Chun b cho k thi tuyn sinh i hc & Cao ng nm 2012

MT S BI TP MI V HAY TRONG MA THI TH 2011

1. Nhng mt thanh Mg vo dung dch c cha 0,6 mol Fe(NO3)3 v 0,05 mol Cu(NO3)2, sau mt thi gian ly thanh kim loi ra v cn li th thy khi lng tng 11,6 gam. Khi lng Mg phn ng l A. 6,96 B. 25,2 C. 20,88 D. 24 2. Cho 240 ml dung dch Ba(OH)2 1M vo 200 ml dung dch hn hp AlCl3 a mol/l v Al2(SO4)3 2a mol/l thu c 51,3 gam kt ta. a c gi tr l: A. 0,12 B. 0,15 C. 0,16 D. 0,2 3. Oxi ha 9,2 gam ru etylic bng CuO un nng, c 13,2 gam andehit, axit, ru cha phn ng v H2O. Hn hp ny tc dng vi Na d sinh ra 3,36 lt H2 (ktc). Phn trm khi lng ru b oxi ha l? A. 75% B. 25% C. 66,67% D. 33,33% 4. Hn hp kh B gm mt hidrocacbon A v lng H2 d. B c t khi so vi H2 l 4,8. Cho B qua ng cha Ni ri un nng phn ng xy ra hon ton th thu c hn hp kh c t khi hi so vi H2 bng 8. Cng thc phn t ca A l A. C3H4 B. C4H6 C. C4H8 D. C4H10 5. Cho hn hp kh gm NH3 v metylamin c t khi hi so vi CO2 l 0,45. t chy hon ton m gam X bng lng oxi va thu c hn hp gm CO2, hi nc v N2 c khi lng 26,7 gam. Tr s ca m l: A. 19,8 B. 9,9 D. 11,88 D. 5,94 6. Cho mt hp cht ca Fe tc dng vi H2SO4 c, nng sinh ra SO2 (sn phm kh duy nht). Nu t l H2SO4 em dng n H2SO4 : n SO2 4 :1 th cng thc phn t ca X l: A. Fe B. FeS C. FeO D. Fe3O4 7. Hn hp A gm X, Y (MX < MY) l hai este n chc c chung gc axit. un nng m gam A vi 400 ml dung dch KOH 1M d thu c dung dch B v (m 12,6) gam hn hp gm hai andehit no, n chc, ng ng k tip c t khi hi so vi H2 l 26,2. C cn dung dch B thu c (m + 6,68) gam cht rn khan. Phn trm khi lng ca X trong A l A. 54,66 % B. 45,55% C. 36,44% D. 30,37% 8. Hn hp X gm 2 este n chc. Cho 0,5 mol X tc dng vi dung dch AgNO3/NH3 d thu c 43,2g Ag. Cho 14,08g X tc dng vi dung dch KOH va thu c hn hp 2 mui ca 2 axit ng ng lin tip v 8,256g hn hp 2 ancol no n chc ng ng lin tip, mch h. Cng thc ca 2 ancol l: A. C4H9OH v C5H11OH B. CH3OH v C2H5OH C. C2H5OH v C3H7OH D. C3H7OH v C4H9OH 9. Hn hp A gm C3H4 v H2. Cho A i qua ng ng bt Ni nung nng thu c hn hp B ch gm 3 hirocacbon c t khi so vi H2 l 21,5. T khi ca A so vi H2 l: A. 10,4 B. 9,2 C. 7,2 D. 8,6 10. Hn hp X gm Al, FexOy. Tin hnh phn ng nhit nhm hon ton m gam hn hp X trong iu kin khng c khng kh thu c hn hp Y. Chia Y thnh 2 phn. Phn 1 cho tc dng vi dung dch NaOH d thu c 1,008 lt H2 (ktc) v cn li 5,04g cht rn khng tan. Phn 2 c khi lng 29,79gam, cho tc dng vi dung dch HNO3 long d thu c 8,064 lt NO (ktc, l sn phm kh duy nht). Gi tr ca m v cng thc ca oxit st l:
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A. 39,72 gam v FeO B. 39,72 gam v Fe3O4 C. 38,91 gam v FeO D. 36,48 gam v Fe3O4 11. Hn hp X gm CnH2n-1 CHO, CnH2n-1COOH, CnH2n-1 CH2OH (u mch h, n N*). Cho 2,8 gam X phn ng va 8,8 gam brom trong nc. Mt khc, cho ton b lng X trn phn ng vi lng d dung dch AgNO3 trong NH3, kt thc phn ng thu c 2,16 gam Ag. Phn trm khi lng ca CnH2n-1 CHO trong X l A. 26,63%. B. 22,22%. C. 20,00%. D. 16,42%. 12. in phn vi in cc tr dung dch cha 0,2 mol AgNO3 vi cng dng in 2,68 A, trong thi gian t (gi) thu c dung dch X (hiu sut qu trnh in phn l 100%). Cho 16,8 gam bt Fe vo X thy thot ra kh NO (sn phm kh duy nht) v sau cc phn ng hon ton thu c 22,7 gam cht rn. Gi tr ca t l A. 2,00. B. 1,00. C. 0,50. D. 0,25. 13. Cho m gam hn hp M gm hai axit X, Y (Y nhiu hn X mt nhm -COOH) phn ng ht vi dung dch NaOH to ra (m + 8,8) gam mui. Nu cho ton b lng M trn tc dng vi lng d dung dch AgNO3 trong NH3, sau phn ng kt thc thu c 43,2 gam Ag v 13,8 gam mui amoni ca axit hu c. Cng thc ca Y v gi tr ca m ln lt l A. HOCO-COOH v 18,2. B. HOCO-CH2-COOH v 30,0. C. HOCO-CH2-COOH v 19,6. D. HOCO-COOH v 27,2. 14. Hn hp X gm hai este n chc l ng phn ca nhau. un nng m gam X vi 300 ml dung dch NaOH 1M, kt thc phn ng thu c dung dch Y v (m - 8,4) gam hn hp hi gm hai anehit no, n chc, ng ng k tip c t khi hi so vi H2 l 26,2. C cn dung dch B thu c (m - 1,1) gam cht rn. Cng thc ca hai este l A. C2H5COOCH=CH2 v CH3COOCH=CHCH3. B. HCOOCH=CHCH3 v CH3COOCH=CH2. C. HCOOC(CH3)=CH2 v HCOOCH=CHCH3. D. CH3COOCH=CHCH3 v CH3COOC(CH3)=CH2. 15. Hn hp M gm ancol no, n chc, mch h X v ancol khng no, a chc, mch h Y (Y cha 1 lin kt trong phn t v X, Y c cng s mol). t chy hon ton mt lng M cn dng V lt O2 (ktc) sinh ra 2,24 lt CO2 (ktc) v 2,16 gam H2O. Cng thc ca Y v gi tr ca V ln lt l A. C4H6(OH)2 v 3,584. B. C3H4(OH)2 v 3,584. C. C4H6(OH)2 v 2,912. D. C5H8(OH)2 v 2,912. 16. Hn hp X gm KClO3, Ca(ClO3)2, CaCl2 v KCl c tng khi lng l 83,68 gam. Nhit phn hon ton X thu c 17,472 lt O2 (ktc) v cht rn Y gm CaCl2 v KCl. Y tc dng va 0,36 lt dung dch K2CO3 0,5M thu c dung dch Z. Lng KCl trong Z nhiu gp 22/3 ln lng KCl trong X. Phn trm khi lng KClO3 trong X l A. 47,62%. B. 58,55%. C. 81,37%. D. 23,51%. 17. Nung hn hp gm 6,4 gam Cu v 54 gam Fe(NO3)2 trong bnh kn, chn khng. Sau phn ng hon ton thu c hn hp kh X. Cho X phn ng ht vi nc, thu c 2 lt dung dch Y. pH ca dung dch Y l A. 1,3. B. 1. C. 0,664. D. 0,523. 18. Ly 15,660 (g) amin n chc, mch h X (X c khng qu 4 lin kt trong phn t) trn vi 168 lt khng kh (ktc). Bt tia la in t chy hon ton X, hn hp sau phn ng c a v 0 0 C, 1 atm ngng t ht hi nc th c th tch l 156,912 lt. Xc nh s ng phn ca X. A. 2 B. 17 C. 16 D. 8 19. Hn hp X gm Fe v kim loi M c ho tr khng i. Cho 15,2 gam X tc dng vi dung dch HCl d thy tht ra 2,24 lt kh H2 (ktc). Nu cho lng X trn tc dng vi dung dch HNO3 d thu c 4,48 lt kh NO (ktc). Kim loi M l: A. Cu B. Al C. Ag D. Hg 20. Cho m gam hn hp A gm Al4C3 v CaC2 vo nc d thu c dung dch X; 7,8 gam kt ta Y v kh hn hp kh Z. Lc b kt ta. t chy hon ton kh Z ri sc chm sn phm chy vo dung dch X phn ng xy ra hon ton thy xut hin thm 9,984 gam kt ta. Xc nh m? A. 36,928 gam B. 8,904 gam C. 12,304 gam D. 22,512 gam

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21. X l hn hp gm C2H2 v H2 c d X
dY
H2

= 5. un X vi bt Ni mt thi gian thu c hn hp Y c

H2

= 9,375. Ly 0,16 mol Y cho i qua bnh ng Br2 d phn ng xy ra hon ton thy khi

lng bnh dng Br2 tng thm m (g). Kt lun no sau y l chnh xc nht? A. 0,78 m 1,68 B. m = 0,78 C. m = 3,0 D. m= 1,68 22. Tin hnh nhit phn hn hp X gm butan v heptan (t l 1:2 v s mol) th thu c hn hp Y (Gi s ch xy ra phn ng cracking ankan vi hiu sut 100%). Xc nh lng phn t trung bnh ca Y ( M Y )? A. 25,8 M Y 43 B. 32 M Y 43 C. M Y =43 D. 25,8 M Y 32 23. Hn hp X gm Al v Fe3O4. tin hnh nung hn hp X nhit cao thu c hn hp Y. Chia Y lm 2 phn bng nhau. Phn 1 cho vo dung dch NaOH ly d, sau phn ng thu c 1,344 lt kh (ktc). Phn 2 ha tan ht trong 310 ml dung dch H2SO4 1M(long) thu c 3,36 lt kh (ktc). Xc nh hiu sut phn ng nhit nhm. A. 60%. B. 66,67%. C. 75%. D. 80%. 24. Nung nng hn hp X cha 15,8 gam KMnO4 v 24,5 gam KClO3 mt thi gian c 36,3 gam hn hp Y gm 6 cht. cho Y tc dng vi dung dch HCl c d un nng, lng kh clo sinh ra hp th hon ton vo 300 ml dung dch NaOH 5M un nng c dung dch Z. Cc phn ng xy ra hon ton. Tnh khi lng cht rn khan thu c khi c cn Z. A. 111 gam B. 12 gam C. 79,8 gam D. 91,8 gam 25. X l hn hp cc mui Cu(NO3)2, Fe(NO3)2, Fe(NO3)3, Mg(NO3)2. Trong O chim 68 % v khi lng. Cho dung dch KOH d vo dung dch cha 50 gam X. Lc kt ta thu c em nung trong chn khng n khi lng khng i thu c m gam oxit. Gi tr ca m l A. 17,15 B. 39.2 C. 11,75 D. 17.6 26. Nhit phn hon ton m gam hn hp Fe(NO3 )2 v AgNO3 thu c 117,6 lt hn hp kh X. Cho X hp th vo nc d thu c dung dch Y v 5,6 lt mt cht kh thot ra(ktc). % khi lng ca Fe(NO3)2 trong hn hp l A. 34,62%. B. 55,95%. C. 55,667%. D. 34,62% hoc 55,95%. 27. Ly m gam K cho tc dng vi 500ml dung dch HNO3 thu c dung dch M v thot ra 0,336 lt hn hp N (ktc) gm 2 kh X v Y. Cho thm vo M dung dch KOH d th thy thot ra 0,224 lt kh Y. Bit rng qu trnh kh HNO3 ch to mt sn phm duy nht. Xc nh m? A. 3,12 gam. B. 7,8 gam. C. 12,48 gam. D. 6,63 gam. 3 28. Hn hp Y gm hirocacbon X v N2. t 300cm hn hp Y bi 725 cm3 O2 d trong mt kh nhin k, thu c 1100 cm3 hn hp kh v hi. Nu ngng t hi nc th cn li 650 cm3 v sau tip tc li qua KOH th ch cn 200 cm3. Tm CTPT ca X. A. C2H6. B. C3H6. C. C3H8. D. C4H8. 29. Cho 1,52g hn hp hai amin n chc no X, Y (c trn vi s mol bng nhau) tc dng va vi 200ml dung dch HCl, thu c 2,98g mui. Kt lun no sau y khng chnh xc? A. Tn gi 2 amin l imetylamin v etylamin B. Nng dung dch HCl bng 0,2 (M). C. S mol mi cht l 0,02 mol D. Cng thc ca amin l CH5N v C2H7N 30. Hn hp X gm mt s hirocacbon l l ng dng k tip c tng khi lng phn t l 252, trong khi lng phn t ca hirocacbon nng nht c khi lng phn t nng gp 2 ln khi lng phn t ca hirocacbon nh nht. Cng thc phn t ca hirocacbon nh nht trong X l A. C2H2. B. C3H8. C. C2H6. D. C3H6. 31. Ha tan hon ton hn hp X gm 0,11 mol Al v 0,15 mol Cu vo dung dch HNO3 th thu c 1,568 lt (ktc) hn hp Y gm 2 kh (trong c 1 kh khng mu ha nu ngoi khng kh) v dung dch Z cha 2 mui. Xc nh s mol HNO3 tham gia phn ng A. 0,63 mol. B. 0,7 mol. C. 0,77 mol. D. 0,76 mol.

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32. X l hp kim ca 2 kim loi gm kim loi kim M v kim loi kim th R. Ly 28,8 gam X ha tan hon ton vo nc, thu c 6,72 lt H2 (ktc). em 2,8 gam Li luyn thm vo 28,8 gam X th % khi lng ca Li trong hp kim va luyn l 13,29%. Kim loi kim th R trong hp kim X l A. Mg B. Ca C. Ba D. Sr 33. Nung nng 27,3 gam hn hp NaNO3 v Cu(NO3)2 n khi lng khng i, cho ton b kh thot ra tc dng hon ton vi 89,2 gam nc, th c 1,12 lt (ktc) kh khng b hp th. Khi lng ca NaNO3 v Cu(NO3)2 trong hn hp ban u ln lt l? A. 8,5 gam v 18,8 gam B. 10 gam v 17,3 gam C. 16,3 gam v 11 gam D. 17 gam v 10,3 gam 34. t a mol X l trieste ca glixerol v axit n chc, mch h thu c b mol CO2 v c mol H2O, bit b c = 4a. Hiro ha m gam X cn 6,72 lt H2 (ktc) thu c 39 gam X. Nu un m gam X vi dung dch cha 0,7mol NaOH n phn ng sau y c cn dung dch sau phn ng th thu c bao nhiu gam cht rn? A. 57,2 gam B. 53,2 gam C. 61,48 gam D. 52,6 gam 35. Trn 18 gam axit axetic vi 23 gam ancol etylic ri un nng mt thi gian. Sau khi ngui hn hp v tch ring ht este th c hn hp lng X. Cho ton b X tc dng vi Na thu c 6,72 lt H2 (ktc). Vy khi lng este to ra l A. 8,5 B. 17,6 C. 26,4 D. 44 36. Cho hn hp X gm 2 este mch h l ng phn ca nhau. Ly 0,2 mol X cho phn ng hon ton vi 300 ml dung dch NaOH 1M, ri tin hnh chng ct c 8,5 gam hn hp hai ancol ng ng k tip nhau. C cn phn dung dch cn li sau chng ct c cht rn A. Nung A trong oxi d n phn ng hon ton c 22 gam CO2 v 7,2 gam H2O cng 1 lng Na2CO3. Cng thc phn t ca hai este l: A. C2H3COOC2H5 v C3H5COOCH3 B. C2H5COOC2H5 v C3H7COOCH3 C. C2H3COOC3H7 v C3H5COOC2H5 D. C3H5COOC3H7 v C4H6COOC2H5 37. Kt lun no sau y lun lun ng? A. Cc nguyn t phi kim u c electron cui cng in vo phn lp p B. Cc nguyn t nhm B u l kim loi C. Cc kh him u c cu hnh electron lp ngoi cng ns2np6. D. Cc nguyn t nhm A (phn nhm chnh) u l kim loi hoc phi kim. 38. Trng hp no sau y khng tha mn quy tc bt t? A. NH3, HCl B. CO2, SO2 C. PCl5, SF6 D. N2, CO 39. Cho a mol kim loi M (ha tr n khng i) tan va ht trong dung dch cha a mol H2SO4 c 1,56 gam mui A v kh B. Lng kh B c hp th hon ton bi 45 ml dung dch NaOH 0,2 M to thnh 0,608 gam mui. Kh B v kim loi M ln lt l: A. SO2; Cu B. H2S; Mg C. SO2; Ag D. H2S, Al 40. Cho 9,6 gam kim loi R tc dng vi 500 ml dung dch HNO3 c mol/l va , thu c 2,24 lt kh A (sn phm kh duy nht, ktc) v dung dch B . C cn dung dch B thu c 59,2 gam mui khan. A khng th l kh no sau y? A. N2 B. N2O C. NO D. NO2 41. Cho x mol Fe tan hon ton trong dung dch cha y mol HNO3 (x : y = 16 : 61) thu c sn phm kh duy nht v dung dch ch cha mui nitrat. S mol e do lng Fe trn nhng khi b ha tan l: A. 2x B. 3x C. y D. 0,75y 42. C hn hp hai ru n chc A, B (hn hp X). un nng hn hp X vi H2SO4 c 180oC th thu c hn hp hai olefin, cn 140oC th thu c hn hp ete, trong c mt ete c khi lng phn t bng khi lng phn t ca 1 trong hai ru. t chy 0,1 mol X th to ra 1,408 gam CO2. Cng thc phn t ca ru c khi lng phn t nh hn l: A. CH3OH B. C2H5OH C. C3H7OH D. C4H9OH 43. Cho m gam hn hp gm FeO, Fe, Fe3O4, Fe2O3 vo 400 ml dung dch HCl 2M. Sau khi phn ng xy ra hon ton thu c 2,24 lt H2 (ktc), dung dch Y v 2,8 gam cht rn khng tan. Gi tr m l: A. 31,6 B. 30,0 C. 27,2 D. 24,4 44. t chy hon ton mt lng hn hp kh X gm mt ankan v mt anken cn dng va 0,7 mol O2, thu c 0,4 mol CO2. Cng thc ca ankan l
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A. C4H10. B. C3H8. C. C2H6. D. CH4. 45. Hn hp M gm axit cacboxylic X (khng no, n chc, mch h), ancol no, n chc, mch h Y (s mol ca Y ln hn s mol ca X) v este Z c to ra t X v Y. Cho mt lng M phn ng va vi dung dch cha 0,25 mol NaOH thu c 27 gam mui v 9,6 gam ancol. Cng thc ca X v Y l A. C3H7COOH v CH3OH. B. C3H5COOH v CH3OH. C. C3H5COOH v C2H5OH. D. C2H3COOH v C2H5OH. 46. t hn hp gm 0,4 mol Fe v 0,2 mol Cu trong bnh ng kh O2, sau phn ng thu c m gam cht rn. em cht rn ny tc dng vi HCl d, sau khi phn ng hon ton c 3,36 lt kh thot ra ( ktc) v 6,4 gam kim loi khng tan. Gi tr ca m l: A. 44,8 B. 41,6 C. 40,8 D. 38,4 47. Trong s cc cht Fe, FeO, Fe2O3, Fe3O4, Fe(OH)2, FeS, Fe(OH)3, FeS2, FeCO3, FeSO4, Fe2(SO4)3, s cht ph hp vi s : X + H2SO4 (c, nng) Fe2(SO4)3 + SO2 + H2O A. 6 B. 7 C. 9 D. 8 48. Hn hp X gm M2CO3, MHCO3 v MCl (M l kim loi kim). Cho 32,65 gam X tc dng va vi dung dch HCl thu c dung dch Y v c 17,6 gam CO2 thot ra. Dung dch Y tc dng vi dung dch AgNO3 d c 100,45 gam kt ta. Kim loi M l A. Na. B. Li. C. K. D. Rb. 49. Hn hp A gm CH4, C2H4, C3H4. Nu cho 13,4 gam hn hp X tc dng vi dung dch AgNO3/NH3 d th thu c 14,7gam kt ta. Nu cho 16,8 lt hn hp X (ktc) tc dng vi dung dch brom th thy c 108gam brom phn ng. % th tch CH4 trong hn hp X l: A. 30% B. 25% C. 35% D. 40% 50. Ha tan ht 6,08 gam hn hp gm Cu, Fe bng dung dch HNO3 thu c dung dch X v 1,792 lt NO (ktc). Thm t t 2,88 gam bt Mg vo dung dch X n khi phn ng xy ra hon ton thu c 0,448 lt NO (ktc), dung dch Y v m gam cht rn khng tan. Gi tr ca m l : A. 4,96 gam B. 3,84 gam C. 6,4 gam D. 4,4 gam 51. Hn hp A gm mui sunfit, hidrosunfit v sunfat ca cng kim loi kim M. Cho 17,775 gam hn hp A vo Ba(OH)2 d to thnh 24,5725 gam hn hp kt ta. Lc kt ta, ra sch cho tc dng vi HCl d, thy cn 2,33 gam rn. Kim loi kim M l A. Li B. K C. Rb D. Na 52. Cho hn hp Na v Mg d tc dng vi dung dch H2SO4. Lng kh hidro thot ra bng 5% khi lng dung dch H2SO4. Gi s sau phn ng kt thc ch thu c 2 mui trung tnh! Nng % dung dch H2SO4 l? A. 62,3 B. 33,64 C. 67,37 D. 30,01 53. C hp cht MX3. - Tng s ht proton, notron v electron l 196, trong s ht mang in nhiu hn s ht ko mang in l 60. - Khi lng nguyn t ca X ln hn M l 8. - Tng s 3 loi ht trong ion X- nhiu hn trong ion M3+ l 16. X v M ln lt l: A. Cr v Cl B. Mg v Br C. Al v Br D. Al v Cl 54. Chn nhn xt sai? A. Cho KOH vo dung dch mui ng (II) glixerat thu c kt ta B. Khi cho phenol vo dung dch Na2CO3 (d) ta thu c dung dch ng nht C. Benzen c th phn ng cng vi Cl2 thu c hexacloran D. C 4 cht hu c mch h c cng thc phn t C2H2On tc dng vi AgNO3/NH3 thu c kt ta. 55. un nng hn hp 1 mol HCOOH, 1mol CH3COOH v 2 mol C2H5OH trong bnh c th tch khng i n trng thi cn bng thu c 0,6 mol HCOOC2H5 v 0,4 mol CH3COOC2H5. Nu un nng hn hp 1 mol HCOOH, 3 mol CH3COOH v a mol C2H5OH iu kin nh trn thu c 0,8 mol HCOOC2H5. Gi tr ca a l: A.12,88 B.9,97 C.5,6 D.6,64 56. Cho mt lng CaCO3 tc dng hon ton vi dung dch HCl 32,85%. Sau phn ng thu c dung dch X trong nng HCl cn li l 24,20%. Thm vo X mt lng MgCO3 khuy u cho phn
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ng xy ra hon ton thu c dung dch Y trong nng HCl cn li l 21,10%. Nng phn trm cc mui CaCl2 v MgCl2 trong dung dch Y tng ng l: A. 10,35% v 3,54% B. 12,35% v 8,54% C. 12,35% v 3,54% D. 8,54% v 10,35% 57. Hn hp A gm mui cacbonat, hidrocacbonat v clorua ca kim loi kim M. Cho 33,27 g hn hp A tc dng ht vi V (ml) (d) dd HCl 10% (D=1,04g/cm3) thu c dung dch B v 5,6 lt kh C (ktc). Chia dd B thnh 2 phn bng nhau Phn 1 phn ng va vi 125 ml dd KOH 0,2M, c cn dung dch sau phn ng thu c m (gam) mui khan Phn 2 p hon ton vi dd AgNO3 d thu c 33,005 kt ta Kim loi M l: A. Li B. K C. Rb D. Na 58. Cho m gam bt Cu vo 200 ml dung dch AgNO3 0,2M, sau phn ng thu c 3,88 gam cht rn X v dung dch Y. Cho 2,925g bt Zn vo dung dch Y sau phn ng thu c 5,265 gam cht rn Z v dung dch ch cha 1 mui duy nht. Gi tr ca m l: A.3,17 B.2,56 C.1,92 D.3,2 59. in phn c vch ngn xp 500ml dd hn hp HCl v 7,8 g mui clorua ca kim loi M thy anot c kh Cl2 bay ra lin tc, catot lc u c kh H2 bay ra, sau n kim loi M thot ra. Sau khi in phn, thu c 2,464 lit kh Cl2 v m gam M. em trn m g M vi 1,3g kim loi N khc, ri cho tc dng vi dd H2SO4 d th V lt H2 bay ra nhiu gp 4 ln so vi khi ch c 1,3g N tc dng. Bit khi trn 1,3g N vi S ri nung nng c cht rn C v khi cho C phn ng ht vi dd H2SO4 d th c hn hp kh D nng 0,52g v c t khi so vi H2 l 13. M v N ln lt l: A. Cu v Ni B. Zn v Sn C. Fe v Cu D. Zn v Ni 60. Cho glucozo ln men vi hiu sut 70%, hp th ton b sn phm kh thot ra cho vo 1 lt dung dch NaOH 1,5M (D = 1,0505 g/ml) thu c dung dch cha 2 mui vi tng nng l 8,68%. Khi lng glucozo dng l: A. 129,68 g B. 168,29 g C. 128,57 g D. 186,92 g 61. Kim loi X c bn knh nguyn t r = 0,1445 nm. Bit rng trong tinh th cc nguyn t chim 74% th tch, cn li l cc khe rng. Tm kim loi X bit tinh th X c khi lng ring = 10,5 gam/cm3 (cho NA = 6,023.1023 v = 3,14). A. Au B. Ag C. Zn D. Cu 62. Nung nng m gam hn hp A gm FexOy v Al. Sau khi phn ng xong (hiu sut 100%) ta c cht rn B. Cho B tc dng va ht 280ml dung dch NaOH 1M thy c 6,72 lt H2 (ktc) bay ra v cn li 5,04 gam cht rn. Cng thc ca oxit st v gi tr m ln lt l : A. Fe3O4 v 14,52g B. Fe3O4 v 13,92g C. Fe2O3 v 14,52g D. FeO v 6,48g 63. Cho bt kim loi M vo 100 ml dd Fe2(SO4)3 0,1M. Sau phn ng c cn phn dung dch thu c 4 g cht rn. M l : A.Zn B.Cu C.Mg D.Ni 64. Nhng thanh kim loi R (ho tr II) c khi lng 9,6g vo dung dch cha 0,24 mol Fe(NO3)3. Sau mt thi gian ly thanh kim loi ra, dung dch c khi lng bng khi lng dung dch ban u. Thanh kim loi sau em ho tan bng dung dch HCl d th thu c 6,272 lt H2 (kc). Kim loi R v khi lng Fe thu c ln lt l A. Zn v 4,48g B. Mg v 4,48g C. Mg v 5,04g D. Zn v 7,78g o 65. un nng hn hp 3 ru X,Y,Z vi H2SO4 c 170 C thu c hn hp 2 anken l ng ng lin tip. Ly 2 trong s 3 ru trn un vi H2SO4 c 140oC thu c 1,32g hn hp gm 3 ete. Mt khc lm bay hi 1,32g hn hp gm 3 ete ny c th tch ng bng th tch ca 0,48g oxi (o cng iu kin). Nu t ht ton b 1,32g hn hp ete trn ri cho ton b CO2 sinh ra vo 250 ml dung dch Ba(OH)2 nng C (mol/l) thu c 9,85g kt ta. Gi tr C l: A.0,1 B.0,2 C.0,25 D.0,5
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66. t chy hon ton m gam hn hp X gm metylamin, imetylamin v etylmetylamin bng O2 va , sau dn sn phm chy qua dung dch H2SO4 c d thy khi lng dung dch tng 11,52g v c 10,752 lt hn hp kh thot ra. Mt khc, trung ho dung dch cha m gam hn hp X cn dng V lt dung dch V (lt) HCl 1M. Gi tr ca V l: A. 0,3 B. 0,2 C. 0,1 D. 0,05 67. Cho C0 i qua ng s cha 0,12 mol hn hp FeO, Fe2O3 nung nng, phn ng to 0,138 mol CO2. Hn hp cht rn cn li trong ng nng 14,352 gam gm 4 cht. Ho tan ht hn hp trong HNO3 d thu V lt kh NO (sn phm kh duy nht). Gi tr ca V l: A.0,672 B. 0,224 C. 2,2848 D. 6,854 68. Nhit phn hon ton m gam hn hp X gm: NaNO3, Cu(NO3)2, Al(NO3)3 thu c 8 gam cht rn Y v hn hp kh Z. Hp th kh Z vo 89,2 gam nc c dung dch axit c nng 12,6% v c 0,448 lt kh (ktc) duy nht thot ra. Phn trm khi lng ca NaNO3 trong X l: A. 17,49% B. 8,75% C. 42,5% D. 21,25% 69. Cho hn hp X gm a mol Mg, b mol Fe, c mol Zn, v b mol Cu. Thc hin cc th nghim: Th nghim 1: Cho X tc dng vi dung dch HCl (va ) thu c dung dch Y v cht rn Z v 6,72 lt kh hidro (ktc). Cho thanh Zn vo Y n khi phn ng hon ton thy khi lng thanh gim 1,8 g. Th nghim 2: Cho X vo dung dch HNO3 d thu c V lt NO (sn phm kh duy nht) (ktc). Gi tr ca V l: A. 6,72 lt B. 4,48 lt C. 8,96 lt D. 11,2 lt 70. Trong bnh kn dung tch V lt khng i c cha 1,3a mol O2 v 2,5a mol SO2 ( 100oC, 2 atm, c mt xc tc V2O5). Nung nng bnh mt thi gian sau lm ngui ti 100oC, p sut trong bnh lc ny l p. Hiu sut phn ng l h. Mi lin h gia p v h c biu th bng biu thc no? 2,5h 1, 25h ) ) A. p 2.(1 B. p 2.(1 3,8 3,8 0, 65h 1,3h ) ) C. p 2.(1 D. p 2.(1 3,8 3,8 71. Ha tan hon ton 80 gam hn hp X gm CuSO4, FeSO4, Fe2(SO4)3 (trong S chim 22,5% v khi lng) vo trong nc thu c dd X. Thm NaOH d vo dung dch X lc kt ta em nung trong khng kh n khi lng khng i thu c cht rn Y. Thi CO d qua Y thu c hn hp rn Z. Bit cc phn ng xy ra hon ton. Khi lng Z l: A. 30 gam B. 40 gam C. 26 gam D. 36 gam 72. Cho 0,4 mol hn hp gm 2 ancol no n chc, bc 1 l ng ng k tip un nng vi H2SO4 c 140oC thu c 7,704 gam hn hp 3 ete. Tham gia phn ng ete ha c 50% lng ancol c khi lng phn t nh v 40% khi lng ancol c khi lng phn t ln. Tn gi ca 2 ancol trong X l: A. propan-1-ol v butan-1-ol B. etanol v propan-1-ol C. pentan-1-ol v butan-1-ol D. metanol v etanol 73. Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh (gm 20% th tch O2 v 80% th tch N2) n khi phn ng xy ra hon ton, thu c cht rn v hn hp kh Y c thnh phn th tch: N2 = 84,77%; SO2 = 10,6% cn li l O2. Thnh phn % theo khi lng ca FeS trong X l A. 68,75% B. 59,46% C. 26,83% D. 42,3% 74. Nung m gam hn hp X gm KClO3 v KMnO4 thu c cht rn Y v O2. Bit KClO3 phn hy hon ton, cn KMnO4 ch b phn hy mt phn. Trong Y c 0,894 gam KCl chim 8,132% theo khi lng. Trn lng O2 trn vi khng kh theo t l th tch VO2 : VKK =1:3 trong mt bnh kn ta thu c hn hp kh Z. Cho vo bnh 0,528 gam cacbon ri t chy ht cacbon, phn ng hon ton, thu c hn hp kh T gm 3 kh O2, N2, CO2, trong CO2 chim 22,92% th tch. Gi tr m (gam) l A. 12,59 B. 12,53 C. 12,70 D. 12,91 75. Phn ng no sau y sai. A. 2HI + Cu CuI2 + H2 B. 2HBr + 2FeCl3 2FeCl2 + Br2 + 2HCl
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C. H2O2 + KNO2 H2O + KNO3

D. 2SO2 + O2 2SO3 76. Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3, Fe3O4 phn ng ht vi dung dch HNO3 long d thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. Dung dch X c th ha tan ti a 12,88 gam Fe. S mol HNO3 c trong dung dch u l A. 1,04 mol B. 0,64 mol C. 0,94 mol D. 0,88 mol 77. Cho 12,12 gam hn hp X gm Al v Fe tc dng vi dung dch HCl d thu c dung dch A v kh H2. C cn dung dch A thu c 41,94 gam cht rn khan. Nu cho 12,12 gam X tc dng vi dung dch AgNO3 d thu c bao nhiu gam kim loi? A. 82,944 gam B. 103,68 gam C. 90,72 gam D. 108 gam 78. Hai hp cht X, Y l hai ancol, trong khi lng mol ca X nh hn Y. Khi t chy hon ton mi cht X, Y u to ra s mol CO2 t hn s mol H2O. t chy hon ton hn hp Z gm nhng lng bng nhau v s mol ca X, Y thu c t l s mol CO2 : H2O = 2 : 3. S hp cht tho mn: A. 2 B. 4 C. 5 D. 6 79. Cho a mol kim loi M (ha tr khng i) tan va ht trong dung dch cha 5a/4 mol H2SO4 c 19,32 gam mui A v kh B. Lng kh B c hp th hon ton bi 250 ml dung dch NaOH 0,2 M to thnh 2,12 gam mui. Kim loi M l A. Na B. Cu C. Zn D. Al 80. Cho m gam hn hp bt gm Fe, Cu v Fe2O3 tc dng va vi dung dch HCl (lng dung dch HCl dng ti thiu) thu c dung dch A gm FeCl2 v CuCl2 vi s mol FeCl2 bng 9 ln s mol CuCl2 v 5,6 lt H2 (ktc) khng cn cht rn khng tan. C cn dung dch A thu c 127,8 gam cht rn khan. m c gi tr l : A.68,8 gam B.74,4 gam C. 75,2 gam D. 61,6 gam 81. Oxi ha mt ru n chc A bng O2 (c cht xc tc) thu c hn hp X gm andehit, axit, nc v ru d. Ly m gam hn hp X cho tc dng va ht vi Na thu c 8,96 lt H2 (ktc) v dung dch Y. Cho Y bay hi th cn li 48,8 gam cht rn. Mt khc 4m gam hn hp X cho tc dng vi Na2CO3 d th thu c 8,96 lt kh (ktc). Bit s mol ru d nh hn s mol ru to andehit. Cng thc phn t ca ru l A. C2H5OH B. CH3OH C. C3H7OH D. C3H5OH 82. Cho hn hp A gm: mt ancol X no n chc v mt ancol Y khng no, c mt ni i, n chc. Bm 8 gam oxi vo bnh B. Sau khi bt tia la in t 0,05 mol hn hp A th to ra 0,35 mol hn hp sn phm kh. Cho sn phm chy vo Ba(OH)2 d th to ra 23,64 gam kt ta. Cng thc phn t ca ancol X l: A. C3H7OH B. CH3OH C. C2H5OH D. C4H9OH 83. t chy 2,24 lt hn hp 3 hidrocacbon A, B, C c hn hp sn phm X. Cho X ln lt i qua bnh 1 ng H2SO4 c v bnh 2 ng KOH thy khi lng bnh 1 tng 4,05 gam v bnh 2 tng 6,16 gam. Bit B, C c cng s nguyn t Cacbon v s mol A gp 4 ln tng s mol ca B v C. Cng thc phn t ca B l: A. C4H8 B. C3H8 C. C3H6 D. C3H4 84. Hn hp X gm mt axit hu c A no, mch h, hai ln axit v mt axit B khng no (c mt ni i), mch h, n chc. S nguyn t cacbon trong cht ny gp i cht kia. t chy hon ton 5,08 gam hn hp X c 4,704 lt kh CO2 (ktc). Nu trung ha ht 5,08 gam X cn 350 ml dung dch NaOH 0,2M c hn hp mui Y. Phn trm khi lng ca A, B ln lt l: A. 57,48% v 42,52% B. 40,94% v 59,06% C. 55,00% v 45,00% C. 37,5% v 62,5% 85. Oxi ha 38 gam hn hp propanal, ancol A no n chc bc 1 v este B (to bi mt axit ng ng ca axit acrylic v ancol A) c hn hp gm X axit v este. Cho lng hn hp X trn phn ng vi CH3OH (hiu sut 50%) thu c hn hp este. Mt khc, cho lng X phn ng vi 0,5 lt dung dch NaOH 1,5 M th sau phn ng trung ha ht NaOH d cn 0,15 mol HCl c dung dch D. C cn D c hi cht hu c E, cn li 64,775 gam hn hp mui. Cho E tch nc 140oC (H2SO4 c xc tc) c F c t khi vi E l 1,61. A v B ln lt l: A. C2H5OH v C3H5COOC2H5 B. CH3OH v C4H7COOCH3
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V2O5 , t o

C. CH3OH v C3H5COOCH3 D. C2H5OH v C4H7COOC2H5 86. Cho 13,32 gam hn hp Zn v ZnO tan hon ton trong dung dch cha 0,38 mol H2SO4 thu c mt sn phm duy nht v dung dch ch cha mui sunfat. S mol sn phm kh thu c l: A. 0,19 B. 0,18 C. 0,16 D. 0,20 87. t chy hon ton 14,2 gam mt hn hp X gm mt ankan v mt anken. Cho hn hp sn phm chy i qua ln lt bnh 1 cha H2SO4 m c v bnh II cha dung dch NaOH (va hp th ton b kh i vo)0, thy khi lng ca bnh I tng 19,8 gam, khi lng bnh II tng 44 gam. Bit 14,2 gam hn hp kh X c th tch bng th tch ca 9,6 gam O2 cng iu kin nhit , p sut. Cng thc phn t ca ankan v anken trong hn hp X ln lt l : A. CH4 v C5H10 B. C2H6 v C4H8 C. C3H8 v C2H4 D. C4H10 v C3H6 88. Mt hn hp gm Al2(SO4)3 v K2SO4, trong s nguyn t oxi chim 20/31 tng s nguyn t c trong hn hp. Ha tan hn hp trn vo nc ri cho tc dng vi dung dch BaCl2 d, hi khi lng kt ta thu c gp bao nhiu ln khi lng hn hp ban u A. 1,488 B. 1,588 C. 1,688 D. 1,788 89. Cho 50 gam hn hp Fe3O4, Cu, Mg tc dng vi dung dch HCl d, sau phn ng thu c 2,24 lt kh H2 (ktc) v cn li 18 gam cht rn khng tan. Phn trm khi lng Fe3O4 trong hn hp ban u l: A. 25,92 B. 46,4 C. 52,9 D. 59,2 90. Ha tan hon ton 3,2 gam mt kim loi ha tr II vo axit sunfuric c, nng. Lng kh SO2 thot ra (duy nht) c hp th ht bi 45 ml dung dch NaOH 2M cho dung dch cha 6,08 gam mui. Kim loi c ha tr II ni trn l: A. Fe B. Cu C. Ca D. Mg 91. Trong cc cht:Cl2, MnSO4, HCl, FeCl3, Fe(NO3)2, Cu(NO3)2, FeSO4, Fe2(SO4)3. S cht c c tnh oxi ha v tnh kh l: A. 6 B. 7 C. 5 D. 4 92. Cho 12,4 gam hn hp gm mt kim loi kim v oxit ca n tc dng vi dung dch HCl d th thu c 27,75 g mui khan. Kim loi kim th l: A. Ba B. Mg C. Ca D. Sr 93. Cho 11,15 gam hn hp gm 2 kim loi Al v kim loi kim M vo trong nc. Sau phn ng thu ch c dung dch B v 9,52 lt kh (ktc). Cho t t dung dch HCl vo dung dch B thu c mt lng kt ta ln nht. Lc v cn kt ta c 15,6 gam. Kim loi kim l: A. Li B. Na C. K D. Rb 94. Ha tan m gam hn hp Ba, Al vo nc thu c dung dch A ch cha mt cht tan duy nht v 12,544 lt H2 (ktc) khng cn cht rn khng tan. Thi CO2 d vo dung dch A thu c kt ta B v dung dch C. un dung dch C n khi phn ng hon ton thu c kt ta D. Ly kt ta B trn vi kt ta D ri em nung trong khng kh n khi lng khng i thu c cht rn E. Khi lng ca E l: A. 35,70 gam B. 38,76 gam C. 49,78 gam D. 38,25 gam 95. Dung dch A gm NaOH 1M v Ba(OH)2 0,5M. Dung dch B gm AlCl3 1M v Al2(SO4)3 0,5M. Cho V1 lt dung dch A vo V2 lt dung dch B thu c 56,916 gam kt ta. Nu cho dung dch BaCl2 d vo V2 lt dung dch B th thu c 41,94 gam kt ta. T l V1/V2 no sau y l ng? A. 0,256 hoc 3,6 B. 0,338 hoc 3,2 C. 0,256 hoc 3,2 D. 0,338 hoc 3,6 96. Cho 21,52 gam hn hp A gm kim loi M ha tr 2 v mui nitrat ca kim loi vo bnh kn ri nung n nhit cao phn ng hon ton. Sn phm thu c l oxit kim loi ha tr 2. Chia cht rn cn li trong bnh sau phn ng lm hai phn bng nhau. Phn 1 phn ng va ht vi 2/3 lt dung dch HNO3 0,38M gii phng kh NO duy nht. Phn 2 phn ng va ht vi 0,3 lt dung dch H2SO4 0,2M (long) thu c dung dch B. Kim loi M l: A. Fe B. Mg C. Ca D. Cu 97. Cho m gam Al ha tan va ht trong dung dch NaOH c dung dch X. Cho m gam Al2O3 ha tan va ht trong dung dch HCl thu c dung dch Y. Trn dung dch X v dung dch Y thu c 5,304 gam kt ta v dung dch Z. C cn dung dch Z thu c bao nhiu gam cht rn khan? A. 5,4885 B. 4,3185 C. 5,6535 D. 3,8635
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98. C bao nhiu cht hu c mch h c cng thc phn t l C2H2On tc dng vi AgNO3/NH3 thu c kt ta? A. 2 B. 3 C. 4 D. 5 99. trung ho m gam hn hp X gm hai axit no, n chc, mch h k tip nhau trong dy ng ng cn dung 100ml dung dch NaOH 0,3 M. Mt khc t chy m gam X ri cho ton ban phm chy ln lt qua bnh (1) ng P2O5, bnh (2) ng dung dch KOH d thy khi lng bnh (1) tng a gam, bnh (2) tng (3,64+ a) gam. Thnh phn % v khi lng ca Axit c nguyn t Cacbon nh hn trong X l A. 33,33% B. 66,67% C. 30,14% D. 69,86% 100. Hn hp kh X gm trimetylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 650 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 350 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t ca hai hirocacbon l A. C3H8 v C4H10 B. C2H4 v C3H6 C. C3H6 v C4H8 D. C2H6 v C3H8

Su tm v bin son bi lemongrass.31.08@gmail.com

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Chun b cho k thi tuyn sinh i hc & Cao ng nm 2012

MT S BI TP MI V HAY TRONG MA THI TH 2011

P N 1 B 21 A 41 D 61 B 81 A 2 C 22 A 42 B 62 B 82 C 3 A 23 C 43 B 63 C 83 B 4 A 24 A 44 D 64 C 84 A 5 B 25 C 45 C 65 C 85 A 6 C 26 D 46 C 66 C 86 B 7 C 27 B 47 B 67 C 87 D 8 C 28 A 48 B 68 A 88 C 9 D 29 D 49 A 69 C 89 B 10 B 30 D 50 D 70 B 90 B 11 C 31 C 51 B 71 C 91 B 12 B 32 A 52 C 72 B 92 C 13 C 33 D 53 B 73 B 93 B 14 B 34 B 54 A 74 A 94 A 15 C 35 A 55 B 75 B 95 B 16 C 36 A 56 A 76 C 96 D 17 B 37 B 57 B 77 B 97 B 18 C 38 C 58 C 78 C 98 C 19 B 39 C 59 D 79 C C 20 A 40 A 60 C 80 A B

99 100

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