Trung Tm Bi Dng HSPHN

ANDEHIT XETON S 2 ( Thi gian 45 pht)

Cu 26 : Hn hp X gm 2 andehit A v B . Oxi ho 7,2 gam hn hp X bng dung dch AgNO3 d trong NH3 sau axit ho thu c 2 axit tng ng . Trung ho ht lng axit bng dung dch NaOH , sau nung nng hn hp vi vi ti xt thu c 3,36 lt hn hp kh , cho hn hp kh vo 300 ml dung dch KMnO4 1M trong H2SO4 thy th tch hn hp gim i 1/3 ng thi mu tm ca dung dch b nht mu. Bit s nguyn t cacbon trong A ln hn trong B mt nguyn t (cc kh u o ktc) . Cho bit cng thc cu to ca A v B A : HCHO v CH3CHO B : CH3CHO v C2H5CHO C : CH2=CH-CHO v CH3-CHO D : kt qu khc Cu 27 : Cho 3,6 gam ankanal X phn ng hon ton vi dung dch AgNO 3/NH3 , lng Ag sinh ra cho tc dng ho ton vi dung dch HNO3 c thu oc 2,8 lt kh NO2 ( sn phm kh duy nht 136,50C , p sut 1,2 atm) . Cng thc phn t ca ankanal l A : HCHO B : CH3CHO C : C2H5CHO D : Kt qu khc Cu 28 : Cho 4,2 gam mt andehit A mch h tc dng vi dung dch AgNO3 d trong NH3 thu c hn hp mui B . Nu cho lng Ag sinh ra tc dng vi dung dch HNO3 c to ra 3,792 lt kh NO2 ( sn phm kh duy nht 270C , p sut 740mmHg) t khi hi ca A so vi nit nh hn 4 . Mt khc khi cho 4,2 gam A tc dng vi 0,5 mol H 2(Ni t0) thu c cht C vi hiu sut 100% . Cho C tan vo nc c dung dch D . cho 1/10 dung dch D tc dng vi Na cho 12,04 lt H 2(ktc) . Cng thc phn t ca A l A : C2H5CHO B : CH3CHO C : C2H3CHO D : Kt qu khc Cu 29 : Hp cht hu c X c cng thc phn t C4H6O2 v ch cha mt loi nhm chc . T X v cc cht v c khc , bng 3 phn ng lin tip c th iu ch c cao su Buna . Cng thc cu to c th c ca X l : A : O=CH-CH2-CH2-CH=O B : HO-CH2-C=C-CH2-OH C : CH3-CO-CO-CH3 D : C A , B , C u ng Cu 30 : Ly 0,94 gam hn hp hai andehit no , n chc , k tip trong cng mt dy ng ng tc dng ht vi dung dch AgNO3/NH3 d thu c 3,24 gam Ag . Cng thc phn t hai andehit l : A : HCHO v CH3CHO B : CH3CHO v C2H5CHO C : C2H5CHO v C3H7CHO D : C3H7CHO v C4H9CHO Cu 31 : Hp cht hu c X khi un nng nh vi dung dch AgNO3/NH3 (d) thu c sn phm Y . Y tc dng c vi dung dch HCl hoc dung dch NaOH . u cho 2 kh v c . Hp cht X l A : HCHO B : HCOOH C : HCOONH4 D : C A , B , C u ng Cu 32 : Ba cht hu c X , Y , Z c cng thc phn t dng (CH2O)n vi n < 3 . Cho bit - X ch tham gia phn ng trng gng - Y Va tham gia phn ng trng gng , va phn ng vi Na - Z tc dng vi NaHCO3 va , lm bay hi nc ca dung dch sau phn ng , sn phm khan cn li c th tip tc tc dng vi Na . Oxi ho Z iu kin thch hp to thnh hp cht ch cha mt loi nhm chc . t chy hon ton X , Y , Z vi s mol bng nhau th s mol nc thu c t X nh hn t Y v s mol nc thu c t Y nh hn t Z . Hy xc nh cng thc cu to ca X , Y , Z A : CH3-CHO ; HO-CH2CH2-CHO ; CH3COOH B : C2H5-CHO ; HO-CH2-CH2-OH ; HO-CH2-COOH C : HCHO . HO-CH2-CHO , HO-CH2-CH2COOH D : Kt qu khc Cu 33 : Cc hp cht hu c mch h cha cc nguyn t cacbon , hidro v oxi l M , N , P , Q u c khi lng phn t bng 60 dvC . Cc cht N , P , Q tc dng c vi Na gii phng H2 . Khi oxi ho N ( c xc tc) to thnh sn phm c kh nng tham gia phn ng trng gng . Cht P

tc dung c vi dung dch NaOH . Cht Q c kh nng tham gia phn ng trng gng Cht M khng tc dng vi Na , khng tc dng vi dung dch NaOH v khng tham gia phn ng trng gng . Cc cht M , N , P ,Q c th l : A B C D M CH3OC2H5 C3H7OH HOCH2CHO N C3H7OH CH3OC2H5 CH3COOH Kt P CH3COOH HOCH2CHO CH3OC2H5 qu Q HOCH2CHO CH3COOH C3H7OH Khc

Cu 34 : Cho s phn ng :
1500 CH3COONa NaOH CaO,t A B +H2O HgSO4,80 D AgNO3/NH3 E lanh nhanh HCl Br2 C2H 2 , xuc tac NaOH F G H I Cc cht E , G , I c th l : A : CH3COONH4 ; CH3COOCH=CH2 ; CH3COONa B : HCOONH4 ; HCOOCH=CH2 ; HCOONa C : C2H5COONH4 ; C2H5COOCH=CH2 C2H5COONa D : C A , B u ng Cu 35 : Hai hp cht hu c X v Y ng chc cha cc nguyn t C , H , O khi tc dng vi dung dch AgNO3 trong NH3 th 1 mol X hoc Y to ra 4 mol Ag . Khi t chy X v Y th t l s mol O2 tham gia phn ng t chy , CO2 v H2O to thnh nh sau - i vi X : n(O2) : n (CO2) : n (H2O) = 1 : 1 : 1 - i vi Y : n (O2) : n (CO2) : n (H2O) = 1,5 : 2 : 1 Cng thc cu to thu gn ca X v Y l A : CH3CHO v HCHO B : HCHO v C2H5CHO C : HCOOH v HCHO D : HCHO v O=CH-CH=O Cu 36 : Cho cc phn ng :
0 0 0

(A) + dd NaOH
0

t0

(B) + (C) (G)

(B ) + NaOH r

Ca(OH) 2 t0

(D) + (E) (C) (A)

(D) 1500 (F) + H2 (C) + NaHSO3

HgSO 4 (F) + H2O (F) + CH3COOH

Cc cht (A) , (C) c th l A : HCOOCH=CH2 v HCHO B : CH3COOCH=CH2 v HCHO C : CH3COOCH=CH2 v CH3CHO D : Kt qu khc Cu 37 : Cho cc phn ng : (A) + (B) (C) + (D) (A) + Ca(OH)2 (E) + (F) (F) + (B) (D) + (G) + (H) (A) (CH3)2CO + (F) (C) + NaOH du (E) + Na2CO3 (E) + (I) (J) + (H) (J) + ? (K) + (H) + Ag + (L) Cc cht (A) , (E) , (J) c th l : A : CH3COOH , CH4 v CH3CHO B : (CH3COO)2Ca , CH4 v HCHO C : CH3COOH , CH4 v HCHO D : Kt qu khc Cu 38 : Cho hp cht hu c X (phn t ch cha C , H , O v mt loi nhm chc) . Bit khi cho 5,8 gam X tc dng vi dung dch AgNO3 d trong NH3 to ra 43,2 gam Ag . Mt khc 0,1mol X sau khi c hidro ha hon ton phn ng va vi 4,6 gam Na . Cng thc cu to ca X l A : HCOOH B : CH3CHO C : O=CH-CH=O D : CH2=CH-CHO Cu 39 : Cho 13,6 gam mt hp cht hu c X cha C , H , O tc dng va vi 300ml dung dch AgNO3 2M trong NH3 thu c 43,2 gam Ag . Bit t khi hi ca X so vi oxi bng 2,125 . Xc nh cng thc cu to ca X A : CH3CH2CHO B : CH2=CH-CH2-CHO C : CH=C-CH2CHO D : CH=C-CHO

Cu 40 : Mt hp cht hu c Y cha cc nguyn t C , H , O ch cha mt loi nhm chc . khi cho 0,01 mol Y tc dng vi dung dch AgNO3 trong NH3 d thu c 4,32 gam Ag . Y c cu to mch thng v cha 37,21% oxi v khi lng . Cng thc cu to ng ca Y l A : HCHO B : CH3CHO C : O=CH-CH=O D : O=CH-(CH2)2CH=O Cu 41 : Cho 0,1 mol andehit X tc dng hon ton vi H 2 th cn 6,72 lt H2(ktc) v thu c sn phm Y . Cho ton b lng Y tc dng vi Na d thu c 2,24 lt kh H 2(ktc) . Mt khc ly 8,4 gam X tc dng vi dung dch AgNO3 d thu c 43,2 gam Ag . Xc nh cng thc cu to ca X v Y A : CH3CHO v C2H5OH B : C2H2(CHO)2 v HOCH2CH(CH3)CH2OH C : C2H2(CHO)2 v HO-CH2(CH2)2CH2OH D : C B v C Cu 42 : Cht hu c X cha C , H , O trong hidro chim 2,439% v khi lng . Khi t chy X thu c s mol ca H2O bng s mol ca X b t chy . Bit 0,1 mol X tc dng hon ton vi dung dch AgNO3 d trong NH3 thu c 43,2 gam Ag . Xc nh cng thc cu to ca X A : HCOOH B : CH3CHO C : CH=C-CHO D : O=CH-C=C-CH=O Cu 43 : Cho 2,4 gam mt hp cht hu c X (cha C , H , O) tc dng hon ton vi dung dch AgNO3 d trong NH3 thu c 7,2 gam Ag . Xc nh cng thc cu to thu gn ca X A : CH3CHO B : C2H5CHO C : HCHO D : C3H7CHO Cu 44 : Cho 3 hp cht hu c X , Y , Z . Bit X cha 3 nguyn t C, H ,Cl trong clo chim 71,72% theo khi lng . Y cha 3 nguyn t C , H , O trong oxi chim 55,71% theo khi lng . Khi thu phn X trong mi trng kim hoc hidro ho Y u thu c hp cht Z . Xc nh cng thc cu to ca X , Y , Z A : CH3Cl , HCHO , CH3OH B : C2H5Cl , CH3CHO , C2H5OH C : C2H4Cl2 , (CHO)2 , C2H4(OH)2 D : Kt qu khc Cu 45 : X l hp cht hu c mch h n chc cha C , H , O . t chy hon ton 1 mol X cn 4 mol oxi v thu c CO2 v hi H2O c th tch bng nhau (o cng iu kin nhit v p sut) . Xc nh cng thc cu to c th c ca X A : CH3-CH2-CHO hoc (CH3)2CO B : CH2=CH-CH2-OH C : CH2=CH-O-CH3 D : c A , B , C Cu 46 : t chy hon ton 0,059 gam hp cht hu c X ch thu c 0,140 gam CO 2 v 0,072 gam H2O . T khi hi ca X i vi oxi bng 2,31 1-Lp cng thc phn t ca X A : C3H6O B : C2H6O2 C : C4H10O D : C5H12O 2- Ly 7,4 gam hp cht X em oxi ho hon ton thnh hai cht Y v Z . Cht Y c phn ng trng gng . Cht Z b trung ho bi 100 ml dung dch NaOH 0,1M . Cng thc cu to thu gn ca Y v Z A : CH3CHO v CH3COOH B : HCHO v HCOOH C : C3H7CHO v C3H7COOH D : Kt qu khc Cu 47 : Cho 47,84 gam ru etylic tc dng vi hn hp K2Cr2O7/H2SO4 . Sn phm ca phn ng c tch ngay ra khi mi trng phn ng bng phng php chng ct v dn vo dung dch AgNO3/NH3 d . Sau khi kt thc phn ng , thu c 124,2 gam Ag . Tnh hiu sut ca phn ng oxi ho ru etylic A : 55% B : 70% C : 75% D : Kt qu khc Cu 48 : X l hp cht hu c cha C , H , O . Bit X c phn ng trng gng v phn ng vi dung dch NaOH . t chy hon ton a mol X thu c 3a mol CO2 v H2O . X l A : HCOOH B : HCOOCH3 C : CHO-COOH D : CHO-CH2-COOH Cu 49 : C th dng nc Brom phn bit A : Andehit no v xeton no B : Andehit no v ru khng no C : Phenol v anilin D : A hoc C Cu 50 : Ngi ta thc hin phn ng trng hp axetandehit ( andehit axetic) trong mi trng axit nhit thp (t0 < 00C) thu c cht t rn gi l cn kh c tn l metandehit . Cng thc ca metandehit l : A : CH3-CH(OH)-CH2-CHO B : [-CH(CH3)-O-]3 C : [-CH(CH3)-O-]4 D : [-CH2-O-]n n = 10 n 100