Nama

: Aprilia Dwi Anisa

NIM

: 11612040

Jurusan

: Ilmu Kimia

JAWABAN KUIS KIMIA ANALITIK 2

1. Diketahui : massa sampel =3,116 gram

O2
Sampel

2Fe(OH)3 Fe2O3+3H2O

(FeSO4.7H20)

0,355 gram

Mol FeSO4.7H20

=Mol Fe2O3

gr/Mr
=0.355 gram:159,6 gram/mol
=2.2243x10 -3 mol

Mol FeSo4.7H20

=2.2243x10-3Mol

9FeSO4.7H20

=2.2243X10-3Mol x 151.8 g/mol

=337,64874.10-3
=0.3376 gram

2. K2SO4 + Al2(SO4)2 Al2O3 + 24H2O

Sampel = 1,9231 gram

Hasil endapan = 0,1357
Berat Al2O3 = 0,1357 gram

Mr= 101,5 g/mol

Mol Al2O3
Mol Al

Berat Al
% Al

=
= 1,3.10-3 mol
= 3 . mol Al2O3
= 3 . 1,3.10-3 mol
= 3,9. 10-3 mol
= 3,9. 10-3 mol . 26,9 g/mol
= 0,10491 gram
=
=
= 5,45%

3. Diketahui: V NaOH = 48,13 mL

M NaOH = 0,1251 M
M sampel= 0,5136 g
Ditanya: kemurnian C6H4N2O2S = ?
Jawab
kesetaraan titrasi = 2 mol H2SO4 = ml NaOH
Mol NaOH = M NaOH x V NaOH
= 0,1251 M x 48,13 mL
= 6,0210 mmol
Mol C6H4N2O2S = mol H2SO4 = x mol NaOH
= x 6,0210 mmol = 3,0105 mmol
M C6H4N2O2S = mol C6H4N2O2S x Mr C6H4N2O2S
= 3,0105 mmol x 168 g/mol
= 505,764 mg
= 0,505764 gram

kemurnian C6H4N2O2S =
=

x 100%
x 100%

= 98,4743 %
Jadi, kemurnian C6H4N2O2S adalah 98,4743 %

4. Diketahui:
V EDTA 1= 0,02614 L
M EDTA 1 = 0,05831 M
V EDTA 2 = 0,03543 L
M EDTA 2 = 0,05831 M
V EDTA 3 = 0,05 L
M EDTA 3 = 0,05831 M
Berat sampel = 0,7176 gram
Ar Ni = 58,69 g/ mol
Ar Fe = 55,847 g/mol
Ar Cr = 60 g/mol
Titrasi 1: mol Ni = mol EDTA 1 (Fe, Cr )
= M EDTA 1 x V EDTA 1
Gram Ni = M EDTA 1 x V EDTA 1 x Ar Ni
= 0,05831 M x 0,02614 L x 58,69 g/mol
= 0,0803 g
Titrasi 2: mol Ni + mol Fe = mol EDTA 2 (Cr )
= mol EDTA 1 + Mol Fe = mol EDTA 2
g Fe = (M EDTA 2 x V EDTA 2) (M EDTA 1 x V EDTA 1) x Ar Fe
= (0,05831 M x 0,03543 L ) ( 0,05831 M x 0,02514 L) x 55,847 g/mol
= 0,0303 g

Titrasi 3 = mol EDTA 2 + mol Cr + mol Cu =mol EDTA 3

= mol EDTA 3 mol EDTA 2 mol Cu
G Cr= M EDTA 3 x V EDTA 3 M EDTA 2 x V EDTA 2 M Cu x Vcu x Ar Cr
= 0,05831 M x 0,05 L 0,05831 x 0,03543 L 0,06316 M x 0,00621 L x 60
= 0,02378 g

0.08946 g 5 = 0.4473 g Ni
0.03025 g 5 = 0.1513 g Fe
0.02378 g 5 = 0.1189 g Cr

5. Ba (OH)2 + CO2

BaCO3 + H2O

Ba(OH)2 + HCl

BaCl2 + 2H2O

Titrasi 1 :
Mol Ba (OH)2 = mmol CO2
50,00 mL . 0,0200 M = mmol CO2
1 mmol = mmol CO2
Titrasi Balik :
mmol HCl = mmol CO2
0,0216 M . 38,5 mL = mmol CO2
0,833328 mmol = mmol CO2
mmol Total CO2 = 1 mmol + 0,833328 mmol
= 1,833328 mmol

Massa CO2 = mmol x Mr CO2

= 1,833328 mmol x 40 mg / mmol
= 73,33 mg
= 0,0733 gram

Volume = m / l
= 0,0733 gram/ 1,98 gr / L
= 0,03703 L
PPm CO2 = 0,07333 gram/ 1000 x 0,0370 L
= 2,71321 x 10-6 ppm