LP BI DNG KIN THC 10, 11, 12 v N THI I HC mn HA HC Thy L Phm Thnh

LTH 15. DN XUT HALOGEN ANCOL PHENOL (P.01)

Dng 1. Vit CTPT, xc nh CTCT, c tn
15.1. Mt ancol no Y c cng thc n gin nht l (C2H5O)n. Y c CTPT l
A. C6H15O3.
B. C2H6O.
C. C4H10O.
D. C4H10O2.
15.2. S ng phn c phn ng vi Na ca C4H10O l
A. 2.
B. 4.
C. 6.
D. 7.
15.3. Cng thc no di y khng phi ca ancol C4H7OH ?
A. CH2=CH-CH2-CH2OH.
B. CH3-CH=CH-CH2OH.
C. (CH3)2C=CH-OH.
D. CH2=CH-CH(OH)-CH3.
15.4. (C 2007) C bao nhiu ancol bc II, no, n chc, mch h l ng phn cu to ca
nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18% ?
A. 2.
B. 3.
C. 4.
D. 5.
15.5. (H khi A 2008) Khi phn tch thnh phn mt ancol n chc X th thu c
kt qu : tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn
ancol ng vi cng thc phn t ca X l
A. 2.
B. 4.
C. 1.
D. 3.
Dng 2. Ancol tc dng vi kim loi kim
15.6. Cho Na tc dng hon ton vi 18,8 gam hn hp hai ancol no, n chc k tip nhau
trong dy ng ng sinh ra 5,6 lt kh H2 (ktc). CTPT ca hai ancol l
B. CH3OH v C2H5OH.
A. C3H7OH v C4H9OH.
C. C2H5OH v C3H7OH.
D. C4H9OH v C5H11OH.
15.7. Cho 1,24 gam hn hp hai ancol n chc tc dng va vi Na thy thot ra 336 ml
kh H2 (ktc). Hn hp cc cht rn cha Na c to ra c khi lng bao nhiu ?
A. 1,90 gam.
B. 1,585 gam.
C. 1,93 gam.
D. 1,57 gam.
15.8. Cho 7,5 gam ancol n chc, no, mch h tc dng va vi Na thu c 10,25 gam
mui khan. CTPT ca ancol l
A. CH3OH.
B. C2H5OH.
C. C3H7OH.
D. C4H9OH.
15.9. (H Khi A 2007) Cho 15,6 gam hn hp hai ancol n chc, k tip nhau trong dy
ng ng tc dng ht vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l
A. C3H5OH v C4H7OH.
B. C2H5OH v C3H7OH.
C. C3H7OH v C4H9OH.
D. CH3OH v C2H5OH.
Lin h : Thy L Phm Thnh (E-mail : thanh.lepham@gmail.com Phone : 0976.053.496)

LP BI DNG KIN THC 10, 11, 12 v N THI I HC mn HA HC Thy L Phm Thnh

Dng 3. Phn ng tch nc t ancol

15.10. (H khi A 2008) Khi thc hin phn ng tch nc t ancol 3-metylbutan-2-ol iu
kin 170oC thu c sn phm chnh l
A. 2-metylbut-1-en.
B. 3-metylbut-1-en.
C. 2-metylbut-2-en.
D. 3-metylbut-2-en.
15.11. (H Khi A 2007) Khi tch nc t mt cht X c cng thc phn t C4H10O to
thnh ba anken l ng phn ca nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn
ca X l
A. (CH3)3COH.
B. CH3OCH2CH2CH3.
C. CH3CH(OH)CH2CH3.
D. CH3CH(CH3)CH2OH.
15.12. un 132,8 gam hn hp 3 ancol no, n chc vi H2SO4 c 140oC thu c hn hp
cc ete c s mol bng nhau v c khi lng l 111,2 gam. S mol mi ete c gi tr no sau
y ?
A. 0,1 mol.
B. 0,2 mol.
C. 0,4 mol.
D. 1,2 mol.
15.13. un nng mt hn hp gm 2 ancol no, n chc, mch h vi H2SO4 c 140oC thu
c 21,6 gam H2O v 72 gam hn hp 3 ete. Bit 3 ete thu c c s mol bng nhau v phn
ng xy ra hon ton. CTCT ca 2 ancol l
A. CH3OH v C2H5OH.
B. CH3OH v C3H7OH.
C. CH3OH v C4H9OH.
D. C 3 p n trn u c th ng.
15.14. un hn hp X gm 2 ancol R, R l ng ng k tip nhau vi H2SO4 c nhit
thch hp thu c hn hp cc cht hu c Y (ch cha ete hoc anken) c t khi so vi X
bng 7/11. X l hn hp 2 ancol no di y ?
A. C3H7OH v C4H9OH.
B. C2H5OH v C3H5OH.
C. C3H5OH v C4H7OH.
D. C2H5OH v C3H7OH.
15.15. (H khi A 2008) un nng hn hp gm hai ancol n chc, mch h, k tip nhau
trong dy ng ng vi H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu c 6 gam
hn hp gm ba ete v 1,8 gam nc. Cng thc phn t ca hai ancol trn l
A. CH3OH v C2H5OH.
B. C2H5OH v C3H7OH.
C. C3H5OH v C4H7OH.
D. C3H7OH v C4H9OH.
15.16. (H khi B 2008) un nng mt ancol n chc X vi dung dch H2SO4 c trong
iu kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng
thc phn t ca X l
A. C3H8O.
B. C2H6O.
C. CH4O.
D. C4H8O.
Dng 4. Phn ng oxi ha khng hon ton
15.17. Cho m gam ru no, n chc X tc dng vi Na d thu c 3,36 lt H2. Oxi ha m
gam ru ny mt thi gian, sn phm thu c (gm anehit, axit, ru d v H2O) li cho tc
dng vi Na d thy thot ra 4,48 lt H2. Cc th tch kh u o ktc. Hiu sut chuyn ha
ru thnh axit l
A. 25,00%.
B. 33,33%.
C. 66,67%.
D. 75,00%.
Lin h : Thy L Phm Thnh (E-mail : thanh.lepham@gmail.com Phone : 0976.053.496)

LP BI DNG KIN THC 10, 11, 12 v N THI I HC mn HA HC Thy L Phm Thnh

15.18. Oxi ha 12,0 gam ru n chc X trong iu kin thch hp thu c 11,6 gam anehit
Y. X l
A. propan-1-ol.
B. propan-2-ol.
C. butan-1-ol.
D. butan-2-ol.
15.19. (H Khi B 2007) Cho m gam mt ancol (ru) no, n chc X qua bnh ng CuO
(d), nung nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim 0,32 gam.
Hn hp hi thu c c t khi i vi hiro l 15,5. Gi tr ca m l
A. 0,92.
B. 0,32.
C. 0,64.
D. 0,46.
Dng 5. Phn ng t chy
15.20. (TNTHPT ln 1 2007) t chy hon ton m gam ru no n chc mch h, sau
phn ng thu c 13,2 gam CO2 v 8,1 gam nc. Cng thc ca ru no n chc l
A. CH3OH.
B. C4H9OH.
C. C2H5OH.
D. C3H7OH.
15.21. t chy hon ton m gam hai ru n chc, mch h lin tip trong cng dy ng
ng thu c 15,84 gam CO2 v 9,18 gam H2O. Cng thc phn t ca 2 ru ln lt l
A. CH3OH v C2H5OH.
B. C3H7OH v C4H9OH.
D. C4H9OH v C5H11OH.
C. C2H5OH v C3H7OH.
15.22. t chy hon ton m gam hn hp hai ru n chc cng dy ng ng cn dng
va V lt kh O2 (ktc), thu c 10,08 lt CO2 (ktc) v 12,6 gam H2O. Gi tr ca V l
A. 17,92 lt.
B. 4,48 lt.
C. 25,76 lt.
D. 15,12 lt.
15.23. (C 2007) t chy hon ton mt ru (ancol) X thu c CO2 v H2O c t l s
mol tng ng l 3 : 4. Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO2
thu c ( cng iu kin). Cng thc phn t ca X l
A. C3H8O3.
B. C3H4O.
C. C3H8O2
D. C3H8O.
15.24. (C 2007) Khi thc hin phn ng tch nc i vi ru (ancol) X, ch thu c mt
anken duy nht. Oxi ho hon ton mt lng cht X thu c 5,6 lt CO2 ( ktc) v 5,4 gam
nc. C bao nhiu CTCT ph hp vi X ?
A. 5.
B. 4.
C. 3.
D. 2.
Dng 6. ru
15.25. Pha a gam ru etylic nguyn cht (D = 0,8 g/ml) vo nc c 80 ml ru 25o. Gi tr
ca a l
A. 16 gam.
B. 20 gam.
C. 32 gam.
D. 40 gam.
15.26. Ha tan 92 gam C2H5OH vo nc thu c 250 ml dung dch A. Bit khi lng ring
ca ru nguyn cht l D = 0,8 g/ml. ru ca dung dch A l
A. 29,44o.
B. 36,8o.
C. 46o.
D. 50o.
Lin h : Thy L Phm Thnh (E-mail : thanh.lepham@gmail.com Phone : 0976.053.496)

LP BI DNG KIN THC 10, 11, 12 v N THI I HC mn HA HC Thy L Phm Thnh

Dng 7. Ancol a chc

15.27. (C 2007) Cho cc cht c cng thc cu to nh sau: HOCH2-CH2OH (X); HOCH2CH2-CH2OH (Y); HOCH2-CHOH-CH2OH (Z); CH3-CH2-O-CH2-CH3 (R);
CH3-CHOHCH2OH (T). Nhng cht tc dng c vi Cu(OH)2 to thnh dung dch mu xanh lam l
A. X, Y, R, T.
B. X, Z, T.
C. Z, R, T.
D. X, Y, Z, T.
15.28. Ru no X c phn t khi l 62 vC. Khi cho 15,5 gam X tc dng vi lng Na d
thu c 5,6 lt H2 (ktc). S nhm OH trong phn t X l
A. 1.
B. 3.
C. 2.
D. 4.
15.29. Ancol X mch h c s nguyn t cacbon bng s nhm chc. Cho 9,2 gam ancol X tc
dng vi Na d, thu c 3,36 lt kh (ktc). Cng thc cu to ca X l
A. CH3OH.
B. CH3CH2OH.
C. HOCH2CH2OH.
D. HOCH2CH(OH)CH2OH.
15.30. Hn hp X gm 2 ru, c t khi hi so vi He l 17,25. Cho 24,15 gam X tc dng vi
Na d thu c 7,84 lt H2 (ktc). Hai ru trong X ln lt l
B. C2H5OH v C3H5(OH)3.
A. C2H4(OH)2 v C3H5(OH)3.
C. C2H5OH v C2H4(OH)2.
D. C3H7OH v C4H9OH.
15.31. (H Khi B 2007) X l mt ancol (ru) no, mch h. t chy hon ton 0,05 mol X
cn 5,6 gam oxi, thu c hi nc v 6,6 gam CO2. Cng thc ca X l
A. C2H4(OH)2.
B. C3H7OH.
C. C3H5(OH)3.
D. C3H6(OH)2.
Dng 8. Phenol v ancol thm
15.32. (H Khi B 2007) S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen)
u tc dng c vi dung dch NaOH l
A. 2.
B. 4.
C. 3.
D. 1.
15.33. t chy hon ton mt phenol Y cn dng va 7,84 lt O2, thu c 6,72 lt CO2 v
2,7 gam nc. Y l cht no di y (cc th tch kh o ktc) ?
A.

B.

C.

D.

15.34. (C 2007) Hp cht hu c X (phn t c vng benzen) c cng thc phn t l

C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol
H2 thu c bng s mol X tham gia phn ng v X ch tc dng c vi NaOH theo t l s
mol 1:1. Cng thc cu to thu gn ca X l
A. C6H5CH(OH)2.
B. HOC6H4CH2OH.
C. CH3C6H3(OH)2.
D. CH3OC6H4OH.
15.35. Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c tnh
cht: tch nc thu c sn phm c th trng hp to polime, khng tc dng c vi
NaOH. S lng ng phn ng vi cng thc phn t C8H10O, tho mn tnh cht trn l
A. 1.
B. 4.
C. 3.
D. 2.
15.36. Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO2 thu c nh hn
35,2 gam. Bit rng, 1 mol X ch tc dng c vi 1 mol NaOH. CTCT thu gn ca X l
A. CH3CH2C6H4OH.
B. HOCH2C6H4COOH.
C. HOC6H4CH2OH.
D. C6H4(OH)2.
Lin h : Thy L Phm Thnh (E-mail : thanh.lepham@gmail.com Phone : 0976.053.496)