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  • 811.2 - The Generic Name "Amine'' Is Applied To Compounds NH2R

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    Anaiza Echelon
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    The document defines primary, secondary, and tertiary amines as compounds with the structures NH2R, NR2, and R3N, respectively. It notes that compounds containing nitrogen in a ring that owe their basicity to the nitrogen atom may also be referred to as amines. When an -NH2 group is not the principal group, it is named with the prefix "amino-". Radicals like RNH-, R2N-, are named as substituted amino groups by changing "ine" of the amine to "ino". Some trivial names are retained, such as those given in examples.

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    The document defines primary, secondary, and tertiary amines as compounds with the structures NH2R, NR2, and R3N, respectively. It notes that compounds containing nitrogen in a ring that owe their basicity to the nitrogen atom may also be referred to as amines. When an -NH2 group is not the principal group, it is named with the prefix "amino-". Radicals like RNH-, R2N-, are named as substituted amino groups by changing "ine" of the amine to "ino". Some trivial names are retained, such as those given in examples.

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    4 views3 pages

    811.2 - The Generic Name "Amine'' Is Applied To Compounds NH2R

    Uploaded by

    Anaiza Echelon
    The document defines primary, secondary, and tertiary amines as compounds with the structures NH2R, NR2, and R3N, respectively. It notes that compounds containing nitrogen in a ring that owe their basicity to the nitrogen atom may also be referred to as amines. When an -NH2 group is not the principal group, it is named with the prefix "amino-". Radicals like RNH-, R2N-, are named as substituted amino groups by changing "ine" of the amine to "ino". Some trivial names are retained, such as those given in examples.

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    811.

    2 - The generic name "amine'' is applied to compounds NH2R, , and , which are called primary, secondary, and tertiary amines, respectively. In a wider sense, compounds containing nitrogen in a ring and owing their basicity to this atom may also be referred to as "amines". 811.3 - An -NH2 group, when not the principal group, is named by the prefix "amino-".
    Examples to Rule C-811.3

    Note: In Beilstein's Handbuch der organischen Chemie use of the prefix "amino-" is permitted as an alternative, when -NH2 is the principal group, but this method is not recommended here; it leads to names such as 1-aminobutane, 2-aminopentane, and 1aminoanthracene. 811.4 - Radicals RNH-, R2N-, and changing "ine'' of the amine to "ino".
    Examples to Rule C-811.4

    are named as substituted amino groups by

    The following are examples of trivial names which are retained:

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