QCVN 1 : 2009/BKHCN

CNG HA X HI CH NGHA VIT NAM

QCVN 1 : 2009/BKHCN QUY CHUN K THUT QUC GIA V XNG, NHIN LIU IZEN V NHIN LIU SINH HC
National technical regulation on gasoline, diesel fuel oils and biofuels

H NI 2009

QCVN 1 : 2009/BKHCN

Li ni u QCVN 1 : 2009/BKHCN thay th QCVN 1 : 2007/BKHCN. QCVN 1 : 2009/BKHCN do Ban son tho Quy chun k thut quc gia v xng du v nhin liu sinh hc bin son, Tng cc Tiu chun o lng Cht lng trnh duyt v c ban hnh theo Thng t s 20/2009/TT-BKHCN ngy 30 thng 9 nm 2009 ca B trng B Khoa hc v Cng ngh.

QCVN 1 : 2009/BKHCN

QUY CHUN K THUT QUC GIA V XNG, NHIN LIU IZEN V NHIN LIU SINH HC
National technical regulation on gasoline, diesel fuel oils and biofuels

1. QUY NH CHUNG
1.1. Phm vi iu chnh Quy chun k thut ny quy nh cc mc gii hn i vi cc ch tiu k thut lin quan n an ton, sc khe, mi trng v cc yu cu v qun l cht lng i vi cc loi xng, nhin liu izen v nhin liu sinh hc, bao gm : Xng khng ch v xng E5; Nhin liu izen v nhin liu izen B5; Nhin liu izen sinh hc gc B100 dng pha nhin liu izen ; Etanol nhin liu bin tnh dng pha xng. 1.2. i tng p dng Quy chun k thut ny p dng i vi cc c quan, t chc, c nhn c hot ng lin quan n vic nhp khu, sn xut, ch bin, pha ch, phn phi v bn l cc loi xng, nhin liu izen v nhin liu sinh hc ti Vit Nam. 1.3. Gii thch t ng Trong Quy chun k thut ny, cc t ng di y c hiu nh sau: 1.3.1. Xng khng ch Hn hp bay hi ca cc hydrocacbon lng c ngun gc t du m vi khong nhit si thng thng t 15 oC n 215 oC, thng c cha lng nh ph gia ph hp, nhng khng pha ch, s dng lm nhin liu cho ng c t trong. 1.3.2. Xng E5 Hn hp ca xng khng ch v etanol nhin liu bin tnh vi hm lng etanol t 4 % n 5 % theo th tch, k hiu l E5.

QCVN 1 : 2009/BKHCN 1.3.3. Nhin liu izen Phn ct gia ca du m ph hp s dng lm nhin liu cho ng c izen lm vic theo nguyn l chy do nn di p sut cao trong xylanh, k hiu l DO. 1.3.4. Nhin liu izen B5 Hn hp ca nhin liu izen v nhin liu izen sinh hc gc vi hm lng este metyl axit bo (FAME) t 4 % n 5 % theo th tch, k hiu l B5. 1.3.5. Nhin liu izen sinh hc gc Nhin liu c chuyn ha t nguyn liu sinh hc (du thc vt hoc m ng vt), c thnh phn chnh l cc mono -alkyl este ca axit bo mch di, cha pha trn vi cc loi nhin liu khc, s dng lm nhin liu cho ng c izen, k hiu l B100. 1.3.6. Etanol nhin liu bin tnh Etanol (C2H5OH) c pha thm cc cht bin tnh, s dng pha ch trong nhin liu cho ng c xng v khng c s dng cho mc ch ch bin ung. 1.3.7. Cht bin tnh s dng cho etanol nhin liu Xng khng ch hoc naphta, khng cha cc hp cht keton, c dng pha thm vo etanol, lm cho etanol tr thnh etanol bin tnh s dng lm nhin liu v khng s dng cho mc ch ch bin ung.

2. QUY NH K THUT 2.1. Xng khng ch, xng E5 2.1.1. Tr s ctan (RON) phi ph hp vi quy nh ti TCVN 6776 : 2005 Xng khng ch Yu cu k thut v cc vn bn php quy hin hnh c lin quan. 2.1.2. Cc ch tiu k thut c bn ca xng khng ch v xng E5 phi ph hp vi cc quy nh trong bng sau:

QCVN 1 : 2009/BKHCN Tn ch tiu 1. Hm lng ch, g/l 2. Hm lng lu hunh , mg/kg 3. Hm lng benzen, % th tch 4. Hm lng hydrocacbon thm, % th tch 5. Hm lng olefin, % th tch 6. Hm lng xy, % khi lng 7. Hm lng etanol, % th tch 8. Hm lng kim loi (Fe, Mn), mg/l Mc,
khng ln hn

Phng php th TCVN 7143 (ASTM D 3237) TCVN 6701 (ASTM D 2622) hoc TCVN 7760 (ASTM D 5453) TCVN 3166 (ASTM D 5580) TCVN 7330 (ASTM D 1319) TCVN 7330 (ASTM D 1319) TCVN 7332 (ASTM D 4815) TCVN 7332 (ASTM D 4815) TCVN 7331 (ASTM D 3831)

0,013 500 2,5 40 38 2,7 5 5

2.1.3. Etanol nhin liu bin tnh dng pha xng khng ch phi ph hp vi quy nh ti khon 2.4 Mc 2 ca Quy chun k thut ny. 2.2. Nhin liu izen v nhin liu izen B5 2.2.1. Cc ch tiu k thut c bn ca nhin liu izen v nhin liu izen B5 phi ph hp vi cc quy nh trong bng sau: Tn ch tiu 1. Hm lng lu hunh, mg/kg, khng ln hn i vi loi 0,05 S i vi loi 0,25 S tr s xtan, hoc ch s xtan
2) 1)

Mc

Phng php th TCVN 6701 (ASTM D 2622) hoc TCVN 7760 (ASTM D 5453)

500 2 500

2. Xtan, khng nh hn 46 46 360 820 860 2 4,5 TCVN 7630 (ASTM D 613) TCVN 3180 (ASTM D 4737) TCVN 2698 (ASTM D 86) TCVN 6594 (ASTM D 1298) TCVN 3171 (ASTM D 445)

3. Nhit ct ti 90 % th tch 3), oC, khng ln hn 4. Khi lng ring 15 oC 3), kg/m 3 5. nht ng hc 40 oC 3), mm2/s
CH THCH:
1)

Khng p dng i vi nhin liu izen v nhin liu izen B5 dng cho phng tin giao thng c gii ng b. 2) Khng p dng i vi nhin liu izen B5. 3) p dng i vi nhin liu izen dng cho phng tin giao thng c gii ng b.

QCVN 1 : 2009/BKHCN 2.2.2. i vi nhin liu izen B5, ngoi cc ch tiu k thut quy nh ti im 2.2.1 khon 2.2 Mc 2, phi ph hp vi cc quy nh trong bng sau: Tn ch tiu 1. Hm lng este metyl axit bo (FAME), % th tch 2. n nh oxy ho, mg/100ml, khng ln hn 3. Hm lng nc, mg/kg, khng ln hn Mc 45 25 200 Phng php th TCVN 8147 (EN 14078) TCVN 8146 (ASTM D 2274) TCVN 3182 (ASTM D 6304)

2.2.3. Nhin liu izen sinh hc gc dng pha nhin liu izen phi ph hp vi cc quy nh ti khon 2.3 Mc 2 ca Quy chun k thut ny. 2.3. Nhin liu izen sinh hc gc Cc ch tiu k thut c bn ca nhin liu i zen sinh hc gc phi ph hp vi cc quy nh trong bng sau: Tn ch tiu 1. Hm lng este metyl axit bo (FAME), % khi lng, khng nh hn 2. Nc v cn, % th tch, khng ln hn 3. nht ng hc ti 40 oC, mm2/s 4. Tro sulpht, % khi lng, khng ln hn 5. Lu hunh, % khi lng, khng ln hn 6. Tr s xtan, khng nh hn 7. Tr s axit, mg KOH/g, khng ln hn 8. n nh xy ho, ti 110 oC, h, khng nh hn 9. Glycerin t do, % khi lng, khng ln hn 10. Glycerin tng, % khi lng, khng ln hn 11. Phospho, % khi lng, khng ln hn Mc Phng php th

96,5 0,050 1,9 6,0 0,020 0,05 47 0,50 6 0,020 0,240 0,001

TCVN 7868 (EN 14103) TCVN 7757 (ASTM D 2709) TCVN 3171 (ASTM D 445) TCVN 2689 (ASTM D 874) TCVN 7760 (ASTM D 5453) TCVN 7630 (ASTM D 613) TCVN 6325 (ASTM D 664) TCVN 7895 (EN 14112) TCVN 7867 (ASTM D 6584) TCVN 7867 (ASTM D 6584) TCVN 7866 (ASTM D 4951)

QCVN 1 : 2009/BKHCN 2.4. Etanol nhin liu bin tnh 2.4.1. Cc ch tiu k thut c bn ca etanol nhin liu bin tnh phi ph hp vi cc quy nh trong bng sau: Tn ch tiu 1. Hm lng etanol, % th tch, khng nh hn 2. Hm lng metanol, % th tch, khng ln hn 3. Hm lng nc, % th tch, khng ln hn 4. axit (tnh theo axit axetic CH3COOH), % khi lng, khng ln hn 5. Hm lng clorua v c, mg/kg, khng ln hn Mc 92,1 0,5 1,0 Phng php th TCVN 7864 (ASTM D 5501) TCVN 7894 (EN 14110) TCVN 7893 (ASTM E 1064)

0,007 40

TCVN 7892 (ASTM D 1613) TCVN 7716 (ASTM D 4806) (Ph lc A)

2.4.2. Ngoi cc ch tiu k thut quy nh ti im 2.4.1 khon 2.4 Mc 2, etanol nhin liu bin tnh phi cha mt lng cht bin tnh vi hm lng t 1,96 % n 5,0 % th tch. Lng cht bin tnh c trong etanol nhin liu c kim sot qua quy trnh sn xut. 2.5. Ph gia 2.5.1. Cc loi ph gia s dng pha xng khng ch, xng E5, nhin liu izen v nhin liu izen B5 phi m bo ph hp vi cc quy nh v an ton, sc kho, mi trng v khng c gy h hng cho h thng ng c. 2.5.2. Vic s dng ph gia khng thng dng sn xut, ch bin v pha ch xng khng ch, xng E5, nhin liu izen v nhin liu izen B5 phi c ng k v chp thun theo quy nh ti Thng t 15/2009/TT-BKHCN ngy 02/6/2009 ca B trng B Khoa hc v Cng ngh v vic hng dn trnh t, th tc ng k vic s dng ph gia khng thng dng sn xut, ch bin, pha ch xng v nhin liu izen. 3. PHNG PHP TH 3.1. Ly mu Mu xc nh cc ch tiu quy nh trong Quy chun k thut ny c ly theo TCVN 6777 : 2007 (ASTM D 4057-06) Sn phm du m Phng php ly mu 7

QCVN 1 : 2009/BKHCN th cng hoc TCVN 6022 : 2008 (ISO 3171-88) Cht lng du m Ly mu t ng trong ng ng v theo Hng dn phng php ly mu xng du ca Tng cc Tiu chun o lng Cht lng. 3.2. Phng php th 3.2.1. Cc ch tiu ca xng khng ch, xng E5 quy nh ti khon 2.1 Mc 2 ca Quy chun k thut ny c xc nh theo cc phng php sau: TCVN 2703 : 2007 (ASTM D 2699 06a) Xc nh tr s c tan nghin cu cho nhin liu ng c nh la. TCVN 7143 : 2006 (ASTM D 3237 02) Xng Phng php xc nh hm lng ch bng quang ph hp th nguyn t. TCVN 6701 : 2007 (ASTM 2622 05) Sn phm du m Phng php xc nh lu hunh bng hunh quang tn x tia X. TCVN 7760 : 2008 (ASTM D 5453 06) Hydrocacbon nh, nhin liu

ng c nh la, nhin liu ng c izen v du ng c Phng php xc nh tng lu hunh bng ph hunh quang t ngoi. TCVN 3166 : 2008 (ASTM D 5580 02) Phng php xc nh benzen, toluen, etylbenzen, p/m-xylen, o-xylen, cc cht thm C 9 v nng hn v tng cc cht thm trong xng thnh phm bng sc k kh. TCVN 7330 : 2007 (ASTM D 1319 02a) Sn phm du m dng lng Phng php xc nh hydrocacbon bng hp ph ch th hunh quang. TCVN 7332 : 2006 (ASTM D 4815 04) Xng Xc nh hp cht MTBE, ETBE, TAME, DIPE, ru tert-Amyl v ru t C1 n C4 bng phng php sc k kh. TCVN 7331 : 2008 (ASTM D 3831 06) Xng Phng php xc nh hm lng mangan bng quang ph hp th nguyn t. 3.2.2. Cc ch tiu ca nhin liu izen , nhin liu izen B5 quy nh ti khon 2.2 Mc 2 ca Quy chun k thut ny c xc nh theo cc phng php sau: TCVN 6701 : 2007 (ASTM 2622 05) Sn phm du m Phng php xc nh lu hunh bng ph hunh quang tn x tia X.

QCVN 1 : 2009/BKHCN TCVN 7760 : 2008 (ASTM D 5453 06) Hydrocacbon nh, nhin liu

ng c nh la, nhin liu ng c izen v du ng c Phng php xc nh tng lu hunh bng ph hunh quang t ngoi. TCVN 7630 : 2007 (ASTM D 613 05) Nhin liu izen Phng php xc nh tr s xtan . TCVN 3180 : 2007 (ASTM D 4737 04) Nhin liu izen Phng php tnh ton ch s xtan bng phng trnh bn bin s. TCVN 2698 : 2007 (ASTM D 86 05) Sn phm du m Phng php xc nh thnh phn ct p sut kh quyn. TCVN 6594 : 2007 (ASTM D 1298 05) Du th v sn phm du m dng lng Xc nh khi lng ring, khi lng ring tng i, hoc khi lng API Phng php t trng k. TCVN 3171 : 2007 (ASTM D 445 06) Cht lng du m trong sut v khng trong sut Phng php xc nh nht ng hc (v tnh ton nht ng lc). TCVN 8147 : 2009 (EN 14078 : 2003) Sn phm du m dng lng Xc nh este metyl axit bo (FAME) trong phn ct gia Phng php ph hng ngoi. TCVN 8146 : 2009 (ASTM D 2274 08) Nhin liu chng ct Phng php xc nh n nh oxy ho (phng php nhanh) . TCVN 3182 : 2008 (ASTM D 6304 04a) Sn phm du m, du bi trn v ph gia Xc nh nc bng chun in lng Karl Fischer. 3.2.3. Cc ch tiu ca nhin liu izen sinh hc gc quy nh ti khon 2.3 Mc 2 ca Quy chun k thut ny c xc nh theo cc phng php sau: TCVN 7868 : 2008 (EN 14103 : 2003 ) Dn xut m v du Este metyl axit bo (FAME) Xc nh hm lng este v este metyl axit linolenic. TCVN 7757 : 2007 (ASTM D 2709 06) Nhin liu chng ct trung bnh Xc nh nc v cn bng phng php ly tm. TCVN 3171 : 2007 (ASTM D 445 06) Cht lng du m trong sut v khng trong sut Phng php xc nh nht ng hc (v tnh ton nht ng lc).

QCVN 1 : 2009/BKHCN TCVN 2689 : 2007 (ASTM D 874 06) Sn phm du m Du bi trn v cc ph gia Xc nh tro sulfat. TCVN 7760 : 2008 (ASTM D 5453 06) Hydrocacbon nh, nhin liu ng c nh la, nhin liu ng c izen v du ng c Phng php xc nh tng lu hunh bng hunh quang t ngoi. TCVN 7630 : 2007 (ASTM D 613 05) Nhin liu izen Phng php xc nh tr s xtan. TCVN 6325 : 2007 (ASTM D 664 06a) Sn phm du m Xc nh tr s axit Phng php chun in th. TCVN 7895 : 2008 (EN 14112 : 2003) Dn xut m v du Este metyl axit bo (FAME) Xc nh n nh oxy ho (php th oxy ho nhanh). TCVN 7867 : 2008 (ASTM D 6584 07) Este metyl izen sinh hc gc B100 Xc nh glycerin t do v glycerin tng - Phng php sc k kh. TCVN 7866 : 2008 (ASTM D 4951 06) Du bi trn Xc nh hm lng cc nguyn t ph gia bng quang ph pht x nguyn t plasma kt ni cm ng (ICP). 3.2.4. Cc ch tiu ca etanol nhin liu bin tnh quy nh ti khon 2.4 Mc 2 ca Quy chun k thut ny c xc nh theo cc phng php sau: TCVN 7864 : 2008 (ASTM D 5501 04) Etanol nhin liu bin tnh Xc nh hm lng etanol Phng php sc k kh. TCVN 7894 : 2008 (EN 14110 : 2003) Dn xut m v du Este metyl axit bo (FAME) Xc nh hm lng metanol. TCVN 7893 : 2008 (ASTM E 1064 05) Cht lng hu c Xc nh nc bng chun in lng Karl Fischer. TCVN 7892 : 2008 (ASTM D 1613 06) Dung mi bay hi v cc ho cht trung gian s dng trong sn, vecni, sn bng v cc sn phm lin quan Xc nh axit. TCVN 7716 : 2007 (ASTM D 4806 06c) Etanol nhin liu bin tnh dng trn vi xng lm nhin liu cho ng c nh la Yu cu k thut (Ph lc A ).

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QCVN 1 : 2009/BKHCN 3.3. X l kt qu th nghim Vic x l kt qu th nghim i vi xng, nhin liu izen v nhin liu sinh hc nh gi s ph hp c thc hin theo TCVN 6702 : 2007 (ASTM D 3244) X l kt qu th nghim xc nh s ph hp vi yu cu k thut.

4. QUN L CHT LNG 4.1. Xng, nhin liu izen v nhin liu sinh hc nhp khu, sn xut trong nc phi c nh gi chng nhn s ph hp vi cc quy nh lin quan ti Mc 2 ca Quy chun k thut ny trc khi a ra lu thng trn th trng. 4.2. Vic nh gi chng nhn s ph hp vi quy chun do t chc gim nh hoc t chc chng nhn c c quan qun l nh nc c thm quyn ch nh hoc tha nhn thc hin. 4.3. Cc phng thc nh gi chng nhn s ph hp v nguyn tc p dng i vi xng, nhin liu izen v nhin liu sinh hc c quy nh ti Ph lc II ca Quy nh v chng nhn hp chun, chng nhn hp quy v cng b hp chun, cng b hp quy ban hnh km theo Quyt nh s 24/2007/Q -BKHCN ngy 28/9/2007 ca B trng B Khoa hc v Cng ngh, c th nh sau: a) Xng khng ch, xng E5, nhin liu izen, nhin liu izen B5 , etanol nhin liu bin tnh v nhin liu izen sinh hc gc nhp khu , sn xut , ch bin , pha ch trong nc phi c nh gi chng nhn hp quy theo Phng thc 5 Th nghim mu in hnh v nh gi qu trnh sn xut; gim st thng qua th nghim mu ly ti ni sn xut hoc trn th trng kt hp vi nh gi qu trnh sn xut hoc Phng thc 7 Th nghim mu i din, nh gi s ph hp ca l sn phm, hng ha; b) Xng khng ch, xng E5, nhin liu izen, nhin liu izen B5, e tanol nhin liu bin tnh v nhin liu izen sinh hc gc sn xut, ch bin, pha ch trong nc sau khi c chng nhn hp quy phi cng b hp quy theo quy nh ti Quyt nh s 24/2007/Q -BKHCN ngy 28 thng 9 nm 2007 ca B trng B Khoa hc v Cng ngh. Xng khng ch, xng E5, nhin liu izen, nhin liu izen B5, etanol nhin liu bin tnh v nhin liu izen sinh hc gc nhp khu sau khi c chng nhn hp quy phi ng k kim tra cht lng ti c quan kim tra theo quy nh ti

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QCVN 1 : 2009/BKHCN Thng t 17/2009/TT -BKHCN ngy 18 thng 6 nm 2009 ca B trng B Khoa hc v Cng ngh. 4.4. Xng khng ch, xng E5, nhin liu izen, nhin liu izen B5, etanol nhin liu bin tnh v nhin liu izen sinh hc gc lu thng trn th trng phi m bo cht lng ph hp vi Quy chun k thut ny. 4.5. Xng khng ch, xng E5, nhin liu izen, nhin liu izen B5, etanol nhin liu bin tnh v nhin liu izen sinh hc gc nhp khu, sn xut, ch bin, pha ch v lu thng trn th trng phi chu s kim tra nh nc v cht lng theo quy nh ca php lut.

5. TRCH NHIM CA T CHC, C NHN 5.1. T chc, c nhn sn xut, ch bin, pha ch v nhp khu xng khng ch, xng E5, nhin liu izen, nhin liu izen B5, etanol nhin liu bin tnh v nhin liu izen sinh hc gc phi thc hin cng b tiu chun p dng vi ni dung khng c tri vi Quy chun k thut ny, m bo cht lng ph hp vi quy nh ti Quy chun k thut ny v theo ng tiu chun cng b p dng. 5.2. T chc, c nhn sn xut, ch bin, pha ch v nhp khu xng khng ch, xng E5, nhin liu izen, nhin liu izen B5, etanol nhin liu bin tnh v nhin liu izen sinh hc gc phi thc hin vic chng nhn hp quy, cng b hp quy theo quy nh ti Quy chun k thut ny. 5.3. T chc, c nhn phn phi v bn l xng khng ch, xng E5, nhin liu izen, nhin liu izen B5, etanol nhin liu bin tnh v nhin liu izen sinh hc gc phi m bo cht lng ph hp vi cc quy nh ti Quy chun k thut ny. 5.4. Ti cc trm hoc ca hng kinh doanh nhin liu hoc phng tin phn phi, bn l khc phi ghi r loi xng v/hoc nhin liu izen vi cc thng tin sau : Tr s octan i vi xng khng ch ; Tr s octan v k hiu E5 i vi xng E5; Hm lng lu hunh i vi nhin liu izen; Hm lng lu hunh v k hiu B5 i vi nhin liu izen B5.

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QCVN 1 : 2009/BKHCN 6. T CHC THC HIN 6.1. Tng cc Tiu chun o lng Cht lng c trch nhim hng dn v phi hp vi cc c quan chc nng lin quan t chc vic thc hin Quy chun k thut ny. Cn c vo yu cu qun l, Tng cc Tiu chun o lng Cht lng c trch nhim kin ngh B Khoa hc v Cng ngh sa i, b sung ni dung Quy chun k thut ny ph hp vi thc tin. 6.2. Khi cc tiu chun vin dn hoc hng dn quy nh ti Quy chun k thut ny c s thay i, b sung hoc c thay th th thc hin theo vn bn mi./. ________________________

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