BI TP S 1 Bi 1. Hai nguyn t ha hc X v Y iu kin thng u l cht rn.

. S mol ca X c trong 8,4 gam X nhiu hn so vi s mol ca Y c trong 6,4 gam Y l 0,15 mol. Bit khi lng mol nguyn t ca X nh hn khi lng mol nguyn t ca Y l 8 gam. Xc nh k hiu ha hc ca X v Y? Bi 2. Ha tan 15,8 gam hn hp A gm Na2CO3; K2CO3 v Na2O bng dung dch HCl thot ra 1,68 lt CO2 (ktc) v thu c dung dch B. C cn dung dch B c 22,025 gam hn hp cha hai mui khan. Tnh thnh phn % hn hp A. Bi 3. Nung FeS2 trong khng kh, kt thc phn ng thu c mt hn hp kh c thnh phn: 7% SO2; 10% O2; 83% N2 theo s mol. un hn hp kh trong bnh kn (c xc tc) 800K, xy ra phn ng:
2SO2 + O2 2SO3

Kp = 1,21.105.

a) Tnh chuyn ho (% s mol) SO2 thnh SO3 800K, bit p sut trong bnh lc ny l 1 atm, s mol hn hp kh ban u (khi cha un nng) l 100 mol. b) Nu tng p sut ln 2 ln, tnh chuyn ho SO2 thnh SO3, nhn xt v s chuyn dch cn bng. Bi 4. t chy hon ton 3 gam mt mu than c cha tp cht S. Kh thu c cho hp th hon ton bi 0,5 lt dung dch NaOH 1,5M c dung dch A, cha 2 mui v c xt d. Cho kh Cl2 (d) sc vo dung dch A, sau khi phn ng xong thu c dung dch B, cho dung dch B tc dng vi dung dch BaCl2 d thu c a gam kt ta, nu ho tan lng kt ta ny vo dung dch HCl d cn li 3,495 gam cht rn. a) Tnh % khi lng C; S trong mu than, tnh a. b) Tnh nng mol/lt cc cht trong dung dch A, th tch kh Cl2 (ktc) tham gia phn ng. Bi 5. Cho 23,52g hn hp 3 kim loi Mg, Fe, Cu vo 200ml dung dch HNO3 3,4M khuy u thy thot ra mt kh duy nht hi nng hn khng kh, trong dung dch cn d mt kim loi cha tan ht, tip t t dung dch H2SO4 5M vo, cht kh trn li thot ra cho n khi kim loi va tan ht th mt ng 44ml, thu c dd A. Ly 1/2 dd A, cho dd NaOH cho n d vo, lc kt ta, ra

ri nung ngoi khng kh n khi lng khng i thu c cht rn B nng 15,6g. a) Tnh % s mol mi kim loi trong hn hp. b) Tnh nng cc ion (tr ion H+-, OH-) trong dung dch A. Bi 6. a) Tnh pH ca dung dch HCl nng 0,5.10-7 mol/lt. b) Tnh pH ca dung dch X c to thnh khi trn 200ml dung dch HA 0,1M (Ka = 10-3.75) vi 200ml dung dch KOH 0.05M; pH ca dung dch X thay i nh th no khi thm 10-3 mol HCl vo dung dch X.