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7 L Kq - ( 232mH 4 67 4g ? 1$ 0,5) .(
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Y #NB ?? + Y = 768nm 1%G( 6 %(  R F (R KU r 1G N "14W Y ;g'7E D >>a2 D>>a1 sR ?+U (? D=2,5m EU( Y  Aq .a 1>a2 sR a2 a1 %

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1
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. Pb k#  Y Po '  %: (1
. x%% ( n% ( 0,5
:N . x%% ? $:7 BN MeV : W $" nUR ( 0,5
1u = 1,66 10 27 Kg c = 3 10 8 m / s e = 1,6 10 19 C
. m( Pb) = 206,0385u
m( ) = 4,00394u
206
82

m( Po) = 210,04824u

210
84

. ln a = f (t )  nUR 210
84 Po 7 a  ) 7 #[% (2
. e ln a = a : N. a #: ( R ( 0,5
. LUR W t1 / 2 8g7 # # ( 0,5
. mo = 10 g : t = 0 _' 7 1%% 210
84 Po  (?  7 #% (3
t = 1h _' 7 4%  % nUR ;%+ U7"  ) 7 B %" ( 0,5
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AG4 :$ 7 G'# . 25C
%"W'q
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 B G|R/

)!o
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 )! /
pK A = 4,7
CH 3COOH / CH 3COO
(X/ (X

NH 4 / NH 3

pK A = 9,2

/ XU

H 3O + / H 2 O

pK A = 0

 1/U

H 2 O / HO

pK A = 1,4

-1$  X:
:1-1 8#: K$  X 0,25) .(
R:2-1 L%B ?( BeNN  0,25) .4"U(
|R ; : -2)! A( o.
|R 8q :1-2)! o d9 Y '( Y ;g'7E V1 = 10ml L$R S1#:f
0,25) . C1 = 2.10 2 mol / l(
B N pH' . pH 1 = 3,2 : S1
:1-2( n% |R ; :)! A( o 0,25) .(
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; : (3(X ( A:
2
'" #q" D (X E ('\ V2 = 10ml L$R S 2#:B N . C 2 = 10 mol / l f pH
' S 2. pH 2 = 10,6 4
:1-3( n% ; :(X ( A 0,25) .(
(2-3 ( KN9 71 G(X/ (X . w%7%7  E ?1' 0,5) . S 2(
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N: (4 |R KO)! o(X E:
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4
' EF" V = 20ml L$R S \'( #q Y |R ?( 2.10 mol / l)! o ?( 10 mol(X27 '%
' ; %" ;k :
+
CH 3 COO + NH 4
CH 3 COOH + NH 3
) ( aq

) ( aq

) ( aq

) ( aq

:1- 4O nUR  E  $ Qr ,i ; %'  0,25) .(

( 0,5) w%7%U: ( Qr ,eq Qr ,i B :2-4

( 0,5) .(4% $" %\? +) .; % x3 f 17 4% "\ Qr ,eq ? # :3-4

?%G; (? + U7" 17 ' E  gR ?( BeN   ? $' : % ? + ; :4-4
+
S 'pH 2Ov #UE. S  'E 71 + X NH 4 / NH 3 CH 3COOH / CH 3COO
( 0,5) . % 7 pH = 4,7 4
: 4 q' #( 5
N "$: 8q . C a = 10m.mol / l f#: o!)| R (? ('Va = 20ml $R v E Aq
" L ;g' ' pH #%( - pH N "j4 C b = 20m.mol / l f#: g U (? Vb $R R'
.EF;
( 0,25) . 4 q' # $\ ;%U #$% 1$ (!; :1-5
( 0,25) . # ; :  (n% :2-5
( 0,25) .`E+% Y g' L%EF AB% VbE $' nUR :3-5
. pH = 4,8 Y ;g' g U (? (' Vb = 5ml EF 7 #%( - pH 1G %" :4-5
( 0,5) . pKe = 14 :N .  B-|R # ; % 17 4% U  ( . : o2" AB 7D; G (? #$%' %(\ AF ! (2(e% 2:X (? G# : 
SBIRO ABDELKRIM

E-MAIL sbiabdou@yahoo.fr

msn :

sbiabdou@hotmail.fr

Correction
Q:

N47

$

B
`U
(1

0.5

Y2

 

Y1

E = u AB + u R
: #:% EF B
dq
q
i=
u AB =
u R = R.i :
dt
C
du AB
1
E
+
u AB =
:(B) F% 
dt
RC
RC
t
t

du AB
E ( RC )

=
e
u AB (t ) = E 1 e RC 7

dt
RC

du AB
(B)  E
u AB (t ) 
dt

0.5

0.5

0.75

0.25

u AB (V )

[I ][T ] [U ] = [T ]
=
[U ] [I ]

[U ] C = [I ][T ]
R=
[I ]
[U ]

(2

(3

(4
= RC 7

.7( " L 4

(5

(6
(7

)t(ms
(  = 0.001ms : $
_ "2"2  L.
 d47 A"2"2 " nUG 4( . R
B EF#:% u AB = u R + u L :
 : F%

(8
(9
(10

(11
-
-
-

0.5
0.5

d 2 u AB R du AB u AB
+
+
=0
L dt
LC
dt 2

du AB
 ?( BeN  n$ G #:: Y ;g' + F% + ((;
dt
. L 0 s'" R=0"E % 4( R `U ? O "2"2.
 N"#( ?" #:%g' G #D 8!+ #: Y (?  QE 67.4
\#%B 1G : #$% ) g_ #(
1$  |: E ?+ BN " G .

T0 = 2 LC
N 0 = 502.8 Hz \ #: QE 67

1
T0

0.25
0.25
0.25

0.5

= N0

0.5

La

E #  1NF ?+ % ((; |#': 

" )N 0 = f(L ,C
 .8!+
L=232mH LE N 0 =330Hz QE 67.Mi 4

0.25
0.5

F ! E:G

(1( \ ( Q4'% \% q 4%U X " %G f #%7 oUq AG E\$: Y ;g'7E0,75 A4
 E.1 %4W
...............................................................................................................................................................
.........
( f2_#  : YU:# '.
  #NB#[k oU  + #  4# .#
) ;+(  QE oU2 U f#NB . 0,75 a1
" :% );+(  QE oU2 U f#NB . a 2
...............................................................................................................................................................
......
(2( ;!: : #  "?  K 4# ". _( 4_ #.;+

#: :

a1

= 1:R# rad

0,5

...............................................................................................................................................................
......
2 D
L

L/2
a1 =
tg =
: L7(
= #[g  U7" tg =
: Q"U; + eO ?( (
1
L
2 D a1
D
.(#[k oU #NB  # # 4 #  )  4 # A( U+ n7% oU #NB tRe
. a1 QE; ) ( + . a 2 #NB #[k oU QE 4 # #X QE;) ( + %" L1 > L2
...............................................................................................................................................................
........
9
2D 2. 768.10
a1 =
=
2,5 = 192.10 6 m (
1
3
L
20.10
..
...............................................................................................................................................................
........
:7 : E s! F
A
Po 206
82 Pb + Z x

: x%%( ( 1
A=4

210 = 206 + A :7' '  : 7

Z =2

84 = 82 + Z :%+' 
4
. 2 He : 1   4B!  7 4B
210
206
4
84 Po 82 Pb + 2 He : x%%(
----------------------------------------------------------------------------------------------------:'% U7" (2
210
206
4
84 Po 82 Pb + 2 He
: 7
2
2
2
3
E = m.c = [(m( Pb) + m( He) m( Po)].c = [(206,0385 + 4,0039 210,0482)]u c 5,8 10 u c 2
210
84

= 5,8 10 3 1,66 10 27 Kg [3.10 8 m / s ] 8,67 10 13 J

(gB7: ). n LG L(( ; k (? # \ 4%U( ? t \" ln a #[: ;! 2 Y7'7(3
.6,9 ;k\ 7 :X ln a = k .t + 6,9 :   L%(
2

k=
e ln a = e ( 5.10

t +6,9)

(ln a) B (ln a) A
6,9 5,9
=
= 5 10 3 Jours 1
tB t A
(0 200) J

: ag: U% f2 E#6 Y # %D  O"

e a +b = e a e b
a = 992 e

5 .10 3.t

: 
:L7(

ln a = 5.10 3.t + 6,9

a = e ( 5.10

t +6,9 )

a = e 6,9 e 5.10

.t

:
:

a = ao.e.t

= 5.10 3 Jours 1 : $ 4"U Be A( 4"

ln 2

t1 / 2 =

ln 2
: A( m = mo e .t
t1 / 2

ln 2
= s 138 Jours :  7 8g7 #

5.10 Jours 1
--------------------------------------------------------------------N = N O e .t :  t _' 7 4% 7( "   5
mo
NO =
.N A :  mo 1%% 7 E 7
M
m
N=
.N A :  m 1%% 7 E 7 
M
m
m
:%O\"
.N A = o .N A .e .t :YX Be E |%"
M
M
:  #( " 4% 7 %
=

m = mo e
( 140 4

210
84

: 7(  4

ln 2
t
t1 / 2

= 10 g e

ln 2
1
138

9,95 g

Po 8g7 # #$( X 50mg 0,05 g "   (? (? x%%  L

:+ F(
k = H 3O . HO (1-1 (1
..............................................................................................................................................................
............


+

: H 2 O / HO
:G U7" (2-1
H 2 O + H 2 O H 3 O + HO

(l )

(l )

( aq )

][

( aq )

k = k A = ke = 10 14

..............................................................................................................................................................
............
CH 3COOH + H 2 O
CH 3 COO + H 3O +
:1-2 (2
..............................................................................................................................................................
............
. CH 3COOH |'? 1 PH < PK A
pK A = 4,7
pH = 3,2 : 7 (2-2
...............................................................................................................................................................
..............
: 4% G (3-2

CH 3 COOH + H 2 O
CH 3 COO + H 3O +

C1V1
C1V1 x1
(C1 10 PH ).V1

#E"
#E"
#E"

x1

x1

10 PH .V1

10 PH .V1

'
'% 7W
17'

x1 f = 10 pH = 6,3.10 6 mol
...............................................................................................................................................................
..............
4
. #D '% x1 < x1 max : " x1. max = C1 .V1 = 2.10 mol.
: 4-2
...............................................................................................................................................................
..............
x1 f
1 =
= 0,03 = 3% : 5-2
x1 max
...............................................................................................................................................................
..............

.o!)| R ? 1 7 o!)| R ?( 3% K4E x : :6-2

...............................................................................................................................................................
..............
(3
+

NH 3 + H 2 O
NH 4 + HO
(1-3
...............................................................................................................................................................
..............
. NH 3  4? 1: PH > PK A
pK A = 9,2
pH = 10,6 :7:2-3
...............................................................................................................................................................
..............
:3-3
+


NH 3 + H 2 O
NH 4 + HO
#E"
#E"
#E"

C 2V2
C 2V2 x 2
Ke
(C 2 pH ).V2
10

x2
Ke.V2
10 pH
ke.V2
pH
ke
2 = 10
= pH
= 0,04 = 4%
C 2 .V2 10 .C 2
...............................................................................................................................................................
..............
+

CH 3 COOH + NH 3
(4
NH 4 + CH 3 COO
( aq )

x2
Ke.V2
10 pH

'
'% 7W
17'

( aq )

( aq )

( aq )

[CH 3COOH ]i .[NH 4 + ]i

=
[CH 3COO ].[NH 3 ]i

Q r ,i

=0

:1-4

Qr ,i = 0 : . ' E  'E (  )!X  G: \

...............................................................................................................................................................
..............
:2-4
K A1
.(1) # Y'7 E  $ N%: Qr , q = K =
= 3,2.10 4 > Qr ,i
KA2
...............................................................................................................................................................
..............
:3-4
+


NH 4 + CH 3COO
CH 3 COOH + NH 3
0
0
'
2.10 4
10 4
4
4
'% 7W
x3
x3
2.10 x3
10 x3
x

2.10

x3 f

10

x3 f

x3 f
Qr ,q =

x3 f

x3 f

17'

(2.10 4 x3 f )(10 4 x3 f )

= 3,2.10 4

.n #D ( x 10 4 ) 4% + n$ QE? '; +. ?R 1 ! G ( (? Y ;g'

. x3 f = 10 4 mol : Y ;g'
...............................................................................................................................................................
..............

.  ; % 3 = 1 NH 3  ; ' % X x3 f = 10 4 mol = x max :4-4

j7" G% o!)| R G  )! 7" . #4: Y%O \( X  'E (X?  1:
PH = pK A1 = 4,7 o2  'E +
...............................................................................................................................................................
..............
: 4 q' #( 5
. #_ :1-5
...............................................................................................................................................................
..............
:# ; : :2-5
CH 3COOH + HO CH 3COO + H 2 O
...............................................................................................................................................................
:7 `E+% 7 :3-5
C .V
VBE = A A = 10ml

C AV A = C B .V BE
CB
...............................................................................................................................................................
:Y ;g'. 4% $" %\? + :4-5
ni (CH 3COOH ) = C A .V A = 10.10 3.20.10 3 = 2.10 4 mol / l
n( HO ) = C B .V B = 20.10 3.5.10 3 = 10 4 mol / l



CH 3COO + H 2 O
+ HO

CH 3 COOH
2.10 4
2.10 4 x

2.10 4 x

10 4
10 4 x
f

10 4 x f

0
x

'
'% 7W

xf

17'

. HO  ; ' %

ni ( HO ) < ni (CH 3COOH )

x
1

xf

. x max = ni ( HO ) = 10 4 mol :%"

[HO ] [
= [HO ].(V

xf

10 14
10 14
=
= 4,8 = 6,31.10 10 mol / l
+
H 3O
10

pH = 4,8 : ; % 1 7

+ VB ) + x f = 10 4 mol / l : L7(

[HO ] = 10V

xf
+ VB

.  # ; : %" =

:$ eO ?(
xf
x max

10 4
= 4 = 1
10
:%9 E

. $ a'g%" 4 Y 1: Y o2 F 2?  2    W E 2: #+
. : o2" AB 7D; G (? #$%' %(\ AF ! (2(e% 2:X (? G# : 
SBIRO ABDELKRIM

E-MAIL sbiabdou@yahoo.fr
.QE% 

msn :

sbiabdou@hotmail.fr