1

C: NS28

-8002
:

():

( 7 ):

( 31 ):
2 ( :3 )

5 ( :2 )

6 ( :1 )

:

():

( )8002

2
6
C: NS28

) (Ibuprofne C13H18O2
.

200 mg .
RCOOH .RCOO
M(RCOOH) = 206 g.mol-1 : RCOOH
. 25C

)3 - I :
200 mg
) (S0 C0 .V0= 100 mL
-1.1 0,75 ( . C0 )
-1.2 pH ) (S0 . pH=3,17
-1.2.1
1,25 ( . )
-1.2.2 Qr 0, 5 ( . )
-1.2.1 Qr :

xmax . 2
) V0 .(1

Qr ,eq

: : xmax .
-4.2.1 K 0,75 ( . )

(1)

)2 -II :
VB = 60,0 mL
) (SB Naaq HOaq CB = 3,0.10-2 mol.L-1
).(S
( ) (S)VB
-2.1 RCOOH )(SB
0,75 ( . )
-2.2 ) ni(HO- HO ) (SB
) ni(RCOOH RCOOH ( .
) 0, 5 ( . )

:

():

( )8002

1
6
C: NS28

-2.1 HO- ) (S V = 20,0 mL

) (SA
. CA = 1,0.10-2 mol.L-1

VAE = 27,7 mL ).(SA

HO- ) (S
H3O+ ) (SA :
H3O+aq + HO- aq
)2H2O(l
-2.1.1 HO RCOOH

.
-2.1.2 m . 0, 5 ( . )
(3)

:
:3 -


24
11
. Na
.

-1 1124 Na
-1.1 0, 5 ( . )
-1.2 22
0,25 ( . t = 15h )
-2 .
t0 = 0 V0 = 5,00 mL 22
. C0 = 10-3 mol.L-1
-2.1 n1 1124 Na
0, 5 ( . t1 = 3h )
-2.2 .t1
23
-1
( 0,25 ( ) NA = 6,02.10 mol )
-2.1 t1 = 3h V2 = 2,00 mL
n2 = 2,1.10-9 mol . 22
Vp 5,00 L
0, 5 ( . )
Mg

24
12

:

():

( )8002

C: NS28

:2 -
.

.

)3 -I :
()1
C

R .K
RC :
U = 0 t<0 U = E t 0. E = 12 V : t = 0

uC .
( )2 ). uc = f(t

R
C

uC

)uC (V
12

-1.1
) 3 ( .uC(t )
t

)t(s

-1.2 ) uC(t) = E .(1 e

t 0
2
0, 5 ( . )
-1.1 0, 5 ( . )
-1.2 C . C = 100 F 0,75 ( . R = 10 k )
4

-1.1 .

( 0,7 5 )

)2 - II :

.
. UC = 360 V

():

( )8002

1
6
C: NS28

t = 0
( r )1
K
t

uC 360.e ' :
) uC (t ). (V

i
uC

-2.1 r
uC(t) = 132,45 V 3 ( . t = 2 ms )
-2.2 0, 5 ( . )
--------------------------------------------------- - 1 :

.

V0

H
G0

( . T)1
i
A
X
A
O

j
G0 ) R( O, i , j
.
H
( g = 10 m.s-2 : ) H= 405 m
.
T
)3 -I :

Y
.
1
t = 0

-1
) A(xA=450 m ;yA = 0 V0 . V0 = 50 m.s
-1.1 ) x(t ) y(t G0

) 1,5 ( . R(O, i , j )
-1.2 0,75 ( . )
-1.1 0,5 ( .G0 )
0

():

( )8002

6
6
C: NS28

)2 -II :

. H . O
. t0 = 0

. f = - 100. v v
. t
.
{ }. m = 150 kg :

-2.1 ) R( O, i , j G1
1,25 ( . )
-2.2 2 G1 Vlim
0,5 ( . )
-2.1 0,5 ( . )
-2.2 v4 3 ( . a4 )
0,6
5,08
6,60

0,5
4,37
7,07

0,3
2,80
8,12

0,4
v4
a4

0,2
1,93
8,71

0,1
1,00
9,33

0
0
10,00

)ti(s
)vi(m.s-1
)ai(m.s-2
)v( m.s-1
16

12

)t(s
15

10