S GDT THANH HO TRNG THPT BM SN ( thi gm c 6 trang)

THI TH I HC T I Mn: HO HC; Khi A, B Thi gian lm bi: 90 pht, khng k thi gian pht

H v tn th sinh:....................................................................... S bo danh:...............................................................................

M 101

Cho: H = 1; C = 12; O = 16; N = 14; Cl = 35,5; S = 32; Li = 9; Na = 23; K = 39; Mg = 24; Ca = 40; Al = 27; Fe = 56; Cu = 64; Ag = 108. I. PHN CHUNG CHO TT C TH SINH (40 cu , t cu 1 n cu 40) 1/ Ho tan hon ton 7,020 gam hn hp CaCO3 v MgCO3 vo dung dch HCl d thy thot ra V lt kh ( ktc). Dung dch thu c em c cn, c 7,845 gam mui khan. Gi tr ca V l a. 1,232 lt b. 1,344 lt c. 1,568 lt d. 1,680 lt 2/ Trn ln 100ml dung dch Ba(OH)2 1M vi 100ml dung dch Al2(SO4)3 0,2M, khuy u cho phn ng xy ra hon ton thu c x gam kt ta v dung dch A. Sc CO 2 d vo A thu c y gam kt ta. Gi tr ca x v y tng ng l a. 13,98 v 7,06. b. 23,3 v 7,06. c. 23,3 v 3,12. d. 13,98 v 3,12. 3/ Ho tan hon ton hn hp 0,12 mol FeS2 v a mol Cu2S bng dung dch HNO3 va , thu c dung dch X (ch cha 2 mui sunfat) v kh NO (sn phm kh duy nht). Gi tr ca a l a. 0,06 b. 0,12 c. 0,04 d. 0,075 4/ Cho 15,0 gam mt aminoaxit X c mt nhm amino v mt nhm cacboxyl tc dng vi dung dch NaOH thu c dung dch Y. C cn Y c 19,4 gam mui khan. X l a. H2NCH2COOH. c. H2NC3H6COOH. b. H2NC2H4COOH. d. H2NC4H8COOH
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5/ Ho tan 23,6 gam hn hp gm 2 axit cacboxylic vo nc thu c dung dch A. Chia A thnh hai phn bng nhau. Phn 1: Cho tc dng vi dung dch AgNO3/NH3 d, thu c 21,6 gam Ag. Phn 2: c trung ho hon ton bi 200ml dung dch NaOH 1M. Hai axit l a. axit fomic v axit acrylic. c. axit fomic v axit oxalic. b. axit fomic v axit propionic. d. axit axtic v axit fomic.

6/ Cho 6,72 gam Fe vo dung dch c 0,4 mol HNO3 (gi thit NO l sn phm kh duy nht). Sau khi phn ng hon ton, phn dung dch c s gam mui tan l a. 29,04 b. 24,2 c. 25,32 d. 21,6 7/ un hn hp gm 0,3 mol Al v 0,3 mol S trong mi trng khng c khng kh. Hn hp thu c em ho tan bng dung dch HCl d thu c hn hp kh A (khng cn cht rn khng tan). Khi lng mol trung bnh ca hn hp A l a. 18,0 b. 23,3 c. 22,4 d. 25,5 8/ Nung hn hp A gm 0,15mol Cu v x mol Fe trong khng kh mt thi gian, thu c 63,2 gam hn hp B gm hai kim loi d v hn hp cc oxit ca chng. Ho tan ht lng hn hp B trn bng dung dch H2SO4 c nng d th thu c 0,3mol SO2 (sn phm kh duy nht). x c gi tr l a. 0,7 mol. b. 0,6 mol. b. 0,4 mol. d. 0,5 mol. 9/ Cho cc ancol n chc sau: CH3OH (1);

(CH3)3C-OH (2); (CH3)3C-CH2-OH (3);

(CH3)2CH-OH (4). Nhng ancol khng b tch nc ni phn t khi un nng vi H2SO4 c, 1700C to anken l a. (1) ; (2) v (3) b. (1) v (3) c. (1) v (4) d. (2) v (3) 10/ Trong cng nghip, iu ch Stiren ngi ta thc hin theo s :
C2H4 ,xt xt,t Benzen C6H5C2H5 S tiren .
0

T 1,0 tn benzen cn ti thiu bao nhiu m3 (ktc) etilen v thu c bao nhiu kg Stiren. Bit hiu sut ca mi giai on phn ng u t 80% a. 229,6m3 etilen v 1606,6 kg Stiren. c. 287,2m3 etilen v 1066,6 kg Stiren. b. 229,6m3 etilen v 835,33 kg Stiren. d. 287,2m3 etilen v 853,33kg Stiren.
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11/ Cho hn hp X gm hai kim loi kim tan ht trong 200ml dung dch cha BaCl 2 0,3M v Ba(HCO3)2 0,8M thu c 2,8 lt H2 ( ktc) v m gam kt ta. Gi tr ca m l a. 43,34 b. 49,25 c. 31,52 d. 39,4 12/ Axit lactic (CH3 - CH(OH) - COOH) c th tc dng c vi tt c cc cht trong dy no sau y ? a. Na, Na2CO3, K2SO4, CH3COOH. c. CH3NH2, HCl, CaSO4. b. Na2O, NaHCO3, C2H5OH, HBr. d. CH3OH, H2, NaOH, Br2.

13/ Cho hn hp X gm 2 axit hu c no. t chy hon ton a mol hn hp X thu c a mol H2O. Mt khc, cho a mol hn hp X tc dng vi NaHCO3 thu c 1,4a mol CO2. % khi lng ca axt c khi lng phn t nh hn trong hn hp X l a. 27,3%. 14/ Cho s sau:
0

b. 35,8%.

c. 25,4%.
0

d. 43,4%.
0

HCl KOH,etanol,t KOH,etanol,t (CH3)2CH-CH2-CH2Cl A B C

HCl NaOH, H2O, t D E.

Cc cht trn s l sn phm chnh. E c cng thc cu to l a. (CH3)2CH - CH(OH)CH3. c. (CH3)2C(OH) - CH2 - CH3. 15/ Cho cc cht sau: b.(CH3)2CH - CH2CH2OH. d.(CH3)2C = CHCH3.

KMnO4, KCl, Al, dd H2SO4 c, dd NaOH. C th iu ch trc

tip c (nhiu nht) cc kh no bng cch trn cc cht vi nhau hoc nhit phn cc cht a. O2, Cl2, H2, SO2, HCl. c. O2, HCl, SO2 b. O2, H2, SO2. d. Cl2, H2, SO2, Cl2O.

16/ Ho tan hon ton 2,16g Mg bng dung dch HNO3 d, thy thot ra 0,896 lt kh NO (ktc) v dung dch X. C cn dung dch X thu c lng mui khan l a. 6,52 gam. b.8,88 gam. c.13,32 gam. d. 13,92 gam. 17/ Cho cc nhn xt sau: 1) Sc Ozon vo dung dch KI s thu c dung dch c kh nng lm h tinh bt ho xanh. 2) Hiro peoxit v hiro sunfua c th lm mt mu dung dch thuc tm trong mi trng
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H2SO4 long. 3) Sc hiro sunfua vo dung dch FeCl3 s thy xut hin vn c mu vng. 4) Dung dch H2S lu trong khng kh s c vn c mu vng. 5) Hiro peoxit l cht kh mnh v khng c tnh oxi ho Cc nhn xt ng l a. 1, 2, 3, 4. b. 2, 4, 5. c. 1, 2, 4, 5. d. 1, 3, 4. 18/ iu no sau y sai ? a. b. c. d. Cho propen hp nc (xc tc H+, t0) thu c 2 ancol. ng vi cng thc phn t C4H8 c ba anken. Tch mt phn t H2 t butan thu c 3 anken. t chy bt k mt anken no cng thu c s mol CO2 bng s mol H2O

19/ Dy no sau y ch gm cc cht c th trc tip iu ch anehit axetic ? a. ancol etylic; etilen; 1,1 -icloetan; axetilen. b. ancol etylic; axetilen; etyl axetat. c. ancol metylic; axit axetic; vinyl axetat. d. etilen; etan; axit fomic ; axetilen. 20/ un nng mui X thu c mui Y. Y tc dng vi dung dch HCl thu c mui X v mui Z. in phn dung dch mui Z thu c 2 kh v cht G. G tc dng vi CO 2 c th thu c X hoc Y. t G trn ngn la xanh, ngn la c mu vng. X, Y, Z, G tng ng l a. Na2CO3, NaHCO3, NaCl, NaOH. c. NaHCO3, Na2CO3, NaOH, NaCl. b. NaHCO3, Na2CO3, NaCl, NaOH. d. K2CO3, KOH, KHCO3, KCl.

21/ Cho tht t t dung dch NaOH vo dung dch H3PO4 ti d dung dch NaOH. Cc mui sinh ra trong th nghim trn ln lt theo th t a. Na3PO4, NaH2PO4, Na2HPO4. c. NaH2PO4, Na2HPO4, Na3PO4. 22/ Nhn xt no sau y ng ? a. C th iu ch axetilen t vi, than qua 2 phn ng. b. Tecpen l nhng hirocacbon khng no c cng thc n gin nht l C5H8. c. Phn t C2H2 c cu to thng.
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b. Na3PO4, Na2HPO4, NaH2PO4. d. NaH2PO4, Na3PO4, Na2HPO4.

d. Tecpen l sn phm trng hp isopren nn c cng thc chung (C5H8)n 23/ Mt ankan to c dn xut monoclo trong hm lng clo l 38,38% khi lng. Ankan c s ng phn l a. 3 b. 4 c. 2 d. 1 24/ Cho t t 200 ml dung dch HCl vo 100ml dung dch cha Na2CO3, K2CO3, NaHCO3 1M thu c 1,12 lt CO2 (ktc) v dung dch X. Cho nc vi trong d vo dung dch X thu c 20 gam kt ta. Nng mol/l ca dung dch HCl l a. 1,25 M. b. 0,5 M. c. 0,75 M. d. 1,0 M. 25/ Phng trnh ho hc no sau y sai ?
K OH , ancol , t a. CH3 - CHBr - CH2- CH3 CH3 - CH = CH - CH3 (sn phm chnh) +
0

HBr

b. CH3 - CH2MgBr + CO2 CH3CH2COOMgBr.

etekhan CH CH - Mg - Br. c. CH3CH2 - Br + Mg 3 2

d. Br - C6H4CH2 - Br + 2NaOH long, d HOC6H4CH2 - OH + 2NaBr.

26/ phn bit cc dung dch khng mu: glyxin, etyl amin, axit acrylic. Cn dng 1 thuc th l a. Dung dch NaOH b. Dung dch Na2CO3 c. Qu tm d. Dung dch HCl

t0

27/ X l hp cht hu c c cng thc phn t C 5H11O2N. un X vi dung dch NaOH thu c mt cht c cng thc phn t C2H4O2NNa v cht hu c Y. Cho hi Y i qua CuO (t0) thu c cht hu c Z c kh nng cho phn ng trng gng. X c cng thc cu to l a. CH3(CH2)4NO2. c. NH2CH2COOCH(CH3)2. b. NH2CH2CH2COOC2H5. d. NH2CH2COO - CH2CH2CH3.
0

HCN H3O , t 28/ Cho s phn ng: CH3CHO A B. B l

a. CH3 - CH2 - COOH. c. CH3 - CH(OH) - COOH.

b. CH3 - CH2 - CN. d. CH3 - CHO - CH3

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29/ in li ca CH3COOH s tng khi a. Thm vo vi git dung dch HCl. b. Thm vo vi git dung dch Na2SO4. c. Thm vo mt lng nh tinh th CH3COONa. d. Pha long dung dch. 30/ Nhn xt no sau y sai ? a. Tnh axit ca cc axit halogenhiric tng dn theo th t HF, HCl, HBr, HI. b. Cho H2SO4 c tc dng vi hn hp rn (NaI v MnO2) un nng, thu c I2. c. Tnh kh ca cc hiro halogenua tng dn theo th t HF, HCl, HBr, HI. d. Cho H2SO4 c tc dng vi NaI rn un nng, thu c hiro iotua. 31/ un nng hn hp 2 ancol n chc, mch h A, B vi H 2SO4 c 1400C thu c hn hp 3 ete. t chy 10,8 gam mt ete trong s 3 ete trn thu c 26,4 gam CO2 v 10,8 gam H2O. A, B l a. ancol metylic v ancol anlylic. c ancol metylic v ancol etylic. b. ancol etylic v ancol vinylic. d. ancol etylic v ancol anlylic.

32/ t chy hon ton 8,8 gam mt hp cht hu c A n chc (c C, H, O) thu c 8,96 lt CO2 (ktc) v 7,2 gam H2O. A c th tc dng c vi Na2CO3 to kh CO2. S ng phn cu to cng chc ph hp vi A l a. 2 b. 4 c. 3 d. 5 33/ Hn hp X gm hai cht hu c n chc tc dng vi 500ml dung dch KOH 1M, thu c hai mui ca hai axit hu c v mt ancol. Cho lng ancol trn tc dng vi Na d th c 3,36 lt H2 (ktc). X gm a. Mt axit mt ancol. c. Mt este mt ancol. 34/ Cho cc nhn xt sau: 1) Anehit l cht kh yu hn xeton. 2) Anehit no khng tham gia phn ng cng. 3) Cng thc phn t chung ca cc anehit no l CnH2nO. 4) Anehit khng phn ng vi nc.
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b. Mt este v mt axit. d. Hai este.

5) Anehit khi phn ng vi phenol d (xc tc axit) un nng s thu c nha novolac. Nhn xt ng l a. 5. b. 1, 4. c. 2, 4, 5. d. 1, 2, 3. 35/ em oxi ho 2,76 gam ancol etylic bng CuO un nng, thu c hn hp A c cha anehit, axit, ancol d v nc. - Cho 1/2 hn hp A tc dng hon ton vi dung dch AgNO3/NH3 d,t0 thu c 3,024 gam Ag. - Cho 1/2 hn hp A trung ho va vi 10ml dung dch NaOH 1M. % khi lng ancol etylic b oxi ho l a. 80%. b. 95%. c. 75%. d. 40%. 36/ Cn trn dung dch A cha (HCl 0,1M v H2SO4 0,2M) vi dung dch B cha (NaOH 0,3M v KOH 0,2M) theo t l th tch nh th no thu c dung dch c pH = 7 ? a. VA/ VB = 1 : 2 b. VA/ VB = 2 : 1 c. VA/ VB = 1 : 4 d. VA/ VB = 1 : 1

37/ Dy gm cc ion X+, Y2+, Z-, T2- v nguyn t M u c cu hnh e 1s22s22p63s23p6 l a. K+, Ca2+, Cl-, S2-, Ar. c. K+, Mg2+, Br-, S2-, Ar. b. Na+, Ca2+, Cl-, O2-, Ar. d. K+, Ca2+, F-, O2-, Ne.

38/ Ho tan hon ton 28,4 gam hn hp hai kim loi X (ho tr I) v Y (ho tr II) bng dung dch HCl d thu c dung dch Z v V lt kh ( ktc). C cn dung dch Z thu c 49,7 gam hn hp mui clorua khan. V bng a. 8,24 lt. b. 11,2 lt. c.6,72 lt. d.8,96 lt 39/ Sc kh hiro sunfua vo cc dung dch: FeCl2, MgCl2, NaCl, CuCl2. C bao nhiu trng hp c cht rn to ra ? a. 4 b. 2 c. 1 d. 3 40/ Cho cc phn ng sau: a) FeS + H2SO4 (c, nng) c) Fe + Fe2(SO4)3 e) CH3CHO + [Ag(NH3)2]NO3 b) MgO + HNO3 (c, nng)

d) C2H2 + H2 f) CH3COOCH3 + NaOH

7
t0

Ni,t 0

g) glixerol + Cu(OH)2 a. 6 b. 4

h) HCHO + Cu(OH)2
c. 7 d. 5

t 0 ,OH

S phn ng thuc loi phn ng oxi ho - kh l

II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (Phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) 41/ Cho A l hp cht thm c cng thc phn t chnh l cng thc n gin nht. t chy hon ton 1,24 gam A ch thu c 1,568 lt CO2 (ktc) v 0,72 gam H2O. Cho a mol A tc dng vi Na d thu c a mol kh H2. Mt khc, a mol A tc dng vi a mol NaOH. S cng thc cu to c th ph hp vi A l a. 4 b. 6 c. 3 d. 5 42/ X c cng thc phn t C6H14. X tc dng vi Clo (as) cho ti a 2 dn xut monoclo. X l a. hexan. b.neohexan. c. 2, 3 - imetylbutan. d. isohexan. 43/ Dung dch X cha a mol NaAlO2. Khi thm vo dung dch X b mol hoc 2b mol HCl th lng kt ta sinh ra u nh nhau. T s a/b c gi tr a. 1,5 b. 1,25. c. 1 d. 1,75. 44/ Hn hp X cha K2O, NH4Cl, KHCO3 v BaCl2 c s mol bng nhau. Cho X vo nc d, un nng, dung dch thu c cha cht tan l a. KCl b. KCl, BaCl2 c. KCl, KOH d. KCl, KHCO3, BaCl2 3. CH3 - COO - CH2 - CH =

45/ Thu phn cc hp cht sau trong mi trng kim 1. CH3 - CHCl2 CH2 4. CH3 - CH2 - CCl3. a. 1, 2, 4, 5 5. (CH3 - COO)2CH2 b. 1, 2, 4 c. 1, 3, 5 d. 1, 2, 5
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2. CH3 - COO - CH = CH - CH3.

Nhng cht sau khi thy phn cho sn phm c phn ng trng bc l

46/ Ho tan hon ton 19,2 gam kim loi M trong dung dch HNO3 d thu c 8,96 lt (ktc) hn hp kh gm NO2 v NO c t l th tch tng ng 3 : 1 (phn dung dch khng c mui amoni). Kim loi M l a. Fe b. Cu c. Al d. Mg 47/ M t hin tng no di y l khng chnh xc ? a. t chy mt mu lng trng trng thy xut hin mi kht nh mi tc chy. b. Nh vi git dung dch HNO3 c vo dung dch lng trng trng thy kt ta mu vng. c. Trn ln lng trng trng, dung dch NaOH v mt t CuSO4 thy xut hin mu c trng. d. un nng dung dch lng trng trng thy hin tng ng t. 48/ Nhn nh no sau y ng ? a. C th phn bit glucoz v fructoz bng phn ng trng bc. b. Tinh bt c phn ng mu vi dung dch It. c. Glucoz v Fructoz c tnh cht ho hc ging nhau. d. Tinh bt v xenluloz u c to thnh t cc gc -glucoz. 49/ Cho phn ng A + 2B C + D vi tc phn ng V = k.[A].[B]2. Nu nhit khng i, nng mol cht A tng 2 ln, nng mol B tng 2 ln th tc phn ng tng a. 6 ln b. 8 ln c. 12 ln d. 4 ln 50/ Cho cc dung dch khng mu : K2S, KI, KNO3, KCl ch dng mt thuc th no sau y nhn bit cc dung dch trn ? a. dung dch AgNO3 b. dung dch BaCl2 c. qu tm d. dung dch HCl

B. Theo chng trnh Nng cao (t cu 51 n cu 60) 51/ Ho tan hon ton 19,2 gam kim loi M trong dung dch HNO3 d thu c 14,336 lt kh (ktc) hn hp kh gm NO2 v NO c t l mol tng ng 1 : 3 (dung dch khng c mui amoni). Kim loi M l
9

a. Mg 52/ Nhn nh sai l

b. Al

c. Fe

d. Cu

a. Phn t mantoz gm hai gc -glucoz ni vi nhau bi lin kt -1,6-glicozit. b. Tinh bt v xenluloz khng th hin tnh kh v trong phn t hu nh khng c nhm OH hemiaxetal t do. c. C th phn bit glucoz v fructoz bng v gic. d. Tinh bt c phn ng mu vi dung dch I2 v c cu trc vng xon. 53/ Ch dng mt thuc th no di y phn bit c ba cht lng: etanal, propan-2-on, pent-1-in. (1) dung dch Br2; a. Thuc th (1). c. Thuc th (3). (2) dung dch AgNO3/NH3; (3) H2/Ni, t0. b. Thuc th (2). d. Thuc th (1) hoc (2)

54/ Cho cc mui sau: Na2CO3, AlCl3, C6H5ONa, CH3COOK, CH3NH3Cl, CuSO4, NaHCO3, NH4NO3, BaCl2, K2SO4, C2H5ONa, NaAlO2. S mui tham gia phn ng thu phn trong nc l a. 12 b. 9 c. 10 d. 11 55/ Khi cho 0,02 mol hoc 0,04 mol CO2 hp th ht vo dung dch Ba(OH)2 th lng kt ta thu c u nh nhau. S mol Ba(OH)2 c trong dung dch l a. 0,03 b. 0,01 c. 0,02 d. 0,04 56/ A l mt cht hu c mch khng nhnh ch cha mt loi nhm chc, tc dng vi dung dch Na2CO3 d thu c mui A'. Nung A' vi vi ti xt th thu c kh metan. B l mt ancol mch h, a mol B tc dng vi Na d thu c a/2 mol H 2; a mol B lm mt mu va dung dch c a mol Br2. t a mol B thu c 3a mol CO2. A tc dng vi B thu c hp cht hu c X l a. CH3COO-CH2-CH=CH-OOCCH3 c. CH2=CH-CH2-OOCCH2COO-CH=CH2. CH=CH2. 57/ C bao nhiu cht c cng thc phn t C6H10 c kh nng tc dng vi dung dch
10

b. CH3-CH=CH-OOC-COO-CH=CH-CH3 d. CH2=CH-CH2-OOCCH2COO-CH2-

AgNO3/NH3 cho kt ta mu vng ? a. 5 b. 6 c. 4 d. 3 58/ Cho cht v c X tc dng vi mt lng va dung dch KOH un nng, thu c kh X1 v dung dch X2. Kh X1 tc dng vi mt lng va CuO nung nng thu c kh X3, H2O, Cu. C cn dung dch X2 thu c cht rn khan X4 (khng cha Clo). Nung X4 thy sinh ra kh X5 (M = 32u). Nhit phn X thu c kh X6 (M = 44u) v H2O. Cc cht X1, X3, X4, X5, X6 ln lt l a. NH3, NO, K2CO3, CO2, O2. c. NH3, N2, KNO3, O2, CO2. b.NH3, NO, KNO3, O2, CO2. d. NH3, N2, KNO3, O2, N2O.

59/ S ng phn thm c cng thc phn t C8H10O, khng tc dng vi NaOH nhng tc dng vi Na l a. 4 b. 5 c. 2 d. 3 60/ C th c bao nhiu tripeptit mch h sinh ra t hai aminoaxit: Alanin, Glyxin ? a. 6 b. 7 c. 5 d. 8 P N THI HO HC M 101
1 d 21 c 41 c 2 d 22 c 42 c 3 a 23 c 43 b 4 a 24 d 44 a 5 a 25 d 45 d 6 c 26 c 46 b 7 b 27 d 47 c 8 a 28 c 48 b 9 b 29 d 49 b 10 d 30 d 50 a 11 a 31 a 51 a 12 b 32 a 52 a 13 d 33 b 53 b 14 c 34 a 54 c 15 a 35 a 55 a 16 d 36 d 56 d 17 a 37 a 57 c 18 b 38 c 58 d 19 a 39 c 59 b 20 b 40 d 60 d

11