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JEE Mains Model Paper 6 Answer Keys

MATHEMATICS
1. (d) If , 2 are roots of ax 2 bx c 0 b c then 3 ,2 2 2b 2 9ac a a 2 Using condition 2b 2 9ac , we get 2 3a 1

9 2

a2

9a 2
2. (b) tan
A 2

6a 1 9a 2

45a 27

39a

26

5a 3 2 a 3

2s

3b

2b c a

g. c
dx dy sin a

om
y cos y sin y cos a sin 2 a y y

5 C 2 , tan 6 2 5 A C 1 tan tan 2 2 3 s b 1 3s 3b s 3 a, b, c are in A.P.

s b s c s b s a . ss a ss c

3.

(b) sin y
dx dy

x sin a

y or x

sin a y y sin 2 a y

dy dx

4. 5. 6.

(a) (c) (a) Applying R1

R1
2 2 2

1 i 1 i i
7. 8. 9. (c) (a)

w
1 1
x

w
1 0
x

R3 we obtain

1 1

.m

(a)

2 1

ye ng
sin 2 a y sin a
1
2n

sin y sin a y

R1 and R2 become identical

1 , which is of the type cosx

sin x

5 2 2 5 2 2 It is true for x = 2 only.

10. (c)

1 1 2
= cos
4

1 i 2
2n

i 2

2n

2n

i sin

cos

i sin

2 cos

n which is same as 1 2

.i n

www.myengg.com 11. 12. 13. 14. 15. (a) (a) (b) (b) (a) Lf K

JEE Mains Model Paper 6 Answer Keys

h [k h] sin (k = lim h 0 h k = 1 k 1 .1.

h 0

lim

f k

f k

,h h)

0 lim k 1
h 0

sin k h

k 1 lim
h 0

sin h . h

16. 17. 18. 19.

(b) (a) (a)

(c) Let n

a2 a1i j a3 k
0 u .n 0 v .n a3 1

w.n
20. (b) Let Y

.m
Y

aX b c

ye ng
aX b c

a1 a2 0 a1 a2 0 a1 0, a 2 is a unit vector) ( n

1 n
21. (b)

Y Y

a2 1 c2 N

g. c
0
Y Y a X c
2 y

om
X
a2 c2
2 x y

a c

log ab

log b

log ab

log b = log

a b b

log a

22.

(a)

fog x
gof x

f g x
g f x

f 3x 1
2 = 3 3x 1 2 = 3 9x 2 g 3x 2 2 = 3 3x 2 2

6x 1 1 9x 2

2 5

27 x 2 18x 5

23. 24. 25. 26.

(d) (b) (a) (b) y 2

4 x and x 2 4 y are symmetric about line y = x 4 x and y = x is

Area bounded between y 2

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4

JEE Mains Model Paper 6 Answer Keys

2 x
0

x dx

8 3

AS2

16 and AS1 3

AS3

16 3

AS1 : AS2 : AS3 : : 1 : 1 : 1

(4, 4)
S1 S2 S3

27. 28.

(c) (a) P A
1 1 1 and P A , PA B 6 4 4 3 P A , PA B 1 P A B =1 P A PB P A B 4 1 1 1 1 PB PB 6 4 4 3 Since P A B P A P B and P A P B therefore A and B are independent but not equally likely. B

29.

(c)

Every point on the line should satisfy equation of plane 5(3) 4 3 = a

30.

(b)

a3

w
3

.m
a=8
A a9
d x log x dx x
2

i.e., (3, 4, 3) should lie in the plan

ye ng
A . adj A

adj A

31. 32.

(b) (b) Given integral = =

log x x log x x dx

A . adj A

| A| I
a6

x log x x

d x log x x dx dx
x 1 log x 1 log x

x log x 2

g. c
a9

om

www.myengg.com 33.

JEE Mains Model Paper 6 Answer Keys

(a) Since a , c , b form a right handed system, therefore, i j k xk c b a 0 1 0 zi

x y z

34. (a) 35. (a)

cos

sin

2 cos

sin cos
cos
36. (d) If
y
x, y,

2 1 cos sin
sin

cos

sin 2 1

sin 2 1

2 1 2 1

sin 2 1

2 1

2 1
2 sin

2 sin

sin

z are in A.P., then

37.

(a) tan m

tan n
K

These values of 38. (a) Since cos

1

.m

m n

ye ng
n K K , where K m n

z x Here, L.H.S. is irrational and R.H.S. is rational, not possible. x , y , z are not in A.P. Similarly, these are neither in G.P. nor in H.P.

are in A.P. with first term

g. c
I

n 1 d and

m 1d

om
y x

n 1 m 1

x2 4

m n

and common difference =

m n

x y cos 1 2 3 2 xy y2 cos 2 3 9
4y2

sin 2
36 sin 2

x2 4

xy cos 3

y2 9

sin 2

9 x 2 12 xy cos

39.

(a)

z2

2 z cos

z2

2 z cos
2 2

= z
z

2 z cos 2z
2

2 1

2 2 1

40.

(a)

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JEE Mains Model Paper 6 Answer Keys

CHEMISTRY
41. (a)

H2C CH2 CH2 CH2 CH3 Cl does not contain any assymmetric C.

42. 43. 44. 45. 46. 47. 48. 49. 50.

(d) (a) (b) (d) (a) (a) (b) (b) (b) The oxidation state of Mn is +7, hence there are only 18 electrons in it, hence EC will be 1s22s22p63s23p64s03d0.

51.

(c)

3160 yrs.

i.e. 2 half lives t1/2 52. (c)

Keq = PCO 2 = 8.21

PV = nRT

8.21 10 3 1 = 2.5 0.0821 400

w
206 82Pb

3160 = 1580 yrs. 2

53.

(a)

238 92U

Equating masses 4a + 206 = 238 a=8 ; Equating atomic numbers 92 = 82 + 2a b = 6. b ; 10 = 16 b

.m

1 of original amount 4

10 3 atm

ye ng
1 . 22

The Reformatsky reaction is the reaction between an bromo acid ester and a carbonyl compound (aldehyde or ketone) in the presence of Zn to form a hydroxy ester.

10 4.
0 +a 4 2 He + + b 1 B

g. c

om

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JEE Mains Model Paper 6 Answer Keys

54.

(a)

W1 W2
4 W2

M2 M1
2 32

W2 = 16 gm. 55. (c) BaF2(s) Ba2+(aq) + 2F(aq) Since Ba2+(aq) also comes from the ionization of Ba(NO3)2, hence the 1 solubility of BaF2 is given as F . 2

57.

(b)

a=

(0.83 + 1.74) = 5.94 A

3
58. (a)
2 SO 3 + H2SO4

SO 2 4 + H2O + SO2

K2Cr2O7 + H2SO4 + 3SO2 59. (d)

.m

H2C2O4 + NaOH or H2C2O4 + OH

By the definition of heat of neutralization, we have Na2C2O4 + H2O ; C2O 2 4 + H2O ; H = 53.35 kJ H = 53.35 kJ H = 57.3 kJ (i) (ii)

H+ + OH

H2O
+ C2O2 4 +H

Subtracting equation (ii) from (i) we get H2C2O4 H2C2O4 60. (d) Al(NO3)3 k3[Fe(CN)6] H = 3.95 kJ H = 7.9 kJ

+ C2O2 4 + 2H

Al3+ + 3NO 3 3k+ + [Fe(CN)6]3

61.

(c)

The electronic configuration of Ni in [Ni(CN4)2 , [Ni(Cl)4]2 and Ni(CO)4 are: Ni2+ in [Ni(CN)4]2 :

ye ng
K2SO4 + Cr2(SO4)3 + H2O

g. c

In ZnS lattice, S2 ions are present as FCC with Zn2+ ions occupying alternate tetrahedral voids. 3a rZn 2 rS2 4

om

56.

(a)

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3d

JEE Mains Model Paper 6 Answer Keys

4s
XX XX XX

4p
XX

dsp2

Ni2+ in [Ni(Cl)4]2 :
3d 4s
XX XX

4p
XX XX

sp3

Ni in [Ni(CO)4] :
3d 4s
XX XX

4p
XX XX

62.

(a)

C 23

2C4+ + 2e

3 moles of KMnO4 5

ye ng
1 mole of FeC2O4

3 moles of KMnO4

5 moles of FeC2O4

g. c
3 . 5

Mn+7 + 5e Mn+2 Fe2+ Fe3+ + e

Number of moles of KMnO4 needed to reacted with 1 mole of FeC2O4 =

N=2 64. (b)

11Na +

0.3 = 0.6.

65.

(b)

The removal of second electron from Mg+ requires less energy (2, 8, 1) as compared to Na+ (2, 8). IInd I.E. Na+ > IInd I.E. of Mg+. Incorrect statement is (b). C+ : 1s2, 2s2, 2p1 N+ : 1s22s2, 2p2 O+ : 1s22s2, 2p3 F+ : 1s22s2, 2p4 Removal of IInd electron requires least energy in carbon than in nitrogen. After loosing one e oxygen acquires stable half filled electronic configuration. Hence, removal of IInd electron requires more energy for oxygen than F. C < N < F < O.

: 2, 8, 1 Na : 2, 8

.m
12Mg +

63.

(d)

H3PO3 is losing 2 proton in this reaction.

: 2, 8, 2 Mg : 2, 8, 1

om

sp3

www.myengg.com 66. (b)

JEE Mains Model Paper 6 Answer Keys

A good leaving group should be (i) electron withdrawing, to polarize the carbon atom (ii) stable i.e. should not be a strong base (iii) polarisable to stabilize the transition state. Therefore,
O O S F C F > O O S CH3 > O
..

O O C CH3 > O CH3

O F

CH2OH ..
67. (c)

H+

CH2 OH2
H2O

CH2

H
conc. H2SO4

68.

(a)

Ph OH

H2O

.m

Intermediate carbocation obtained after rearrangement C 6 H 5 C H CH 2 CH(CH3)2 is highly stable. 69. (b)

CH3 C=O H

H+

+ CH3 C=OH H

ye ng
Ph H
.. NH2OH (i)

g. c
OH CH3 C + H NH2OH
(ii)

H+

In the above mechanism step (ii) is RDS (at pH 5 to 6) which increases with increase in [H+] ion concentration. At very low pH step (i) becomes RDS which (rate) decreases with decrease in pH due to consumption of nucleophile (NH2OH) by H+ ion. 70. 71. 72. (c) (b) (c) In the presence of acid, cyclic ether are cleaved and nucleophile attack at the carbon which is more substituted. CH3 CH3 CH3 CH3 (+) Br + + Br O: H OH OH OH

73.

(c)

om
H

CH3 C=NOH + H2O H

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JEE Mains Model Paper 6 Answer Keys

74. 75.

(a) (b)

KE =

3 3 RT ; 8.314 300 = 3741.3 J or 3.741 kJ. 2 2

1s2 *1s1 2 1 1 Bond order = = . 2 2

He 2

76. 77. 78.

(d) (d) (a) 2SO2(g) + O2(g) 2SO3(g)

n V
2

n [O 2 ] V

79.

(a)

H = U + ng RT H

U = ng RT =

80.

(a)

The complex [Ni(CO)4] has Ni atom in sp3 hybridised state and its shape is tetrahedral.

.m

ye ng

3 8.314 298 = 7.4327 kJ mol 1. 1000

g. c

Now, P =

n n is constant for SO2 and SO3. PSO 2 = PSO 3 . RT as V V [ PSO 2 ] 2 1 1 3.5 = ; 3.5 = or [O2] = 0.285 atm. 2 [O 2 ] [PSO 3 ] [O 2 ]

om

Keq =

[SO 3 ]2 [O 2 ] [SO 2 ]2

3.5 =

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JEE Mains Model Paper 6 Answer Keys

PHYSICS
41. 42.
E. ds

(c)
qencl
0

if qencl. = 0 ,

E. ds 0 , E may or may not be zero.

(c) 43. 44.

vm

(d)
2v r sin 30 = 2 20

1 , vm 2

20ms

(d) 45.

u sin
Favg =

v sin ,
p mv cos t t (a)

46.

Idisc < Iring (a)

Disc will start to roll earlier.

ye ng
AB AA

47.

TA

4TB , l
(d)

TL , YA

lA lB

.m
TA TB YB YA
2 10
2
8

48.

dL 100 L

T2

(T )dT 100
2

T1

T2 100 2

= 10 [(400) (300) ] = 0.07% (a) 49. (pA pB)A = ma, (d) 50. Emissive power (b)

ghA

Ala ,

W A

e T4 , A

W e T4

g. c
1 2 3 8 3
400 300

, Favg =

mu sin (cot t

la g

om
cot )

u sin sin mu cos

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JEE Mains Model Paper 6 Answer Keys

Q1 Q2 T1 T2

51.

For carnot refrigeration,

Q2 mL

50 103 80 = 4 106 cal;

Q1

4 106

300 , 273

Q1

4.4 106 cal

(a) 52.

v
T

200 , 0.5

400 cms1,

v2

(400) 2 5 , (c)

8 105 dyne,

8N

53.

Potential at origin V (d)

kq

om
6

1 x0

1 2 x0

1 3x 0

......... which is =

kq ln 2 x0

q 4
0

x0

ln 2

Current through ammeter, I 2 '

56.

I2R 100 R 1.5R 1.5 1.5R , I1 I 2 ' I2 ' 450 400R 30000 400R 30000 400R 30000 450R , R 600 (b) d d ( BA) | | dt dt dI | | 0 nA 4 10 7 1000 4 10 4 100 16 10 dt (b)

55.

1.5 A 450 100R If S1 & S2 both are closed, Req = 300 + R 100 1.5 1.5 R 100 I2 Req 400R 30,000
When S1 & S2 both are open, I1

(d)

.m

ye ng

g. c
16 V

54.

When S is open, U i

1 C (10) 2 = 50 C 2 10 When S is closed, at steady state, I 2A 5 potential difference across C (V 1 ) I (3 1) 8V 1 1 Uf CV 2 C (8) 2 = 32 C 2 2 Uf 32 % difference = 1 100 = 36% 100 1 50 Ui

1 CV 2 2

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JEE Mains Model Paper 6 Answer Keys

100 100 2 2 1 10 2

57.

P = vrms. Irm cos = (c)

= 2.5 watt

58.

t 1

1 1
(i)

1 t 1

t 1 2.5 3.5mm 1 (i) 1 = 3.5 1

(c) 59.

7 5

Number of atoms in 276ng sample of 92kr

0.693 t1 / 2 0.693 2.079 1 3

Initial activity (A0) = N 0 (a) 60. 61. (a)

B 2 10 8 sin(60 106 t 0.2 y)k (a)

62. Induced emf = Bvb cos ,

.m

E0 , B0 B0

E0 C

6 3 108

ye ng
B E
6s) 15ms
1

1 18 1014 3

6 1014 disintegration s1

g. c
, i B J

om
9

6 1023 276 10 92

18 1014

2 10 8 T ,

If v is terminal speed, Fm cos 63.

Bvb cos B 2b 2 v cos , Fm IBb R R 2 2 2 B b v cos mg sin , mg sin , v R

mgR sin b 2 B 2 cos2

(d) From, t 0 to 6s v t 5 5 5 2 t dt , v a t , dv t , v(t 6 0 12 6 0

x1 6

dx
0

5 2 t dt , x1 12 0

30m

From t

x2

6s to 9s, a 5ms 2 1 2 1 2 vt at , x2 15 3 at = 45 + 22.5 = 67.5 m 2 2 x1 x2 97.5m (c)

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m l1 g l

JEE Mains Model Paper 6 Answer Keys

64.

m l l1 g , l1 l

l 1

(c) 65.
K .E. According to work energy theorem, Wnet Wmg W f k f ki , Wmg mgh 1 9.8 5 = 49 J
x2 2

Wf
x1

f dx
0

(10x 5)dx = 30

(c) 66. For maximum mass M, reaction R1 at C should be zero, W OD Mg DB ( O is the center of the bar) 1 g 30 M g 20 M 1.5 kg (b)

67.

68.

Reynolds number ( N R )

.m
vd 4 Q d 4 103 3 10 3 10 3 60 4 10

Q
NR
69. 70.

Av , v

4Q , NR d2 5000, N R 3000 (b) (d)

ye ng
2R

Net force at the centre C of the line joining C1 & C2 will be zero, for minimum v, mass m should be able to reach at C, GMm GMm 1 2 GMm By conservation energy, mv 2 R 7R 2 4R 9GM 1 2 GMm 8GMm 1 2 9GMm , mv ,v mv 7R 2 2R 7R 2 14R (d)

leq

k2 l2 l (c)

leq

71.

nv 315 , 2l 420 (n 1) 315 n (b) f1

f2

(n 1)v 2l
f

420
v 2l 315 3

n 3

g. c
2

105Hz

om

www.myengg.com 72.

JEE Mains Model Paper 6 Answer Keys

There will be no field inside the shell, (b) (b) 4A current flow in both vertical brances. Vab 6 4 3 4 12V (b)

73. 74.

75.

Field due to 10A & 8A is downward and field due to 20A is upwards. Therefore net field is due to 2A upwards. For field to be zero, I should be 2A opposite to 10A current such that it produces downward field at centre. (b)
V 1 hc e

76.

,
1 3600

V2 V1

V2 V1 12400

1 = 0.34 V 4000

(a) 77.

I = 10 A, B = 0.2 T, l = 8 cm = 0.08 m,
IlB b cos 60 0

10 0.08 0.2 0.06

(d) 78.
1 sin 60
prism liquid

w
liquid

.m
1.5

79.

d d BA A 0.8 0.8 2 = 1.6 V dt dt Induced current will be in clockwise direction, 20 1.6 Net emf induced = 18.4 V (b)
induced

80.

Vs Vp

Ns , Vs Np

Is

Vs Rs

Vp I p

2.4 = 0.16 A 15 2.4 0.16 3.2 103 A = 3.2 mA Vs I s , I p 120 (a)

(b)

10 120 = 2.4 V, 500

ye ng
b = 0.06 m

3 2

1.3

g. c
2
0.0048 Nm

1 1 hc e 2

1
1

om