Xun Cng THPT Kim Thnh

Anehit- Axit cacboxylic Cu 1: Cu no sau y khng ng: A.Anehit no, n chc l hp cht hu c m trong phn t c mt nhm CHO lin kt vi gc hirocacbon no B. Dung dch cha khong 40 % HCHO trong nc c gi l fomon hay fomalin C. Trong phn t anehit no, n chc mch h ch c lin kt D. Anehit fomic l cht kh tan nhiu trong nc, khng mu, c mi xc Cu 2: Trng hp no khng c s ph hp gia loi hp cht v cng thc chung ca chng A. Anehit no, n chc, mch h: CnH2nO ( n 1) B. anehit no, mch h: CnH2n+2-2xOx (n1,x1) C. Anehit khng no, n chc, mch h: CnH2n+1-2aCHO(n0, a1) D. Anehit bt k: CnH2n+2-2ax(CHO)x(n0,a0,x1) Cu 3: Chn pht biu sai: A. Anehit va c tnh oxi ha, va c tnh kh B. Khi cho anehit tc dng vi H2(xc tc Ni,t0) thu c ru bc 1 C. Khi oxi ha ru bc 1 ta thu c anehit D. Mi anehit n chc khi tc dng vi Ag2O/NH3 u c nAg = 2 nanehit Cu 4: Cho cc cht sau: H2(Ni, t0); dung dch Ag2O/NH3; Cu(OH)2, t0; NaOH, Na. S cht tc dng c vi CH3CHO l: A. 2 B.3 C.4 D.5 Cu 5: un nng mt anehit A vi dung dch Ag2O/NH3 thu c cht hu c B. Bit B c phn ng trng gng. Cng thc cu to ca A l: A. H-CHO B. CH3-CHO C. CH3CH2CHO D. A,B,C u sai Cu 6: Cu no sau y khng ng ATrong cng nghip HCHO c iu ch bng cch oxi ha CH3OH bng oxi khng kh xc tc l Cu hoc Pt nhit cao B. HCHO c ng dng trong cng nghip iu ch cht do phenolfomanehit C. phn bit C2H5OH v CH3CHO ta c th dng dung dch Ag2O/NH3 v un nng nh D. phn bit 2 dung dch HCOONH4 v HCHO ta c th dng dung dch Ag2O/NH3 v un nng nh Cu 7: Chn phng n khng ng khi gi tn cc anehit A. H-CHO: Metanal B. CH3-CH(CH3)-CHO: Anehit butiric C. CH3-CH2-CH2-CHO: Butanal D.CH3-CH2-CH(CH3)-CHO: 2-Metylbutanal

M N P. P l Cu 8: Cho s : CaC2 A. CH3CHO B. CH3OH C.CH3-CH2-OH D. HCHO Cu 9: t chy hon ton hn hp 2 anehit A,B thu c s mol kh CO2 = s mol nc th A. A, B u l anehit no, n chc, mch h B. trong hn hp c t nht 1 anehit no, n chc, mch h C. A,B du l anehit khng no, n chc, mch h D. trong hn hp phi c t nht 1 anehit khng no + Ag 2O / NH 3 Cl 2 , as NaOH ,t 0 CuO ,t 0 Cu 10: Cho s A + B + E ( E l axit benzoic). A l: C + D A. Benzen B. Etylbenzen C. ru benzylic D. toluen Cu 11: Cho s phn ng sau Ag 2O / NH 3 Cl2 NaOH CuO X + Y + Z + T + G ( axit acrylic). Cc cht X, Z c th l cht no sau y ? A. C3H8 v CH3CH2CH2OH B. C2H6v CH2=CH-CHO C. C3H6 v CH2=CH-CHO D. C3H6 v CH2=CH-CH2OH Cu 12: Khi cho 0,1 mol mt anehit n chc A tc dng vi dug dch Ag2O trong mi trng amoniac( ly d) ta thu c 43,2 gam Ag kt ta. Cng thc cu to ca A l: A. CH3CHO B. HCHO C. CH3CH2CHO D. CH2=CH-CHO Cu 13: Cho 8,8 gam hn hp X gm HCHO v C2H5CHO tc dng vi dung dch Ag2O/NH3 d, sau khi phn ng xy ra hon ton thu c 64,8 gam Ag kt ta. % khi lng ca HCHO v C2H5CHO ln lt l: A. 34,1 v 65,9 B. 25,7 v 74,3 C.65,7 v 34,3 D. kt qu khc Cu 14: t chy hon ton 0,5 mol hn hp gm CH3OH v CH3CHO, CH3COOH , sau phn ng thu c 0,9 mol CO2 v 1 mol nc. Tnh % s mol ca CH3OH c trong hn hp? A.10% B. 20% C.30% D. 40% Cu 15: Hn hp A gm HCHO, CH3CHO, CH2=CH-CHO. Cho 0,4 mol A tc dng vi dung dch Ag2O (ly d) trong mi trng amoniac thu c 108 gam Ag kt ta. Tnh khi lng ca HCHO c trong 0,4 mol hn hp A. A. 1,5 gam B. 3 gam C. 4,5 gam D. kt qu khc Cu 16: Cho 0,2 mol mt anehit no A tc dng vi H2 d ( xc tc Ni, t0) thu c ru B. Cho B tc dng vi Na d thu c 0,1 mol kh H2. Mt khc t chy hon ton 11,6 gam A thu c 13,44lt kh CO2 ( ktc). Cng thc cu to ca A l: A. HCHO B. CH3CHO C. CH3CH2CHO D. CH2(CHO)-CH2(CHO) Cu 17: Oxi ha ht 7,4 gam mt ru no n chc A bng CuO un nng thu c anehit B. em ht B thc hin phn ng trng gng thu c 21,6 gam Ag. Cng thc cu to ca B l: A. HCHO B. CH3-CH(CHO)-CH3 C. CH3-CH2-CH2-CHO D. C A v B ng Cu 18:Cho 1,02 gam hn hp X gm 2 andehit no, n chc mch h A,B k tip nhau p vi dung dch Ag2O trong mi trng NH3 d thu c 4,32 gam Ag. Cng thc phn t ca A,B l :

+ H 2O

+ H 2O , HgSO4 ,t 0

+ H 2 , Ni ,t 0

Xun Cng THPT Kim Thnh

A. HCHO v CH3CHO B. CH3CHO v C2H5CHO C. C2H5CHOv C3H7CHO D. C3H7CHO v C4H9CHO Cu 19: Cho cc cht sau: HCOOH; HCOO-CH3; HCOONa; CH3CHO; CH3-COO-CH3; CH2=CH-CHO; CH3COOH; C2H5OH; C6H5CHO; HCOONH4. S cht c phn ng trng gng l: A. 7 B.8 C.9 D.10 Cu 20: Hn hp X gm 2 ru n chc bc 1 l A,B ( MA < MB). Cho m gam X tc dng vi Na d thu c 2,24 lt kh H2(ktc)> Mt khc khi oxi ha m gam X thu c hn hp anehit Y. Cho Y tc dng vi dung dch Ag2O/NH3 thu c 64,8 gam Ag. (Cc phn ng xy ra hon ton). Cng thc cu to ca A l: A. CH3OH B. CH3-CH2-OH C. CH3-CH2-CH2-OH D. kt qu khc Cu 21:Cho cc cht sau:CH3CH2CHO(1); CH3CH2CH3(2);CH3-O-CH3(3); C2H5OH(4):Th t nhit si tng dn l: A. 1<2<3<4 B. 2<3<1<4 C. 2<1<3<4 D.2<3<4<1 Cu 22: Trng hp no khng c s ph hp gia cng thc v loi hp cht A. Axit no, n chc mch h: CnH2nO2(n1) B. Axit no, a chc mch h: CnH2n+22xO2x(n2, x2) C. Axit khng no, mch h, cha 1 lin kt i: CnH2n-1COOH(n0) D. Axit thm thuc ng ng ca benzoic: CnH2n-7COOH(n6) Cu 23: Axit CH3COOH c nhit si ln hn ru etylic l: A. do 2 phn t CH3COOH lin kt vi nhau bng 2 lin kt hiro B. do lin kt hiro gia cc phn t axit CH3COOH mnh hn gia cc phn t ru C.do ru etylic khng tc dng c vi dung dch NaOH, cn CH3COOH tc dng c vi dung dch NaOH D.c A,B ng Cu 24: Trng hp no khng ph hp gia tn gi v cng thc cu to: A. CH2=CH-COOH: axit acrylic B. CH3-CH2-CH2COOH axit butanoic C.CH3-CH(CH3)-COOH axit iso-butiric D. CH3-CH(CH3)-CH2-COOH: axit 2-metylbutiric Cu 25: Trng hp no khng ph hp gia tn gi v cng thc cu to: A. HOOC-(CH2)4-COOH: axit aipic B. CH2=C(CH3)-COOH: axit metacrylic C. CH3-(CH2)16-COOH: axit stearic D. CH3-(CH2)14-COOH: axit oleic Cu 26: So snh tnh axit ca cc cht sau: p-Metylbezoic (1); p-nitrobenzoic(2); axit benzoic(3); phenol(4). A. 4<1<3<2. B.1<4<3<2. C.4<1<3<2. D.4<3<1<2. Cu 27:So snh tnh axit ca cc cht sau: CH3-CH2-COOH(1); CH2Cl-CH2COOH(2); CH3CHClCOOH(3);CH3CHF-COOH(4). A.1<2<3<4. B. 1<2<4<3. C.2<3<4<1. D.4<3<2<1. Cu 28: cho cc axit: CH3COOH; C2H5COOH; CH2Cl-COOH; HCl. Axit yu nht l: A. CH3COOH B. C2H5COOH C. CH2Cl-COOH D. HCl Cu 29: Cho cc cht sau: C2H5OH (H2SO4 c, t0); MgCO3; Cu, Ba(OH)2. Cht khng tc dng vi CH3COOH l: A. C2H5OH (H2SO4 c, t0) B. MgCO3 C. Cu D. Ba(OH)2 Cu 30: Cho cc cht sau: CaO; Mg; CH3OH, HCl; NaHSO4; KOH; NaCl; Na2CO3; KHCO3; S cht tc dng c vi dung dch CH3COOH l: A. 6 B.7 C.8 D.9 Cu 31: S cht ng phn c cng thc phn t C4H8O2 tc dng c vi CaCO3 l: A. 2 B.3 C.3 D.8 Cu 32:Hai cht hu c X,Y cng c cng thc phn t C3H4O2. X phn ng vi Na2CO3 ,ru etylic v phn ng trng hp. Y phn ng vi dung dch KOH, bit Y khng phn ng Na. Cng thc ca X, Y ln lt l: A. OHC-CH2-CH2-CHO v HO-CH2-CC-CH2-OH B HCOO-CH=CH2v CH2=CH-COO-CH3 C.CH2=CH-COO-CH3 v CH3-COOCH=CH2 D.CH2=CH-COOH v HCOO-CH=CH2 Cu 33:HCOOH c th tc dng vi tt c cc cht trong nhm no sau y: A. Mg, CH3OH( H2SO4 c, nng); NaOH; KHCO3; NaCl B. dung dch amoniac; CaO; Cu; CaCO3 C. Dung dch Ag2O/NH3; BaCO3; Mg; C2H5OH( H2SO4 c , nng) D. dung dch K2SO4; Na; dung dch Na2CO3 Cu 34: Dung dch trong nc ca cht no di y khng lm chuyn mu qu tm A. Axit metacrylic B. Axit aipic C. Axit aminoaxetic D. Axit glutamic Cu 35: Hai cht X,Y c cng cng thc phn t C4H8O2. Khi cho X,Y tc dng vi dung dch NaOH , th X to cht X c cng thc C4H7O2Na cn Y to cht Y c cng thc C3H5O2Na. Vy X,Y ln lt thuc loi A Ru ; axit B. Axit; este C. Este; ru D. Axit; ru Cu 36:Chn phng n sai A. Axit CH2=CH-COOH phn ng c vi tt c cc cht:nc brom, Na, NaOH, CH3OH(xt), HBr, v c p trng hp B. Tnh axit CH2=CH-COOH > CHC-COOH>CH3COOH> H2CO3 > C6H5OH > H2O C.Axit HOOC-CH=CH-COOH c ng phn cis- trans D. CH3COOH c th tc dng vi tt c cc cht: dung dch NH3; CHCH (c xt) ; dung dch C6H5Ona Cu 37: Cho m gam hn hp gm CH3COOH v C3H7OH tc dng vi Na d, thu c 4,48 lt kh H2 ( ktc). Tnh m? A. 12 g B. 24g C. 30 g D. kt qu khc Cu 38: 3,15 gam hn hp gm CH3COOH, axit acrylic, axit propionic lm mt mu va dung dch cha 3,2 gam Br2. trung ho hon ton 3,15 gam hn hp trn cn 90ml dung dch NaOH 0,5M. % khi lng ca mi axit trong hn hp ln lt l:

Xun Cng THPT Kim Thnh

A. 25; 25; 25 B. 19,04; 35,24; 45,72 C. 19,04; 45,72; 35,24 D. 45,71; 35,25; 19,04 Cu 39: trung ho 2,25 gam mt i axit A cn 20ml dung dch NaOH 2,5M. Cng thc phn t ca A? A. C2H2O4 B. C3H4O4 C.C4H4O4 D. kt qu khc Cu 40: t chy 0,1 mol mt axit hu c n chc X cn 0,3 mol O2. Cng thc phn t ca X l: A. C2H4O2 B. C3H6O2 C.C3H4O2 D. kt qu khc Cu 41: trung ho 50ml dung dch A cha mt axit hu c n chc v mui Ba ca axit cn va 100ml dung dch MOH 0,15mol/l ( M l kim loi kim) thu c dung dch B, c cn B thu c 6,33 gam mui khan Mt khc khi cho dung dch H2SO4 d vo 50ml dung dch khc ca A thu c 4,66 gam kt ta. Cng thc ca Axit l: A. HCOOH B.CH3COOH C. CH3-CH2COOH D. CH2=CH-COOH Cu 42: trung ho 13,4 gam hn hp 2 axit A, B n chc, k tip nhau cn 200ml dung dch Ba(OH)2 0,5M. Cng thc ca A,B ln lt l: A.HCOOH v CH3COOH B. CH3COOH v CH3CH2COOH C.C2H3COOH v C3H5COOH D. Kt qu khc Cu 43:Cho hn hp X gm ru metylic v 2 axit k tip nhau trong dy ng ng ca CH3COOH td ht vi Na thu c 6,72 lt kh H2(ktc). Nu un nng hn hp X ( c H2SO4 c xuc tc ) th cc cht trong hn hp phn ng va ht vi nhau thu c 25 gam este. Cng thc ca 2 axit l: A.HCOOH v CH3COOH B. CH3COOH v CH3CH2COOH C. C2H5COOH v C3H7COOH D. Kt qu khc Cu 44: 0,2 mol mt axit A phn ng va 20 gam CaCO3 th A thuc loi axit A. n chc B. 2 chc C. 3 chc D. khng no, n chc Cu 45:: t chy hon ton m gam mt axit X thu c t l th tch kh CO2 v hi nc tng ng l 1:1. Mt khc trung ho 14,8 gam X cn 100ml dung dch Ba(OH)2 1M. Cng thc ca X l A. HCOOH B. CH2(COOH)2 C. CH3CH2COOH D. CH2=CH-COOH Cu 46: Cho 21,2 gam hn hp A gm HCOOH v HCHO tc dng vi dung dch NaHCO3 d thu c 4,48 lt kh CO2 (ktc). Nu cho 10,6 gam hn hp A phn ng vi lng d dung dch Ag2O /NH3 thu c m gam Ag. Gi tr m l: A. 10,8 gam B. 216 gam C. 108 gam D. 64,8 gam