59-240 Introductory Physical Chemistry - Fall 2006 Exercise and Problems - Lecture 11 Updated: October 24, 2006 Reading:

4.3 7th edition, 3.3, 8th edition 7th edition: 4.14, 4.15, 4.18, 4.19, 4.20, 4.24, 4.25, 4.26 8th edition: M3.6, 3.5, 3.8, 3.9, 3.10, M3.7, 3.14, 3.15 M3.6a (Ex. 4.14a, 7th edition) Calculate the change in entropy when 50 g of water at 80 oC is poured into 100 g of water at 10 oC in an insulated vessel given that Cp,m = 75.5 J K-1 mol-1. M3.6b (Ex. 4.14b, 7th edition) Calculate the change in entropy when 25 g of ethanol at 50 oC is poured into 70 g of ethanol at 10 oC in an insulated vessel given that Cp,m = 111.5 J K-1 mol-1. M3.7a (Ex. 4.24a, 7th edition) Calculate the change in entropy when a monatomic perfect gas is compressed to half of its initial volume and simultaneously heated to twice its initial temperature. M3.7b (Ex. 4.24b, 7th edition) Calculate the change in entropy when a diatomic perfect gas is compressed to one-third of its initial volume and simultaneously heated to three times its initial temperature. Answers: M3.6a (Ex. 4.14a, 7th edition) +2.8 J K-1 M3.6b (Ex. 4.14b, 7th edition) 0.2 J K-1 M3.7a (Ex. 4.24a, 7th edition) n(CV,m - R) ln 2 M3.7b (Ex. 4.24b, 7th edition) (3/2)nR ln 3 A-list answers for the 8th edition: 3.5 93.4 J K-1 3.8 -386.1 J K-1 mol-1; +92.6 J K-1 mol-1; -153.1 J K-1 mol-1 3.9 -521.5 kJ mol-1; +25.8 kJ mol-1; -178.7 kJ mol-1 3.10 -522.1 kJ mol-1; +25.78 kJ mol-1; -178.6 kJ mol-1 3.14 817.90 kJ mol-1 3.15 = 0.11; = 0.38