7/LAUNDRY PROCEDURES
Prewash Steps .............................................................89 TABLES:
Wash Steps ................................................................ 92 T a b l e 2-1:Degree to which water can be softened-
General Laundry Formulas ............................................... 98 minimum hardness attainable. ppm a s CaC03.......................... 3 0
Item Classifications ...................................................... 104 T a b l e 3-1:Comparison of surfactant types . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4. 0
Chemical Supplies ........................................................ 114 T a b l e 3-2:Common alkaline builders . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 5
Chemical Selection .......................................................114 T a b l e 3-3:Solid alkaline silicate ratios . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 7
Dyeing Textiles in the Plant ............................................. 119 T a b l e 4-1:Effect of chlorine bleach on general soil removal . . . . . . . . . . . . . . .53
8/SAFE HANDLING O F WASHROOM CHEMICALS T a b l e 4-2:Effect of available chlorine solutions on cotton fabric .......... 55
Chemical Handling ....................................................... 121 T a b l e 4-3:Chlorine bleaches ................................................58
Chemical Storage ......................................................... 122 T a b l e 4-4:Oxygen bleaches .................................................6 0
Hazard Communication Standard .......................................122 T a b l e 5-1:Common laundry sours . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 3
T a b l e 7-1:Soil classification by item . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .90 .
9/PROBLEM SOLVING AND TROUBLESHOOTING
T a b l e 7-2:Ratio of soiled to clean weight
Troubleshooting Typical Operating Problems ............................127
for various textile classifications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .92
Causes of Textile Damage .................................................130
Tests for Damage .......................................................... 136 T a b l e 7-3:Sour guidelines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9. 7
T a b l e 7-4:Very-light-soil formula ..........................................100
Tests for Bacteriological Growth ..........................................138
T a b l e 7-5:Light-soil formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100
Stain Removal Methods ...................................................139
T a b l e 7-6:Medium-soil formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101 .
lO/LAUNDRY AND THE ENVIRONMENT T a b l e 7-7:Heavy-soil formula .............................................-102
Water Pollution ............................................................145 T a b l e 7-8:Very-heavy-soil formula ........................................ 103
Water and Energy Conservation ..........................................147 T a b l e 7-9: Industrial shirt formula ......................................... 107
Air Pollution ............................................................... 149 T a b l e 7-10:Industrial pants formula ...................................... 108
ll/WASHING AND FINISHING EQUIPMENT T a b l e 7-11:Mat formula .................................................... 110
Conventional Washing and Finishing Equipment .......................151 T a b l e 7-12:Shop towel formula ............................................112
Tunnel Washing ...........................................................156 T a b l e 7-13:Printer towel formula .......................................... 113
T a b l e 7-14:Chemical makeup of selected detergent powders ............. 115
GLOSSARY .................................................................. 163 T a b l e 7-15:Liquid sodium silicate formulas ............................... 117
APPENDIX ...................................................................183 T a b l e 7-16:Liquid potassium silicate formulas ........................... 118
T a b l e 9-1:Chemical damage to cotton caused by common medicines .... 131
INDEX ....................................................................... -203 T a b l e 9-2:pH values of foodstuffs ..........................................132
T a b l e 9-3:Stain removal procedure for unknown stains ..................141
T a b l e 9-4:Stain removal procedure for reducible stains .................. 142
What You Should Know About Laundering and Textiles written by P. Eugene
Smith and Pauline Beery Mack. Much of the material in these two texts,
prepared under the direction of the Texas Woman's University, was identical
or based on the same studies a s used to prepare editions of Textile Laundering
Technology. The first edition of Textile Laundering Technology written by
Charles L. Riggs and Joseph C. Sherrill was published in 1979. The first edition
was reprinted in 1982 and 1987.
This second edition represents a complete rewriting and update. This text
incorporates still-valid material t h a t appeared in the previous editions.
The authors have relied heavily on manufacturers, distributors, and suppli- LAUNDRY CHEMISTRY
ers for information on the most recent developments in the textile and laundry
industries.
TRSA's Production and Engineering Committee is grateful to Dr. Charles
Riggs and Dr. Joseph Sherrill for their efforts in preparing this volume, thereby
T
recognizing our industry's need for a comprehensive text on textile laundering he trend toward increased scientific analysis, application, and control h a s
technology. made a n impact on the textile maintenance industry.
Industry members are urged to acquaint themselves with the contents of this Very careful analysis and control of all phases of the washing process
book and to make certain that their washroom supervisors and managers use it have become necessary because of the increasing cost of energy, water, a n d
regularly. chemicals.
New developments in detergents, textile fibers and blends, and textile fin-
Mark Dmlet ishes, a s well a s improvements in laundering techniques, reemphasize the need
Chairman for textile rental business owners and managers to become more familiar w i t h
TRSA Production and Engineering Committee the fundamental principles and applications of laundry chemistry.
This chapter explains basic tests commonly used in the washroom to deter-
mine chemical concentrations of wash formulas and how soils are removed
from textiles.
A
lthough it's commonly accepted t h a t soiled laundry gets clean by a
combination of time, temperature, chemical action, and mechanical
action, t h e truth i s t h a t water is the single most important chemical
used in laundering.
Its role is to remove soil from the textiles by the processes of dissolving and
dilution. Time, temperature, chemical action, and mechanical action serve to
enhance t h e role of water in removing soil.
Water's ability to dissolve a wide variety of substances makes it a n effective
cleaning agent for a large percentage of soils. Most substances are more soluble
in water than in any other solvent.
Detergents and "builders" (described in detail in Chapter 3) have been deve-
loped to enhance the cleansing action provided by water in the presence of
mechanical action.
Water allows the action of the washer to be distributed throughout the soiled
load. It acts a s a wetting agent penetrating the soil/fiber interfaces and remov-
ing the soil from the fabric. Water also carries chemical supplies to and from
the textiles and c a m e s away suspended soil.
Water i s used in large quantities in all laundries. Water consumption per
pound of work processed varies from less t h a n one gallon per pound for light
soils to more than four gallons per pound for very heavy soils.
This chapter describes sources of water a n d the impurities launderers have
to contend with in the laundering process.
SOURCES OF WATER
Pure water is the logical choice for cleaning because of its universal solvent
action. Pure water freezes a t 32OF (O°C) and boils a t 212OF (lOO°C).
Absolutely pure water is very rare and expensive to produce. It's soft; abso-
3 Deportment of Fashion and Textiles
Texas Woman's University lutely colorless, odorless, and tasteless; and is neutral with a pH value of 7.0.
P.O.Box 22509, TvVU Station Water found in nature is always contaminated with dissolved or suspended
Denton, TX 76204 gases, liquids, and solids.
Vestfabrics. Inc.
Water follows a never-ending cycle. A vast amount of water from oceans,
P.O. Drawer 0 lakes, and waterways evaporates into the air. I t then condenses and returns to
200 Blackford Ave. the earth's surface a s rain, snow, or some other form of precipitation. It runs
Middlesex. NJ 08846
over or under the surface of the earth and finally finds its way back to a n origi- Chlorine
nal source - a lake, ocean, or waterway. Chlorine, especially in bleaches, is a very common ingredient in laundering,
Water evaporates in a relatively pure form, but it immediately begins to pick but it's regarded a s an impurity in the water supply. To meet federal, state, and
up impurities a s it flows through the cycle. Water falling a s precipitation is local requirements for safe drinking water, most municipalities add chlorine to
fairly soft; however, it contains dissolved gases and suspended particles. The the water distributed to homes and businesses. The required chlorine content
level of air pollution directly affects the quality of water falling a s a t the most distant point in the distribution system is from 0.5 to 2.5 ppm. If the
precipitation. laundry is near the treatment plant, the added level of chlorine can measure
Once water reaches the earth, it begins to collect soluble impurities and, in several parts per million. Chlorine content higher than 0.5 ppm degrades many
many cases, exchanges one type of impurity for another. Air pollution in the types of water-softening resins. The level of residual chlorine may need to be
form of oxides of sulfur or nitrogen lower the pH of water falling a s precipita- lowered by a reducing agent such a s sodium sulfite before the water passes
tion - a condition referred to a s acid rain. The acidity makes water corrosive through the water softener.
and able to dissolve a large number of substances such a s iron, developing Iron
higher levels of dissolved impurities. Water containing a s little a s 0.2 ppm iron can discolor laundry. Iron can enter
Water can be temporarily diverted from the cycle and used for drinking, cook- the water a t the source or be picked up from rusty water lines and tanks. Iron is
ing, laundering, or industrial purposes. Water is present in a n almost constant usually a soluble, colorless form called ferrous iron. When exposed to air, fer-
amount, and it's very doubtful we'll ever run out of it. However, water quality rous iron rapidly converts to insoluble ferric iron, which can vary in color from
and location are of immediate concern. yellow to reddish brown.
Water is diverted from its original cycle as either ground water or surface Since the allowable level of iron in drinking water is much higher than for
water. Surface water includes reservoirs, lakes, rivers, streams, ponds, or laundry use, treating for iron in the laundry with water pretreatment or rust
creeks. Surface water is generally replaced more rapidly by water's natural removing sour may be needed. In addition to staining problems, iron can accel-
cycle than is ground water. Ground water falls to earth a s precipitation and erate the action of some chemicals such a s bleach, damaging textiles.
then seeps into the ground and later appears a s springs or remains in under-
ground lakes and rivers. Alkalinity
The amount and kind of impurities in a water supply depend on many fac- Alkalinity isn't a problem during laundry suds steps, but high levels of bicar-
tors, including temperature of the water, turbidity and turbulence of flow, solu- bonate alkalinity can adversely affect rinsing.
bility of the matter it comes in contact with, the size and density of particles it If the water used for rinsing and souring is alkaline, the rinse steps won't
encounters, and the chemical nature of other impurities in the water. neutralize the alkalinity sufficiently and sour (acid) amounts will need to be
increased.
WATER IMPURITIES
Problems created by impurities depend on the type of industry using the water. Acidity
Only impurities of concern to the laundry industry will be discussed in this For proper laundering, the water should be neutral or slightly alkaline. In some
chapter. Water impurities can have a major impact on the quality of textiles parts of the country, water supplies are acidic because of acidic industrial and
washed by a laundry. Since the amount and kind of water impurities vary domestic wastes and, occasionally, seepage into ground water of acidic depos-
greatly, each laundry operator must evaluate treatment needs on an individual its i n deep mine shafts. Some energy recovery devices t h a t introduce combus-
basis. The following impurities must be reduced or avoided by laundries. tion gases into the water can also create acidic water conditions. Small
amounts of acidity can be neutralized a t or near the water source with a suita-
Hardness ble alkali such a s soda ash.
Hard water contains dissolved calcium and magnesium salts. Water hardness
is reported in terms of grains per U S . gallon or parts per million (ppm) of cal- Carbon dioxide
cium carbonate equivalents (CaCOJ. One grain per gallon equals 17.1 ppm. Most natural water supplies contain dissolved carbon dioxide. Carbon dioxide
Soap loses its effectiveness i n hard water because hard water turns soap into comes from a number of sources such a s the atmosphere, decaying organic
insoluble curds t h a t have no surfactant properties to remove and suspend soil. matter, a n d underground sources. While dissolved carbon dioxide is corrosive
Most synthetic surfactants don't produceinsoluble curds in hard water, but the in itself, it also accelerates the corrosive action of dissolved oxygen and reduces
efficiency of most surfactants is reduced by water hardness. alkalinity of water. Water with little or no alkalinity can become acidic from
Water softening treatment is usually less expensive than using larger dissolved carbon dioxide.
amounts of detergents. Some municipal water treatment plants reduce the
level of hardness of the processed water a s a service to their users. Some treat- Color
ment plants increase the hardness of the water by adding coagulating agents. Deep well and spring waters are usually colorless. Occasionally, water from
shallow wells will contain significant amounts of color. Color is very common produce poor quality textiles coupled with poor economy, regardless of the type
in surface water and is usually caused by organic compounds from decaying of surfactant used.
plant and animal matter. The chemicals responsible for water hardness are calcium and magnesium
Colored water will discolor all textile products if used for laundering. Colored salts and other less abundant alkaline elements. They're troublesome because
matter is usually removed by coagulation, settling, and filtering -the normal they form insoluble compounds with soaps or reduce the effectiveness of syn-
function of municipal water treatment plants. thetic detergents. The insoluble soaps formed tend to trap soil particles in the
fabric, causing grayness. Also, they tend to oxidize, causing rancid odors on
Organic growihs fabrics. Some types of water hardness cause scale in boilers, water heaters, and
Any water supply t h a t has been exposed to the atmosphere before use can be pipes, resultingin poor efficiency, increased maintenance and repair costs, and
expected to contain organic growths, mainly algae and bacteria (both patho- excessive fuel consumption.
genic and nonpathogenic), that cause clogging, slimy deposits, color, bad taste, Free fatty acids contained in body soil or certain other fatty soils can react
and odors. They may also constitute a health hazard. Bacteria growths are with water hardness, making these soils less soluble and more difficult to
usually controlled by chlorination, while algae growth is reduced by storing remove. Some clay soils exchange sodium ions for hardness ions in hard water,
the water in covered tanks. making the clay much more difficult to remove.
Several types of chemical water treatments are used in reducing water hard-
owgen ness. The most important methods are described below.
Oxygen, which is present in all water, is chemically very active and, therefore,
corrosive. This corrosive action is particularly apparent in water heaters and Lime-soda treatment
hot water lines, leading to iron in the water system and, eventually, equipment This method, used in community water treatment plants, involves adding cal-
and plumbing replacement. Processing water can be treated with oxygen sca- cium hydroxide and sodium carbonate to the water, and then allowing the
vengers such a s sodium sulfite to counteract this corrosion. insoluble material formed to settle out. This treatment method doesn't lower
Suspended matter
hardness sufficiently for laundry use and works only where enormous quanti-
Suspended matter is rarely found in ground water because water is naturally ties of partially softened water exist, such a s in a municipal water treatment
filtered a s it seeps from the surface to the water table. However, following plant. The treatment does help laundry operators somewhat, however, because
heavy rains, shallow wells may contain suspended matter because rapid seep- it decreases the amount of hardness they have to contend with.
age rates allow for little filtration. Phosphate treatment
Suspended matter is very common in surface water - the calmer the water, This treatment involves adding some of the commonly available complex
the less suspended matter present. For example, a lake may have very little phosphates, such a s sodium hexametaphosphate, sodium tripolyphosphate, or
suspended matter on a calm day; however, high winds can greatly increase the tetrasodium pyrophosphate, to the wash load. However, phosphate use is re-
amount of suspended matter. The amount of suspended matter in rapidly mov- stricted or banned in some areas.
ing rivers is usually very high. These phosphates may be a n ingredient in formulated soaps or detergents.
Suspended matter can be classified into two categories: They tie up or "sequester" the calcium and magnesium ions in such a way that
1. sediment, consisting of large particles that rapidly settle out in calm water; the ions are not available to react, rendering the hardness components incapa-
and ble of forming insoluble compounds with or "precipitating" soap.
2. turbidity, consisting of small particles that may remain suspended for sev- Complex phosphates frequently are used in washing formulas a s an aid to
eral days even in calm water. the rinse baths. Adding complex phosphates to the bleach or first rinse helps
Frequently, both types are referred to a s turbidity. Turbidity is the more dif- strip the soap from the textiles and regenerates insoluble soaps t h a t may have
ficult to remove, and sediment is removed in all processes that remove turbid- accumulated in prior laundering.
ity. Turbidity is removed by coagulation - adding chemicals to make the small Complex phosphates also can be used in the first flush bath in diaper
particles floc to sediment-sized particles-followed by settling and filtration. laundering.
WATER SOFTENING F O R LAUNDERING These compounds, acting a s separating agents, prevent formation of lime
The dissolved minerals in water are responsible for hardness. A relatively soaps in the diapers during the suds baths. Lime soaps are likely to form
small amount of hardness won't interfere with good laundering, but most because fecal matter is very rich in calcium salts.
laundries soften water having more than two grains per gallon (34.2 ppm) of Chelate treatment
hardness. Chelates are chemical compounds that tie up hardness components, rendering
The water in most sections of the country, however, has a high degree of them incapable of precipitating soap. Chelates may also be used with other
hardness. Unless hardness is removed or reduced to a minimum, the water will
metallic ions, such a s iron, and are frequently used in textile mill operations a s The useful softening capacity of the resin is expressed in kilograins of hard-
separating agents. ness per cubic foot of resin (kgr). This capacity depends on the amount of salt
used for regeneration and may vary from 20 to 30 kgr per cubic foot. Salt dosage
Demineralization usually ranges from 5.5 to 15 or more pounds per cubic foot of resin. Table 2-1
This method depends on removing mineral salts from water by special syn- shows the minimum hardness obtainable a s a function of raw water hardness
thetic organic resins, simultaneously using two ion-exchange reactions. and salt dosage.
One reaction removes positively charged cations, such a s calcium, magne- The figures in Table 2-1 are based on single-stage softeners. Improved results
sium, and sodium; while another removes negative anions, such a s sulfate, can be obtained by using two softeners in series.
bicarbonate, and chloride. Table 2-1 and Equation 2-1 provide a simple description of the base-ion
Often demineralized water h a s a mineral content equal to distilled water exchange bath process. Table 2-1 illustrates the softening cycle, and Equation
produced from the same source. 2-1 shows how the resin radical is represented a s Re.
Distillation is widely accepted by industries needing water with a very low As the hardness cations in the water exchange places with the sodium
content of dissolved solids, but laundries don't need such pure water and can't cations in the resin material, the elements causing hardness (calcium and
justify the higher costs. magnesium) are taken from the water into the resin bed.
Baseion exchange (zeolite or resin) Resin material h a s a specific capacity for exchanging ions with the calcium
This method is based on the absorption of hardness components, such a s cal- or magnesium in the hard water. When this capacity has been reached, the
cium and magnesium ions, by certain natural minerals or by synthetic resins, material is said to be exhausted; i t no longer h a s the ability to remove hardness
leaving the effluent water free of hardness. ingredients in the water supply. Before it's completely exhausted, the resin
Since this treatment is widely used for laundry purposes, i t is the only material should be restored to its original form a s follows:
method of water softening t h a t will be discussed in detail. 1. Backwash the resin bed a s illustrated in Figure 2-2. This is done by passing
The base exchange process softens water by exchanging the sodium ions of a vigorous current of water upwards through the softener. This procedure
certain natural greensands (glauconite) or synthetic mineral resins with the loosens and regrades the resin bed, holds it in a semi-suspended condition,
calcium and magnesium hardness in water. Synthetic resins are used widely a n d removes any dirt t h a t collected on top of the resin bed during the soften-
because they have excellent softening capacity and are longer lasting. i n g part of the bath. Make sure the water pressureisn't too high or channels
Ion exchange resins are available in a number of forms - natural zeolites, will form t h a t allow the water to pass through without cleaning the resin
synthetic gel-types, carbonaceous minerals manufactured from coal, and syn- bed.
thetic resins produced by copolymerization of styrene with divinylbenzene.
Nearly all of the cation exchangers sold today are of this last type. Figure 2-1: Base-ion exchange (zeolite or resin)
Table 2-1: Degree to which water can be softened - minimum hardness attaina- @
Q- Softening cycle
ble, ppm as CaCO,
(Courtesy of Permutit Co.,Inc.)
Equation 2-4
Na,Re
resin
+ Ca*'or Mg'.
hardness
- CaRe or MgRe
spent
resin
+ 2Nai
sodium
cations
Compacted zeolite
-.. . .. . ...
Outgoing soft water
wrth sodium ions
Figure 2-2: Backwashing of base-ion exchange water softener 2. Brine the exhausted resin a s illustrated in Figure 2-3. This is done by intro-
ducing a predetermined amount of concentrated sodium chloride (salt or
cycle brine) solution into the softener. The concentrated salt solution is distrib-
uted over the top of the bed and passes through it. The salt reacts with the
resin, removing the calcium and magnesium in the form of soluble chlorides,
and restoring the resin to its original active or sodium condition. The regen-
eration process is shown in Equation 2-2.
3. Rinse the resin bed to remove the released calcium and magnesium salts as
well a s the residue of unused sodium chloride solution. After these salts have
&??+++-0utgolng dirty water been rinsed out, return the softener to service.
Bound hardness
Equation 2-2
CaRe or MgRe
spent
resin
+ 2NaCI
sodium
chloride
- Na,Re
regenerated
resin
+ CaCI, or MgCI,
soluble
salts
(saw
Zeolite loosened
r
addition
. .
.. . . .. ' . . . .
. Incoming brine with
- . 4.
00 . . ' .- 0 . sodium ions
.
. a 0
Zeolite loosened . ,, F:
and regraded
. . .. . .. . . . b
a .
*In this chapter, the term "soi1"refers to the normal insoluble soils that can be removed
using conventional wash formulas. Soil that can't be removed and discolors the fabric
is referred to a s a "stain."Stains aregenerally removed b y bleaching, which is covered
in Chapter 4.
Every surfactant molecule is made up of two parts, a s shown in Figure 3-1. loving) part of many surfactant molecules plus molecules of oil. The exterior is
One part - drawn a s a rectangular tail in Figure 3-1 -is hydrophobic (water made up of the hydrophilic (water-loving) part of the surfactant molecules,
hating), also called oleophilic (oil loving). The other part - drawn a s a circular which allows the oil to disperse into the water.
head in Figure3-1 -is hydrophilic (water loving), also oleophobic (oil hating).
Figure 33: Oily surfactant complex
Figure 3-1: Surfactant molecule schematic
Water
Moderate agitation will then disperse the oil into the water a s small globules
surrounded by surfactant molecules, a s shown in Figure 3-3. The interior of
these oil/surfactant formations contains the hydrophobic (water-hatingor oil-
To free these trapped particles so they can be removed, surfactants penetrate Figure 3-7: Oily soil lifted from textile
the oil or grease film. Surfactant molecules a t the oil/water interface surround-
ing the soil particle lower the tension or force separating the oil from the water,
allowing mechanical action to lift the soil particle from the fiber surface, a s
shown in Figure 3-7.
When the soil particle is free from the fiber, it moves through the washing
solution, where it is affected by gravity and turbulence. Free soil particles tend
to attract each other, causing them to draw together or agglomerate. This
makes them larger and more susceptible to gravity forces, which could make
them redeposit on the fabric.
Figure 36:Surfactant dispersing oily soil It's here that the surfactant's soil suspension properties become important.
After mechanical action frees soil from the fiber, surfactant molecules hold it in
suspension in the washing solution, a s shown in Figure 3-3.
SoiVsurfactant formations such a s the one shown in Figure 3-3are limited in
size by the nature of the hydrophilic part of the surfactant. The formations are
small enough to remain in suspension until removed from the water by the
dilution effect of each successive bath in the washing/rinsing process.
Surfactant classifications
Surfactants are organic chemicals t h a t contain a s their principal parts the
elements carbon a n d hydrogen, along with oxygen a n d nitrogen, and minor
amounts of sulfur. Surfactants are classified based on how they ionize in solu-
tion; t h a t is, how the active portion of a surfactant molecule is charged:
+
cationic - the active portion i s a cation or a charge;
R anionic - the active portion is a n anion or - charge; and
nonionic - the active portion isn't electrically charged, meaning no
ionization.
- -
- 0 I
(-0-CH2-CH2)n-0-H
a s shown in Equation 3-3.
Equation 3-3
NaCl + H20 -+ N ~ + + CI-
Often called ethylene oxide adducts of alkyl phenol, this is the most impor- + H70
tant single class of surfactant in the laundry. General laundry use is when the sodium wafer sodium ch1oricYe
wafer
chlon'de cations anions
"n" value equals 9 or 10 and temperatures range from 100' to 180°F. (salt)
ALKALIES A salt formed by the reaction of a strong acid and a weak alkali is acid, a s
While soaps and synthetic surfactants are organic chemicals, alkalies, in con-
shown in Equation 3-4.
trast, are inorganic chemicals derived almost entirely from the earth's crust.
Alkalies and alkaline salts are added to surfactants to assist in soil removal Equation 3-4
and soil suspension. For this reason, they are frequently referred to as builders + 3H,O --b AI(OH), + 3H7 + 3Ci-
or alkaline builders.
aluminum
Textile detergency is most effective in an alkaline medium rather than acid. Chloride water alumirium acid chlonde
While some detergent processes use an acid medium, practically speaking, tex- (salt) hydroxide anions
tile cleaning normally occurs in an alkaline medium.
This statement is especially true for tallow soap. Tallow soap (produced by
percent for sodium metasilicate pentahydrate. Another good choiceis anhy-
-
A salt formed by the reaction of a weak acid and a strong alkali is alkaline,
a s shown in Equation 3-5. drous metasilicate, but only where the absence of water provides a concen-
trated product.
Equation 3-5
Na2C03 + H20 2Na' + OH- + HCO; Table 3-2: Common alkaline builders
sodium water sodium hydroxide bicorbonde
carbonate cations anions anions Percent Na,O pH d water solulions
(%concentrationsas sham)
(salt)
Bullder Fonnula Active' Total*'
Theoretical
total
-
1.0% 0.5% 0.1%
Compounds referred to a s alkalies in the laundering industry usually aren't
true alkalies but salts of a weak acid and a strong alkali. In solution, these salts Sodium hydroxide
produce the hydroxide anion (OH-), a s shown in Equations 3-5,3-6, and 3-7. (caustic soda) NaOH 75.5% 76.0% 77.5% 13.1 129 122
Equation 3.6 Potassium
hydroxide KOH - - 55.3 13.1 12.9 12.3
Na2Si03 + H20 -------,
2Na+ + OH- + HSiO;
Potassium
sodium water &;urn hydroxide any one of orthosilicate KAsioA - - 50.0 13.0 12.7 12.1
metas;licate cations anions several
silcate Sodium
anions orthosilicate NaASio4 59.0 60.8 67.4 13.0 12.7 11.9
(anhydrous)
Equation 3-7 Sodium
metasilicate Na2Si0, 49.0 50.8 50.8 12.6 12.3 11.6
Na3mA + H20 ------b 3Na' + H2FQ + 20H- (anhydrous)
tisodium water sodium dihydrogen hydroxide Sodium
phosphate cations phosphate anions orthosilicate Na~Sio4.5~~0 440 4.8 45.3 12.9 12.6 11.8
anions (pentahydrate)
Sodium
metasilicate NazSi03.5~~0 28.2 29.2 29.2 12.4 12.0 11.4
Table 3-2 lists common alkaline builders used in the laundering industry. (pentahydrate)
This group contains alkalies and alkaline salts.
Sodium
The terms "active" and "inactive" alkali have been used by laundry technol- carbonate Na2C0, 28.7 57.4 57.4 11.3 11.2 10 7
ogists and operators for many years. Broadly speaking, active alkali is the per- (soda ash)
centage of total sodium oxide content available a t a pH greater than 8.3. Sodium
Except for sodium hydroxide, the alkaline silicates appear to have the high- bicarbonate NaHC03 0.0 36.9 36.9 8.4 8.3 8.3
est active and total sodium oxide (Na,O) levels a s well as the highest pH values. Sodium
Both of these factors - pH and sodium oxide content - measure the building tripolyphosphate Na3P3010 4.3 16.9 43.0 9.4 9.6 9.9
strength of a n alkali and reflect the concentration of hydroxide anions (OH-) in Trisodium
solution. phosphate Na3POp12H20 10.0 18.8 24.1 12.1 11.8 11.0
(dodeca
The role of sodium oxide content and/or solution pH in a n alkali's ability to
build or enhance a detergent is very complex. In general, alkalis are ranked by
'Titratable with phenolphthalein
their percentage of active sodium oxide content, which correlates with their
"Titratable with methyl orange
solution pH, as shown in Table 3-2.This measure of alkalinity is often referred
to as alkaline pressure.
Note the sodium metasilicate and sodium bicarbonate listings in Table 3-2. The alkaline silicates
The total sodium oxide content of sodium bicarbonate a t 36.9 percent is signifi- Generally, the surfactant is considered the principal agent in soil suspension,
cantly greater than that of sodium metasilicate pentahydrate at 29.2 percent. but studies show that alkalies help in this role.
Yet no experienced laundry operator would choose sodium bicarbonate over Alkaline silicates, in particular, have excellent soil-suspendingpower and
sodium metasilicate pentahydrate for laundering items such a s aprons work hand in hand with surfactants.
because the active alkalinity of bicarbonate is 0.0 percent compared with 28.2 In addition to helping in soil suspension, alkaline silicates help maintain pH
levels, or buffer a solution. Buffers are ingredients that help a solution main- The solid silicates
tain a stable pH when acid or alkali is added. Some alkaline silicates are available in dry form a s listed in Table 3-3.
True buffers are usually a mixture of a weak acid salt, or a mixtureof a weak Table 33: Solid alkaline silicate ratios
alkali and a weak alkali salt. Laundry alkalies are not true buffers, but they do
provide some resistance to pH change from added acids a s shown in Figure 3-
Theomtical
11. On the chart, caustic soda and silicated alkalies show strong buffering Molecular percent sodium
action; that is, they do not change much in pH a s they're neutralized. Name formula oxlda (total)'
Sodium metasilicate
(pentahydrate) Na20. SIO, 5H20
Figure 3-4 4: Bufferingeffect of alkali, solutionsof industrialalkaliescontaining 0.02%
Sodium orthosilicate
Na20(Courtesy of pQ Cop.) (pentahydrate)
-
. NaOH -- -.- - -- -. (Caustic soda)
2Na20 SIO, 5H20
~ ..- -.--.-
Sodium metasilicate
3 ~20a. . 2 -.~ .- (Sodium sesquisilicate) (anhydrous) Na,O SIO,
Na2Si03- . - .- . - (Sodium metasilicate)
Na3pQ --- - - --- - - (Trisodium phosphate) Sodium orthosilicate 2Na20 SIO, 67.4'
Equation 3-8
Na2Si03 -- Na20 + Si02 >- Na20 Si02
The molecular weight of the sodium oxide unit is (2x23) 16 = 62; for t h e+
6
-- -:-=
+
silica unit it's 28 (2X 16) = 60. The proportion of sodium oxide in the anhy-
drous compound Na,O SiO, is 62/(62 + 60) = 50.8 percent. This is referred to
\
\
as the total sodium oxide content of sodium metasilicate. In the pentahydrate,
+ +
\
\
I the total sodium oxide content is 62/[(62 60 (5 X 18)] = 29.2 percent.
I 2 3 While sodium nietasilicate has a one-to-oneratio of sodium oxide to silica,
ML N/5 HCL PER I00 ML sodium orthosilicate has a two-to-oneratio of sodium oxide to silica. The total
sodium oxide content of sodium orthosilicate(2 X 62)/[(2 X 62) 601is 67.4 per- +
cent. As Equation 3-9 indicates, sodium orthosilicate is manufactured by
mechanically combining proportionate amounts of caustic soda with sodium
Caustic soda is also an active builder for soap or synthetic detergent if prop- metasilicate.
erly handled and controlled in the washer. Prior to about 1950, many plants
used straight caustic soda, but this practice has completely disappeared Equation 3-9
because: 2NaOH
Caustic soda is hazardous to handle. Na2Si03 + (Na20+ H20) >-- 2Na20. Si02 + H20
Caustic soda is concentrated and difficult to control i n the laundering sodium caustic sodium water
process. It's easy to over or under use. metasilicate soda metasilicate
To offset these problems but maintain the benefits of caustic soda, chemical
The finished compound, though called anhydrous in the trade, actually con-
companies combine i t with silicates, carbonates, and to a lesser extent, phos-
tains moisture. Taking this into account, the total sodium oxide content of
phates and alkaline silicates. Silicates are available in either liquid or pow-
dered form. Each has its uses, a s described on the following pages.
commercial sodium orthosilicate is not 67.4 percent but about 60.5 percent. Alkaline damage to fabrics
Although i t would seem that all silicated alkalies should produce the same Washing with alkaline builders declined in the 1980s because of a decrease in
results as long a s the break and subsequent baths achieve proper alkalinity, cotton fabrics and a n increase in polyester fabrics.
there's reason to believe that all alkalies don't perform alike. Cotton is more resistant to damage from strong alkaline solutions. In fact,
For some time, operators have used orthosilicate for linen supply operations cotton fabric strength is often increased by alkaline solutions. For maximum
and metasilicate for industrial laundering. soil removal, strong alkaline detergent solutions are usually used to launder
Linen supply processing generally involves oily soils of animal and vegeta- cottons.
ble fat. These soils are best removed by the strong saponification action of the Polyester, on the other hand, can be damaged in strong alkaline solutions.
active sodium oxide portion of an alkali. Therefore, a n alkali with a relatively The fiber surface becomes pitted and/or the fabric loses strength - a chemical
high proportion of active sodium oxide such as orthosilicate is needed. process termed alkaline hydrolysis. All the conditions that lead to alkaline
For the mineral oil-based soils found on industrial uniforms, shop towels, hydrolysis haven't been firmly established, but a combination of higher pH
and similiar classifications, the better emulsifying action of metasilicate plays and temperature causes the greatest damage and, in some cases, can destroy
a significant role in soil removal. For example, studies indicate that shop tow- the polyester fiber.
els laundered with metasilicate show greater absorbency and less redeposition Quaternary ammonium surfactants (quats), which are used to formulate
than those laundered with orthosilicate when both alkalies are added to an many types of fabric softeners, dramatically increase the severity of alkaline
equal titration level. hydrolysis. Some manufacturers of polyester fabric recommend not using
quarternary ammonium fabric softeners on their fabrics. In addition, polyes-
The liquid silicates ter's resistance to alkaline hydrolysis depends on the type of polyester and the
The alkaline silicates listed in Table 3-3 can be made in the laundry plant by treatments the fibers may have received during manufacturing.
combining liquid causticsoda with liquid silicate. Liquid caustic soda X 50per- The best practice is to avoid pH values above pH 11 and temperatures above
cent by weight is a common item, as is liquid silicate. 160°F.
Liquid silicate comes in many forms. The type used in laundries, 8.9 percent Many detergent manufacturers offer formulated detergents that produce
Na,O and 28.7 percent SiO,, is known as 1:3.22 (the ratio of Na,O to SiOJ. only moderately alkaline solutions. These detergents provide excellent surfac-
Liquid caustic soda and silicate can be purchased in tanker quantities and tant action to make up for the work done by alkaline builders in more tradi-
stored. They then can be combined in the proper proportions to produce the tional detergent formulations.
aforementioned silicates or, for that matter, any other molecular ratio required.
For example, 7.2 gallons of liquid caustic combined with 14.7 gallons of liquid Phosphates
silicate and enough water to bring the volume up to 100 gallons produces iden- Phosphorous forms many compounds with sodium and oxygen, all of which
tically the same mixture as one 100-pound bag of anhydrous sodium metasili- are alkaline. These alkaline salts are very useful in laundering and other clean-
cate added to a 100-gallon tank of water. ing procedures, but many areas of the U.S.have banned or restricted phos-
While the mixtureis identical, the cost isn't. Orthosilicate made by combining phate use, resulting in lower levels of soil removal and fabric whiteness.
11.6 gallons of liquid caustic with 9.7 gallons of liquid silicate, a practice fol- The complex phosphates - including sodium tripolyphosphate ("tripoly")
lowed by many plants, is about 45 to 50 percent below the cost of bagged alkali. (Na,P,O,,J, tetrasodium pyrophosphate, and sodium hexametaphosphate -
Commercially available potassium orthosilicate is a highly concentrated are used most frequently as builders for industrial and consumer laundry
liquid silicate. Potassium salts are alwaysmore soluble than sodium salts and detergents.
prices range from the same to about 1.7 times as much as their sodium counter- Phosphates sequester the hardness in water, leaving the detergent free t o
parts. Potassium orthosilicate is a very effective alkaline builder. remove and suspend soil. They render calcium and magnesium ions incapable
Potassium silicates can be prepared in water solutions a s concentrated a s 4.2 of forming insoluble soaps, but don't precipitate these hardness elements. T h e
pounds per gallon. Potassium silicate solutions are far more resistant to freez- advantage of this sequestering action is that soil can't be occluded or trapped
ing than sodium silicate solutions of the same strength. For this reason, potas- in the fabric by precipitates if no precipitates are formed. So the whiteness of
sium orthosilicate solutions can be transported, stored, and used a t higher con- whites and the brightness of colors are preserved. Sodium tripolyphosphate
centrations than can sodium orthosilicate solutions. also sequesters a large number of metallic ions.
In order to achieve equal results from potassium- and sodium-based alkalies, For many years, plants using tallow soap have added complex phosphates i n
1.1to 1.5 times (depending on Na,O to SiO, ratio) a s much potassium silicate as the bleach bath to regenerate soluble soap from its precipitated form. This
sodium silicate must be used. This produces a solution with equal alkalinity enhances the whiteness and brightness of the finished product. Even relatively
and SiO, amounts. small amounts of precipitated soap that have become lodged in fabrics because
of minute amounts (1 to 10 ppm) of water hardness in softened water can b e
regenerated by adding small amounts of complex phosphate.
Complex phosphate use is certainly not limited to soap formulas; it also ironing if bicarbonates haven't been properly removed in rinsing or neutralized
enhances the performance of synthetic detergents, suspending soil and help- by souring. The yellowing is caused by the action of carbonates formed when
ing to preserve the whiteness of white and the brightness of colors. the bicarbonates begin to decompose.
On an equal-weight basis, the most effective phosphate is sodium hexameta- Optical brighteners, also known a s fluorescent whitening agents, are essen-
phosphate, and trisodium phosphate is the least effective. tially colorless dyes that, when applied to textiles, papers, plastics, and other
Trisodium phosphate (Na,PO,) is a simple phosphate in the form of an alka- substances, absorb ultraviolet radiation and emit light of various hues. Blue i s
line salt. Its pH is 11.8(at a 0.1 percent concentration), and total sodium oxide the preferred hue for white textiles becauseit complements or counterbalances
content is 24.1 percent. Although its structure suggests it could function as a the yellow tint already present in off-white substances, imparting a greater
detergent builder, its low available sodium oxide content excludes it from apparent whiteness to the materials treated.
general use. Trisodium phosphate, technically sodium orthophosphate, Manufacturers add brighteners to practically all proprietary washroom
softens water by precipitating the calcium and magnesium ions in the form of supplies to gain a marketing advantage. Certain brighteners can produce sig-
calcium and magnesium phosphate. In this respect, it resembles sodium car- nificantly brighter finished textiles than might ordinarily be the case, even
bonate. Trisodium phosphate is widely used in non-textile applications where after a single wash, if added in sufficient quantities.
its mild alkalinity provides a wide spectrum of soil- and stain-removal action. Brighteners generally are absorbed only by cellulosic fibers, such a s cotton.
A few respond to nylon, while others are absorbed by wool and acetates. Cur-
Phosphate-freesequestering agents rently, no brighteners have an affinity for polyester fibers, so most producers of
Organic sequestering agents have replaced phosphates in certain parts of the polyester fiber incorporate brighteners within the fiber during manufacturing.
country where phos'phate use h a s been restricted. These materials aren't a s A brightener's effect is decreased as the fiber ages, which explains w h y
effective a s phosphates, but they're stronger sequestering agents for a wider laundered fabrics differ so markedly in whiteness. This is particularly evident
range of substances. when all-cotton items such a s bath towels are compared with sheets and pil-
Some of these organic compounds are derived from the sodium salts of ethy- lowcases that may have been washed in the same load. The bath towel fibers.
lenediaminetetraacetic acid (EDTA). These phosphate-free compounds are generally all-cotton, have a far greater capacity to absorb brighteners in t h e
very stable under all conditions. Some EDTA derivatives maintain their struc- washing process than the fibers of the sheets and pillowcases, which generally
ture and sequestering power under extreme conditions of heat and alkalinity, are 50/50 polyester/cotton.
conditions that cause complex phosphates to revert to the basic trisodium Operators who purchase generic or raw chemicals can get the benefits of a
phosphate and lose sequestering power. brightener by adding one proprietary chemical to the generic mix, by making a
They are also quite effective in sequestering soluble iron. A number of these stock solution of a water-soluble brightener, or by including a water-soluble
compounds, sometimes referred to a s chelating agents, have similar chemical brightener in the stock solution of one of the other washroom supplies.
structures. The correct point in the wash process to add a brightener is determined by t h e
While chelating agents are very efficient sequestering agents, their main solubility and bleach resistance of the brightener. Most brighteners are best
function in the laundry is to control impurities such a s iron and manganese, absorbed in a high-temperature surfactant bath. Therefore, manufacturers
which cause problems in very low concentrations. EDTAs can sequester (or commonly add brighteners to detergent formulations.
chelate) iron in almost any concentration. The specific EDTA compound The effectiveness of some types of brighteners is reduced by bleach.
selected to do the job depends on the pH of the application - for example, the To avoid this problem, certain warm- and cold-water-solublebrighteners c a n
EDTA best suited for pretreating incoming water is different from the one best be used in a sour bath, protecting the chemical structure of the brightener from
suited for the sour bath. bleach used earlier in the formula.
Consult suppliers for information on the proper concentration of these
sequestering agents, since the amounts needed depend on the concentration of Carboxymethylcellulose (CMC)
the contaminant. Soap or synthetic detergent's job in thelaundering process is to wet, penetrate,
deflocculate, and suspend soil. Tallow soap used in soft water can perform a l l
OTHER WASHING CHEMICALS four functions well. Synthetic detergents alone don't suspend soil a s well as
Surfactants, alkalies, and phosphates constitute the bulk of chemicals used in soap does.
the washing process. Other chemicals may be used in small amounts to Early research on soil-suspending products found that certain colloidal sub-
increase quality. stances, notably sodium carboxymethylcellulose (CMC), a versatile cellulose
derivative, have the unique ability to enhance the soil-suspending power of a l l
Optical brighteners synthetic detergents. As a result, CMC is widely used as an additive in most
Cotton, in its natural state, is cream white to beige. Even after bleaching, cot- laundry detergents containing anionic and nonionic surfactants.
ton tends to revert to its natural color. Moreover, cottons can turn yellow during Modern laundry detergents are complex mixtures of many substances for-
mulated to provide balanced washing action. By adding from 0.5 to 1.5percent
of CMC to the detergent, synthetic formulations gain soil-suspending power
about equal to tallow soap. CMC alternatives include various long-chain
polymers such as the polyacrylates.
Proprietary products
Some proprietary alkalies combine caustic soda with soda ash in formulations
balanced to provide the same alkaline pressure (sodium oxide content) as the
alkaline silicates. These products may also combine phosphates and other
chemical specialties for a wide spectrum of building performance.
Many laundries use proprietary built soaps and syntheticdetergents instead
of buying basic supplies. These products are compounded using all the ingre-
dients necessary for laundering a wide variety of classifications. Considerable
research time and money have been spent to develop these formulas, so manu-
facturers often protect them by patents.
These proprietary products usually consist of the following:
B
leach has three roles in the laundering process: removing stains, steriliz-
a surfactant or surfactants, ing linens, and maintaining whiteness.
an alkali or a blend of alkalies, Of the three roles, bleach is most effective in removing stains and kill-
water softeners, ing bacteria and other microorganisms. It does have a whitening effect on cot-
suds stabilizers, ton, but whiteness retention is best accomplished by proper washing proce-
soil-suspending agents, and dures. The whitening action of bleach is simply a fortunate byproduct.
brighteners. This chapter discusses the reasons and methods for using bleach.
The more alkaline products range in pH from pH 11.5to 12.5 and have active/
total alkalinity ratios that compare favorably to metasilicate and orthosili- STAlN REMOVAL
cate. These products rely on alkaline chemistry to break down and remove soils Most soils encountered in a laundry can be removed by a good, bleach-free
from the textiles. washing formula. Bleach has no place in general soil removal because it
The less alkaline products range in pH from pH 9.5 to 11.0and are especially doesn't effectively remove inert dirt that's been bound onto fabric by animal
suited for polyester fabrics to avoid alkaline damage. These products use the and vegetable fats or mineral oils.
most current surfactant technology to emulsify and remove soil and may con- In fact, bleach only removes inert soil when it's used in such high concentra-
sist of a blend of several surfactants. They perform on a comparable level with tions and temperatures and a t such unfavorable pH conditions that it com-
the more alkaline products. Low-alkaline products generally cost more than pletely removes the surface of cotton fibers and severely reduces textile strength
high-alkaline products, but the costs may be offset by prolonged fabric life, (see Table4-1).Even under those conditions, the small amount of soil removed is
color retention, and/or reduced water and energy consumption. probably the result of mechanical action and the bleach's alkali content.
Table 4-1: Effect of chlorine bleach on general soil removal
(Soil removal measured on cotton standard soil cloth produced at
Texas Woman's University)
Bleach Concentrdon Strength Soil
strength (quartsper Ternpercrhrre loss removal
(%Cln) 100 pounds) pprn (OF) PH
T
Many of these problems have been addressed by a new generation of syn- he purpose of this chapter is to summarize the nature of textile fibers t h a t
thetic sizings. However, additional information on thesenew synthetic sizings may be encountered in a textile rental plant or related operation plus their
wasn't available for this edition. chemical and physical characteristics, uses, and limitations.
Many of the fibers included in this chapter are not frequently found in t h e
SOIL-RELEASE FINISHES professional laundry but are included to provide a complete list of fibers
Soil-release finishes are classified a s durable or nondurable. available.
The durable types of soil-release finishes are applied during fabric manufac-
turing. These finishes are intended to function for the useful life of the fabric. CLASSIFICATION OF TEXTILE FIBERS
The nondurable soil-release finishes usually are applied in the washing pro- Although fibers may be classified in several ways, a logical division is natural
cess. Nondurable finishes coat the fiber during a rinse or sour operation, and fibers and man-made fibers.
the fabric retains this coating until the next washing. Natural fibers used to make textiles occur in nature in fibrous form. Cotton,
As the fabric becomes soiled, the soil does not bind a s strongly with the fiber probably the most common natural fiber, is composed of cellulose (C,2H20010)X.
because of the film between soil and fiber surfaces. Film and soil are then Cotton fibers and other forms of cellulose can be dissolved chemically a n d
removed more easily during the next washing. regenerated to produce rayon. Both cotton and rayon have many properties i n
Several materials including starch, polyvinyl acetate, and polyvinyl alcohol common. Natural fibers also may be treated with a finish to alter characteris-
have the ability to function a s nondurable soil-release finishes if properly tics such a s crease resistance, flammability, and luster.
applied. Man-madeor synthetic fibers are made synthetically by chemically combin-
ing elements or compounds (simple or complex) such a s petroleum products;
PROPRIETARY FINISHING CHEMICALS they're also made from chemically regenerated natural fibers.
Proprietary sours, softeners, sizing, and other products are based on one or With a few exceptions, textile fibers are composed of molecules called poly-
more of the generic materials described in this chapter. In general, proprietary mers. A polymer is a very long molecule formed when several smaller mole-
products also contain optical fabric brighteners. cules link together in a regular, repeating manner that defines the combination
Some proprietary products combine different products. For example, one
of elements and determines many fiber proportions. The number of repeating
product may combine softener and bacteriostat or softener and sour. Multi-
units making up the polymer is termed the degree of polymerization.
functional products offer the following advantages and disadvantages:
Advantages- FIBER NAMES
Only one product instead of several must be purchased and stored. One of the provisions of the Textile Fiber Products Identification Act (TFPIA)
Chance of washroom personnel forgetting one of the chemicals is reduced. requires t h a t fibers be identified using "generic" names for man-made fibers
Amount of required dispensing equipment may be reduced. and "commonly accepted terms" for natural fibers. The generic terms for m a n -
Disadvantages- made fibers are based on the structure of the polymer repeating unit only. As of
ICould be more costly. 1988,23 generic names for man-made fibers existed under Rule 7 of the TFPIA:
Recommended use may cause underuse or overuse of one of the chemicals.
acetate modacrylic rubber wool (sheep),alpaca, camel, cnshmerc, guanaco, llama, mohair (Angora goat),
acrylic novoloid saran vicuna, mink, muskrat, and Angora rabbit.
anidex nylon spandex In 1939, Congress passed the Wool Products Labeling Act (amendedin 1980)
aramid nytril sulfar "to protect producers, manufacturers, distributors, and consumers from t h e
azlon olefin triacetate concealed presence of substitutes and mixtures in spun, woven, knit, felted, o r
glass PBI vinal otherwise manufactured wool products." This act requires products containing
lastrile polyester vinyon wool to be labeled a s to whether the wool is new or recycled.
metallic rayon The term "wool" as defined by the Act, is a fiber grown naturally as the coat
of a living animal. Since the Act does not specify sheep as the sole source of
In addition to the 23 classes above, several new fibers have not yet been clas- wool, any fibers classified a s animal hair fibers can legally be labeled a s wool.
sified. To establish a new generic name, manufacturers must apply in writing However, most products labeled a s wool are derived from sheep. Manufactur-
to the Federal Trade Commission. New generic names are added to the list a s ers have the option, and usually prefer, to specify the animal of origin if other
the commission approves them. than sheep.
Man-made fibers formed by combining two or more generic classes of poly- Protein fibers made from animal secretions include all varieties of silk from
mers a s the fiber is made are classified according to how the polymers are com- cultivated or wild silk caterpillars or spiders.
bined. These are called:
B bigeneric, TEXTILE LABELS
bicomponent, A wide variety of labels are attached to textile products, especially wearing
biconstituent, or apparel. Many of these labels are required by federal legislation.
W matrix fibers. A brief summary of the major labels required for the textile rental industry
Manufacturers of these fibers must indicate the generic name of the compo- follows:
nents used to make the fiber. For example, fabric made from a matrix fiber H The Wool Products Labeling Act of 1939 (amended in 1980) requires labels
composed of 50 percent vinyon and 50 percent vinal must be labeled: 100 per- for wool or part-wool products to indicate whether the wool content is new
cent matrix fiber (50 percent vinyon/50 percent vinal). wool (called wool, virgin wool, or lambs wool) or recycled.
H The TFPIA requires most textile products to be stamped, tagged, or labeled
NATURAL FIBERS with:
Natural fibers are not classified by any universal method, so a logical choice 1. the fiber or combination of fibers used in the item identified by generic
is to classify them according to their origin. This system includes three broad name (man-made fibers) or common name (natural fibers). All fibers
categories of fibers: must be designated with equal prominence.
Icellulosic, 2. the percentage by weight of each fiber present, excluding ornamentation
H protein, and and fibers not exceeding five percent by weight of the total fiber content.
W mineral. Percentages must be accurate within a tolerance of three percent of t h e
total.
Cellulosic fibers 3. for upholstered products, information on whether the stuffing has been
Cellulose is the primary solid substance in most plants. However, only certain used a s stuffing in another upholstered product.
sections of some plants provide fibers that are suitable for making textiles. 4. the name or other identifying mark of the product's manufacturer.
Fibers that grow from the plant seed are called seed hairs. In the case of cot- 5. if the item is imported, the name of the country of origin.
ton, the seeds and seed hairs are combined in a boll. Other suitable seed hairs 6. other items of information, such a s fiber trade names, a s long a s they
come from milkweed, kapok, and cattail. Fibers that are found in the stalk of don't violate the Act.
the plant are called bast fibers. These include flax, ramie, hemp, jute, and U Fabric flammability standards currently are in effect for entrance mats,
urena. Leaf fibers suitable for textile use are obtained from abaca, pineapple, carpets and rugs, mattresses and mattress pads, and some clothing. Labels
agave, palm, and yucca plants. Fibers found between the husk and the nut of must specify how much flammability protection can be expected from t h e
the coconut, referred to as nut husk fibers, also have been used for textile items. item. Since laws and regulations may change, operators must consult cur-
rent requirements to ensure compliance.
Protein fibers
Protein fibers are obtained from animal hair, fur, or secretions. COMMON FIBERS ENCOUNTERED IN PROFESSIONAL LAUNDRIES
The largest category of protein fibers come from animal hair and include Not all of the fibers mentioned so far are used in products processed by the pro-
fessional launderer. The ones most often encountered are listed on the follow-
ing pages in alphabetical order. Figure 64:Nonmercerized cotton' Figure 62: Mercerized cotton
Acetate Cross-section 5OOX Cross-section500X
Acetateis used in blends with cotton or rayon a s well a s with other fibers. When
blended with nylon or acrylic, it imparts a softer hand to the fabric.
Acetate has many excellent characteristics. It resists shrinking, spotting,
and staining. I t dries quickly, h a s a soft, natural feel, isn't attacked by moths,
and is mildew resistant.
On the other hand, acetate is thermoplastic, meaning it softens or melts
when exposed to heat above 350°F and must be pressed or ironed with extreme
care. Acetate burns readily and melts while burning, leaving a blackened
residue. In addition, temperatures from 194' to 225OF cause acetate to lose
strength.
Acetate decomposes when exposed to strong acids and weak organic acids
such a s acetic acid and perspiration. Strong alkalies cause swelling and loss of
fiber strength, while acetone and solvents used in fingernail polish removers
and lacquers dissolve acetate.
Aramld
Aramid was first introduced as a type of nylon but has properties very different
from most nylons - it's very strong and highly heat resistant.
In 1974, the generic definition for nylon changed, and the generic term
aramid was added to the TFPIA. The most common trade names for aramid are
Nomex and Kevlar (duPont trade names).
Aramid is used in applications requiring high strength and/or heat resist-
ance. Nomex is used in covers for laundry presses and ironers, fire fighters'
apparel, and flame-retardant furnishings for aircraft. Kevlar is used to rein-
force radial tires and to manufacture cables, body armor, and gaskets.
Cotton
Cotton fibers usually vary in length from three-quarters of an inch to one and Longitudinalview 5OOX Longitudlnaiview 500X
one-half inches. In general, the longer the fiber (staple length), the better the
quality of the textiles. Water a t the boiling temperature or below has no effect on cotton fiber other
While cotton fiber has very little tendency to shrink, cotton fabrics do. Shrin- than to soften it and cause it to swell.
kage occurs when cotton fabric "relaxes" from beingstressed. The fiber can be The action of hypochlorite on cotton varies according to the concentration
stressed - stretched or elongated - up to about seven percent, usually in and temperature. Hypochlorites are used extensively for bleaching cotton.
manufacturing. The shrinkage caused by this relaxation commonly occurs When properly controlled, they are also effective for sterilizing and for remov-
during the first washing cycle and may be a s great a s 15percent. Once the fiber ing oxidizable stains. Hypochlorite solutions will damage cotton if the concen-
has relaxed, no more shrinkage should occur. tration (with respect to the amount of available chlorine) is used a t too high a
Mercerized cotton has undergone a strong caustic solution treatment to temperature or a t too low a pH. Cellulose converts rapidly to oxycellulose with
cause permanent swelling of the fiber. The swollen fiber has a high luster and a n accompanying weakening or even destruction of the fiber. In addition,
increased strength. hypochlorite solutions should be used judiciously on colored cottons because
Mercerizing and relaxation shrinking offabric increase the number of yarns they can damage dyes.
per inch, causing the fabric to seem to gain in strength. Alkali solutions, even a t boiling temperatures, do not weaken cotton fibers.
Cotton material, especially when coated by foreign organic matter such as However, fibers can be damaged during high-temperature drying and ironing
starches and gums and when stored in a warm moist atmosphere, is likely to be
attacked by certain low-order plant organisms, known a s mildew. Mildew dis- *Figures 6-1 through 6-8 are copyrighted by the American Association of Textile Chem-
colors and decreases the strength of cotton. ists and Colorists.
if strong residuals of alkali are left in the fabric. Proper souring prevents this The color of unbleached flax varies from cream to gray, depending on pre-
damage. vious treatment of the fiber. Bleaching may make linen snow white, but t h i s
In general, concentrated mineral acids damage cotton severely and, in many tends to weaken the fiber. Consequently, linen often is used at various stages of
cases, destroy it completely. Cold dilute mineral acids have less action on cot- bleaching, such a s half-bleached, quarter-bleached, or unbleached.
ton if the last traces are washed out. Hot dilute acids, such a s sulfuric acid, Linen fibers have a high cellulose content and are uniform in thickness - 12
weaken cotton if left in contact with it for any length of time. to 25 microns or millionths of a meter. They may vary in length from a few
Volatile organic acids, such a s acetic and formic acids, have less effect on inches to nearly five feet, depending on the manufacturing process.
cotton a t o r d i ~ a r ytemperatures; but a t high temperatures, they may damage Like cotton, linen is decomposed by hot solutions of strong acids and by oxid-
the fiber. These two acids were widely used a s neutralizing or souring agents izing bleaches. The first action of the acid or bleach i s to weaken the fiber.
but have been discontinued because they have unpleasant odors. Strong alkaline solutions do not cause much weakening of the linen fiber
Excessive use of some types of sours can lead to acid damage during high- unless the solution is hot.
temperature drying and ironing. Linen, when subjected to a temperature of 300°F or more for any length of
time, gradually turns brown and weakens. At 500°F, linen fibers decompose
Flax (linen) rapidly.
The flax plant, which normally has a single stalk with a few branches, gmws to
a height of several feet. The fiber itself occurs in the inner bark of the plant. As Nylon
would be expected, the quality of the fiber depends on the type of flax grown Nylon was the first truly synthetic textile fiber to find practical use. The aver-
(coarse or fine), seasonal conditions, and the time and manner of harvesting.
Figure 6-4: Bright nylon Figure 6-5: Low-modificationratio trilobal nylon.
Figure 6-3:Flax (linen) 15 denier per filament, bright luster
Cross-section500X
As the polyester and cotton fibers are blended during the finisher drawing operation, the
blend becomes more uniform. This illustration, taken with ultroviolet light, clearly shows the
Yarns are usually converted into fabrics either by weaving or knitting. presence of the fwo fiben and the resulting blend as the drawing operation proceeds from
Weavinginterlaces two ormoresets of yarns, oneof which is always atright the feeding of the individual fiber slivers to the final blended sliver and to the roving.
angles to the other sets. The set of yarns that runs the long dimension of a roll
or bolt of fabric forms the warp, and theindividual warp yarns are called ends.
A second set of yarns interlaced a t right angles to the warp in a predetermined
pattern is referred to a s filling, weft, or woof. Individual filling yarns areidenti- double and plain or patterned. In warp knitting, loops made from each warp
fied a s picks. yarn are formed along the length of the fabric. Warp knits are usually formed
Enlarged views of basic weaves are shown in Figure 6-11 through 14. Elabo- i n a flat, single layer and can be plain or patterned. The essential elements of
rate designs can be produced in woven fabrics by combining these basic knitted fabrics are described in Figures 6-15 and 16.
weaves.
Knitting forms a fabric by interlocking loops of yarn. The two basic types of
knitting machines are weft and warp. Weft knitting forms fabric by interlock-
ing loops of yarns across the width of the fabric. Weft knits may be single or *Figures 6-10 through 6-16 copyrighted by Spring Mills, Inc.
Figure 6-4 4: Plain weave fabric
PRESS Wash or
Pntcure dryclean.
1 RATH
DRYING OVEN
press
LAUNDRY PROCEDURES 7
&
Conventional Home wash 120'
postcunr or dryclean
BATH
T
his chapter deals with all phases of laundry operations: soil separation
and washer loading, processing steps, general formulas based on soil con-
Low-temperature tent, applying the general formulas to item classifications, and chemical
Vapor
phase wash or dryclean handling in the washroom.
PAD
BATH CHAMBER
PREWASH STEPS
Soil sorting
Textiles should be sorted according to soil classifications such as light,
medium, and heavy because not all items require the same laundering process
Durable soil-release finishes are applied during fabric manufacturing. or intensity. Proper soil sorting allows the load to be matched to the best for-
Durable finishes are either a soil-resistant or soil-release type. Soil-resistant fin- mula for soil removal, resulting in the most economical use of chemicals, water,
ishes are designed to resist penetration by either waterbornestains or oilborne
stains. Finishes that resist penetration by waterborne stains are very similar --
and enerav.
Proper sorting also reduces textile damage and extends the life cycle for
to water-repellant finishes and are usually based on silicone or fluorochemi- lightly soiled items, which otherwise would be exposed to excessively intense
cals. Other fluorochemicals can be used to produce resistance to oilborne soils. laundering procedures. Hotel and motel sheets, for example, require less laun-
Soil-release finishes function by attracting water and allowing the water to dering supplies, water, time, and energy for processing than do kitchen and bar
remove the soil. Acrylic-based soil-release finishes may increase the stiffness towels. Pillowcases usually require heavier laundering procedures than do
of the fabric. sheets from the same hotel or motel to remove hair and body oils, lipstick and
cosmetic stains.
The finishing method also governs how textiles are sorted. Laundry opera-
tors should separate items to be fully dried from items to be conditioned. Items
to be finished on different types of equipment, a t different speeds on the same
equipment, or with different crewing on the same equipment need to be sorted.
Fiber content also influences soil sorting. Polyester/cotton blends should be
separated from cotton items. Polyester blends must be handled differently from
cotton because the thermoplastic nature of polyester requires lighter load
weights, gradual cooling during rinsing, and very light extraction.
Items of 100 percent polyester should be separated from polyester/cotton
blends. Polyester/cotton blends require more extraction than does 100 percent
polyester to remove the moisture held by the fabric.
The system of soil classification by item suggested in Table 7-1allows for dif-
ferences in individual plants and is widely used.
The weight of water and soil in soiled fabric can vary from almost none to a
Table 7-1: Soil classification by item
sizable percentage of the fabric weight. In order to provide consistent stand-
Vew Vey shop ards, loading factors normally are based on the weight of clean, dry fabric pro-
Item ligk Light Medlum Hecnry hecnry towels cessed.
Hotel/motel Load sizes have increased over the years. In the 1930s, commercial laundry
Sheets practice in the U.S. was to load wooden washers a t about 3 pounds per cubic
Pillowcases foot and metal washers a t about 4.5 pounds per cubic foot. British Launderers
Bath towels, mats Research Association standards in 1945 specified 3.5 pounds per cubic foot
Heatthcare loading for cottons.
Spreads Following World War 11, load sizes began increasing. In the 1960s, it became
Hospital linen virtually universal practice to load a 42- by 84-inch washer a t 350 pounds, cor-
Operating room linen responding to a load capacity of 5.2 pounds per cubic foot. Larger diameter
Pediatrics washers permit somewhat higher loading factors.
Nursing home linen Tunnel washers have a load range from about 1.2 to 1.9pounds per cubic foot
General linen supply w/o of compartment volume.
Dehairing Dehairing The volume in cubic feet of a washing cylinder can be computed from Equa-
Barber towels
Hair cloths tion 7-1:
Continuous towels
Dental/doctor towels Equation 7-1:
Hand towels v = d2z/2200
Massage towels Where:
Roller towels v = volume in cubic feet
Diapers d = diameter in inches
Food sewice z = length in inches
Table tops
Napkins Overloading leads to poor laundering performance. Supplies can't be distrib-
Colored table linen uted properly throughout the load, and the tightly packed condition of the tex-
Garments tiles impedes dilution, lowers soil removal, and results in poor mechanical
Aprons action. Additional rinses may be required to remove loose soil and supplies
Kitchen/bor towels remaining in the load; or frequently, loads must be rewashed.
Indudrial Underloading also can result in poor performance due to less mechanical
Garments action and can lead to excessive costs if water levels and chemical concentra-
Dust control tions are not adjusted accordingly.
Entrance mats Some fabrics must be underloaded because of their bulk a s compared to their
Sweeping cloths weight. Garments containing polyester blends.usually are loaded a t 65 to 85
Dust mops percent of calculated capacity to minimize wrinkling and provide easier subse-
Wet mops quent finishing.
W~pingcloths Loading figures should be based on equivalent clean, dry textile weight.
Printer wipers Operators who want to load on the basis of soiled weight must use a reliablesys-
Shop towels tem for converting clean, dry weight to soiled weight for each individual plant
classification. Data collected in the plant is used to determine the ratio of soiled
to clean weight to establish proper load sizes. Approximate figures for these
Guidelines for loading ratios are given in Table 7-2.
Washer loading is expressed a s pounds of fabric per cubic foot of cylinder To use Table 7-2, multiply the weight of the textiles desired on a clean, dry
volume. Loading: weight basis by the ratio forthat item given in the table. The resultingfigure is
varies with fabric and machine type; the weight of soiled textiles that corresponds to the required weight of clean
affects soil removal, fabric strength, and, in certain fabric types, the ten- textiles. For example, if a washer has a rated capacity of 350 pounds of textiles
dency of blended fabrics to wrinkle; and on a clean weight basis and the load consists of bib aprons, then 350 pounds x
influences the costs for chemicals, water, and energy.
Table 7-2: Ratio of soiled to clean weight Brecrk
for various textile classifications (examples only) The word "break" is used to describe the first wash-chemical bath. In light- and
medium-soil formulas, all of the surfactant and alkali to be used i n the entire
m o : Soiled weight formula generally is added to the washer in the break bath.
Ifem Clean weight The break is the single most important step in the laundering process from
the standpoint of soil removal. It is a crucial checkpoint for chemical control.
Sheets, pillowcases. continuous towels. For optimum soil removal in medium-soil classifications, the total sodium
hand towels, family work 1.O
oxide content of the break solution must be between 500 and 1,000 ppm. For
Table linen 1.O
Bib aprons 1.15 heavier soil classifications, higher concentrations of sodium oxide are required.
Garments 1.0 up For surfactant-based products, the surfactant, not the alkali, h a s the major
Kitchen and bar towels 1.3 cleaning role, which means that high alkali concentrations may not be
Infant diapers 1.45 necessary.
Shop towels (industrials) 1.5 up The break bath is monitored by titrating with phenolphthalein to measure
active alkalinity. The total or methyl-orange alkalinity also may be measured
1.15 = 402.5 pounds or approximately 400 pounds of soiled aprons is the correct
load size. by titration. Titration procedures are explained in Chapter 1.
The figures i n Table 7-2 are merely guidelines; the ratios will vary with indi- Some alkalies have much of their titration value below the phenolphthalein
vidual plant conditions. Consequently, each plant must determine these ratios limit; for example, 50 percent of the titratable alkalinity of sodium carbonate
by weighing soiled loads and comparing the soiled weight to the clean weight (soda ash) lies above pH 8.3, with the remainder lying below this value. Alkali
for the same load after processing. If proper soil sorting is practiced, the ratio of that titrates below pH 8.3 is considered inactive.
soiled weight to clean weight should be consistent and will need to be deter- In general, most of the alkalinity of the silicated alkalies (sodium metasili-
mined only pericdically. cate, sodium sesquisilicate, and sodium orthosilicate) is available above pH 8.3.
Counting is another method of sizing washer loads. Operators determine the
number of clean, dry aprons, towels, garments, or other items needed for a Suds and carryover suds
proper load size and make up soil loads by counting out that number of items Any number of suds and flush baths may occur between the break and bleach
kach time. baths, depending on the nature and intensity of the load's soil content.
Suds baths are carried out a t low water levels, usually with hot or tempered
WASH STEPS water. The temperature of the water is thermostatically controlled. Suds baths
Flushes are referred to a s carryover suds; no alkali or detergent is added. Their function
The word "flush" is used to describe a fairly quick, high-level bath prior to the is to:
break or the bleach bath. (The word "rinse" is usually reserved for high-level Iincrease soil removal by lengthening thecontact time between alkali/deter-
baths following the bleach bath.) gent and fabrics a t a n elevated temperature,
Flushes generally are used to condition textiles before subsequent baths and Ilower the soil content of the water in the washer and textiles prior to bleach-
to remove debris and loose soil. ing, and
Hospital work is sometimes given a n opening flush or flushes a t a low W reduce pH and total alkalinity to the level a t which bleaching can be carried
temperature-below llO°F-so a s not to set blood a n d albuminous stains out most effectively.
(blood, serum, and many proteinaceous stains are set a t temperatures above
llO°F). Bleach suds
Many operators also add some alkali to this initial flush to prevent setting of The bleach suds bath is the last point a t which detergency-promoting agents
blood stains. This reasoning is valid only if the alkali is distributed throughout are added to the laundry formula.
the load before blood stains are set; however, some alkali or a surfactant in a In the past, this step has been referred to a s the "bleach suds" because a light,
low-temperature flush can be beneficial in removing blood stains. running suds was the visual indicator that the pH was correct. But the advent
Flushes also are used to: of low-sudsingsynthetic detergents and the practice of adding flushes between
W raise washing temperatures from low to high, brcak and bleach to lower alkalinity have made pH testing a necessity to deter-
lower temperatures from high to low, mine that the pH is correct for bleaching.
Ilower alkalinity prior to bleaching, The key measurement of the bleach bath is pH, although titration values can
W lower the soil concentration, and more. also have meaning, especially when the chemical composition of the alkali is
known. The pH of the bleach bath a t 150°F should fall within 10.2 to 10.8 for
Other special applications of flushes are discussed in the formula section chlorine bleach. A pH below 10.2 results in accelerated bleach action, with its
starting on page 98.
accompanying fabric damage, while a pH above 10.8retards bleaching action, It is good practice to check for residual chlorine bleach in the last rinse by
which lessens stain removal and causes trailing of unspent bleach into the sub- adding a few drops of a 0.1 percent solution of orthotolidine reagent as described
sequent bath. in Chapter 1.The reagent can be added to a sample of the rinse solution or can
Bleach pH values may be lower provided water temperatures are also lower. be dropped onto the fabric itself. If fabric is used, it must be thoroughly rinsed
and rewashed.
Rinsing A yellow color indicates the presence of chlorine. However, tap and softened
Rinsing i s the term used for baths following the bleach and preceding the sour waters used in rinsing also may contain sufficient available chlorine to be
or finishing bath. detected with orthotolidine reagent, plus some water impurities may produce
Duringrinsing the final portions of loosened soil are removed along with the false-positive results.
bulk of the washing compounds used in laundering. The temperature of the Dilution. Rinsing also accomplishes dilution, a key function in the overall
load
.-- also is gradually reduced to the point a t which textiles can- be .
removed
. washing process. The degree of dilution depends on the type of fabric being
from the washer. ~ i i s e are
s always carried out a t a high water level and usu- processed and whether high or low water levels are used. Cotton retains more
ally with no additional chemicals except for antichlors. water than polyester.
The number of baths required to complete the washing cycle is determined by The cost of water has risen dramatically in recent years, a s have the costs of
the amount of dilution needed to remove the soil and lower the alkalinity and softening, heating, and disposing of it. For these reasons, less rinsing is done
chlorine content. Titration measurements help determine the proper number of today than was thought necessary in past years. A minimum of four rinses, two
rinses. The following paragraphs deal with the controllable factors in rinsing, hot and two split, was the rule a generation ago. Today, three rinses or two
which have a bearing on the minimum rinsing requirements. rinses and a n intermediate extraction are common.
Tem~erature.Rinsing lowers temperature a s well a s soil content, alkalin- The following mathematical model illustrates the magnitude of dilution in a
ity, and chlorine content. rinsing process. Under ideal conditions, the amount of soil remaining after any
Usuallv the temperature of the wash load is between 130' and 150°F.when . - number of baths in a washer can be calculated a s shown in Equation 7-2.
the bleaclh bath is dumped. The optimum temperature for handling a wash load
with bare hands is in the range of 95' to 105OF.This means that rinsing reduces Equation 7-2 :
temperature by about 35 to 45 degrees if the load will be removed by hand
(pulled). If the washroom has self-dumping equipment or washer/extractors, s, = % (VfNtY
Where:
the linen can be dumped from the equipment at 130' to 140°F. x = number of baths
Number of rinse baths. The function of the rinse baths is to remove loos- S, = concentration of soil after x baths
ened soil (most of which has been eliminatedprior to the bleach step) and the Si = amount of soil present before washing/rinsing begins
chemicals used in laundering (alkali, detergent, and bleach). All of the chemi-
-- Vf= amount of water held by the fabric after draining
cals are highly soluble and are easily removed a t a water temperature of from Vt = total amount of water to achieve the set water level
110° to 140°F. with the washer loaded (includes Vf)
The best way to check rinsing adequacy or completeness is to titrate for the Assume the titration of the bleach bath is three drops 1.0 N (N/l) acid. This
amount of residual alkalinity. Each rinse must be titrated and compared with alkalinity is expressed a s a concentration of 186 pprn sodium oxide (Si)A 42-by
that of the tap or softened water being used in the rinse. This procedure is de- 84-inch washer loaded with 350 pounds of cotton fabric will retain 105 gallons
scribed in detail in Chapter 1.The final rinse titration should be in the range of of water (Vf) after draining. To reach a 12-inch rinse level requires an addi-
50 to 125 pprn bicarbonate above the tap-water titration. tional 116 gallons of water, producing a total rinse water volume of 221 gallons
For many years, experts said that the differential should not exceed 50 pprn
bicarbonate. This was true when all-cotton textiles, which are highly sensitive
+
(Vt=Vf+ water to produce 12-inchlevel or 221 = 105 116). Equation 7-2 is ap-
plied below to show the dilution of the concentration of 186 pprn sodium oxide.
to yellowing from alkaline scorch in tumblers and on presses, constituted 95 to
99 percent of the fabrics used by textile rental operators. However, currently a Concentration after first rinse: (SI) = 186 pprn (105/221)' = 186 (.475) = 88 pprn
125 pprn bicarbonate differential between tap and the last rinse is sometimes Concentration after second rinse: (52) = 186 pprn (105/221)2 = 186 (.475)"
acceptable because of the increased use of polyester/cotton textiles and fabric = 186 (.226) = 42 pprn
concentration after third rinse: (S3) = 186 pprn (105/221 )3 = 186 (.475)3
brighteners in many laundering supplies, a s well a s the need to conserve water
= 186 (.107) = 20 pprn
and heat. If titration shows that alkalinity is reduced sufficiently, usually the
other laundry chemicals are reduced enough for the textiles to proceed to sour- The chemical concentration after the third rinse is approximately equivalent
ing and finishing. to three drops of N/1 acid. This rinse bath would consume a total of 348 gallons
(116 gallons for each of three rinses), which is considered adequate rinsing by
current standards.
Different concentrations are obtained for 50/50 polyester cotton, which sour or acid bath is to neutralize the alkalinity of the water in the textiles before
holds about 55 percent as much water as cotton after draining (Vf= 58 gallons). finishing. The function of the sour and its role in the process have been de-
To reach a 12-inch rinse level, a rinse volume of 174 gallons (Vt) is needed. scribed in Chapter 5.
Concentrationafter first rinse: (Si) = 186 (581174)' = 186 (.333) = 62 pprn
Souring is done a t a low water level, generally a t the temperature desired for
concentrationafter second rinse:( S 2 ) = 186(58/1 74)2= 186(.333)== 186(.111)= 21 pprn extracting and finishing the textiles. Higher souring temperatures improve
extraction and reduce drying time. Souring time varies depending upon
To achieve the same dilution effect on poly/cotton a s with all cotton (20 pprn conditions.
or three drops of N/10), only two rinses consuming a total of 232 gallons [2 x In this bath, other finishing supplies such a s fabric softeners, antibacterial
(174-58)]of water are needed since poly/cotton rinses more rapidly than 100 agents, brighteners-even starch-may be added along with the sour. Starch
percent cotton and requires fewer rinses. use general1y requires lengthening the bath time.
Another factor t h a t governs the number of rinses needed is the type of equip- Proper souring is determined by monitoring the pH ofthe finished work. This
ment used. Washer/extractors allow an intermediate extract. One of the rinses can be done in two ways:
may be followed by 30 to 60 seconds of extraction, which spins off some of the The pH of the sour solution can be checked in the same way described for the
water from the textiles, reducing soil, alkali, detergent, and bleach content, and bleach bath, using a pH meter, slide colorimeter, or pH papers on a sample of
allowing the machine to take on more water on the subsequent filling. In the sour bath.
cotton example, the dilution produced by following the first rinse with an inter- By far the most commonly used technique is to drop Universal Indicator
mediate extraction is increased because Vf is reduced to 53 gallons from 105 and onto an item in the washer. Universal Indicator is a pH-sensitive formula-
an additional 168gallons (instead of 116) must be added to achievethe 12-inch tion of dyestuffs that indicates pH by color.
rinse level: Recommended souring guidelines are given in Table 7-3.
Concentration after first rinse and intermediate extract: Table 7-3: Sour guidelines*
(S,) = 186 p p r n (53/221) = 45 pprn
concentration after second rinse: (S2) = 45 pprn (1051221) = 21 pprn sour color pH range lndlcafes
Bluegreen to blue above 7.5 Not soured
The total water consumed is 116 gallons to fill the first rinse plus 168 gallons Green 6.5-7.5 OK for flatwork
to fill the second rinse for a total of 284 gallons. A general guideline is that the Yellow 6.0-6.5 Mid-range
dilution effect of a n intermediate extraction is equivalent to one rinse. This Orange 5.5-6.0 OK for towels
procedure is particularly suited to loads containing all-cotton goods. With one Red 4.5-5.5 OK for diapers
less rinse operation, water savings result despite the fact that the water
removed during extraction must be replaced on the next fill to reach the desired 'Using Universal Indicator as supplied in the TRSA Washroom Test Kit.
rinse level. Extraction
I n the cotton example, two rinses and a n intermediate extraction using 284 Extraction is used to lower moisture.
gallons of water yield the same dilution effect a s the 348 gallons needed for Laundering begins by saturating the textiles; no free water will accumulate
three rinses and no intermediate extraction. The actual production time may be in the cylinder until the textiles have first absorbed water up to the saturation
the same for both procedures because some machines require additional time to point. For cotton, this is approximately 0.3 gallons per pound or 2.5 pounds of
start and stop a n intermediate extraction. water per pound of cotton. For 100 percent polyester, the waterretained between
Antichlors. Antichlors are added to rinses to help remove residual chlorine. the fibers is about 0.1 gallons per pound or 0.8 pounds of water per pound of
They are generally added to the first or second rinse following the bleach and polyester. Thus, a 350-pound load of cotton will hold about 105 gallons (875
also may be combined in the sour bath. Common antichlors are sodium bisul- pounds) of water when saturated. A 350-pound load of polyester will hold
fite, sodium thiosulfate, or proprietary products; usage is usually a t the rate of approximately 35 gallons (292 pounds).
0.5 to 2.0 ounces per 100 pounds of textiles. The water consumption of laundering formulas is determined by adding the
Antichlors can help conserve water by reducing thenumber of rinses. They're amount of water required for saturation to the amount of free water in the
often added if there is danger t h a t fabrics will retain available chlorine even washing cylinders. Extraction reduces water content in textiles to 25 to 70 per-
though the rinse water sampled a t the dump shows n6 residual chlorine present. cent moisture retention, depending on the type of fabric and equipment.
For example, certain resin finishes such a s some permanent-press finishes are Moisture retention is a n expression of the ratio of the weight of the retained
chlorine-retentive. This is why antichlors usually are added if chlorine bleach moisture to the weight of the clean, dry textile. Clean, dry weight is most con-
is used in laundering resin-finished garments. sistently determined in the plant by weighing textiles after full drying. A
Sour bath pound of cotton textile holds 0.3 gallons of water (2.5 pounds) or 250 percent of
Souring is normally the final step in the launderingprocess. The purpose of the the dry weight.
96
Extraction reduces retained moisture to 50 percent, removing two pounds of these measurements are outlined in Chapter 1.
water per pound of fabric. Since 50/50 polyester/cotton retains only 1.7 pounds Titrations for active and total alkalinity are conducted using phenolphtha-
of water per pound of fabric, only 1.2 pounds mut be removed to reach the 50- lein and methyl orange indicators, respectively. The relationship between the
percent moisture-retention level. However, polyester/cotton textiles come out phenolphthalein (active alkali) and methyl orange (total alkali) endpoints
drier than cotton for the same extraction effort. depends on the chemical constitution of the alkali, that is, the ratio of active
Extraction takes place automatically in washer/extractors; controls shift and total alkali, a s described in Chapter 1.
the washer into high-speed rotation following the laundering cycle. Early research on removing soil from fabric pointed to a distinct correlation
With conventional and tunnel washers, however, the work must be removed between the efficiency of particulate soil removal and the amount of sodium
from the washer and loaded into a separate extractor. There are two types of oxide (Na20) contained in the detergent solutions. Based on their findings,
extractors: centrifugal and hydraulic. washroom chemists suggest maintaining total alkalinity (Na20)limits a t 250
In centrifugal extraction, the centrifugal force spins the water out of the to 500 ppm for light soil, 500 to 1,000 ppm for medium soil, and 1,250 to 3,000
fabric. I n one type of hydraulic extractor, the water is squeezed from fabrics by ppm for heavy and extra-heavy soil.
means of fluid pressure exerted against a flexible diaphragm i n which the tex- These guidelines are not appropriate for surfactant-based products that rely
tiles rest. I n another type of hydraulic extractor, fabrics are placed between a on the surfactant content rather t h a n alkaline content for cleaning. For these
piston and a bulkhead. The piston is forced toward the bulkhead, thus squeez- products, titrations are used only to measure detergent concentration. Appro-
ing water from the textiles. A hydraulic press is usually used with tunnel priate titrations vary from product to product.
washers. The following formulas represent guidelines based on many years of
Each method of extraction h a s advantages a n d disadvantages, but regard- research a n d in-plant experience. They may be used a s written for alkaline
less, extraction is a more cost-effective method of removing water than dryers, products or modified to suit the characteristics of soil classification, type of
washer, or other variables in a n y given laundry.
ironers, and presses.
The extraction process is most efficient a t high temperatures and if fiber lub- The authors, task force committee, and publishers present these formulas a s
procedures for producing clean textile products a t reasonable consumption
-ricants
- - -- ..- such a s fabric softeners have been added to the sour bath. In general,
-
the warmer the fabric extracted, the better the moisture removal. levels of water, energy, and chemicals. No consideration h a s been given to
modifications t h a t may be necessary to meet wastewater requirements or to
GENERAL LAUNDRY FORMULAS protect laundry workers from exposure to hazardous soils. Each operator is
Sorting by soil content and item classification h a s been described earlier in responsible for ensuring that plant procedures are in compliance with all envi-
this chapter. In this section, basic formulas are described for five levels of soil ronmental and safety requirements.
Operators must obtain Material Safety Data Sheets (MSDS) from customers
content:
for hazardous soils that are likely to be on the soiled textiles a n d consult with
Ivery light soil,
Ilight soil,
water treatment facilities and other appropriate agencies to ensure all proce-
Imedium soil,
dures are in compliance.
Iheavy soil, Very light soil
Ivery heavy soil. Table 7-4 is a formula for very lightly soiled items such a s hotel sheets. The
Beginning - on page
- 104 of this chapter, these formulas are applied to the formula suggested here i s a one-suds procedure with a six- to eighbminute
com&on item' classifications listed in Table 7-1: break suds. One quart of 1.0 percent chlorine bleach per 100 pounds of textiles is
Ihotel/motel, included along with alkali and detergent. This is followed by two rinses using
Ihealthcare, tempered water to cool t h e load to the desired finishing temperature. The sour
Igeneral linen supply, including food service a n d other items,
bath, which may include fabric softener, antibacterial agent, antichlor, and
Iindustrial garments, brightener, follows rinsing.
dust control, and If the hot water tank i s set a t about 165OF,expect a break temperature of l3s0
Iwiping cloths.
to 145OF, which is well within the limits for proper use of bleach.
The last three classifications-industrial, dust control, and wiping towels-
vary enough from the general soil-content formulas to warrant specific formu- Light soil
las of their own. The formula for light soil in Table 7-5 is a two-suds procedure with t w o five- to
For each formula, supply usage i s based on pH and titration values. Meas- seven-minute steps followed by three rinses and a sour. Formulas for very light
uring and closely controlling pH is essential for bleaching and souring baths; soil and light soil differ in two ways:
titrations normally are confined to sudsing and rinsing baths. Procedures for IVery-light-soilforn~ulasadd bleach to the break; in the light-soil formula, the
bleach step follows the break.
99
Table 7 6 : Very-light-soil formula The light-soil formula calls for three rinses, whereas only two are suggested
in the very-light-soil formula.
Supply usage The break titration for the light-soil sequence is higher t h a n for very light soil
Water Temperature Tlme Supply
Operatlon level (OF) (min.) type PH Titratlon because the light-soil formula requires more alkali a t the break t h a n does the
very-light-soil formula. Because time and washing compounds increase, deter-
Break suds Low 135-145 6-8 Alkali, swp/ 9.8 60 to 180 pprn gency increases with the light-soil formula.
detergent, to Na,O ( I to 3
Preliminary flushing is used for blood and albuminous stains. When there
bleach 10.8 drops N/l with
phenolphthalein) are no blood stains, the formula can begin with the break suds bath.
Rinse High 120-140 1-2 Antichlor Rinse Hiah 120-130 1-2 Antichlor
Rinse High 105-115 1-2 50 to 120 pprn Rinse High 105-115 1-2 50 to 120 ppm
HCOj (4 to 10 HCOj (4 to 10
drops N/10 with drops N/10 with
methyl orange) methyl orange)
over tap
Finish Low 105-115 4-6 Sour, softener. 5.5
bacteriostat to Finish Low 105-115 4-6 Sour, softener, 5.5
7.0 bacteriostat to
7.0
Heavy soil Table 7-8: Very-heavy-soil formula
This classification represents a departure from previous formulas. Heavy soil
removal requires a high water temperature, 165' to 180°F, and greater alka- Supply usage
Water Temperature Tlme Supply
linity than for medium soil. To remove the added alkali, the formula calls for a Operation level (OF) Win.) tVpe
flush or flushes following the carryover. The flushing reduces bleach bath pH pH Thotion
below 10.8, assuring proper bleaching. Flush' High 100-110 2-5
Another significant difference is t h a t the time devoted to the break a n d Flush High 140-160 1-2
bleach baths is longer t h a n in previous formulas. For proper cleansing action,
Break suds Low 165-180 15-20 Alkal~.soap/ 11.8 1,800-2.150 ppm
soil and stain levels in this classification need longer contact with laundering
detergent to Na,O (30 to 35
solutions.
12.6 drops N/l with
phenolphthalein)
Table 7-7: Heavysoil formula
Break suds Low 165-180 10-12 Alkali. soap/ 11.5 1.250-1.550 ppm
detergent to Na,O (20 to 25
Supply usage
Water Temperdun, Tlme Supply 12.5 drops N/l with
Operation level (OF) (mln.) type pH Tltrdon phenolphthalein)
Flush' High 100-110 25 Suds LOW 165-180 5-8 h p /
detergent
Flush -
Hiah 140-160 1-2
Flush High 140-160 1-2
Break suds Low 165-180 10-12 Alkali, soap/ 11.5 1,250-1.550 ppm
deteraent
" to Na,O (20 to 25 Flush High 140-160 1-2
12.5 dr&s N/I with
phenolphthalein) 9.8
Bleach Low 135-145 8-10 Bleach to
Carryover Low 165-180 10-12 (Soap/ 10.8
~ ~~
excluding table linen. Hospital stain rejects usually range from four to seven Rinse High 100-125 2
percent.
Rinse High Cold-100 2 50 to 120 Darn
Color transfer. Color transfer on healthcare linens occurs when hospital
greens, blues, and whites are laundered together. The colors transfer from HCO; (4 ~O'IO
colored to white fabrics, producing a tinting on white. This tinting is perman- drops N/10 with
methyl orange)
ent because polyester does not release color. Although dyed polyester fibers are over tap
fast to laundering, the migration of loose dye contained on new fabrics is suffi-
cient to produce this tinting effect. 5.5
Sour Low Cold 4 Sour to
This problem can be avoided by simply separating whites and colors.
6.5
-
General linen supply 'Bleach is added here for white classifications.
General linen supply covers textile items such a s aprons, the many types of
towels used in commerce and industry, table linens, and wearing apparel not or tunnel.
soiled with mineral greases.
- (The "general linen supply" and "food service" Industrial garments are usually heavily soiled with mineral soils and
items in Table 7-1.) greases, and a few operators elect to dryclean them. Drycleaning prevents the
The soil content of these items ranges from medium (white and colored table problem of wrinkling, since solvent temperature a n d moisture levels are nor-
linen) to heavy (continuous towels a n d the many types of hand towels used in mally low a n d loading is light. Garments can be easily dried wrinkle-free. Also,
clubs and in dentists' and doctors' offices) to very heavy (aprons and kitchen the solvent h a s a powerful degreasing impact on the oily soil.
and bar towels). The trade-off, however, is that water-soluble soils such a s perspiration and
These items primarily contain animal and vegetable greases that can either many food stains tend to accumulate and detract from the wearing quality of
be saponified using alkalies or emulsified with surfactants. Refer to Tables 7-6 drycleaned garments. To solve this problem, some operators launder the gar-
through 7-8 for appropriate washing formulas. ments every third or fourth cycle to keep water-soluble stains a t a minimum.
Others use specially designed drycleaning machines capable of handling both
Industrial garments water a n d solvent. Environmental concerns and regulations have affected the
Industrial garments are most frequently made of polyester/cotton blends. Cot- number of rental operators using drycleaning a s opposed to laundering.
ton provides comfort while polyester offers strength and wrinkle resistance Washing formulas for industrial garments require certain modifications.
that can eliminate pressing. Typical washing formulas for industrial shirts and pants are shown in Tables
Poly/cotton garments are often simply placed on hangers and passed 7-9 and 7-10.
through a warm-air or steam cabinet, which relaxes the wrinkles. On the other The rinse temperature should decrease gradually in order to minimize the
hand, polyester can "remember" wrinkles, so it's important not to overload possibility of wrinkling due to thermal shock. Rinse-to-rinse temperature
washers and set wrinkles. These wrinkles don't relax in the finishing cabinet
Table 7-40: Industrial pants formula a surfactant-usually nonionic or a blend of nonionics with other organic
surfactants,
Supply usage carboxymethylcellulose, and
Water Temwroture Time Suppb
Opercrtion level (OF)' (min.) lype pH Titration fabric brightener.
Bleach is used to removestains and maintain whiteness on whitework, such
Break Low 130-160 18 Alkali. 10.0 375 to 500 ppm a s lab coats, smocks, and shirts. Bleach can pose problems, however. Industrial
surfactant. to Na20(6 to 8
phosphate. 11.0 drops N/l with garments frequently are produced from resin-finished fabrics that provide
CMC phenolphthalein) wrinkle resistance and easy care. These resins may be chlorine retentive.
This retained chlorine will cause permanent yellowing a n d degradation of
Canyover Low 130-160 9 the fabric if i t isn't neutralized. To counter this, antichlors (bleach neutralizers)
-
Rinse High 115-145 2 are added to the rinses following bleaching.
Using oxygen bleach i s a n alternative, although the bleaching action is
Rinse High 100-125 2
milder t h a n sodium hypochlorite on some stains.
Rinse High Cold-100 2 50 to 120 ppm Extraction, drying, a n d finishing of industrial garments must be carefully
HCO; (4 to 10 controlled to minimize wrinkling. Since polyester fiber absorbs virtually no
drops N/lO with
methyl orange)
water, extraction usually is minimal, ranging from merely bringing the basket
wer top up to speed to extracting for two, three, or four minutes. For compression-type
extractors, lower pressures are used.
5.5 Garments can be finished and dryed by pressing or by being passed through
Sour Low Cold 4 Sour to hot-air/steam cabinets or tunnels. Some operators tumble dry garments before
6.5 using a cabinet or tunnel, while other plants pull the garments directly from
the extractor and hang them wet for cabinet or tunnel finishing. The latter,
obviously, requires a much longer time in the finishing system than do fabrics
decreases of about 15°Fare best until the solution reaches about 110°F. t h a t are fully dried. Wet-to-dry tunnel finishing produces a better flat finish
Pants are frequently loaded a t full capacity and shirts a t about 65 to 80 per- than does dry-to-dry.
cent of full capacity if tunnel or cabinet finished (3..5 to 4.0 pounds per cubic While these finishing methods differ, the basic principle of dealing with a
foot) and 100 percent if pressed. thermoplastic fiber such a s polyester is to ensure that wrinkles aren't set into
Washing supplies used in industrial garment washing are different from the fabric during processing. Following these precautions will avoid wrinkle-
those used in other fabric classifications for two reasons: setting:
High alkalinity, like high temperature, is harmful to polyester fiber, which Scale back load weights from normal machine standards.
predominates in industrial garment fabrics. Minimize drain times between washer baths to avoid setting sleeve wrinkles.
Mineral greases must be emulsified since they aren't saponifiable by high al- Reduce temperature gradually during rinsing.
kalinity. Therefore, detergents designed for industrial garments contain Minimize extraction.
mild alkalies; are high in complex phosphates; a n d are very rich in surfac- Finish garments by either pressing or drying in a cabinet or tunnel a s soon
tants, which have a key role in penetrating a n d emulsifying mineral a s possible following extraction or full-drying.
greases. Do not overload hampers holding fabrics in process.
Of course. all fabrics become soiled with body oils, especially wearing
apparel a t cbllars and cuffs. Alkali is needed to clean the entire garment. Dust control
Nonionic surfactants play a key role in industrial detergents, which may The term dust control refers to textiles used by industry for floor care: mats,
contain several different nonionics, making them effective in degreasing a s dust mops, wet mops, dusting cloths, and sweeping cloths.
well a s in removing water-soluble soil. Another important ingredient in indus- Mats. Mats are widely used in shops and markets, restaurants, offices, and
trial formulations i s sodium carboxymethylcellulose (CMC), a cellulose deriva- industrial plants. They can be constructed of anylon pile with rubber backing,
tive that promotes particulate soil suspension, minimizing soil redeposition. cotton pile with rubber backing, cotton pile with latex backing, or polyester pile
Therefore, a n effective industrial detergent will combine most of the follow- with vinyl backing.
ing elements: Mats are quite durable. By virtue of their chemical composition, the syn-
a n alkali-usually low pH (less than 11.0), thetic-pile types are relatively resistant to soil and moisture retention, although
a complex phosphate-sodium tripolyphosphate or tetrasodium pyrophos- vinyl mats are quite sensitive to heat. Therefore, for best results, mats
phate, shouldn't be processed above 120°F.
Figure 7-1:Closed-oil mop washing system
Table 7-1I:Mat formula
Suppty usage
Water Temperature Tlme SUPP~~ Phenolphthalein
operation level (OF) (min.) bP PH tthation
Rush High 110-120' 2
Rrwk Hiah 110-120' 6-10 Alkal~,soap/ 10.5 60 to 180 ppm
detergent to Na,O ( ?to 3
. .,
11.5 dro~sN/1'1""
Carryover" High 110-120' 6
Rinse"' High 110-120 2
Rinse High Cold 2
'130-140°F for cotton pile mats
"Only for heovily soiled cotton and nylon pile mats
"'Two or more split rinses for heavily soiled cotton and nylon pile mats
""Up to 960ppm (16 drops N/1 acid using phenolphthalein indicator) for heovily soiled
cotton and nylon pile mats
Break suds Low 165-180 12-20 Alkali. Grater 2.000-3.1 00 ppm Break suds Low 165-180 12-20 Alkali, Greater 2.000-3.100 ppm
detergent than Na,O (32 to 50 detergent than Na,O (32 to 50
11.5 drops N i l ) 11.5 drops N/1)
Carryover Low 165-180 5-8 Flush High 160-170 1-2
shift and drained a t the close of each operating day to prevent congealing. 1 (Sodium metasilicate) NazO.Si02 7.2 14.7
Finishing chemicals can be purchased in several forms and combinations. 2 (Sodium orthosilicate") 2Na2OOSiO2 11.6 9.7
Dry sours and antichlors are available from all chemical suppliers. Specialty 3(3 to 1") 3Na200Si02 13.7 73
products such a s rust-removing sours and formulations containing sour and 5(5 t o l " ) 5Na200SiO~ 15.9 4.8
fabric softener or a softener and a bacteriostatic agent are widely used. Add to
this the fact that these finishing agents usually contain a fabric brightener, 'Figures are gallons of caustic soda and sodium silicate needed to produce 7OOpounds of
and it becomes apparent that there are many products to choose from. alkali in 100 gallons of stock solution.
"Liquid system provides solutions equal to the theoretical values obtained from anhydrous
For liquid systems, sour may becombined with a fabricsoftener and a bacte- solids. Due to moisture in the "dry" solids, the liquid-produced systems are slightly more
riostatic agent. This mixture also needs to be agitated, since softeners have concentrated.
some tendency to salt out or be thrown out of solution by the high ion activity of
the sour. If antichlor is incorporated in the finish mix, the softener, bacterio-
stat, and antichlor can be combined, but the sour must be maintained separ- Table 7-15 shows examples of some alkaline silicate formulations. For
ately since some sours-notably fluosilicic acid (nfs)-will drive sulfur dioxide example, combining 7.2 gallons of liquid caustic soda, 14.7 gallons of liquid
out of the antichlor, producing noxious odors. A successful combination of sour, sodium silicate, and enough water to bring the volume up to 100 gallons pro-
softener, bacteriostat, and antichlor can be made using ammonium silicofluo- vides the same product a s one 100-pound bag of anhydrous sodium metasili-
ride a s the sour. cate (k=l) dissolved in 100 gallons of water. The results are the same, but com-
Starch usually is maintained a s a separate supply, or it can be combined with bining- the generic
- liauids costs less.
polyvinyl alcohol or polyvinyl acetate for sizing polyester and its blends. While The proportions of each component necessary to produce 100 gallons ( a t a
starch is most commonly added dry to the washer, it works best if first concentration of 1.0 pound of alkali per gallon of solution) of other k ratios
dispersed in water by cooking in a starch cooker. (Na,O:SiO,) can be calculated using the following proportions:
W gallons of sodium silicate = 1791 (62k 60) +
Formulating liquid alkali W gallons of caustic soda = (1252k - 376)/(62k 60) +
Alkali stock solutions can be prepared by dissolving 100 pounds of dry silicated W enough water to provide a total volume of 100 gallons
alkali in 100 gallons of stock solution. Each gallon of this solution will contain To take maximum advantage of this system, a laundry needs about 5,000
one pound of alkali. gallons of storage-tank capacity for each component to hold tankwagon quan-
Equivalent solutions of sodium silicates can be prepared in the laundry by tities, and personnel who are knowledgeable in the safe handling and mixing
combining liquid caustic soda (50.0 percent NaOH or 38.8 percent Na,O) and of these types of chemicals.
liquid sodium silicate (8.9 percent Na,O, 28.7 percent SiO,; 1:3.22 Na,O:SiO,). Potassium silicates also can be formulated. A whole range of potassium sili-
These chemicals, common to many industries, can be purchased in tankwagon cates are formed by combining liquid caustic potash with liquid potassium
quantities and held underground or in the plant in storage tanks. However, silicate.
they must be stored a t or above the temperatures shown in the following chart There are three distinct advantages to using potassium metasilicate, ortho-
to keep them from solidifying. silicate, or other potassium ratios instead of sodium silicates:
The properties of these materials are listed below: W The alkaline potassium silicates can be produced in concentrates up to 4.5
pounds per gallon. This allows the producer to combine the caustic potash
Liquid caustic Liquid sodium and potassium silicate before shipping so that the product is ready to use a t
soda silicate (4:3.22) the plant without mixing and/or dilution. Sodium silicate concentrations,
Density, lb./gal. 12.76 on the other hand, are limited to about 1.25 pounds per gallon.
Percent Nan0 38.8 W Potassium orthosilicates solidify below -20°F, making them suitable for use
Percent SiOn 0.0 in any climate.
Solidifcation temperature 52°F W Potassium silicates are superior alkaline builders because of their very high
solubility.
Combined in the proper proportions, liquid caustic soda and sodium silicate The trade-off comes in terms of cost. Potassium salts cost the same as or up to
produce alkaline silicates of any molecular ratio (k value, where k is the ratio of 1.7 times more than their sodium counterparts, and up to 1.1 to 1.5 times
Na,O to SiO,) up to a maximum solution concentration of about 1.25 pounds
per gallon.
Table 7-16: Liquid potassium silicate formulas
To remove mineral oil-based soils found in industrial uniforms, shop towels,
and similar classifications, the emulsifying action of metasilicate works b e s t
Caustic potash Potassium silicate In addition, shop towels laundered with metasilicate show greater absorbency
k ( m o of KzO: SiOi) Formula (gallons') (gallons') than those laundered with orthosilicate when both alkalies are added to a n
equal titration level.
1 (Potassium metasilicate) KQsSi02 9.2 72.7
2 (Potassium orthosilicate) 2K20.Si02 14.1 8.0 DYEING TEXTILES IN THE PIANT
3 (31) 3KD&i02 16.2 5.8
Using stain-treatment formulas on heavily stained textiles shortens their life.
'figures are gallons of caustic potash and potassium silicate needed to produce 100 An alternative is to redye heavily soiled items to a darker shade. Some plants
pounds of alkali in 100 gallons of stock solution. also dye new textiles to customize certain services such a s continuous towels,
mops, shop towels, and other specialty items.
(depending on Na,O to SiO, ratio) a s much of the potassium silicate is required The dyeing process can be carried out in the plant or by a dye specialist.
to obtain the same alkalinity.
The chemicals used for producing liquid potassium silicates are: Direct dyeing
Many operators direct dye wiping cloths a s part of the regular formula. Also,
Liquid caustic Liquid potassium plants offering colored table linens can use a touch-up procedure to prevent a
potash silicate ( 1 3 . 2 9 )
rainbow-of-hues effect caused by a mixing of new and used inventories.
Denslty, Ib./gal. 12.09 Wiping cloths may be purchased either a s greige (unbleached) goods or white
Percent I40 37.8 fabrics. Many operators initially offer white wiping cloths and then dye them
Percent SiO, 0.0 when they become too stained to serve.
Soiidiflcation temperature -20°F Direct cotton dyes are sufficiently washfast for wiping cloths and can be ap-
plied to fabrics being washed during the rinse bath or the break, or applied a s a
Potassium silicates are produced a t a concentration of one pound per gal- separate procedure. The dye generally comes in pouches, each containing suf-
lon of solution by combining these chemicals in the proportions given in ficient dye for the contents of the washer.
Table 7-16. When the dye is added to the third hot rinse, the rinse is extended to five or
As previously stated, potassium silicates can be produced in highly concen- more minutes, followed by the usual split and cold rinses. However, this proc-
trated solutions. For example, 14.1 gallons of caustic potash and 8.0 gallons of ess is time-consuming, adds measurably to formula expense, and the dye
potassium silicate will mix together without dilution. This solution contains doesn't penetrate the fabric well. Adding the dye packet a t the break improves
100 pounds of K,SiO, (potassium orthosilicate) or 100/22.1, which equals 4.5 the process; it has a long time to exhaust before the bath is drained. The dyestuff
pounds per gallon. works independently of the detergent to accomplish its task.
Solutions of the same strength and concentration but a t significantly lower The most effective method of'direct dyeing in the washer relies on additional
cost can be produced by substituting sodium silicate (1:3.22)for potassium sil- time and steps to achieve a washfast color. This is the procedure:
icate (l:3.29) in equal volumes. The chemical species produced by this substitu- load the textiles and draw a high level of hot water;
tion is about 85 percent potassium orthosilicate and 15percent sodium orthosil- add the dye and increasethe water temperature to 200°F by direct admission
icate. Except for slight crystallization a t extremely low temperatures, little of steam;
efficiency is lost with this substitution. agitate the load for 15 minutes to thoroughly distribute the dye;
add rock or tablesalt, usually 10 to 20 pounds per 100 pounds of textiles (the
Choosing an alkali salt lowers the solubility of the dye in water and forces it into the fibers); and
The selection of silicated alkali depends on the type of soil being removed. A t B rinse the textiles four to six times.
first thought, it would seem that all silicated alkalies (orthosilicates, metasil-
Vat dyeing
icates) should produce the same results a s long a s the proper alkalinity is
achieved in the break and subsequent baths. However, silicated alkalies Textiles used in food service or wearing apparel must be vat dyed in order to
may not all perform alike. resist fading during heavy-soil washing and/or bleaching. Vat dyeing also can
For some time, operators have selected orthosilicate for linen supply opera- be done in a regular laundry washer.
tions and metasilicate for industrial laundering. The contention is that the oily Here's a n example based on a 42- by 84-inch open-pocket machine loaded
with no more than 200 pounds of merchandise:
soils present in linen supply items are primarily derived from animal fat,
draw eight inches of hot water into the empty machine a t a temperature of
which needs the strong saponification action of the sodium oxide portion of the
170" to 190°F, adding about six ounces of nonionic synthetic detergent and a
alkali to be removed.
weighed amount of anthraquinone (vat) dye;
Irun the washer for about a minute, add 10 pounds of caustic soda, and allow
several minutes of mixing;
Iadd the load of merchandise to be dyed;
Irun the load for at least five minutes, then add sodium hydrosulfite, 2.5
pounds a t a time, up to 12.5 pounds;
Irun the machine an additional 30 minutes and add one quart of 1.0 percent
chlorine bleach;
Irun the machine an additional 10 minutes; SAFE HANDLING OF
Igive the contents of the washer three high-level rinses, all hot, followed by a
regular light-soil washing formula. WASHROOM CHEMICALS
Although this procedure has been used for many years, it's complicated and
time-consuming, and it involves chemicals not commonly used in the profes-
sional laundry, notably sodium hydrosulfite. An easier alternativeis to use pre-
mixed vat dye kits from chemical and textile distributors.
N
ormal operating procedures in a laundry create several safety issues for
Dye specialists the employees. The very nature of the work being performed i n a laun-
Some companies specialize in vat dyeing textiles, saving operators from the dry environment exposes employees to slippery floors, moving equip-
tedious procedure of dyeing textiles in the washer. These dye specialists color ment parts, hot water, high-temperature metal surfaces, live steam, hazardous
merchandise to the desired shade and convert stained goods to useful life. chemicals, microorganisms, soils, and extremes in both air temperature and
humidity.
Employers can control the risk to employees by providing appropriate safety
equipment, training, and first-aid information and materials. This chapter
deals primarily with hazards from chemicals used in the washroom and is not
intended to be all-encompassing. Employers must continually review current
publications to obtain the most up-to-date legal requirements.
CHEMICAL HANDLING
Chemicals used in the washroom can be classified into the following broad
categories:
Ialkalies and alkaline builders,
Isurfactants and detergents,
Isours and acids,
Ibleaches (oxidizing type),
Isolvents, and
Ispecialty chemicals.
The potential for danger when using the above compounds depends a great
deal on their strength. Most of the chemicals are hazardous in their concen-
trated forms. Although makeup solutions and stock solutions are less hazard-
ous than the concentrated form, they must be handled properly.
All employees and supervisors who handle any washroom chemical must
read the product label and the Material Safety Data Sheet (MSDS) supplied by
the manufacturer. In addition, everyone handling these chemicals must have
access to and use all appropriate protective devices such a s protective clothing,
breathing devices, gloves, goggles, ventilation systems, eye-wash stations,
and safetv showers.
Each employer is responsible for providing proper facilities and training in
required procedures and use of safety devices. Management is responsible for
Figure 8-1: NFPA hazardous material code with numerical scale
ensuring that employees follow established procedures.
CHEMICAL STORAGE
Many of the classes of compounds available in the washroom are capable of HEALTH HAZARD
4 Deadly
reacting with each other and must be stored separately. 3 Extreme danger 4 Below 73°F
In general, alkaline materials must be stored separately from acid materials 2 Hazardous
such a s sour, and chlorine bleaches must be stored separately from acids. The hazardous (Boiling pt. atfabove 1 0 0 ~ ~
same precautions apply to transporting washroom chemicals - do not move 0 Normal material andfor atfabove 73'F-not
incompatible items together on the same pallet.
Container labels
Alkali
o v
Use NO WATER w
&R" f
\/
1 V
change
1 Unstable if
heated
A chemical container label provides the following information: Rodiwctive f' 0 Stable
Ihazard rating,
Ihazardous ingredients, I
precautions of use, and mended System for the Identification of the Fire Hazards of Materials," (NFPA
Ifirst-aid instructions. i No. 704M).
IFlammability
In addition, the container label may contain information about a chemical's
4 Very flammable gases, very volatile flammable liquids, and mate-
flammability, health, and reactivity rating as defined by the National Fire
Protection Association (NFPA). The NFPA codes are an approved method of rials that in the form of dusts or mists readily form explosive mix-
rating the hazard level of chemicals. They provide an easy way to identify the tures when dispersed in air. Shut off flow of gas or liquid and keep
hazardous properties of the chemical under normal and emergency situations. cooling water streams on exposed tanks or containers. Use water
NFPA uses a four-color, diamond-shaped symbol. Each color has a special spray carefully in the vicinity of dusts so as not to create dust clouds.
hazard meaning: red a t the top (fire),yellow (reactivity), white (specific hazard), 3 Liquids which can be ignited under almost all normal temperature
and blue (health). The level of the hazard, indicated by a number from zero to conditions. Water may be ineffective on these liquids because of
four, or specific hazard identification abbreviations are printed in the color their low flash points. Solids which form coarse dusts, solids in
box referring to the type of hazard. (See Figure 8-1.) shredded or fibrous form that create flash fires, solids that burn
The numerical values mean: rapidly, usually because they contain their own oxygen, and any
4-Severe hazard material that ignites spontaneously a t normal temperatures in air.
I3-Serious hazard 2 Liquids which must be moderately heated before ignition will occur,
I2-Moderate hazard and solids that readily give off flammable vapors. Water spray may
I1-Slight hazard be used to extinguish the fire because the material can be cooled to
I0-Minimal hazard below its flash point.
1
The following explanation of the numerical values is taken from "Recom- 1 Materials that must be preheated before ignition can occur. Water
may cause frothing of liquids with this flammability rating number
f
if it gets below the surface of the liquid and turns to steam. However, 1 Materials which in themselves are normally stable but which may
water spray gently applied to the surface will cause a frothing which become unstable a t elevated temperatures and pressures or which
will extinguish the fire. may react with water with some release of energy but not violently.
0 Materials that will not burn. Caution must be used in approaching the fire and applying water.
0 Materials which are normally stable even under fire exposure condi-
W Health tions and which are not reactive with water. Normal fire fighting
4 A few whiffs of the gas or vapor could cause death; or the gas vapor or procedures may be used.
liquid could be fatal on penetrating the fire fighters' normal full pro-
tective clothing, which is designed for resistance to heat. For most Material Safety Data Sheets (MSDSs)
chemicals having a Health 4 rating, the normal full-protective cloth- Under the provisions of OSHA's Hazard Communication Standard, employees
ing available to the average fire department will not provide ade- have the right to examine any Material Safety Data Sheet (MSDS) upon writ-
quate protection against skin contact with these materials. Only spe- ten request. Employers must maintain MSDSs for all hazardous chemicals in
cial protective clothing designed to protect against the specific use in the workplace and must make them available for employee review. In
hazard should be worn. addition, MSDSs must be readily available to emergency personnel in the
3 Materials extremely hazardous to health, but areas may be entered event of fire or other emergency.
with extreme care. Full-protective clothing, including self-contained The MSDS contains more detailed information than the product label and
breathing apparatus, rubber gloves, boots a n d bands around legs, should always be consulted during a n emergency.
arms, and waist should be provided. No skin surface should be A typical MSDS is divided into sections of required information. The infor-
exposed. mation may appear in a different order, but it will always be labeled for easy
2 Materials hazardous to health, but areas may be entered freely with identification. The sections are:
self-contained breathing apparatus. W P r o d u c t identification. Gives both the name and chemical family of the
1 Materials only slightly hazardous to health. I t may be desirable to product.
wear self-contained breathing apparatus. H a z a r d o u s components. Identifies the components of the product consi-
0 Materials which on exposure under fire conditions would offer no dered to be hazardous by EPA or OSHA standards. This information is
health hazard beyond that of ordinary combustible material. based on the hazardous nature of the component in its pure and concentrated
W Reactivity state, and includes exposure limits for the concentrated material. In general,
4 Materials which in themselves are readily capable of detonation or of exposure to a formulation of the material represents a lesser hazard than
explosive decomposition or explosive reaction a t normal tempera- what's indicated by the MSDS because the material is diluted with water
tures and pressures. Includes materials which are sensitive to and/or other chemicals.
mechanical or localized thermal shock. If a chemical with this hazard W P h y s i c a l d a t a . Lists the chemical and physical properties of the substance.
rating is in a n advanced or massive fire, the area should be evacuated. W F i r e a n d e x p l o s i o n d a t a . Contains essential information in the event of a
3 Materials which in themselves are capable of detonation or of explo- fire or other emergency, including proper fire fighting techniques in the
sive decomposition or of explosive reaction but which require a presence of the material.
strong initiating source or which must be heated under confinement R e a c t i v i t y d a t a . Describes hazardous conditions to avoid and hazardous
before initiation. Includes materials which are sensitive to thermal products that can form if the material chemically decomposes.
or mechanical shock a t elevated temperatures and pressures or H e a l t h h a z a r d d a t a . Describes chronic or acute effects of exposure and
which react explosively with water without requiring heat or confine- provides first-aid information. Anyone handling the product must tho-
ment. Fire fighting should be done from a n explosion-resistant loca- roughly understand emergency and first-aid procedures and must make cer-
tion. tain t h a t the required items for first-aid treatment are readily available. For
2 Materials which in themselves are normally unstable and readily washroom chemicals, the normal first-aid procedure is to thoroughly flush
undergo violent chemical change but do not detonate. Includes mate- the affected body area with water, either in a safety shower or eye wash
rials which can undergo chemical change with rapid release of station.
energy a t normal temperatures and pressures or which can undergo W P r e c a u t i o n s f o r s a f e h a n d l i n g a n d use. Describes precautions for han-
violent chemical change a t elevated temperatures and pressures. dling a spill or disposing of the product and precautions to be taken in
Also includes those materials which may react violently with water general handling and storage.
or which may form potentially explosive mixtures with water. I n W C o n t r o l m e a s u r e s . Describes protective devices for safe handling of the
advanced or massive fires, fire fighting should be done from a pro- product.
tected location.
The best source of information on handling washroom chemicals is the
MSDS for the product in question.
Employee fraining
Every employer is responsible for providing a safe working environment and
training all employees required to work with or be exposed to any hazardous or
toxic substance. The training includes proper safety procedures and hazard
information on the substance.
This chapter only highlights the major provisions on laws relating to safe PROBLEM SOLVING
handling of chemicals. Operators must consult the most recent edition of
national, state, and local regulations to ensure compliance.
AND TROUBLESHOOTING
D
iagnosing problems in the washroom involves analyzing both t h e
mechanical and chemical processes necessary to producegood quality.
This chapter presents information and procedures for troubleshooting
mechanical and chemical problems a s well a s tests operators can perform in
the plant to maintain consistent quality in day-to-day operations. While it con-
centrates on washroom chemistry, it nevertheless touches on many phases of
operations.
Machine maintenance is not covered in this chapter. However, properly
maintained equipmentis a prerequisite for using the procedures described here.
For example, leaking fill and/or dump valves can lead to wrong titration
values i n the same manner a s improper chemical use can.
TROUBLESHOOTING TYPICAL OPERATING PROBLEMS
Plant and production managers are constantly faced with quality problems.
Here are some typical problems and possible causes.
P o o r s o i l removal:
- Suds bath was too low.
- Suds time was too short.
- Washing temperature was too low.
- Not enough detergent was added.
- Washer was overloaded.
- Water levels were too high/low.
- Water was too hard.
- Soil loads were mixed.
- Wrong formula was used.
Poor color (redeposition):
- Water was too hard.
- Washers were overloaded.
- Not enough detergent was used.
- Detergent ingredients were poorly balanced.
- Formula didn't call for enough rinses.
- Rinse times were too short.
P o o r color (not redeposition):
- Mechanical action was excessive because of:
Wunderloading
- Dye transfer occurred. Wtoo lengthy formulas
- Bleach was used incorrectly. Wtoo much time between filling and draining
- Washing temperature was too high. Wlow water levels
- Alkalinity was too high. - Highly alkaline builders were used excessively in the presence of steam and
- Textiles lacked colorfastness. high water temperatures on fabrics containing polyester.
W P o o r color, w h i t e s ( o t h e r t h a n redeposition): - Wrong souring agents were used.
- A yellow or brown color indicates: - Souring agents were used improperly (too much/too little).
W iron
W Linting/pilling:
W poor rinsing - Mechanical action was excessive because of:
W undersouring Wunderloading
W unneutralized bleach
Wtoo lengthy formulas
- Yellowing indicates chlorine-retentive resins.
Wtoo much time between filling and draining
- Pink indicates an iron/bleach/brightener complex. Wwater levels too low
- Green indicates:
Wleaky washers (dump valves, shell, etc.)
W metallic salts
- Textile fibers are too short.
W dye bleeding
- A dull appearance indicates: - Textiles contain low-twist yarns.
W not enough bleach
- Washers, conditioners, tumblers, or flatwork ironers have rough surfaces.
W weak bleach
- Too much bleach was used.
W short bleaching time
- Textiles were exposed to excessive heat in tumblers.
W not enough flushes
- The pH of bleach was too low.
W not enough rinses
- Bleaching temperature was higher than 155°F.
W short rinses
- Strong alkalies weren't rinsed out of polyester in fabrics before finishing.
W poor soil removal
- Souring agents were improperly used.
W P o o r s t a i n removal: W O d o r i n textiles:
- Temperatures weren't controlled in preliminary flushing. - Hard water reacted with soap.
- Not enough bleach was added. - Poorly soured loads have fermented.
- Bleach stock solution was too weak. - Too much sour was used.
- Bleach pH was incorrect. - Soil remains in the textiles.
- Washing temperature was too low for the detergent. - Rinsing was incomplete.
- Water level in bleach bath was too high. - Boiler treatment chemicals have contaminated the load.
- Washer was overloaded. - Resin-treated fabrics have retained soil and chemicals.
- Bleach bath contained too much soil. W F l a t w o r k r o l l i n g o n ironer:
- Bleach time was too short. - Rinsing was incomplete.
- Improper bleach for stain type was used. - Too much sour was used.
- Alkalinity was too low. - Souring time was too short.
- Not enough soap/detergent was used. - Sour was added improperly.
- Sudsing time was insufficient. - Wrong type of sour Mias used.
- Sudsing temperature was too low. - The work was too damp.
- Merchandise was abused in customer locations. - Ironer chests were dirty.
W H i g h tensile s t r e n g t h loss: - Chest was lubricated improperly.
- Bleach wasn't diluted to one percent. - Starch or other substance such as wax has accumulated on chests.
- Too much bleach was used. - Rust is present on chest surfaces.
- Bleach pH was too low. - Ironer chests have been assembled in the wrong machine sequence.
- Bleach temperature was higher than 155OF
- Steam had escaped into the bleach bath.
- Chests were cold because of: Also, operators handling doctors' and nurses' uniforms, towels from medical
Iimproperly sized steam lines or dental offices, and hospital linens have to contend with holes caused by:
Itoo low steam pressure Imedicines;
Iimproperly operating traps Initric acid;
Iair-bound chests Isilver nitrate;
- Chests were warped. Ialum;
- Static electricity was present. Iferric chloride;
- Goods were improperly feeding. Idisinfectants and antiseptics such as hydrogen peroxide, hypochlorites,
- Fabrics lacked lubrication. -
potassium permanganate, merthiolate, mercurochrome, carbolic acid, cres-
- Apron covers, padding, ribbons, and guide strings were poorly maintained. ols, and iodine; and
Iastringents such a s zinc sulfate, zinc chloride, and aluminum chloride.
IGarment wrinkling:
- Washers were overloaded. Much of the chemical damage from these corrosive substances occurs when
- Cool down in rinsing was too rapid. the solutions dry on the textiles. During drying the solutions evaporate and
- Time between washer reversals was too long. become increasingly concentrated. If the chemicals remain on the textile for
- Drain times were too long. any length of time, they cause serious degradation, which in most cases does
- Cylinder rotation speed was too slow. not become apparent until the textile has been laundered once or twice.
- Intermediate extraction was used. This damage occurs after laundering because chemically treated cotton loses
- Extraction time was too long. its wet strength more rapidly than its dry strength. Degraded cotton textiles
- Extraction speed was too high. often retain sufficient dry strength to remain intact during use, but fail, devel-
- Basketloads awaiting hanging were overloaded. oping holes and tears, during laundering or while the textile is wet.
Textile strength measurements on unused cotton indicate wet strength is
- Delay before hanging was too long. 1.2 to 1.3 times dry strength. Chemically degraded cotton, on the other hand,
- Steam has leaked. has lower wet strength than dry strength; severely damaged textiles can have
CAUSES OF TEXTILE DAMAGE a wet strength less than half the dry strength.
Textile damage is a source of concern to all laundry plant operators. Textile Numerous studies have been conducted on the effect of various chemical
degradation is expected in normal use from physical abrasion and flexing dur- agents on the strength of cotton textiles. One study revealed strength loss
ing wear and laundering, chemicals used in laundering, and oxidizing agents ranging from 16.6 to 65 percent when certain common medicines were allowed
in the environment. This relatively long-term deterioration is an anticipated to remain on cotton textiles for three weeks. Findings from this study appear in
part of the cost of operation. Table 9-1.
On the other hand, abnormal textile damage that becomes apparent after
items have been laundered only a few times or suddenly and unexpectedly after
many launderings signals problems in the plant or a t the customer's, or indi- Table 9-1: Chemical damage to cotton caused by common medicines
cates a n inherent weakness in materials received from the mill due to imperfec- (3-week exposure)
tions in the manufacturing process. Chemical and physical laboratory tests
often must be conducted by experienced analysts to determine the true extent Percent loss in
and nature of the damage. Textile damage usually can be classified into a few Staining substance bursting strenglh
major categories. The most common ones are described here.
Tincture of ferric chloride .............................................. 65.0
Chemical damage during use Picric acid solution (2%) .............................................. 55.8
Tannic acid (5%) ..................................................... 30.1
Chemical damage occurs when the chemical makeup of fibers i s altered in a Tincture of merthiolate ................................................ 21.7
way that causes a decrease in tensile strength. Silver nitrate solution (12%). ........................................... 19.4
Chemical damage results when textiles are exposed to: Iodine (7%) ointment ................................................. 19.4
U acids, lcyfhyol(10%) ointment.. ............................................. 18.6
I alkalies, Syrup of phosphate. .................................................. 17.1
oxidizing agents, Zinc chloride solution ................................................. 17.1
I certain atmospheric gases that have a degrading effect, Mercurochrome . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16.6
I light and other types of radiation, and
I high temperatures in drying or pressing.
Foodstuffs also cause appreciable damage to textiles. Frequently acidic sub- The acids found in fruits and vegetables, with the exception of oxalic acid,
stances in foods are responsible for much of this damage, although other sub- are weak acids t h a t ordinarily would not be considered corrosive materials.
stances also can degrade textiles. However, when foodstuffs containing these substances are spilled on textiles
Table linens and napkins, a s well a s shirts and other wearing apparel, often a n d permitted to remain and evaporate, a relatively concentrated amount of
develop holes because of the corrosive effect of foods. Even spinach, when acid crystals results. With the aid of moisture from the air, the action of the acid
spilled on cotton textiles and allowed to age for a s short a time a s two weeks, eventually breaks down the cellulose.
will cause sufficient deterioration to produce holes t h e first or second time the
textile is laundered. I
Damage tom fungi
Textile soiled with medicines or foods t h a t have been allowed to dry and age ! Certain microorganisms, especially molds, cause significant textile damage.
plainly show some damage when examined under a n ultraviolet lamp; this Molds or fungi are found practically everywhere, and the varieties that can
damage may not be visible to the unaided eye. damage textiles are numerous. The coating or discoloration on cotton, linen, or
Table 9-2 gives pH values for a number of common foodstuffs. All of these other materials that results from fungi growth is called mildew.
foods are strongly acidic. Most fungi grow best in humid conditions a t temperatures ranging from 70°
to 90°F. Many fungi can withstand freezing for months or years, but their
Chemical studies of the composition of fruits and vegetables show that
growth is slowed a n d they eventually die when exposed to higher tempera-
oranges, grapefruit, a n d lemons are rich in citric acid. Grapes contain potas-
tures. Temperatures of 160°F or higher will kill fungi, usually in a few minutes.
sium hydrogen tartrate, a n acid salt. Cranberries, plums, and prunes contain
Fungi can use a large variety of materials a s food sources. They're able to do
benzoic acid. Oxalic acid is present in spinach, beet greens, and pineapple. The
so by secreting a number of different digestive enzymes t h a t chemically
oxalic acid content of spinach varies from about 0.5 to 1.2 percent, depending I
change the materials into simple-soluble materials t h a t the organisms use for
on the variety of spinach.
food.
Practically all materials, with the exception of metals, are considered food
Table 9-2: pH value of foodstuffs sources by fungi. In addition to some types of textiles, leather, paper, paint and
wood are subject to attack. Fungi have been known to corrode lenses of micro-
Food pH values scopes and other optical instruments under the proper growth conditions.
Ordinarily, the cellulose fibers of cotton and linen have little or no nutritive
Apples. ............................................................. .2.9-3.3 value for higher organisms. Fungi, however, through the action of the specific
Apricots ............................................................ .3.&4.0 enzymes they produce, are capable of decomposing cellulose for food.
Blackberries ......................................................... .3.2-3.6 The extent of decomposition ranges from slight discolorations to extensive
Cherries ............................................................ .3.2-4.0 weakening of the fibers t h a t results in holes in the textiles. Molds also produce
Cider ............................................................... .2.9-3.3 grey or grey-brown stains on fabrics. These stains may not appear until the
Gooseberries ........................................................ .2.8-3.0
affected textileis laundered and subjected to the heat of the tumbler or ironer.
Grapefruit .......................................................... .3.0-3.3
Jellies (fruit) ......................................................... .2.8-3.4
Table a n d kitchen linens are most often subject to mold damage. The
Lemons ............................................................. .2.2-2.4 damage occurs when the linens have been stored in dark, humid, warm places
Limes ............................................................... .I .8-2.0 for a period of several days or longer before being picked up for laundering.
Olives .............................................................. ,363.8 Under these conditions, the almost universally present mold spores develop
Oranges ............................................................ .3.0-4.0 into mold plants, which grow prolifically. They attack the textiles and certain
Peaches ............................................................ .3.4-3.6 types of soils, specifically foodstuffs, in their quest for food. The longer the
Pears ............................................................... .3.6-4.0 molds are left on the linen, the more damage they'll do.
Pickles (dill) ......................................................... .3.2-3.6 Methods for treating textiles to prevent mildew are presented in Chapter 5 .
Pickles (sour). ....................................................... .3.0-3.4
Plums. .............................................................. .2.8-3.0
Rhubarb.. .......................................................... .3.1-3.2
Mechanical damage
Sauerkraut .......................................................... .3.4-3.6 Mechanical damage to textiles is characterized by the abrading, cutting, or
Soft drinks.. ......................................................... .2.0-4.0 breaking of textile fibers and yarns. Mechanical damage results from:
Strawberries ......................................................... .3.0-3.5 W normal wear;
Tomatoes ........................................................... .4.0-4.4 mechanical action during laundering;
Vinegar. ............................................................ .2,4-3.4 W cuts or snags made by sharp instruments;
Wines. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2.8-3.8 W abrasions;
cutting oftextiles by insects such a s moths or silverfish (Although they don't from the same lots were also tested and showed evidence of chemical break-
ordinarily attack cellulose, insects may use certain types of soil on textiles down. Items that have been chemically damaged during manufacturing often
a s food. In consuming the food, they may cause damage to the fibers.); show satisfactory strength before laundering; but during laundering the
cuts from foodstuffs; and damaged yarns and fibers pull apart, leaving holes and tears.
defective manufacturing procedures (These failures can be distinguised
Damage in the laundry
from mechanical damage of similar appearance only by careful
Apart from the mechanical damage due to careless handling and to defective
examination.).
equipment, the main source of damageto textiles in the laundry is improper use
Mechanical damage resulting from abrasion is common. For example, of chemical agents, especially bleaches.
sheets and pillowcases may be dragged across hard, rough surfaces such a s The conditions necessary for proper bleach usage have been discussed in
bed frames and sometimes even concrete floors and truck beds. detail i n Chapter 4. But to reiterate, damage from bleach is most often caused
Snags and cuts from sharp instruments also arecommon. For example, hand by:
towels can be damaged by razor cuts; the results may not appear until after using excessive amounts;
laundering when the weakened fibers give way under the stresses of the laund- failure to maintain the proper conditions of time, temperature, and pH; and
ering process. Tablecloths frequently receive knife cuts. Yarn failures that leaving residual bleach in the textiles because of inadequate rinsing.
occur a t a n angle to the warp and filling yarns are almost certainly from knife Another source of chemical damage in the laundry is caused by leaving mer-
cuts because tears in textiles always occur parallel to the warp or filling yarns. chandise for extended periods in laundry baskets t h a t are made from two or
Mechanical damage also can be caused from materials imbedded in or over- more dissimilar metals or alloys, such a s brass and stainless steel. These
laid on the textile. For example, when foods containing dissolved acids, salts, metals provide the necessary conditions for electrolytic action when they come
or even sugar evaporate on cloth, they form crystals or hard deposits of a non- in contact with textiles containing moisture and salts from laundering.
crystalline nature in the spaces between the fibers. Crystals are well-defined Electrolytic action produces corrosive chemicals in sufficient concentration
structures with angular, often sharp edges that can abrade or actually cut tex- to cause discoloration and permanent damage to the textiles. The damage isn't
tile fibers. Some foodstuffs such a s maple sugar or egg white beaten with sugar noticeable until the affected textiles are exposed to the heat of tumbling or iron-
are relatively harmless to textiles from the chemical standpoint, but do form ing. Then the damaged areas appear a s brown spots, which often disintegrate
crystalline coatings that can cause mechanical damage. and leave pinholes during use.
Damage to table linens, bedspreads, and the poorer grades of sheeting fre- A common mechanical problem t h a t causes damage to textiles in the
quently can be traced to manufacturing imperfections or to impractical design. laundry is overheated tumblers. Excessively high temperatures cause scorch-
For example, some table linens and bedspreads, particularly items with special ing. In addition, laundries that use perchloroethylene may encounter acid
designs, are constructed to have many floats (yarns running over the top of the damage to textiles from overheated tumblers. When exposed to flames or red-
woven yarns without interlacing). Yarns that arenot interwoven usually have hot metal higher than 900°F, perchloroethylene can decompose to produce
a very low twist and aren't very durable. The filaments are very easily broken strong corrosive acids that can damage cotton textiles. This problem may be
by slight abrasion and by stresses encountered during wear or in the washer. corrected by proper maintenance and operation of tumblers.
Poorly constructed table linens and bedspreads often sustain physical dam-
age during laundering. For example, some tablecloths made of cotton and
rayon with jacquard designs contain many floated yarns of loosely twisted Damage to polyester/cotton blends
rayon filaments. This particular type of construction sacrifices durability for While the cotton portion of a blended textile is subject to the same types of
a n attractive appearance. Consequently, during laundering and even general damage a s items of 100 percent cotton, the polyester portion has a higher
use the loose floating yarns have a great susceptibility to wear a n d a tendency resistance to chemical (other than alkali) and mechanical damage than does
to snag, leading to increased possibilities of damage. the cotton portion.
A common occurrence in blended textiles is the almost complete removal of
Chemical damage during manufacture the cotton portion due to either chemical damage, a s described earlier, or
During manufacture, textile damage can also occur in the finishing process. mechanical damage. This mechanical damage is caused by a n abrasive action
Chemical agents, particularly bleach, are usually responsible. As in launder- of the polyester on the cotton during use and laundering. The flexing of the
ing, bleach used in high concentrations or a t excessively high temperatures blended fabric causes the polyester fibers to cut or abrade the cotton fibers into
during manufacture causes marked degradation of fibers. short lengths. These short cotton fibers are removed in laundering, usually
Tests of many samples of cotton tablecloths t h a t have developed holes or appearing a s lint. Many laundries observe more lint from blends than from all-
even fallen apart during laundering have proven t h a t the damage was caused cotton items due to this action.
by overbleaching during manufacture. To check results, unlaundered items The polyester portion of blended fabrics most often is damaged by strong
alkaline solutions. This damage, called alkaline hydrolysis, is greatest a t high
temperatures or in the presence of quaternary ammonium compounds (some Turnbull's b l u e t e s t
softeners and some bacteriostats). Chemicals:
Polyester fabrics are thermoplastic and become "relaxed" a t high tempera- 1. Solution A - 10 grams of ferrous sulfate per liter of water.
tures. This relaxed state allows the fiber to free itself of wrinkles and return to 2. Solution R - 10 grams of potassium ferricyanide per liter of water.
the desired shape. However, wrinkles are believed to be set into polyester by
too-rapid cooling from a relaxed state. This problem usually occurs during rins- Procedure:
ing as the water temperature is lowered and is often referred to a s thermal 1. Immerse the sample in Solution A.
shock. Overloading increases the amount of wrinkling because of increased 2. Rinse in warm water (55"C, 131°F).
compression of the load and erratic cool down. 3. Immerse in Solution B for five minutes.
4. Rinse in hot water (70°C, 158°F).
TESTS F O R DAMAGE Obseruation: A deep blue color shows the presence of carboxyl groups, indi-
A number of tests can be used to evaluate the nature a n d extent of damage to cating cellulose damage.
fibers a n d textiles. The procedures listed here are for analyzing some of the
types of damage typically found in a professional laundry. For a comprehensive R e s i s t d y e i n g test
listing of test methods, refer to more specialized sources such a s Analytical Chemicals: A solution of 5 grams of Chlorazol Sky Blue F F (C.I. Direct Blue
Methods for a Textile Laboratory, Third Edition, American Association of 1) per liter of water.
Textile Chemists and Colorists, 1984. Procedure:
Chemicals referred to in the following tests may be purchased from local 1. Immerse the sample in the dye solution a n d boil for five minutes.
chemical supply companies. 2. Rinse in hot water (70°C, 158°F).
Teds for chemical damage to cellulosic fibers (coffon, linen) Observation: Light spots show the presence of carboxyl groups, indicating
Fehling's solution cellulose damage.
chemicals:
1. Solution A - 60 grams of copper sulfate per liter of water. Muller's t e s t
2. Solution B - 346 grams of potassium sodium tartrate and 100 grams of Chemicals:
sodium hydroxide per liter of water. 1. Solution A - 10 grams of phenylhydrazine-p-sulfonic acid per liter of
water.
Procedure: 2. Solution B - 2 grams of Fast Blue Salt (C.I. Azoic Diazo Component 48)
1. Mix equal parts of solutions A and B. and 1 gram of sodium bicarbonate per liter of water.
2. Immerse the sample i n the mixture and boil for 10 minutes.
3. Rinse in hot water (70°C, 158°F). Procedure:
1. Immerse two samples in Solution A (boiling).
Observation: Pink or red deposits (cuprous oxide) indicate the presence of 2. Remove one sample after 30 seconds, the other after one hour.
reducing groups, which damage cellulose. 3. Rinse both samples thoroughly in warm water (55OC, 131°F).
Harrison's test 4. Immerse both samples in Solution B (room temperature) for 20 minutes.
Chemicals: 5. Rinse in hot water (70°C, 158°F).
1. Solution A - 80 grams of silver nitrate per liter of water. Obseruations:
2. Solution B - 200 grams of sodium thiosulfate and 200 grams of sodium 1. Sample 1(30 seconds in Solution A, 20 minutes in Solution B) - a brown-
hydroxide per liter of water. red stain indicates oxycellulose (bleach/alkali damage).
Procedure: 2. Sample 2 (one hour in Solution A, 20 minutes in Solution B)-a red-violet
1. Dilute Solution A 1:20 with water and diluteSolution B 1:10 with water. stain indicates hydrocellulose (mineral acid damage).
2. Mix equal volumes of the diluted solutions. Tests for chemical damage to nylon (and other polyamide) fibers
3. Immerse sample and boil for five minutes. Ninhydrin test
4. Rinse in Solution B dilution (1:lO). Chemicals: 5 grams of ninhydrin per liter of water.
5. Rinse i n hot water (70°C, 158°F).
Procedure:
Observation: A gray or black deposit of silver indicates the presence of 1. Place a sample of damaged fabric and a sample of undamaged fabric in
reducing (aldehyde) groups, which damage cellulose. the test solution and bofi for five minutes.
2. Rinse and allow to dry. bacteria are able to grow. Effective bacteriostatic and bactericidal agents pre-
vent growth of the bacteria species toward the fabric. The greater the distance
Observation: If the damaged sample absorbs less dye and is a different between the bacteria growth and the fabric, the more effective the finishing
shade than the undamaged sample, damage from light is indicated. Sam- treatment.
ples damaged by acid or alkali absorb more dye than the undamaged
sample. STAIN REMOVAL METHODS
Most of the stains encountered in the professional laundry are removed in the
Test for damage to polyester regular washing process. The stains remaining after washing are generally of
W N,N-dimethylparaphenylenediaminehydrochloride test unknown origin, although long experience usually allows operators to judge
Chemicals: A solution of 0.2 grams of N,N-dimethylparaphenylenediamine the basic character of the stain - grease- or oil-based, rust, and so forth.
hydrochloride, 5 milliliters of 0.4 N potassium hydroxide, 95 milliliters of Many methods have been developed to deal with the large number and var-
methyl alcohol, and 100milliliters of benzene. (Dissolvethe 0.2 grams in the iety of stains encountered on textiles. In professional drycleaning, stains are
potassium hydroxide, then add the methyl alcohol, followed by the benzene.) dealt with on an individual basis, and highly skilled spotters employ specific
stain-removal procedures for known and unknown stains.
Procedure: Immerse the sample in the test solution and shake it for two However, the professional launderer, working with largevolumes of textiles,
hours. simply cannot treat stains on a n individual basis. Stains must be treated in
Observation: A yellow-brown stain indicates damage from weathering. bulk.
This approach is presented in this section on stain removal. The stain remo-
TESTS K)R BACTERIOLOGICALGROWTH val procedures discussed here have been reduced to a few basic treatments,
A number of bacteriological tests designed to monitor the presence and/or type each of which can be applied to large volumes of stained fabrics in the washer.
of bacteriological species on equipment and/or fabric are available to the (Detailed formulas a m e a r in Tables 9-3 and 9-4.)
A A
laundry operator. Stains are grouped broadly into four basic categories:
Specialized training and equipment are needed to perform culture-type 1. grease- and oil-based (animal or vegetable derived),
evaluations. 2. oxidizable (many foods and medicines),
Hard surfaces such as laundry carts, washing machines, and trucks are 3. reducible (dye), and
normally evaluated. A trained technologist collects samples fromvarious loca- 4. metallic (aluminum and rust).
tions. The samples are cultured to encourage bacterial growth, and the colonies The proper approach to dealing with these stains is to remove each of them
of bacteria are identified and counted to determine the type and level of con- sequentially in the washer by the shortest, simplest, and least costly procedure
tamination. Culture testing i s especially appropriate in healthcare that preserves the color and strength of the fabrics being treated.
applications.
Textile surfaces such a s ironer covers and press covers are not normally Grease and oil-based stalns
evaluated using the above procedure. The porous and rough texture of these Grease- and oil-based stains come from a number of sources. Body oils and
surfaces makes obtaining accurate samples for evaluation difficult. greases, either exuded or applied, stain wearing apparel. The numerous fatty
Researchers have had success using impression plates, a method in which substances contained and used in food are found on restaurant linen and
fabric surfaces are pressedinto a growth medium and later cultured, identified, garments.
and counted. However, research indicates that the transfer to impression plate On cotton, these stains usually yield to high temperature and high alkalinity
i s not always complete, leaving some organisms undetected because they for extended periods of time. One treatment is a n alkaline boil (boil out):
didn't transfer to the medium. Draw a low water level.
A more accurate procedure for evaluating bacteriological species on fabric is W Add about three pounds of anhydrous sodium orthosilicate per 100 pounds
to cut a specimen of the fabric, pulverize the specimen in a blender, and sample of textiles and sufficient soap or synthetic detergent to produce a heavy suds
the resulting solution. a t temperatures ranging from 195O to 205OF.
Some tests are designed to monitor the performance of bacteriostatic or bac- Agitate for 30 minutes to three hours.
tericidal finishes, either permanent or laundry applied. Rinse.
The standard test used to evaluate the effectiveness of a finish is the zones of This treatment does have drawbacks. It consumes large amounts of time,
inhibition test. The technologist takes samples of the fabric, places them in a supplies, and energy. It also affects tensile strength because the textiles are pro-
bacteriological media, adds bacteria species to the media, and allows them to cessed a t high temperatures in oxygenated water of very high alkalinity.
grow. After a specified period of time, the technologist evaluates the samples in An alternative treatment is to use a surfactant-based formula with less alka-
terms of zones of inhibition, which measure how close to the fabric sample the linity and lower temperature. Surfactant-based products are also more effec-
tive than alkaline products on mineral-oil stains. The recommended formula is: oxalic acid treatment generally is the first used in any sequential stain removal
H Draw a low water level a t 180°F. procedure; it can be removed or neutralized by subsequent treatments in the
H Add about four pounds of product per 100 pounds of textiles. cvcle.
H Agitate for 20 minutes. The process is:
H Rinse. H Draw a low water level a t 150' to 160°F.
I Add oxalic acid a t the rate of 8 to 16 ounces per 100 pounds of textiles being
Oxidizable stains processed.
These stains are from the color-based materials found in foods, medicines, and I Agitate for about 20 minutes.
cosmetic preparations. They yield to the action of an oxidizing bleach, such a s I Rinse three or four times.
chlorine, hydrogen peroxide, or even sodium perborate.
These stains require strong bleaching action, much more intense t h a n the The stain-removalsequence in the washer
bleaching action encountered in the regular washing process t h a t they may The common stain-removal procedure in the washer combines the boil out,
have already undergone. However, a n intensified bleaching process leads to a bleach treatment, and oxalic treatment into a single formula. The reducing
decrease in tensile strength. To minimize this problem, the formula calls for a bleach treatment is used only in special instances.
low temperature. By reducing the bleaching temperature from 160' to 88OF,
bleach activity is reduced sixteen fold (six percent of the activity a t 160°F),allow- Table 9-3: Stain-removal procedure for unknown stains
ing for corresponding increases in bleach-bath strength. An overnight soak is
the most effective way to bleach out oxidizable stains: Water Temperature Time Supply usage
H Draw a high level of water a t a temperature not exceeding 80°F. Operation level ("F) (min.) Supply type per I00 Ibs.
H Add 5 to 15 quarts of one percent bleach per 100 pounds of fabric.
I Soak the textiles for four hours to overnight. Bleach soak High 80 Overnight Bleach 5 to 15 quarts
I Add antichlor to the rinse water to deactivate the heavy concentration of of 1%bleach
bleach. Rinse High 110 3 M u m b~suif~te 2 ounces
Reducible stains Rinse High 110 1
Reducible stains generally are dyes, most commonly hair preparations, but Rinse High 110 1
also other fugitive dyes encountered in the professional laundry. They require
the action of reducing bleaches; the most common one used is sodium hydrosul- Fabrics still stained should be set aside and treated as follows:
fite with an alkali such a s soda ash. Reducing sour Low 150 15-20 Oxal~cacid 8 to 16 ounces
The process is:
H Draw a low water level a t 160°F. Rinse High 150-160 1
H Add sodium hydrosulfite a t the rate of 2 pounds per 100 pounds of fabric. Rinse High 150-160 1
I Agitate for about 20 minutes.
H Rinse. Boil out Low 195-205 60-180 Sodium 4 pounds
ortho-
Metallic stains silicate
Iron rust i s the most common stain in this group. Rust stains are removed by a
reducing agent such a s oxalic acid, sodium or ammonium bifluoride, sodium Soop or To suds
trisulfate, or hydrofluoric acid. detergent
The bifluorides and hydrofluoric acid are relatively safe for fabrics because Rinse High 150-170 1
they can be left in textiles in lower concentrations without danger of tendering
Rinse High 130-150 1
or weakening the fabric.
The fluoride compounds are hazardous and must be used carefully. Hydro- Rinse High 100-120 1
fluoric acid, in particular, can be fatal to humans and must be used only with
Rinse High 110 1
extreme caution.
Oxalic acid is a reducing sour, and its reducing action also is effective Rinse High 110 1
against other reducible stains in the load. However, it's very damaging to cot- Sour Low 110 4 Sour To des~redpH
ton if allowed to remain in the textile following treatment. For this reason, the
Experience shows that the overnight bleach soak (top portion of Table 9-3) For example, most linen supply classifications average about three percent,
normally removes between 70 a n d 85 percent of all stains encountered in the but bib aprons are likely to average much higher in stain rejection. This reflects
professional laundry. This procedure does not take time out of the productive the severe use and abuse aprons receive. Similarly, diapers t h a t are exposed
day and frequently is carried out a s a single step. The 15to 30 percent of stained to food and medicines are very stain-prone.
textiles that don't respond to the treatment are set aside for oxalic treatment Stain reject averages should be used a s a guide to washing intensity. For
and boil out (bottom portion of Table 9-3), which must be done during produc- example, a washing formula that holds stain reject percentages in diapers
tion hours. below five percent may be taking a n inordinate toll on textile strength. Test
A plant processing 100,000 pounds per week with three percent stain reject pieces can help determine if washing intensity is too great. Similarly, hospital
has a weekly stain load of 3,000 pounds. This represents four 800-pound over- linens showing 10 percent stain reject may need a more intensive washing
night loads a week, but only one load needs to be treated with oxalic acid and formula (greater concentration of alkali, detergent, bleach, higher tempera-
boiled out. tures, and longer washing time) to reduce stain rejects.
The reducing bleach treatment (Table 9-4) is used only in special instances Removing silver nitrate stains
in which stains are known to be reducible. These stain-removal procedures Silver nitrate stains pose special problems in hospital and medical work. The
(Tables 9-3 and 9-4) are intended only a s guides to problems currently being above formulas don't work on these stains, but the following will:
experienced in the industry. Various segments of the textile rental industry To spot stains:
encounter high or low stain percentages depending upon the soil classification Make a cold 1percent alcoholic solution of iodine crystals and apply to the
and the severity of washing. stained area.
After a few minutes, decolorize the iodine-moistened area with a 3 percent
Table 96: Stain-removal procedure for reducible stains sodium thiosulfate solution.
Follow with regular laundry processing.
Water Temperature Time Supply usage To soak linens in bulk, two solutions are needed:
Operation level ("F) (min.) Supply type per 400 Ibs. To immerse garments, prepare a solution containing 11 ounces per gallon
each of citric acid and thiourea.
Flush High Hot 2 To soak garments overnight, use this solution diluted 30:l.
-
- -
Reducing sour Low 150 15-20 Oxalic acid 8 to 16 ounces Launder fabrics lightly following immersion or soaking.
-
Soap or To suds
detergent
Rinse High 170-180 1
Rinse High 150-160 1
-
T
he professional laundry plant uses water and energy to process linen
supply and industrial textiles. In the process, it discharges chemicals and
soils a s wastewater and stack emissions.
This chapter identifies water and air pollution considerations and how
launderers can conserve energy.
For more complete information on wastewater processes, refer to publica-
tions by TRSA and other sources. The material presented in this chapter pro-
vides a n introduction and historical perspective only.
WATER POLLUTION
In the years following World War 11, the sudden rise in industrial and home
construction forced many municipalities to enlarge their sewage disposal facil-
ities and build new treatment plants to handle the increasing amounts of
waste.
To get the funds to build new plants and expand existing facilities, local
governments had to find new revenues. Many decided to impose surcharges for
handling industrial sewage rather than add to the residential tax burden.
However, even the enlarged publicly owned treatment works (POTWs)
couldn't keep up with two problems caused in part by laundry products used by
both consumers and professional launderers:
nonbiodegradable detergents were producing large amounts of stable foam
in lakes, rivers, and streams.
phosphates were enriching the water, causing rapid plant growth that
accelerated aging of slow-moving bodies of water.
Nonbiodegradable detergents
POTWs use both chemical and natural processes to remove pollutants from
wastewater effluent. Bacterial action is a key factor in water purification. Bac-
teria and other microorganisms in water, with the assistance of sunlight and
dissolved oxygen, decompose many natural and synthetic substances. This
phenomenon is referred to a s biodegradation, and substances acted upon by
bacteria are said to be biodegradable.
Most soils and chemical washing agents are completely biodegradable.
However, synthetic detergents produced from petroleum sources prior to 1963 als such a s cadmium, lead, mercury, and zinc.
were not easily biodegraded, and their wide use in consumer laundry deter- Normally, BOD and SS (suspended solids) are considered compatible to a
gents in the 1950s and early 1960s led to severe problems of foaming in streams POTW. However. POTWs have been setting limitations on the acceptable con-
and waterways. Standing suds on streams and sewage treatment ponds were a centration of these compatibles and assessing a user charge for excess
common sight a t that time. On Mondays and Tuesdays, traditional consumer amounts discharged. POTWs also have been setting maximum discharge lirn-
wash days, foam heights often reached six or seven feet. its for oils, greases, and heavy metals. Limits on heavy metal concentrations
Manufacturers of laundry detergents reacted by reformulating consumer can be particularly troublesome for some professional laundries.
products to combat this problem. Beginning on July 1,1963,nonbiodegradable The cost of discharging water into a POTW probably will continue to
detergents were gradually replaced by products meeting rigid standards for increase a s municipalities charge higher industrial recovery costs and user
biodegradation established cooperatively by the government and the Soap and fees or ad valorem taxes. Municipal sewer districts assess industrial recovery
Detergent Association. costs against most industrial dischargers to repay money loaned to the POTW
to expand and upgrade its facilities. User charges or ad valorem taxes a r e
Phosphates in detergents assessed against users of a municipal sewer system depending on the amount
In the late 1960s,consumer groups expressed much concern about the presence of contaminants they discharge into the system.
of algae and slime in lakes, ponds, and waterways. This growth of algae and But perhaps even more of a concern to professional launderers is the fact
slime is termed eutrophication - the process by which aquatic vegetation that their ability to discharge many substances into municipal sewer systems
grows to such a n extent that it clogs lakes and waterways, making them unfit is likely to be severely limited, if not banned, as the list of potentially toxic a n d
for industrial use, navigation, and recreation. hazardous substances is expanded by the federal Environmental Protection
Research indicated that phosphorus compounds were causing eutrophica- Agency (EPA).
tion because of their nutrient qualities for plant life. Whether phosphorus in
detergents is a principal cause of eutrophication is debatable. Both human WATER AND ENERGY CONSERVATION
excrement from sewage disposal plants and fertilizer contained in runoff from The cost of water for laundry processing has risen sharply in the past decade.
farm lands constitute major sources of phosphorus pollution. The cost increase is attributable to the increased cost of water itself, to t h e
Chemists have tested and evaluated many possible replacements for phos- added charge for sewage disposal, and to special user charges for discharging
phates in detergents, including carbonates, zeolites, citrates, and complex certain pollutants in sewage.
organic sequestering agents. An even more compelling reason for conserving water than its cost alone i s
None of these has proven to be as effective in the detergency process a s phos- the fact that 40 to 60 percent of all water usedin the professional laundry must
phates. In fact, some of these phosphate replacements have created new envir- be heated. Obviously, the less water used, theless energy is required forheating.
onmental concerns because they can resuspend heavy metal contaminants. The rapid risein energy costs has given added impetus to the search for ways
This issue is not yet completely resolved. Certain localities ban the use of to reduce water consumption.
phosphorus and its compounds in laundry detergents. However, many other Water can be conserved in a t least two ways:
areas allow the use of phosphates in commercial laundry detergents figuring 1. Rinse waters can be recycled with no treatment.
that the detergency benefits outweigh the small contribution to overall phos- 2. Water can be recycled through a water reclamation system.
phorus levels. By using the formulas listed in Chapter 7, laundry operators can reduce
water use about 20 to 50 percent below traditional formulas without using a
Wastewater regulations water reclamation system.
The professional laundry can expect to see higher costs to purchase water, Washer/extractors eliminate one rinse cycle by adding an intermediate
higher costs to discharge polluted water, and severe limitations on the dis- extraction step between rinses. Obviously, because less rinse water is used o n
charge of toxic or hazardous substances into municipal sewer systems. equipment with intermediate extraction, less water is saved by reuse.
With the emergence of environmental protection agencies at every level of Continuous washing systems can reduce water consumption to as low as one
government from local to federal, industrial establishments are coming under gallon per pound of merchandise. By design, continuous washing systems
increasingly stringent regulations governing sewer discharges. As substantial reuse a substantial portion of water and energy, which in part accounts for
users of water, professional laundries have come under close scrutiny. their increasing popularity.
Many municipalities now assess fees for industrial discharge based on the The cost of gas or oil required to heat water, generate steam, and run condi-
volume and characteristics of the wastewater. Pollutants normally measured tioning and drying equipment adds up to about 50 percent of total nonlabor
as characteristics of wastewater are materials that consume dissolved oxygen, variable laundry processing costs. For this reason, many operators closely
biological oxygen demand (BOD),and chemical oxygen demand (COD);mate- monitor and control steam and hot water consumption and the use of gas i n
rials (mineral-basedoiland grease) soluble in Freon or hexane; and heavy met-
conditioning and drying. stantial. Two methods of conserving dryer heat are:
However, a total energy and water conservation plan requires vigilance 1. using a heat pipe (or wheel) unit, which warms incoming air by running it
throughout the operation: through a finned bank of tubes set in the dryer exhaust, and
2. recirculating air from the dryer.
Physical plant and maintenance The first method is commonly used in heavy industry and has been adapted
Energy conservation in the plant starts with insulating hot water and steam to the professional laundry. For the second method, factors such a s lint filter-
pipes and tanks, inspecting steam traps, repairing steam and condensate ing and the moisture level and re-entry point of recirculated air must be consi-
leaks, repairing water leaks, and using low-energy light bulbs in all light dered when selecting, sizing, and installing air recirculating units.
fixtures.
Boiler operation and heat recovery AIR POLLUTION
For maximum savings, boilers must be maintained a t peak operating effi- Increasingly stringent local regulations in various parts of the country control
ciency. More importantly, an efficient wastewater heat reclaimer can reduce atmospheric pollution.
energy consumption by a s much a s 40 percent over a-system with no reclaimer. Two emission standards that come under the jurisdiction of the EPA and
that are being regulated a t federal, state, and local levels are particularly
Processing important to linen supply and industrial rental plants:
Processing procedures offer many opportunities to conserve energy. 1. discharges of pollutants from boiler stacks, primarily from coal-fired and
Reduce h o t w a t e r temperatures. Many plants maintain hot water high-sulfur, fuel-oil-fired boilers, and
temperatures of 180°F.While this temperature may be needed for breaks, suds, 2. perchloroethylene (perc) emissions from drycleaning operations.
and carryovers, it's often higher than needed for rinsing and souring. The Occupational Safety and Health Administration (OSHA) also is impos-
An energy-saving procedure here is to lower water tank temperature to 160°F ing strict standards on the use of perchloroethylene.
or less and use a thermal control that adds steam to the wheel to boost water Usually, local agencies have the authority to enforce regulations that are
temperature as high as needed for the break. While some may argue that using more strict than federal government regulations. Therefore, each operator
steam in the hot water heating tank is more efficient than in the washer, a must exercise close vigilance over actions being taken, or considered, by state
lower hot water tank temperature probably results in lower overall energy use. and local regulatory bodies.
One reason for this is that light- and medium-soil formulas perform satisfactor-
ily at a top temperature of 130" to 145OF.
L o w e r w a t e r levels. Reducing water levels reduces the liquid/fabric ratio
in each bath, which in turn reduces the efficiency of the dilution process.
Many operators have attempted to reduce energy consumption by lowering
suds levels by one inch and rinse levels by two inches. However, to offset the
reduced dilution effect, they've had to add processing steps. For example, in
many cases, lowering the rinse levels by two inches requires an additional
rinse. In this situation, total water consumption actually increases rather than
decreases.
Substitute a n i n t e r m e d i a t e e x t r a c t f o r a rinse. This is frequent practice
with washer/extractors. In general, a one-minute intermediate extract elimi-
nates one rinse. This practice also represents a n efficient means of managing
washing temperatures by reducing the amount of water requiring temperature
change. Intermediate extraction decreases the amount of moisture retained in
the fabric by approximately one-half of what is retained after a simple drain
step. For example, 100 percent cotton retains 0.3 gallons of water per pound fol-
lowing a drain operation and only 0.15 gallons per pound following an inter-
mediate extraction. Although this lost water must be made up in the next cycle
after the intermediate extraction, the subsequent fill uses less water than does
an extra rinse step. The intermediate extraction also provides the benefit of
chemical consistency of the rinsing bath.
Recover d r y e r heat. For many years, operators paid no attention to the
energy lost in dryer and conditioner exhaust. However, the waste can be sub-
WASHING AND
FINISHING EQUIPMENT
I
,
I
down other molecular units. The term is often applied to chemical damage to
polyester fibers caused by contact with a strong alkaline solution.
Alkaline pressure-A measure of the alkalinity of a solution a s expressed by its
percentage of sodium oxide content.
Amine -A compound t h a t may be regarded a s a derivative of NH3 (ammonia)
I
in which one or more of the hydrogen atoms h a s been replaced by hydrocar-
bon radicals.
Anhydrous - Free from water, a s in anhydrous metasilicate.
Aniline dye - A type of dye derived chemically from aniline or other coal t a r
ii derivatives.
Anionic - A class of surfactants t h a t ~ r o d u c e snegatively charged active
Antibacterial - A chemical agent t h a t is able to kill or retard the growth of a Boiling polnr - The temperature a t which a substance passes from the liquid to
bacteria. the vaDor state.
Antichlor - Reducing chemicals used in rinse or sour baths to facilitate com- Bolt - roll or length of fabric.
plete removal of residualchlorine. They includesodium bisulfite, sodium thio- Bonding - A process of pressing fibers into thin sheets or webs held together
sulfate, and proprietary antichlors. by adhesive chemicals.
Antirnycotlc - Having the property to minimize thegrowth of mold or mildew. Borax - A weak and sparingly soluble alkali, known chemically a s sodium
Antiseptic - A substance, generally applied to living tissue, that prevents or tetraborate.
arrests the growth of microorganisms either by inhibiting their activity or Break (breaksuds) - T h e first wash chemical bath. In light- and medium-soil
destroying them. formulas, all of the surfactantldetergent and alkali to be used in the entire
Anti-static - Able todisperseelectrostatic charges on a fabric and prevent build- formula is generally added to the washer in the break bath. The break is the
up of static electricity. single most important step in the laundering process from the standpoint of
Aseptic - Free of microorganisms capable of causing infection. soil removal.
Aspergillusniger- A type of fungus responsible for thedevelopment of mildew Break compound - Any washroom supply used in the break or initial opera-
in fabrics. tion in the washing formula.
Atmospheric fading (gas or fume fading) - Fading of some dyestuffs through Broadcloth-A fine, rich-looking. closely woven cotton fabric, usually mercer-
exposure to certain gases given off during the burning of fuels. ized. Most dress shirts are broadcloth.
Basic dye - A type of dye capable of coloring silk a n d wool directly but requir- Brownian movement - A ceaseless movement of ultra-microscopic particles of
ing a n assistant on cotton. Although they produce a very bright color, such colloidal nature, first observed by a n investigator named Brown. This
dyes are little used because of their poor fastness. movement is important in detergent processes a n d is exhibited by soap and
Bentonite - A colloidal clay capable ofadsorbing largequantities ofan oily soil. other colloidal substances.
Bichloride of mercury - Sometimes referred to a s bichloride or corrosive subli- Brush - To finish knitted or woven fabrics by raising a n a p on them with circu-
mate. A poisonous, corrosive salt of mercury used chiefly in pharmaceuticals lar brushes.
and antiseptics. I t frequently attacks and tenders cottons a n d linens, and the Buffer -Substance or mixture of substances that in solution maintains a con.
damage does not appear until the textiles are laundered. s t a n t hydrogen ion concentration despite addition of comparatively large
Biochemical oxygen demand (BOD) - A measure of the amount of oxygen amounts of acid or alkali.
consumed in the biologicc: ,oce;s that breaks down organic matter in Building - The use of an alkali to enhance thedetergcnt efficiency of a soap.('
water. Large amounts of organic waste use up large amounts of dissolved detergent solution.
oxygen, thus the greater the degree of pollution, the greater the BOD. Bursting strength - The pressure required to rupt,ure a fabric.
Biodegradable - A substance subject to the process of biodegradation. Calico - A coarse, printed cotton fabric, usually made from low-grade cotton
Biodegradation - The decomposition of a natural or synthetic substance and heavily sized.
through t h e action of bacteria a n d other microorganisms in water with the Carbonate - An alkaline chemical salt in which carbonic acid is the neutral-
assistance of sunlight and dissolved oxygen. ized acid.
Bleachbath (bleach suds) -The bath in which bleach is added a s the last deter- Carboxyrnethylcellulose(CsH701(OH)10CH~COOHJn - Used a s a surface-active
gency-promoting agent incorporated into the laundry formula. I n the past, agent. (See surfactant.)
this step h a s been referred to a s t h e bleach suds because a light running suds Carboy - A container often encased in a protective covering and usually used
was taken a s the visual indicator t h a t the pH was correct. With the advent of to hold from 5 to 15 gallons of a corrosive liquid.
low-sudsing synthetic detergents and the placement of flushes between Carryover (carryover suds) -Acleaningstepin a laundry formula in which no
break and bleach to lower alkalinity for correct pH a t the bleach, testing for supplies a r e added, but supplies previously added a r e retained for use.
bleach pH rather than using the visual presence.of suds is a necessity. Catalyst - A substance capable of speeding up a chemical reaction. I t can be
Bleaching in the clear - Bleaching under conditions where minimal amounts recovered practically unchanged a t the end of the reaction.
of soil, chemicals, and other materials remain in solution. Cationic - A class of surfactants that produces positively charged active
Bleaching intensity - The quantity, concentration, time, and temperature of ingredients when dissolved in water.
bleaching. Caustic potash - See potassium hydroxide.
Bleed - To lose dye from a colored fabric during laundering or drycleaning; Caustic soda - See sodium hydroxide.
can be caused by improper cleaning methods, dye application, or excess sur- Causticity- The amount of free alkali or hydroxyl ions liberated when alkaline
face dye. salts are dissolved in water.
Body - The compact, solid. or firm feel of a fabric.
-
Celsius Referring to a temperature scale in which the interval between the Color buildup - Accumulation of loose or nonfast dies a n d other coloring mat-
freezing poirit and the boiling point of water, under standard pressurecondi- ter from fabrics in a cleaning solvent.
tions, is divided into 100 equal parts or degrees, so t h a t 0°C corresponds to Calorimeter - An optical instrument for measuring color intensity; used to
32OF and 100°C to 212°F. Indicated by the letter C after the stated temper- evaluate and standardize a colored solution.
ature. Combed yarn - 11 cotton yarn t h a t h a s been subjected to a special combing
-
Centigrade See celsius. operation to remove short fibers and impurities remaining after the carding
Centrifugal force - The force t h a t tends to propel a thing or its parts outward operations. This added process produces finer, smoother, and stronger yarns.
from a center of rotation. Compatible - Capable of being used in conjunction with other materials
Choelomium globosurn - A microorganism responsible for the development without loss of essential properties.
of mildew in textile fabrics. Condensate - The purified substance, usually water or solvent, formed a s a
Charged system - A method of cleaning, employing drycleaning solvent to
result of a condensing or distilling action.
which a quantity of detergent h a s been added for improved cleaning.
Condense -To reduce from one state to another s t a t e with a denser form, a s
-
Chelate To tie up or render certain substances inactive.
steam to water. Also, to compress or compact.
-
Chelating agent A substance t h a t h a s the ability to tie up and render certain
Condition - To prepare goods for ironing, pressing, or other finishing opera-
substances, such a s hardness salts and iron, inactive in water. tions by running in a tumbler until desired moisture retention is reached.
Chemical oxygen demand (COD) - A measure of the amount of oxygen Construction-Thenumber of yarns per inch in warp a n d filling in a fabric; for
required to oxidize organic and oxidizable inorganic compounds in water. example, 60 x 52 means 60 yarns per inch of warp and 52 yarns per inch of
The COD test, like the BOD test, is used to determine the degree of pollution filling.
in a n effluent. Contact stain - A stain acquired by a textile touching a staining surface or
Chino - A particular type of all-cotton, khaki-colored army twill made of another textile and picking up color.
combed two-ply cotton yarns. Corduroy - A coarse, durable fabric having a piled surface raised in cords,
Chintz - A glazed cotton fabric often printed with figures a n d large flower ridges, or ribs.
designs. Count - See yarn count.
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Chloride of lime A low grade of calcium hypochlorite assaying 35 percent Counterflow- A concept in which textiles being processed in a tunnel washer
available chlorine. and the water used for processing them move through the machine in oppo-
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Chlorite 'l'he bleaching agent sodium chlorite. site directions.
Chrome dye - A type of dye t h a t uses a chromium compound a s a mordant or Coupling agent -- A substance soluble in both water and in material to be
assistant. emulsified; improves the stability of a n emulsion.
Clarify- To remove foreign matter and soluble impurities from a solvent usu- Crease resistant - Refers to fabrics with high resistance to wrinkling or creas-
ally by distillation or filtration. ing and good recovery from wrinkling. Often obtained by chemical finishing
Classify- To separate goods according to degree of soil and resistance of fabric a s in durable press.
and color to physical and chemical attack. Cretonne - A drapery or slipcover fabric, usually printed, similar to chintz, but
Cleaning cycle -The total time consumed from the beginning to the end of a
without the glaze.
complete round of cleaning operations. -
CRF Abbreviation for crease-resistant finish.
-
Clearing agent A material added to lower the cloud point of a liquid deter- Crimp -To apply a wavy appearance to a fiber or yarn by means of a twist or
gent product. mechanical application.
Cloud point - The temperature a t which a nonionic detergent or wetting Crock - To rub loose dye off one fabric onto another. May also be a container
agent, in solution, tends to become cloudy with consequent decreased solubil- for chemicals.
ity and effectiveness.
-
CMC See rarboxymeihy~ce~lulose.
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Cross-infection An infection t h a t is acquired from a contaminated environ-
ment.
Coagulate -To clot or consolidate into a mass. The solidification of egg white Crowsfeet - Indistinct wrinkles in a fabric.
by boiling is an example. Crystal - A physical shape or form of matter, always conforming to a definite
Coalesce - T h e tendency for smaller droplets of a liquid to form one larger geometric pattern.
drop. In a good e m ~ ~ l s i ocoalescence
n, does not occur. Crystalline- Being in the form of crystals. A material t h a t is not crystalline is
COG - See NOG. Customer-owned goods. amorphous.
Colloidal - State of subdivision of matter in which particles of 100 mu Culture - A growth of microorganisms on a nutrient medium; to grow micro-
(microns) are dispersed in a continuous medium. organisms on such a medium.
Cure - To set a resin finish in treated fabric by converting it to the insoluble Disinfectant detergent - A chemical compound formulated to disinfect while
form by heat. it cleans.
Cut pile - Fabrics such a s velvets, plush, or corduroy in which pile surface is Disperse - To scatter finely divided particles in such a manner t h a t the indi-
produced by cutting yarns,either warp or filling, t h a t were originally woven vidual particles are not visible to the naked eye.
in loop form. Distill - To purify a liquid. such a s contaminated drycleaning solvent, by
Damask- A type of fabric in which the figures are formed by contrast between boiling, condensing, and collecting its vapors.
warp and filling yarns. The figures appear reversed on the wrong side. D.P. - Abbreviation for durable press.
Decompose - To break up into similar component parts by heat or chemical Drill - A stout twilled cotton fabric.
action; for example. the decomposition by heat of sodium bicarbonate into Drip dry - See wash-and-wear.
soda ash and carbonic acid. Dry side - Pertaining to cleaning or spotting agents t h a t dissolve in
Degrease - To remove greases and oils from garments prior to laundering or drycleaning solvents but not in water.
drycleaning with detergent a n d water. Duck- A dense, heavy cotton fabric usually having two warp yarns woven a s
Deleterious - Harmful or destructive, a s the action of strong acids on fabrics. one. Lighter weights used for service coats and uniforms, the heavier for
Deliquesce - The a c t of a solid turning to a liquid due to the absorption of tents, awnings, tarpaulins, aprons, and wherever unusual strength is
atmospheric moisture. required.
Denier - The weight in grams of 9,000 meters of fiber or yarn. The lower the Durable press - A long-lasting finish applied to textile fabrics to improve their
denier number, the finer the yarn. crease and wrinkle resistance. Synthetic resins are normally used for this
Density - A substance's weight per unit of volume. With dry products, it is purpose and are usually applied to cotton fabrics or blends of cotton and
generally expressed a s ~ o u n d per
s cubic foot; with liquid products, a s pounds polyester.
per gallon. Dye - Complex chemical coloring matter having a n affinity for textile fibers.
Deodorize - T o destroy or mask odor. Elasticity -The ability of fibers, yarns, or woven and knit fabrics to return to
Deposit - To settle upon, a s lime soap on a washwheel. their original shape after being stretched.
ksiccate -To remove moisture; to dry. Electrolysls - A decomposition caused by a n electrical current.
Desize -To remove the sizing from textile fabric. Electrolyte - A solution t h a t easily conducts electricity.
Desizingagent- A compound t h a t h a s the capability of removing sizing from Elongation - Lengthening or stretching of a textile fiber, yarn, or thread by a
textile fabric. Some enzymes are excellent desizing agents. force applied to it. It is expressed a s a percentage of the original length.
Detergent - A surface-active agent or a blend of chemicals containing surface- Emulsification - Method of dispersing one immiscible liquid in another.
active agents t h a t concentrates a t all the surfaces in the washing zone and Enzymatic action - The splitting up of fats, oils, proteins, and sugars by
aids in the removal of insoluble foreign substances or soil from textile fibers. enzymes.
Dlafomaceous earth - The hard skeletal remains of microscopic plants called Enzyme - One of many complex proteins formed by living organisms t h a t are
diatoms. Used in filter powder. capable of increasing the speed of some decomposition reactions.
Diffuse- To spread or penetrate rapidly throughout. Esterilication- A process of producing a n ester (-C-O-)by reaction of a n alcohol
Dilution - A process using water to remove suspended soil from the washer by with a n acid.
lowering the concentration of soil in each successive bath. Dilution occurs Eufrophicatlon-The process by which a body of water, such a s a lake, becomes
with each drain and fill and is frequently monitored to evaluate the effec- rich i n dissolved n u t r i e n t s with consequent oxygen deficiency.
tiveness of rinsing. For conventional washers, a s the water from each bath is Eutrophication may occur by natural means or by artificial means such a s
dumped from the washer, soil is removed so t h a t the water in t h e next bath contamination by fertilizers.
h a s to suspend less soil. Dilution depends upon the total amount of water in Extensibility- Length gained by stretching a fiber, yarn, or thread to the break-
the washer for each bath a n d the amount of water retained by the load after ing point. It is expressed a s a percentage of the original length.
draining. Fabric - A system of textile fibers produced first by building yarns a n d then
Dimensionalstability- Ahility of fabric to retain its shape and size after being weaving or knitting these yarns.
subjected to wear, washing, and drycleaning. Fabric softener - A chemical added to the washer duringor after thcsour bath
Direct dye - A typeof dye used primarily to dye cotton and rayon, for which i t for t h e purpose of improving the feel or hand a n d suppleness and reducing
h a s good affinity. harshness of fabrics.
Dirt - Foreign matter out of place such a s soil or stains. Fadeometer - A standard laboratory device for testing the iastness of a
Disinfect (disinfectant) - To free from infection, usually with a chemical agent colored fabric to sunlight.
that destroys disease germs or other harmful microorganisms.
Greige (gray) - Pertaining to fabric produced by weaving or knitting prior to
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Fahrenheit Referring to a temperature scale on which the interval between
dyeing, bleaching, or finishing. It usually contains sizing or other finishes
the freezing point of water a t 32'F and the boiling point a t 21Z°F,under
standard pressure conditions, is divided into 180 equal parts or degrees. that are subsequently removed.
Indicated by the letter F after the stated temperature. Grelge goods - Unbleached fabric, such a s unbleached muslin or sheeting.
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Fast color A color t h a t when applied to a fiber will not fade or change shade Gum - A sticky, viscous, water-soluble substance exuded from various trees
by exposure to sunlight, washing processes, or body wastes. and plants. The substance hardens when exposed to air.
Felt - To shrink wool fabrics with accompanying interlocking of the fibers. Hand - The feel of fabrics such a s soft, harsh, or hoardy.
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Fllament A fine, continuous fiber, such a s silk, rayon, polyester, or nylon. Heat-set - The stabilization of synthetic fabrics to prevent change in size or
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Filler A material added to soap or other detergent t h a t does not improve its sha~e.
Hemoglobin - The pigment of blood. I t contains 0.4 percent iron and is a
effectiveness under the conditions of use.
Film - A thin coating, layer, or membrane. Colloidal films have a n important common source of staining.
part in emulsification and adsorption. High tenacify - Referring to yarn of high strength.
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Flame retardant (flame resistant) Pertaining to fabric treated or impregnated -
Highlight A lustrous or shiny area appearing on the surface of a starched
to resist burning. Also a chemical compound capable of imparting flame fabric.
resistance to fabrics. -
Humidify The amount of moisture in the atmosphere.
-
Flammable Capable of being easily ignited a n d burned. Humidify (relative) -The percentage of moisture in the a i r a s compared with
Flash point -The lowest temperature a t which the vapors of a liquid decompose the total amount of moisture t h a t the air can hold a t the same temperature.
Hydrate -To combine with water. Also, a chemical compound formed by the
to a gaseous mixture t h a t can be ignited.
union of water with some other substance.
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Flatwork ironer rolling The rolling t h a t occurs, under certain conditions, to
Hydrogen - A colorless, odorless, tasteless gas; flammable and lighter than
the edges of flatwork when they pass through a chest-type ironer.
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Fluorocarbon A hiehlv volatile solvent similar to verchloroethylene except any other known substance.
that it contains fluorine atoms in place of chlorine in its chemical makeup. Hydrogenation - A process in which hydrogen is added to the unsaturated
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Flush A high-level bath for a short period of time prior to the break or the
portion of fats or oils t,o make them more solid and resistant to oxidation.
Hydrotrope - Substances t h a t act a s solubilizers and coupling agents for
bleach bath. Flushes generally are used for conditioning textiles before sub-
sequent baths and for removing debris and loose soil. otherwise incompatible materials. They help overcome turbidity or stratifi-
Foam/fwmlng agent - A colloidal hen omen on involving a n air-liquid cation in aqueous solutions containing a sparingly soluble oil or solid. They
also act a s cloud point depressors for light-duty liquids. Examples are
colloidal system. A material that increases the stability of this colloidal
phenomenon. sodium or potassium toluene sulfonate.
Hygienic - Pertaining to the preservation of health. I t requires sanitary
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Fray To wear out due to rubbing or friction.
conditions.
Fugifive (color) -
A color t h a t h a s poor affinity for the fiber to which it is
Hygienicallyclean -Although not a precise definition, one t h a t h a s received
applied and h a s a tendency to bleed, run, or be washed away entirely.
Fused fabric -
A resilient two-layer collar or cuff bonded together by a n acceptance i s merchandise free of microorganisms in quantities capable of
intervening solid film of binder. causing disease.
Hygroscopic - Capable of absorbit:$ atmospheric moisture readily.
Gas fade- To fade or to change color because of contact with g a s fumes in the
air. Hymolal salt - The sulfated fatty alcohols derived from the higher chain
Germicide - Anything t h a t destroys germs (microorganisms); applied alcohols and having soap-like properties.
In vitro - Refemng to the testing of antibacterial properties "in glass," a s in
especially to agents t h a t kill disease germs.
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Gingham A yarn-dyed cotton fabric usually woven in checks or stripes. test tubes, with no interfering material present.
In vivo - Testing of antibacterial properties a s "in life" usage, in which
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Globule A small drop of a liquid or particle of solid.
Glyceride - A chemical compound composed of fatty acids and glycerine. practical contaminants and denaturants are present.
Industrial clothing (fabrics)- Clothing for wear in industry rather than for
When reacted with strong, hot caustic, it forms soap and glycerine.
GO-back -An improperly laundered or drycleaned piece sent back for apparel and household use.
Infection - Invasion by pathogenic organisms t h a t multiply and cause
recleaning.
Gravity (specltic)- The relative weight of a certain volume of a solid or liquid disease.
compared with t.he weight of the same volume of water.
-
Infectioncontrol chemicals Any chemicals used to prevent cross-infection.
-
Gray Dull appearance of fabric color due to redeposition of soil or dye from Infectious - Having the ability to transmit disease.
wash water br solvent. Insoluble - Incapable of being dissolved.
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Grease A general name for oily solids.
Interfacialtension - The surface tension existing betwcen two liquids or a solid Mordant - A chemical agent applied t o a tcxtilefiber to improve the affinity of
and liquid t h a t keeps the liquids from mixing or a liquid from spreading on a a certain dye for the fiber and make the color fast.
solid. Soap lowers the interfacial tension between water and some soils and Mote - A small impurity that may occur in cotton yarn, such a s a spcck of
thus allows the soil to be flushed away. cotton seed or other impurity from the cotton plant.
Iridescent - Pertaining to fabrics having contrasting colored warp and filling Moth repellent - Chemically treated to resist moth damage. Also, a chemical
rams. compound for treating fabric, usually wool, to render it moth repellent.
Keratin - Principal constituent of cuticle, hair, hoofs, and feathers. Very rich in Muck (filter) - The combination of insoluble soil, used solvent, and filter
sulfur. powder t h a t i s removed from the bags, screens, or tubes of a filter. Also called
Kier - A mechanical device i n which cotton fiber or fabrics a r e boiled out to sludge.
remove the natural impurities. Muriatic acid - The commercial name for hydrochloric acid.
Kier boil - A treatment for t h e removal of deap-seated stains. T h e fabrics are -
Muslin A firm, plain, white cotton fabric used largely for sheeting.
boiled in a solution of alkalinedetergent a n d soap in a n open tank, preferably Nap - Fiber ends lifted from the body of a fabric to produce a soft, downy
provided with a steam injector for continuous circulation. surface.
Laminated - Pertaining to fabrics composed of layers of cloth joined together Net - A porous bag, usually constructed of cotton or nylon, to contain
with resin. garments during the cleaning process.
Latent alkalinify - Alkalinity present in t h e water supply. Neutralization - A chemical reaction in which a given quantity of a n acid,
Lecithin - An organic fatty material containing nitrogen and phosphorous either mineral or organic, reacts with a chemically equivalent amount of
found in practically all animal tissues and in somevegetable matter, chiefly alkali to form water and a salt.
the seeds. NOG - See COG. Not our goods.
Level -The heightof the water or solvent inside thecylinder ofthe washwheel Nonlonic - A class of surfactants that produce no charged active ingredients
when the machine is loaded and in motion. when dissolved in water.
Liberate - To set free, a s to liberate chlorine or oxygen in bleaching. Nonpathogenic - Not capable of producing disease.
Lime - Calcium oxide or hydroxide. Nontoxic - Not poisonous; not capable of produciug injury or disease.
Llnt - Short fiber produced a n d loosened by mechanical action or the action of Nonwoven - A fabric produced directly from fibers matted together instead of
chemicals in the cleaning process. being spun or woven.
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Lipase A fat-splitting enzyme. Nutrient - A nutritious chemical element or compound; a s a n example,
Lubricant - A material added to some laundry products to help keep washer phosphate or nitrate absorbed by plants to promote growth.
doors from sticking and/or to make fabrics easier to process during ironing. Onebath system -A drycleaning procedure employing a low concentration of
Luster -The shine occurring on or imparted to fibers, yarns, or finished fabrics. detergent in which garments receive a single wash with no rinse.This is also
Mercerizing - A process in which cotton yarns are held under tension while referred to a s a single-bath system.
being passed through a caustic soda solution. The resulting yarn is strong One-shot - A built soap or built synthetic detergent t h a t is added to the
and lustrous. washwheel, usually in a single dosage.
Micelle- A special grouping of a number of molecules of a chemical substance, Opaclfier - A substance t h a t imparts a white, uniform creaminess or lotion
such as detergent, held loosely together by chemical bonds. effect to a liquid detergent mixture.
Mil - A unit, 1/1000 inch, used for measuring the diameter of textile fibers. Optical brightener - A type of dye t h a t enhances the brightness of ccrtain
Mild charge - L o w concentration of detergent in drycleaningsolvent; usually fibers by converting invisible ultraviolet light to visible light. Common
one-half to two percent. ingredients in almost all manufactured or compounded laundry products.
Mildewcide - A chemical agent t h a t is able to kill mildew-forming organisms. Frequently added to some fibers during manufacture.
Mileage (solvent) -The number of pounds of clothing t h a t can be cleaned with Ozone - A highly active form of oxygen containing three atoms per molecule
one gallon of solvent. instead of the usual two. I t i s usually formed by a silent electrical discharge
Mineral spirits - Petroleum solvent. in the air a n d is used as a n oxidizing a n d deodorizing agent in the
Moire - Fabrics having a grain or wood effect produced during finishing. purification of water.
Moistureretention- Amount of moisture, usually expressed a s a percentage of -
Package dye To dye yarn wound on perforated spools or tubes p l a c ~ din a
textile dry weight, t h a t a load of laundry retains before or after a processing special dyeing machine containing the dye liquor. Also a small contamer uf
operation. concentrated dye.
Monofilament - A single-filament yarn. Packageplant- A plant doing a complete cleaning service with all work done
on the premises.
Pad - To impregnate fabric with dye liquor or other liquid by squeezing Pineoil - A byproduct of the steam distillation of pine stumps in the manufac-
between rolls. Also, to impregnate with liquid for a special purpose, a s to pad ture of turpentine and rosin. It is used a s a solvent and deodorant.
mops with a dust control oil. Ply- Yarn formed by twisting together twoor more single strands or threads.
Pad dye - To dye fabric by first passing i t through a trough containing the dye Polyethylene - A ~ l a s t i film
c of high molecular weight; polymerized ethyline
and then squeezing it between rollers to remove the excess. produced by polymerization a t high pressure. I t is translucent, is the lightest
Pastel -Pertaining to light shades of color. of all plastics, and remains tough and flexible even a t low temperatures.
Pathogen - Microorganisms capable of causing disease. Polymer - The molecular chain-like structure from which resins a n d synthetic
pearl ash -Common name for potassium carbonate. I t is a n alkali t h a t absorbs fibers are produced by the linking together of molecular units called
moisture from t h e a i r readily a n d h a s approximately 77 percent of the neu- monomers.
tralizing power of soda ash, which it resembles. Palymerize- To link molecules together to form a polymer.
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Penetrate/penetrating agent To wet out a fiber completely. A surfactant can -
Pony washer Any small washwheel. Usually used for special pieces or s ~ n a I I
be considered a penetrating agent. l o t . needing careful treatment.
Percale - A closely woven fabric, either white or colored, principally used for Poplin - A ribbed fabric, usually cotton.
dresses, shirts, and sheets. Pore - The opening or space between yarns in a fabric t h a t produces
Perchloroethylene - Tetrachloroethylene (C12CC12).Popular drycleaning sol- "breathing" properties. Also may refer to spaces between fibers in yarns.
vent. Porous (porosity) - Having minute openings t h a t permit t h e passage of air or
Permanent linish -A finish applied to fabric t h a t retains its specific properties liquid through a material.
throughout the normal period of wear and maintenance. -
Post-cure The application of heat to set permanent press resins after the
Permanganate (potassium) - A strong oxidizing agent frequently used in garment h a s been completely manufactured.
stain removal. Potash - Common term for potassium and its compounds.
Permeable - Able to be penetrated by fluids or gases. Potassium hydroxide (KOH) - A strongly alkaline chemical used chiefly for
Perspiration - A body excretion containing salt, albumin, fatty acids, and making soap and a s a reagent in chemical titrations.
other constituents. It may be acid or alkaline depending upon varying Precipitate - To separate, a s a solid from a liquid. Also refers to a s o l ~ d
conditions. substance separated from a liquid.
Petri dish - A round glass or plastic dish with a cover used for growing bacteria. Pre-shrunk - Term used to describe fabrics or garments that have becn
Petroleum solvent - Flammable drycleaning solvent derived from petroleum subjected to a shrinking process before being placed on the market.
products. Two main types are in use: 140°F,and Stoddard solvent with a Pre-spot- To apply a cleaning or spotting compound to fabric spots or stains
flash point of a t least 100°F. before cleaning.
pH -The term applied to a scale of values designating the degree of acidity or Pressure (detergent or alkaline) - The total amount of alkali present for
alkalinity of a solution. The pH scale runs from 0 to 14 with 7 representing a detergent use.
neutral state. Values greater t h a n 7 a r e alkaline. Values less t h a n 7 are Primary treatment - First stage of sewage treatment t h a t involves settling out
acidic. larger suspended solids by screening and sedimentation before discharge for
Pharmaceutical - Pertaining to drug o r medicinal uses. A pharmaceutical further treatment.
grade of chemical is suited to ~ h a r m a c e u t i c a use.
l -
Print A general term for fabric with designs from dyes applied by engraved
Photometer - An optical instrument for measuring the light reflectancy of rollers, wood block, or screens.
surfaces. Used in determining whiteness, soil removal, and color fading for Pure finish - Finish in which no sizing or treatment is added to the fabric.
laboratory control of cleaning formulas. Quality control - Testing a n d inspecting materials during manufacture or
Physical - Pertaining to a n y properties or forces not chemical. processing to assure conformance to quality standards.
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Pick One filling thread on the loom or in the finished fabric. Quat (quaternary ammonium compound) - Derivative of ammonium
Pigment - Coloring matter that, in general, h a s no affinity for a surface. For hydroxide or its salts in which nitrogen is bound to four replaceable groups
example, t h e pigments in paint have n o affinity for wood. but they have a n (usually organic mdicals).
affinity for oil. Dyes, on the other hand, have a n affinity for fibers. -
Reagent Any substance used in a chemical reaction to detect, measure,
Pile - A fabric made with y a r n s or fibers t h a t stand upright from the main examine, or produce other substances.
body of the material, such a s velvet. These may be looped a s in terry. Reclaim -To recover for further use, a s stained fabrics in a laundry. Also, to
Pill - A small ball of fibers on the surface of a fabric caused by abrasion and recover solvent from drycleaning garments by condensing the vapors driven
wear. off during drying. Also, recovering wash water for treatment and/or subse-
quent reuse.
Relative humidity (solvent) - The amount of rnoislure present in drycleaning Silica - A substance known chemically as silicon dioxide; sand is reprcsenta.
solvent expressed a s a percentage of the maximum amount t h a t the solvent tive of silica.
could contain a t the same temperature and pressure. Silt - A very fine suspension of mineral matter, usually found in water.
Repel - To force away from or prevent from mixing with or adhering to a s a Silver nitrate - A corrosive chemical t h a t causes black silver stains on textiles.
chemical agent to repel soil from fabrics. -
Sizing Starch or synthetic polymer added to fabric to increase the firmness or
Repellent - A chemical or substance that repels. crispness of the fabric.
Residue - The nondistillable matter remaining behind after solvent Slippage - A form of textile damage that results when one set of threads slips
distillation. over the opposite set. Smooth natural fibers, yarns possessing little twist,
Resllient - Referring to the ability of fabrics to withstand crushing or creasing fancy weaves (floats), and wear are common causes of slippage.
without objectionable change in appearance or shape. Slub-A thick placein a yarn thatproducesan irregularity in the fabric. Filling
Rlnse - High water-level bath or baths following the bleach and preceding the yarns are sometimes dubbed purposely to give a n irregular ribbed effect to
sour or finishing bath. During rinsing the final portions of loosened soil are the fabric.
removed along with the bulk of the washing compounds used in laundering. Sludge - See muck. Also a concentrate in the form of a semi-liquid mass
Except for antichlors, chemicals are usually not added to rinse. deposited a s a result of the treatment of sewage and industrial wastes.
Rinse solvent - Solvent used for rinsing garments. -
Snap The quality of a finished fabric when it possesses luster, uniformity,
Rosin - An acidic material obtained from coniferous or pine trees; sometimes and unimpaired whiteness.
used to extend soap. Sodium hydroxide (NaOH) - A strongly alkaline compound used in making
Rosin soap - A soap made from rosin-containing material. soaps and alkaline builders.
Salt - Chemically, the product of thereaction between a n acid and a base. Also, Soil release - A finish applied to textiles designed to provide easy removal of
sodium chloride (common table salt, brine). subsequently applied soil.
Sanforizing - T h e trademark for a patented process for pre-shrinking cotton -
Soil repellent See soil retardant.
fabrics by controlled compression during manufacture. Articles made from Soil retardant -Treated to resist soiling. Also, achemical substance that, when
properly Sanforized cloth are not subject to appreciable shrinkage. applied to fabric, will enable it to resist soiling.
Saponification- Alkaline hydrolysis of a n oil or fat, or the neutralization of a Soluble - Capable of being dissolved in water or solvent.
fatty acid to form a soap. Solvent - A substance, usually liquid, capable of dissolving other suhstances.
Saturate - To charge or furnish with something to the point a t which no more I t is the name usually given to the liquid used for drycleaning garments.
can be absorbed, dissolved, or retained. Solvent (140°F) - See petroleum solvent.
Scour -To clean fibers or fabric to remove such impurities a s sizing, oil, and Solvent retention - Amount of solvent that a load of drycleaning retains after
dirt in preparation for dyeing or bleaching. cleaning and extraction.
Secondary infection - A super-imposed infection occurring in a host who is Sour - An acidic agent used in the final bath of the laundering process to neu-
already suffering from a n earlier infection. tralize the last traces of alkali from soaps and builders left in fal~ricsfrom
Secondary treatment - The biological treatment of sewage wastes following previous steps in the process.
primary treatment by sedimentat~on. Sour bath - Normally the final bath in the laundering process. The purpose of
Selvage - The natural edge of a woven fabric finished so t h a t it will not ravel. the sour (or acid) bath is to neutralize the alkalinity of the water in the tex-
I t always runs parallel to the warp threads. tiles before removing them from the machine for finishing.
Semicolloid - A particle having only partial colloidal characteristics. Specific gravity - The ratio of the weight of a definite volume of a given sub-
Sepsis - Poisoning caused by absorption into the blood of pathogen~c stance to the weight of a n equal volume of water. Temperature must be
microorganisms. specified.
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Septic Causing sepsis or putrefaction; infective. Split rinse - A rinse of moderate temperature obtained by complrtely opening
Sequester - A chemical process in which a soluble complex is formed that pre- both hot and cold water supply valves a t the same time.
vents the normal react~onof certain chemical species, for example, the action Spot - To treat by hand a spot or stain with a chemical for the purposeof remov-
of water hardness ions i s sequestered by complex phosphates. ing it. To ~ o s i t i o nthe washwheel for openingAoading.
Shakeout - To straighten out cleaned goods prior to finishing. Squeeze roll - A mechanical device for applying pressure to squeeze out
Shrinkage -The contraction and increase in density of fibers and yarns caus- liquid.
ing a change in shape and size of textile fabrics. Moisture, sudden tempera-
ture changes, fabric design, and mechanical and chemical actions promote
shrinkage.
Staple-Theaveragelength of a raw textile fiber t h a t is twisted into a yarn. I t Surface tension - T h a t property of all liquids in which the ex1,osed surface
may vary from one-half inch as in the case of cheaper cottons to many miles tends to contract to the smallest possible area, namely a sphere. This ten-
in length a s in the case of rayon filaments. I n general, when comparing nat- dency is greatly reduced by detergents, which aid i n t h e wetting a n d removal
ural fibers of the same type, the longer staple is of higher quality a n d is of soil from fabrics.
stronger. Surfactant (surfaceactive agent) - A substance t h a t alters energy relation-
Starch lubricant - An oily o r w a x y m a t e r i a l added t o s t a r c h t o i n c r e a s e ships a t interfaces, such a s wetting agents and foaming agents.
flexibility. Suspended solids (SS) - Small particles of solid pollutants in sewage t h a t
Sfatic electricity - An electrical charge generated by rubbing unlike bodies contribute to turbidity and t h a t resist separation by conventional means.
together. The examination of suspended solids and the BOD test constitute the two
Sfeam sweep -The injection of wet steam to the still, just above the liquid sol- main determinations for water quality performed a t wastewater treatment
vent level, to help flush out the solvent vapors. facilities.
Stearine - A glyceride composed of a stearic acid and glycerine. When tallow W a l e - A stain t h a t exhibits a wavy outline.
cools from a melted condition, stearine is the first material to solidify. Syndet - Shortened form of synthetic detergent.
Sterile - Free of living organisms. Synthetic detergent - A surface-active material made from synthetic organic
Stocksolution - A solution of laundry or drycleaning supplies prepared in con- compounds that h a s cleansing action similar to soap. These detergents may
centrated form for later convenient use. be anionic, cationic, or nonionic, depending on their constitution.
Stop spot - To spray, splash, or pour a soil-spotting compound on apparently Synthetic solvent - A nonflammable chlorinated or fluorinated drycleaning
heavy or tenacious soil stains prior to cleaning. solvent such a s perchloroethylene.
Straight s o a p - Commercially pure soap containing a t least 88 percent anhy- Tenderize (tender) - To lower the fiber strength of fabric by chemical or
drous soap. mechanical me:ms.
Streak- A stain taking the form of a line on a drycleaned garment caused by Tenslle strength - The measure of the ability of a yarn or fabric to resist
the nonvolatile residue in highly contaminated solvent. breaking.
Strength, breaking - See tensile strength. The force required to cause fabric Tertiarytreatment - A phase of wastewater treatment beyond the 85 to 95 per-
breakage. cent BOD removal of the secondary stage by such processes a s carbon
Strip - To remove dyes or stains from fabric by use of a chemical reducing adsorption, reverse osmosis, ion exchange, and demineralieation.
agent. Tetrachloroethyiene - See perchloroethylene.
Stripper (stripping agent) -The agent used to strip dyes or stains from fabrics. Texfile-The construction of yarns or knitted or woven fabrics.
Strong c h a r g e - High concentration of detergent in drycleaning solvent, usu- Thermoplastic - Having the property of becoming soft under application of
ally about four percent. heat, specifically referring to certain synthetic resins and textile fibers.
Substantive - Self-combining or adhering tenaciously, a s a dye substantive to Thermosetting - Having the property of hardening or setting with heat a s do
cotton. certain plastics or synthetic resins.
Suds - A bath occurring between the break and bleach bath. Suds baths are Thixotropy -The property of a substance decreasing in viscosity upon agitation
carried out a t low water levels, usually with hot or tempered water. If alkali or and increasing in viscosity on standing after agitati0n.Thi.s term is encoun-
detergent isn't added on these additional suds baths, they are referred to a s tered mostly in soap stock tanks.
carryover suds. Titanium stripper - A chemical reducing agent containing a compound of tita-
Suds carryover - See suds. nium used for dye or stain removal.
Sulfur black - A black dye t h a t is f a s t to washing but very sensitive tochlorine Titanous chloride (Tic!,) - A compound of titanium a n d chloride t h a t is a n
bleach. active reducing agent. I t is strong enough to remove m a n y dyes and is used
Sulfur dioxide- An irritating, gaseous compound of sulfur found frequently in a s a stain remover.
the atmosphere. I t is capable of causing dye fading and fabric tendering Titration - A process used to measure the concentration o r amount of a chemi-
when in contact with moisture. cal present in a solution.
Sulfur dye - A type of dye having sulfur in its basic structure; h a s poor bleach Tolerance - Ability to withstand or endure without ill effects.
resistance. Top dye - To add color to a fabric t h a t h a s already been dyed to produce a
Sunfast- Fabrics colored with dyes t h a t will not fade under normal exposure to greater depth or a change of shade to match the desired standard.
sunlight. Total fatly acid (T.FA) - The total amount of fatty material t h a t is obtained
Supersafurafe -To cause to contain more dissolved matter in a solution than is when a sample of f a t or fatty acid i s completely saponified and, after acidula-
normally possible. Such solutions are unstable and readily return to t h e sat- tion, extracted with petroleum ether or ethyl ether.
urated state.
Translucent - Allowing passage of light, but diffusing it so that objects beyond Yarncount-Thenurnber ofyarns per inch used in the construction of a fabric.
cannot be clearly seen; in between transparency and opacity. Zeolite - A hydrous aluminum-sodium silicate capable of exchanging sodium
Two-bath system - A drycleaning system utilizing two distinct cycles in the for calcium magnesium a n d other metal. It also h a s the capability of regen-
cleaning process, one with solvent containingdetergent, the other with clear erating (reversing) itself when treated with brine(concentrated sodium chlo-
rinse solvent. ride solution).
Vapor- A gas, especially from a substance t h a t is a solid or liquid a t ordinary Zero son water - Sometimes called "zero hardness? This refers to water tha t is
temperature. free from hardness salts.
Vat dye - An extremely light and wash-fast type of dye applied to fibers in a
soluble form by reducing action and then permanently set by oxidizing to its
original insoluble form. Used primarily on cotton yarns and fabrics.
Verdigris - A greenish or bluish deposit of copper soap or salts formed on
copper, brass, or bronze surfaces.
Viscosity - The resistance to flow exhibited by a liquid product. Viscosity in
detergent practice is measured in centipoises, water a t room temperature
having a viscosity of 1 centipoise. The higher the viscosity, the thicker (less
fluid) the product.
Viscous - Possessing or characterized by viscosity.
Volatile - Readily evaporated.
Volatile matter - T h a t portion of a chemical substance t h a t vaporizes below a
specified temperature within a specified length of time.
Warp - The h e ~ v yyarns running lengthwise (parallel to the selvage) in a
fabric and upon which the cross yarns or filling yarns are built.
Wash-and-wear - Fabrics or garments treated with a wrinkle-resistant finish
allowing them to be washed and used without pressing.
Washing s o d a - A form of soda a s h containing crystallized water within its
molecular structure.
Washwheel - A washing machine.
Water conditioning -The treatment of water prior to washing to remove unde-
sirable, suspended, or dissolved matter.
Water repellent - Referring to fabric or garments treated to resist wetting by
water without closing the fabric pores. Also, a chemical used to impart water
repellency to fabrics.
Waterproof - Referring to fabrics t h a t have been treated in such a manner a s
to make them impervious to penetration by water. Rubber, oil, or plastic-
coated fabrics are typical.
Weight - T o apply a finish to fabric to give increased weight.
Wet - To cover or saturate with water or solvent.
Wet clean - To clean by washing in water.
Wet-dry - Pertaining to spotting agents that are soluble or miscible and rinse-
able in both water and drycleaning solvents.
Wet-side- Pertaining to detergents orspotting agents that aresoluble and rin-
seable in water.
Wetting agentlwetting - A material that increases the spreading of a liquid
medium on a surface.
Whiteness retention - The whiteness reflectance of a laundered or drycleaned
fabric expressed a s a percentage of the original reflectance.
Yarn - The continuous thread-like strand resulting from the spinning opera-
tion and used for weaving, knitting, or crocheting.
APPENDIX 1: WEIGHT OF TEXTILE
RENTAL ITEMS
1i
I
8
TRSA weigh1 chart Weight in pounds of 100
clean, dry pieces
Weight In pounds of 100
clean, dry plseas Weighted Range of weight
average reported
WeigMed Range of wdgM
average reported Law High
Law Hlgh
BIB
DUST CONTROL - 100%cotton
DUST MOPS - 65% polyester/35%cotton
100%cotton - 50%polyester/50%cotton
100%cotton
50% polyester/50%cotton FOUR-WAY
100%cotton - 65% polyester/35% cotton
50% polyester/50% cotton - 50% polyester/50% cotton
100%cotton
100%cotton MECHANICS
50% polyester/50%cotton - 100%cotton
100%cotton
100%cotfon SHOP, DENIM
50% polyester/50%cotton - 100%cotton
100%cotton - 50%polyester/50%cotton
PlllOWCASES TERRY
42"x33" - 100%cotton 26 23 30 BATH MATS
- 65% polyester/35%cotton 23 19 25 18"x24" - 100%cotton
- 50%~olyester/50%cotton 24 21 33 20"x30" - 100%cotton
42"x36" - 50% polyester/50%cotton 25 24 27
Weight In pounds of I00 WelgM In pounds of I00
clean, dry pieces clean, dry pieces
Welghted Range of weight Weighted Range of weight
average repor)ed average reported
Low Hlah Low Hlgh
BATH TOWELS Jackels, Bus Boy, long
20"x4OU - 100%cott on Sleeve - 65% polyester/35%cotton
20"xM" - 100%cotton Jackets, Lapel, Long
22"xM" - 100%cotton Sleeve - 65% polyester/35% cotton
Vests, No
MASSAGE/HAND Sleeve - 65% pobpster/35% cotton
15"x25" - 100%cotton
16"x26" - 100%cotton DRESSES
Belted, Short
WASHCLOTHS, FACE Sleeve - 65% polyester/35% cotton
12"x12" - 100%cotton Rlncess. long
Sleeve - 65% polyester/35%cotton
Rlncess, Short
LINEN SUPPLY GARMENTS Sleeve - 65% polyester/35%cotton
CAPS, CHEF GOWNS, ARTIST'S
- 100%cotton Not-fitted,Long
- 65% polyester/35%cotton Sleeve - 65% polyester/35% cotton
Seml-tltted, Long
COATS. LONG Sleeve - 65% polyester/35%cotton
Frocks, Long Seml-fltted, 314
Sleeve - 65% polyester/35% cotton 123 100 133 Sleeve - 65% polyester/35%cotton
Frocks, 314
Sleeve - 65% polyester/35% cotton 143 120 150 SHIRTS
Lugger, Meat/ Kltchen. Short
Butcher- 50% polyester/50% cotton 124 110 126 Sleeve - 65% polyester/35% cottohn
Shop
Coat - 65% polyester/35%cotton 135 107 156 PANTS SUITS
Wraparound. Long Tops. Short
Sleeve - 65% polyester/35%cotton 74 74 81 Sleeve - 65% polyester/35% coilon 58 40 75
Wraparound, 314 Slacks - 65% polyester/35% cotton 89 75 100
Sleeve - 65% polyester/35%cotton 87 75 105
PANTS/TROUSERS
COATS. SHORT Chefs - 65% polvester/35% cotton 101 78 105
Chef. Long Cook's - 65%polyester/35% cotton 102 79 108
Sleeve - 65% polyester/35% cotton 94 80 105
Chef, Short I
FACE TOWEL
Wx26" - 100% cotton
APPENDIX 2: CAPACITIES OF
WASHCLOlH
CYLINDRICAL TANKS
12"x12" - 100% cotton
SURGEON/NURSE GOWN
-
100%cotton
APPENDIX 3: CONVERSION FACTORS
-1 7.8 0 32 35 95 203
-15 5 aI 37.8 100 212
-12.2 10 50 40.6 105 22 1
- 9.4 15 59 43.3 110 230
- 6.7 20 68 46.1 115 239
- 3.9 25 77 48.9 120 248
- 1.1 %
. 86 51.7 125 257
1.7 35 95 54.4 130 266
4.4 40 104 57.2 135 275
7.2 45 113 60 140 284
10 50 122 62.8 145 293
12.8 55 131 65 6 150 302
15.6 60 Ido 68 3 155 31 1
18.3 65 149 71 1 160 320
21.1 70 158 73.9 165 329
23.9 75 167 76 7 170 338
26.7 80 176 79.4 175 34 7
29.4 85 185 82 2 180 356
32.2 Q3 194 85 185 365
195
Conversion factors
TO convert trom To MuRpfy by
Acres Square feet (ft?)
Square meters (rnl) 43560
4046 8
Btu Calorie
Foot pounds
Joules
Kilowott hours
Calories Btu
b t pounds
Joules
Centigrams Grams
Centil~ters
METRIC CONVERSION TABLE Ounces (U.S.. fluid)
Centimeters Feet
Metric units used in this table are based upon the following units: Inches
Meters
QuanMy Name SVmbOl Millimeters
Meter rn Yards
Length
Mass Gram Q Cubic centimeters (cc) Gallons (US, fluid)
Time Second s Liten
Electric current Ampere A Ounces (U.S,fluid)
Frequency Hertz Hz (57) Pints (U.S . fluid)
Force Newion N (rn.K~.s-~) Quarts (U.S., fluid)
Pressure Pascal Pa (N/m2)
Cubic feet Cubic centimeters
Energy, work, heot Joule J (N-m)
Gallon (U S.. fluid)
Liters
The metric system uses prefixes (see below) in conjunction with unit names. Cubic yards Gallons (U.S.. dry)
For example, a kilometer (km) is equal to 1,000 meters (m) (kilo = lo3= 1,000). Gallons (U.S.,fluid)
Liters
Factor ~retlx SVmbOl Feet Centimeters
10'2 or (1.OM).000.000.000) tera T Meters
109or (I ,OM).M)O.OOO) g w G
bet/second
I @or (1.OOO.OM)) mega M
103 or (1.000) kilo k
lo7or (100) hecto h
10' or (10) deka do
lo-' or (0 1) deci d Gallons (U.S., d v ) Cubic feet
10-2 or (0 01) cent1 c Gallons (U.S.. fluid)
10-3 or (0 001) m~lli rn Liters
10-~or(0000001) micro IJ
-
Poles (British) 0 1818
One horsepower hour = 2547
0.746kilowatt hours
One port per million = one milligram per liter
= 0 0584 grains per U.S. gallon
One grain per U.S.gcilon = 17.118 ports per million
Conversion of water meter reading to gallons 100 cubic feet (cu. fl.) = 748 gallons
,
Equivalent units tor defining boiler output
Itom Equlwlent unb
1 pound steam @ 212T 970 Btu/pound
1 square foot of steam 240 Btu/hour
1 square foot of water 150 Btu/hour
1 boiler horsepower (Bhp) 34.5 pounds of steam/hour @ 212°F
33.472Btu/hour
139.5square feet of steam
223 square feet of water
Labels Mildewcides 66
Heated fluid 155 Loading 24,89-91, 107, 156, 157, Mildistats 66,69
Heavy soil 98,99, 102-104, 119, chemical 57.66.67, 115, 121,
161 Mineral 13, 17,30, 48,53, 72, 76.
159 122,125
Lubricants 64,98 78.80, 106-108. 112, 119. 1.77,
Hemp 72 textile 72, 73 Luster 71.74, 77, 79,80,86
Lastrile 72 140
Hexametaphosphate 29,49.50 Magnesium 12, 26, 29-31,33,49, greases 147
Hexane 114,146 Latex 109 50 Modacrylic 72
Hotel sheets 99
Polyester 24, 41, 49, 51, 52,65, Rayoil 12, 63, 71, 72, 74, 79-81,
Mohair 73 Oxidizing agents 61, 80, 130
68, 72.78, 79,81,83,89,91, 134
Moisture retention 97, 98, 109, Oxycellulose 75, 137 94, 95-98, 106, 108-110, 116,
O x w e n 12, 23, 27, 28, 39, 49.60, bright 77, 79, 80
129, 135, 136, 138, 153, 159, dull 79
Mold 133 160 semi-dull 79
Molecules 11, 13, 36-39, 42, 71 0zone.173 Polyester/cotton 89, 94, 98, 106,
P a d 155 Reactivity 122, 124, 125
Monofilament 81 135, 153, 159 Recirculated air 149
Mops 109-112, 119 Pathogenic 28,65 Polyethylene 42, 78
microorganisms 54, 106, 121 Redeposition 16, 17, 39, 48, 108,
Motel sheets 89 Polytetrafluorethylene 80-81 127, 128
Moths 74, 78, 134 PBI (Polybenzimidazole) 72 Polymer 12,68, 70, 71, 78,80, 81 Reducible stains 54, 140. 142
MSDS 125 Pearl a s h 174 Polyvinyl acetate 68, 70, 116 Reducing agent 27,62, 140
Multi-filament 81 Penetrate 35,38,51, 119 Post-cure 87 Reducing sour 140
Muslin 173 Peptize 17 Potash 40, 117, 118 Reduction 113
Neutralize 12, 14, 27, 43, 5 6 6 1 , Percale 174 Potassium 18, 21, 43, 48,54,58, Regeneration 29,31,32,33,49.
62,96 Perchloroethylene 135,149 117, 118, 131, 132, 136-138 71.81
Neutralizing 16, 17,62,63,76 Permanganate 54,131 ferricyanide 137 Relative humidity 176
Neutralizing value 62 Perspiration 74, 107 hydrogen tartrate 132 Repeating unit 71
Ninhydrin 137 Petroleum 71,111, 146 hydroxide 43, 138 Residual 14, 19, 27, 56, 57, 61, 65,
pH 13-23, 25, 26, 43-46, 49, 50, 52, iodide 18, 21 94-96, 114, 135, 159, 160
Nitrogen 26, 39,64,67
Nonionic 39-42, 51, 64, 67. 103, 53, 55-57,59,60,65,67,75, orthosilicate 22, 48 Resin finishes 96
93, 94, 97,98, 102, 104, 108,
108, 109, 112,115, 119 permanganate 54,131 Rewash 95, 104
115,118,128,129,132,135 sodium tartrate 136 Rice starch 69
Nonpathogenic 28,65
effect of on bleach 22,56, 59, POTW (Publicly owned treat- Right-to-know law 122
Nontoxic 173 93,94, 128, 129,132
Nonwoven 173 ment works) 145, 147 Rinse times 127
foodstuffs 132 Pre-cure 87 Rinsing 94-96, 129
Nutrient 68.69, 146
Nylon 51, 72, 74, 77-78, 81, 109, indicator 13, 14. 15.16 Precipitate 49 Rock salt 119
137, 155 meter 97 Pre-conditioning 155 Rolling, ironer 62, 129
pads 155 test papers 13, 16, 18,21,22 Pre-shrunk 175 Rosin 176
Nvtril 72 P h e n o l ~ ~ h t h a l e 16,18,
in 20, 22, Presses 69, 74, 94,98, 105, 154- Rotary vacuum filter 112
93,-99 156, 159, 160 Rotation speed 130, 153
occluded 49
Phosphate treatment 29 extraction 97, 98, 109, 130 Rubber 72, 109, 114,124,159
Odor 12,63,70,80,105, 112,129
Phosphates 17, 29,46,49-50,52, Prewash operations 89 Hugs 73
Olefin 72, 78
One-suds procedure 99 58,108,115,145,146 soil sorting 89, 92 Running suds 93
Opacifier 173 in detergents 146 Print 175 Rust 12, 27, 62, 63, 69, 1 16, 129,
Optical brighteners 50-51,64 Phosphorous 12,49,146 Printing 86,87 139, 140
Organic 13, 16, 17, 20, 27, 28: 30, Photometer 174 Problem solving and trouble- Safety 62, 67, 99, 121, 122, 125,
39, 42, 50, 54,58, 59, 74, 76, Pick 26,106,110,158 shooting 127-143 126,149
78, 109, 146 Pigment 67,79 Proprietary products 42,52,70, chemical handling 121
bleach 58, 59 piiling 129 96 chemical storage 122
Orientation 36 Pillowcases 51, 89, 104, 134, 155 Propylene 42 hazard communication
Ornamentation 73 Ply 175 Protein 72, 73 standard 122-126
Orthosilicate 11-13, 22, 47, 48,52, Pollutants 145-147, 149 Proteinaceous 92 safe handling of washroom
93, 112, 115, 117-119, 139 Pollution 26, 145,146,149 Publicly owned treatment works chemicals 121-126
Orthotolidine 18, 22,23, 95 air 26, 149 (POTW) 145,147 Salt 11, 13, 31, 33, 41, 43. 4 4 , 46,
OSHA 122, 125, 149 water 11, 12, 15, 16, 19, 22, 25- Quaternary ammonium 49,67, 50,54,61,63,64, 116, 119,
29,52,65. 67,75, 89, 90.95, 78, 136 132, 137
Overbleaching 134
96, 110, 123-125, 127-129, compounds l2,44 Salts 12, 13, 26, 29, 30, 33, 32-44,
Oxidation 59
137. 145,147,153,159,160 Ramie 72. 78-79 48-50, 59, 117, 128, 131, 135
Oxidizable stains 75, 140
Sanforizing 176 carbonate 13, 29,50,60,93 Sour bath 13, 22, :j0, 51, 61, 65, Strength loss 23, 24, 55, 58, 59,
Saponify 16, 17 chloride 18,33 67, 96-99 68, 104. 128
Saponification 17, 48, 118, 176 hexametaphosphate 29, 49,50 Sour guidelines 97 Slripping 54
Saran 72 hypochlorite 57 Spandex 72 Stuffing 73
Saturation 97 hydrosulfite l3,54,61, 120, 140 Specific gravity 78 Substantive 178
Sediment 28 hydrosulfite dihydrate 13 Spinneret 81,82 Suds and carryover suds 93
Seed hairs 72 hydroxide 12, 43,44, 136 Spinning 79,81 Suds time 127
Selvage 176 metasilicate 118 Split rinse 177 Sulfated fatty alcohols 4 1
Semi-colloid 176 orthosilicate 11-13, 47, 48, 93, Stain 12, 20, 24, 35, 50,53,54, Sulfated nonionics 41
Sepsis 176 112, 115, 118, 139 56, 66,68, 94, 102, 104, 106, Sulfonated amides 41
Septic 176 oxide 16, 20, 44, 47, 48, 50,52, 119, 128, 137-143 Sulfonated oils 68
93, 95,99, 118 albuminous 52, 101 Sulfonation 41
Sequester 29,49,50
perborate 54,60, 140 grease- and oil-based 139 Sulfur 11, 13, 26,39, 116
Serum 92
percarbonate 54,60 metallic 30, 72, 128, 139, 140 Sulfur dye 178
Sewage disposal 145-147
peroxide 54 mildew 54,67,68, 74, 78, 133 Sulfuric acid 13, 18, 76
Shop and printer towels 48, 111,
silicofluoride 12 oxidizable 139, 140 Sunfast 178
113, 119
stearate 40 reducible 139, 140 Surface-active agent 35
Shrinkage 74
sulfite 27, 28, 61 removal 20, 24, 50, 53,56, 94, Surface tension 35
Silica 47 104, 128, 139, 141, 142
Silicated alkali 116, 118 thiosulfate 18, 21,54, 61, 96, Surface water 26, 28
136, 140, 143 Stain reject percentages 106, 143 Surfaces :35, 37, 40. 70, 121, 129,
Silicates 42, 44-48,52, 116-118
tripolyphosphate 12, 13, 29, 49, Stain removal methods 139-143 134, 138, 156,158
alkaline 13, 42, 45, 49
108 grease and oil-based stains Surfactants 12, 16, 17, 26, 35-42,
liquid 48 139-140
Softeners 45, 49-52, 64, 106, 108, 109,
solid 17, 47 metallic stains 140-141
fabric 64-65 114, 115, 121, 156
Silicon 12 oxidizable stains 140
textile 64 anionic 40-41
Silk 73.81 reducible stains 140
Soil classification 24,89,90,99, cationic 39, 64
Silver nitrate 131, 136, 143 silver nitrate stains 143
103,142,157,158 classification of 39-42, 71
Silverfish 134 stain removal sequence in the
Soil-release finishes 70, 87 how surfactants work 25-39
Sizing 68-70, 116, 149, 158 washer 141-143
Soil removal 24,35, 42,48, 49, nonionic 40-42, 108, 112
starch 68-70
53, 89-91,93,99, 102, 118, Standard solution 16 synthetic anionic 4 1
synthetic polymer 70
119, 127, 128 Staph 66 Suspended matter 28
Skin irritation 61
Soil retardant 177 Staple 74,78, 79,8 1, 114 soil 16, 25
Slide calorimeter 97
Soil sorting 89-90,92 Starch 68-70,97, 116, 129, 145 solids 123
Slime 146 modified 69, 152
Soil suspension 39, 42, 45, 108 Suspending power 17,42,45,51,
S n a g s 133,134
Solvent 17,25,107, 113 thick boiling 69 52
Soap 12, 14, 18, 26, 29, 40-42, 46,
synthetic 30, 41,51,52, 68, 70, thin boiling 68,69 Swale 179
49-52, 61, 64, 67, 102, 103,
116, 128, 129, 139, 146 146 Static 64, 65, 81, 130 Swell 68, 75, 80
Soap specks 12, 103 Sorting 89,92,98, 104, 157, 161 Steam 106, 119, 121, 124,128, Symbol, chemical 11. 12
Soda ash 22, 27, 52, 93, 115, 140 Sour 12-14, 18,22, 23, 27,50, 51, 130, 147, 148, 155, 156 Synthetic detergent 46, 51, 103,
Sodium 11-13, 16, 18, 20.21, 27- 61-65, 67,69.70, 78, 94,96, Steam air finishers and special- 119. 139
31, 33, 40, 41, 43-45, 47-52, 97, 98,99, 116, 122, 129, 140, ized presses 155, 156 synthetic resins 30
54, 57, 58-63, 78, 93, 95, 96, 153 Steam tunnel 155-156 Synthetic solvent 30, 41, 51, 52,
99, 108, 109, 112, 115-118, lubricating 64, 104 Sterile 105 68, 70, 146
120, 136, 137, 139, 140, 143 reducing 17,35,54, 64,65,96, Sterilizing 53, 54, 75 Table salt 119
bicarbonate 30.137 148 Stock solution 20, 51, 56, 59, 60, Tallow 40, 42, 49,5132, 64, 67,
bisulfite 54, 61, 96 under souring 128,129 116, 128 116
borate 60 Tank capacities 193
Teflon 80-81
Temperature 15, 17, 21, 25, 26, physical function 64, 116 Very heavy soil 98,102, 103,159 Waxes 68
49, 51.54-57.59-61,6567, Textile strength loss 55,59,68 Very light soil 98-101, 104, 159 Weaving 81.82.86
69, 75, 76-78, 92-94, 97,99, Texturized 81 Vicuna 73 Weft 82
101, 102, 105, 107-109, 111, Thermal shock 107.124.136 Vinal72 Weight of textile rental items 183
113, 117, 119, 121, 123, 127- Thermoplastic 74,89,109,136 Vinyon 72 Wet spinning 81
129, 135.137, 139, 140, 148, Titanium dioxide 79 viscosity 17, 180 Wet strength 131
154,155,159,160 Titanous chloride 54 viscous 68, 180 Wetting agent 16, 25,35, 41
Tempered water 93,99 Titration 13, 15, 16, 18-22,48,93- Volatile 76. 123 Wheat starch 68.69
Tender 140,179 95,98,101, 114, 115,118, 119 Warp 82,83,86,134 Whiteness 23,24, 40, 49dl,53,
Tensile strength 23, 2455, 59, Top dye 179 yarns 82.83 62,86,lO4, 109
104, 128, 130, 139, 140 Tow 81 Wash-and-wear 180 maintenance 63,62, 109
loss 23, 24,55,59, 104, 128 Toxicity 66, 113 Wash steps 92-98 retention 24,53
Test kit 18, 19 Trailing of bleach 94 Wash test piece services 23-24 Whitening agents 51
Test piece 23,24 Training 11, 121,122,126,138 Washer 120, 151-154 woo1 51,73,78,81
Tests Triacetate 72,81 loading guidelines 90-92 lambs 73
bacteriological growth 138-139 Trilobal 77, 79, 81 Washer/extractor 94,96,98, 147, new 11
cellulosic fibers 72 Tripolyphosphate 12, 13,29, 49, 148, 154 virgin 73
chemical concentrations 15-16 108 Washfast 119 Wool Products Labeling Act 73
chemical damage 130,134 Trisodium phosphate 50 Washing and finishing equip- Wrinkling 78, 87, 91, 107, 130,
textile damage 136-138 Troubleshooting typical operat- ment 151-161 136, 155
washroom 19-23 ing problems 127-130 Washing formulas 29, 106, 107 Yarn 80,82,83,86,87, 134, 180
Tetrasodium phosphate 29,49, Tumblers 94, 105, 129, 135, 155 Washroom compounds count 181
108 Tunnel, steam 155 optical brighteners 50, 51,64 structure 81-82
Textile Tunnel washer 156-161 sizing 68, 70, 149, 158 Yellowing 59,61, 94, 109, 128
dyeing 86-88 development of 156 Washroom test kit 18, 19 Zeolite 30, 32
finishing 86-88 dryers 161 Wastewater 145-146 Zinc 63, 131, 147
printing 86-88 extractors for 159-161 Wastewater regulations 146-147 chloride 131
Textile damage 89, 130, 133, 134, load sizes for 157-158 Water silicofluoride 63
138 mechanical action 158 absorption 65 sulfate 131
causes of 130-136 scheduling loads 158-159 color 27, 28, 52,87, 106
chemical, during manufacture textile handling systems after conservation 147-149
130, 134-135 extraction 160-161 consumption 25,52, 97, 99,
chemical, during use 130-133 sizing for 157-159 147, 148, 156
from fungi 133, 138 textile handling systems free 97
in the laundry 135 for 157 hardness 26,40
types of 157 impurities 26-28,95
mechanical 17,37, 129,133-
134,152,158 Turbidity 26,28,41 levels 17,91,93,95, 127, 129,
to polyester/cotton blends 135- Twill 84,85 148,151,153
136 Two-suds procedure 99 nature and sources 25-26
Textile fibers Ultraviolet light 51,32 pollution 145-147
classification of 71-73 Uniforms 48,68,119,131 purification 145
Textile labels 73 Universal Indicator 18.23.97 reclamation 119
Textile softeners 64 Unloading 152, 154,156, 161 recycled 147
application 11,67 Upholstered 73 repellent 88
Urea 64 rusty 12
chemical structure 39,49,64,
User charge 147 softening 12, 14, 16,28-33
70
Vat dye 120 sources 25-26
performance 65, 98, 104, 136
spray jets 110