Professional Documents
Culture Documents
Neutron scattering
H/D containing molecules
Interference of photons scattered by ordered structures Point lattice with crystalline long range (min. 10 unit cells) Interference positive for:
n = 2d sin
Braggs Law
a. a
b. b
200 220 222 400 420 422 440 600 442 620 622 444 640 642
111 200 220 311 222 400 331 420 422 511 333 440 531 600 442 620 533 622 444 711 551 640
A fraction of the crystallites will be orientated to satisfy the Bragg condition for each set of planes (hkl). These (hkl) crystallites will be randomly oriented around the incoming beam, so the diffracted beams forms a cone around the incident beam at the angle of 2.
KCl
NaCl
8/4
7/5
9/3
Properties of neutrons
Mass m=1.675 x 10-24g Charge = 0 Spin = Magnetic moment = 1.913 nuclear magnetons
=
k=
h 2 = mv k 2
mv
Neutron energy
E=
2 2 1 2 k mv = 2 2m
Neutron momentum
p = mv = k
p = mv = k Q=
Q
(k
kf
)
k0
Energy Transfer
E=
2 2 1 2 k mv = 2 2m
2
= E0 E f =
k= 2 = mv
2m
(k
2 0
k2 f
Ni
Coherent scattering interference effects between waves scattered from different nuclei Inelastic scattering
kf < k0 (energy loss) Structure and motion of atoms relative to each other
Elastic scattering
kf = k 0 0 =0 only momentum (Q) is transferred
Incoherent scattering deviation of individual atom positions from the g p mean potential
Motion of single atoms
Experimental setup
Elastic neutron scattering
Neutrons are scattered by the nuclei, Xrays b th electrons by the l t Light nuclei (e.g., H, C) are easier to locate in structures with heavy atoms by neutron diffraction
Neutron scattering densities for C6D6 adsorbed on ZSM5, (top) 4 mol/UC, (bottom) 8 mol/UC
http://www.frm2.tum.de
Thermal neutrons: from D2O moderator Hot source: Block of graphite (20 cm diameter, 30 cm high) heated by the gamma radiation to a temperature of ~ 2900 K. Spectrum from 100 meV to 1eV Cold source: Liquid D2 moderator (20 l) temperature about 25 K at a distance of 40 cm from the core axis. The cold neutron spectrum peaked around 5 meV
Energy of neutrons and their application in a research reactor. reactor The size of the colorized area is proportional to the amount of neutrons available for the application.
EXAFS
Single scattering plane wave approximation
(k ) =
2 2 F (k ) N sin (2kr + (k )) e 2 k r2 k
0.4
Constructive (in phase)
10
0.08
0.06
NiO experimental i t NiO experimentall NiO 1 shell NiO 2 shells NiO 3 shells NiO 7 shells
FT mag. FT mag g.
0.04 0.04
4-membered rings
2.0
0.02 0 02 0.02
2.0 2.0
0 0 1 1 2 2 3 3 4 4 5 5 6 6 7 7 8 8
0.00 0.00
r[A]
3.4 34
N 4.28 1.75 4 2 3 2 2 2
FFT mag
Zn 6MR
ZnO
Ni/HTC NiRh/HTC
Zn 5MR
Metall 0 2 4 6 8
Zn 4MR
Ni foil
3 R ()
r []
Preferential l P f ti l location of ti f
Zn2+ Z
0.0081 0.0095
0.0043 0.0050
Rh/HTC
5d
3/2
FFT
NiRh/HTC
Rh foil
2p
2 3
R ()
3/2
LIII
2(2) N Rh-Ni R () 2(2)
2p
1/2
II
Electron deficient particles show a higher peak above the absorption edge
0.0017 0.0090 7.1 2.52 0.0041
0.0087 0.0029
Information level
Structural environment Number and kind of Neighbors Distance Disorder Oxidation state Electronic information DOS in the final state Geometry, distortions
XANES
Electronic transitions Multiple scattering Exact description based on quantum-mechanical calculations t h i l l l ti Interpretation of characteristic spectral features using references (peak fitting, PCA correlation fitting PCA, spectroscopy)
The first accelerators (cyclotrons) were built by particle physicists in the 1930s. The nucleus of the atom was split using the collision of high energy particles. From the results of these collisions the physicists tried to deduce the laws of fundamental physics that govern our world and the whole of the universe. Synchrotron radiation was seen for the first time at the General Electric in the USA in 1947 in a different type of accelerator (synchrotron). It was first considered a nuisance because it caused the particles to lose energy, but in the 1960s exceptional properties as light source were recognized.
SRs Daresbry UK
10-15 MeV 20 mA
Bending Magnet
Wiggler
Sample cooling
Sample heating
Gas inlet
Capton windows
Gas outlet