Luyn tp : Oxi v Lu hunh

(Tit 2)
A. Mc tiu
- Gip HS n tp v cc dng bi tp tnh ton lin quan ti Oxi, lu hunh v cc hp cht
ca oxi, lu hunh
- Rn luyn k nng gii bi tp nh lng
B. Chun b ca GV v HS
- GV : My tnh, my chiu, h thng bi tp
- HS : n tp kin thc ca chng, chun b bi tp SGK
C. Tin trnh dy hc
Hot ng 1. Phn dng bi tp
GV : Phn dng bi tp tnh ton chng
Oxi Lu hunh
a) Dng 1. Bi tp
2
SO v
2
H S tc dng
vi dung dch kim
2 3 2
SO NaOH NaHSO H O + +
2 2 3 2
2 2 SO NaOH Na SO H O + +
Sn phm to ra ph thuc vo gi tr
2
NaOH
SO
n
T
n
=
- T s 1 ch to thnh
3
NaHSO
- 1 < T < 2 to thnh hn hp 2 mui
- T > 2 ch to thnh
2 3
Na SO
Tng t i vi
2
H S
b) Dng 2. Bi tp hiu sut phn ng
Hiu sut phn ng : H =



Gi tr c th l s mol, khi lng, th
tch,... ca cht tham gia hay sn phm to
thnh.
i vi qu trnh nhiu giai on
3 1 2
% % % H c H a H b
A B C
= = =

Hiu sut chung ca phn ng
%. %. % H a b c =
c) Dng 3. Bi tp kim loi tc dng vi
2 4
H SO
Cch tnh nhanh s mol
2
4
SO

(hay
2 4
H SO )
to mui :
2
2 2
4
3 4 .
2
SO S H S X
SO
a
n n n n n

= + + =

Trong a l s mol m
6
S
+
thu vo to
ra sn phm kh X

Hot ng 2. Hng dn gii bi tp SGK
GV : - Cho HS tho lun v ln bng hon
thnh bi tp 8
- Phng trnh ha hc :
o
t
Zn S ZnS +
x x
o
t
Fe S FeS +
y y
V S d nn Zn, Fe phn ng ht.
2 4 4 2
ZnS H SO ZnSO H S + +
x x
2 4 4 2
FeS H SO FeSO H S + +
y y
- Ta c h phng trnh :
65 56 3, 72
1, 344
0, 06
22, 4
x y
x y
+ =

+ = =

0, 04
0, 02
x
y
=

- Khi lng mi kim loi trong hn hp
ban u :
65.0, 04 2, 6
Zn
m g = =
56.0, 02 1,12
Fe
m g = =
GV : - Gi HS ln bng lm bi tp 9

a) Gi CT ca oleum l
2 4 3
. H SO nSO .
Gi s mol ca 3,38g A l a
Phng trnh :
2 4 3
. H SO nSO +
2
nH O
2 4
( 1) n H SO +
a a(n+1)
2 4 2 4 2
2 2 H SO KOH K SO H O + +
a(n+1) 2a(n+1)
Theo u bi :
KOH
n = 0,8.0,1 = 0,08 mol
ta c h:
2 ( 1) 0, 08
(98 80 ) 3, 38
a n
a n
+ =

+ =

Gii h phng trnh ta c
0, 01
3
a
n
=

Vy cng thc ca oleum l
2 4 3
.3 H SO SO
b) Phng trnh :
2 4 3 2 2 4
.3 3 4 H SO SO H O H SO +
b 4b
Gi s mol oleum cn dng l b khi
lng oleum l 338b
Khi lng dung dch
2 4
H SO l 200 +
338b
Khi lng
2 4
H SO trong dung dch 10%
l :
10
(200 338 ) 20 33,8
100
b b + = +
Theo phng trnh ta c :
20
4 .98 20 33,8
358, 2
b b b = + =
Khi lng oleum l :
20.338
18, 872
358, 2
=

Hot ng 3. Bi tp m rng
Cu 1. Ha tan hon ton 6,44 (g) hn hp
bt X gm Fe
x
O
y
v Cu bng dung dch H
-
2
SO
4
c nng (d). Sau phn ng thu c
0,504 (l) kh SO
2
(sn phm kh duy nht,
ktc) v dung dch cha 16,6 (g) hn hp
mui sunfat. Cng thc ca oxit st l:
A. FeO B. Fe
3
O
4

C. FeO hoc Fe
3
O
4
. D. Fe
2
O
3

Cu 2. Ha tan 3,38 (g) oleum X vo lng
nc d thu c dung dch. trung ha
1/10 dung dch A cn dng 80 ml dung dch
NaOH 0,1M. Xc nh cng thc ca
oleum
A. H
2
SO
4
.4SO
3
B. H
2
SO
4
.3SO
3

C. H
2
SO
4
.2SO
3
D. H
2
SO
4
.SO
3

Cu 3. Oxi ha hon ton V (l) SO
2
ktc
trong oxi khng kh to thnh SO
3
cho ton
b lng SO
3
trn vo dung dch H
2
SO
4

10% thu c 100g dung dch H
2
SO
4
20%.
Gi tr ca V l:
A. 3,36 (lit) B. 2,4888 (lit)
C. 1,12(lit) D. 1,422(lit)
Cu 4. phn ng ht a mol kim loi M
cn 1,25a mol H
2
SO
4
v sinh ra kh X (sn
phm kh duy nht). Ha tan ht 19,2 (g)
kim loi M vo dung dch H
2
SO
4
to ra
4,48 (l) kh X (sn phm kh duy nht,
ktc). Kim loi M l
A. Fe. B. Cu.

C. Mg. D. Al.
Cu 5. Nung hn hp SO
2
, O
2
c s mol
bng nhau trong mt bnh kn c th tch
khng i vi cht xc tc thch hp. Sau
mt thi gian, a bnh v nht ban u
thy p sut trong bnh gim 10% so vi p
sut ban u. Hiu sut ca phn ng
xy ra bng:
A. 50% B. 75%
C. 20% D. 40%

Hot ng 4. Cng c v giao BTVN
GV : - Yu cu HS lm cc bi tp trong
SGK v SBT