Buffer kecut

HK== H3O + KKli---- K- + Li+

Kk=
C-k=
C-g=

1.00E-03
0.1 M
0.05 M

dengn sumsi
[H3O+]=
2.00E-03
tnp sumsi
m=
n=
o=

pH=

[H3O+]=
1 pH=
5.10E-02
-1.00E-04

2.69897
0.001891
2.723379

-0.9%

0.0035

0.003

s C-okslt

0.0025

0.002
Series1

0.0015

0.001

0.0005

0
0

8
pH

10

12

14

16

K1
K2
Ksp=

5.60E-02
5.42E-05
1.70E-09

pH
1
2
3
4
5
6
7
8
9
10
11
12
13
14

[H3O+]
1.00E-01
1.00E-02
1.00E-03
1.00E-04
1.00E-05
1.00E-06
1.00E-07
1.00E-08
1.00E-09
1.00E-10
1.00E-11
1.00E-12
1.00E-13
1.00E-14

Fktor
5140.694
218.4486
19.77965
2.848313
1.184535
1.018451
1.001845
1.000185
1.000018
1.000002
1
1
1
1

s
0.002956
0.000609
0.000183
6.96E-05
4.49E-05
4.16E-05
4.13E-05
4.12E-05
4.12E-05
4.12E-05
4.12E-05
4.12E-05
4.12E-05
4.12E-05

25

y = -2x + 21.904
R = 1

20

15

10
pS

Series1
Linear (Series1)

0
0

-5

-10
pH

10

12

14

16

K1=
K2=
c-H2S
pH

9.60E-08
1.30E-14
0.1
[H3O+]
[S2-]
1
0.1 1.25E-20
2
0.01 1.25E-18
3
0.001 1.25E-16
4
0.0001 1.25E-14
5 0.00001 1.25E-12
6 0.000001 1.25E-10
7
1E-07 1.25E-08
8
1E-08 1.25E-06
9
1E-09 1.25E-04
10
1E-10 1.25E-02
11
1E-11 1.25E+00
12
1E-12 1.25E+02
13
1E-13 1.25E+04
14
1E-14 1.25E+06

pS
19.90379
17.90379
15.90379
13.90379
11.90379
9.903785
7.903785
5.903785
3.903785
1.903785
-0.09621
-2.09621
-4.09621
-6.09621

3.00E-09

2.50E-09

2.00E-09

s-CuS

1.50E-09
Series1

1.00E-09

5.00E-10

0.00E+00
0

-5.00E-10
pH

10

12

14

16

K1
K2
Ksp=

9.60E-08
1.30E-14
8.00E-37

pH
1
2
3
4
5
6
7
8
9
10
11
12
13
14

[H3O+]
1.00E-01
1.00E-02
1.00E-03
1.00E-04
1.00E-05
1.00E-06
1.00E-07
1.00E-08
1.00E-09
1.00E-10
1.00E-11
1.00E-12
1.00E-13
1.00E-14

Fktor
s
8.01E+18 2.53E-09
8.01E+16 2.53E-10
8.01E+14 2.53E-11
8.02E+12 2.53E-12
8.09E+10 2.54E-13
8.78E+08 2.65E-14
15705129 3.54E-15
849360 8.24E-16
77725.36 2.49E-16
7701.321 7.85E-17
770.3109 2.48E-17
77.92388
7.9E-18
8.692316 2.64E-18
1.769231 1.19E-18

S-PbCO3

Series1

0
0

-1
pH

10

12

14

16

K1
K2
Ksp=

4.45E-07
4.69E-11
7.40E-14

pH
1
2
3
4
5
6
7
8
9
10
11
12
13
14

[H3O+]
Fktor
1.00E-01 4.79147E+14
1.00E-02 4.79167E+12
1.00E-03 47935842458
1.00E-04 481277402.1
1.00E-05 5004672.666
1.00E-06 69237.48212
1.00E-07 2612.341367
1.00E-08 219.0110683
1.00E-09 22.36987614
1.00E-10 3.132675307
1.00E-11 1.213224408
1.00E-12
1.02132201
1.00E-13 1.002132197
1.00E-14
1.00021322

s
5.95457
0.595469
0.059559
0.005968
0.000609
7.16E-05
1.39E-05
4.03E-06
1.29E-06
4.81E-07
3E-07
2.75E-07
2.72E-07
2.72E-07

nSilver

ion is being considered as a reagent for

separating I- from SCN- in a solution that is
0.060 M in KI and 0.070 M in NaSCN.
n(a) What Ag+ concentration is needed to
lower the I- concentration to 1.0 10-6 M?
n(b) What is the Ag+ concentration of the solution when AgSCN begins to precipitate?
n(c) What is the ratio of SCN- to I- ion when AgSCN begins to precipitate?
n(d) What is the ratio of SCN- to I- when the Ag+ concentration is 1.0 10-3 M?
Ksp Silver Iodid
silver
SCN

1)
2)
3)

4)

8.3E-17
1.10E-12

[I-]=
1.00E-06 M
[Silver+]
8.30E-11 M
[Silver+]
1.57E-11 M
[I-] pd st SCN muli mengendp
5.28E-06 M
rsio [SCN]/[I]=
1.33E+04
[Silver+]
1.00E-03 M
[I-]=
8.30E-14
[SCN-]=
1.10E-09
[SCN]/[I-]= 1.33E+04