' -,  ' () (*+,  %  

$

" !     
   2008/2007

 % )13(

8 6 )(  %: 3$) 6(

! C = 1F J,F "$' ?-B; '    > F . E G! 3 C

D! ?-B :
. :;< (= > (; ' ? @"$
K " =( <; : :
L 3O- P' F' FQ' M'. C
3' 3, L 3O- P' F' FQ' M'. C
3' R r 3, ' T' ' M'. R J, $Q6 ) (2) (1) (;F (3  Y,,C ?'%
.:;M

 u c

? ' ;( 
@"$
?' P$ * JCD PW- VK" =

[   *,F! (5

() @"$ M' FQ' ' . 'F' 3,; <  () ' $  : VK; < )( 0,5) t = 0 \-C(
[   *,F! (6
() @"$ M' FQ' ' . 'F' R 3,; < 
 M ^  J*B 6 @ )M VK; < )0,5(

' 8  % " !( :

` )4(
; ` 3 c ! = 8 '% eC   C ' , d ' `
D ?$C aCD = 768nm 3,? <;
aCD ,( a1 ?' D=2,5m ) ' aCD Q Q gO! .a 1>a2 f a2 aCD PW-) D >>a2 D>>a1 f ?$C >. 1M

.i ` PCD OC (
M,
 B,! '* hM-, P ( ,75
.iC P$ h) 
P$B? )()(C$B ( ' ( \  
\  '? ? 0,75

(1

L = 20mm 38D = 8 FM Q B aCD  B) a1 V;< K iC k,-! a2  V;< K iC P%! (2
.2 M>  J*

. *F eD > D ( 0,5

. ( 1 :m +,! ?'  > D L  a1 *F  YT * ,D (
1
. a1 
< o,,(
1
( .3) :D FQp; B!6 : % )( f " 8

. ZA Ba !  *  3,, ?D  , B D FQ 137
55 Cs  %! 
. ( 0,5) Z A ?F '? P <
 -' G,, K  F' :,( 1
. m0 = 1mg 3,C, 137
55 Cs  % '? D aCD t = 0 \-C D ) ,! (2
. ( 0,75) t = 0 \-C D F  )( D N O :(
(1) . t1 / 2 = 30ans

Cs  %C @W
 D
CD t = 3ans \-C D F VK3 a (D FQp B( ` <

. ( 0,75) . =* F '? ! 20 O O 3) G,, (,' %(` 

:(;F!
137
23

27
N A = 6,02.10  ) D 1an = 365 jours m( 55 Cs ) = 136,90707u  % !  C, 1u = 1,66.10 Kg
137
55

(7) 
 $ 8 '

SBIRO Abdelkrim Lyce Agricole Oulad-Taima rgion dAgadir Maroc

mail: sbiabdou@yahoo.fr
MSN-MESSAGERsbiabdou@hotmail.fr

C`  p T D

 3$: % )( 6 8

.@"$
 [ : '  \ aCD P
,B  3!6 @"$
 [ RC --------1 P$B( 1
0,25 2
. 'F' 3,' M'  "' LC - ----2 P$B
0,25 2 . "'  = )( 3$ K K ! T \ 
.
t  u : \ 
'F' R 3,' M' )( K K ^
RLC --------3 P$B
0,25 2
. = 1ms : aCD PW-!. ! *' - 3,
< ?'% , " %
, .@"$
 [ : u 1 P$B( )( 2
. TO = 3ms aCD PW-!. ! *' - J,
< TO t  %
, .  "'  = )( 3$ K K ! T u
. T TO = 3ms aCD PW-!. ! *' - J,
< T J*B %
, . RLC )( K K  ^
u

0,25
0,25
0,25

R=

TO
(3.10 3 ) 2
=
0,23H
4 2 .C 4. 2 .10 6

10 3
= 10 3 = 1K
6
10

L=

0,5

(3

TO = 2 L.C : t
(4

3P$B

2P$B

1 P$B

uC + u( L,r ) = 0

uC + u L = 0

uC + u R = 0

0,75

0,75
0,75

L.C

d 2uc
du
+ r.C c + u C = 0
2
dt
dt

d 2uc
1
+
uC = 0
2
L.C
dt

m = 0

0,5

R.C

du c
+ uC = 0
dt

P$B
:,(

,< D (
C8 ,  F
(

.FQ C d Y
"@ ; < $
! )( %t
 = 3$(; < 5
1
1
2
e = C.u c = .10 6.5 2 = 1,25.10 5 J : t = o \-C)(
2
2
(6

= 0 3 :( 6  J*B ^ M
; <
1
1
1
1
2
0 = C.u c = .10 6.5 2 = 12,5.10 6 J
2
2
2
2
.' M
 ` +,! ` F
 < d P$Q aCD < ; VK M)
= 5,26.10 6 J : J'

3 = C.u c 2 = .10 6.(3,8) 2 = 7,22.10 6 J

0,5


` : % " !( )( 8

0,75 gM* aCD PW-) + g
` () O B, iC V ,` F 6 OC (
M,
 B,! '* hM-,  ((1
.1 ,M>   )( B

........................................................................................................................................................................
. -  u : a
 \ VK(
.* % 
FM* D $
C YT iC
<; C
. 0,75 a1  V;< K iC h) )(  P$B
. a 2  V;< K iC h)) (  P$B :( ,
.....................................................................................................................................................................
4

. . : (( 2

rad  3 =

: * F
a1
.....................................................................................................................................................................
2 D
L

L/2
a1 =
: J'
tg =
= YW %C * tg =
: h  P$B( '? ^
1
L
2 D a1
D
.(YT iC
<; C * % 
FM* D
C ) FM* D g' $D : , iC <; k!
. a1 h) ) (  P$B . a 2  <; YT iC h)  FM*C D *6 h)) ( 
P$B ( , L1 > L2
.......................................................................................................................................................................
2D 2. 768.10 9
a1 =
=
2,5 = 192.10 6 m ..(
1
3
L
20.10
.......................................................................................................................................................................
   -,: % )( f " 8

0,5

N = NO

20 N O
20
80
NO =
N O : M*,
  D $
 CT6 '?  20 o o G,, ' D
100
100
100
: ,< F 3;F t \-C D M*,
  D

N = N O e t

0,8NO = NOe.t

:(C
x*W ^6 VK3)

0,8 = e.t
ln 0,8 = ln e .t
=

ln 2
t1 / 2

: g'

:?); aCD  *, R C  P^!

ln 0,8 = t

: t \-C t,! J'

ln 0,8 =

ln 2
t
t1 / 2

(ln 0,8) t1 / 2
ln 2
(ln 0,8) 30
t=
= 9,66ans = 9ans ..240 j...2h...42mn...12 s
0,75
ln 2
------------------------------------------------------------------------------------------------------------------------------:
 $ 8 '
:D < y
 D , !M
  -,
: 
g' i ! "
 y
 PD   F'(-1.1
t=

HCOO + H 3O +

HCOOH + H 2 O

0,25

( aq )

( aq )

(l )

( aq )

(2-1

[HCOO ][. H O ] = [H O ]
=

kA

+ 2

:O
- , > :u -C'

[HCOOH ]

[HCOOH ]

n( H 3 O + ) H 3 O +
( 1) =
=
=
:
x max
C A .V A
CA
xf
C A = [HCOOH ] +
VA
xf

C A = [HCOOH ] + H 3 O +

xmax = C A .V A : -
 PD ,
 i ! "
 y
 (
3-1

[HCOOH ] =

C AV A x f
VA
xf

:( ,

VA

= CA

= H 3O +

[H O ]
=
[HCOOH] + [H O ]

xf
VA

:  3` ?'

:  ^3` ?'

:aCD PW-! (1) () y F,

KA
[H 3O + ] :() ^6< F VK M' e 8 +

:
aCD
PW-!
K A + H 3O +
[HCOOH ]
KA
=
:z) [H 3O + ] = 10 pH :

PH
K A + 10

1,8.10 4
=
= 0,125 = 12,5%
:D h*;
0,75
1,8.10 4 + 10 2,9
.
:  (-4-1
+
pH
2 , 9
xf
H O
10
10
10 pH
CA =
=
= 10 2 mol / l

=
= 3
=
0,5

x max
CA
CA
0,125

: F
 PD (1-2 (2

. (C PD 
HCOOH + HO
HCOO + H 2 O
0,25

( aq )

( aq )

( aq )

(l )

.
. pH E 7,8 : VBE = 10ml : m) $,; M! (,>( 2-2
0,25
.
c V
10.10 2
. M  +, h) ' 
c A = B BE =
= 10 2 mol / l (3-2
0,25
VA
10

: PD , M ( `3

 F

HCOOH + HO
HCOO + H 2 O
M,
 -

C AV A
C AV A x f

C B .V ' B
C B .V ' B x f

xf
6

0
)

0
xf

=*
= 3!.

. V ' B = 5cm 3 :  ,

M aCD PW-! PH = 3,7 :'* ! *
: , ;< P
F,!
HCOO
: ,< F J;F eCt pH  CF!
pH = pK A + log
[HCOOH ]
:z) pH = pK A = 3,7

C AV A x f = x f

[HCOOH ] = [HCOO ]

: M, '? ^ `

C A .V A 10 2 mol / 10.10 3
=
= 5.10 5 mol
2
2
ke
10 14
HO =
=
= 5.10 11 mol / l :
C (! 6 +< D  '? ^
+
3, 7
H 3O
10
C B .V ' B x f
C .V ' 5.10 5

M, '? ^ `
5.10 11 = B B
HO =
VA + V 'B
VA + V 'B

xf =

0,75

a6  '? ` F' (

] [

V A .5.10 11 + 5.10 5 10.10 3.5.10 11 + 5.10 5

=
= 5.10 3 = 5ml
V ' B +- 3) 3+

11
2
11
C B 5.10
10 5.10

V 'B =

CH 3OCH 3 CH 4 + CH 2 O
(g)

(g)

a
a-x

0
x

:= 
$ -
: (T  +(1
 F


(g)

0
x

M,
0
x

 -
=*
-,

0,25

n g = n1 + n 2 + n3 = (a x) + x + x = a + x

:
! p )( C$ Y(
 ' 2

P = PO = 32,9 KPa = 32900 Pa : Y eY8

t = 0 \-C( )( 1-3
0,5
P
a
= O
Po .V = a.R.T t = 0 \- ()
V R.T
x
a
x
:t J' Pt = PO + .RT : Pt = RT + RT Pt .V = (a + x).R.T t \- ()
V
V
V
x Pt PO
=
V
R.T
0,25

.
D aCD Q *' > 3 ( P' D -  ` PD ,  aCD eYO  > P` >* `  '? :+ ( 2 3
.PD ,
.
x Pt PO Pt 32,9.10 3
=
=
= 1,55.10 4 Pt 5,1
(3-3
V
R.T
8,31 777
Pt = 46,1KPa = 46100 Pa
 t = 25mn :\-C D +'? ^
0,75
x
= 1,55.10 4.(46,1.10 3 ) 5,1 2.mol / m 3 = 2.10 3 mol / : C V *,! :+
V
[CH 4 ] = [CH 2 O] = x = 2.10 3 mol /
V
7

[CH 3OCH 3 ] = a x =
V

a x PO
x
=
= (5,1 2) = 3,1mol / m 3 = 3,1.10 3 mol /
V V RT V

Pa / mn ( 454,5 J 1 .mol ( RT ) 1 ( 1,55.10 4 a J*,!

Pa mol N .m 2 .mol
=
= mol / m 3 .mn : ( D (  ,
J .mn
N .m..mn
............................................................................................................................................................................
x
x max
Pt max = PO + max .R.T : eYOC * ?$ x =
: h)  PD ,@ W! ?'( 2-4
0,75
V
2
P + Pt max 32,9 + 61,7
x
P' = O
=
= 47,3KPa
y F, P ' = PO + max RT t ' = t1 / 2 \-C D
2
2
2V
t1 / 2 = 30 min :aCD PW-! ! *'
( Pa / mn).( J 1 .mol ) =

. 2008/3/27 *( " !     

  +, -,' K%+!
16/20: @  Q K
C, 3CD PW ;M! aCD
15.75/20:FC %%D :K
C, JC >
.  =F iK g<
 R P`*( '? +, -,' g8" ' F* K', K 6!` '?
F k
SBIRO ABDELKRIM E-MAIL sbiabdou@yahoo.fr msn : sbiabdou@hotmail.fr