THI GI BI GII TUYN SINH CAO NG NM 2007 Mn thi : HA HC, khi B PHN CHUNG CHO TT C TH SINH (44 cu,

u, t cu 1 n cu 44) Cu 1: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh ( ttc) nh nht cn dng t chy hon ton lng kh thin nhin trn l (Cho H = 1; C = 12; O = 16). A. 70,0 lt B. 84,0 lt C. 56,0 lt D. 78,4 lt Cu 2: C th dng NaOH ( th rn) lm kh cc cht kh A. NH3, O2, N2, CH4, H2 B. N2, Cl2, O2, CO2, H2 C. NH3, SO2, CO, Cl2 D. N2, NO2, CO2, CH4, H2 Cu 3: un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ha l (Cho H = 1; C = 12; O = 16). A. 50% B. 62,5% C. 55% D. 75% Cu 4: Khi ha tan hiroxit kim loi M(OH)2 bng mt lng va dung dch H2SO4 20% thu c dung dch mui trung ha c nng 27,21%. Kim loi M l (Cho H = 1; O = 16; Mg = 24; S = 32; Fe = 56; Cu = 64; Zn = 65). A. Mg B. Zn C. Cu D. Fe Cu 5: Ha tan hon ton hn hp X gm Fe v Mg bng mt lng va dung dch HCl 20% thu c dung dch Y. Nng ca FeCl2 trong dung dch Y l 15,76%. Nng phn trm ca MgCl2 trong dung dch Y l (Cho H = 1; Mg = 24; Cl = 35,5; Fe = 56) A. 11,79% B. 24,24% C. 15,76% D. 28,21% Cu 6: Cho 50ml dung dch glucoz cha r nng tc dng vi mt lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 2,16 gam bc kt ta. Nng mol (hoc mol/l) ca dung dch glucoz dng l (Cho H = 1; C = 12; O = 16; Ag = 108) A. 0,20M B. 0,01M C. 0,02M D. 0,10M Cu 7: Cho kim loi M tc dng vi Cl2 c mui X; cho kim loi M tc dng vi dung dch HCl c mui Y. Nu cho kim loi M tc dng vi dung dch mui X ta cng c mui Y. Kim loi M c th l A. Mg B. Al C. Zn D. Fe Cu 8: Dn V lt ( ktc) hn hp X gm axetilen v hir i qua ng s dng bt niken nung nng, thu c kh Y. Dn Y vo lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 12 gam kt ta. Khi i ra khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z thu c 2,24 lt kh CO2 ( ktc) v 4,5 gam nc. Gi tr ca V bng (Cho H = 1; C = 12; O = 16; Br = 80; Ag = 108). A. 13,44 B. 11,2 C. 8,96 D. 5,60 Cu 9: Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%) tc dng vi clo theo t l s mol 1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng phn ca nhau. Tn ca X l (Cho H = 1; C = 12; Cl = 35,5) A. butan B. 2,3-imetylbutan C. 3-metylpentan D. 2-metylpropan Cu 10: C bao nhiu ru (ancol) bc 2, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18%? (Cho H = 1; C = 12; O = 16). A. 2 B. 4 C. 3 D. 5 63 65 Cu 11: Trong t nhin, nguyn t ng c hai ng v l 29 Cu v 29 Cu . Nguyn t khi trung bnh ca ng l 63,54. Thnh phn phn trm tng s nguyn t ca ng v 63 Cu l 29 A. 50% B. 27% C. 54% D. 73% Cu 12: Cc kh c th cng tn ti trong mt hn hp l A. H2S v Cl2 B. Cl2 v O2 C. NH3 v HCl D. HI v O3 Cu 13: Ch dng Cu(OH)2 c th phn bit c tt c cc dung dch ring bit sau : A. glucoz , lng trng trng, glixerin (glixerol), ru (ancol) etylic B. glucoz, mantoz, glixerin (glixerol), anehit axetic. C. saccaroz, glixerin (glixerol), anehit axetic, ru (ancol) etylic D. lng trng trng, glucoz, fructoz, glixerin (glixerol) Cu 14: kh ion Cu2+ trong dung dch CuSO4 c th dng kim loi A. K B. Na C. Ba D. Fe

Cu 15: Cho kh CO (d) i vo ng s nung nng ng hn hp X gm Al2O3, MgO, Fe3O4, CuO thu c cht rn Y. Cho Y vo dung dch NaOH (d), khuy k, thy cn li phn khng tan Z. Gi su cc phn ng xy ra hon ton. Phn khng tan Z gm A. Mg, Fe, Cu B. MgO, Fe, Cu C. Mg, Al, Fe, Cu D. MgO, Fe3O4, Cu Cu 16: Cho cc cp kim loi nguyn cht tip xc trc tip vi nhau : Fe v Pb; Fe v Zn; Fe v Sn; Fe v Ni. Khi nhng cc cp kim loi trn vo dung dch axit, s cp kim loi trong Fe b ph hy trc l A. 4 B. 1 C. 2 D. 3 Cu 17: Cho s chuyn ha: Glucoz X Y CH3COOH. Hai cht X, Y ln lt l B. CH3CH2OH v CH2=CH2 A. CH3CHO v CH3CH2OH C. CH3CH(OH)COOH v CH3CHO D. CH3CH2OH v CH3CHO Cu 18: SO2 lun th hin tnh kh trong cc phn ng vi A. dung dch NaOH, O2, dung dch KMnO4 B. O2, nc Br2, dung dch KMnO4 C. dung dch KOH, CaO, nc Br2 D. H2S, O2, nc Br2 Cu 19: kh ion Fe3+ trong dung dch thnh ion Fe2+ c th dng mt lng d A. Kim loi Mg B. Kim loi Ba C. Kim loi Cu D. Kim loi Ag Cu 20: Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam mui ca axit hu c. Cng thc cu to thu gn ca X l (Cho H = 1; C = 12; O = 16; Ca = 40) A. CH3-CH2-COOH B. HCC-COOH C. CH2=CH-COOH D. CH3COOH Cu 21: Cho s phn ng : Nacl (X) NaHCO3 (Y) NaNO3. X v Y c th l A. Na2CO3 v NaClo B. NaOH v NaCIO C. NaClO3 v Na2CO3 D. NaOH v Na2CO3 Cu 22: trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l (Cho H = 1; C = 12; N = 14) A. C2H7N B. CH5N C. C3H5N D. C3H7N Cu 23: Mt dung dch cha 0,02 mol Cu2+, 0,03 mol K+, x mol Cl v y mol SO42. Tng khi lng cc mui tan c trong dung dch l 5,435 gam. Gi tr ca x v y ln lt l (Cho O = 16; S = 32; Cl = 35,5; K = 39; Cu = 64) A. 0,03 v 0,02 B. 0,05 v 0,01 C. 0,01 v 0,03 D. 0,02 v 0,05 Cu 24: Cho cc nguyn t M (Z = 11), X (Z = 17), Y (Z = 9) v R (Z = 19). m in ca cc nguyn t tng dn theo th t A. M < X < R < Y B. R < M < X < Y C. M < X < Y < R D. Y < M < Z < R Cu 25: S hp cht n chc, ng phn cu to ca nhau c cng cng thc phn t C4H8O2, u tc dng c vi dung dch NaOH l A. 5 B. 6 C. 4 D. 3 Cu 26: Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%, cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu oc 4,85 gam mui khan. Cng thc cu to thu gn ca X l (Cho H = 1; C = 12; N = 14; O = 16; Na = 23). A. CH2=CHCOONH4 B. H2NCOO-CH2CH3 C. H2NC2H4COOH D. H2NCH2COO-CH3 Cu 27: Este X khng no, mch h , c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x phng ha to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X ? (Cho H = 1; C = 12; O = 16) A. 4 B. 5 C. 3 D. 2 Cu 28: Phn ng ha hc xy ra trong trng hp no di y khng thuc loi phn ng nhit nhm? A. Al tc dng vi Fe2O3 nung nng B. Al tc dng vi CuO nung nng. C. Al tc dng vi Fe3O4 nung nng D. Al tc dng vi axit H2SO4 c nng Cu 29: Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu oc 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l (Cho H = 1; C = 12; O = 16; Na = 23) A. etyl propionat B. metyl propionat C. ety axetat D. isopropyl axetat Cu 30: Trong s cc dung dch : Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa, nhng dung dch c pH > 7 l A. Na2CO3, NH4Cl, KCl B. KCl, C6H5ONa, CH3COONa C. Na2CO3, C6H5ONa, CH3COONa D. NH4Cl, CH3COONa, NaHSO4

Cu 31: Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3 thu c cht hu c T. Cho cht T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l A. CH3COOCH=CH2 B. HCOOCH3 C. CH3COOCH=CH-CH3 D. HCOOCH=CH2 Cu 32: Cho mt mu hp kim Na-Ba tc dng vi nc (d) thu c dung dch X v 3,36 lt H2 ( ktc). Th tch dung dch axit H2SO4 2M cn dng trung ha dung dch X l A. 150 ml B. 60 ml C. 75 ml D. 30 ml Cu 33: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn ng v X ch tc dng c vi NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l A. CH3C6H3(OH) B. CH3OC6H4OH C. C6H5CH(OH)2 D. HOC6H4CH2OH Cu 34: Thm m gam kali vo 300 ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c thu dung dch X. Cho t t dung dch X vo 200ml dung dch Al2(SO4)3 0,1M thu c kt ta Y. thu c lng kt ta Y ln nht th gi tr ca m l (Cho H = 1; O = 16; Na = 23; Al = 27; S = 32; K = 39; Ba = 137) A. 1,17 B. 1,95 C. 1,59 D. 1,71 Cu 35: Trong cng nghip, natri hiroxit c sn xut bng phng php A. in phn dung dch NaCl, khng c mng ngn in cc. B. in phn dung dch NaCl, c mng ngn in cc C. in phn dung dch NaNO3 , khng c mn ngn in cc D. in phn NaCl nng chy Cu 36: Ha tan hon ton 3,22 gam hn hp X gm Fe, Mg v Zn bng mt lng va dung dch H2SO4 long, thu c 1,344 lt hiro ( ktc) v dung dch m gam mui. Gi tr ca m l (Cho H = 1; O = 16; Mg = 24; S = 32; Fe = 56; Zn = 65). A. 9,52 B. 10,27 C. 8,98 D. 7,25 Cu 37: t chy hon ton mt ru (anol) X thu c CO2 v H2O c t l s mol tng ng l 3 : 4. Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO2 thu c ( cng iu kin). Cng thc phn t ca X l A. C3H8O2 B. C3H8O C. C3H4O D. C3H8O3 Cu 38: Polivinyl axetat (hoc poli(vinyl axetat)) l polime c iu ch bng phn ng trng hp A. CH3COO-CH=CH2 B. CH2=CH-COO-CH3 C. C2H5COO-CH=CH2 D. CH2=CH-COO-C2H5 Cu 39: Th t mt s cp oxi ha - kh trong dy in ha nh sau : Fe2+/Fe; Cu2+/Cu; Fe3+/Fe2+. Cp cht khng phn ng vi nhau l A. Cu v dung dch FeCl3 B. Fe v dung dch CuCl2 C. Fe v dung dch FeCl3 D. dung dch FeCl2 v dung dch CuCl2 Cu 40: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (Cho : H = 1; C = 12; O = 12; th tch dung dch thay i khng ng k). A. C2H5OH v C3H7OH B. C4H9OH v C5H11OH C. C3H7OH v C4H9OH D. C2H5OH v C4H9OH

2NH 3 (k) . Khi Cu 41: Cho phng trnh ha hc ca phn ng tng hp amoniac N 2 (k) + 3H 2 (k) tng nng ca hiro ln 2 ln, tc phn ng thun A. gim i 2 ln B. tng ln 2 ln C. tng ln 8 ln D. tng ln 6 ln Cu 42: Cho 2,9 gam mt anehit phn ng hon ton vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 21,6 gam Ag. Cng thc cu to thu gn ca anehit l (Cho H = 1; C = 12; O = 16; Ag = 108) A. CH2=CH-CHO B. CH3CHO C. OHC-CHO D. HCHO Cu 43: Khi cho 100ml dung dch KOH 1M vo 100ml dung dch HCl thu c dung dch c cha 6,525 gam cht tan. Nng mol (hoc mol/l) ca HCl trong dung dch dng l (Cho H = 1; O = 16; Cl = 35,5; K = 39) A. 1M B. 0,25M C. 0,75M D. 0,5M Cu 44: Cho cc cht sau: phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc dng c vi nhau l A. 1 B. 3 C. 4 D. 2 PHN T CHN : Th sinh ch c chn lm 1 trong 2 phn (Phn I hoc Phn II) Phn I. Theo chng trnh KHNG phn ban (6 cu, t cu 45 n cu 50) Cu 45: Polime dng ch to thy tinh hu c (plexiglas) c iu ch bng phn ng trng hp

t 0 ,xt

A. CH3COOCH=CH2 B. C6H5CH=CH2 C. CH2=CHCOOCH3 D. CH2=C(CH)3COOCH3 Cu 46: Khi thc hin phn ng tch nc i vi ru (ancol) X, ch thu c mt anken duy nht. Oxi ha hon ton mt lng cht X thu c 5,6 lt CO2 ( ktc) v 5,4 gam nc. C bao nhiu cng thc cu to ph hp vi X? (Cho H = 1; C = 12; O = 16) A. 4 B. 5 C. 3 D. 2 Cu 47: Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit st n khi phn ng xy ra hon ton. Khi thu oc phn ng c t khi so vi hiro bng 20. Cng thc ca oxit st v phn trm th tch ca kh CO2 trong hn hp kh sau phn ng l (Cho H = 1; C = 12; O = 16; Fe = 56) A. Fe2O3 75% B. Fe3O4 75% C. FeO 75% D. Fe2O3 65% Cu 48: Trong s cc loi t sau : t tm, t visco, t nilon-6,6, t axetat, t capron, t enang, nhng loi t no thuc loi t nhn to A. T tm v t enang B. T nilon-6,6 v t capron C. T visco v t nilon-6,6 D. T visco v t axetat Cu 49: Cho cc cht c cng thc cu to nh sau : HOCH2-CH2OH(X); HOCH2-CH2-CH2OH(Y); HOCH2-CHOH-CH2OH(Z); CH3-CH2-O-CH2-CH3(R); CH3-CHOH-CH2OH(T). Nhng cht tc dng c vi Cu(OH)2 to thnh dung dch mu xanh lam l A. Z, R, T B. X, Y, R, T C. X, Z, T D. X, Y, Z, T Cu 50: Cho hn hp X gm Mg v Fe vo dung dch axit H2SO4 c nng n khi cc phn ng xy ra hon ton, thu c dung dch Y v mt phn Fe khng tan. Cht tan c trong dung dch Y l A. MgSO4, Fe2(SO4)3 v FeSO4 B. MgSO4 v Fe2(SO4)3 C. MgSO4 v FESO4 D. MgSO4 Phn II. Theo chng trnh phn ban (6 cu, t cu 51 n cu 56) Cu 51: trung ha lng axit t do c trong 14 gam mt mu cht bo cn 15ml dung dch KOH 0,1M. Ch s axit ca mu cht bo trn l (Cho H = 1; O = 16; K = 39) A. 4,8 B. 6,0 C. 5,5 D. 7,2 Cu 52: Trong cng nghip, axeton c iu ch t A. propan-1-ol B. cumen C. propan-2-ol D. xiclopropan Cu 53: Cho cc ion kim loi : Zn2+, Sn2+, Ni2+, Fe2+, Pb2+. Th t tnh oxi ha gim dn l A. Sn 2+ > Ni 2+ > Zn 2+ > Pb 2+ > Fe 2+ B. Zn 2+ > Sn 2+ > Ni 2+ > Fe 2+ > Pb 2+ C. Pb 2+ > Sn 2+ > Fe 2+ > Ni 2+ > Zn 2+ D. Pb 2+ > Sn 2+ > Ni 2+ > Fe 2+ > Zn 2+ Cu 54: Cc hp cht trong dy cht no di y u c tnh lng tnh ? B. Cr(OH)3, Fe(OH)2, Mg(OH)2 A. Cr(OH)3, Zn(OH)2, Mg(OH)2 C. Cr(OH)3, Zn(OH)2, Pb(OH)2 D. Cr(OH)3, Pb(OH)2, Mg(OH)2 Cu 55: Khi cho 41,4 gam hn hp X gm Fe2O3, Cr2O3 v Al2O3 tc dng vi dung dch NaOH c (d) , sau phn ng thu c cht rn c khi lng 16 gam. kh hon ton 41,4 gam X bng phn ng nhit nhm, phi dng 10,8 gam Al. Thnh phn phn trm theo khi lng ca Cr2O3 trong hn hp X l (Cho : hiu sut ca cc phn ng l 100%; O = 16; Al = 27; Cr = 52; Fe = 56) A. 50,67% B. 20,33% C. 36,71% D. 66,67% Cu 56: T l s ngi cht v bnh phi do ht thuc l gp hng chc ln s ngi khng ht thuc l. Cht gy nghin v gy ung th c trong thuc l l A. nicotin B. aspirin C. cafein D. moocphin Nguyn Tn Trung (Trung tm LTH Vnh Vin)