1. Consider the following gaseous equilibria with equilibrium constants K1 and K2 respectively.

SO2(g) + O2(g) SO3(g) 2SO3(g) 2SO2(g) + O2(g) The equilibrium constants are related as ______. (A) (B) (C) (D) 2. A compound formed by elements X and Y crystallizes in a cubic structure in which atoms X are at the corners of the cube and atoms Y are at the face-centers. The formula of the compound is (A) X3Y (B) XY (C) XY2 (D) XY3 3. 1.00 g of non-electrolyte solute (molar mass 250 g mol-1) was dissolved in 51.2 g of benzene. If the freezing point depression constant, Kf of benzene is 5.12 K kg mol-1, the freezing point of benzene will be lowered by (A) 0.3 K (B) 0.5 K (C) 0.2 K (D) 0.4 K 4. In a zero-order reaction for every 10 rise of temperature, the rate is doubled. If the temperature is increased from 10C to 100C, the rate of the reaction will become (A) 64 times (B) 128 times (C) 256 times (D) 512 times 5. The Gibbs energy for the decomposition of Al2O3 at 500C is as follows: Al2O3 Al + O2, rG = +966 kJ mol-1

The potential difference needed for electrolytic reduction of Al2O3 at 500C is at least: (A) 2.5 V (B) 5.0 V (C) 4.5 V (D) 3.0 V