CHUYN : GIAI TOAN AMIN AMINO AXIT PROTIT GIAI TOAN AMIN AMINO AXIT - PROTIT Dang 1: Giai

iai toan AMIN 1.1. Phan ng t chay cua Amin: CxHyNt + x +

y y t O2 xCO2 + H2O + N2 4 2 2 1 H2O 2

nO2 phan ng = nCO2 +

Lu y: Khi t chay 1 amin ngoai khng khi thi: nN2 sau phan ng = nN2 sinh ra t phan ng t chay amin + nN2 co sn trong khng khi 1.2. Phan ng vi dung dich axit Vi amin A, co a nhom chc, gia s amin bc I R(NH2)n + a HCl R(NH3Cl)a S chc amin: a =

nHCl va mmui = mamin + mHCl nA

1.3. Vi dung dich mui cua kim loai: Mt s mui d tao kt tua hidroxit vi dd amin Vi du: AlCl3 + 3CH3NH2 + 3H2O Al(OH)3 + 3CH3NH3Cl Lu y: Tng t nh NH3 cac amin cung tao phc cht tan vi Cu(OH)2, Zn(OH)2, AgCl Vi du: Khi suc khi CH3NH2 ti d vao dd CuCl2 thi ban u xut hin kt tua Cu(OH)2 mau xanh nhat, sau o kt tua Cu(OH)2 tan trong CH3NH2 d tao thanh dd phc [Cu(CH3NH2)4](OH)2 mau xanh thm. 2CH3NH2 + CuCl2 + H2O Cu(OH)2 + 2CH3NH3Cl Cu(OH)3 + 4CH3NH2 [Cu(CH3NH2)4](OH)2 Ap dung: 1. Cho 9,3g mt amin no n chc, bc I tac dung vi dd FeCl3 d thu c 10,7g kt tua. CTPT cua amin la: A. CH3NH2. A. CH3NH2 B. C2H5NH2 B. C2H5NH2. C. C3H7NH2 C. C3H7NH2 D. C4H9NH2 D. C4H9NH2 2. Cho 0,4mol mt amin no n chc tac dung vi dd HCl (va u) thu c 32,6g mui. CTPT cua amin la: 3. t chay hoan toan 1 amin no n chc, bc I, mach h thu c ti l mol CO2 va H2O la 4:7. Tn goi cua amin la: A. Etyl amin. A. 0,05 B. imetylamin B. 0,1. C. etyl metyl amin C. 0,07 D. propyl amin D. 0,2 4. t chay hoan toan a mol amin no n chc thu c 13,2g CO2 va 8,1g H2O. Gia tri cua a la : 5. t chay hoan toan m(g) hn hp gm 3 amin thu c 3,36 lit CO2 (ktc) ; 5,4 (g) H2O va 1,12 lit khi N2 (ktc). Gia tri cua m la : A. 3,6 B. 3,8. C. 4 D. 3,1

DANG 2: GIAI TOAN AMINO AXIT

- Cng thc chung: (H2N)a R (COOH)b

- Da vao phan ng trung hoa vi dd kim xac inh b. Phng trinh phan ng; (H2N)a R (COOH)b + b NaOH (H2N)a R (COONa)b + b H2O

CHUYN : GIAI TOAN AMIN AMINO AXIT PROTIT

nNaOH = a - s nhom chc COOH nX

Chu y: - Vic tim gc R da trn tng s nhom chc xac inh hoa tri cua gc R va suy ra cng thc tng quat cua gc nu gia thit cho bit gc R co c im gi? Vi du: H2N R (COOH)2 vi R gc no R la gc no hoa tri III R co dang CnH2n-1 - Nu gc R khng ro la no hay cha no thi nn dung cng thc tng quat la CxHy ri da vao kt lun cua gc R bin lun (cho x chay tim y tng ng) Ap dung: 6. Cho 0,01 mol amino axit A tac dung va u vi 80ml dd HCl 0,125M. C can dd thu c 1,835g mui. Khi lng phn t cua A la: A. 97 B. 120 C. 147. D. 157 7. Cho 0,2 mol - amino axit X phan ng va u vi 100 ml dd HCl 2M thu c dd A. Cho dd A phan ng va u vi dd NaOH, sau phan ng c can san phm thu c 22,2g mui. X co tn la: A. Glixin BAI TP: 1. Trich mt s thi KTTN-THPT: 1.1. t chay hoan toan m gam mt amin mach h n chc, sau phan ng thu c 5,376 lit CO 2; 1,344 lit N2 va 7,56g H2O (cac th tich o ktc). CTPT cua amin la: A. C3H7N B. C2H5N C. CH5N D. C2H7N. 1.2. Khi trung ngng 7,5g axit amino axetic vi hiu sut 80%, ngoai amino axit d ngi ta con thu c m gam polime va 1,44g nc. Gia tri m la: A. 4,25g B. 5,56g C. 4,56g. D. 5,25g 1.3. Cho m gam anilin tac dung vi dd HCl (c d). C can dd sau phan ng thu c 15,54g mui khan. Hiu sut phan ng la 80% thi gia tri cua m la: A. 11,16g B. 13,95g. C. 16,2g D. 21,6g 1.4. Trung hoa 1 mol amino axit X cn 1mol HCl tao ra mui Y co ham lng Clo la 28,286% v khi lng. CTCT cua X la: A. H2N-CH2-CH2-COOH B. CH3-CH(NH2)-COOH. C. H2N-CH2- CH(NH2)-COOH D. H2N-CH2-COOH 1.5. Cho 5,58g anilin tac dung vi dd Brom, sau phan ng thu c 13,2g kt tua 2,4,6 tribrom anilin. Khi lng Brom a phan ng la: A. 7,26g B. 9,6g C. 19,2g. D. 28,8g 1.6. Cho 500g benzen phan ng vi HNO3 (c) co mt H2SO4 (c), san phm thu c em kh thanh anilin. Nu hiu sut chung cua qua trinh la 78% thi khi lng anilin thu c la: A. 564g B. 465g. C. 456g D. 546g 2. Trich mt s thi tuyn sinh ai hoc, Cao ng 2007, 2008, 2009: 2.1. Thuy phn 1250g protein X thu c 425g alanin. Nu phn t khi cua X bng 100.000 vC thi s mc xich alanin co trong phn t X la: A. 453 B. 382. C. 328 D. 479 2.2. (CA-2009). Cho 1,82 gam hp cht hu c n chc, mach h X co CTPT C3H9O2N tac dung va u vi dd NaOH, un nong thu c khi Y va dd Z. C can Z thu c 1,64g mui khan. CTCT thu gon cua X la: A. HCOONH3CH2CH3 C. CH3CH2COONH4 B. CH3COONH3CH3. D. HCOONH2(CH3)2 B. Alanin. C. Valin D. Axit glutamic

CHUYN : GIAI TOAN AMIN AMINO AXIT PROTIT 2.3. (CA-2009). Cho tng cht H2NCH2COOH; CH3COOH; CH3COOCH3 ln lt tac dung vi dd NaOH (to) va vi dd HCl (to). S phan ng xay ra la: A. 3 A. 4. B. 6 B. 2 X + NaOH Y + CH4O Y + HCl d Z + NaCl CTCT cua X va Z ln lt la: A. H2NCH2CH2COOCH3 va CH3CH(NH3Cl)COOH B. CH3CH(NH2)COOH va CH3CH(NH3Cl)COOH. C. CH3CH(NH2)COOCH3 va CH3CH(NH3Cl)COOH D. H2NCH2CH2COOC2H5 va ClH3NCH2COOH 2.6. (HB-2009). S ipeptit ti a co th tao ra t mt hn hp gm alanin va glyxin la: A. 2 B. 3 C. 4.
o

C. 4 C. 5

D. 5. D. 3

2.4. (CA-2009). S ng phn cu tao cua amin bc mt co cung CTPT C4H11N la: 2.5. (CA-2009). Cht X co CTPT C4H9O2N. Bit:

D. 1

2.7. (HB-2009). Ngi ta iu ch anilin bng s sau:

c Benzene + HNO3 c , H Nitrobenzen Fe + HCl Anilin 2 SO4 ,t

Bit hiu sut giai oan tao thanh nitrobenzene at 60% va hiu sut giai oan tao thanh aniline at 50%. Khi lng aniline thu c khi iu ch t 156g benzene la: A. 186,0g B. 111,6g C. 55,8g. D. 93,0g 2.8. (HB-2009). Cho 0,02 mol amino axit X tac dung va u vi 200ml dd HCl 0,1M thu c 3,67g mui khan. Mt khac 0,02mol X tac dung va u vi 40g dd NaOH 4%. Cng thc cua X la: A. (H2N)2C3H5COOH C. H2NC3H6COOH 2.9. (HA-2009). Phat biu nao sau y la ung: A. Anilin tac dung vi axit nitr khi un nong thu c mui iazoni B. Benzen lam mt mau nc brom nhit thng C. Etylamin phan ng vi axit nitr nhit thng, sinh ra bot khi. D. Cac ancol a chc u phan ng vi Cu(OH)2 tao dd mau xanh lam 2.10. (HA-2009). Cho 1 mol amino axit X phan ng vi dd HCl (d), thu c m 1 gam mui Y. Cung 1 mol amino axit X phan ng vi dd NaOH (d), thu c m2 gam mui Z. Bit m2 m1=7,5. CTPT cua X la: A. C4H10O2N B. C5H9O4N. C. C4H8O4N2 D. C5H11O2N 2.11. (HA-2009). Hp cht X mach h co CTPT la C4H9NO2. Cho 10,3g X phan ng va u vi dd NaOH sinh ra mt cht khi Y va dd Z. Khi Y nng hn khng khi, lam giy quy tim m chuyn mau xanh. Dung dich Z co kha nng lam mt mau nc brom. C can dd Z thu c m gam mui khan. Gia tri cua m la: A. 8,2 B. 10,8 C. 9,4. D. 9,6 2.12. (HA-2009). Cho 10g amin n chc X phan ng hoan toan vi HCl (d), thu c 15g mui. S ng phn cu tao cua X la: A. 8 B. 7 C. 5 D. 4 2.13. (HA-2009). Phat biu nao sau y ung: A. Anilin tac dung vi axit nitr khi un nong thu c mui iazoni B. Benzen lam mt mau nc brom nhit thng. C. Etylamin phan ng vi axit nitr nhit thng, sinh ra bot khi. D. Cac ancol a chc u phan ng vi Cu(OH)2 tao dd mau xanh lam B. H2NC2C2H3(COOH)2 D. H2NC3H5(COOH)2.

CHUYN : GIAI TOAN AMIN AMINO AXIT PROTIT 2.14. (HA-2009). Cho 1 mol amino axit X phan ng vi dd HCl (d), thu c m 1 gam mui Y. Cung 1 mol amino axit X phan ng vi dd NaOH (d), thu c m2 gam mui Z. Bit m2m1=7,5g. CTPT cua X la: A. C4H10O2N2 B. C5H9O4N. C. C4H8O4N2 D. C5H11O2N 2.15. (HB-2008). Cho 8,9g mt hp cht hu c X co CTPT C3H7O2N phan ng vi 100ml dd NaOH 1,5M. Sau khi phan ng xay ra hoan toan, c can dd thu c 11,7g cht rn. CTCT thu gon cua X la: A. HCOOH3NCH=CH2 C. CH2=CHCOONH4 B. H2NCH2CH2COOH D. H2NCH2CH2COOCH3.

2.16. (HB-2008). Cho cht hu c X co CTPT C2H8O3N2 tac dung vi dd NaOH, thu c cht hu c n chc Y va cac cht v c. Khi lng phn t (theo vC) cua Y la: A. 85 B. 68 C. 45. D. 46 2.17. (HB-2008). Mui phenyliazoni Clorua c sinh ra khi cho C6H5-NH2 (anilin) tac dung vi NaNO2 trong dd HCl nhit thp (0 5oC). iu ch c 14,05g (vi hiu sut 100%), lng C6H5-NH2 va NaNO2 cn dung va u la: A. 0,1mol va 0,4mol B. 0,1mol va 0,2mol C. 0,1mol va 0,1mol. D. 0,1mol va 0,3mol 2.18. (CA,B-2008). Trong phn t amino axit X co nhom amino va mt nhom cacboxyl. Cho 15,0g X tac dung va u vi dd NaOH, c can dd sau phan ng thu c 19,4g mui khan. Cng thc cua X la: A. H2NC4H8COOH B. H2NC3H6COOH C. H2NC2H4COOH D. H2NCH2COOH. 2.19. (CA-2007). -amino axit X cha mt nhom NH2. Cho 10,3g X tac dung vi axit HCl (d), thu c 13,95g mui khan. CTCT thu gon cua X la: A. H2NC2H4COOH C. CH3CH(NH2)COOH B. H2NCH2COOH D. CH3CH2CH(NH2)COOH.

2.20. (CA-2007). Cho hn hp X gm hai cht hu c co cung CTPT C2H7NO2 tac dung va u vi dd NaOH va un nong, thu c dd Y va 4,48 lit hn hp Z ( ktc) gm 2 khi (u lam xanh giy quy m). Ti khi cua Z i vi H2 bng 13,75. C can dd Y thu c khi lng mui khan la: A. 8,9g B. 15,7g C. 16,5g D. 14,3g. 2.21. (CA-2007). Khi t chay hoan toan 1 amin n chc X, thu c 8,4 lit khi CO 2, 1,4 lit khi N2 (cac th tich khi o ktc) va 10,125g H2O. CTPT cua X la: A. C3H7N B. C2H7N C. C3H9N. D. C4H9N 2.22. (CA-2007). t chay hoan toan 1 lng cht hu c X thu c 3,36 lit khi CO 2; 0,56 lit khi N2 (cac khi o ktc) va 3,15g H2O. Khi X tac dung vi dd NaOH thu c san phm co mui H 2N-CH2-COONa. CTCT thu gon cua X la: A. H2N CH2 COO C3H7 C. H2N CH2 COO C2H5 B. H2N CH2 COO CH3. D. H2N CH2 CH3 COOH

2.23. (CB-2007). trung hoa 25g mt amin n chc X nng 12,4% cn dung 100ml dd HCl 1M. CTPT cua X la: A. CH5N. B. C3H5N C. C2H7N D. C3H7N 2.24. (CB-2007). Hp cht X co CTPT trung vi CT n gian nht, va tac dung c vi axit va tac dung c vi kim trong iu kin thich hp. Trong phn t X, thanh phn phn trm khi lng cua cac nguyn t C, H, N ln lt bng 40,449%; 7,865%; 15,73%; con lai la O2. Khi cho 4,45g X phan ng hoan toan vi 1 lng va u dd NaOH (un nong) thu c 4,85g mui khan. CTCT thu gon cua X la: A. H2N COO CH2 CH3 B. CH2=CHCOONH4 C. H2N C2H4 COOH D. H2N CH2 COOH CH3. 2.25. (CB-2007). Chi dung Cu(OH)2 co th phn bit c tt ca cac dd ring bit sau: A. Glucozo, long trng trng, glixerin (glixerol), ru (ancol) etylic. B. Glucozo, matozo, glixerin (glixerol), anehit axetic

CHUYN : GIAI TOAN AMIN AMINO AXIT PROTIT C. Long trng trng, glucozo, fructozo, glixerin (glixerol) D. Saccarozo, glixerin (glixerol), anehit axetic, ru (ancol) etylic 3. Bai tp thm: 3.1. Cho 2,6g hn hp 2 amin no, n chc la ng ng k tip tac dung vi dd HCl loang d. Sau phan ng c can dd thu c 4,425g mui. CTPT cua 2 amin la: A. CH3NH2 va C2H5NH2 B. C2H5NH2 va C3H7NH2. C. C3H7NH2 va C4H9NH2 D. C4H9NH2 va C5H11NH2 3.2. Hn hp X gm 2 mui AlCl3 va CuCl2. Hoa tan hn hp X vao nc thu c 200ml dd A. Suc khi metyl amin ti d vao dd A thu c 11,7g kt tua. Mt khac, cho t t dd NaOH ti d vao dd A thu c 9,8g kt tua. Nng mol/l cua AlCl3 va CuCl2 trong dd A ln lt la: A. 0,1M va 0,75M A. 2 B. 0,5M va 0,75M B. 3 C. 0,75M va 0,5M. C. 4. D. 0,75M va 0,1M D. 5 3.3. Thc hin phan ng trung ngng hn hp gm glixin va alanin. S ipeptit c tao ra t Glixin va alanin la: 3.4. Cho 20g hn hp 3 amin no n chc la ng ng k tip co ti l mol tng ng la 1:10:5, tac dung va u vi dd HCl thu c 31,68g hn hp mui. CTPT cua amin nho nht la: A. CH3NH2 A. 0,5 T < 1 A. C7H7NH2 B. C2H5NH2. B. 0,4 T 1 B. C8H9NH2. C. C3H7NH2 C. 0,4 T < 1. C. C9H11NH2 D. C4H9NH2 D. 0,5 T 1 D. C10H13NH2 3.5. t chay hoan toan cac amin no n chc vi ti l s mol CO2 va hi H2O (T) nm trong khoang nao sau y: 3.6. t chay hoan toan 1 ng ng X cua anilin thi ti l nCO2 : nH2O = 1,4545. CTPT cua X la: 3.7. t chay amin A vi khng khi (N2 va O2 vi ti l mol 4:1) va u, sau phan ng thu c 17,6g CO2, 12,6g H2O va 69,44 lit N2 (ktc). Khi lng cua amin la: A. 9,2g B. 9g C. 11g D. 9,5g. 3.8. Hp cht Y la 1 -amino axit. Cho 0,02mol Y tac dung va u vi 80ml dd HCl 0,25M. Sau o, c can c 3,67g mui. Mt khac, trung hoa 1,47g Y bng 1 lng va u dd NaOH, c can dd thu c 1,91g mui. Bit Y co cu tao mach khng phn nhanh. CTCT cua Y la : A. H2N-CH2-CH2-COOH B. CH3-CH-COOH C. HOOC-CH2-CH2-CH-COOH. D. HOOC-CH2-CH-COOH

NH2

3.9. Este A c iu ch t amino axit B va ancol metylic. t chay hoan toan 0,1mol A thu c 1,12 lit N2 (ktc); 13,2g CO2 va 6,3g H2O. Bit ti khi cua A so vi H2 la 44,5. CTCT cua A la: A. H2N-CH2-COO-CH3. B. H2N-CH2-CH2-COOCH3 C. CH3-CH-COOCH3 D. CH2-CH=C-COOCH3

NH2

NH2

NH2 NH2 -amino axit co CTTQ dang H2N-R-COOH. Cho 8,9g X tac dung vi 200ml dd HCl 1M, thu c dd 3.10. X la 1
Y. phan ng ht vi cac cht trong dd Y cn dung 300ml dd NaOH 1M. CTCT ung cua X la: A. H2N-CH2-COOH C. CH3-CH-COOH. B. H2N-CH2-CH2-COOH D. CH3-CH2-CH-COOH

3.11. Amino axit X mach khng phn nhanh cha nhom COOH va b nhom NH2. Khi cho 1 mol X tac dung ht vi dd HCl thu c 169,5g mui. Cho 1 mol X tac dung ht vi dd NaOH thu c 177g mui. CTPT cua X la: A. C3H7NH2 B. C4H7NO4. C. C4H6N2O4 D. C5H7NO2 3.12. Cho 0,1mol cht X (CH6O3N2) tac dung vi dd cha 0,2mol NaOH un nong thu c cht khi lam xanh quy tim m va dd Y. C can dd Y thu c m gam cht rn khan. Gia tri cua m la:

NH2

NH2

CHUYN : GIAI TOAN AMIN AMINO AXIT PROTIT A. 5,7 A. C2H5NH2 A. CH5N B. 12,5. B. CH3NH2. B. C3H9N C. 15 C. C4H9NH2 C. C2H7N D. 21,8 D. C3H7NH2 D. C5H11N 3.13. t chay hoan toan 6,2g mt amin no, n chc phai dung ht 10,08 lit khi O2 (ktc). CT cua amin o la: 3.14. Cho 17,7g mt amin no n chc tac dung vi dd FeCl3 d thu c 10,7g kt tua. CT cua Amin o la: 3.15. phn bit 3 cht long: axit axetic, anilin va ru metylic, trong cac thi nghim sau: I/ TN 1 dung nc va TN2 dung quy tim II/ TN 1 dung Cu(OH)2 va TN 2 dung Na III/ Chi cn dung quy tim Thi nghim cn dung la: A. I, II. B. I, III C. II, III D. Chi dung III 3.16. Cho 0,59g hn hp 2 amin no n chc tac dung va u vi 1 lit dd hn hp gm HCl va H 2SO4 co pH = 2. (Bit s nguyn t C trong amin khng qua 4). Hai amin co CTPT la: A. C2H7N va C3H9N B. CH5N va C4H11N C. CH5N va C2H7N D. u la C3H9N. 3.17. Chiu tng lc baz cua cac cht o c sp xp theo th t la: (I) (III) NH2 NH2 (II) CH3-NH (IV) N H B. I < II < III < IV. (II) Cl C. III < II < IV < I NH2 D. IV < III < II < I (III) Cl NH2

A. II < I < III < IV

3.18. Cho cac cht: (I) CH3- C6H4-NH2 Th t tng dn lc baz cua cht o la: A. IV < III < II < I

B. III < IV < II < I.

C. II < III < IV < I

D. III < II < IV < I

3.19. Cho X la mt tripeptit cu thanh t cac amino axit A, B va D (D co cu tao mach thng). Kt qua phn tich cac amino axit A, B va D nay cho kt qua sau: Cht % mC % mH % mO % mN M A 32,00 6,67 42,66 18,67 75 B 40,45 7,87 35,95 15,73 89 D 40,82 6,12 43,53 9,52 147 Khi thuy phn khng hoan toan X, ngi ta thu c hai phn t ipeptit la A-D va D-B. Vy cu tao cua X la: A. Gli Glu Ala. B. Gli Lys Val C. Lys Val Gli D. Glu Ala Gli 3.20. X la mt -amino axit mach thng cha mt nhom amin (-NH2) va mt nhom axit (-COOH). Cho 0,1 mol X tac dung vi dd NaOH d tao mui hu c Y. Cho toan b lng Y nay tac dung vi dd HCl d tao 18,15g mui hu c Z. T X co th trc tip iu ch: A. Nilon 6 B. Nilon 7. C. Nilon 8 D. Nilon 6,6 3.21. Cho 15g hn hp gm 3 amin no, n chc, ng ng k tip nhau tac dung va u vi dd HCl 1M ri c can dd thi thu c 26,68g hn hp mui. Th tich dd HCl a dung la : A. 100ml B. 50ml C. 200ml D. 320ml. 3.22. Thuy phn tng phn t pentapeptit thu c cac ipeptit va tripeptit sau : C B, D C, A D, B E va D C B (A, B, C, D, E la ki hiu cac gc -amino axit khac nhau). Trinh t cac amino axit trong peptit trn la:

CHUYN : GIAI TOAN AMIN AMINO AXIT PROTIT A. A-B-C-D-E B. C-B-E-A-D C. D-C-B-E-A D. A-D-C-B-E. 23. Nguyn nhn gy nn tnh bazo ca amin l: A. Do amin tan nhiu trong nc B. Do phn t amin b phn cc mnh C. Do nguyn t N c m in ln nn cp electron cung ca nguyn t N v H b ht v pha N D. Do nguyn t N cn cp electron t do nn amin c th nhn proton. 24. Th t gim dn tnh bazo ca cc cht trong dy sau l: Amoniac (1), metylamin (2), imetylamin (3), phenylamin (4), iphenylamin (5) A. 1>2>3>4>5 A. Bt git ra v nc C. dd NaOH v nc. B. 3>2>1>4>5. C. 5>3>2>4>1 D. 4>2>3>1>5 25. Anilin l cht rt c, ra sch cc dng c th nghim ng anilin ta cn dng cc cht: B. Dung dch HCl v nc D. dd nc vi trong v nc

26. Mi tanh ca c l do mt s amin gy ra, chng hn trimetylamin. kh mi tanh ca c, trc khi nu ta c th dng cht no sau y: A. Ancol etylic A. Qu tm A. CnH2n+2N B. Gim n. B. Dd Brom B. CnH2n+1N C. Mui n bo ha C. Axit HCl. C. CnH2n+3N D. Nc ozon D. Na D. CnH2nN 27. phn bit anilin v phenol c th dng cht no di y: 28. Cng thc tng qut ca aminno n chc mch h l: 29. Trong cc cht sau: CH3NH2, C6H5NH2, H2N-CH2-COOH, CH3COONa, H2N-CH(NH2)-COOH, C6H5OH. S cht to ra dd lm hng phenolphatlein l: A. 1 B. 2 C. 3. D. 5 30. Cho t t anilin vo X thy vn c, thm tip Y vn c tan, thm tip Z vo li thy vn c. Vy X, Y, Z theo th t l: A. dd HCl, dd NaOH, H2O C. H2O, dd HCl, dd NaOH. B. dd HCl, H2O, dd NaOH D. H2O, dd NaOH, dd HCl

31. Mt aminoaxxit trung tnh X phn ng va vi 100ml dd NaOH 0,2M to ra mui c khi lng l 2,22g. CTPT ca aminoaxit ny l: A. CH3-CH2-CH(NH2)-COOH C. HOOC-CH2-CH(NH2)-COOH B. CH3-CH(NH2)-COOH D. H2N-CH2-CH(NH2)-COOH

32. Benzerin hay amphetamine l cht c tc dng kch thch h thn kinh trung ng, lm tng huyt p v mch, thng dng chng mt mi, gim suy nhc, tr bnh ng kinh. Benzerin c CTCT l:

Tn gc chc ca Benzerin l: A. Phenyl propylamin B. 1-metyl-2-phenylamin. C. 1-phenylpropan-2-amin D. Benzyl etylamin 33. Nhn nh no sau y khng ng ? A. Tn gc -chc v tn thay th ca amin u c tn cng l amin B. Gia cc phn t amin tn ti lin kt hidro nn chng tan tt trong nc. C. Anilin t tan trong nc do gc C6H5 l phn k nc kh ln D. Mt s amin nh metylamin, etylamin, imetylamin l kh c mi kh chu 34. Anilin v phenol u c th tc dng c vi : A. dd HCl B. dd NaOH C. dd Br2. D. dd Na2CO3 35. Dy c sp xp theo chiu tng dn tnh bazo l:

CHUYN : GIAI TOAN AMIN AMINO AXIT PROTIT A. (CH3)2NH > C2H5NH2 > CH3NH2 > C6H5NH2 > NH3 B. (C6H5)2 NH > C6H5NH2 > CH3NH2 > NH3 > (CH3)2NH2 C. (CH3)2NH > C2H5NH2 > CH3NH2 > NH3 > C6H5NH2. D. C2H5NH2 > (CH3)2NH > CH3NH2 > NH3 > C6H5NH2 36. Cho t t dd metylamin vo dd CuSO4, hin tng xy ra theo th t l: A. Xut hin kt ta xanh lm, khng tan B. Xut hin kt ta xanh lm sau tan thnh dd khng mu C. Xut hin kt ta xanh lm sau tan thnh dd mu xanh thm. D. C kt ta mu trng, sau thnh dd khng mu trong sut. 37. C 3 cht lng benzen, anilin, stiren ng trong 3 l mt nhn. phn bit ha cht trong mi l cn dng thuc th no sau y? A. H2O A. 4 A. 9 A. 9. A. 2,47 B. Dd Br2. B. 7 B. 8. B. 11 B. 1,62 C. dd HCl C. 9 C. 6 C. 4 C. 1,21 D. Dd NaOH D. 8. D. 4 D. 6 D. 1,24 38. S ng phn amin no n chc bc 1 c cha 16,09% nito v khi lng l: 39. S ng phn amin n chc c phn t khi l 73 l: 40. C bao nhiu ng phn amin thm bc 1 c CTPT l C8H11N? 41. Cho dd anilin tc dng vi nc brom thu c 4,4g kt ta trng, khi lng ca anilin trong dd ban u l: 42. to ra 6,6g 2,4,6-tribromanilin cn ti thiu 246,15ml dd nc brom (d=1,3g/ml). Nng % ca dd brom dng l: A. 5% B. 7% C. 10% D. 3%. 43. Tn gi thay th ca aminoaxit co CTPT CH3-CH(CH3)-CH(NH2)-COOH l: A. Axit 2-amino-3-metylbutanoic. C. Axit 2-amino-isopentanoic B. Axit 2-amino-2-isopropyletanoic D. Axit 3-amino-2-metylbutanoic

44. Cho 11,25g C2H5NH2 tc dng vi 200ml dd HCl x(M). Sau khi phn ng xong thu c dd c cha 22,2g cht tan. Xc nh x(M)? A. 1,25 B. 1,36 C. 1,3 D. 1,5 45. Tng Bn, mt loi nc chm ni ting ng bng Bc B ca Vit Nam c lm t u tng. V ngt ca tng Bn l ca loi hp cht hu c no sau y? A. Aminoaxit. B. Saccarozo C. Mantozo D. Glucozo 46. Hp cht X cha cc nguyn t C, H, N, O v c khi lng phn t l 89 u (vC). Khi t chy 1 mol X thu c 3 mol CO2 v 0,5 mol N2. Bit X tc dng vi kim gii phng kh NH3 v lm mt mu dd nc Brom. X l: A. H2N-CH=CH-COOH4 C.CH2=CH-COONH4 a. C6H5NH2 B. H2N-CH2-COOH B. CH2=C(NH2)-COOH D. CH2=CH-CH2- COONH4 C.CH3NH2 D.H2N-CH(COOH)-CH2-CH2-COOH

47. Dung dch no sau y lm qu tm i sang mu xanh? 48. Khi cho HNO3 c vo ng nghim cha 2ml dd long trng trng (anbumin) th c hin tng g xy ra? A. Lng trng trng ng t li, c kt ta vng B. Lng trng trng khng tan, c s phn lp, long trng trng nh trn C.C kt ta mu vng D. Dung dch mu vng, c kh NH3 bay ra. 49. Thuc th no di y khng th phn bit c dd CH3NH2 v C6H5NH2?

CHUYN : GIAI TOAN AMIN AMINO AXIT PROTIT A. Qu tm B. Dung dch brom C. Dung dch HCl D.Dung dch NaOH 50. Mt dng hemoglobin (hng cu trong mu) c cha 0,4% st v mi phn t hemoglobin ch cha mt nguyn t st. Phn t khi ca hemoglobin ny l: A. 15.000u B.14.000u C. 14.200u D. 14.500u 51. t chy hon ton mt amin X bng V lt Oxi, thu c 12,6g nc; 8,96 lt CO2 v 2,24 lt N2 (ktc). Gi tr ca V l: A. 24,64 lt B.16,8 lt C. 40,32 lt D. 19,04 lt 52. t chy hon ton 1 amin n chc bng khng kh va , thu c 6,48g H 2O; 7,168 lt CO2 v 45,696 lt N2 (ktc). Bit rng trong khng kh O2 chim 20%, N2 chim 80%. Cng thc amin l: A.C4H9N B. C4H11N C. C3H9N D. C2H7N 53. t chy ht m gam hn hp C4H9N, C3H9N, C2H8N2 thu c 3,06g H2O; 2,464 lt CO2 v 0,672 lt N2 (ktc). Gi tr ca m l: A. 5,2g B.2,5g C. 2,05g D. 5,02g 54. Cho hp cht X c CTCT: HOOC-CH2-CH2-CH-COOH . Tn gi no sau y ca X khng ng?

CH3
A. Axit amino glutaric C.Axit amino glutamic A. Nh hn nc C.L hp cht ion do to mui ni phn t B. Axit Glutamic D. Axit 2-amino penta-1,5-ioic B. To lin kt hiro trong nc D. Do c khi lng phn t nh

55. Cc amino axit d tan trong nc l do nguyn nhn chnh no sau y?

56. Cho cc cht sau: C6H5NH2; HOOC-COOH; CH3(CH)NH2CH(NH2)COOH; CH3CH(NH2)COOH; HOOCCH2CH2CH(NH2)COOH; HOOCCH(NH2)CH2CH(NH2)COOH, C2H5NH2 C bao nhiu cht lm i mu qu tm? A. 3 A. Phn ng vi C2H5OH C. Phn ng vi Cu(OH)2 B.4 C. 5 B. Phn ng vi HNO2 D.Phn ng thy phn D. 6 57. Axit glutamic khng c tnh cht no sau y?

58. amino axit X trong phn t ch cha 1 nhm -NH2 v 1 nhm COOH. Cho 1 lng X tc dng va vi 100ml dd HCl 0,5M. Mt khc cng cho lng X trn phn ng vi 150ml dd NaOH 0,5M, sau khi phn ng xong, c cn dd thu c 6,55g cht rn. CTCT thu gn ca X l: A. CH2(NH2)-COOH B.CH3-CH(NH2)-COOH C. CH2(NH2)-CH2COOH D. CH3CH2CH(NH2)-COOH 59. t chy hon ton 1 cht hu c X thu c 1,344 lt CO2; 0,168 lt N2 (ktc) v 1,485g H2O. Khi cho X tc dng vi NaOH thu c mt sn phm l CH3COONa. CTCT thu gn ca X l: A.CH3COONH3CH2CH3 C. CH2(NH2)-CH2COOH 60. Bc ca amin c tnh bng: A. S nguyn t H trong phn t hirocacbon c thay th bi nhm amin B. Bc ca nguyn t C lien kt trc tip vi nhm amin C.S nguyn t H trong phn t ammoniac b thay th bi gc hirocacbon D. S nguyn t H trong phn t amoiac b thay th bi cc gc t do 61. Khi lng tripeptit c to ra t 178g alanin (CH3-CH(NH2)-COOH) v 75g glyxin (CH2(NH2)-COOH) l: A. 253g B. 235g C.217g D. 271g 62. C 4 bnh khng nhn cha cc cht: methanol, glixerol, dd glucozo, dd aniline. C th dng 2 cht no trong s cc cht di y nhn ra cc cht trn? B. CH3COOCH(NH2)CH3 D. CH3CH2CH(NH2)COOH

CHUYN : GIAI TOAN AMIN AMINO AXIT PROTIT 1. Qu tm A. 2 v 5 A. T tm 2. Natri B. 1 v 4 B.Lipit 3. Cu(OH)2 4. dd Brom C. 4 v 5 C. Mng nhn 5. AgNO3 trong NH3 D.3 v 4 D. Tc

63. Cu to ca cht no sau y khng cha lin kt peptit trong phn t? 64. C 4 dd khng mu: glucozo, glixerol, h tinh bt, long trng trng g. Ha cht no di y c th phn bit c 4 dd trn? A. dd HNO3 c, to B. dd AgNO3/NH3 C. dd I2 D.CuSO4, dd NaOH 65. Mt tetrapeptit c to nn t amino axit n chc c phn t khi 414 vC. Khi lng ca phn t khi amino axit ny l: A. 103 B. 121 C. 119 D.117 66. Mt pentapeptit c to ra t glyxin v alanin c phn t khi 345 vC. S mt xch to ra t glyxin v alanin trong chui peptit trn l: A. 1 v 4 B. 4 v 1 C. 2 v 3 D.3 v 2 67. Amino axit Y phn ng vi NaOH theo t l 1:2 v vi HCl theo t l 1:1, khi lng phn t ca Y l 147. Xc nh CTPT ca Y: A.C5H9O4N B. C6H10O2N C. C8H5O2N D. C4H7O4N 68. t chy hon ton 2,575g cht hu c X, thu c 2,025g H 2O; 2,24 lt CO2 v 0,28 lt N2 (ktc). T khi hi ca X so vi hidro l 51,5. Cng thc ca X l: A.C4H9O2N B. C4H7O2N C. C3H5O3N D. C4H11O2N 69. Cho cc hp cht C2H5NH2 (X); H2N-CH2-COOH (Y); CH3COONH4 (Z); H2N-CH2CH2-COOCH3 (T); CH3COOC2H5 (M). Dy gm cc cht va phn ng vi NaOH va phn ng vi HCl l: A. X, T, Z B.Y, Z, T C. Y, Z, T, M D. X, Z, M 70. Ngi ta iu ch anilin bng cch nitro ha 500g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu bit rng hiu sut mi giai on u c 78% ? A.362,7g A. C2H5NH2 B. 463,5g B. C3H7NH2 C. 358,7g C. C4H9NH2 D. 346,7g D.CH3NH2 71. Cho 9,3g mt anilin tc dng vi dd FeCl3 d thu c 10,7g kt ta. CTPT ca amin l : 72. X l mt cht hu c c CTPT C5H11O2N. un X vi dd NaOH thu c mt cht hu c c CTPT C2H4O2NNa v cht hu c Y. Cho hi Y qua CuO/to thu c cht hu c Z c kh nng cho phn ng trng bc. CTCT thu gn ca X l: A. CH2=CH-COONH3-C2H5 C. H2N-CH2-CH2-COOC2H5 B. CH3(CH2)4NO2 D.NH2-CH2COO-CH2-CH2-CH3

73. Khi t chy ng ng ca metylamin, t l th tch k = VCO2 : VH2O bin i nh th no theo s lng nguyn t C trong phn t: A. 0,25 < k < 1 A.(1) < (2) < (3) < (4) B. 0,75 < k < 1 B. (1) < (3) < (4) < (2) C. 0,35 < k < 11 C. (2) < (3) < (4) < (1) D.0,4 < k < 1 D. (2) < (1) < (4) < (3) 74. Nhit si ca C4H10 (1); C2H5NH2 (2); C2H5OH (3); NH2CH2COOH (4) tng dn theo th t sau:

10