TRNG I HC BCH KHOA TP.

H CH MINH KHOA K THUT HA HC B MN K THUT HU C

N MN HC
TNG HP NANO COMPOSITE Fe3O4 NG DNG TRONG TNG CNG THU HI DU, CHNG SA LNG MUI V N MN NG NG KHAI THC
GVHD: PGS. TS. NGUYN PHNG TNG SVTH : ON C MINH MSSV : 60801245

TP.HCM, 05-2012

Ni dung
Tnh hnh chung Tng cng thu hi du Vt liu nanocomposite C s l thuyt

Tng quan
Thc nghim

Quy trnh tng hp nano Fe3O4 Bin tnh b mt Kho st tnh nng ca ht nano composite Fe3O4

Tnh hnh chung

Du m
- Nhin liu - Nguyn liu - Sn xut in

87%

Du m - ngun mu ca th gii

Tnh hnh chung Thc trng

Nhu cu s dng ngy cng cao
87 triu thng/ngy 32 t thng /nm Tng khong 1-1,5% /nm.

Khan him cc m du

Thm d, tm kim kh khn

Trang thit b hin i K thut cao

Tr lng tham d hng nm gim 6,7 %

Du m - Vng en c nguy c b tuyt chng

Tnh hnh chung Gii php

a dng ha ngun nng lng Tit kim nng lng

Tng cng thu hi du

Tng cng thu hi du

Qu trnh khai thc

Du c khai thc bng nng lng t nhin ca va

Bm p cht lu duy tr p sut trong va

Tng kh nng rt du, gip ta c th thu li mt lng kh ln du cn li trong b.

Tng cng thu hi du

Tng nht ca h dung dch bm p Gim sc cng b mt gia hai pha du/ nc Thay i tnh dnh t ca va

Tng cng thu hi du

3 phng php
Phng php nhit
- Bm p cht lu nng vo va : nc nng, hi nc, - t ti ch

Phng php kh
Bm p kh vo va lm gim nht , tng kh nng linh ng ca du th v to p lc y du ln.

Phng php bm p ha cht

S dng cc ha cht c bit ( polymer, cht HBM,..)nhm tng hiu sut y du nh lm gim SCBM

Tng cng thu hi du

Cht hot ng b mt
Tp trung ti giao din lng - lng, lm gim sc cng b mt gia du vi mi trng nc

Tng cng thu hi du

C ch tc ng ca cht HBM
Tng h s mao dn Nc Lake (1989)
= _ = _
so

Ci thin tnh dnh t nc ca va

so sw cos wo
du wo sw

nc cht rn

Chn cch gim lc mao dn. Cht HBM c th gip gim lc mao dn bng cch gim SCBM gia hai pha du nc

Thay i tnh dnh t ca va t dnh t du sang dnh t nc hay dnh t trung gian

Tng cng thu hi du

S dng Polymer
_ = = _

Tng nht ca dng cht lu c bm p vo va th gi tr Nc cng tng theo, do tng kh nng y du

Nhc im

Kh khn trong qu trnh bm. Km bn nhit, b gim cp khi bm xung va.

Tng cng thu hi du Vt liu Nano

- C kh nng thay i tnh lu bin ca dng lu cht di va: tng nht ca dung dch bm p. - Thay i tnh dnh t ca b mt . - Hiu ng b mt. - Tng kh nng bn nhit cho polymer

Nhc im

D kt t khi khng c t trng ngoi

Tng cng thu hi du

Vt liu nanocomposite
Nanocomposite Fe3O4

Tng cng thu hi du

Chng xa lng mui

Chng n mn ng ng khai thc

Vt liu nanocomposite
nano Fe3O4
2-5 nm

Vt liu t hp
C cu trc tng t cc qu cu bn trong c nhn vi kch thc nano, c bc bn ngoi bi cc lp v to bi vt liu th hai (polymer hu c).

Vt liu nanocomposite
Qu trnh pht trin
Nm 2006, X. Liu et al tng hp ra loi vt liu c cu trc dng core/shell vi ht nano SiO2 ng vai tr l ht nhn c bao bc bi cc phn t polymer. Nm 2007, Jianping Ge et al tng hp ra cc vt liu core/shell siu t tnh, vi ht nhn l oxit st t Fe3O4 c bao bc bi cc phn t polystyrene Nm 2008, Ke Yang-Chuan et al, cc ht nano SiO2 c bin tnh b mt bi 3-methacryloxypropyl trimethoxy silane (MPS). Nm 2009, Qiang Gao et al. xut s dng poly(methacrylic acid-covinyl triethoxylsilane) bao bc cc ht nano SiO2 bin tnh thu c h cht mang thuc dng core/shell.

C s l thuyt
C ch tc ng Tng cng thu hi du Chng sa lng mui
Chng n mn ng ng

Kt hp cc c tnh ca cc thnh phn cu to: do dai, n hi, bn nhit,

- Thit lp h thng t trng trong ging khoan - Cht c ch lng ng

Bo v s n mn in ha : c vai tr nh cht kh bo v catot.

C s l thuyt
v mt s u im khc..
Kh nng phn tn tt trong mi trng: nano Fe3O4 sau khi bin tnh va c kh nng phn tn trong du li ng thi c th phn tn trong nc. Kh nng dn truyn dng chy, gia tng nht ng k cho dung dch bm p. Gia nhit bng t tnh. Khng c i vi mi trng.

C s l thuyt
Quy trnh tng hp
Tng hp nano Fe3O4
Bc 1
Phng php ng kt ta Phng php nhit phn

Gn tc nhn ghp ni
Bc 2
grafting to grafting from

Bc 3

Bc ht nano Fe3O4 bng cc polymer hu c

C s l thuyt
Tng hp nano Fe3O4 - Ht nano t tnh Fe3O4 c tng hp bng phng php ng kt ta di s h tr ca sng siu m.

- Khi nng ca cht t n mt trng thi bo ha ti hn, trong dung

dch s xut hin t ngt nhng mm kt t. Fe2+ + 2Fe3+ + 8OH- = Fe3O4 + 4H2O
Sng siu m ng vai tr l tc cht xc tc gip y nhanh tc phn ng v gip hnh thnh cc hat nano

C s l thuyt
Gn tc nhn ghp ni

- B mt ht nano Fe3O4 c gn cc phn t acid Oleic bng sng siu m v khuy c thng thng to mt lp OA bao bc quanh ht nano thng qua tng tc ca nhm carboxyl ca OA vi b mt ca ht. - Yu cu i vi cc tc nhn ghp ni : c nhm lin kt i C=C c th thc hin phn ng polymer ha.

C s l thuyt
Bc ht nano Fe3O4
Phn ng polymer ha gc t do trong h vi nh tng c to ra bng h thng phn ng khuy trn di tc ng ca sng siu m trong dung mi l nc.
2-Acrylamido-2-methyl-1-propanesulfonic acid sodium salt solution ( AMPS)

acrylamide

Quy trnh tng hp nano Fe3O4

Gn tc nhn ghp ni

Bc ht nano Fe3O4

Kho st tnh nng

Quy trnh
To cc mu kho st Pha trn hai h dung dch: nano composite Fe3O4 phn tn v cht HBM theo cc t l khc nhau o SCBM gia hai pha du v dung dch bm p

Thit b o sc cng b mt spinning drop Interfacial Tensionmeter Model 500 o nht dung dch bm p
Thit b o nht Brookfield DV-III Ultra, M

Xc nh bn nhit ca h sau 31 ngy 91oC

The End