Titular 50 ml de Ca al 0.01M con EDTA al 0.

01M

Vol Aadido Vol de Ca

EDTA (ml)
(ml)
0
5
10
15
20
25
30
35
37
36
35
40
45
49
50

50
45
40
35
30
25
20
15
13
12
11
10
5
1
0

Vol total (ml)

50
55
60
65
70
75
80
85
87
86
85
90
95
99
100

CM
0.01
0.00727273
0.005
0.00307692
0.00142857
4.3644E-07
2.8571E-11
7.619E-11
1.0549E-10
1.1429E-10
1.2468E-10
1.7143E-10
4.5714E-10
2.7429E-09
#DIV/0!

CL

0.00125
0.00235294
0.00275862
0.0027907
0.00282353
0.00333333
0.00421053
0.00484848
0.005

Ccomplejo

0.0025
0.00176471
0.00149425
0.00139535
0.00129412
0.00111111
0.00052632
0.00010101
0

pM
2
2.1383027
2.30103
2.51188336
2.84509804
6.36007965
10.544068
10.1180993
9.97677016
9.94200805
9.90421949
9.76591679
9.33994806
8.56179681
#DIV/0!

Keq Ca=
C Ca=
C EDTA=

1.75E+10
0.01
0.01

Titular 50 ml de Ca al 0.01M con EDTA al 0.01M

Vol Aadido Vol de Ca

EDTA (ml)
(ml)
0
5
10
15
20
25
30
35
40
45
49
50

50
45
40
35
30
25
20
15
10
5
1
0

Vol total (ml)

50
55
60
65
70
75
80
85
90
95
99
100

CM

CL

0.01
0.007272727
0.005
0.003076923
0.001428571
4.36436E-07
2.85714E-11
7.61905E-11
1.71429E-10
4.57143E-10
2.74286E-09
#DIV/0!

Ccomplejo

0.00125
0.00235294
0.00333333
0.00421053
0.00484848
0.005

0.0025
0.00176471
0.00111111
0.00052632
0.00010101
0

pM
2
2.1383027
2.30103
2.51188336
2.84509804
6.36007965
10.544068
10.1180993
9.76591679
9.33994806
8.56179681
#DIV/0!

pM
12
10
8
6

pM

4
2
0
0

10

20

30

40

50

60

Keq Ca=
C Ca=
C EDTA=

1.75E+10
0.01
0.01

Titular 50 ml de Ca al 0.01M con EDTA al 0.01M

Vol Aadido
EDTA (ml)

Vol de Ca
(ml)

0
5
10
15
20
25
30
35
40
45
49
50
52
55
58
Keq Ca=
C Ca=
C EDTA=

Vol total (ml)

50
45
40
35
30
25
20
15
10
5
1
0

50
55
60
65
70
75
80
85
90
95
99
100
102
105
108

C EDTA
(ligante)

CM

0.01
0.008181818
0.006666667
0.005384615
0.004285714
0.003333333
0.0025
0.001764706
0.001111111
0.000526316
0.00010101
5.34522E-07
2.29E-12 0.00019608
5.71E-12 0.00047619
9.14E-12 0.00074074

C complejo
(Ca y)

pCa

2
2.08715018
2.17609126
2.26884531
2.36797679
2.47712125
2.60205999
2.75332767
2.95424251
3.2787536
3.99563519
6.27203402
0.00490196 11.6409781
0.0047619
11.243038
0.00462963 11.0389181

1.75E+10
0.01
0.01

V Ca=

50

pM
14
12
10
8
pCa

6
4
2
0
0

10

20

30

40

50

60

70

Alumna Zashery Gutierrez Cruz

Grafica de Titulacion de complejos
2 "D" Q.F.B.

Se valoran 50 ml de Fe
Vol de Fe
(ml)

2+

a concentracion 0.1M con Ce

Vol Aadido
Vol total (ml)
de Ce (ml)

4+

E1

0.1N

CCe4+

50
49

0
1

50
51 -0.67010941

45

55 -0.71360427

40

10

60 -0.73441825

35
30

15
20

65 -0.74825257
70 -0.75959301

25

25

75

20
15
10
5
0

30
35
40
45
50
50.1
50.5
51
52
54
56
60

80
85
90
95
100
100.1
100.5
101
102
104
106
110

CCe3+

-0.77
-0.78040699
-0.79174743
-0.80558175
-0.82639573
1.19
1.87956041
100.1
1.83845539
20.1
1.8209174
10.1
1.80362492
5.1
1.78680273
2.6
1.77732917 1.76666667
1.76598874
1.1

0.1998004
0.1990099
0.19803922
0.19615385
0.19259259
0.18928571
0.18333333

2.5
2
1.5
1
0.5
0
-0.5
-1
-1.5

EFe

0.0591
-0.77

Ece

1.72

PFe

0.77

PCe

1.61

CCe4+

0.1

CFe2+

0.1

E1

E1
0

10

20

30

40

50

60

70