DNG 1: Bi tp tnh pH ca dung dch

Cu 1: Trn 200 ml dung dch HCl 0,25M vi 800ml dung dch cha Ba(OH)2 0,025M v NaOH 0,025M. Tnh pH ca dung dch thu c ? Cu 2. Sc kh CO2 vo 200 ml dd cha NaOH 1M v Ba(OH)2 0,5M thu c 19,7 gam kt ta. Hy cho bit th tch kh CO2 (ktc) sc vo l : Cu 3. Ho tan va ht oxit ca kim loi ho tr II trong dung dch H2SO4 17,5% thu c dung dch mui c nng 20%. Xc nh cng thc ca oxit. Cu 4. Cho 200 ml dung dch NaOH 1M vo 100 ml dung dch Zn(NO3)2 thu c 7,92 gam kt ta. Hy xc nh nng mol/l ca dung dch Zn(NO3)2 . A. 0,8M B. 0,9M C. 1,0M D. 1,2M Cu 5. Trn dung dch HNO3 1,5M v HCl 2,5M theo t l th tch 1 : 1 thu c dung dch X. Hy xc nh th tch ca dung dch NaOH 1M cn dng trung ho 100 ml dung dch X. Cu 6: Trn 250ml dung dch hn hp gm HCl 0,08 mol/l v H2SO4 0,01 mol/l vi 250ml dung dch Ba(OH) 2 a mol/l thu c m gam kt ta v 500 ml dung dch c pH = 12. Tnh m v a. Cu 7: Trn 100ml dung dch gm (Ba(OH)2 0,1M v NaOH 0,1M) vi 400ml dung dch gm( H2SO40,375M v HCl,0,0125M) thu c dung dch X. a.Tnh pH ca dung dch X b. C cn X thu c mg mui khan, tm m.

b mol NaOH. thu c kt ta th cn c t l A. a : b = 1 : 4. B. a : b < 1 : 4. C. a : b = 1 : 5. D. a : b > 1 : 4. Cu 17. Cho 200 ml dung dch NaOH 1M vo 200 ml dung dch HCl 2M thu c dung dch X. Cho Zn d vo dung dch X. Tnh th tch kh H2 thot ra (ktc) ? Cu 18. Cho 200 ml dung dch NaOH 1,2M vo 200 ml dung dch AlCl3 0,25M thu c dung dch X. a/ Xc nh nng [OH-] trong dung dch X. b/ Xc nh th tch dung dch HCl 1M cn cho vo dung dch X : - Bt u xut hin kt ta. - Thu c kt ta c khi lng cc i. Cu 19. Cho 100 ml dung dch NaOH vo 100 ml dung dch ZnCl2 thu c 4,95 gam kt ta. Cho 200 ml dung dch NaOH vo 100 ml dung dch ZnCl 2 thu c 4,95 gam kt ta. Hy la chn gi tr ng vi nng mol/l ca dung dch NaOH v dung dch ZnCl2 . A. NaOH 0,9M v ZnCl2 0,75M B. NaOH 1M v ZnCl2 0,65M C. NaOH 1M v ZnCl2 0,75M D. NaOH 1,2M v ZnCl2 0,85M.

DNG 4: Bi tp nhn bit.

Cu 20: Ch dng mt thuc th, hy nhn bit cc l ng dung dch mt nhn sau: NH4Cl; (NH4)2SO4 Na2CO3; NaNO3 Cu 21: Phn bit cc cht ng ring bit trong cc bnh khc nhau: a, dd cha: HCl, HNO3, H2SO4, H3PO4. b, dd Na3PO4, NH3, NaOH, NH4NO3, HNO3. Cu 22: Nhn bit bng: a, qu tm Ba(OH)2, H2SO4, NH4Cl, (NH4)2SO4, NH3. b, mt thuc th: NH4NO3, (NH4)2SO4, NaNO3, Fe(NO3)3.

DNG 2: Bi tp s dng nh lut bo ton in tch trong dung dch

Cu 8: Cho V ml dung dch gm(NaOH 0,1Mv Ba(OH)2 0,05M) phn ng va vi 50ml dung dch gm (HCl 0,3M v HNO3 0,2M). C cn dung dch sau phn ng thu c mg mui. tm V v m. Cu 9: Mt dung dch X cha 0,1mol Fe2+; 0,2 mol Al3+; x mol Cl- v y mol
2 SO4 . C cn dung dch thu c 46,9g

Dng 5: Bi tp thnh lp v vit s phn ng.

Cu 23: Thc hin dy chuyn ha ( ghi r iu kin nu c) 1 2 3 4 HCOOH CO CO2 Ca(HCO3)2 CaCO3 8
5 6 7 H3PO4 HNO3 AgNO3 O2 Cu 24: Vit phng trnh ha hc th hin dy chuyn ha (ghi y iu kin) a, N2 NO NO2 HNO3 Fe(NO3)3 NO2. b, NH4NO3 N2 NO2 NaNO3 O2. NH3 Cu(OH)2 [Cu(NH3)4]OH c) NH3 NO NO2 HNO3 H3PO4 Ca3(PO4)2 CaCO3.

cht rn khan. Tm x v y. ( tng s mol in tch(+) = tng s mol in tch (-)) Cu 10: Mt dung dch cha Ca2+(0,2mol) Na+(0,2mol) Cl(0,4mol)

NO3 (0,2mol).C cn dung dch thu c m g mui

khan. Tm m Cu 10: C 500 ml dung dch X cha Na+ , NH4+ , CO32- v SO42-. Ly 100 ml dung dch X tc dng vi lng d dung dch HCl thu 2,24 lt kh (ktc). Ly 100 ml dung dch X cho tc dng vi lng d dung dch BaCl 2 thy c 43 gam kt ta. Ly 100 ml dung dch X tc dng vi lng d dung dch NaOH thu 4,48 lt kh NH3 ( ktc). Tnh tng khi lng mui c trong 500 ml dung dch X. Cu 11: Cho dung dch Ba(OH) 2 n d vo 100 ml dung dch X c cha cc ion: NH4+, SO42-, NO3- th c 23,3 gam mt kt ta c to thnh v un nng th c 6,72 lt (ktc) mt cht kh bay ra. Nng mol/l ca (NH4)2SO4 v NH4NO3 trong dung dch X l bao nhiu?

d, Ca3(PO4)2 H3PO4 NaH2PO4 Na2HPO4 Na3PO4 Ag3PO4 e, Ca3(PO4)2 P P2O5 H3PO4 Ca3(PO4)2 H3PO4 CO2

Dng 6: Bi tp v hn hp kh N2, H2, NH3

Cu 25: Mt hn hp X gm hai kh N2 v H2 theo t l mol 1 : 3 , nung nng bnh mt thi gian ri a v trng thi ban u th thu c hn hp kh Y. T khi hi ca X i vi Y l 0,6 .Tnh hiu sut phn ng tng hp NH3 . Cu 26: Cho mt bnh kn dung tch 112 lt trong cha N2 v o H2 theo t l th tch 1:4 O C v 200 at ( xc tc thch hp ) nung o nng bnh mt thi gian sau a v nhit O C thy p sut trong bnh gim 10% so vi p sut ban u . Tnh H % phn ng . Cu 27: Mt hn hp kh gm N2 v H2 c t khi i vi H2 bng 3,6 .Sau khi un nng mt thi gian h t ti trng thi cn bng th t khi ca hn hp sau phn ng i vi H 2. bng 4,5. Tnh H% .

DNG 3: Bi tp v hiroxit lng tnh.

Cu 12: Ha tan ht m gam ZnSO 4 vo nc c dung dch X. Cho 110ml dung dch KOH 2M vo X, thu c a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th cng thu c a gam kt ta. Gi tr ca m l A. 20,125.B. 12,375.C. 22,540. D. 17,710 Cu 13: Trn 200ml dung dch NaOH1M vi 100ml dung dch HCl aM thu c dung dch X. Cho dung dch X vo 200ml dung dch AlCl3 0,5M thu c 1,56g kt ta. Hy la chn gi tr ng ca a Cu 15. Cho 200 ml dung dch NaOH 2M vo 100 ml dung dch AlCl3 1,2M. Tnh khi lng kt ta thu c sau phn ng. A. 7,8 gamB. 9,36 gam C. 6,24 gam D. 4,68 gam Cu 16. Trn dung dch cha a mol AlCl3 vi dung dch cha

Cu 28: Tnh th tch N2 v H2 ( ktc) cn dng iu ch 34g NH3 bit hiu sut l 50%.Mun trung ha lng NH3 trn cn dng bao nhiu ml dd HCl 20%(d=1,1g/ml)

Dng 7: Bi ton v axit nitric v nh lut bo toan electron

Cu 29: Cho 31,3 gam hn hp gm Al v Fe3O4 phn ng va vi 280 gam dung dch HNO3 63% thu c dung dch A v V lit kh mu nu duy nht thot ra (ktc). a) Vit phng trnh phn ng xy ra. b) Tnh thnh phn phn trm khi lng mi cht rn trong hn hp ban u. c) Dn ton b V lit kh thu c trn vo 1 lit H2O c ho tan oxi d. Tnh pH ca dung dch to thnh. Xem th tch dung dch khng thay i. Cu 30: ) Cho 8,3 gam hn hp Fe v Al vo dung dch HNO3 long ly d .Phn ng xong thu c 4,48 lt kh NO duy nht (o kc ) a) Vit phng trnh phn ng xy ra v tnh phn trm khi lng mi kim loi trong hn hp ban u. b) Ha tan 0,1 mol Cu kim loi trong 120 ml dung dch X gm HNO3 1M v H2SO4 0,5M. Sau khi phn ng kt thc thu c V lt kh NO duy nht (ktc).Tnh V? Bi 31: Cho 30,4g hn hp Cu v Fe tc dng vi 500ml dung dch HNO3 long du th thu c 8,96 lt NO ( ktc) a) Tnh thnh phn phn trm theo khi lng mi kim loi trong hn hp. b) trung ha lng axit d trong dung dch th cn phi dng 150g dung dch NaOH 20%. Tm nng mol/l dung dch HNO3 ban u. Bi 32*: Ha tan ho ton m gam hn hp FeO, Fe2O3 v Fe3O4 bng dung dch HNO3 d th thu c 4,48 lt kh NO2 (kc). C cn dung dch thu c 145,2 gam mui khan. Tm m? Bi 33*: Nung m gam bt Fe trong oxi thu c 3 gam hn hp rn X. Ho tan rn X trong dng HNO3 d thot ra 0,56 lt kh NO (kc) l sn phm kh duy nht. Tm m? Bi 34: Ha tan ht 14,4 gam hn hp Fe v Mg trong HNO3 long d thu c dung dch A v 2,352 lit (ktc) hn hp 2 kh N2 v N2O c khi lng 3,74 gam. a) Tnh %(m) ca mi kim loi trong hh ? Tnh s mol HNO3 ban u, bit lng HNO3 d 10% so vi lng cn thit. vi mt lng d Ba(OH)2 thu c 29,55g kt ta.Tnh nng mol/lt ca cc cht trong dd. Cu 52. Dn t t V lt kh CO qua m g b oxit ca mt kim loi n phn ng hon ton thu c 3,2 g kim loi v hn hp kh. Dn hn hp kh thu c dn qua dung dch Ca(OH)2 d thy c 5 gam kt ta v c 2,24 lt kh thot ra. Xc nh tn kim loi v % CO phn ng (ktc)

7. (H B-2008) Trn ln V ml dung dch NaOH 0,01M vi V ml dung dch HCl 0,03M c 2V ml dung dch Y. Dung dch Y c pH l 10. (H A-2009) Nung 6,58 gam Cu(NO3)2 trong bnh kn khng cha khng kh, sau mt thi gian thu c 4,96 gam cht rn v hn hp kh X. Hp th hon ton X vo nc c 300ml dung dch Y. Dung dch Y c pH bng 11. (H A-2009) Dy gm cc cht u tc dng vi dung dch HCl long l: D. AgNO3, (NH4)2CO3, CuS 12. (H A-2009) Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 200ml dung dch HCl 1M vo 100ml dung dch X, sinh ra V lit kh (ktc). Gi tr ca V l 13. (H A-2009) C nm dung dch ng ring bit trong nm ng nghim: (NH4)2SO4, FeCl2, Cr(NO3)3, K2CO3, Al(NO3)3. Cho dung dch Ba(OH)2 n d vo nm dung dch trn. Sau khi phn ng kt thc, s ng nghim c kt ta l 14. (H B-2009) Trn 100ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100ml dung dch hn hp gm NaOH 0,2M v Ba(OH)2 0,1M, thu c dung dch X. Dung dch X c pH l 15. (H B-2009) Cho cc phn ng ha hc sau: (1) (NH4)2SO4 + BaCl2 (2) CuSO4 + Ba(NO3)2 (3) Na2SO4 + BaCl2 (4) H2SO4 + BaSO3 (5) (NH4)2SO4 + Ba(OH)2 (6) Fe2(SO4)3 + Ba(NO3)2 Cc phn ng u c cng 1 phng trnh ion rt gn l: 16. (H B-2009) Cho dung dch X cha hn hp gm CH3COOH 0,1M v CH3COONa 0,1M. Bit 250C, Ka ca CH3COOH l 1,75.10-5 v b qua s phn li ca nc. Gi tr pH ca dung dch X 250C l 17. (H A-2010) Dung dch X cha: 0,07 mol Na +; 0,02 mol SO42 v x mol OH-. Dung dch Y c cha ClO4-, NO3- v y mol H+; tng s mol ClO4- v NO3- l 0,04. Trn X v Y c 100ml dung dch Z. Dung dch Z c pH (b qua s in li ca nc) l 18. (H A-2010) Nh t t tng git n ht 30ml dung dch HCl 1M vo 100ml dung dch cha Na2CO3 0,2M v NaHCO3 0,2M, sau phn ng thu c s mol CO2 l 19. (H A-2010) Cho dung dch X gm: 0,007 mol Na+; 0,003 mol Ca2+; 0,006 mol Cl-; 0,006 mol HCO3- v 0,001 mol NO3-. loi b ht Ca2+ trong X cn mt lng va dung dch cha a(g) Ca(OH)2. Gi tr ca a l 22. (H B-2007) Trong cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2. Dy gm cc cht u tc dng c vi dung dch Ba(HCO3)2 l 23. (H B-2007) Cho bn phn ng: (1) Fe + 2HCl FeCl2 + H2 (2) 2NaOH + (NH4)2SO4 Na2SO4 + 2NH3 + 2H2O (3) BaCl2 + Na2CO3 BaCO3 + 2NaCl (4) 2NH3 + 2H2O + FeSO4 Fe(OH)2 + (NH4)2SO4 S phn ng thuc loi phn ng axit-baz l 24. (H A-2007) Dung dch HCl v dung dch CH 3COOH c cng nng mol/l, pH ca hai dung dch tng ng l x v y. Quan h gia x v y l (gi thit, c 100 phn t CH3COOH th c 1 phn t in li) 25. (H A-2007) Cho dy cc cht: Ca(HCO3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong dy c tnh cht lng tnh l

Dng 8 : bi ton tng hp :

3. (H B-2008) Cho dy cc cht: KAl(SO 4)2.12H2O, C2H5OH, C12H22O11 (saccaroz), CH3COOH, Ca(OH)2, CH3COONH4. S cht in li l 4. (H B-2008) Trn 100ml dung dch c pH=1 gm HCl v HNO3 vi 100ml dung dch NaOH nng a (mol/l) thu c 200ml dung dch c pH=12. Gi tr ca a l (bit trong mi dung dch [H+][OH-]=10-14) 5. (H B-2008) Cho 0,1mol P2O5 vo dung dch cha 0,35 mol KOH. Dung dch thu c c cc cht: 6. (C-2007) Trong s cc dung dch: Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa. Nhng dung dch c pH>7 l