Professional Documents
Culture Documents
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MC LC
MC LC................................ ................................ ................................ .............. 1
DANH MC CC BNG ................................ ................................ ..................... 3
DANH MC HNH NH................................ ................................ ...................... 4
M U ................................ ................................ ................................ ................ 7
PHN 1: TNG QUAN ................................ ................................ ........................ 8
CHNG 1: C S L THUYT................................ ................................ ......8
1.1 Phng php sol-gel................................ ................................ ................... 8
1.1.1 Gii thiu................................ ................................ ............................. 8
1.1.2 Cc qu trnh chnh xy ra trong Sol-Gel ................................ ............. 9
1.1.3 u im v nhc im ca qu trnh Sol-Gel ................................ ..13
1.1.4 Mt s ng dng hin nay ca phng php sol-gel ......................... 14
1.1.5 Cc phng php to mng ................................ ............................... 16
1.2 Hp cht TiO2 v cc ng dng................................ ................................ 20
1.2.1 Cc tnh cht l-ha ................................ ................................ .......... 20
1.2.2 Tnh nng quang xc tc ................................ ................................ ... 22
1.2.3 S lc v vt liu t lm sch ................................ .......................... 26
1.2.3.1 Gc tip xc ................................ ................................ ................ 26
1.2.3.2 Tnh k nc ................................ ................................ ............... 27
1.2.3.3 Tnh a nc ................................ ................................ ............... 28
1.3 Cc phng php phn tch m u trong kha lun ................................ ..... 32
1.3.1 Nguyn l v ng dng ca ph UV-VIS................................ ........... 32
1.3.2 Nguyn l v ng dng ca ph nhiu x tia X (XRD) ...................... 33
1.3.3 Nguyn l v ng dng ca cc knh hin vi TEM, SEM, AFM......... 35
1.3.3.1 Knh hin vi in t truyn qua (TEM)................................ ........ 35
1.3.3.2 Knh hin vi in t qut (SEM)................................ .................. 36
1.3.3.3 Knh hin vi lc nguyn t (AFM) ................................ .............. 38
PHN 2: THC NGHIM ................................ ................................ ................. 40
CHNG II: TO V KHO ST TNH CHT VT LIU ....................... 40
2.1 To vt liu TiO2 ................................ ................................ ...................... 40
2.1.1 Qu trnh to sol ................................ ................................ ................ 40
2.1.1.1 Chun b................................ ................................ ...................... 40
Ha cht ................................ ................................ ................................ ...... 40
Dng c th nghim ................................ ................................ ..................... 40
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DANH MC CC BNG
Bng 1.1
Bng 1.2
Bng 3.1
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DANH MC HNH NH
Hnh 1.1
Hnh 1.2
Hnh 1.3
Hnh 1.4
Hnh 1.5
Hnh 1.6
Hnh 1.7
Hnh 1.8
Hnh 1.9
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Hnh 1.27 Cng tia sng trong phng php o UV-VIS ............................. 33
Hnh 1.28 My UV-Vis Cary 100 Conc - Variant ................................ ............... 33
Hnh 1.29 S tn x tia X bi nguyn t................................ ......................... 34
Hnh 1.30 S nhiu x tia X bi tinh th. ................................ ....................... 34
Hnh 1.31 My chp ph XRD ................................ ................................ ........... 35
Hnh 1.32 S cu to my TEM ................................ ................................ ..... 35
Hnh 1.33 My JEM 1400 ................................ ................................ ................ 36
Hnh 1.34 S cu to my SEM ................................ ................................ ..... 37
Hnh 1.35 My Jeol 6600 ................................ ................................ .................... 38
Hnh 1.36 My Nanotec Electronica S.L ................................ ............................. 38
Hnh 1.37 S cu to my AFM ................................ ................................ ..... 39
Hnh 1.38 th cc vng hot ng ca mi d................................ ................ 39
Hnh 2.1
Hnh 2.2
Hnh 2.3
Hnh 2.4
Hnh 3.1
Hnh 3.2
Hnh 3.3
Hnh 3.4
Hnh 3.5
Hnh 3.6
Hnh 3.7
Hnh 3.8
Hnh 3.9
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M U
Vt liu TiO2 l cht bn dn c tnh nng quang xc tc rt mnh trong vic
ng dng mi trng, c rt nhiu cng trnh trong v ngoi n c nghin cu vt
liu ny [1,6,34]. Ch bng vic chiu sng, cc nh nghin cu nhn thy cc cht
hu c, cc cht bn b phn hu. c bit trong mi trng nc, di tc dng
ca nh sng v s c mt ca TiO 2, cc hp cht nhim d dng b phn hy.
Tnh cht ny c p dng lm sch nc, khng kh v dit khun.
Vi rng vng cm khong 3,2eV 3,5eV, vt liu TiO2 ch c th cho
hiu ng xc tc trong vng nh sng t ngoi (UV). Tuy nhin, bc x UV ch
chim khong 4%-5% nng lng mt tri nn hiu ng xc tc ngoi tri thp [26].
s dng trc tip nng lng mt tri c hiu qu hn, cn m rng ph hp thu
TiO2 v vng nh sng kh kin (loi bc x chim gn 45% nng lng mt tri)
[26], nhiu tc gi pha tp N vi TiO2 bng phng php phn x magnetron,
phng php ny i hi thit b t tin v kh pha tp N vi nng cao.
khc phc nhng hn ch ca vt liu TiO2 c tnh quang xc tc tt trong vng nh
sng kh kin, chng ti tng hp mng v bt TiO2 pha tp vi SnO2 bng phng
php sol gel, y l phng php cho tinh khit cao v c th pha tp vi nng
cao [16,21,22,24]. Sau chng ti dng cc phng php quang ph nghin
cu tnh cht quang ca vt liu TiO2 pha tp SnO2.
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PHN 1
TNG QUAN
CHNG I:
C S L THUYT
1.1
1.1.1
Gii thiu:
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Hnh 1.1
10
(1.1)
(1.2)
Ngng t nc:
M(OH)(OR) n-1 + M(OH)(OR) n-1 (OR) n-1M-O-M(OR)n-1 + H2O (1.3)
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Hnh 1.2
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Phn ng ngng t
thnh dung dch sol gm nhng ht oxide kim loi nh (ht sol) phn tn trong dung
dch sol. Dung dch c th c dng ph mng bng phng php ph quay (spin
coating) hay ph nhng (dip coating).
dung dch tin ra v hn do c s hnh thnh mng li oxide kim loi (M-O-M) ba
chiu trong dung dch.
khin bi nng lng phn gii. Thng qua qu trnh ny gel s chuyn t pha v
nh hnh sang pha tinh th di tc dng ca nhit cao.
Trong ton b qu trnh, hai phn ng thu phnngng t l hai phn ng
quyt nh cu trc v tnh cht ca sn phm sau cng. Do , trong phng php
sol-gel, vic kim sot tc phn ng thu phn-ngng t l rt quan trng.
SVTH: Hunh Ch Cng
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Hnh 1.3
Hnh 1.4
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Hnh 1.5 S pht trin cu trc mng trong qu trnh sol -gel
1.1.3
u im:
C th to ra mng ph lin kt mng mang n s dnh cht rt tt gia
vt liu kim loi v mng.
C th to ra mng dy cung cp cho qu trnh chng s n mn.
C th d dng to hnh cc vt liu c hnh dng phc tp.
C th sn sut c nhng sn phm c tinh khit cao.
Kh nng thiu kt nhit thp, thng l 200 600 .
C th iu khin cc cu trc vt liu.
To c hp cht vi pha tp ln.
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khuych tn ng u cao.
Ch to nano thay i thnh phn d
Lm vic nhit thp hiu qu, kinh t, n gin sn xut nhng mng
c cht lng cao.
u im ni tri nht ca phng php sol-gel l kh nng ch to c
nhng vt liu mi c cu trc ng u: vt liu xp, vt liu microballoon ...
Nhc im:
S lin kt trong mng yu.
C thm thu cao.
Rt kh iu khin xp.
D b rn nt trong qu trnh nung sy.
1.1.4
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Hnh 1.6
15
loi cc dng c quang hc: gng nng (hot mirror), gng l nh (cold mirror),
thu knh v b tch tia (beam splitter)
gel). Gel kh c ng dng trong nhiu lnh vc: hp th nng lng mt tri (silica
aerogel), xc tc (alumina (Al 2O3) aerogel c pha tp kim loi), cht cch in v
cch nhit (silica aerogel)
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1.1.5
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Hnh 1.7
Hnh 1.8
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(1.4)
vi
h: dy lp ph.
: nht dung dch.
: sc cng b mt lng-hi.
: t trng.
g: lc hp dn.
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Hnh 1.9
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1.2.1
Pha
Chit sut
Cu trc tinh th
Anatase
2.49
3.84
Tetragonal
Rutile
2.903
4.26
Tetragonal
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Bng 1.2
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H tinh th
Rutile
Anatase
Brookite
Tet
Tet
Orth
4.5845
3.7842
9.184
n v
a(Ao)
b(Ao)
5.447
c(Ao)
2.9533
9.5146
5.145
Vol
62.07
136.25
257.38
Density
4.2743
3.895
4.123
28.9
0.2890
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Brookite: c hot tnh quang ho rt yu. Brookite c rng khe nng lng
3,4 eV, khi lng ring 4,1 g/cm 3 (hnh 1.15).
Do vt liu mng mng v ht nano TiO 2 ch tn ti dng th hnh anatase
v rutile, hn na kh nng xc tc quang ca brookite hu nh khng c nn ta s
khng xt n pha brookite trong phn cn li ca ti.
1.2.2
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(1.5)
D + h + D+
(1.6)
(1.7)
(1.8)
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TiO2 + h h+ + e
(1.9)
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Bc tinh th
Bc tinh th l khi nim ch xa ca trt t sp xp tinh th trong vt l
S lc v vt liu t lm sch[1]:
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lng tri rng ra trn b mt. Cui cng, gc tip xc ln hn 90 0 tc l cht lng c
khuynh hng to thnh git hoc ngng t trn b mt vt liu rn.
1.2.3.2 Tnh k nc:
Vt liu c tnh cht ny s t hoc khng thm nc. Khi nc nh ln b mt
vt liu k nc s c khuynh hng ngng t thnh nhng git ri rc trn b mt
vt liu. Vt liu k nc c gc tip xc ln hn 70 0. Gc tip xc cng ln, nng
lng dnh t cng nh. Kh nng t lm sch ca vt liu da trn tnh siu k
nc c bit n rt lu t vic nghin cu b mt t lm sch ca l cy, in
hnh l l sen. Gn y, vi vic quan st cu trc b mt ca l sen cc nh nghin
cu c th gii thch v ch to vt liu t lm sch da trn hiu ng l sen. Trn
b mt l sen c rt nhiu vi cu trc nh (hnh 1.19), cc vi cu trc ny lm cho
gc tip xc ca nc trn b mt ln hn 130 0. iu ny c ngha l bm dnh
ca nc cng nh ca cc phn t gim i rt nhiu. Khi nc tip xc vi b mt
vt liu ny s ngay lp tc co cm li to thnh git. Cc phn t cht bn do
bm dnh vi b mt vt liu ny rt thp; khi c nc, cc phn t cht bn ny s
bm dnh vi cc git nc tt hn v chng s b cun i cng git nc lm cho
b mt vt liu tr nn sch s (hnh 1.20).
20nm
50nm
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1.3
1.3.1
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C
Io
I0 = I A + I r + I
(1.10)
Trong :
Io : Cng ban u ca ngun sng.
I : Cng nh sng sau khi i qua dung d ch.
IA: Cng nh sng b hp thu bi dung dch.
Ir : Cng nh sng phn x bi thnh cuvet v dung dch, gi tr ny c
loi b bng cch lp li 2 ln o.
C : Nng mol cht ban u.
l : Chiu dy lp dung dch m nh sng i qua.
1.3.2
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Hiu quang l xut pht t hai mt lin tip trong h mt biu din c tnh
theo cng thc :
2d.sin()=m
m= 1, 2, 3, ... ( nh lut Bragg ) l bc cc i cng ca phn x.
d: khong cch gia cc mt mng.
: l gc nhiu x tng ng.
(1.11)
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T nhng c s l thuyt trn, chng ti tin hnh tng hp vt liu TiO2 pha
tp SnO 2 v nghin cu cc tnh cht quang ca vt liu.
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PHN 2
THC NGHIM
CHNG II:
TO V KHO ST TNH CHT VT LIU
2.1
To vt liu TiO2:
2.1.1
Qu trnh to sol:
2.1.1.1 Chun b:
Ha cht
Ethanol C 2H5OH ca Merk , M = 46,07 g/mol , d = 0,789
Tin(II) cloride SnCl 2.2H2O ca Merk, M=225,63 g/mol
Tetraisopropylorthotitanate
Ti(OC 3H7)4
ca
Merck,
M=284,25g/mol,
d=0,96g/ml.
Axit acetic CH 3COOH ca Merck, M = 60,05 g/mol , d = 1,049
Iso propanol (CH 3)2CHOH ca Merck, M=60,10 g/mol , d= 0,785
Methanol CH 3OH ca Merk, M = 32,04 g/mol , d = 0,791
Dng c th nghim
L trung tnh, pipet, a thy tinh, mung thy tinh, c t, bp khuy t c h
thng n nh nhit v tc khuy, cn, nhit k.
Chun b dng c trc v sau khi s dng:
u tin : Pipet, l, a thu tinh, mung thy tinh c ngm trong nc
sch khong 30 pht, l v a thy tinh ra vi x phng, sau ra sch vi
nc, trng qua nc ct v sy kh trong l nhit 100-120oC.
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m SnCl 2
M SnCl 2
16,74
0.074(mol )
225,63
C2H5OH:
mC 2 H 5 OH VC 2 H 5 OH d C 2 H 5 OH 157,8( g )
nC 2 H 5 OH
mC 2 H 5 OH
M C 2 H 5 OH
157,8
3,379(mol )
46,7
C2H5OH:SnCl 2 = 46:1
Cc bc tin hnh:
Cn 8,37g SnCl 2.2H2O cho vo l, sau cho 100ml C 2H5OH vo, y np li.
Khuy u dung dch trong 5h vi nhit c gi n nh 80oC ta c sol
SnO2. em mt mu sol thu c o ph UV-VIS ta thy b hp thu ca sol thu
c c bc sng ~345 nm. Ta s dng sol ny pha tp vo TiO 2.
S to sol:
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CH3COOH:
mCH 3COOH VCH 3COOH d CH 3COOH 7,259( g )
nCH 3COOH
mCH 3COOH
M CH 3COOH
0,1200( mol )
(CH3)2CHOH:
m(CH 3 ) 2 CHOH V(CH 3 ) 2 CHOH d (CH 3 ) 2 CHOH 1,603( g )
n(CH 3 ) 2 CHOH
m(CH 3 ) 2 CHOH
M (CH 3 ) 2 CHOH
0,0267 ( mol )
CH3OH:
mCH 3OH VCH 3OH d CH 3OH 4,545( g )
mCH 3OH
nCH 3OH
0,1419( mol )
M CH 3OH
Ta c t l mol:
Ti(OC3H7)4: CH3COOH: (CH 3)2CHOH: CH 3OH=1:6,06:1,34:7,17
Cc bc tin hnh:
Mt trong nhng kh khn ca cht TiP l rt nhy vi khng kh v nc v
vy nu ban u cho phn ng vi nc thi dung dch s nhanh chng kt ta v
nh th qu trnh sol-gel s khng xy ra. khc phc nhng nhc im trn,
u tin chng ti pha trn cht TiP vi axid acetic (Hac):
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(2.1)
Hac s ng vai tr lm gim tnh kch hat ca TiP trong khng kh, v v y
cht TiP s khng b kt ta.
Vai tr th hai ca Hac l c th tham gia vo phn ng ester.
iPrOH + HOAC <-> iPrOAC + H 2O.
(2.2)
(2.3)
(2.4)
(2.5)
Cc bc tin hnh:
Cho 11,53 ml Axit acetic (CH 3COOH) vo l, sau cho 10 ml
Tetraisopropylorthotitanate Ti(OC 3H7)4 vo, y np kn li khuy trong 30 pht.
Sau cho thm 3,4 ml Iso propanol (CH 3)2CHOH vo khuy tip 30 pht na. Sau
cho thm 9,5 ml Methanol CH 3OH vo khuy 30 pht. Sau ly 1,17 ml sol
SnO2 pha trc thm vo dung dch thu c khuy thm 30 pht na ta c
sol TiO2 pha tp 5% SnO 2. y k np l li, 4 ngy th em to mng.
Lp li cc bc trn, gi nguyn cc cht ban u, thay i th tch sol SnO 2
pha thm vo thu c cc sol TiO 2 vi nng phn trm SnO 2 pha tp vo
khc nhau.
Thm vo 2,35ml sol SnO 2 thu c sol TiO 2 pha tp 10% SnO 2.
Thm vo 4,69ml sol SnO 2 thu c sol TiO 2 pha tp 20% SnO 2.
Thm vo 7,04ml sol SnO 2 thu c sol TiO 2 pha tp 30% SnO 2.
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S to sol
Hnh 2.2
Sau tin hnh thay i nng phn trm SnO 2 theo cc t l 5%, 10%,
20%, 30% khi lng.
2.1.2
Qu trnh to mng:
Mng c to trn thy tinh kch thc:7,5x2,5cm
Chng ti tin hnh to mng bng 2 phng php: Ph nhng v ph quay.
X l b mt :
cn c x l v bo qun tht k v c vai tr quan trng, nh hng
n bm, tinh khit v mt s tnh cht khc ca mng. Sau y l quy trnh
x l :
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c ngm trong dung dch axt HCl long 0.5 M kho ng 2030
pht loi b tp cht.
Sau khi ngm axt, x nc, dng bn chi ch sch vi x phng.
Ra vi nc v tip tc ngm vo dung dch baz NaOH 10% trong
15 pht.
Sau khi ngm baz, x nc, dng bn chi ch sch li vi x phng.
Ngm trong nc ct.
nh siu m trong 15 pht b ng nc ct v acetone.
Sy kh b mt .
sau khi x l sch, c bo qun trong hp ng lam chuyn dng.
Ph quay:
Chng ti thc hin qu trnh to mng bng phng php ph quay trn thit
b quay ph ca PTN Cng ngh Nano.
Trnh t ph mng gm cc bc nh sau:
Bt ngun bin tn. nh trc vn tc quay ca motor bng bin tn.
t ln b g mu ca motor quay. Dng ng nh git nh mt
lng va dung dch ln.
Bt motor quay. Cho motor quay trong 1 pht dung mi bay hi.
Lp li t bc 2 n bc 3 cho qu trnh ph nhiu lp.
Gp mu ra khi b g. Lau sch dung dch d bm vo b g bng
aceton trnh lm bn mu tip theo.
dy mng c iu chnh bng cch iu chnh tc quay ca hoc
tng s ln ph. Trong trng hp ph nhiu lp, ui bt dung mi trc khi
ph ln mt lp khc, thi gian quay dnh cho mi lp ph l 1 pht. Sau mng
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Hnh 2.3
Ph mng 1 lp:
M t: dng ph mng c a xung v c nhng hon ton trong
cht lng vi 1 vn tc nht nh. Ch khong 1 pht ri ko mng ln vi cng vn
tc .
Trong qu trnh thc nghim chng ti chn c tc nhng tt nht l
6cm/pht. Vi vn tc ny mng thu c l ng u nht.
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X l nhit:
2.2
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2.2.1
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Tin hnh o tnh nng quang xuc tc c a mng bng cc phng php th
Metyl Blue (MB) v th tnh nng dit khun ca mng ti PTN Cng ngh Nano
HQG TpHCM. Sau o gc thm t ca mng bng my OCA-20 ca hng
Dataphysics ti Phng Th nghim trng im Quc gia v Vt liu Polymer v
Composite H BK HQG TpHCM .
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Hnh 2.4
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My OCA-20 Dataphysics
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I
lC
I0
(2.6)
Trong :
A : hp thu.
C : Nng (mol/l; mg/l).
l : Chiu dy lp dung dch (cm).
: H s hp thu phn t.
T cng thc trn ta suy ra:
C
A
C0 A0
(2.7)
C
theo thi gian ng vi cc mu c nng phn trm SnO2
C0
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CHNG III
KT QU V BN LUN
3.1
Sol TiO2
Sol SnO2
Sol 5%
Sol 10%
Sol 20%
Sol 30%
3.0
2.5
Abs
2.0
1.5
1.0
0.5
0.0
380
400
420
440
460
480
500
(nm)
Hnh 3.1
Hnh 3.1 l ph hp thu UV-Viss ca dung dch SnO2, TiO2, v TiO 2: SnO 2 ti
cc nng khc nhau (5%, 10%, 20%, 30%). T ph hp thu trn cho thy khi pha
tp TiO2:SnO2 ph UV Viss c s dch chuyn v pha bc sng vi nng
pha tp SnO 2 cng cao th dch chuyn cng nhiu bc sng ln hn b hp
thu ca TiO2 (= 380 nm), v hp thu cng tng, trong khi b hp thu ca cc
dung dch trn u khng thay i, nguyn nhn ny c th l do di tc dng ca
nh sng, cc in t hnh thnh t TiO2 chuyn n SnO 2 v nguc li l trng t
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SnO2 chuyn n TiO 2 do hnh thnh mi ni bn trong hai cht bn dn TiO 2:SnO2
[25] kt qu l lm chm qu trnh ti hp v hp thu tng khi nng pha tp
SnO2 cng nhiu. Mt khc nng pha tp cng nhiu th SnO 2 cng mun nhn
nhiu in t t TiO2 chuyn qua, v vy khi nng pha tp tng th hp thu
tng. y chng ti ch kho st nng pha tp n 30%, v trn 30% dung d ch
b kt ta nhanh.
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TiO2
5%
10 %
20 %
30 %
0.3
Abs
0.2
0.1
0.0
390
400
410
420
430
440
450
460
470
480
(nm)
3.2
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3000
2500
R
A
1500
3 0 0 0C
4 0 0 0C
9 0 0 0C
2000
I n te n s ity
54
A
R
A
A
1000
500
0
20
30
40
50
60
70
80
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5 %
10 %
20 %
30 %
R (1 1 0 )
900
I n te n s ity
R (1 0 1 )
600
R (2 2 0 )
A (1 0 1 )
R (1 1 1 )
SnO 2
SnO 2
R
SnO 2
300
A (2 0 0 )
A (0 0 6 )
A (0 0 4 )
0
24
26
28
30
32
34
36
38
40
42
44
46
48
50
52
54
56
d hkl
0.9
(2 )Cos
(3.2)
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Hnh 3.6
nh TEM ca mu TiO2:SnO2
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Hnh 3.8
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T hnh 3.8 ta thy nh cng cho thy hnh thi b mt mng kh g gh. B
mt g gh gip lm tng hiu sut quang xc tc cho mng. Cc k t qu v tnh
nng quang xc tc sau s cho ta thy hiu qu ca b mt ny.
3.3
3.3.1
5%
10%
20%
30%
1 .1
1 .0
0 .9
0 .8
C / C0
0 .7
0 .6
0 .5
0 .4
0 .3
0 .2
0
50
100
150
200
250
T h i g ia n (p h u t )
Hnh 3.9
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T hnh 3.19 ta thy vi nng SnO2 pha tp cng cao, MB cng nhanh b
phn hy, hot tnh quang xc tc ca mng cng mnh khi chiu nh sng bng
n compact.
Hnh 3.20 l th so snh hot tnh quang xc tc ca mng TiO 2:SnO2 vi
mng TiO 2.
TiO2:SnO2(30%)
TiO2
1.1
1.0
0.9
0.8
C/C0
0.7
0.6
0.5
0.4
0.3
0.2
0
50
100
150
200
250
Th
i gian (phut)
Hnh 3.10
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Hnh 3.11 S mt mu ca dung dch MB trn lam knh theo thi gian
a) Mu lam knh ph mng
b) Mu lam knh cha ph mng.
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3.3.2
61
Hnh 3.13 Gc thm t trn mng TiO 2:SnO2 trong iu kin bnh thng
SVTH: Hunh Ch Cng
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b)Mng TiO 2
Hnh 3.14 Gc thm t trn mng TiO 2:SnO2 chiu sng 2 gi (a) v mng
TiO2 chiu UV [2](b)
Bng 3.1
Lam trng
46,25o
12,19o
<2o
T hnh 3.13 ta thy khi chiu sng t (tip xc vi nh sng hng ngy trong
thi gian ngn) gc thm t ca mng gim rt nhiu so vi lam knh trng. Kt
qu hnh 3.14 ta thy sau khi c chiu bng n compact (thnh ph n tia UV rt
t) mng (a) cng c tnh cht siu thm t nh mng TiO 2 (b) sau khi chiu t
ngoi.
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3.3.3
63
Tnh cht dit khun ca mng c kim nghim bng phng php m s
khun lc trn a petri (hnh 3.15 ). Mu lam kim nghim gm c mu lam khng
c ph mng lm mu i chng, v mu lam c ph mng TiO 2:SnO2. C hai
mu ny u c kch thch bng n compact trc khi th vi sinh. Sau cc
mu lam c nh 100 l dung dch vi khun nng 10-4 CFU ln trn v gi
trong khong thi gian 04 gi, tip sau c ra li bng 5ml nc tit trng, v ly
100 l dung dch sau ra ny cy li ln cc a thch vi khun pht trin (nhit
370C, trong 24 gi).
Hnh 3.15
T hnh 3.15 ta thy khi pha tp thm SnO 2 hiu ng quang xc tc tng ln
ng k. iu ny ph hp vi suy on t kt qu ph UV-VIS ni trn.
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KT LUN
Trong qu trnh nghin cu thc hin kha lun ny, chng ti tm hiu l
thuyt v sol-gel, c ch quang xc tc v dit khun ca TiO2. Nhm m rng b
hp thu ca vt liu nano bn dn TiO2 v vng kh kin, tng hiu sut quang xc
tc ca TiO2 chng ti thc hin pha tp SnO 2 vo TiO 2 bng phng php SolGel.
Chng ti thu c cc kt qu sau:
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[2]
[3]
[4]
[5]
[6]
[7]
[8]
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[9]
Chen Shifu, Chen Lei, Gao Shen, Cao Gengyu (2006), The preparation of
coupled SnO2/TiO2 photocatalyst by ball milling, Department of Chemistry,
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China.
[10]
[11]
[12]
Funda Saylkana, Meltem Asiltrk, Nadir Kiraz, Esin Burunkaya, Ertu grul
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Turkey.
[13]
[14]
[15]
[16]
[17]
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[18]
Jianwei Gong, Quanfang Chen (2004), Sol -Gel Prepared Single Wall
Carbon Nanotube SnO 2 Thin Film for Micromachined Gas Sensor,
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of Central Florida, Orlando.
[19]
Kwang Soo Yoo, Nam Woong Cho, Han Sang Song, Hyung Jin Jung (1995),
Surface morphology and gas -sensing characteristics of SnO 2-x thin films
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and Technology, P.O. Box 131, Cheongryang, Seoul 130 -650, South Korea.
[20]
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[23]
[24]
[25]
Minghua Zhou, Jiaguo Yu, Shengwei Liu, Pengcheng Zhai, Li Jiang (2008),
Effects of calcination temperatures on photocatalytic activity of SnO2/TiO2
composite films prepared by an EPD method, State Key Laboratory of
Advanced Technology for Material Synthesis and Processing, Wuhan
University of Technology, Wuhan 430070, PR China
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[26]
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