THI TH LN I

S GIO DC V O TO H NI
TRNG THPT CHU VN AN

K THI TUYN SINH I HC, CAO NG NM 2010

MN HO HC
Thi gian lm bi: 90 pht

( thi gm 6 trang)
M thi 132
H, tn th sinh:.......................................................................
S bo danh:............................................................................
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39;
Ca = 40; Sr = 88; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80;
Ag = 108; Sn = 119; Ba = 137; Pb = 207; I = 127.
I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)
Cu 1: t chy hon ton ancol n chc X thu c hn hp CO2 v H2O c t khi hi so vi H2
l 133/9. Khi thc hin phn ng tch nc t X ch thu c 1 hirocacbon. C bao nhiu cng thc
cu to ca X ph hp vi cc iu kin trn
A. 5.
B. 3.
C. 4.
D. 2.
Cu 2: Hn hp gm 2 axit no X v Y. t chy hon ton 0,3 mol hn hp thu c 11,2 lt kh
CO2 (ktc). trung ha 0,3 mol hn hp cn 500ml dung dch NaOH 1M. Hai axit l
A. CH3COOH v C2H5COOH
B. HCOOH v C2H5COOH
C. HCOOH v HOOC-COOH
D. CH3COOH v HOOC-CH2-COOH
Cu 3: Phenol tc dng c vi tt c cc cht sau:
A. Na, NaOH, NaHCO3, Br2.
B. Na, NaOH, HCl, Br2.
C. Na, NaOH, NaCl, Br2.
D. K, KOH, Br2, HNO3.
Cu 4: Cho 175 gam lipit c ch s axit l 8 tc dng vi dung dch KOH d, sau phn ng, khi
lng mui thu c l 191,15 gam. Khi lng KOH tham gia phn ng l
A. 28,6 gam.
B. 16,5 gam.
C. 14 gam.
D. 35 gam.
Cu 5: t chy hon ton a gam mt hn hp X gm CH4O v C2H6O, hp th ton b sn phm
chy vo 150 ml dung dch Ba(OH)2 1M thy c kt ta v khi lng dung dch gim 4,6 gam.
Thm dung dch Ba(OH)2 d vo li thy c 19,7 gam kt ta na. Gi tr ca a l
A. 3,2.
B. 6,4.
C. 4,2.
D. 5,5.
Cu 6: Trong s cc dung dch sau: (1) glucoz, (2) 3-monoclopropan-1,2-iol (3MCPD), (3)
etilenglicol, (4) KOH long, (5) tripeptit, (6) amoniac, (7) propan-1,3-iol. S cc dung dch ho tan
c Cu(OH)2 l
A. 3.
B. 4.
C. 5.
D. 6.
Cu 7: Oxi ho 1 ancol n chc X bng CuO un nng c anehit Y. Oxi ho khng hon ton Y
bng O2 thu c axit Z. Cho Z tc dng vi X thu c m gam este. Thu phn m gam este ny
bng dung dch KOH va th thu c m1 gam mui khan. Nu thu phn m gam este bng dung
dch Ca(OH)2 va th lng mui khan thu c l m2 gam. Bit m2 < m < m1, cng thc ca Y l
A. CH3CHO.
B. C2H5CHO.
C. C2H3CHO.
D. HCHO.
Cu 8: Cho H2SO4 + X
SO2 + Bit s mol SO2 sinh ra bng s mol X tham gia phn
ng. Vy trong s cc cht: (1) Cu, (2) MgSO3, (3) S, (4) C, (5) Fe3O4, (6) MgBr2, X c th l:
A. (2), (4), (5).
B. (1), (2), (6).
C. ( 2), (5), (6).
D. (1), (2), (5).
Cu 9: Cho cc cht
1. CH3OH.
2. MgO.
3. NaOH.
4. dung dch AgNO3/NH3 d.
5. Cu.
6. Cu(OH)2.
s cht c th phn ng vi axit fomic l (cc iu kin phn ng coi nh )
A. 4.
B. 6.
C. 5.
D. 3.
Trang 1/6 - M thi 132

Cu 10: Ha tan hon ton mt oxit kim loi bng mt lng va dung dch H2SO4 10%, sau phn
ng thu c dung dch A ch cha mt mui c nng 11,8%. Kim loi l
A. Zn
B. Mg
C. Fe
D. Pb.
Cu 11: Chuyn ho hon ton 5,2 gam hn hp X gm 2 anehit n chc thnh hn hp Y gm 2
axit n chc. tc dng ht vi Y cn 150 gam dung dch NaOH 4%. Mt khc, ly 5,2 gam hn
hp X cho tc dng vi lng d dung dch AgNO3/NH3, sau phn ng, thy khi lng dung dch
gim 48,8 gam. Hai anehit l
A. HCHO v C2H5CHO
B. HCHO v CH3CHO.
C. CH3CHO v C2H5CHO.
D. HCHO v C2H3CHO.
Cu 12: C cc dung dch: AlCl3, Cu(NO3)2, FeCl3, FeCl2, Na2SO4 ng trong cc l ring bit. Cho
rt t t dung dch NH3 n d vo cc dung dch trn. Sau khi cc phn ng xy ra hon ton, c bao
nhiu l thu c kt ta?
A. 3.
B. 2.
C. 4.
D. 1.
Cu 13: Cho 6,4 gam hn hp 2 kim loi nhm IIA, 2 chu k lin tip tc dng vi dung dch
H2SO4 10% d, thu c 4,48 lt kh (ktc). Phn trm v khi lng ca kim loi c khi lng mol
nguyn t (M) nh hn l
A. 62,5%
B. 37,5%
C. 31,25%.
D. 68,75%.
Cu 14: Cho 200 ml dung dch hn hp NaOH 0,5M v Ba(OH) 2 0,1M vo 100 ml dung dch hn
hp H2SO4 0,2 M v Al2(SO4)3 0,15M. Sau khi cc phn ng xy ra hon ton, khi lng kt ta thu
c l
A. 7 gam.
B. 62,2 gam.
C. 6,22 gam.
D. 4,66 gam.
Cu 15: C cc cht: NaCl, Ca(OH)2, HCl, Na2CO3. Cp cht no sau y lm mm c nc cng
tm thi
A. Ca(OH)2, Na2CO3. B. NaCl, Ca(OH)2.
C. Ca(OH)2, HCl.
D. HCl, Na2CO3.
Cu 16: Cho 0,1 mol cht X c cng thc phn t C 2H8O3N2 tc dng vi dung dch cha 0,2 mol
NaOH un nng, thu c mt cht kh lm xanh giy qu m v dung dch Y. C cn dung dch Y
khi lng cht rn khan thu c l
A. 15 gam.
B. 5,7 gam.
C. 12,5 gam.
D. 21,8 gam.
Cu 17: Cho 0,92 gam hn hp axetilen v anehit axetic tc dng vi lng d dung dch AgNO 3
trong NH3 thu c 5,64 gam cht rn. Phn trm v khi lng ca anehit axetic trong hn hp trn
l
A. 28,26%.
B. 71,74%.
C. 67,73%.
D. 32,27%.
Cu 18: C cc phn ng sau:
NH3 + HCl
NH4Cl.
(1).
+
+
NH3 + H
NH4 .
(2)
NH3 + Cl2
N2 + HCl.
(3)
Khi cho kh Cl2 tc dng vi kh NH3 to khi trng, th t phn ng xy ra ln lt l
A. (1) v (3).
B. (1) v (2).
C. (3), (1) v (2).
D. (3) v (1).
Cu 19: t chy hon ton m gam este n chc X cn va 20,16 lt O2, sn phm thu c gm
17,92 lt CO2 v 7,2 gam H2O (cc th tch kh o iu kin tiu chun). Mt khc, khi thu phn X
trong mi trng kim th thu c 2 mui. C bao nhiu cng thc cu to tho mn tnh cht ca X
l
A. 5.
B. 1.
C. 4.
D. 3.
Cu 20: Hn hp A c khi lng 53,4 gam gm Cu, Al, Fe. Cho A tc dng vi khng kh thu c
cht rn A1 gm cc oxit c khi lng 72,6 gam. ho tan ht A1 ngi ta cn dng V ml dung
dch hn hp HCl 1M v H2SO4 0,5M . V c gi tr l
A. 600
B. 1200
C. 60
D. 1000
Cu 21: T khi hn hp X gm: C2H6; C2H2; C2H4 so vi H2 l 14,25. t chy hon ton 11,4 gam
X, cho sn phm vo bnh ng dung dch Ca(OH)2 d thy khi lng bnh tng m gam v c a gam
kt ta. Gi tr ca m v a ln lt l
A. 51,4 v 80.
B. 68,50 v 40.
C. 62,4 v 80.
D. 73,12 v 70.
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Cu 22: Cumen cn c tn l isopropylbenzen. Khi cho cumen phn ng vi Br 2 c xc tc Fe bt v

un nng thu c sn phm chnh l
A. 4-brom isopropylbenzen.
B. 2-brom-2-phenylpropan.
C. 1-brom-2-phenylpropan.
D. 3-brom isopropylbenzen.
Cu 23: Thm 150 ml dung dch NaOH 2M vo cc cha 100 ml dung dch AlCl3 xM, khuy u
cho ti khi phn ng xy ra hon ton thy trong cc c 7,8 gam kt ta. Thm tip vo cc 100 ml
dung dch NaOH 2M, khuy u khi kt thc cc phn ng tng lng kt ta thu c l 10,92 gam.
Gi tr ca x l
A. 3,2.
B. 1,0.
C. 2,0.
D. 1,6.
Cu 24: Hn hp 3 kim loi Al, Mg, Cu c ha tan hon ton trong dung dch H 2SO4 thu c 1,12
lt (ktc) mt cht kh duy nht. S mol H2SO4 tham gia phn ng l
A. 0,25.
B. 0,15.
C. 0,1.
D. 0,2.
n+
Cu 25: Ion X tn ti trong dung dch v c cu hnh electron l [Ar] 3d10. Vy s electron lp
ngoi cng ca nguyn t nguyn t X
A. l 1 hoc 2.
B. ch c th l 1.
C. l 3.
D. ch c th l 2.
Cu 26: Mt lt kh hiro giu teri 21 D iu kin tiu chun nng 0,10 gam. Phn trm v s
lng nguyn t 21 D trong loi kh hiro l (coi hiro ch c hai loi ng v 11 H v 21 D)
A. 12,0%
B. 0,2%
C. 99,8%
D. 88%.
Cu 27: Kt lun no sau y ng:
A. I2 c dng lm thuc th nhn ra xenluloz.
B. Trong qu trnh tiu ho, tinh bt b thu phn ch yu nh axit HCl c trong dch v d dy .
C. Phn ng quang hp c th to ra c glucoz.
D. Fructoz tham gia phn ng trng gng chng t fructoz c nhm CHO.
Cu 28: Tm nhn xt ng:
A. Khi thay i bt k 1 trong 3 yu t: p sut, nhit hay nng ca mt h cn bng ho hc
th h s chuyn dch sang mt trng thi cn bng mi.
B. Trong bnh kn, phn ng 2SO2 + O2
2SO3 trng thi cn bng. Thm SO2 vo ,
trng thi cn bng mi, ch c SO3 l c nng cao hn so vi trng thi cn bng c.
C. Trong bnh kn tn ti cn bng 2NO2(nu)
N2O4. Nu ngm bnh trn vo nc
thy mu nu trong bnh nht dn. iu chng t chiu nghch ca phn ng l chiu thu nhit.
D. Khi thm cht xc tc, hiu sut phn ng tng hp NH3: N2 + H2
NH3 s tng.
Cu 29: Cho 21,9 gam mt amin tc dng vi lng d dung dch FeCl 3, sau phn ng thu c 10,7
gam kt ta. Cng thc ca amin l
A. CH3NH2
B. C4H7NH2
C. C3H7NH2
D. C4H9NH2
Cu 30: Cho cc dung dch c cng nng (1) CH3NH3Cl, (2) C6H5NH3Cl, (3) NH2-CH2-COOH,
pH cc dung dch trn tng dn theo th t t tri qua phi l
A. (2), (1), (3).
B. (1), (2), (3).
C. (3), (1), (2).
D. (2), (3), (1).
Cu 31: Dy nhng dung dch phn ng vi dung dch Ba(HCO3)2 to ra kt ta l
A. Ca(OH)2, KHSO4, Na2SO4, NaOH.
B. Ba(OH)2, HCl, Na2SO4, NaOH.
C. NaOH, Na2SO4, Ca(OH)2, MgCl2.
D. NaOH, Ca(OH)2, KHSO4, Mg(NO3)2.
Cu 32: Cho cc polime sau:
(1) Nha PVC, (2) thu tinh hu c (Plexiglas), (3) t capron, (4) nha bakelit, (5) cao su
isopren, (6) t lapsan.
S lng nhng polime c iu ch bng phn ng trng hp l:
A. 3.
B. 4.
C. 2.
D. 5.
Cu 33: in phn 1 lt dung dch X gm Cu(NO3)2 v AgNO3 vi cng dng in 0,804 A n
khi bt kh bt u thot ra cc m th mt thi gian l 2 gi, khi khi lng cc m tng thm l
3,44 gam. Nng ca Cu(NO3)2 trong dung dch X
A. 0,02M.
B. 0,01M.
C. 0,08M
D. 0,04M.
Cu 34: C bao nhiu hp cht thm X - cng thc phn t C8H10O - tham gia dy chuyn ho
Trang 3/6 - M thi 132

-H

2O

polime ?
A. 1
B. 2
C. 3
D. 4.
Cu 35: X l hn hp 2 kim loi Zn v Al, cho X tc dng va vi 4 gam Br 2 v 12,7 gam I2. Sau
phn ng thu c 19,46 gam cc mui bromua v iotua. Khi lng ca Al trong hn hp X l
A. 0,81 gam.
B. 0,54 gam.
C. 1,08 gam.
D. 0,27 gam.
Cu 36: Hn hp kh A gm O2 v O3, t khi ca A so vi H2 bng 20. Hn hp kh B gm CO v
H2. S mol hn hp A cn dng t chy hon ton 1 mol hn hp kh B l :
A. 0,6.
B. 0,8.
C. 0,4.
D. 1.
Cu 37: Cho s chuyn ho sau y:
X
C3H6Br2
Y CuO ; t C Z
,
Bit 1 mol Z khi tc dng vi lng d dung dch AgNO3/NH3 d thu c 4 mol Ag. X l
A. mt ankin.
B. mt anken.
C. mt ankaien.
D. mt xicloankan.
Cu 38: Mt bnh kn, dung tch khng i ng kh oxi t0C v P1 atm. Sau khi phng tia la in
chuyn O2 thnh O3 bnh c a v nhit ban u, p sut trong bnh lc ny l 0,975P 1 atm,
hiu sut ca phn ng ozn ho l
A. 5%.
B. 10%.
C. 7,5%.
D. 15%.
Cu 39: Bit rng ion Pb2+ trong dung dch oxi ha c Sn. Khi nhng hai thanh kim loi Pb v Sn
c ni vi nhau bng dy dn in vo mt dung dch cht in li th
A. c Pb v Sn u b n mn in ho.
B. ch c Sn b n mn in ho.
C. ch c Pb b n mn in ho.
D. c Pb v Sn u khng b n mn in ho.
Cu 40: Chia m gam hn hp X gm 2 kim loi Al, Zn thnh 2 phn bng nhau. Phn 1 cho tc dng
vi dung dch HNO3 long, d thu c 2,12 lt N2 v dung dch A trong c 2 mui. Phn 2 ho
tan hon ton trong dung dch NaOH thy thot ra V lt kh. Cc th tch kh o cng iu kin. Gi
tr ca V l
A. 10,6.
B. 21,2.
C. 4,42.
D. 8,84.
0

II. PHN RING [10 cu]

Th sinh ch c lm mt trong hai phn (phn A hoc B)
A. Theo chng trnh Nng cao (10 cu, t cu 41 n cu 50)
Cu 41: Cho 10,6 gam hn hp 2 axit no, n chc l ng ng lin tip vi nhau tc dng ht vi
300 ml dung dch NaOH 1M. Sau khi phn ng kt thc thu c 19 gam cht rn. Hai axit l
A. C2H5COOH v C3H7COOH.
B. CH3COOH v C2H5COOH.
C. HCOOH v CH3COOH.
D. C4H9COOH v C3H7COOH.
Cu 42: un nng 1 hn hp gm mt ancol bc 1 v mt ancol bc 3 u l nhng ancol no, n
chc, mch h vi H2SO4 c nhit 1400C thu c 26,4 gam hn hp 3 ete ( c s mol bng
nhau) v 5,4 gam H2O. Cho rng cc phn ng xy ra hon ton - ancol bc 1 l
A. CH3OH.
B. C4H9OH.
C. C2H5OH.
D. C3H7OH.
Cu 43: Cho 0,03 mol Al v 0,05 mol Fe tc dng vi 100 ml dung dch A cha Cu(NO 3)2 v
AgNO3. Sau phn ng thu c dung dch A' v 8,12 gam cht rn B gm 3 kim loi. Cho cht rn B
tc dng vi dung dch HCl d thu c 0,672 lt H2 (kc). Cho bit cc phn ng xy ra hon ton.
Nng mol/l ca Cu(NO3)2 v AgNO3 trong dung dch A ln lt l
A. 0,4M v 0,2M.
B. 0,5M v 0,3M.
C. 0,3M v 0,7M.
D. 0,4M v 0,6M.
Cu 44: Cho bit pH cc dung dch (1) HNO3, (2) HCl, (3) NH4Cl, (4) H2SO4 u bng nhau. Dung
dch dn in tt nht l dung dch
A. (2).
B. (1).
C. (3).
D. (4).
Cu 45: Trong cc pht biu sau:
(1) Ging nh H2SO4, H2CrO4 cng rt bn.
(2) Crom tan trong dung dch HCl d to ra dung dch CrCl3.
(3) Ion CrO42- c mu vng, ion Cr2O72- c mu da cam nn cc dung dch Na 2CrO4 v K2Cr2O7 c
mu tng ng.
Trang 4/6 - M thi 132

(4) Mui Cr (III) c c tnh oxi ha v tnh kh.

(5) Crom (III) oxit Cr2O3 tan d dng trong dung dch kim long.
Cc pht biu ng l:
A. (2), (4) v (5).
B. (1), (2), (3), (4) v (5).
C. (1) v (3).
D. (3) v (4).
Cu 46: C bao nhiu cht trong s sau:
2-clobutan; phenyl bromua; 1-clobut-2-en; benzyl bromua; p-clotoluen,
phn ng c vi dung dch NaOH long, un nng?
A. 4.
B. 5.
C. 2.
D. 3.
Cu 47: Hn hp X gm 2 amino axit no, mch h. Ly 8,9 gam X cho tc dng vi dung dch HCl
d c a gam mui, cng lng 8,9 gam X khi tc dng vi dung dch NaOH d th lng mui thu
c l (a 1,45) gam. Hai amino axit l
A. NH2C4H8COOH v NH2C3H6COOH.
B. NH2CH2COOH v NH2C2H4COOH.
C. NH2C2H4COOH v NH2C3H6COOH.
D. NH2CH2COOH v NH2C3H6COOH.
Cu 48: Ngi ta tin hnh ng trng hp buta-1,3-ien v acrilonitrin ( vinyl xianua) thu c 1
loi cao su Buna-N c cha 8,69% N v khi lng. T l s mt xch buta-1,3 ien v acrilonitrin
ln lt l
A. 3:1.
B. 2 : 1.
C. 1 : 2.
D. 1 : 1.
Cu 49: Cho a gam hn hp Mg v Zn phn ng ht vi Cl2 to ra m gam mui. Cho a gam Cu tc
dng ht vi Cl2 cng thu c m gam mui. T l s mol gia Mg v Zn l
A. 1 : 1.
B. 1 : 2.
C. 3 : 325.
D. 1 : 40.
Cu 50: Mun phn bit c 4 dung dch ring r gm: Na2CO3, NaOH, Na2SO4, HCl bng phng
php ho hc th khng th ch dng thm
A. qu tm.
B. dung dch BaCl2.
C. dung dch KOH.
D. Mg.
B. Theo chng trnh Chun (10 cu, t cu 51 n cu 60)
Cu 51: Khi thu phn hon ton 500 gam protein A th c 170 gam alanin. Nu phn t khi ca
A l 50.000 th s mt xch alanin trong phn t A l
A. 200.
B. 211.
C. 173.
D. 191.
Cu 52: Cn bao nhiu tn t n c cha 94% CaC2 ( cn li l tp cht tr) sn xut 10 tn
axit axetic? Coi hiu sut ca ton b qu trnh chuyn ho l 60%
A. 10,667 tn.
B. 18,912 tn.
C. 9,423 tn.
D. 11,348 tn.
Cu 53: Cho cc cht K2O, NH4Cl, KHCO3 v BaCl2 c s mol bng nhau vo mt cc nc, un
nng cc phn ng xy ra hon ton thu c dung dich X. Trong X c cha:
A. KCl.
B. KCl, KOH, BaCl2.
C. KCl, KHCO3, BaCl2.
D. KCl, KOH.
Cu 54: Nhit phn hon ton m gam hn hp Cu(NO3)2, AgNO3 c 18,8 gam cht rn v hn hp
kh X c t khi so vi H2 l 21,25. Gi tr ca m
A. 38,4.
B. 35,8.
C. 32,4.
D. 30,6.
Cu 55: t hon ton qung X (gm ZnS v ZnCO3) bng O2 d thu c cht rn X v 8,96 lt hn
hp kh B (ktc). B c cha 0,1 mol O2 v lm mt mu va ht 200 ml dung dch Br2 1M. Cho CO
d i qua X thu c m gam kim loi Zn. Gi tr ca m l:
A. 13,0.
B. 19,5.
C. 20,5.
D. 26,0.
Cu 56: Mun phn bit 3 dung dch ring bit khng mu sau : H2SO4, Ba(OH)2, HCl bng phng
php ho hc th khng th ch dng thm
A. dung dch Na2SO4. B. dung dch NaOH. C. Qu tm.
D. dung dch BaCl2.
Cu 57: trung ho 2,36g mt axit hu c cn va 160 ml dung dch KOH 0,25M. Cng thc
ca axit l:
A. C3H6(COOH)2
B. CH3COOH
C. CH2(COOH)2
D. C2H4(COOH)2
Trang 5/6 - M thi 132

Cu 58: Cho 50 gam hn hp X gm glucoz v saccaroz vo nc c dung dch Y. Dung dch

Y lm mt mu va 160 gam dung dch Br2 20%. T l v khi lng ca saccaroz trong hn
hp l
A. 25%.
B. 40%.
C. 72%.
D. 28%.
Cu 59: em ho tan hn hp gm 10,8 gam Ag, 6,4 gam Cu v 16 gam Fe 2O3 trong dung dch
H2SO4 1M d. Sau khi cc phn ng xy ra hon ton thy cn m gam cht rn khng tan, gi tr ca
m l
A. 17,2.
B. 6,4.
C. 10,8.
D. 16.
Cu 60: Cho m gam ancol n chc X qua ng ng CuO d, un nng. Sau khi phn ng xy ra
hon ton, ngoi cht rn thu c hn hp gm 2 cht c t khi hi so vi H2 l 19. Ancol X l
A. C3H7OH.
B. C3H5OH.
C. CH3OH.
D. C2H5OH.
--------------------------------------------------------- HT ----------

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