S GD&T BC NINH TRNG THPT CHUYN BN TTH LN I

THI TH I HC MN: HA HC, KHI A, B

( thi c 4 trang)

Thi gian lm bi: 90 pht; (60 cu trc nghim)

M 148

H, tn th sinh:............................................................................. SBD: ............................. Cho bit nguyn t khi ca cc nguyn t: H = 1; He = 4; Li = 7; Be = 9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5;K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Rb = 85; Sr = 88; Ag = 108; Sn = 119; Cs = 133; Ba = 137; Pb = 207. (Th sinh khng c s dng bng h thng tun hon) I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Ho tan hon ton a gam Al 2O3 trong 400 ml dung dch HNO3 2M thu c dung dch X. Thm 600 ml dung dch NaOH 1M vo dung dch X th thu c 7,8 gam kt ta . Vy gi tr ca a tng ng l A. 8,5 gam B. 10,2 gam C. 5,1 gam D. 15,3 gam Cu 2: Hn hp X gm axit fomic, axit acrylic, axit oxalic v axit axetic . Cho m gam X phn ng ht vi dung dch NaHCO3 thu c 0,672 lt CO2 (ktc). t chy hon ton m gam X cn 1,008 lt O2 (ktc), thu c 2,42 gam CO2 v a gam H2O. Gi tr ca a l A. 1,80. B. 0,72 C. 1,44. D. 1,62. Cu 3: Cho hn hp X gm KMnO4 va MnO2 vo dung dich HCl c, d un nng (phn ng hon ton), thy thot ra kh Cl2. Xc nh % khi lng ca MnO2 trong hn hp X, bit rng HCl b kh chim 60% lng HCl phn ng. A. 26,9% B. 35,5% C. 52,4% D. 45,2% Cu 4: Cho m gam bt st vo 200 ml dung dch HNO3 4M, un nng, sau phn ng hon ton thy thot ra kh NO (sn phm kh duy nht ca HNO3) v dung dch ch cha 52,6 gam mui. Vy gi tr ca m tng ng l A. 11,20 gam B. 12,17 gam C. 15,40 gam D. 16,80 gam Cu 5: Cho m gam dung dch H2SO4 nng C% tc dng ht vi mt lng hn hp hai kim loi Kali v Magie (dng d), thy khi lng kh hiro bay ra l 0,05m gam. Gi tr ca C l: A. 19,73%. B. 15,80%. C. 17,93%. D. 18,25%. Cu 6: Tnh th tch dung dch NaOH 1M ln nht cn cho vo dung dch cha 0,1 mol H 2SO4 v 0,2 mol ZnSO4 sau phn ng hon ton thu c 9,9 gam kt ta? A. 0,6 lt B. 0,8 lt C. 0,4 lt D. 1,0 lt Cu 7: Dung dch X gm cc cht tan: AgNO 3, Al(NO3)3, Cu(NO3)2, Zn(NO3)2. Chia dung dch X lm hai phn ri thc hin hai th nghim sau: - Cho dung dch NaOH d vo phn 1. - Cho dung dch NH3 d vo phn 2. Tng s cht kt ta thu c c hai th nghim l: A. 2. B. 3. C. 4. D. 5. Cu 8: Cho cc nguyn t sau : X(Z = 8), Y(Z = 13), M (Z = 15) v T (Z = 19). S sp xp no ng vi chiu tng dn m in ca cc nguyn t ? A. T, M, Y, X B. X, Y, M, T C. T, Y, M, X D. Y, T, X, M Cu 9: t chy hon ton 20 ml hi hp cht hu c X (ch gm C, H, O) cn va 110 ml kh O 2, thu c 160 ml hn hp Y gm kh v hi. Dn Y qua dung dch H2SO4 c (d), cn li 80 ml kh Z. Bit cc th tch kh v hi o cng iu kin. S ng phn X tc dng c Na gii phng kh l A. 3 B. 5 C. 4 D. 6 Cu 10: Cho cc cht sau: FeS, Fe3O4, NaCl, NaI, Na2CO3 v Cu2O tc dng vi dung dch H2SO4 c . S phn ng m trong , H2SO4 ng vai tr cht oxi ha? A. 6 B. 4 C. 3 D. 5 Cu 11: Cho phng trnh ha hc: Fe3O4 + HNO3 Fe(NO3)3 + NaOb + H2O. Sau khi cn bng phng trnh ha hc trn vi h s ca cc cht l nhng s nguyn, ti gin th h s ca H2O l A. 45a 18b. B. 13a 9b. C. 46a 18b. D. 23a 9b. Cu 12: X phng ha hon ton 13,2 gam hn hp hai este HCOOC3H7 v CH3COOC2H5 bng dung dch NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H2SO4 c 140 oC, sau khi phn ng xy ra hon ton thu c m gam nc . Gi tr ca m l A. 1,35 B. 2,7 C. 5,4 D. 4,05. Cu 13: un nng hn hp hai ancol n chc, mch h vi H 2SO4 c, thu c hn hp gm cc ete . Ly 3,6 gam mt trong cc ete em t chy hon ton, thu c 4,48 lt kh CO2 ( ktc) v 3,6 gam H2O. Hai ancol l A. CH3OH v C3H7OH. B. C2H5OH v CH2=CH-CH2-OH. C. CH3OH v CH2=CH-CH2-OH. D. C2H5OH v CH3OH.

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Cu 14: Ho tan hon ton 12,42 gam Al bng dung dch HNO3 long (d), thu c dung dch X v 1,344 lt ( ktc) hn hp kh Y gm hai kh l N2O v N2. T khi ca hn hp kh Y so vi kh H2 l 18. C cn dung dch X, thu c m gam cht rn khan. Gi tr ca m l A. 97,98. B. 106,38. C. 38,34. D. 34,08. Cu 15: Gi s trong bnh kn, ti 800C tn ti cn bng sau: 2NO + O2 2NO2 (1) Hp = ? Khi h nhit bnh xung 400C, thy mu ca hn hp m hn. Vy kt lun no sau y ng? A. Hp < 0, phn ng to nhit. B. Hp > 0, phn ng to nhit. C. Hp < 0, phn ng thu nhit. D. Hp > 0, phn ng thu nhit. Cu 16: m (g) phoi bao st (A) ngoai khng khi mt thi gian bin thanh hn hp B co khi lng 30 gam gm FeO, Fe3O4, Fe2O3, Fe . Cho B phan ng hoan toan vi dung dich HNO 3 thy giai phong ra 5,6 lit khi NO duy nht (ktc). Gi tr cua m la: A. 27,5 g B. 22,5 g C. 26,2 g D. 25,2 g Cu 17: Hn hp kh X gm H2 v mt anken c t khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H 2 bng 13. S ng phn anken tha mn l A. 2 B. 3 C. 4. D. 5 Cu 18: t chy hon ton hn hp gm FeS2 v Ag2S vi s mol bng nhau thu c 3,696 lt SO 2 (ktc) v cht rn B . Cho B tc dng vi H2SO4 long d, sau phn ng hon ton thy cn li m gam cht rn khng tan. Gi tr ca m l: A. 11,88 gam B. 13,64 gam C. 17,16 gam D. 8,91gam Cu 19: Cht hu c X c cng thc phn t C3H5Cl. S ng phn ca X l: A. 4 B. 3 C. 6 D. 5 Cu 20: Ho tan 28,4g pht pho (V) oxit trong 500 gam dung dch axit photphoric c nng 9,8%. Nng phn trm ca dung dch axit photphoric thu c l A. 16,7 %. B. 17,6 %. C. 13,0 %. D. 14,7 %. Cu 21: Dung dch X cha hn hp gm Na 2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 350 ml dung dch HCl 1M vo 100 ml dung dch X, sinh ra V lt kh ( ktc). Gi tr ca V l A. 1,12. B. 3,36. C. 2,24. D. 4,48. Cu 22: Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC . tng hp 150 kg PVC theo s trn th cn V m 3 kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca tng giai on l 80%) A. 262,50. B. 131,25. C. 134,40. D. 168,00. Cu 23: Hn hp kh X gm xiclopropan, etan, propen, buta-1,3-ien c t khi so vi H 2 l 18. t chy hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi lng bnh gim m gam. Gi tr ca m l A. 4,3 B. 9,8 C. 2,7 D. 8,2 Cu 24: Cho cc phn ng sau: 0 (1) Cu(NO3)2 t (2) H2NCH2COOH + HNO2 0 0 t (3) NH3 + CuO (4) NH4NO2 t 0 0 (0 5 ) (5) C6H5NH2 + HNO2 HCl (6) (NH4)2CO3 t S phn ng thu c N2 l : A. 4, 5, 6. B. 2, 3, 4. C. 1, 2, 3. D. 3, 4, 5. Cu 25: Cho 21 gam hn hp X gm kim loi kim R v Al vo H2O d c 11,2 lt kh (ktc) v 4,5 gam cht rn khng tan. Tm R? A. Li B. Na C. K D. Rb Cu 26: 200C Fe c D = 7,87 g/cm3, nguyn t khi trung bnh l 55,85, gi thit cc khe rng chim 26% th tch tinh th. Bn knh nguyn t gn ng ca Fe l A. 1,38 A . B. 1,26 A . C. 1,28 A . D. 1,18 A . Cu 27: Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch KOH 1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to ca X l A. CH3 -COO-CH=CH-CH3. B. CH3-CH2-COO-CH=CH2. C. CH2=CH-CH2-COO-CH3. D. CH2=CH-COO-CH2-CH3. Cu 28: Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l A. 29,75. B. 24,25. C. 27,75. D. 26,25. Cu 29: Cho dy cc cht: C3H6,CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6 (benzen). S cht trong dy lm mt mu dung dch brom l A. 8. B. 7. C. 5. D. 6.
o o o o

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Cu 30: t chy hon ton 4,64 gam mt hirocacbon X (cht kh iu kin thng) ri em ton b sn phm chy hp th ht vo bnh ng dung dch Ba(OH) 2. Sau cc phn ng thu c 39,4 gam kt ta v khi lng phn dung dch gim bt 19,912 gam. Cng thc phn t ca X l A. CH4. B. C2H4. C. C3H4. D. C4H10. Cu 31: Cho cc pht biu sau: (a) Cht bo c gi chung l triglixerit hay triaxylglixerol. (b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong dung mi hu c. (c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch. (d) Tristearin, triolein c cng thc ln lt l: (C17H35COO)3C3H5, (C17H33COO)3C3H5. S pht biu ng l A. 4. B. 1. C. 3. D. 2. Cu 32: Cho dy cc cht: C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH (3), (C2H5)2NH (4), NH3 (5) (C6H5- l gc phenyl). Dy cc cht sp xp theo th t lc baz gim dn l: A. (4), (1), (5), (2), (3). B. (4), (2), (5), (1), (3). C. (4), (2), (3), (1), (5). D. (3), (1), (5), (2), (4). Cu 33: Este X khng no, mch h, c t khi hi so vi oxi bng 2,6875 v khi tham gia phn ng x phng ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cht ph hp vi X ? A. 3. B. 4. C. 2. D. 5. Cu 34: A l hn hp kh gm N2 v H2 c t khi so vi oxi bng 0,225. Dn A vo bnh c Ni un nng, phn ng tng hp amoniac xy ra th thu c hn hp kh B c t khi so vi oxi bng 0,25. Hiu sut ca qu trnh tng hp NH3 l A. 20%. B. 15%. C. 25% D. 30%. Cu 35: Cc cht: mantoz, glucoz, fructoz v saccaroz c tnh cht chung l: A. p vi Cu(OH)2 to dung dch xanh lam B. p vi Cu(OH)2, to c kt ta gch C. p vi AgNO3/NH3 cho Ag kt ta D. thy phn trong mi trng axit cho monosaccarit nh hn Cu 36: Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO 3)2 0,2M v H2SO4 0,25M. Sau khi cc phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m v V ln lt l A. 10,8 v 4,48. B. 17,8 v 4,48. C. 17,8 v 2,24. D. 10,8 v 2,24. Cu 37: Cho hn hp X gm hai cht hu c c cng cng thc phn t C 2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l A. 14,3 gam. B. 16,5 gam. C. 8,9 gam. D. 15,7 gam. Cu 38: Thu phn hn hp gm 0,03 mol saccaroz v 0,02 mol mantoz mt thi gian thu c dung dch X (hiu sut phn ng thy phn mi cht u l 80%). Khi cho ton b X tc dng vi mt lng d dung dch AgNO 3 trong NH3 th lng Ag thu c l A. 0,056mol. B. 0,095 mol. C. 0,16 mol. D. 0,168 mol. Cu 39: Cho dy cc cht: phenylamoni clorua, benzyl clorua, isopropyl clorua, m-crezol, ancol benzylic, natri phenolat, anlyl clorua . S cht trong dy tc dng c vi dung dch NaOH long, un nng l A. 4. B. 3. C. 5. D. 6. Cu 40: Dy cc cht no sau y m phn t phn cc ? A. CO2, HF, NH3 B. HCl, H2O, SO2 C. NH3, CO2, SO2 D. Cl2, SO2, CH4 II. PHN RING [10 cu]Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Cho cc dung dch sau: saccaroz, fructoz, etilenglicol, anehit axetic, axeton, anbumin, mantoz, metanol, axit fomic . S lng dung dch c th phn ng vi Cu(OH)2 iu kin thng l A. 5 B. 4 C. 6 D. 7 Cu 42: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cngthc phn t ca X l A. C3H7COOH B. HCOOH. C. C2H5COOH. D. CH3COOH. Cu 43: Cho 0,01 mol mt este ca axit hu c phn ng va vi 100ml dung dch NaOH 0,2M, sn phm to thnh ch gm 1 ancol v 1 mui c s mol bng nhau. Mt khc khi x phng ho hon ton 1,29 gam este bng lng va 60 ml dung dch KOH 0,25M. Sau khi kt thc phn ng, em c cn dung dch thu c 1,665 gam mui khan. Este c cng thc phn t l COOCH2 COOCH2 COOCH2 C H A. C3H6 B. 2 4 C. C3H7COOC2H5 D. C4H8 COOCH2 COOCH2 COOCH2 Cu 44: Ha tan hon ton 30,4 g cht rn X gm Cu. CuS, Cu 2S v S bng HNO3 d, thot ra 20,16 lt kh NO duy nht (ktc) v dung dch Y. Thm Ba(OH)2 vo Y thu c m (g) kt ta . Gi tr ca m l A. 119,5g B. 112g C. 115,9g D. 110,95g Trang 3/5 - M thi 148

Cu 45: Hy cho bit trong cc ha cht sau: NaClO, KMnO4, CaOCl2, Na2CO3, Na2ZnO2 v AgNO3. Hy cho bit dung dch HCl tc dng c vi bao nhiu dung dch? A. 6 B. 3 C. 5 D. 4 Cu 46: Khi lng dung dch KOH 8% cn ly cho tc dng vi 47g K2O thu c dung dch KOH 21% l: A. 250 g B. 320g C. 354,85g D. 400g Cu 47: Thy phn khng hon ton pentapeptit X ngi ta thu c tripeptit l Ala-Glu-Gly v cc ipeptit l Val-Ala, GluGly v Gly-Ala . Vy cng thc cu to ca X l A. Ala-Val-Glu-Gly-Ala B. Gly-Ala-Val-Ala-Glu C. Val-Ala-Glu-Gly-Ala D. Ala-Glu-Gly-Ala-Val Cu 48: Hn hp rn X gm Al, Fe2O3 v Cu c s mol bng nhau. Hn hp X tan hon ton trong dung dch A. NaOH (d). B. AgNO3 (d). C. NH3(d). D. HCl (d). Cu 49: Cho cc th nghim sau: (1) dung dch AlCl3 + dung dch Na[Al(OH)4]; (2) dung dch NaOH d + dung dch AlCl3; (3) kh CO2 (d) + dung dch Na[Al(OH)4]; (4) Na[Al(OH)4] (d) + dung dch HCl; (5) kh CO2 (d) + dung dch Ba(OH)2. Nhng th nghim thu c kt ta sau phn ng l: A. (2), (3), (5) B. (1), (2), (5) C. (1), (3), (4) D. (1), (2), (4) Cu 50: Thu phn 51,3 gam mantoz trong mi trng axit vi hiu sut phn ng t 80% thu c hn hp X. Trung ho X bng NaOH thu c dung dch Y. Cho Y tc dng ht vi lng d dung dch AgNO 3 trong NH3 un nng, sinh ra m gam Ag. Gi tr ca m l A. 58,32. B. 51,84. C. 32,40. D. 58,82. B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Cho cc dung dch cha cc cht tan : glucoz, fructoz, saccaroz, mantoz, axit fomic, glixerol, vinyl axetat, anehit fomic . S dung dch va ho tan Cu(OH)2 va lm mt mu nc brom l A. 4. B. 3. C. 5. D. 6. Cu 52: Cho 8,04 gam hn hp kh v hi gm anehit axetic v axetilen tc dng hon ton vi dung dch AgNO 3 trong NH3 thu c 55,2 gam kt ta . Lc ly kt ta sau cho vo dung dch HCl d, sau khi kt thc phn ng thy c m gam cht khng tan. Gi tr ca m l: A. 61,78 B. 21,6 C. 41,69 D. 55,2 Cu 53: Thuc th no trong cc trng hp sau c th dng phn bit c 5 kim loi: Mg, Zn, Fe, Ba, Ag. A. Dung dch HCl B. Dung dch NaOH C. H2O D. Dung dch H2SO4 long Cu 54: Cho cc cht sau: Fe, Mg, Cu, AgNO3, CuCl2, Fe(NO3)2. S cp cht tc dng vi nhau l? A. 7. B. 9 C. 6 D. 8. Cu 55: Ho tan hon ton 74 gam hn hp X gm FeO, Fe 3O4, Fe2O3 bng dung dch H2SO4 long d sinh ra 178 gam mui sunfat. Nu cng cho 74 gam hn hp X trn phn ng vi lng d kh CO nhit cao v dn sn phm kh qua dung dch nc vi trong d th khi lng kt ta thu c l (cc phn ng xy ra hon ton) A. 240 g B. 130 g C. 150 g D. 180 g Cu 56: Hoa tan 12 gam Mg trong V(lit) dung dich HNO3 2M thu c 2,24 lit khi N2O (ktc) va dung dich X. C can dung dich X thu c m (g) mui khan. Gia tri cua V va m ln lt la: A. 625; 74 B. 500; 76 C. 500; 74 D. 625; 76 Cu 57: Cho 0,1 mol axit cacboxylic n chc X tc dng vi 0,15 mol ancol n chc Y thu c 4,5 gam este vi hiu sut 75%. Vy tn gi ca este l: A. metyl axetat B. etyl axetat C. etyl propionat D. metyl fomiat Cu 58: Nh t t n ht dung dch cha 0,1 mol Na 2CO3 v 0,3 mol NaHCO3 vo 150 ml dung dch H2SO4 1M thu c kh CO2 v dung dch X. Cho dung dch Ba(OH)2 d vo dung dch X th thu c kt ta c khi lng l A. 34,95 gam B. 66,47 gam C. 74,35 gam D. 31,52 gam Cu 59: Trn ln dung dch cc cp cht sau: (1) Na[Al(OH)4] + CO2 (d) (2) Ca(OH)2 (d) + Mg(HCO3)2, (3) CuSO4 + NH3 (d), (4) Na2CO3 (d) + FeCl3 (5) KOH (d) + Ca(H2PO4)2 (6) Na2CO3 + AgNO3 (d) C bao nhiu trng hp to thnh kt ta? A. 3 B. 4 C. 2 D. 5 Cu 60: t chy hon ton mt amin, no, n chc, mch h. Sn phm chy sau khi ngng t hi nc c t khi so vi H 2 l 19,333. Cng thc phn t ca amin l A. CH3NH2 B. C2H5NH2 C. C3H7NH2 D. C4H9NH2 ----------- HT ---------(Gim th khng gii thch g thm)

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TRNG THPT CHUYN BC NINH P N THI TH I HC LN 1 NM HC 2012-2013 MN: HA HC, KHI A, B Cu 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 148 A B B C B B B C C B D A C B A D C A D A D A A B C C B D B C 239 D D D A C D C B D C A D B A C A D A B D D C B A A B C A D A 395 D C B C A D D A A C B A D D C D C B A D D A A A B C A D C A 406 B D A B D B C A A D B C D C B B D C A D B B A A C D D C C B Cu 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 148 A B A C A C A D C B C D D D A C C D C A B A D D B D D B D A 239 D B D A C B D C B B C A A C C C D C B B B D A A A C B C B B 395 B C B C A D B B A D D C A C C D C B B A A B D C B D B B B C 406 C B D D C B C A A A A D D B A A A C A D B B C A C C D C D B

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