UBND TNH THI NGUYN

K THI CHN HSG LP 12

NM HC 2012 2013
(tp ny gm 08 trang)

S GIO DC V O TO

Mn thi: HO HC (GII TON BNG MTCT)

Hi ng

S phch

thi: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
................................................
..............
H tn th sinh: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.........
Phng thi . . . . . . . . . . S bo danh . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
GIM TH 1
GIM TH 2
(K ghi r h tn)

(K ghi r h tn)

UBND TNH THI NGUYN

K THI CHN HSG LP 12

NM HC 2012 2013
(tp ny gm 08 trang)

S GIO DC V O TO

Mn thi: HO HC (GII TON BNG MTCT)

Hi ng thi: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . S phch
...............................................
...........
H tn th sinh:
.............................................
1

 THI

S PHCH

Phng thiCHN
. . . . . HSG
. . . . .TNH
S bo
danh
. . . . BNG
. . . . . . MTCT
...................
GII
TON
GIM TH
GIM TH 2
NM1 HC 2012-2013

(K ghi
r h
tn) HC LP 12 (VNG 1)
(K ghi r h tn)
MN
THI:
HO
(Thi gian lm bi 120 pht khng k thi gian giao )

im bng s

im bng ch

Gim kho (k, h tn)

1............................
2.............................

(Cho H=1; C =12; N=14; O=16; Na=23; Mg=24; P=31; S=32; Cl=35,5;
K=39; Fe=56;
Cu=64; Br=80; Ag=108.)

Th sinh lm bi vo ch trng sau mi cu hi; kt qu mi php tnh phi ly 8

ch s sau du phy nu c.
Cu 1 (5,0 im)
8200C hng s cn bng Kp ca cc phn ng nh sau:
CaCO3 (tt)
CaO (tt) + CO2 (k)
C gr + CO2(k)
2CO (k)

K1 = 0,2
K2 = 2

Cho 1 mol CaCO3 v 1 mol C vo bnh chn khng th tch 22,4 lt duy tr 8200C.
a) Tnh s mol cc cht khi cn bng.
b) Cn mt bnh th tch l bao nhiu th s phn hy CaCO3 s xy ra hon ton.
Cch gii
Kt qu

im

Cu 2 (5,0 im)
Cho 6,2 gam hn hp X gm 2 kim loi kim A, B thuc 2 chu k lin tip trong bng tun
hon (MA < MB) tan ht trong nc d thu c 2,24 lt kh H2 o iu kin tiu chun ( ktc)
v dung dch Y.
a) Xc nh A, B.
b) Tnh % khi lng mi kim loi trong hn hp u.
c) trung ha ht dung dch Y trn cn va V lt dung dch HCl 0,2M. Tnh V.
Cch gii
Kt qu
im

Cu 3 (5,0 im)
Ho tan hon ton m gam bt nhm trong dung dch cha HCl v HNO3 thu c 3,36 lt hn
hp Y gm hai kh khng mu, dung dch cn li ch cha mui ca cation Al 3+. em ton b
lng hn hp kh Y trn vi 1 lt oxi thu c 3,688 lt hn hp gm 3 kh. Bit th tch cc
kh u o ktc v khi lng ca hn hp kh Y nh hn 2 gam. Tm m.
Cch gii
Kt qu
im

Cu 4 (5,0 im)
Cho 10,62 gam hn hp gm Fe, Zn vo 800 ml dung dch hn hp X gm NaNO3 0,45 M v
H2SO4 0,9M. un nng cho phn ng xy ra hon ton thu c dung dch Y v 3,584 lt kh NO
sn phm kh duy nht ca NO3-, o ktc. Dung dch Y ha tan ti a m1 gam bt Cu v thu c
V lt kh NO ktc v l sn phm kh duy nht ca NO3-.
1) Tnh % khi lng tng kim loi trong hn hp ban u.

2) Tnh gi tr m1 v V.
3) Cho m2 gam Zn vo dung dch Y to kh NO l sn phm kh duy nht ca NO3-, sau phn
ng thu c 3,36 gam cht rn. Tnh gi tr m2.
Cch gii
Kt qu
im

Cu 5 (5,0 im)
1. Mt dung dch cha Ba(OH)2 v NaOH nng ln lt l 0,2M v 0,1M. Cho CO2 hp th
t t vo 200ml dung dch trn ta c 4 gam kt ta. Tnh th tch CO2 ktc c hp th.
2. C 2 kim loi A v B . Khi lng nguyn t u l mt s gm 2 ch s a v b (a v b
khc 0 v a>b). Khi lng nguyn t ca A l ab v khi lng nguyn t ca B l ba. Hiu 2
s khi lng nguyn t nh hn 10. Tng s hai khi lng nguyn t nm trong khong t
100 n 140. Hy xc nh 2 kim loi A v B.
Cch gii
Kt qu
im

Cu 6 (5,0 im)
Dung dch X cha HCl 4M v HNO 3 aM. Cho t t Mg vo 100 ml dung dch X cho ti khi
kh ngng thot ra thy tn ht b gam Mg, thu c dung dch B ch cha cc mui ca Mg v
thot ra 17,92 lt hn hp kh Y gm 3 kh. Cho Y qua dung dch NaOH d thy cn li 5,6 lt
hn hp kh Z thot ra c dZ / H2 =3,8. Cc phn ng xy ra hon ton. Th tch cc kh u o
ktc. Tnh a, b?
Cch gii
Kt qu
im