:

( - (

------------------------------------------------------------------------------------------------------:
!" # $ ( (' -
!

'+!

23
23
23

c1 .V
c1 .V x
c1 .V x

: 65 )'
!
:<=>?' +!

x max = C1 .V
xf

[H O ].V = [H O ] = 10
+

xf

xf

xf

!)
/ 45 )

!:

(-1-3

93 23
C1 .V x max = 0

x f = n( H 3O + ) = H 3 O + .V
pH

)
/'0

:#/ 45 ' +!

3, 01

10
= 0,0977 = 9,77 10 2 : #/ 45 ' +! 0:@
2
x max
C1 .V
C1
10
10
.#" 2 A !) < 1
-------------------------------------------------------------------------------------------------------
C 6 H 7 O6 H 3 O +
Qr =
:
! G (-
[C 6 H 8O6 ]
xf

H 3 O + = C 6 H 7 O6 =
= 10 pH
V
c .V x f
xf
[C 6 H 8 O6 ] = 1
= c1
= c1 10 pH
V
V

+
pH 2
3, 01 2
C H O H 3O
(10 )
(10
)
Qr = 6 7 6
=
= 2
= 1,058 10 4 1,06 10 4
pH
3, 01
[C 6 H 8O6 ]
c1 10
10 10

] [

][

][

. K = Qr ,q = 1,06 10 4 :
! H4 @2+ ! J
------------------------------------------------------------------------------------------------------------
(- (
C 6 H 8 O6 + HO C 6 H 7 O6 + H 2 O
( aq )

( aq )

( aq )

(l )

------------------------------------------------------------------------------------------------------------
C A .V A = C B .VBE
: K3 ! > L LG M (-
C B .V BE 1,5 10 2 9,5
=
= 1,425 10 2 mol / L
VA
10
------------------------------------------------------------------------------------------------------------:2+ #3 P

( -
3
n = c A .V = 14,25 10 mol / L 0,2 L = 2,85 10 3 mol
:2+ #3 P

"!
3
<" )! R 2> #5 C 500 M ! 3 :! m = M .n = 176 g / mol 2,85 10 mol 0,5 g = 500mg
.

M 500mg
------------------------------------------------------------------------------------------------------------
(- (
C 6 H 8 O6 + C 6 H 5 COO C 6 H 7 O6 + C 6 H 5 COOH
CA =

( aq )

( aq )

( aq )

( aq )
pkA1

K
K A (C 6 H 8 O6 / C 6 H 7 O6 )
10
= A1 = pkA2 = 10 pkA2 pkA1 = 10 4, 2 4,04 1,41

K A (C 6 H 5 COOH / C 6 H 5 COO ) K A 2 10
------------------------------------------------------------------------------------------------------------(-
Qr =

#3 #43. Qr K : S! ?

-------------------------------------------------------------------------------------------------------------

RC

uc + u R = U
du
u R = R.c c
dt
du c
u c + R.c
=U
dt

TS+ #/ 5U

2 MR2 !

(
> @ V 0S! (-

: 5R' M)X #3 2 ! 3
du
dq d (c.u c )
i=
=
= c. c :
dt
dt
dt
: #"R > < L Y0=

u R = R.i :
u R = R.c

duc
:
dt

du c
= U : " ! )= "< 53 = R.c : Z@
dt
------------------------------------------------------------------------------------------------------------uc +

u c ( t ) = U (1 e

uc +

= R.C

"

"

du c
=U : "
dt

u c ( t ) = U (1 e

) :

(-

)
t

!
U

#3
t

du c U
= e :
dt

R !

+ U (1 e ) = Ue

+ U Ue

=U

------------------------------------------------------------------------------------------------------------u c = U = 300V : [/\ '5 #3 (-

-----------------------------------------------------------------------------------------------------------1
1
E c = cU 2 = 120 10 6 (300) 2 = 5,4 J (-
2
2
-----------------------------------------------------------------------------------------------------------@ `_/ 24 > S
Eo = 1,5V : 2) 24 6 >
S 2^ 0 ' M)^ '5 (-
1
1
2
E c = cE O = 120 10 6 (1,5) 2 = 0,135. 10 3 J < 5 J : aJ #3
2
2
. aJ M)X H ! M R ? # !
-----------------------------------------------------------------------------------------------------------(
(-

-----------------------------------------------------------------------------------------------------------. = 1,2ms <" =)@ @ (-

-----------------------------------------------------------------------------------------------------------
1,2 10 3 s
r= =
= 10

rc = (-
c 120 10 6 F
-----------------------------------------------------------------------------------------------------------:c J MR2 !
(
(-

r Vox = Vo. cos

VO
Voy = Vo. sin

v x 4++) #! "

: /'0 2X LG M
( t = o \)" ' 5 ) M !02 4

r
.f+3 P 4@ 2 Z` 4!2 LG
r
r
P = m.aG :#"R T! M 5 #@ J @ + M 20 > L

dv x
=0
dt

dv y

= g aY = g
dt
C ' = Vo. sin v y = Vo. sin : t = 0 \)" ' 5 5R'
v y :"

V y = g .t + Vo. sin

2: 4(!

0 = m.a x : <"

=)@ ox "< ) + g

Vx = Vo. cos : 93 65 v x = C te
P = m.a x : <"

=)@ oy "< ) + g

/'0 2X LG M

V y = g .t + C ' : 93 65

# !

-----------------------------------------------------------------------------------------------------------: <" =)@ /'0 2X 0!

(-
x = Vo.(cos ).t
1
x2

+ x.tg : :
y = g. 2

1 2
2
2 Vo . cos
y = 2 g .t + Vo.(sin ).t
-----------------------------------------------------------------------------------------------------------: y B <" =)@ : #3
R ! x B = 15m 5R' (-
2

x
1
(15) 2
y B = g . 2 B 2 + x B .tg = 0,5 10 2
+ 15.tg 20 = 0,796 + 5,459 = 4,66m < 5m
2 Vo . cos
40 . cos 2 20
.2(X 'S=! 2
-----------------------------------------------------------------------------------------------------------y = y Q = 0 x = OQ = 120m Q 2 ) #3 2 2 f+: '5 = 24 R "_0:5 (-

: :

86272.5
VO

= 53,43

#3

[U

1
120
0 = 10. 2
+ 120.tg 24
2 Vo . cos 2 24

VO = 40,2m / s
-----------------------------------------------------------------------------------------------------------(
:#+3 ! : 3 2 2
( -
r
r
. P 4@ R ! : 2 Uj! 2 Z`
r r
r
P + R = m.aG : #"R T! M 5 #@ J @ + M 20 > L

2)

"

d 2x
# m 2 + f = 0 : 0 f = ma x : <"
dt

=)@ ox "< ) + g
.2 _ >= 2

+!: 2 2 a x =

f
m

2,25 10 2
45 10

= 0,5m / s 2 : 5R' + : > L LG M (-

. kl 0! @!\ 2 m!
--------------------------------------------------------------------------------------------------v = at + v1 : 2: LG M (-
0 = 0,5.(4) + V1
4 s : R : 5 ' LG 2 ) ' < 5
2: 2 =
. V1 = 2m / s
--------------------------------------------------------------------------------------------------: # ^g X5 nRj! : MR2 !
:o! ! ( -
14
0
A
Z = 7 A = 14
6 C 1 e + Z X
C 10 e+ 147N
--------------------------------------------------------------------------------------------------: 5 !) H > l(-
2
2
E = m.c = [m( N ) + m(e) m(C )].c = [14,0076 + 0,00055 14,0111].c 2 = 0,00295u.c 2
14
6

= 0,00295 931,5( MeV / c 2 ) c 2 = 2,7479 MeV 2,75MeV

ln 2
ln 2
=
= 3,39 10 7 Jours 1
(- (
t1 / 2 5600 365 Jours
--------------------------------------------------------------------------------------------------a
a
ln
= .t

= e .t

a = a o .e .t : 5R' (-
ao
ao
a
28,7
a
ln
ln
ln o
ao
21,8
a =
t=
=
= 811171,5427 Jours 2222ans + 141,5 jours

3,39 10 6
--------------------------------------------------------------------------------------------------. L 0> 5 #
5 : o>2A(-
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