Professional Documents
Culture Documents
Reich 2002
Acronyms-1
DMSO2 Dimethyl Sulfone DMTSF Dimethyl(methylthio)sulfonium tetrafluoroborate DNP Dinitrophenylhydrazine DNPBA 2,4-Dinitroperbenzoic acid dppb 1,4-Bis(diphenylphosphino)butane N N dppe (diphos) 1,2-Bis(diphenylphosphino)ethane dppp 1,3-Bis(diphenylphosphino)propane O E Entgegen (opposite, trans) DMPU E Methoxycarbonyl CO2CH3 EDTA Ethylenediaminetetraacetic acid NMe2 ee Enantiomeric Excess O=P NMe2 EE 1-Ethoxyethoxy (alcohol protection) NMe2 en Ethylene Diamine HMPA FC Friedel-Crafts Reaction Fmoc 9-Fluorenylmethoxycarbonyl Fp Cyclopentadienyldicarbonylferrate Li N Glyme 1,2-Dimethoxyethane Galvinoxyl Radical trap HBT Hydroxybenzotriazole LDA HMDS Hexamethyldisilazide HMPA,HMPT Hexamethylphosphorictriamide (solvent, cosolvent) N HSAB Hard-Acid-Soft-Base Li HVZ Hell-Vollhardt-Zelinsky Reaction ("-bromination of carboxylic acids) LiTMP Ipc2BH Bisisopinocampheylborane KDA Potassium Diisopropylamide LAH Lithium Aluminum Hydride (LiAlH4) )2 BH LDA Lithium Diisopropylamide LFER Linear Free Energy Relationship Ipc2BH LHMDS Lithium Hexamethyldisilazide (LiN(SiMe3)2) LICA Lithium N-isopropylcyclohexylamide N LICKOR Lithium-potassium alkoxide reagents N LiTMP Lithium Tetramethylpiperidide N LTA Lead Tetraacetate (Pb(OAc)4) MA Maleic Anhydride HBT OH MCPBA meta-Chloroperoxybenzoic Acid MEM $-Methoxyethoxymethyl (CH3OCH2CH2O-CH2-, alcohol protection) Mes Mesityl (2,4,6-trimethylphenyl) Cl MOM Methoxymethyl (CH3OCH2-, alcohol protection). OOH MoOPH MoO5@Py@HMPA (oxidizing agent) Ms Methanesulfonyl (Mesyl, CH3SO2) O MTPA "-Methoxy-"-trifluoromethylphenylacetic acid (Mosher) MCPBA MTM Methylthiomethyl CH3-S-CH2- (alcohol protection) MVK Methyl Vinyl Ketone (3-Butene-2-one) NBA N-Bromoacetamide NBS, NCS N-Bromo, N-Chlorosuccinimide Nf Nonaflate (C4F9SO2) NIS N-Iodosuccinimide NMO N-Methylmorpholine-N-oxide NMP N-Methylpyrrolidone; solvent Ns p-Nitrobenzenesulfonyl PBB, PCB Polybrominated, Polychlorinated Biphenyls PCC Pyridinium chlorochromate PDC Pyridinium dichromate PG Prostaglandins phen 1,10-Phenanthroline PhthN Phthalimido
Acronyms-2
PMDTA PMB PNB PPA PPTS PTAD PTC Pv Py RT SEM SES Sia2BH TASF TBAF TBDMS TBDPS TBHP TBS TCE TCNE TCNQ TEA TES Tf TFA Thexyl THF THP TIPS TMEDA TMS TMSI Tol TOSMIC TPAP TPP TRIS Trityl Troc Ts TTN WK Z
N,N,N',N'',N''-pentamethyldiethylenetriamine p-Methoxybenzyl para-Nitrobenzoate . O Polyphosphoric Acid Pyridinium p-Toluenesulfonate N-Phenyl-1,2,4-triazolinedione Phase Transfer Catalyst Pivaloyl Pyridine; Solvent, base, catalyst O Room Temperature 2-Trimethylsilylethoxymethoxy (alcohol protection) Trimethylsilylethylsulfonyl (amine protection SO2CH2CH2SiMe3) Disiamylborane (Me2CHMeCH)2BH Tris(dimethylamino)sulfonium difluorotrimethylsilicate Tetra-n-butylammonium fluoride t-Butyldimethylsilyl (alcohol protection) t-Butyldiphenylsilyl (alcohol protection) t-Butylhydroperoxide t-Butyldimethylsilyl (also TBDMS) 2,2,2-Trichloroethyl (alcohol, acid protection) Tetracyanoethylene 7,7,8,8-Tetracyanoquinodimethane Triethylamine Triethylsilyl Triflate (CF3SO2) Trifluoroacetic(yl) Me2CHMe2CTetrahydrofuran; solvent Tetrahydropyran (alcohol protecting group) Triisopropylsilyl (alcohol protection) N,N,N',N'-Tetramethylethylenediamine Tetramethylsilane, also Trimethylsilyl Trimethylsilyl Iodide p-Tolyl p-Toluenesulfonylmethylisocyanide Tetra-n-propylammonium Perruthenate meso-Tetraphenylporphyrin Tris(hydroxymethyl)aminomethane (buffer) Triphenylmethyl Trichloroethyloxycarbonyl (CCl3CH2OC(O)-) Tosyl (p-CH3C6H4SO2) Thallium Trinitrate Wolff-Kishner Reduction Zusammen (together, cis)
CH
Galvinoxyl
N Br NBS
N CH3 NMP
N+ H PCC
Cl-CrO3-
N TMEDA
Acronyms-3
O
O Dess-Martin
N-Methyl-N-nitroso-p-toluenesulfonamide (diazomethane) Me2N+=CH2 I- (Mannich reagent) 11 (CFCl3), 12 (CF2Cl2), 13 (CF3Cl), 13B1 (CF3Br), 14 (CF4), 21 (CHFCl2), 22 (CHF2Cl), 23 (CHF3), 114 (CF2ClCF2Cl), 116 (CF3CF3) (KO3S)2NO Lithium Diorganocuprates S S Diisopropylethylamine (base catalyst) MeO P P Chromic acid in acetone S
S Lawesson Pd on CaCO3/PbO Methyl cyanoformate (NCC(=O)OMe Triethyloxonium Fluoroborate (Me3O+ BF4-, methylating reagent) "-Methoxy-"-trifluromethylphenylacetates Potassium monopersulfate (KHSO5) CH2 Sodium bis(2-methoxyethoxy)aluminum Hydride Ti Cl tri-sec-butylborohydride (L = Li, K = potassium) CH2I2-Zn(Cu) Petroleum ether solvents (alkane fractions) Tebbe Sodium Triethylborohydride Cp2Ti(CH2)(Cl)AlMe2 Me2N+=CCl2 ClMe2N+=CHCl ClO
OMe
CH3 Al CH3
(Ph3P)3RhCl Ph3P=CR2
Wieland-Miescher
ASIS
Acronyms-4
GLC HETCOR HMQC HOESY HPLC ICR INDOR INEPT IR J LC LIS MCD MS NMR NOE(SY) OD ORD ORTEP PES Rf ROESY TLC UV VPC XPS
Gas-liquid Chromatography (VPC) Heteronuclear correlation (NMR) Proton detected Heteronuclear Multiquantum Coherence (NMR) Heteronuclear Overhauser Spectroscopy (NMR) High Performance Liquid Chromatography Ion Cyclotron Resonance Internuclear Double Resonance Insensitive Nuclei Enhanced by Polarization Transfer (NMR) Infrared Coupling Constant (NMR) Liquid Chromatography Lanthanide Induced shifts (NMR) Magnetic Circular Dichroism Mass spectrum Nuclear Magnetic Resonance Nuclear Overhauser Effect (Spectroscopy) Optical Density Optical Rotatory Dispersion Oak Ridge Thermal Ellipse Program Photoelectron Spectroscopy Retention Factor (chromatography) Rotating frame Nuclear Overhauser Spectroscopy (NMR) Thin Layer Chromatography Ultraviolet spectroscopy Vapor Phase Chromatography (GLC) (ESCA) X-Ray Photoelectron Spectroscopy
Acronyms-5