Q15. Q16.

Calculate the pressure exerted by one mole of CO2 gas at 273 K if the der Waals constant a= 3.592 dm3 aatm mol-2. Assume that the volume occupied by C)2 molecules is neglible. Using van der Waals equation, calculate the constant a when two moles of a gas confined in a four litre flask exerts a pressure of 11.0 atmospheres at a temperature of 300 K. The value of b is 0.05 lit mol-1 100 g of CO2 are contained in a 5 litre globe at 400C. Calcul and (ii) as a real gas (a=3.59, b = 0.043). ate its pressure (i) as an ideal gas,

Q17. Q21.

The compression factor (compressibility factor) for one mole of a van der Waals gas at 00C and 100 atmosphere pressure is found to be 0.5. Assume that the volume of gas molecules is negligible, calculate the van der Waals constant a.

*Q22. The density of the vapour of a substance at 1 atm pressure and 500 K is 0.36 kg m-3. The vapour effuses through a small hole at a rate of 1.33 times faster than oxygen under the same condition. (a) Determine (i) molecular weight, (ii) molar volume, (iii) comperssion facter (Z) of the vapour and (iv) which frorces among the gas molecules are dominating, the attreactiver or the repulsive ? (b) If the vapour behaves ideally at 1000 K, determine the average translational kinetic energy of a molecule. Q99. van der Waals equation explains the behaviour of (a) all gaseous substances (b) ideal gases (c) real gases (d) none of the above Q101. van der waals, constains a and b correspond to the following respectively (a) intermolecular attraction and bond energy (b) actual volume of the molecules and intermolecular repulsion (c) shaps of molecules and intermolecular repulsion (d) intermolecular attraction and actual volume of the molecules Q:102. In van der waals, equation of state of the gas law, the constant b is a measure of (a) volume occupied by the molecules (b) intermolecular attraction (c) intermolecular repulsIions (d) intermolecular collisions per dnit volume Q103. In van der Waals equation of state for a non-ideal gas, the term that accous for intermolecular forces is (a) V b (b) RT a (c) P 2 (d) (RT)-1 (I.I.T.1988) V Q141. Which of the following statements is incorrect of ideal gaseus behaviour (a) all the molecules are identical and have intermolecular forces of attraction (b) the gaseous molecules exchange energies during molecular collisions (c) the collisions are inelastic (d) all of the above