CHUYN ESTE

Cu 1: un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng thu c 11 gam este. Hiu sut ca phn ng este ho l A. 50%. B. 75%. C. 55%. D. 62,5%. Cu 2: Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy gm 4,48 lt CO2 (ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dd NaOH va dn khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l A. isopropyl axetat. B. etyl axetat. C. metyl propionat. D. etyl propionat. Cu 3: Cho cht X tc dng vi mt lng va dd NaOH, sau c cn dd thu c cht rn Y v cht hu c Z . Cho Z tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3 th c cht hu c T. Cho cht T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l A. CH3COOCH=CH2. B. HCOOCH=CH2. C. HCOOCH3. D. CH3COOCH=CH-CH3. Cu 4: Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch KOH 1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to ca X l A. CH2=CH-COO-CH2-CH3. B. CH3 -COO-CH=CH-CH3. C. CH2=CH-CH2-COO-CH3. . CH3-CH2-COO-CH=CH2. Cu 5: (C.A-2008) X phng ho hon ton 22,2 gam hn hp gm hai este HCOOC2H5 v CH3COOCH3 b ng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l: A. 400 ml. B. 200 ml. C. 300 ml. D. 150 ml. Cu 6: un nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH (c H2SO4 lm xc tc, hiu sut phn ng este ho bng 50%). Khi lng este to thnh l: A. 8,8 gam. B. 6,0 C. 5,2 gam. D. 4,4 gam. Cu 7: Cho 20 gam mt este X (c phn t khi l 100 vC) tc dng vi 300 ml dung dch NaOH 1M. Sau phn ng, c cn dung dch thu c 23,2 gam cht rn khan. Cng thc cu to X l A. CH2=CHCH2COOCH3. B. CH3COOCH=CHCH3. C. C2H5COOCH=CH2. D. CH2=CHCOOC2H5. Cu 8: Hn hp Z gm hai este X v Y to bi cng mt ancol v hai axit cacboxylic k tip nhau trong dy ng ng (MX < MY). t chy hon ton m gam Z cn dng 6,16 lt kh O 2 (ktc), thu c 5,6 lt kh CO2 (ktc) v 4,5 gam H2O. Cng thc este X v gi tr cc m tng ng l A. CH3COOCH3 v 6,7 B. HCOOC2H5 v 9,5 C. HCOOCH3 v 6,7 D. (HCOO)2C2H4 v 6,6 Cu 9: (A-2010)Cho 45 gam axit axetic phn ng vi 69 gam ancol etylic (xc tc H2SO4 c), un nng, thu c 41,25 gam etyl axetat. Hiu sut cc phn ng este ho l A. 62,50% B. 50,00% C. 40,00% D. 31,25% Cu 10: Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v hai Loi axit bo. Hai loi axit bo l A. C15H31COOH v C17H35COOH. B. C17H33COOH v C15H31COOH. C. C17H31COOH v C17H33COOH. D. C17H33COOH v C17H35COOH. Cu 11: (A-2007)X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng Xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l A. 8,56 gam. B. 3,28 gam. C. 10,4 gam. D. 8,2 gam. Cu 12: (A-2007)Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut cc phn ng este ho u bng 80%). Gi tr cc m l A. 10,12. B. 6,48. C. 8,10. D. 16,20. Cu 13: Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit ) A. 0,342. B. 2,925. C. 2,412. D. 0,456. Cu 14: Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va vi 100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu gn X l A. CH3OOC(CH2)2COOC2H5. B. CH3COO(CH2)2COOC2H5. C. CH3COO(CH2)2OOCC2H5. D. CH3OOCCH2COOC3H7. Cu 15: X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng phn t x phng l A. 17,80 gam. B. 18,24 gam. C. 16,68 gam. D. 18,38 gam. Cu 16: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dHch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol (ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn
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phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l A. CH3COOH v CH3COOC2H5. B. C2H5COOH v C2H5COOCH3. C. HCOOH v HCOOC2H5. D. HCOOH v HCOOC3H7. Cu 17: Este X (c khi lng phn t bng 103 vC) iu ch t mt ancol n chc(c t khi hi so vi oxi ln hn1) v mt amino axit cho 25,75X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l A.27,75 B.24,25 C.26,25 D.29,75 Cu 18: (A-2008) Este X c cc c im sau: - t chy hon ton X to thnh CO2 v H2O c s mol bng nhau; - Thy phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s nguyn t cacbon bng mt na s nguyn t cacbon trong X). Pht biu khng ng l: A. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O. B. Cht Y tan v hn trong nc. C. Cht X thuc loi este no, n chc. D. un Z vi dung dch H2SO4 c 170oC thu c anken. Cu 19 : (A-2009)X phng ha hon ton 66,6 gam hn hp hai este HCOOC2H5 v CH3COOCH3 Bng dung dch NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H2SO4 c 1400C sau khi phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l A. 18,00. B. 8,10. C. 16,20. D. 4,05. Cu 20: (A-2009) X phng ha hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca hai este l A. HCOOCH3 v HCOOC2H5. B. C2H5COOCH3 v C2H5COOC2H5. C. CH3COOC2H5 v CH3COOC3H7. D. CH3COOCH3 v CH3COOC2H5. Cu 21: (A-2009)Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X tc dng va ht vi dung dch NaOH, thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc ca X l A. CH3COOC(CH3)=CH2. B. HCOOC(CH3)=CHCH3. C. HCOOCH2CH=CHCH3 D. HCOOCH=CHCH2CH3. Cu 22: Hp cht hu c mch h X c cng thc phn t C6H10O4. Thy phn X to ra hai ancol n chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l A. CH3OCO-CH2-COOC2H5. B. C2H5OCO-COOCH3. C. CH3OCO-COOC3H7. D. CH3OCO-CH2-CH2-COOC2H5. Cu 23: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X cn 40 ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO 2 (ktc) v 11,7 gam H2O. S mol ca axit linoleic trong m gam hn hp X l A. 0,015. B. 0,010. C. 0,020. D. 0,005. Cu 25: Thy phn hon ton 0,2 mol mot este E cn dng va 100 gam dung dch NaOH 24%, thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l A. HCOOH v C2H5COOH. B. HCOOH v CH3COOH. C. C2H5COOH v C3H7COOH. D. CH3COOH v C2H5COOH. Cu 26. Thy phn 1 mol este X cn 2 mol KOH. Hn hp sn phm thu c gm glixerol, axit axetic v axit propionic. C bao nhiu CTCT tha mn vi X? A. 2 B. 4 C. 6 D. 12 Cu 27. t chy este X to ra CO2 v H2O vi s mol nh nhau. Vy X l: A. este n chc B. este no, a chc C. este no, n chc D. este c mt ni i, n chc Cu 28: Cht hu c (A) cha C, H, O. Bit rng (A) tc dng c vi dung dch NaOH, c cn c cht rn (B) v hn hp hi (C), t (C) chng ct c (D), (D) tham gia phn ng trng gng cho sn phm (E), (E) tc dng vi NaOH li thu c (B). Cng thc cu to ca (A) l: A. HCOOCH2-CH=CH2 B. HCOOCH=CH-CH3 C. HCOOC(CH3)=CH2 D. CH3COOCH=CH2 Cu 29: Cho 0,0125 mol este n chc M vi dung dch KOH d thu c 1,4 gam mui.T khi ca M i vi CO 2 bng 2. M c cng thc cu to l: A. C2H5COOCH3 B. CH3COOC2H5 C. HCOOC3H7 D. C2H3COOCH3 Cu 30. Hai este X, Y l ng phn ca nhau. 17,6 gam hn hp ny chim th tch bng th tch ca 6,4 gam oxi cng iu kin. Hai este X, Y l: A. CH3COOCH3 v HCOOC2H5 B. CH3COOC2H5 v HCOOC3H7 C. HCOOC3H7 v C3H7COOH D. CH3COOCH3 v CH3COOC2H5 Cu 31: Mnh khng ng l:
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A. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3. B. CH3CH2COOCH=CH2 tc dng vi dung dch NaOH thu c anehit v mui. C. CH3CH2COOCH=CH2 tc dng c vi dung dch Br2. D. CH3CH2COOCH=CH2 c th trng hp to polime. Cu 32: X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l (cho H = 1, C = 12, O = 16, Na = 23) A. 8,56 gam. B. 3,28 gam. C. 10,4 gam. D. 8,2 gam. Cu 33: Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm hu c X v Y. T X c th iu ch trc tip ra Y. Vy cht X l A. ru metylic. B. etyl axetat. C. axit fomic. D. ru etylic Cu 34: Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l (cho H = 1, C = 12, N = 14, O = 16) A. HCOOC2H5 v CH3COOCH3. B. C2H3COOC2H5 v C2H5COOC2H3. C. C2H5COOCH3 v HCOOCH(CH3)2. D. HCOOCH2CH2CH3 v CH3COOC2H5. Cu 35: Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2 phn ng. Tn gi ca este l A. n-propyl axetat. B. metyl axetat. C. etyl axetat. D. metyl fomiat. Dng cho cu 36, 37, 38: Hn hp X gm 2 este n chc trong s mol este ny gp 3 ln s mol este kia. Cho a gam X tc dng ht vi NaOH thu c 5,64g mui ca 1 axit hu c n chc v 3,18 gam hn hp Y gm 2 ru no, n chc, u to olefin. Nu t chy ht Y th thu c 3,36 lt kh CO2 (ktc). Cu 36: S nguyn t cacbon ca 2 ru trong Y l A. 1 v 2. B. 2 v 3. C. 2 v 4. D. 3 v 4. Cu 37: Gi tr ca a l A. 6,42. B. 6,24. C. 8,82. D. 8,28. Cu 38 : Tn gi ca axit to 2 este trong X l A. axit fomic. B. axit axetic. C. axit acrylic. D. axit metacrylic. Dng cho cu 39, 40, 41: Cho m gam mt este n chc X tc dng hon ton vi 500 ml dung dch KOH 0,24 M ri c cn thu c 10,5 gam cht rn khan Y v 5,4 gam ru Z. Cho Z tc dng vi CuO nung nng, thu c anehit T (h=100%). Thc hin phn ng trng gng hon ton vi T thu c 19,44 gam Ag. Cu 39: Tn gi ca Z l A. butan-2-ol. B. propan-2-ol. C. butan-1-ol. D. propan-1-ol. Cu 40: Gi tr ca m l A. 8,24. B. 8,42. C. 9,18. D. 9,81. Cu 41: Tn gi ca X l A. n-propyl axetat. B. n-butyl fomiat. C. iso-propyl axetat. D. iso-butyl axetat. Cu 42: Thu phn hon ton 0,1 mol este E (ch cha 1 loi nhm chc) cn va 100gam dung dch NaOH 12%, thu c 20,4gam mui ca mt axit hu c v 9,2gam mt ru. Bit 1 trong 2 cht (ru hoc axit) to E l n chc. Cng thc ca E A. (C2H3COO)3C3H5. B. (HCOO)3C3H5. C. C3H5(COOC2H5)3. D. C3H5(COOCH3)3. Dng cho cu43, 44, 45: un nng a gam mt hp cht hu c X mch thng (cha C, H, O) vi dung dch cha 11,2g KOH n khi phn ng hon ton thu c dung dch B. trung ho KOH d trong B cn 80 ml dung dch HCl 0,5 M v thu c 7,36g hn hp 2 ru n chc v 18,34g hn hp 2 mui. Cu 43: Cng thc ca 2 ru to X l A. C2H5OH v C3H5OH. B. C3H5OH v CH3OH. C. CH3OH v C3H7OH. D. C3H7OH v C2H5OH. Cu 44: Cng thc ca axit to X l A. HOOC-COOH. B. HOOC-[CH2]4-COOH. C. HOOC-CH=CH-COOH. D. HOOC-CH2-CH=CH-CH2-COOH. Cu 45: Gi tr ca a l A. 11,52. B. 14,50. C. 13,76. D. 12,82. Dng cho cu 46, 47, 48, 49: un nng 0,1 mol este no, n chc E vi dung dch cha 0,18 mol MOH (M l kim loi kim). C cn dung dch sau phn ng, thu c m gam cht rn A v 4,6 g ru B. t chy A thu c 9,54 g M 2CO3 v 4,84 gam CO2 v a gam H2O. Cu 46: Kim loi kim M l A. Li. B. Na. C. K. D. Rb. Cu 47: Tn gi ca E l A. etyl axetat. B. etyl fomiat. C. metyl axetat. D. metyl fomiat. Cu 48: Gi tr ca m l
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A. 14,1. B. 22,3. C. 11,4. D. 23,2. Cu 49: Gi tr ca a l A. 3,42. B. 2,70. C. 3,60. D. 1,44. Dng cho cu 50, 51: un nng 7,2 gam A (l este ca glixerin) vi dung dch NaOH d, phn ng kt thc thu c 7,9 gam hn hp mui ca 3 axit hu c no, n chc mch h D, E, F; trong E, F l ng phn ca nhau, E l ng ng k tip ca D. Cu 50: A c s lng ng phn l A. 2. B. 3. C. 4. D. 5. Cu 51: Tn gi ca axit c khi lng phn t nh nht to A l A. axit fomic. B. axit axetic. C. axit propionic. D. axit butyric. Dng cho cu 52, 53, 54: Cho 0,1 mol mt este X tc dng va vi 100ml dung dch NaOH 2M thu c hn hp 2 mui ca 2 axit hu c mch h Y, Z u n chc v 6,2 gam mt ru T. Axit Y no, khng tham gian phn ng trng gng. Axit Z khng no, ch cha mt lin kt i (C=C), c mch cacbon phn nhnh. t chy ht hn hp hai mui thu c trn to ra H2O, m gam Na2CO3, v 0,5 mol CO2. Cu 52: Tn gi ca T l A. etan-1,2-iol. B. propan-1,2-iol. C. glixerol. D. propan-1-ol. Cu 53: Gi tr ca m l A. 21,2. B. 5,3. C. 10,6. D. 15,9. Cu 54: Tn gi ca Y l A. axit propionic. B. axit axetic. C. axit butyric. D. axit iso butyric. Cu 55 (B-07): X l mt este no n chc, c t khi hi so vi CH 4 l 5,5. Nu em un 2,2 gam X vi dung dch NaOH d th thu c 2,05g mui. Cng thc cu to thu gn ca X l A. CH3COOC2H5. B. HCOOCH2CH2CH3. C. C2H5COOCH3. D. HCOOCH(CH3)3. Cu 56 (B-07): Thu phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm X v Y. t X c th iu ch trc tip ra Y. Vy cht X l A. ru metylic. B. etyl axetat. C. axit fomic. D. ru etylic.

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