42.

The order of reactivity of phenyl magnesium bromide with the following compound is O O O

Me (I)

Me

Me (II)

Ph (III)

Ph

(A) II > III > I (C) II > I > III

(B) I > III > II (D) all react with the same rate

43. An organic compound C3H6O does not give a precipitate with 2, 4 dinitro phenyl hydrazine and does not react with metallic sodium. It could be (A) CH3CH2CHO (B) CH3COCH3 (C) CH2 = CH CH2OH (D) CH2 = CH OCH3 44. Iodoform test is applicable for O (A)

(B)
H3C

CH3
O

CH3

(C)

(D)

All the above

CH3

45. Which of the following compound on heating with caustic potash gives ammonia? (A) CH3CONH2 (B) CH3CH2NH2 O (C) (CH3)2C = NOH (D) CH2 C N CH3 2
||

46. Identify the final product in the following sequence of reactions O

CH 3CH 2MgBr

H2 C

CH 2

KMnO 4

(A) CH3CH2CH2COOH (C) CH3CH2COOH O

P2 O5 Br2 47. X R C NH2 Y OH ||

Z (B) CH3CH(CH3)COOH (D) CH3CH2CH2CH2OH

X and Y respectively are (A) R CN, RCH2NH2 (B) RNH2, RCN (C) RCN, RNH2 (D) RCN, RCH2NH2 48. Which of the following reaction/s will yield carboxylic acid? 1. RMgX + CO2 2. PhOH + CHCl3 + NaOH + 3. PhCN + H3O 4. PhOH + NaOH + CO2 (A) 3 and 4 (C) 2 only (B) 2 and 4 (D) 4 only
H