S GD&T TNH VNH PHC

K THI I HC LN 2 NM HC 2012 2013 LN TH 2. THI MN: HA HC KHI A. Thi gian lm bi 90 pht, khng k thi gian giao . thi gm: 4 trang. ----------------------------

H v tn th sinh:.. S bo danh:... I. Phn chung cho cc th sinh( cu 1 ti cu 40) Cu 1: Cho cn bng: (trong bnh kn) sau: CO (k) + H2O (k) CO2 (k) + H2 (k) H < 0 Trong cc yu t: (1) tng nhit ; (2) thm mt lng hi nc; (3) thm mt lng H 2; (4) tng p sut chung ca h; (5) dng cht xc tc. Dy gm cc yu t u lm thay i cn bng ca h l: A. (1), (2), (3) B. (2), (3), (4) C. (1), (2), (4) D. (1), (4), (5) Cu 2: t chy hon ton hn hp Q gm 2 ankin X, Y. Hp th ton b sn phm chy vo 4,5 lt dung dch
Ca(OH)2 0,02M thu c kt kt ta v khi lng dung dch tng 3,78 gam so vi ban u. Cho dung dch Ba(OH)2 va vo dung dch thu thm kt ta. Tng kt ta 2 ln l 18,85 gam. Bit rng s mol ca X bng 60% tng s mol ca X v Y c trong hn hp Q. Cc phn ng xy ra hon ton. Cng thc ca X, Y ln lt l: A. C2H2 v C4H6 B. C4H6 v C2H2 C. C2H2 v C3H4 D. C3H4 v C2H6 Cu 3: phn bit CO2 v SO2 ch cn dng thuc th l:

A.dung dch Ba(OH)2 B. nc brom C. CaO D. dung dch NaOH Cu 4: Cho cc este: vinyl axetat, vinyl benzoat, etyl axetat, isoamyl axetat, phenyl axetat, anlyl axetat, s este c th
iu ch trc tip bng phn ng ca axit v ancol tng ng (c H2SO4 c lm xc tc) l: A. 5 B. 3 C. 2 D. 4 Cu 5: Nhn xt no sau y khng ng? A. T poliamit km bn trong cc mi trng axit v baz. B. Khi cho fomanehit d tc dng vi phenol, c baz xc tc thu c nha novolac. C. Saccaroz khng to kt ta khi cho vo dung dch AgNO3 trong NH3 . D. T xenluloz axetat thuc loi t ha hc. Cu 6: Tch nc hon ton 1,08 gam hn hp hai ancol thu c hn hp hai anken ng ng k tip. t chy hon ton 2 anken trn trong 2,24 lt O 2 d, lm lnh hn hp sau phn ng ngng t ht hi nc thu c 1,568 lit kh (th tch cc kh o ktc). Cng thc ca hai anken l: A. C4H8 v C5H10 B. C3H6 v C4H8 C. C5H10 v C6H12 D. C2H4 v C3H6 Cu 7: Ha hi 3,35 gam X gm CH3COOH, HCOOC2H5, CH3COOCH3, CH3COOC2H5 thu c 1,68 lt hi X ( 136,5 0C v p sut 1 atm). t chy hon ton 3,35 gam hn hp X trn th thu c m gam H2O. Gi tr ca m l A. 2,7 gam B. 3,6 gam C. 3,15 gam D. 2,25 gam Al(NO3)3 + N2O + N2 + H2O.Nu t l s mol N2O :N2 ln lt l 2:3 th h s Cu 8: Cho phn ng: Al + HNO3 cn bng ti gin ca HNO3 l: A. 138 B. 148 C. 168 D. 76 Cu 9: Trong cng nghip m Zn ln Fe ngi ta lm nh sau: A. Anot lm bng Fe, catot lm bng Zn v nhng trong dung dch FeSO4. B. Catot lm bng Zn, anot lm bng Fe v nhng trong dung dch ZnSO4. C. Anot lm bng Zn, catot lm bng Fe v nhng trong dung dch ZnSO4. D. Nhng thanh Fe vo Zn nng chy. Cu 10: Cho cc nhn xt sau: 1. Trong in phn dung dch NaCl trn catot xy ra s oxi ho nc. 2. Khi nhng thanh Fe vo dung dch hn hp CuSO4 v H2SO4 th c bn Fe b n mn in ho. 3. Trong thc t loi b NH3 thot ra trong phng th nghim ta phun kh Cl2 vo phng 4. Khi cho mt t CaCl2 vo nc cng tm thi s thu c nc cng ton phn. 5. Nguyn tc sn xut gang l kh qung st oxit bng than cc trong l cao. 6. Sc H2S vo dung dch hn hp FeCl3 v CuCl2 thu c 2 loi kt ta. 7. Dung dch FeCl3 khng lm mt mu dung dch KMnO4 trong H2SO4 long S nhn xt ng l: A. 4. B. 5. C. 3. D. 6.

Cu 11: Dy gm cc cht sp xp theo chiu tng dn ca tnh axit l A. C6H5OH < CH2=CH-COOH < CH3COOH < HCOOH. B. C6H5OH < HCOOH < CH3 COOH < CH2=CH-COOH. C. C6H5OH < CH3COOH < HCOOH < CH2=CH-COOH. D. C6H5OH < CH3COOH < CH2=CH-COOH < HCOOH. Cu 12: Hn hp X gm axit propionic, axit fomic,axit axetic v axit oxalic. Khi cho m gam X tc dng vi NaHCO 3
(d) th thu c 13,44 lt kh CO2. Mt khc, t chy hon ton m gam X cn 10,08 lt kh O2, thu c 16,8 lt kh CO2 v y mol H2O. Bit th tch cc kh o ktc. Gi tr ca y l : A. 0,7 B. 0,6 C. 0,5 D. 0,4 Cu 13: Ly 3,93 gam hn hp X gm Fe2(SO4)3 v M2SO4 (M l kim loi kim) tc dng vi dung dch BaCl2 d thu c 6,99 gam kt ta. Xc nh thnh phn % v khi lng ca M2SO4 trong hn hp X A. 32,52 B. 25,19 C. 10,84 D. 8,40 Cu 14: in phn 2 lt dung dch hn hp gm NaCl v CuSO4 n khi H2O b in phn hai cc th dng li, ti catt thu 1,28 gam kim loi v ant thu 0,336 lt kh ( ktc). Xem th tch dung dch khng i th pH ca dung dch thu c bng? A. 2,3 B. 2 C. 12 D. 3 Cu 15: Cho cc cht: Al, Zn, NaHCO3, Al2O3, ZnO, Zn(OH)2, Cr2O3, Ba, Na2O, K, MgO, Fe. S cht c th b ha tan trong c dung dch NaOH v dung dch KHSO4 l: A. 11 B. 10 C. 8 D. 9 Cu 16: Cho m gam NaOH vo 300ml NaAlO2 0,5M c dung dch X. Cho t t dung dch cha 500ml HCl 1,0M vo dung dch X, thu c dung dch Y v 7,8 gam cht kt ta. Sc CO2 vo dung dch Y thy xut hin kt ta. Gi tr ca m l: A. 4,0 gam B. 12,0 gam C. 8,0 gam D. 16,0 gam Cu 17: Oxi ho hn hp 1 ancol n chc v 1 anehit n chc thu c 1 axit hu c duy nht (Hiu sut phn ng l 100%). Cho lng axit ny tc dng ht vi m gam dung dch NaOH 2% v Na 2CO313,25% thu c dung dch ch cha mui ca axit hu c c nng 21,87%. Tn gi ca anehit ban u l: A. etanal B. metanal C. Butanal D. Propanal Cu 18: Cho cc d kin thc nghim: (1) Cho dung dch NaOH d vo dung dch Ca(HCO3)2; (2) Cho Ba vo dung dch Ba(HCO3)2; (3) cho Ba vo dung dch H2SO4 long; (4) Cho H2S vo dung dch FeSO4; (5) Cho SO2 n d vo dung dch H2S (6) Cho NaHCO3 vo dung dch BaCl2; (7) Sc d NH3 vo Zn(OH)2; (8) dung dch NaAlO2 d vo dung dch HCl S trng hp xut hin kt ta khi kt thc th nghim l ? A. 8 B. 5 C. 6 D. 4 Cu 19: X phng ha hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l: A.17,80 gam. B. 18,24 gam. C. 16,68 gam. D. 18,38 gam. Cu 20: Cho s sau:
Cl Cl NaOHH 2 O(t , e ol( ) e ol( ) (CH3)2CH-CH2CH2Cl KOH/tant A H B KOH/tant C H D ) E E c cng thc cu to l A. (CH3)2CH-CH2CH2OH B. (CH3)2C=CHCH3. C. (CH3)2CH-CH(OH)CH3. D. (CH3)2C(OH)-CH2CH3. Cu 21: Cho 33,35 gam hn hp A gm Fe3O4, Fe(NO3)3, Cu tc dng hon ton vi dung dch cha 0,414 mol H2SO4 (long) th thu c kh NO duy nht v dung dch B ch cha 2 mui. C cn B thu c bao nhiu gam mui khan? A. 64,400 hoc 61,520 B. 65,976 hoc 61,520 C. 73,122 hoc 64,400 D. 65,976 hoc 75,922 Cu 22: X l hn hp AlBr3 v MBr2. Ly 0,1 mol X nng 24,303 gam tc dng vi dung dch AgNO3 d thu c 52,64 gam kt ta. Xc nh % v khi lng AlBr3 trong X? A. 47,10% B. 58,23% C. 41,77% D. 51,63% Cu 23: Trong cc phn ng sau, xy ra trong dung dch : 1. Na2CO3 + H2SO4 2. Na2CO3 + FeCl3 3. Na2CO3 + CaCl2 4. NaHCO3 + Ba(OH)2 5. (NH4)2SO4 + Ba(OH)2 6. Na2S + AlCl3 Cc phn ng c to ng thi c kt ta v kh bay ra l: A. 1, 3, 6 B. 2, 5, 6 C. 2, 3, 5 D. 2, 4, 6 Cu 24: Trong cc dung dch sau: (1) saccaroz, (2) 3-monoclopropan1,2-iol (3-MCPD), (3) etilenglycol, (4) ipeptit, (5) axit fomic, (6) tetrapeptit, (7) propan-1,3-iol. S dung dich c th ha tan Cu(OH)2 l
0 0 0

A. 4 B. 6 C. 3 D. 5 Cu 25: Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CaCl2, Ca(NO3)2, NaOH, Na2CO3, KHSO4, Na2SO4,
Ca(OH)2, H2SO4, HCl. S trng hp c to ra kt ta l A. 5. B. 6. C. 7. D. 4. Cu 26: Cac cht u khng bi thuy phn trong dung dich H2SO4 loang, nong la A. poli (vinyl axetat); polietilen, cao su buna. B. t capron; nilon-6,6, polietylen. C. nilon-6,6; poli(etylen-terephtalat); polistiren. D. polietilen; cao su buna; polistiren. Cu 27: Cho hn hp Mg, Al v Fe vo dung dch AgNO3, n phn ng hon ton thu c cht rn X v dung dch Y. Cho dung dch Y tc dng vi NaOH d thu c kt ta Z. Nung Z trong khng kh ti khi lng khng i thu c hn hp cht rn T cha 3 cht rn khc nhau. Vy trong dung dch Y cha cc cation: A. Mg2+, Fe3+, Ag+. B. Mg2+, Al3+, Fe3+, Ag+. 2+ 3+ 2+ 3+ C. Mg , Al , Fe , Fe . D. Mg2+, Al3+, Fe2+, Fe3+, Ag+. Cu 28: Monome khi tham gia phn ng trng hp iu kin nhit , p sut v xc tc thch hp to cao su BuNa l: A. buta-1,2-ien B. But-1-en C. Buta-1,3-ien D. But-2-en Cu 29: Cho cc phn ng: (1) O3 + dung dch KI; (2) F2 + H2O; (3) MnO2 + HCl (to); (4) H2S + dung dch Cl2 d; (5) Cl2 + NH3 d; (6) CuO + NH3 (to); o o (7) KMnO4 (t ); (8) H2S + SO2; (9) NH4Cl + NaNO2 (t ); (10) NH3 + O2 (Pt, 800oC). S phn ng to ra n cht l A. 6 B. 8 C. 9 D. 7 Cu 30: Ly 5,2 gam hn hp FeS2 v Cu2S tc dng hon ton vi dung dch HNO3 th thu c dung dch ch cha 2 mui v 12,208 lt hn hp NO2 v SO2 (ktc). Xc nh % v khi lng ca FeS2 trong hn hp ban u A. 71,53% hoc 81,39% B. 93,23% hoc 71,53% C. 69,23% hoc 81,39% D. 69,23% hoc 93,23% Cu 31: Hn hp X gm 2 ancol. t chy hon ton 8,3 gam X bng 10,64 lt O2 thu c 7,84 lt CO2, cc kh o ktc. Hai ancol l: A. HOCH2CH2CH2OH v CH3CH2CH2CH2OH. B. CH3CH2CH2OH v CH3CH2CH2CH2OH. C. CH3CH2CH2OH v OHCH2CH2CH2OH. D. HOCH2CH2CH2OH v HOCH2CH2CH2CH2OH. Cu 32: Ly 3,51 gam hn hp Al, Zn tc dng vi dung dch HNO 3 d th thu c 1,344 lt (ktc) kh X l sn phm kh duy nht. Xc nh X? A. NO2 B. N2 C. NO D. N2O Cu 33: Theo danh php IUPAC ancol (CH3)2C=CHCH2OH c tn gi l: A. 3-metylbut-2-en-1-ol. B. pent-2-en-1ol. C. ancol iso-pent-2-en-1-ylic. D. 2-metylbut-2-en-4-ol. Cu 34: Tin hnh in phn 100 ml dung dch Fe(NO3)3 1M v Cu(NO3)3 1M trong bnh in phn vi in cc tr, I=19,3A, sau mt thi gian ly catot ra cn li thy n nng thm 3,584 gam (gi thit rng ton b kim loi sinh ra u bm vo catot). Tnh thi gian in phn? A. 1060 giy B. 960 giy C. 560 giy D. 500 giy

Cu 35: Cu 36: Nhit phn hon ton hn hp A gm Fe(NO3)3 v Cu(NO3)2 thu c hn hp kh X v cht rn Y. Hp th
ht X vo nc c dung dch Z, kh hon ton Y bng CO d c cht rn T. T tan va ht trong dung dch Z (to kh NO duy nht). % v khi lng Cu(NO3)2 trong A c th l? A. 36,81% B. 60,84% C. 27,98% D. 43,72% Cu 37: Dy no sau y c sp xp tng dn theo th t nhit si: A. C2H5OH, C2H5Cl, CH3COOH, C6H5OH. B. C2H5Cl, C2H5OH, CH3COOH, C6H5OH. C. C2H5Cl, C2H5OH, C6H5OH, CH3COOH. D. C2H5Cl, C6H5OH , C2H5OH, CH3COOH Cu 38: Cho cc qu trnh ha hc : 1. Sc kh H2S vo dung dch FeCl3 2. Dung dch AlCl3 tc dng vi dung dch Na2S 3. Hidrat ha C2H4 4. Nhit phn CaOCl2 5. KF tc dng vi H2SO4 c, nng 6. in phn dung dch NaCl 7. Al4C3 tc dng vi dung dch HCl 8. n mn gang, thp trong khng kh m C bao nhiu qu trnh xy ra phn ng oxi ha kh? A. 5 B. 7 C. 6 D. 4

Cu 39: Hai hp cht X, Y c cng cng thc phn t C 4H7ClO2 tc dng vi dung dch NaOH thu c cc sn phm
sau: X + NaOH mui hu c X1 + C2H5OH + NaCl Y + NaOH mui hu c X2 + C2H4(OH)2 + NaCl Cng thc cu to c th ca X, Y ln lt l: A. CH3-CHCl-COOC2H5 v CH3COOCHCl-CH3 B. ClCH2-COOC2H5 v CH3COOCH2CH2Cl C. ClCH2-COOC2H5 v CH3COOCHCl-CH3 D. CH3COOCHCl-CH2Cl v CH3COOCH2CH2Cl Cu 40: Aminoaxit X c 1 nhm NH2. Cho 0,01 mol aminoaxit X tc dng va vi 200ml dung dch NaOH 0,1M. Mt khc 0,03 mol X tc dng vi 40g dung dch NaOH 7,05% c cn dung dch thu c 6,15 gam cht rn. Cng thc ca X l A. (H2N)2C3H5COOH B. H2NC4H7(COOH)2 C. H2NC2H3(COOH)2. D. H2NC3H5(COOH)2. Cu 41: Cho m gam hn hp A gm Al4C3 v CaC2 vo nc d thu c dung dch X; a gam kt ta Y v kh hn hp kh Z. Lc b kt ta. t chy hon ton kh Z ri dn sn phm chy vo dung dch X thu c thm a gam kt ta na. Hi trong hn hp X, Al4C3 v CaC2 c trn vi t l mol th no A. 1: 1 B. 1:3 C. 1:2 D. 2:1 Cu 42: Cho 20 g hn hp 3 amin no n chc l ng ng lin tip ca nhau, tc dng va vi dung dch HCl, c cn dung dch thu c 31,68g hn hp mui. Nu 3 amin trn c trn vi t l s mol 1:10:5 theo th t phn t khi tng dn th cng thc ca 3 amin l: A. C4H9NH2, C5H11NH2 , C6H13NH2. B. CH3NH2, C2H5NH2, C3H7NH2. C. C2H5NH2, C3H7NH2, C4H9NH2. D. C3H7NH2, C4H9NH2, C5H11NH2. Cu 43: thu c 120 gam axit axetic cn ln men bao nhiu lt ancol etylic 350 . Bit rng khi lng ring ancol etylic nguyn cht l 0,8 g/ml v hiu sut qu trnh ln men dm l 75%. A. 0,438 lt B. 0,635 lt C. 0,0537 lt D. 0,246 lt Cu 44: Cho cc dung dch sau: (1): dung dch C6H5NH2; (2): dung dch CH3NH2; (3): dung dch H2N-CH2COOH; (4): dung dch C6H5ONa; (5): dung dch Na2CO3; (6): dung dch NH4Cl. Nhng dung dch lm xanh qu tm l: A. (1); (2); (4); (5). B. (3); (4); (6). C. (2); (4); (5). D. (2); (5). Cu 45: C bao nhiu nguyn t tha mn iu kin trong mi nguyn t ca nguyn t ( trng thi c bn) c tng s e trn cc phn lp s l 8? A. 6 B. 7 C. 15 D. 17 Cu 46: Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc nung nng, thu c hn hp Y gm C2H4, C2H6, C2H2 v H2. Sc Y vo dung dch brom (d) th khi lng bnh brom tng 19 gam v thot ra 4,48 lt hn hp kh (ktc) c t khi so vi H2 l 8,5. Th tch O2 (ktc) cn t chy hon ton hn hp Y l A. 22,4 lt. B. 26,88 lt. C. 58,24 lt. D. 53,76 lt. Cu 47: Cho hn hp X gm C3H7COOH, C4H8(NH2)2, HO-CH2- CH=CH-CH2OH. t chy hon ton m gam hn hp X, sn phm chy hp th hon ton vo dung dch Ca(OH) 2 thy to ra 20g kt ta v dung dch Y. un nng dung dch Y thy xut hin kt ta. C cn dung dch Y ri nung cht rn thu c n khi lng khng i thu c 5,6 gam cht rn. Gi tr ca m l A. 8,2 B. 5,4 C. 8,8 D. 7,2 Cu 48: Cho hn hp bt cha 0,01 mol Al v x mol Fe vo 200 ml dung dch hn hp AgNO 3 0,2M v Cu(NO3)2 0,1M. n phn ng hon ton thu c dung dch A v 6,16 gam kim loi. Gi tr ca x l: A. 0,035 mol. B. 0,05 mol. C. 0,03 mol. D. 0,025 mol. Cu 49: Mt ancol 2 chc phn t khng cha nguyn t C bc 3. un nng nh m gam hi ancol trn vi CuO d n khi phn ng xy ra hon ton thy khi lng cht rn trong bnh gim 2,24 gam ng thi thu c hn hp kh v hi c t khi so vi H2 l 18. m c gi tr l: A. 5,32 gam B. 1,54 C. 7,84 gam D. 12,88 gam Cu 50: a mt hn hp kh N2 v H2 c t l 1: 3 vo thp tng hp, sau phn ng thy th tch kh i ra gim 1/10 so vi ban u. Hiu sut ca phn ng tng hp NH3 l A. 25%. B. 20%. C. 15%. D. 10%.