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T LUYN THI I HC S 01 MN: HA HC

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Cu 1: Ho tan hon ton 6,4 gam hn hp gm Mg v MgO trong dung dch HCl thu c 2,24 lit kh H2. C cn dung dch sau phn ng thu c m gam mui khan. Gi tr ca m l A. 9,5. B. 14,5. C. 11,9. D. 19,0. Cu 2: iu kin thng, photpho hot ng ho hc mnh hn nit l do A. nguyn t photpho c m in nh hn nguyn t nit B. phn t photpho (P4) c khi lng ln hn phn t nit (N2) C. nguyn t photpho c bn knh ln hn nguyn t nit D. lin kt trong phn t photpho km bn hn trong phn t nit Cu 3: t chy hon ton mui sunfua ca kim loi M c cht rn X, ha tan X trong dung dch HCl c dung dch Y khng mu. Sc NH3 d vo dung dch Y thy xut hin kt ta, thm tip dung dch NaOH vo thy kt ta tan. Kim loi M l A. Zn B. Cr C. Al D. Mg Cu 4: Cho 3,08 gam hn hp gm etylenglicol, phenol, glixerol v axit axetic tc dng vi 1,15 gam Na sinh ra 448 ml H2 (ktc). Khi lng mui thu c sau phn ng l A. 3,96 gam B. 4,19 gam C. 3,124 gam D. 3,52 gam Cu 5: t chy hon ton a mol mt anehit X mch h thu c b mol CO2 v c mol nc, bit a = b c. Nu cho a mol X tc dng va vi brom trong dung dch th s mol Br2 phn ng l A. a mol. B. 0,5a mol. C. 2a mol. D. 1,5a mol. Cu 6: Cho 0,5 mol hn hp hai anehit cng dy ng ng vo bnh ng AgNO3 d trong NH3 thy to ra 172,8 gam Ag, khi lng bnh tng 23,4 gam. Hai anehit l: A. HCHO v C2H5CHO B. HCHO v C3H7CHO C. CH3CHO v C3H7CHO D. (CHO)2 v HCHO Cu 7: C bao nhiu cht c cng cng thc phn t C3H7O2N (khng k peptit) tc dng c vi c dung dch HCl v NaOH ? A. 2 B. 3 C. 4 D. 6 Cu 8: Mt hn hp gm SO2 v CO2 c t khi hi so vi oxi bng 1,6875. Sc 0,672 lit hn hp kh trn vo dung dch nc vi trong d th khi lng mui to thnh l A. 3,3 gam B. 6,6 gam C. 3,4 gam D. 3,48 gam Cu 9: Hp cht X c cng thc C5H8O2 mch thng. X va c phn ng vi Na, va c phn ng trng gng. Oxi ha nh X bng CuO cho hp cht tp chc, cn hiro ha X li cho cht a chc. un X vi H2SO4 c/170oC ch cho 1 anken duy nht, c ng phn hnh hc. Cng thc cu to ca X l: A. CH2OHCH2CH2CH2CHO B. CH3CHOHCH2CH2CHO C. CH3CH2CHOHCH2CHO D. CH3CH2CH2CHOHCHO Cu 10: Thy phn hon ton 1 mol mt heptapeptit X cho 2 mol Gly, 2 mol Phe, 1 mol Lys, 1 mol Ala, v 1 mol Val. Nu thy phn khng hon ton X cho cc tripeptit sau: Gly-Ala-Lys, Phe-Gly-Val, LysPhe-Gly, Ala-Lys-Phe, Gly-Val-Phe. Th t lin kt cc amino axit trong X l: A. Gly-Val-Phe-Gly-Ala-Lys-Phe B. Gly-Ala-Lys-Phe-Gly-Val-Phe C. Phe-Gly-Val-Phe-Gly-Ala-Lys D. Ala-Lys-Phe-Gly-Val-Phe-Gly Cu 11: Mnh no sau y l khng ng ? A. Cho dung dch brom vo dung dch phenol, xut hin kt ta trng B. Nh dung dch phenol vo mu giy qu tm, qu tm chuyn thnh mu C. Cho phenol vo dung dch NaOH, phenol tan ra cho dung dch trong sut khng mu D. Sc kh hiroclorua vo dung dch natri phenolat, xut hin vn c trng Cu 12: Ha tan ht 2,04 gam hp kim Al Mg (trong Al chim 52,94% v khi lng) trong dung dch HNO3 c 448 ml (ktc) kh X v dung dch Y. C cn cn thn dung dch Y c 14,84 gam mui khan. Kh X l A. N2. B. N2O. C. NO2. D. NO.
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Cu 13: A c cng thc phn t C3H5Cl3, tc dng vi dd NaOH un nng c sn phm B va c phn ng vi Na va c phn ng trng gng. Oxi ha B bng CuO, un nng c mt cht tp chc. Cng thc cu to ca A l: A. CH2Br-CHBr-CH2Br B. CH3-CBr2-CH2Br C. CH3-CHBr-CHBr2 D. CH2Br-CH2-CHBr2 Cu 14: C ba l ng 3 hn hp: Fe + FeO, FeO + Fe2O3, Fe + Fe2O3. Ch s dng mt ho cht no di y c th nhn bit 3 hn hp trn ? A. dung dch CuSO4 B. dung dch HNO3 C. dung dch HCl D. dung dch AgNO3 Cu 15: Cho cc cht sau: CH4, SO2, AlCl3, NaF, CaO, CF4, NH3, Cl2 (Bit m in ca C l 2,55; H l 2,20; S l 2,58; O l 3,44; Al l 1,61; Cl l 3,16, Ca l 1,00; F l 3,98; N l 3,04). Dy gm cc cht cha lin kt cng ha tr phn cc l: A. CH4, SO2, CF4, NH3, Cl2. B. CH4, SO2, CF4, NH3, AlCl3. C. AlCl3, CaF2, CaO. D. SO2, CF4, NH3, AlCl3. Cu 16: Cho ba l Zn ging nhau vo ba dung dch (ly d) c nh s th t 1, 2, 3 c nng mol v th tch nh nhau. Sau khi phn ng kt thc, ly ba l Zn ra cn thy: l Zn th nht khng thay i khi lng, l Zn th hai c khi lng gim i, l Zn th ba c khi lng tng ln. Ba dung dch 1, 2, 3 ln lt l: A. FeSO4, NaCl, Cr(NO3)3 B. MgCl2, FeCl2, AgNO3 C. Pb(NO3)2, NiSO4, MgCl2 D. AlCl3, CuCl2, FeCl2 Cu 17: X phng ha hon ton 95 kg gam lipit cn 13,7 kg NaOH, sau phn ng ngi ta thm mui n vo v lm lnh thy tch ra m kg mui. Dung dch cn li c loi tp cht, c c ri li tm tch mui n thu c 10,12 kg glixerol. em ton b mui thu c p cng cc ph gia th c bao nhiu gam x phng (gi s trong x phng cc cht ph gia chim 20% v khi lng). A. 98,355 kg B. 122,944 kg C. 98,58 kg D. 123,225 kg Cu 18: Oxi ha 1 mol mt ancol no, mch h X bng CuO, un nng c Y; cho ton b Y phn ng vi dung dch AgNO3 trong NH3 c 4 mol Ag. Cho 1 mol X tc dng ht vi Na c 1 mol H2. t chy 1 mol X cho lng CO2 nh hn 90 gam. Tm cng thc phn t ca X. A. CH3OH B. C2H5OH C. C2H4(OH)2 D. C3H6(OH)2 Cu 19: C bao nhiu ng phn cu to c cng thc C4H8O2 bit chng u c phn ng trng bc A. 4 B. 5 C. 7 D. 10 Cu 20: C 6 dung dch long ca cc mui NaCl, Ba(NO3)2, AgNO3, CuSO4, FeCl2, ZnCl2. Khi sc kh H2S vo cc dung dch mui trn, c bao nhiu trng hp c phn ng to ra kt ta? A. 1 B. 2 C. 3 D. 4 Cu 21: Ha tan ht mt lng Fe trong dung dch cha 1 mol hn hp HCl v HBr (va ), thu c dung dch A. Dung dch A phn ng va ht vi 0,45 mol Cl2 (1 trong cc sn phm l Br2). S mol HCl v HBr ln lt l: A. 0,1 v 0,9 mol B. 0,6 v 0,4 mol C. 0,4 v 0,6 mol D. 0,5 v 0,5 mol Cu 22: Sp xp cc cht sau theo th t tng dn tnh kh: S, SO2, H2S, Br2, Cl2 A. Br2 < Cl2 < H2S < S < SO2 B. H2S < S < SO2 < Br2 < Cl2 C. Cl2 < Br2 < SO2< S < H2S D. SO2< S < H2S < Cl2 < Br2 Cu 23: Cho cc cht sau: anilin, phenol, amoniac, metylamin, natri hiroxit, amoni clorua, 2,3imetylpropanoic, glyxin, natri axetat. S cht m dung dch ca chng lm i mu qu tm thnh xanh l: A. 2 B. 4 C. 5 D. 6 Cu 24: Trong cc phn ng ho hc di y, phn ng no chuyn dch theo chiu t tri sang phi (chiu thun) khi tng p sut ca h? A. 2 SO2(k) + O2(k ) 2SO3(k) B. C (r) + H2O(k) CO(k) + H2(k) C. H2(k) + I2(k) 2HI(k) D. CaCO3(r) CaO(r) + CO2(k) Cu 25: Cho cc cht sau: metanol, anilin, etyl benzoat, phenol, axit butiric, natri phenolat, phenylamoni clorua, etylen glicol, anllyl bromua, o-metylphenol. C bao nhiu cht tc dng c vi dung dch NaOH ( nhit thng hoc un nng) ?

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A. 6. B. 4. C. 7. D. 3. Cu 26: C 5 cc dung dch ring bit, trong khng kh cha: H2SO4, AgNO3, FeCl3, ZnCl2, HCl c ln AlCl3, H2SO4 c ln CuSO4. Nhng vo mi dung dch mt thanh kim loi thic nguyn cht. S cc xy ra s n mn in ho l A. 1. B. 2. C. 3. D. 4. Cu 27: Anion X- v cation Y2+ u c cu hnh electron lp ngoi cng l 3s23p6. V tr ca cc nguyn t X v Y trong bng tun hon l: A. X c s th t 19, chu k 4, nhm VIIA; Y c s th t 16, chu k 3 nhm VIA B. X c s th t 18, chu k 3, nhm VIA; Y c s th t 21, chu k 4 nhm IIIA C. X c s th t 17, chu k 3, nhm VIIA; Y c s th t 20, chu k 4 nhm IIA D. X c s th t 17, chu k 3, nhm VIIA; Y c s th t 20, chu k 3 nhm IIA Cu 28: t chy hon ton 0,1 mol hn hp gm mt axit cacboxylic 2 chc X v mt este Y l ng phn ca X cn 7,84 lit oxi thu c 17,6g CO2 v m gam H2O. Gi tr ca m l A. 5,4. B. 2,7. C. 1,8. D. 3,6. Cu 29: t chy hon ton m gam mt ancol thu c 0,03 mol CO2 v 0,04 mol H2O. em ancol thc hin phn ng tch nc hon ton 170oC c xc tc H2SO4 c thu c 1 anken lm mt mu va ht V ml dung dch Br2 0,2M. Gi tr ca V l: A. 100ml B. 50ml C. 80ml D. 150ml Cu 30: Cht no di y c ng phn hnh hc ? A. 2-metylpent-2-en B. anehit butiric C. vinyl metacrylat D. 1,3-iclobuta-1,3-ien Cu 31: Cho t t n ht 300 ml dung dch HCl 1M vo 100 ml dung dch Na2CO3 2M, thu c V lt kh (ktc) v dung dch A. Thm Ba(OH)2 d vo dung dch A, c m gam kt ta. Gi tr ca V v m ln lt l: A. 3,36 v 9,85. B. 4,48 v 0,0. C. 3,36 v 19,7. D. 2,24 v 19,7. Cu 32: SO2 v SO3 cng phn ng c vi dung dch A. BaCl2 B. brom. C. Na2CO3 D. NaCl Cu 33: Dy gm cc cht v ion u c tnh lng tnh l: A. ZnO, Al2O3, Fe2O3, Pb(OH)2 B. Mg(OH)2, Cr(OH)3, Zn(OH)2, Sn(OH)2 C. HCO3 , HSO4 , HS , Al(OH)3 D. HCO3-, H2O, Cu(OH)2, Cr2O3 Cu 34: Cho 16,7 gam hn hp kim loi X gm Mg, Zn, Al b oxi ha mt phn bng oxi c 19,9 gam hn hp Y (gm 3 oxit v 3 kim loi). Ha tan Y trong H2SO4 long c 6,72 lit H2 v dung dch Z. T l s mol axit H2SO4 tham gia phn ng oxi ha kh v trao i l: A. 1 : 1 B. 1 : 2 C. 3 : 2 D. 2 : 1 Cu 35: t chy hon ton hn hp hai este no, n chc cn 3,976 lt oxi ktc, thu c 6,38 gam kh CO2. Cho lng este ny tc dng va vi NaOH, thu c hn hp hai ancol k tip v 3,28 gam mui ca mt axit hu c. Cng thc cu to thu gn ca hai este l A. CH3COOCH3 v CH3COOC2H5 B. HCOOC2H5 v HCOOC3H7 C. CH3COOC2H5 v CH3COOC3H7 D. C2H5COOCH3 v C2H5COOC3H7 Cu 36: Thu phn x gam tinh bt trong mi trng axit, sau mt thi gian ly hn hp phn ng em lm ngui ri nh vo hai git dung dch iot khng thy xut hin mu xanh. em trung ho axit ri cho dung dch thu c phn ng vi dung dch AgNO3/NH3 d thu sinh ra 64,8 gam Ag. Gi tr ca x l : A. 84,6. B. 64,8. C. 48,6. D. 97,2. Cu 37: Dy cht no c sp xp theo chiu tng dn tnh axit: A. HCl, H2S, NH3 B. HI, HBr, HCl, HF. C. H3PO4, H2SiO3, H2SO4 D. HClO2, HClO3, HClO4 Cu 38: Cp t no sau y u thuc loi polipeptit ? A. t enang v t capron. B. t visco v t axetat. C. t nilon-6 v t clorin. D. t nilon-6,6 v t lapsan. Cu 39: Kt lun no khng ng v metylamin A. hai l ng dung dch HCl v metylamin c cnh nhau thy c khi trng. B. Sc metylamin vo dung dch Fe(NO3)3 xut hin kt ta nu, sau kt ta tan. C. Metylamin c tnh baz mnh hn amoniac nhng yu hn etylamin.

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D. Cho dung dch metylamoni clorua phn ng vi NaOH thy c kh mi khai thot ra. Cu 40: Cho phng trnh phn ng: Zn + HNO3 Zn(NO3)2 + N2 + NO + H2O. Hn hp N2 v NO sinh ra c t khi hi so vi khng kh bng 1 th h s ca Zn v HNO 3 trong phn ng trn ln lt l: A. 13 v 30 B. 13 v 32 C. 13 v 26 D. 7 v 18 Cu 41: Pht biu no khng ng v xeton A. Cc xeton u c ng phn nhm chc l anehit v ancol khng no. B. Xeton th hin tnh kh khi phn ng vi H2/Ni, un nng. C. t chy mt xeton bt k lun cho mH2O/mCO2 9/22. D. Xeton no khng lm mt mu dung dch brom v dung dch thuc tm. Cu 42: Sp xp cc cp oxi ho kh sau theo th t tng dn tnh oxi ho, gim dn tnh kh: Mn 2+/Mn, Cu2+/Cu, Ag+/Ag, 2H+/H2: A. Mn2+/Mn < Cu2+/Cu < Ag+/Ag < 2H+/H2 B. Mn2+/Mn <2H+/H2 < Cu2+/Cu < Ag+/Ag C. Mn2+/Mn < Cu2+/Cu <2H+/H2 < Ag+/Ag D. Mn2+/Mn <2H+/H2 < Ag+/Ag< Cu2+/Cu Cu 43: Trn hn hp hai anehit no n chc k tip vi lng kh oxi bng 1,5 ln lng cn cho phn ng vo bnh kn 135oC v 1,1 atm. t chy hon ton hn hp, sau a v nhit ban u thy p sut bnh l 1,25 atm. Cng thc ca hai anehit l: A. HCHO v CH3CHO B. C2H5CHO v C3H7CHO C. CH3CHO v C2H5CHO D. C4H9CHO v C3H7CHO Cu 44: lm sch mt mu Ag c ln Zn, Sn, Pb, Cu m khng lm thay i khi lng Ag, ngi ta cho mu Ag ny phn ng vi dung dch A. CuSO4 B. HgSO4 C. Fe(NO3)3 D. AgNO3 Cu 45: phn bit bn dung dch glucoz, anehit fomic, etanol, etylen glicol, c th dng cht no sau y: A. Br2/H2O B. AgNO3/NH3 C. Cu(OH)2/NaOH D. CuO Cu 46: Kh CO2 sinh ra khi ln men ancol mt lng glucoz c dn vo dung dch Ca(OH)2 d thu c 40 gam kt ta. Th tch ancol etylic thu c l (khi lng ring ca ancol etylic = 0,8g/ml): A. 23 ml B. 14,71 ml C. 46 ml D. 18,4 ml Cu 47: Amphetamin c cng thc: C6H5-CH2-CH(CH3)-NH2. Tn thay th ca Amphetamin l: A. phenyl propylamin B. 1-phenylpropan-2-amin C. 1-metyl-2-phenyletylamin D. benzyl etylamin Cu 48: Cho cc hn hp cht rn vi s mol bng nhau: Al v Na (1); NaOH v Ba(HCO3)2 (2); Na2O v Al2O3 (3); Na2CO3 v Ba(OH)2 (4); KHSO4 v NaOH (5). S lng cc hn hp khi ho tan trong nc d ch to dung dch l A. 3. B. 4. C. 2. D. 1. Cu 49: Tch nc t 1,368 gam hn hp hai ancol no n chc, mch h thu c hn hp hai anken l ng ng k tip. t chy hon ton 2 anken trn trong 2,5088 lt oxi, lm lnh sn phm sau phn ng thu c 1,7024 lit kh (th tch cc kh o ktc). Cng thc ca hai anken l: A. C2H4 v C3H6 B. C3H6 v C4H8 C. C4H8 v C5H10 D. C5H10 v C6H12 Cu 50: C mt mu hp kim Cu-Ag, cho bit hp kim ny c th tan trong nhng dung dch no sau y: A. Fe(NO3)3 B. H2SO4 long C. AgNO3 D. Au(NO3)3

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