HALOGEN

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Hon thnh cc phng trnh phn ng di y v nu r vai tr ca clo trong mi phn ng : a) FeCl2 + Cl2 FeCl3 b) Cl2 + SO2 + H2O HCl + H2SO4 c) KOH + Cl2 KCl + KClO3 + H2O d) Ca(OH)2 + Cl2 Ca(ClO)2 + CaCl2 + H2O. C bn bnh khng dn nhn, mi bnh cha mt trong cc dung dch HCl, HNO 3, KCl, KNO3. Hy trnh by phng php ho hc nhn bit dung dch cha trong mi bnh. Cho 69,6 g mangan ioxit tc dng ht vi dung dch axit clohiric c. Ton b lng clo sinh ra c hp th ht vo 500 ml dung dch NaOH 4M. Hy xc nh nng mol ca tng cht trong dung dch thu c sau phn ng. Coi th tch dung dch khng thay i. Cho 1,000 lit H2 v 0,672 lit Cl2 (ktc) tc dng vi nhau ri ho tan sn phm vo 38,540 g nc ta thu c dung dch A. Ly 50,000 g dung dch A cho tc dng vi dung dch AgNO 3 (ly d) thu c 7,175 g kt ta. Tnh hiu sut ca phn ng gia H2 v Cl2. Hy cho bit tnh cht ho hc quan trng nht ca nc Gia-ven, clorua vi v ng dng ca chng. V sao clorua vi c s dng nhiu hn nc Gia-ven ? Cho cc ho cht NaCl(r), MnO2(r), NaOH (dd), KOH (dd), H2SO4 (dd c), Ca(OH)2(r). T cc ho cht , c th iu ch c cc cht sau y hay khng ? a) Nc Gia-ven; b) Kali clorat; c) Clorua vi; d) Oxi; e) Lu hunh ioxit. Vit phng trnh cc phn ng xy ra. iu ch kali clorat vi gi thnh h ngi ta thng lm nh sau : Cho kh clo i qua nc vi un nng, ly dung dch thu c trn vi KCl v lm lnh. Khi kali clorat s kt tinh. Hy vit phng trnh cc phn ng xy ra v gii thch v sao kali clorat kt tinh. Cho lng d dung dch AgNO 3 tc dng vi 100 ml dung dch hn hp NaF 0,05M, NaCl 0,1M. Vit phng trnh phn ng xy ra v tnh khi lng kt ta thu c. Chng minh rng brom c tnh oxi ho yu hn clo v mnh hn iot. Ngi ta c th iu ch brom bng cch cho axit sunfuric c tc dng vi hn hp rn KBr v MnO2. a) Vit phng trnh phn ng v cho bit vai tr ca tng cht trong phn ng. b) Tnh khi lng ca mi cht cn dng iu ch 32 g Br2. Cht A l mui canxi halogenua. Cho dung dch cha 0,200 g A tc dng vi lng d dung dch bc nitrat th thu c 0,376 g kt ta bc halogenua. Hy xc nh cng thc cht A. Kh hiro, thu c bng phng php in phn dung dch NaCl, i khi b ln tp cht l kh clo. kim tra xem kh hiro c ln clo hay khng, ngi ta thi kh qua mt dung dch c cha kali iotua v tinh bt. Hy gii thch v sao ngi ta lm nh vy ? C ba bnh khng ghi nhn, mi bnh ng mt trong cc dung dch NaCl, NaBr v NaI. Ch dng hai thuc th (khng dng AgNO3) lm th no xc nh dung dch cha trong mi bnh ? Vit phng trnh phn ng xy ra. Chia mt dung dch nc brom c mu vng thnh hai phn. Dn kh A khng mu i qua phn mt th dung dch mt mu. Dn kh B khng mu i qua phn hai th dung dch sm mu hn. Hy cho bit kh A v kh B c th l nhng cht g ? Vit cc phng trnh phn ng xy ra. Thm 78 ml dung dch bc nitrat 10% (khi lng ring 1,09 g/ml) vo mt dung dch c cha 3,88 g hn hp kali bromua v natri iotua. Lc b kt ta. Nc lc phn ng va vi 13,3 ml dung dch axit clohiric nng 1,5 mol/l. Hy xc nh phn trm khi lng tng cht trong hn hp mui ban u v tnh th tch hiro clorua (ktc) cn dng to ra lng axit clohiric dng. Cho cc cht : brom, clo, hiro clorua, iot, bc bromua, natri clorua. Hy chn trong s cc cht trn : a) Mt cht lng nhit phng; b) Mt cht c trong nc bin nhng khng c trong nc nguyn cht; c) Mt cht kh mu lc; d) Mt cht b phn hu bi nh sng mt tri; e) Mt cht kh khng mu to "khi" trong khng kh m; f) Mt hp cht c dng bo qun thc phm; g) Mt cht kh khi tan trong nc tc dng dn vi nc to ra hai axit; h) Mt cht rn khi c un nng bin thnh kh mu tm; i) Mt cht kh ty trng giy mu m.