S GD & T HA BNH

TRNG THPT KIM BI

THI TH I HC LN TH NHT
Mn : Ha Hc
Thi gian lm bi: 90 pht
M thi 132

H, tn th sinh.. ................
S bo danh:...............................................................................
Cho nguyn t khi ca cc nguyn t:
H = 1, C = 12, O = 16, N = 14, Fe = 56, S = 32, Se = 79, Te = 128, Zn = 65, Cu = 64, Ag = 108
Cr = 52, Na = 23, K = 39, Ca = 40, Ba = 137, Mg = 24; Sr = 88; Cl = 35,5; Br = 80; Sn = 119.
Cu 1: Hn hp X gm (Fe, Fe2O3, Fe3O4, FeO) vi s mol mi cht l 0,1 mol, ha tan ht vo dung dch Y
gm HCl v H2SO4 (long, d) thu c dung dch Z. Nh t t dung dch Cu(NO3)2 1M vo dung dch Z cho
ti khi ngng thot kh NO (sn phm kh duy nht). Th tch dung dch Cu(NO3)2 cn dng v th tch kh
thot ra ktc l
A. 25 ml; 1,12 lt.
B. 50 ml; 2,24 lt.
C. 0,5 lt; 22,4 lt.
D. 50 ml; 1,12 lt.
3+
Cu 2: Trong s cc kim loi di y c bao nhiu kim loi c th kh Fe trong dung dch thnh kim loi :
Zn, Na, Cu, Al, Fe, Ca, Mg
A. 4
B. 2
C. 6
D. 3
Cu 3: Cho s chuyn ha:
+H O
+ Br2 + dung dch NaOH
+ S ,t 0
Cr
Y
Z
X 2
Cc cht X, Y, Z ln lt l
A. CrS, Cr(OH)2, Na2Cr2O7.
B. Cr2S3, Cr(OH)3, Na2Cr2O7.
C. Cr2S3, Cr(OH)3, Na2CrO4.
D. CrS, Cr(OH)2, NaCrO2 (hay Na[Cr(OH)4]).
Cu 4: Ha tan hon ton 24,9 gam hn hp X gm Zn v Sn bng dung dch HCl (d) thu c 6,72 lt kh H 2
(ktc). Th tch O2 ( ktc) cn phn ng hon ton vi hn hp X trn l
A. 3,36 lt
B. 3,92 lt
C. 4,48 lt
D. 2,08 lt
Cu 5: Cho 9,55 gam hn hp gm Mg, Al v Zn tc dng va vi 870 ml dung dch HNO 3 1M, thu c
dung dch cha m gam mui v 0,06 mol hn hp kh N2 v N2O. T khi ca hn hp kh so vi H2 l 20,667.
Gi tr ca m l
A. 54,95
B. 40,55
C. 42,55
D. 42,95
Cu 6: Cho hn hp cha x mol Mg v 0,2 mol Fe vo 200 ml dung dch hn hp Fe2(SO4)3 1M v CuSO4 1M, n
phn ng hon ton thu c dung dch A v 18,4 gam cht rn. Gi tr ca x l:
A. 0,4.
B. 0,2.
C. 0,3.
D. 0,1.
Cu 7: Ha tan hon ton m gam hn hp gm Ba v Al2O3 vo nc thu c dung dch X v 0,2 mol H2. Sc
kh CO2 ti d vo X, xut hin 11,7 gam kt ta. Gi tr ca m l
A. 21,35.
B. 37,60.
C. 42,70.
D. 35,05.
Cu 8: Cho hn hp A gm hai este c cng thc phn t C4H8O2 v C3H6O2 tc dng vi NaOH d thu c 6,14 gam
hn hp hai mui v 3,68 gam ru B duy nht c t khi hi so vi oxi l 1,4375. Khi lng C 4H8O2 v C3H6O2 trong
A ln lt l
A. 4,4 v 2,22 gam
B. kt qu khc
C. 2,2 v 1,11 gam
D. 6.6 v 3,33 gam
Cu 9: Hn hp X gm 1 ankin, 1 ankan (s mol ankin bng s mol ankan), 1 anken v 2 amin no, n chc,
mch h Y v Z l ng ng k tip (M Y < MZ). t chy hon ton mt lng hn hp X trn cn 174,72 lt
O2 (ktc), thu c N2, CO2 v 133,2 gam nc. Cht Y l
A. etylamin.
B. butylamin
C. propylamin.
D. metylamin.
+
+
2Cu 10: S electron trong cc ion sau: NO3 , NH4 , HCO3 , H , SO4 theo th t l
A. 32; 12; 32; 0; 50
B. 32; 10; 32; 0; 50
C. 31;11; 31; 0; 48
D. 32; 10; 32; 0; 46
Cu 11: Cho 25,65 gam mui gm H2NCH2COONa v H2NCH2CH2COONa tc dng va vi 250 ml dung
dch H2SO4 1M. Sau phn ng c cn dung dch th khi lng mui do H2NCH2COONa to thnh l
A. 37,9 gam
B. 29,25 gam
C. 18,6 gam
D. 12,4 gam
Cu 12: Magie trong thin nhin gm 2 loi ng v l X, Y. ng v X c nguyn t khi l 24. ng v Y
hn X mt ntron. Bit s nguyn t ca hai ng v c t l X/Y = 3/2. Nguyn t khi trung bnh ca Mg l
Trang 1/5 - M thi 132

A. 24,8
B. 25,0
C. 24,4
D. 24,0
Cu 13: Hn hp A gm 3 ankin X,Y,Z c tng s mol l 0.05 mol.S nguyn t cacbon trong phn t mi
cht u ln hn 2.t chy hon ton 0,05 mol A,thu c 0,13 mol H2O.Cho 0,05 mol A vo dung dch
AgNO3 0,12M trong NH3 th thy dng ht 250 ml dung dch AgNO 3 v thu c 4,55 gam kt ta.Cng thc
phn t ca Y l?Cho bit ankin c khi lng phn t nh nht chim 40% s mol ca
A. C5H8
B. C3H4
C. C4H6
D. C6H10
Cu 14: Phng php no sau y dng iu ch etanol trong phng th nghim:
A. Thy phn dn xut halogen(C2H5Br) bng dung dch kim
B. Cho etilen hp nc (xc tc axit)
C. Kh andehit(CH3CHO) bng H2
D. Thy phn este CH3COOC2H5(xc tc axit)
Cu 15: Cho dy cc cht: axetilen, anehit axetic, axit fomic, anilin, phenol, metylxiclopropan. S cht trong
dy lm mt mu nc brom l
A. 6.
B. 5.
C. 4.
D. 3.
Cu 16: Cho dy cc cht: C2H5COOH (1), CH3CHClCOOH (2), CH2ClCH2COOH (3), CH2ClCOOH (4),
CH2FCOOH (5). Dy cc cht sp xp theo th t lc axit gim dn t tri sang phi l
A. (5), (2), (4), (3), (1). B. (1), (3), (2), (4), (5). C. (5), (4), (2), (3), (1). D. (4), (5), (3), (2), (1).
Cu 17: Dn mu kh thi ca mt nh my qua dung dch AgNO3 d th thy xut hin kt ta mu en. Hin
tng chng t trong kh thi nh my c kh no sau y?
A. HBr.
B. HI.
C. H2S.
D. HCl.
Cu 18: X v Y l hai nguyn t thuc hai nhm A lin tip. Tng s proton ca nguyn t X v Y l 25. Y
thuc nhm VIA. n cht X khng phn ng trc tip vi n cht Y. Nhn xt no sau y v X, Y l ng?
A. trng thi c bn, nguyn t X c 3 electron c thn.
B. Cng thc oxi cao nht ca X l X2O5.
C. Bn knh nguyn t Y ln hn bn knh nguyn t X.
D. m in ca Y ln hn m in ca X.
Cu 19: Ha tan hon ton m gam hn hp X gm Na v K vo dung dch HCl d thu c dung dch Y.
C cn dung dch Y thu c (m + 31,95) gam hn hp cht rn khan. Ha tan hon ton 2m gam hn
hp X vo nc thu c dung dch Z. Cho t t ht dung dch Z vo 0,5 lt dung dch CrCl3 1M n phn
ng hon ton thu c kt ta c khi lng l :
A. 51,5 gam.
B. 54,0 gam.
C. 30,9 gam.
D. 20,6 gam.
Cu 20: phn bit CH3NH2; (CH3)2NH; (CH3)3N ta dng thuc th no sau y:
A. Dung dch HNO2.
B. Dung dch HCl.
C. Dung dch phenolphlatein.
D. Qu tm.
Cu 21: C cc nhn nh sau:
(1) iu ch anehit fomic trong cng nghip bng phn oxi ha metanol.
(2) iu ch ancol etylic trong phng th nghim bng phn ng hirat ha etilen.
(3) Glucoz v saccaroz u tham gia phn ng trng gng.
(4) Khng th nhn bit dung dch glucoz v v dung dch axit acrylic bng nc brom.
S nhn inh ng l
A. 3
B. 4
C. 1
D. 2
Cu 22: Nhit phn hon ton R(NO3)2 (vi R l kim loi) thu c 8 gam mt oxit kim loi v 5,04 lt hn
hp kh X gm NO2 v O2 (o ktc). Khi lng ca hn hp kh X l 10 gam. Xc nh cng thc ca mui
R(NO3)2 ?
A. Fe(NO3)2.
B. Cu(NO3)2 .
C. Mg(NO3)2.
D. Zn(NO3)2 .
Cu 23: C phn ng xy ra trong dung dch: C2H5Br + KOH C2H5OH + KBr
Nng ban u ca KOH l 0,07M. Sau 30 pht ly ra 10ml dung dch hn hp phn ng th thy n c
trung ha va bi 12,84ml dung dch HCl 0,05M. Tnh tc trung bnh ca phn ng trong khong thi
gian trn.
A. 3.10-5M.s-1
B. 3,22.10-6M.s-1
C. 2,32.10-6M.s-1
D. 2.10-6M.s-1
Cu 24: Ho tan x mol CuFeS2 bng dung dch HNO3 c nng sinh ra y mol NO2 (sn phm kh duy
nht). Lin h ng gia x v y l :
A. x =15y.
B. x =17y.
C. y =17x.
D. y =15x.
Trang 2/5 - M thi 132

Cu 25: Thc hin crackinh V lit kh butan thu c 1,75V lit hn hp kh gm 5 hirocacbon. Hiu sut phn
ng crackinh butan l (Bit cc kh o cng iu kin nhit v p sut)
A. 80%
B. 50%
C. 25%
D. 75%
Cu 26: Cho 6,44 gam mt ancol n chc phn ng vi CuO un nng, thu c 8,68 gam hn hp X gm
anehit, nc v ancol d. Cho ton b X tc dng vi lng d dung dch AgNO3 trong NH3, kt thc cc
phn ng thu c m gam Ag. Gi tr ca m l
A. 60,48.
B. 30,24.
C. 86,94.
D. 43,47.
Cu 27: Trng hp no sau y khng thu c kt ta khi cc phn ng kt thc?
A. Cho dung dch Na2S2O3 vo dung dch H2SO4 long.
B. Nh t t ti d dung dch Ba(OH)2 vo dung dch Al2(SO4)
C. Sc kh SO2 vo dung dch KMnO4.
D. Cho AgNO3 vo dung dch CuCl2.
Cu 28: Hn hp X gm C2H5OH, C2H5COOH, CH3CHO trong ancol chim 50% theo s mol. t chy m
gam hn hp X c 3,06 gam H2O v 3,136 lt CO2 (ktc). Mt khc 13,2 gam hn hp X thc hin phn ng
trng bc thy c p gam Ag kt ta. Gi tr ca p l
A. 8,64 g
B. 10,08 g
C. 6,48 g
D. 9,72 g
Cu 29: S tripeptit mch h ti a thu c t hn hp ch gm glyxin v alanin l
A. 8.
B. 4.
C. 6.
D. 9.
Cu 30: t chy hon ton 0,1 mol cht hu c X l dn xut ca benzen thu c CO2 c khi lng nh
hn 35,2 gam. Bit rng a (mol) X phn ng va vi 500 ml dung dch NaOH 2a(M). Cng thc cu to ca
X l
A. HO-CH2-C6H4-COOH
B. C6H4(OH)2.
C. HO-C6H4-CH2OH.
D. C6H5-CH2OH.
Cu 31: Tnh oxi ha ca (1)HClO; (2)HClO2; (3)HClO3; (4)HClO4 c sp sp theo th t tng dn l
A. 2<3<4<1
B. 4<3<2<1
C. 1<2<3<4
D. 4<1<2<3
Cu 32: t chy hon ton mt amin n chc X bng mt lng khng kh (cha 80% th tch N2, cn li l
O2) va , ch thu c 0,15 mol CO2; 0,175 mol H2O v 0,975 mol N2. Cng thc phn t ca X l
A. C9H21N.
B. C3H9N.
C. C2H7N.
D. C3H7N.
Cu 33: Cht hu c Y thnh phn cha C, H, O c kh nng tc dng vi Na gii phng H 2, tham gia phn
ng trng bc v ha tan Cu(OH)2 thnh dung dch mu xanh. Khi t chy 0,1 mol Y thu c khng qa 0,2
mol sn phm. Cng thc phn t Y l
A. C2H4O2
B. CH2O3
C. CH2O
D. CH2O2
Cu 34: Cho cc dung dch c cng nng mol sau: C2H5ONa(1); CH3COONa(2); C6H5ONa(3);
C2H5COOK(4); Na2CO3(5). Th t tng dn PH t tri sang phi l:
A. 2;3;5;4;1
B. 2;4;5;3;1
C. 3;4;5;1;2
D. 2;5;1;4;3
Cu 35: in phn 500 ml dung dch CuSO4 0,2M (in cc tr) cho n khi catot thu c 3,2 gam
kim loi th th tch kh (ktc) thu c anot l :
A. 1,12 lt.
B. 0,56 lt.
C. 3,36 lt.
D. 2,24 lt.
Cu 36: PVC c iu ch t kh thin nhin theo s :
CH4 C2H2 CH2=CHCl PVC. Nu hiu sut ton b qu trnh iu ch l 20% th th tch kh thin
nhin (ktc) cn ly iu ch ra 1 tn PVC l (xem kh thin nhin chim 100% metan)
A. 6426 m3
B. 3584 m3
C. 12846 m3
D. 8635 m3
Cu 37: t chy hon ton 12,5 gam mt hirocacbon X mch h (l cht kh iu kin thng), ri em
ton b sn phm chy hp th ht vo bnh ng dung dch Ba(OH)2. Sau cc phn ng thu c 108,35 gam
kt ta v phn dung dch gim 59,85 gam. S nguyn t hiro trong phn t X l
A. 2.
B. 8.
C. 6.
D. 4.
Cu 38: Nhm th c sn trn nhn benzen nh hng phn ng th vo v tr ortho v para l:
A. OH , NH2 , gc ankyl , halogen
B. CnH2n+1- , NO2
C. OH , NH2 , CHO
D. CnH2n+1- , COOH
Cu 39: Hai dung dch CH3COONa v NaOH c cng PH,nng mol/l ca cc dung dch tng ng l x v
y.Quan h ca x v y l:
A. x=0,1
B. x<y
C. x>y
D. x=y
Trang 3/5 - M thi 132

Cu 40: Pht biu no sau y khng ng ?

A. Mui AgI khng tan trong nc, mui AgF tan trong nc.
B. Dung dch HF ho tan c SiO2.
C. Trong cc hp cht, ngoi s oxi ho -1, flo v clo cn c s oxi ho +1, +3, +5, +7.
D. Flo c tnh oxi ho mnh hn clo.
Cu 41: Cho hn hp kh X gm HCHO, C2H2 v H2 i qua ng s ng bt Ni nung nng. Sau mt thi gian
thu c hn hp Y (gm kh v hi). t chy hon ton Y cn dng va 0,07 mol O 2, sinh ra 0,055 mol
CO2 v 0,81 gam H2O. Phn trm th tch ca HCHO trong X l
A. 25,00%.
B. 33,33%.
C. 66,67%%.
D. 75,00%.
Cu 42: Axit photphoric v axit nitric cng phn ng c vi nhm cht no sau y:
A. MgO,KOH,CuSO4,NH3
C. CuCl2,KOH,Na2CO3,NH3
B. KOH,Na2CO3,NH3,MgCl2
D. KOH,K2O,NH3,Na2CO3
Cu 43: X, Y, Z l cc hp cht v c ca mt kim loi, khi t nng nhit cao u cho ngn la mu
vng. X tc dng vi Y thnh Z. Nung nng Y nhit cao thu c Z, hi nc v kh E. Bit E l hp cht
ca cacbon, E tc dng vi X cho Y hoc Z. X, Y, Z, E ln lt l cc cht no di y?
A. NaOH, Na2CO3, CO2,NaHCO3
B. NaOH,NaHCO3,Na2CO3,CO2
C. KOH, KHCO3, CO2, K2CO3
D. NaOH,Na2CO3,NaHCO3,CO2
Cu 44: Ha tan hn hp ba kim loi Zn, Fe, Cu bng dung dch HNO3 long. Sau khi phn ng xy ra hon
ton, thu c cht khng tan l Cu. Phn dung dch sau phn ng c cha cht tan no?
A. Zn(NO3)2; Fe(NO3)3; Cu(NO3)2
B. Zn(NO3)2; Fe(NO3)2; Cu(NO3)2
C. Zn(NO3)2; Fe(NO3)3
D. Zn(NO3)2; Fe(NO3)2
Cu 45: X l dung dch Al2(SO4)3, Y l dung dch Ba(OH)2. Trn 200ml X vi 300ml Y c 8,55 gam kt ta.
Trn 200ml X vi 500ml Y c 12,045 gam kt ta. Nng mol/l ca dung dch X v Y ln lt l:
A. 0,1M v 0,05M
B. 0,1M v 0,2M
C. 0,05M v 0,075M
D. 0,075M v 0,1M
Cu 46: Cho V lt CO2 (ktc) hp th ht trong dung dch cha 0,2 mol Ba(OH)2 v 0,1 mol NaOH.Sau phn
ng xy ra hon ton thu c kt ta v dung dch cha 21,35 gam mui.Gi tr ca V l
A. 7,84
B. 8,96
C. 6,72
D. 8,4
Cu 47: Cho vo mt bnh kn dung tch khng i 2 mol Cl 2 v 1 mol H2 th p sut ca bnh l 1,5 atm. Nung
nng bnh cho phn ng xy ra vi hiu sut t trn 90%. a bnh v nhit ban u th p sut ca bnh l
P. Gi tr no sau y ca P l tho mn:
A. 1,35 atm.
B. 1,75 atm.
C. 2 atm.
D. 1,5 atm.
Cu 48: Tin hnh cc th nghim sau:
(a) Cho Mg vo dung dch Fe2(SO4)3 d;
(b) Dn kh H2 (d) qua bt MgO nung nng;
(c) Cho dung dch AgNO3 tc dng vi dung dch Fe(NO3)2 d;
(d) Cho Na vo dung dch MgSO4;
(e) Nhit phn Hg(NO3)2;
(g) t Ag2S trong khng kh;
(h). in phn dung dch Cu(NO3)2 vi cc dng lm bng ng, cc m lm bng thp.
S th nghim khng to thnh kim loi l
A. 3.
B. 2.
C. 5.
D. 4.
Cu 49: Cho cc pht biu sau:
(a) Mantoz b thy phn trong dung dch kim long, un nng to thnh glucoz.
(b) Dung dch glucoz khng lm mt mu nc brom.
(c) Glucoz, mantoz v fructoz u tham gia phn ng trng bc.
(d) Amilopectin c cu trc mng li khng gian.
(e) Xenluloz khng phn ng vi Cu(OH)2.
(g) H tinh bt tc dng vi I2 to ra sn phm c mu xanh tm.
S pht biu ng l
A. 4.
B. 5.
C. 2.
D. 3
Cu 50: Nhit si ca cc cht sau: Ancol etylic(1), etyl clorua (2), ietyl ete (3) v axit axetic (4) c sp
xp theo th t gim dn l
A. (1 ) > (2) > (3) > (4) B. (1) > (2) > (3) > (4) C. (4) > (3) > (2) > (1 ) D. (4) > (1) > (3) > (2)
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