TRNG PTTH CHUYN L HNG PHONG H v tn th sinh: ........................................................ S bo danh: ................................................................

M 121

THI TH I HC LN 3 THNG 3 2011 MN HA HC KHI 12 NNG CAO Thi gian: 45 PHT thi bao gm 30 cu trn 2 trang

Cu 1: t chy hon ton 0,1 mol mt axit cacboxilic n chc, cn va 6,72 lt O2 (ktc), thu c 0,3 mol CO2 v a mol H2O. Gi tr ca a l A. 0,2 B. 0,4 C. 0,1 D. 0,3 Cu 2: Ha tan 5 gam mui ngm nc CuSO4.nH2O vo nc, in phn dung dch thu c cho n khi c kh thot ra ti catot th dng li, thu c dung dch A. Trung ha dung dch A cn mt lng va dung dch cha 1,6 gam NaOH. Vy n c gi tr l A. 5 B. 6 C. 8 D. 4 Cu 3: Cho a mol CO2 hp th ht vo dung dch cha b mol Ca(OH)2. Phn ng to kt ta khi A. a / b < 1/2 B. 1 < a / b < 2 C. a / b < 2 D. a / b = 1 Cu 4: Hp cht hu c thm X c cng thc phn t C8H10O. Khi thc hin phn ng tch nc t X thu c mt hirocacbon Y, trng hp Y to polistiren (PS). S cng thc cu to ca X tha mn iu kin trn l A. 3 B. 4 C. 2 D. 1 Cu 5: Ha tan hn hp X gm Na, K trong nc d, to thnh dung dch A v 0,672 lt (ktc) kh H2. Cho dung dch A tc dng vi dung dch cha 0,016 mol AlCl3 th lng kt ta thu c l A. 0,312 gam B. 1,17 gam C. 0,234 gam D. 0,78 gam Cu 6: Tnh th tch dung dch FeSO4 1,5 M cn dng phn ng va vi 100ml dung dch cha KMnO4 0,2M v K2Cr2O7 0,1M trong mi trng axit. A. 0,32 lt B. 0,64 lt C. 0,106 lt D. 0,08 lt Cu 7: Este E c cng thc phn t l C5H8O2. Thy phn E trong mi trng axit thu c imetyl xeton. Cng thc cu to thu gn ca E l A. CH3COOCH=CHCH3 B. CH3COOC(CH3)=CH2 C. HCOOCH=CHCH2CH3 D. HCOOC(CH3)=CHCH3 Cu 8: 22Gia mui icromat (Cr2O7 ) v mui cromat (CrO4 ) c cn bng: 22+ Cr2O7 + H2O 2CrO4 + 2H (da cam) (vng) Cho t t dung dch NaOH vo ng nghim ng dung dch K2Cr2O7 th hin tng quan st c l g? A. Mu da cam nht dn do c s pha long ca dung dch NaOH. B. Khng thy c hin tng g v khng xy ra phn ng.

C. Mu da cam m dn do cn bng chuyn dch v bn tri. D. Dung dch chuyn sang mu vng. Cu 9: Thi H2 d qua hn hp gm cc oxit MgO, Al2O3,Fe2O3, CuO v PbO nhit cao th hn hp cht rn thu c sau phn ng gm A. MgO, Cu, Fe, Al 2O3, Pb B. MgO, Cu, Fe, Al, Pb C. Mg, Cu, Fe, Al, Pb D. Mg, Cu, Fe, Al2O3, Pb Cu 10: C th iu ch kim lai Canxi bng phng php no sau y? A. Kh CaO bng lng d kh CO nhit cao. B. Kh CaO bng lng d cacbon nhit cao. C. T CaCO3 iu ch CaCl2 khan ri in phn CaCl 2 nng chy. D. Nhit phn CaO nhit cao. Cu 11: Cho cc cht sau: (1): HOCH2-CH2OH (2): HOCH2-CH2-CH2OH (3): CH3-CH2-O-CH3 (4): HOCH2-CHOH-CH2OH (5): C6H12O6 (glucoz) (6): CH3COOH Cc cht (trong nc) tc dng c vi Cu(OH)2 l A. (1),(3),(5),(6) B. (1),(2),(4),(5) C. (1),(4),(5),(6) D. (2),(3),(4),(6) Cu 12: Xc nh cc h s a, b, c trong phng trnh ho hc sau aFeS2 + bHNO3 Fe2(SO4)3 + H2SO4 + cNO + 4H2O A. a = 2, b = 5, c = 5 B. a = 2, b = 10, c = 10 C. a = 2, b = 4, c = 4 D. a = 2, b = 8, c = 8 Cu 13: un nng hn hp 2 ancol n chc mch h vi o H2SO4 c 140 C thu c hn hp 3 ete. t chy hon ton mt trong ba ete th thu c kh cacbonic v hi nc c t l mol l nCO2 : nH2O = 3 : 4. Cng thc phn t ca 2 ancol l A. CH3OH v C2H5OH B. C2H5OH v CH3CHOHCH3 C. CH3OH v CH3CH2CH2OH D. C2H5OH v CH3CH2OH Cu 14: Ha tan m gam ancol etylic (D = 0,8 g/ml) vo 108 ml nc to thnh dung dch A. Cho dung dch A tc dng vi Na d thu c 85,12 lt (ktc) kh H2. Dung dch A c ru l o o o o A. 92 B. 46 C. 90 D. 85 Cu 15: Mt hn hp X gm 3 ancol n chc thuc cng mt dy ng ng. t chy hon ton m gam hn hp X thu c 4,4 gam CO2 v 2,7 gam nc. Gi tr ca m l

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A. 2,3 gam

B. 2,5 gam C. 3,0 gam D. 1,6 gam

Cu 16: S ng phn amin bc 2 ca C5H13N l A. 6 B. 5 C. 7 D. 4 Cu 17: Ch s axit l s mg KOH cn dng trung ha cc axit bo t do c trong 1 gam cht bo. Tnh ch s axit ca mt loi cht bo, bit rng trung ha axit bo t do c trong 14 gam cht bo cn 15 ml dung dch NaOH 0,1M. A. 14 B. 7 C. 5,6 D. 6 Cu 18: Pht biu no sau y khng ng? A. Khi thm t t tng lng nh dung dch HCl vo dung dch Na2CO3 ng thi khuy u hn hp th phn ng ha hc u tin xy ra l: CO2 + H+ HCO3 . 3 B. Cc kim loi kim lun c s oxi ha +1 trong mi hp cht ca chng. C. Khi in phn NaOH nng chy (vi cc in cc tr), trn anot xy ra qu trnh oxi ho: + 2OH O2 + 2H + 2e D. iu ch cc kim loi kim, ngi ta c th in phn cc mui clorua hoc cc hiroxit nng chy ca chng. Cu 19: Mt hn hp X gm 3 ancol n chc thuc cng mt dy ng ng. t chy hon ton m gam hn hp X thu c 4,4 gam CO2 v 2,7 gam nc. Cng thc tng qut ca 3 ancol l A. CnH2n-1OH B. CnHn+1OH C. CnH2n+1OH D. CnH2n-3OH Cu 20: Mt hp cht hu c X cha C, H, O, N c phn t khi 89 vC. X tc dng vi dung dch HCl v dung dch NaOH. Khi cho 0,1 mol X tc dng vi dung dch NaOH d thu c 9,4 gam mui. Cng thc cu to ng ca X l A. CH2=CH-COONH4 B. H2N-CH2-COO-CH3 C. CH3-CH(NH2)-COOH D. H2N-CH2-CH2-COOH Cu 21: Cho metyl amin ln lt phn ng vi dung dch HCl, NaOH, NH3, HNO2, FeCl3. S ln xy ra phn ng ha hc l A. 1 B. 2 C. 3 D. 5 Cu 22: Cho dung dch cha 0,03 mol NaAlO2 tc dng vi 100 ml dung dch HCl x(M), thy sinh ra 1,56 gam kt ta. Gi tr ca x l A. 0,1M hay 0,4M B. 0,2M C. 0,2M hay 0,6M D. 0,6M

Cu 23: Cho 0,01 mol Fe vo 100 ml dung dch AgNO3 0,4 M th s mol Ag sinh ra l A. 0,01 mol B. 0,04 mol C. 0,03 mol D. 0,02 mol Cu 24: Cho cc pht biu v tnh cng ca nc nh sau: (1): un si ta ch loi c tnh cng tm thi ca nc. (2): C th dng Na2CO3 loi c tnh cng tm thi v tnh cng vnh cu ca nc. (3): C th dng HCl loi tnh cng ca nc. (4): C th dng NaCl loi tnh cng ca nc. Chn pht biu ng. A. Ch c (1),(2),(3) B. Ch c (1),(2) C. Ch c (2) D. Ch c (1),(2),(4) Cu 25: t nng hn hp gm bt Al v bt Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy ra hon ton, thu c hn hp X. Cho hn hp X tc dng vi dung dch NaOH d thy c kh H2 thot ra. Hn hp X gm A. Al, Fe, Fe3O4, Al2O3 B. Al, Fe, Fe2O3, Al 2O3 C. Al, Fe, Al2O3 D. Al, Fe, FeO, Al 2O3 Cu 26: Cho cc kim loi Al, Fe, Cr, Na. Hy sp xp cc kim loi theo chiu tng dn cng. A. Na < Fe < Al < Cr B. Na < Al < Fe < Cr C. Na < Cr < Al < Fe D. Na < Al < Ni < Fe Cu 27: Cho 10,8 gam hn hp gm Fe, Al, Mg tc dng va vi dung dch c cha 0,8 mol HCl. Khi lng mui khan thu c l A. 37,2 gam B. 38,2 gam C. 40,2 gam D. 39,2 gam Cu 28: Thi mt lung kh CO qua m gam Fe2O3 nung nng thu c 6,72 gam hn hp X gm 4 cht rn l Fe, FeO, Fe3O4, Fe2O3. Hn hp X tc dng vi dung dch HNO3 d sinh ra 0,16 mol NO2. Gi tr ca m l A. 7 gam B. 6 gam C. 5 gam D. 8 gam Cu 29: Ha tan m (gam) Na2O vo 100 ml dung dch NaOH 20% (D = 1,2g/ml) thu c dung dch NaOH 30%. Vy m c gi tr l A. 15,22 gam B. 10,2 gam C. 13,12 gam D. 12,12 gam Cu 30: Cho s chuyn ho trc tip: C2H5OH X C2H5OH. Trong cc cht sau: C4H6 (ivinyl), CH3CHO, CH3COOH, C2H4, C2H5ONa, (C2H5)2O, C2H5Cl, CH3COOC2H5, s cht c th l cht X l A. 4 cht B. 7 cht C. 8 cht D. 6 cht

Cho nguyn t khi: H = 1, C = 12, N = 14, O = 16, S = 32, Cl = 35,5, Na = 23, Mg = 24, Al = 27, K = 39, Fe = 56, Cu = 64, Ag = 108, Ba=137

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P N 121 1. A 2. A 3. C 4. C 5. A 6. C 7. B 8. D 9. A 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30.

C C B A B A A D C C A C C C B C B D D D D

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