Bi tp n thi i hc ha 12- nm hc 2012-2013

IU CH KIM LOI A. NHIT LUYN Cu 1. Hy cho bit dy cc kim loi no sau y c th c iu ch bng cch cho CO kh oxit kim loi nhit cao ? A. Fe, Cu, Al, Ag B. Mg, Fe, Zn v Cu C. Ca, Cu. Fe v Sn D. Cu, Ni, Pb v Fe Cu 2. Tin hnh kh hon ton m gam oxit kim loi MO bng kh CO d thu c 7,2 gam kim loi M, kh CO2 thot ra hp th hon ton trong nc vi trong d, thu c 11,25 gam kt ta. Vy cng thc ca oxit l: A. CuO B. FeO C. PbO D. ZnO Cu 3. Dn kh CO d qua hn hp X gm 0,1 mol Fe 3O4 ; 0,15 mol CuO v 0,1 mol MgO sau cho ton b cht rn sau phn ng vo dung dch H 2SO4 long d. Tnh th tch kh thot ra(ktc). A. 5,6 lt B. 6,72 lt C. 10,08 lt D. 13,44 lt Cu 4. Nung hn hp gm Fe3O4, CuO v Al nhit cao, sau phn ng hon ton cho phn rn vo dung dch NaOH thy c kh H2 bay ra. Hy cho bit kt lun no sau y ng : A. Al d, Fe3O4 ht B. Al, Fe3O4, CuO u d. C. Al d, Fe3O4 d, CuO ht D. Al d, Fe3O4 v CuO ht Cu 5. Cho kh H2 d i qua hn hp X gm 0,05 mol CuO; 0,05 mol Fe3O4 v 0,1 mol Al2O3 cho cht rn sau phn ng vo dung dch CuSO 4 d th thu c bao nhiu gam kt ta ? A. 19,2 gam B. 32,0 gam C. 23 gam D. 40 gam Cu 6. Hn hp X gm Al2O3, MgO, Fe3O4, CuO. Cho kh CO d qua X nung nng c cht rn Y. Ha Y vo dd NaOH d c dung dch E v cht rn G. Ha tan cht rn G vo dd Cu(NO3)2 d thu c cht rn F. Xc nh thnh phn ca cht rn F. A. Cu B. Cu, Al2O3, MgO, Fe3O4 C. Cu, MgO D. Cu, MgO, Fe3O4 Cu 7. Cho 20 gam hn hp X gm Cu, Fe, v Mg tan hon ton trong dd HNO3 long nng d thu c dung dch Y v 8,96 lt kh NO duy nht (ktc). Cho dung dch NaOH vo dung dch Y n khi kt ta hon ton cc cation kim loi th thu c kt ta Z. Nung kt ta Z n khi lng khng i thu c m gam cht rn l hn hp cc oxit. a/ Xc nh m .A. 23,2 gam B. 26,4 gam C. 29,6 gam D. p n khc. b/ Cho kh CO d i qua m gam hn hp Z nhit cao thu c m1 gam cht rn G v kh CO 2. Hp th hon ton kh CO 2 bng dung dch Ba(OH)2 d thu c 39,4 gam kt ta. Xc nh m 1.A. 28 gam B. 26,4 gam C. 24,8 gam D. 21 Cu 8. Dn kh CO qua 16,0 gam CuO nung nng thu c 14,08 gam cht rn X. Cho X vo dd AgNO3 d thu c m gam kt ta. Bit phn ng ca Cu vi AgNO 3 xy ra hon ton. m l A. 43,2 gam B. 32,32 gam C. 25,92 gam D. 34,56 gam Cu 9. Kh hon ton 14,4 gam mt oxit kim loi (MO) bng CO thu c 0,2 mol CO 2 v m gam kim loi. Cho m gam kim loi vo 400 ml dd AgNO3 1,2M thu c bao nhiu gam kt ta? A. 43,2 gam B. 51,84 gam C. 45,36 gam D. 52,96 gam Cu 10. kh hon ton 2,784 gam mt oxit ca kim loi R bng CO thu c 2,016 gam kim loi R. Hy cho bit oxit l oxit no trong cc oxit sau A. FeO B. CuO C. Fe3O4 D. PbO Cu 11. Kh hon ton m gam hn hp X gm CuO, FeO, Fe 3O4 v ZnO bng CO thu c kh CO2 v hn hp cc kim loi. Hp th hon ton kh CO2 bng nc vi trong thu c 40 gam kt ta. ho tan hon ton m gam hn hp X cn bao nhiu ml dd H2SO4 1M.A. 400 ml B. 500 ml C. 600 ml D. 800 ml

Nguyn Th Hng- THPT Thnh Long

Cu 12. Kh hon ton m gam hn hp X gm CuO, Fe 2O3 v NiO bng CO thu c kh CO2 v hn hp Y gm cc kim loi. Hp th hon ton kh CO 2 bng nc vi trong thu c 50 gam kt ta. Cho hn hp Y tan hon ton trong dung dch H 2SO4 c, nng thu c bao nhiu lt SO2 (ktc) ? A. 11,2 lt B. 13,44 lt C. 8,96 lt D. 10,08 lt Cu 13. Kh hon ton oxit ca kim loi R bng kh CO thu c CO 2 v 7,056 gam kim loi R. Hp th ht kh CO2 bng nc vi trong d thu c 16,8 gam kt ta. Ha tan hon ton 7,056 gam kim loi R trong dd H 2SO4 long d thu c 2,8224 lt H 2 (ktc). Vy cng thc ca oxit kim loi R l: A. Fe3O4 B. CuO C. NiO D. Fe2O3 Cu 14. Cho 5,4 gam Al vo m gam hn hp X gm Fe 2O3 v CuO thu c hn hp Y. Nung hn hp Y nhit cao, sau phn ng hon ton thu c hn hp Z. Ha tan hon ton hn hp Z trong dd HNO3 c, nng d thu c bao nhiu lt NO2 (ktc)? A. 13,44 lt B. 10,08 lt C. 11,2 lt D. 8,96 lt Cu 15. Ag c ln tp cht l Cu. Ha cht no sau y c th dng loi b Cu thu c Ag tinh khit? A. dung dch AgNO3 d. B. dung dch HCl d C. dung dch H2SO4 c, nng d. D. dung dch Cu(NO3)2 d. Cu 16. Ag c ln tp cht l Fe, Cu. Ha cht no sau y c th dng loi b Fe, Cu thu c Ag tinh khit c khi lng ng bng khi lng Ag c trong hh ban u? A. dung dch Fe(NO3)3 d. B. dung dch HCl d C. dung dch H2SO4 c, nng d. D. dung dch AgNO3 d. Cu 17. C mt hn hp gm Cu v Ag. C th s dng phng php no sau y thu c Ag tinh khit? A. cho hn hp vo dung dch AgNO3 d. B. t hn hp bng oxi d sau ha hn hp vo dung dch HCl. C. Cho hn hp vo dung dch mui ca Fe3+ d. D. C A, B, C u ng. O2 du , t 0 cao CO du , t cao Cu 18. Cho s sau: FeS 2 + Fe. Fe2O3 + sn xut c 56 kg Fe cn bao nhiu qung pirit. Bit hiu sut chung ca qu trnh l 80%. A. 187,5 kg. B. 150 kg C. 120 kg D. 96 kg
0

B. IN PHN Cu 1. Hy cho bit dy cc dung dch no sau y khi in phn, pH ca dd gim i. A. NaCl, NaOH, HCl B. NaCl, NaOH, NaNO3 C. Na2SO4, NaOH, HNO3 D. CuSO4, HNO3, AgNO3 Cu 2. Tnh V kh (ktc) thu c khi in phn ht 0,1 mol NaCl trong dd vi in cc tr, mng ngn xp. A. 0,024 lit B. 4,489 lit C. 2,240 lit D. 1,120 lit Cu 3. Trn V lt dd NaOH 1M vi V lt dd HCl 2M thu c dd Y. Tin hnh in phn dd Y vi in cc tr. Hy cho bit pH ca dd thay i nh th no trong qa trnh in phn? A. ban u gim sau khng i. B. pH tng C. pH ban u tng, sau gim. D. pH gim Cu 4. Hy cho bit dy cc dd no sau y khi in phn pH ca dd tng ln. A. Na2SO4, NaCl, HNO3 B. BaCl2, H2SO4, HCl C. NaCl, NaOH, HCl D. NaCl, NaOH, NaNO3 Cu 5. Tin hnh in phn dd X cha HCl, NaCl v CuCl 2 (in cc tr, c mng ngn). Hy cho bit pH ca dung dch thay i nh th no trong qu trnh in phn. (b qua s thay i v th tch dung dch trong qa trnh in phn).

Bi tp n thi i hc ha 12- nm hc 2012-2013

A. pH ban u khng i sau tng. B. pH ban u tng, sau gim C. pH ban u gim sau khng i. D. pH ban u khng i, sau gim. Cu 6. Tin hnh in phn dung dch X cha NaCl a M, CuSO 4 aM, HCl aM c mng ngn. Hy cho bit khi catot bt u c kh thot ra th pH ca dung dch thu c c gi tr trong khong no? B qua s thay i th tch ca dung dch. A. 7 B. <7 C. =7 D. >7 Cu 7. Tin hnh in phn 200 ml dung dch c cha 12,5 gam mui CuSO 4 ngm nc trong bnh in phn vi cc in cc tr vi dng in c cng l I = 9,65A . Khi thi gian in phn c 1000s th catot c kh bay ra. Xc nh cng thc ca mui CuSO4 ngm nc. A. CuSO4. 4H2O B. CuSO4. 5H2O C. CuSO4. 6H2O D. CuSO4. 3H2O Cu 8. Tin hnh mc ni tip 2 bnh in phn: bnh 1: ng 500 ml dung dch CuSO 4 0,1M. bnh 2: ng 500 ml dung dch AgNO 3 0,1M. Hy cho bit nu bnh 1 c 1,6 gam Cu thot ra th khi lng dung dch trong bnh 2 gim bao nhiu gam? A. 5,6 gam B. 5,8 gam C. 6,2 gam D. 5,4 gam Cu 9. Tin hnh in phn 200 ml dd KCl 1M (d=1,15 gam/ml) c mng ngn xp, in cc tr. Tnh C % ca KOH trong dd sau in phn bit rng ti catot thot ra 1,12 lt H2(ktc)? A. 3,658% B. 3,295% C. 2,644% D. 2,474% Cu 10. Tin hnh in phn dung dch Na 2SO4 a M v HCl b M. Hy cho bit pH ca dung dch bin i nh th no trong qu trnh in phn. A. pH ban u tng sau khng i. B. pH ban u tng, sau gim. C. pH ban u gim sau khng i. D. pH ban u khng i, sau gim. Cu 11. Cho cc phng trnh in phn sau, phng trnh no vit sai? A. 4AgNO3 + 2H2O dpdd 4Ag+O2+4HNO3 B. 2MCln dpdd 2M+nCl2 dpdd dpdd C. 4MOHn D. 2CuSO4 + 2H2O 4M+2H2O 2Cu+O2+2HNO3 Cu 12. Dung dch X c cha HCl 1,0M; Fe2(SO4)3 0,05M v CuSO4 0,4M. Tin hnh in phn 400 ml dung dch X bng in cc tr vi dng in c cng I = 7,72A n khi catot thu c 5,12 gam kim loi th dng li. a/ Tnh th tch kh thot ra ti anot. A. 2,24 lt B. 3,36 lt C. 2,8 lt D. 4,48 lt a/ Xc nh thi gian in phn. A. 2000s B. 5000s C. 2500s D. 4000s Cu 13. in phn n ht 0,1mol Cu(NO 3)2 trong dung dch vi in cc tr, th sau in phn khi lng dung dch gim bao nhiu gam? A. 6,4gam B. 1,6gam C. 18,8gam D. 8,0 gam Cu 14. Hy cho bit dy cc dd no sau y khi in phn, pH ca dd khng i. A. BaCl2, HCl B. NaCl, NaOH C. H2SO4, CuCl2 D. Na2SO4, NaNO3 Cu 15. Trong cng nghip, ngi ta tin hnh iu ch Cl2 bng phng php in phn dung dch NaCl c mng ngn. Tnh thi gian cn in phn iu ch c 22,4 lt Cl2 bng dng in c cng I= 9,65A. A. 5.000s B. 10.000s C. 40.000s D. 20.000s Cu 16. Phn ng iu ch kim loi no di y khng thuc pp nhit luyn? A. Zn + CuSO4 ZnSO4 + Cu B. HgS + O2 Hg + SO2 C. 2Al + Cr2O3 2Cr + Al2O3 D. 3CO + Fe2O3 2Fe + 3CO2 Cu 17. Cho dng in 3A i qua mt dd ng (II) nitrat trong 1 gi th lng ng kt ta trn catot l bao nhiu gam? A. 9,1gam B. 3,18gam C. 3,58gam D. 7,12gam

Cu 18: Dy gm cc kim loi c iu ch trong cng nghip bng phng php in phn nng chy hp cht ca chng l : A. Na, Ca, Zn B. Na, Cu, Al C. Na, Ca, Al D. Fe, Ca, Al Cu 19: Cho kh CO i vo ng s nung nng ng hh X gm Al 2O3, MgO, Fe3O4, CuO thu c cht rn Y. Cho Y vo dd NaOH d thu c phn khng tan Z. Gi s cc jphn ng xy ra hon ton. Phn khng tan Z l: A. MgO, Fe, Cu B. Mg, Fe, Cu C. MgO, Fe 3O4, Cu D. Mg, Al, Fe, Cu Cu 20: kh ion kim loi Cu 2+ trong dd CuSO4 c th dng kim loi A. Fe B. Na C. K D. Ba Cu 21: in phn dd cha a mol CuSO 4 v b mol NaCl vi in cc tr( c mng ngn xp ). dd sau in phn lm phenolphtalein chuyn sang mu hng th iu kin ca a v b l (bit ion SO 42khng b in phn trong dung dch) A. b<2a B. b=2a C. b>2a D. 2b= a Cu 22 Tin hnh in phn dung dch X cha NaCl a M, CuSO4 0,5aM, HCl aM c mng ngn. Hy cho bit pH ca dung dchqu trnh in phn thay i nh th no? A. ban u gim, sau mt thi gian khng i v sau li tng B. ban u tng, sau mt thi gian khng i v sau li tip tc tng. C. ban u khng i, sau mt thi gian tng v tip tc khng thay i. D. ban u khng i, sau mt thi gian gim v tip tc khng i. Cu 23 in phn dung dch CuCl2 bng in cc tr trong 1 gi vi cng dng in 5 ampe. Khi lng ng gii phng catt l bao nhiu gam? A. 5,97gam B. 7,52gam C. 7,94gam D. 5,56gam Cu 24 in phn (in cc tr) dung dch cha 0,02mol CuSO 4 vi cng dng in 5A trong 6 pht 26 giy. Khi lng catot tng ln bao nhiu gam? A. 2,56gam B. 0,64gam C. 1,28gam D. 0,16gam p n: Phn A: 1D,2A, 3B, 4D, 5C, 6C; 6C; 7-C, 7b-B; 8B; 9B; 10C; 11A ; 12A ; 13A; 14A; 15A; 16A; 17D; 18B Phn B: C 1 2 3 4 5 6 7 8 9 10 11 12 u A D C B C A B B B D A C A-C C 13 14 15 16 17 18 19 20 21 22 23 24 u a D D D A C C A A C C A B

Nguyn Th Hng- THPT Thnh Long

BT Tng hp 1. in phn dung dch CuSO 4 vi anot bng Cu, nhn thy mu xanh ca dung dch khng thay i l do: A. S in phn khng xy ra B. Thc cht l s in phn nc C. ng va to ra catot li tan ngay

Bi tp n thi i hc ha 12- nm hc 2012-2013

D. Lng ng bm vo catot bng lng ng tan ra anot nh in phn 2. in phn dung dch NiSO4 2M trong thi gian v cng dng in nh nhau trong 2 trng hp: (a) Dng hai in cc tr (b) Dng 2 in cc l Niken. Hin tng thu c trong 2 trng hp l: A. Ging nhau v bn cht in cc khng nh hng n sn phm in phn. B. Trng hp (b) anot b ho tan, khi lng ca catot trong trng hp (a) v (b) u tng ln. C. Trng hp (b), catot b ho tan, khi lng ca anot trng hp (a) v (b) u tng. D. Ging nhau. u c kh thot ra anot, khi lng catot u tng. 3. Mun m ng ln mt vt bng st (vt X) chng g v tng v sng p, nn dng phng php: A. Ngm vt trong CuSO4. B. in phn vi catot l X, anot l Cu, dung dch in phn l CuSO4. C. in phn vi catot l Cu, anot l X, dung dch in phn l CuSO4. D. C A v B. 4. in phn dung dch cha HCl a mol/l; CuCl 2 a mol/l; NaCl a mol/l vi in cc tr c mng ngn. Nhn tng qut s thay i pH ca dung dch trong qu trnh in phn l: A. Tng dn. B. Gim dn. C. Lc u tng, sau gim dn. D. Lc u gim, sau tng dn. 5. in phn dung dch hn hp FeCl 3, CuCl2, CaCl2, NaNO3. Kim loi u tin thot ra catot l:A. Fe B. Cu C. Ca D. Na 6. in phn dd CuSO 4 vi anot l thanh ng cha cc tp cht Fe, Zn, Ag, Au, Pt. 1) Cht thu c anot l: A. Ag, Zn, Fe, Au B. Ag, Zn, Pt C. Ag, Au, Pt D. Au, Fe, Pt 2) Cc na phn ng xy ra anot, catot tng ng ln lt l: A. Anot: Cu Cu2++2e catot: Cu2+ + 2e Cu 2+ 2+ B. Anot: Fe Fe +2e ; Cu Cu +2e ; Au Au3++3e 2+ catot: Cu + 2e Cu C. Anot: Zn Zn2++2e ; Fe Fe2++2e ; Cu Cu2++2e catot: Cu2+ + 2e Cu D. Anot: Zn Zn2++2e ; Cu Cu2++2e; Ag Ag++1e 2+ catot: Cu + 2e Cu 7. Dung dch X cha cc mui NaCl, CuCl2, FeCl3, ZnCl2. Th t in phn catot X l: A. Fe3+, Cu2+, Zn2+, H2O B. Fe3+, Cu2+, Fe2+, Zn2+, H2O 3+ 2+ 2+ 2+ C. Fe , Cu , H2O, Fe , Zn D. Fe3+, Cu2+, Fe2+, Zn2+, H2O, Na+ 8. in phn dd cha a mol CuSO 4 v b mol NaCl vi in cc tr, mng ngn xp. dd thu c sau in phn lm qu tm chuyn mu th iu kin ca a v b l:

A. a = 2b B. a > 2b C. a < 2b D. a < 2b hoc a > 2b 9. in phn nng chy hon ton 14,9 gam mui clorua ca kim loi ho tr I thu c 2,24 lt kh (ktc) anot. Kim loi l: A. Li B. Na C. K D. Rb 10. in phn dung dch Cu(NO 3)2 in cc tr, vi cng dng in 9,65A n khi catot bt u c kh thot ra. Thi gian in phn l 40 pht. Khi lng Cu thot ra l: A. 6,68 gam B. 7,68 gam C. 8,68 gam D. 8,86 gam 11. in phn dung dch AgNO3 in cc tr cho n khi dung dch thu c c pH=3 th dng li (khi tin hnh in phn c 80% lng AgNO3 cho). Th tch dung dch coi nh khng thay i ( 1 lt). Nng cc cht trong dung dch thu c sau khi ngng in phn v khi lng AgNO3 ban u l: A. [AgNO3 ] = [HNO3 ] = 10-3M; mAgNO3 = 0,17 gam B. [AgNO3 ] = 2,5.10-3M; [HNO3 ] = 10-3M; mAgNO3 = 0,2125 gam C. [AgNO3 ] = 0,125M ; [HNO3 ] = 10-3M; mAgNO3 = 0,2125 gam D. [AgNO3 ] = 2,5.10-4; [HNO3 ] = 10-3M; mAgNO3 = 0,2125 gam 12. in phn 400 ml dung dch CuSO 4 6% (d=1,02 g/ml) vi in cc tr cho n khi khi lng dung dch gim 10 gam. Khi lng Cu thot ra anot l: A. 10 gam B. 8 gam C. 2 gam D. 0 gam 13. in phn nng chy mui clorua kim loi kim thu c 0,896 lt kh (ktc) anot v 3,12 gam kim loi catot. Cng thc mui l: A. LiCl B. NaCl C. KCl D. RbCl 14. in phn dung dch Cu(NO3)2 in cc tr, vi cng 9,65A. n khi catot bt u thot kh th dng li, thi gian in phn l 60 pht. Khi lng kim loi sinh ra catot l: A. 11,520 gam B. 13,005 gam C. 9,600 gam D. 4,800 gam 15. in phn dung dch Cu(NO 3)2 in cc tr, trong thi gian 1930 giy, thu c 9,6 gam Cu catot. Cng dng in trong qu trnh in phn l: A. 15A B. 22,5A C. 7,5A D.1,5A 16. in phn in cc tr, mng ngn xp 1 lt dd X cha 0,01 mol CuCl2, 0,01 mol HCl v 0,01 mol NaCl. Khi anot thot ra 0,336 lt kh (ktc) th ngng in phn. dd trong bnh in phn c pH l: A. 2,0 B. 2,3 C. 7,0 D. 12,0 17. in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,64 gam kim loi catot v mt lng kh X anot. Hp th hon ton lng kh trn vo 200 ml dung dch NaOH nhit thng. Sau phn ng nng NaOH cn li l 0,05M. Gi thit th tch dung dch khng thay i. Nng ban u ca NaOH l: A. 0,15M B. 0,2M C. 0,1M D. 0,05M 18. in phn dung dch cha m gam hn hp CuSO 4, NaCl vi in cc tr,mng ngn xp cho n khi nc bt u in phn c 2 in cc th dng li anot thu c 0,672 lt kh (ktc). Dung dch

Nguyn Th Hng- THPT Thnh Long

Bi tp n thi i hc ha 12- nm hc 2012-2013

thu c sau in phn ho tan ti a c 1,02 gam Al2O3. Gi tr ca m l:A. 6,710 hoc 8,955 B. 5,710 hoc 7,955 C. 4,710 hoc 6,955 D. 3,710 hoc 5,955 19. in phn dung dch cha 0,02 mol FeSO4 v 0,06 mol HCl vi I=1,34A trong 2 gi(in cc tr, mng ngn). B qua s ho tan ca clo trong nc, coi hiu sut in phn 100%. Khi lng kim loi thot ra catot v th tch kh (ktc) thot ra anot l: A. 11,2 g v 8,96 lt B. 1,12 g v 0,896 lt C. 5,6 g v 4,48 lt D. 0,56 g v 0,448 lt 20. Dung dch X cha HCl, CuSO4, Fe2(SO4)3. Ly 400 ml dung dch X em in phn in cc tr vi I = 7,72A n khi catot c 0,08 mol Cu th dng li. Khi anot c 0,1 mol mt cht kh bay ra. Thi gian in phn v nng mol/l ca Fe 2+ ln lt l (coi th tch dung dch thay i khng ng k): A. 2.300 s v 0,1M B. 2.500s v 0,1M C. 2.300s v 0,15M D. 2.500s v 0,15M 21. in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,32 gam Cu catot v mt lng kh X anot. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH nhit thng. Sau phn ng nng NaOH cn li l 0,05 mol. Gi thit th tch dung dch khng thay i. Nng ban u ca NaOH l: A. 0,15M B. 0,2M C. 0,1M D. 0,05M 22. in phn 100 ml dung dch cha NaCl vi in cc tr, c mng ngn vi cng dng in l 1,93A. Th tch dung dch in phn coi nh khng i, hiu sut in phn = 100%. Thi gian in phn l bao nhiu thu c dung dch c pH = 12 l: A. 100s B. 50s C. 150s D. 200s 23. H khi A 2012 in phn 150 ml dung dch AgNO 3 1M vi in cc tr trong t gi, cng dng in khng i 2,68A (hiu sut qu trnh in phn l 100%), thu c cht rn X, dung dch Y v kh Z. Cho 12,6 gam Fe vo Y, sau khi cc phn ng kt thc thu c 14,5 gam hn hp kim loi v kh NO (sn phm kh duy nht ca N+5). Gi tr ca t l: A. 0,8. B. 0,3. C. 1,0. D. 1,2. 24. H khi B 2012 in phn dung dch hn hp gm 0,1 mol FeCl 3, 0,2 mol CuCl2 v 0,1 mol HCl (in cc tr). Khi catot bt u thot kh th anot thu c V lt kh (ktc). Bit hiu sut ca qu trnh in phn l 100%. Gi tr ca V l: A. 5,60. B. 11,20. C. 22,40. D. 4,48. 25. C 2012 Tin hnh in phn (vi in cc tr) V lt dung dch CuCl2 0,5M. Khi dng in phn thu c dung dch X v 1,68 lt kh Cl2 (ktc) duy nht anot. Ton b dung dch X tc dng va vi 12,6 gam Fe. Gi tr ca V l : A. 0,15. B. 0,60. C. 0,45. D. 0,80.

26. H Khi A nm 2010 in phn vi in cc tr mt dung dch gm NaCl v CuSO 4 c cng s mol n khi catot xut hin bt kh th dng in phn. Trong c qu trnh in phn trn, sn phm thu c anot l: A. Kh Cl2 v H2 B. Kh Cl2 v O2 C. Ch c kh Cl2 D. Kh H2 v O2 27. H Khi A nm 2010 in phn vi in cc tr mt dung dch X cha 0,2 mol CuSO 4 v 0,12 mol NaCl bng dng in c cng 2A. Th tch kh (ktc) thot ra anot sau 9650 giy in phn l: A. 1,344 lt B. 2,240 lt C. 1,792 lt D. 2,912 lt 28. H Khi B nm 2010 in phn (vi in cc tr) 200 ml dung dch CuSO4 nng x mol/l, sau mt thi gian thu c dung dch Y vn cn mu xanh, c khi lng gim 8 gam so vi dung dch ban u. Cho 16,8 gam bt Fe vo Y, sau khi cc phn ng xy ra hon ton thu c 12,4 gam kim loi. Gi tr ca x l: A. 2,25 B. 1,50 C. 1,25 D. 3,25 29. H khi B nm 2009 in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl 2 0,1M v NaCl 0,5M(in cc tr, hiu sut 100%) vi cng dng in 5A trong 3860 giy. Dung dch thu c sau in phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l: A. 4,05 B. 2,70 C. 1,35 D. 5,40 30. H khi A-2007 Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, ZnO, MgO nung nhit cao.Sau phn ng hn hp rn cn li l: A. Cu, FeO, ZnO, MgO. B. Cu, Fe, Zn, Mg. C. Cu, Fe, Zn, MgO. D. Cu, Fe, ZnO, MgO. 31. Kh ht 6,4 gam MxOy , thy cn 2,688 lt CO (kc. Cng thc ca oxit l A. CuO B. FeO C. Fe2O3 D. Cr2O3 32. Dn CO d qua ng s nung nng cha 21,6 g hn hp: MgO, Fe 3O4 . Sau p thu c m gam rn v hh kh. Dn ht kh vo dd Ca(OH) 2 d , thy c 14 gam kt ta. Tnh m? A. 19,36g B. 10,80g C. 13,48g D. 13,96g 33. Dn CO d qua ng s nung nng cha 21,6 g hn hp: CuO, Fe 2O3 . Sau mt thi gian thu c m gam rn v hh kh. Dn ht kh vo dd Ca(OH)2 d , thy c 14 gam kt ta. Tnh m? A. 19,36g B. 10,80g C. 13,48g D. 13,96g 34. Trn 2,7 gam Al vi 2,4 gam Fe 2O3 ri nung nng thc hin phn ng nhit nhm. Sau phn ng ta thu c m gam hn hp cht rn. Gi tr ca m l A. 1,12g B. 2,04g C. 5,1g D. 10,2g 35. Cho 12,8 gam hn hp bt Fe v oxit st ha tan vo dung dch axit HCl thy c 0,224 lt H2 (ktc) thot ra. Mt khc ly 6,4 gam hn

Nguyn Th Hng- THPT Thnh Long

Bi tp n thi i hc ha 12- nm hc 2012-2013

hp trn em kh bng H 2 thy c 5,6 gam cht rn. CT ca oxit st l: A. Fe2O3 B. FeO C. Fe3O4 D. FexOy 36. H khi B-2007 Nung hn hp bt gm 15,2 gam Cr2O3 v m gam Al nhit cao. Sau khi phn ng hon ton thu c 13,3 gam hn hp rn X. Cho ton b hn hp X phn ng vi dung dch HCl d thy thot ra V lt H2 (ktc). Gi tr ca V l: A. 4,48 lt B. 3,36 lt C. 7,84 lt D. 10,08 lt 37. H khi B-2007 Thc hin phn ng nhit nhm vi hn hp X cha Al v Fe2O3 (hai cht ny phn ng vi nhau va ) ta thu c mt cht rn B nng 214 gam. B tc dng vi dung dch NaOH d li mt cht rn duy nht nng 112gam. Khi lng Al ban u c trong hn hp X l A. 54g B. 42g C. 27g D. 48g 38 H khi A-2008 Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c khng kh) n khi phn ng xy ra hon ton , thu c hn hp rn Y. Chia Y ta thnh hai phn bng nhau: - Phn 1 tc dng vi dd H 2SO4 long ( d) sinh ra 3,08 lt kh H2 ( ktc). - Phn 2 tc dng vi dd NaOH (d) , sinh ra 0,84 lt kh H2 ( ktc). Gi tr ca m l A. 22,75 B. 21,40 C. 29,40 D. 29,43 39.H khi A-2008 Cho V lt hn hp kh ( ktc) gm CO v H 2 phn ng vi mt lng d hn hp rn gm CuO v Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr ca V l: A. 0,448. B. 0,112. C. 0,224. D. 0,560. 40C-2007 Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit st n khi phn ng xy ra hon ton. Kh thu c sau phn ng c t khi so vi hiro bng 20. Cng thc ca oxit st v phn trm th tch ca kh CO 2 trong hn hp kh sau phn ng l A. FeO; 75%. B. Fe2O3; 75%. C. Fe2O3; 65%. D. Fe3O4; 75%. 41. -2007 Khi cho 41,4 gam hn hp X gm Fe 2O3, Cr2O3 v Al2O3 tc dng vi dd NaOH c (d), sau phn ng thu c cht rn c khi lng 16 gam. kh hon ton 41,4 gam X bng phn ng nhit nhm, phi dng 10,8 gam Al. Thnh phn phn trm theo khi lng ca Cr2O3 trong hn hp X l (Cho: H cc phn ng l 100%) A. 50,67%. B. 20,33%. C. 66,67%. D. 36,71%. 42. CD-2008 Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn hp rn gm CuO, Fe 2O3 ( nhit cao). Sau khi cc phn ng xy ra hon ton, thu c kh X. Dn ton b kh X trn vo lng d dung dch Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l A. 1,120 B. 0,896 C. 0,448 D. 0,224

43. C-2007 t nng mt hn hp gm Al v 16 gam Fe 2O3 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng va vi V ml dung dch NaOH 1M sinh ra 3,36 lt H2 ( ktc). Gi tr ca V l A. 100 B. 150 C. 200 D. 300 44. H khi B 2012 Dn lung kh CO i qua hn hp gm CuO v Fe2O3 nung nng, sau mt thi gian thu c cht rn X v kh Y. Cho Y hp th hon ton vo dung dch Ba(OH) 2 d, thu c 29,55 gam kt ta. Cht rn X phn ng vi dung dch HNO3 d thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 2,24. B. 4,48. C. 6,72. D. 3,36. 45. H Khi B nm 2010 Kh hon ton m gam oxit MxOy cn va 17,92 lt kh CO (ktc) thu c a gam kim loi M. Ho tan a gam M bng dung dch H2SO4 c nng d thu c 20,16 lt SO2 (sn phm kh duy nht, ktc). Oxit M xOy l: A. Cr2O3 B. FeO C. Fe3O4 D. CrO

Nguyn Th Hng- THPT Thnh Long

IU CH KIM LOI A. NHIT LUYN Cu 1. Hy cho bit dy cc kim loi no sau y c th c iu ch bng cch cho CO kh oxit kim loi nhit cao ? A. Fe, Cu, Al, Ag B. Mg, Fe, Zn v Cu C. Ca, Cu. Fe v Sn D. Cu, Ni, Pb v Fe Cu 2. Tin hnh kh hon ton m gam oxit kim loi MO bng kh CO d thu c 7,2 gam kim loi M, kh CO2 thot ra hp th hon ton trong nc vi trong d, thu c 11,25 gam kt ta. Vy cng thc ca oxit l: A. CuO B. FeO C. PbO D. ZnO Cu 3. Dn kh CO d qua hn hp X gm 0,1 mol Fe 3O4 ; 0,15 mol CuO v 0,1 mol MgO sau cho ton b cht rn sau phn ng vo dung dch H 2SO4 long d. Tnh th tch kh thot ra(ktc). A. 5,6 lt B. 6,72 lt C. 10,08 lt D. 13,44 lt Cu 4. Nung hn hp gm Fe3O4, CuO v Al nhit cao, sau phn ng hon ton cho phn rn vo dung dch NaOH thy c kh H2 bay ra. Hy cho bit kt lun no sau y ng : A. Al d, Fe3O4 ht B. Al, Fe3O4, CuO u d. C. Al d, Fe3O4 d, CuO ht D. Al d, Fe3O4 v CuO ht

Bi tp n thi i hc ha 12- nm hc 2012-2013

Cu 5. Cho kh H2 d i qua hn hp X gm 0,05 mol CuO; 0,05 mol Fe3O4 v 0,1 mol Al2O3 cho cht rn sau phn ng vo dung dch CuSO 4 d th thu c bao nhiu gam kt ta ? A. 19,2 gam B. 32,0 gam C. 23 gam D. 40 gam Cu 6. Hn hp X gm Al2O3, MgO, Fe3O4, CuO. Cho kh CO d qua X nung nng c cht rn Y. Ha Y vo dd NaOH d c dung dch E v cht rn G. Ha tan cht rn G vo dd Cu(NO3)2 d thu c cht rn F. Xc nh thnh phn ca cht rn F. A. Cu B. Cu, Al2O3, MgO, Fe3O4 C. Cu, MgO D. Cu, MgO, Fe3O4 Cu 7. Cho 20 gam hn hp X gm Cu, Fe, v Mg tan hon ton trong dd HNO3 long nng d thu c dung dch Y v 8,96 lt kh NO duy nht (ktc). Cho dung dch NaOH vo dung dch Y n khi kt ta hon ton cc cation kim loi th thu c kt ta Z. Nung kt ta Z n khi lng khng i thu c m gam cht rn l hn hp cc oxit. a/ Xc nh m .A. 23,2 gam B. 26,4 gam C. 29,6 gam D. p n khc. b/ Cho kh CO d i qua m gam hn hp Z nhit cao thu c m1 gam cht rn G v kh CO 2. Hp th hon ton kh CO 2 bng dung dch Ba(OH)2 d thu c 39,4 gam kt ta. Xc nh m 1.A. 28 gam B. 26,4 gam C. 24,8 gam D. 21 Cu 8. Dn kh CO qua 16,0 gam CuO nung nng thu c 14,08 gam cht rn X. Cho X vo dd AgNO3 d thu c m gam kt ta. Bit phn ng ca Cu vi AgNO 3 xy ra hon ton. m l A. 43,2 gam B. 32,32 gam C. 25,92 gam D. 34,56 gam Cu 9. Kh hon ton 14,4 gam mt oxit kim loi (MO) bng CO thu c 0,2 mol CO 2 v m gam kim loi. Cho m gam kim loi vo 400 ml dd AgNO3 1,2M thu c bao nhiu gam kt ta? A. 43,2 gam B. 51,84 gam C. 45,36 gam D. 52,96 gam Cu 10. kh hon ton 2,784 gam mt oxit ca kim loi R bng CO thu c 2,016 gam kim loi R. Hy cho bit oxit l oxit no trong cc oxit sau A. FeO B. CuO C. Fe3O4 D. PbO Cu 11. Kh hon ton m gam hn hp X gm CuO, FeO, Fe 3O4 v ZnO bng CO thu c kh CO2 v hn hp cc kim loi. Hp th hon ton kh CO2 bng nc vi trong thu c 40 gam kt ta. ho tan hon ton m gam hn hp X cn bao nhiu ml dd H2SO4 1M.A. 400 ml B. 500 ml C. 600 ml D. 800 ml Cu 12. Kh hon ton m gam hn hp X gm CuO, Fe 2O3 v NiO bng CO thu c kh CO2 v hn hp Y gm cc kim loi. Hp th hon ton kh CO 2 bng nc vi trong thu c 50 gam kt ta. Cho hn hp Y tan hon ton trong dung dch H 2SO4 c, nng thu c bao nhiu lt SO2 (ktc) ? A. 11,2 lt B. 13,44 lt C. 8,96 lt D. 10,08 lt Cu 13. Kh hon ton oxit ca kim loi R bng kh CO thu c CO 2 v 7,056 gam kim loi R. Hp th ht kh CO2 bng nc vi trong d thu c 16,8 gam kt ta. Ha tan hon ton 7,056 gam kim loi R trong dd H 2SO4 long d thu c 2,8224 lt H 2 (ktc). Vy cng thc ca oxit kim loi R l: A. Fe3O4 B. CuO C. NiO D. Fe2O3 Cu 14. Cho 5,4 gam Al vo m gam hn hp X gm Fe 2O3 v CuO thu c hn hp Y. Nung hn hp Y nhit cao, sau phn ng hon ton thu c hn hp Z. Ha tan hon ton hn hp Z trong dd HNO3 c, nng d thu c bao nhiu lt NO2 (ktc)? A. 13,44 lt B. 10,08 lt C. 11,2 lt D. 8,96 lt Cu 15. Ag c ln tp cht l Cu. Ha cht no sau y c th dng loi b Cu thu c Ag tinh khit? A. dung dch AgNO3 d. B. dung dch HCl d

Nguyn Th Hng- THPT Thnh Long

C. dung dch H2SO4 c, nng d. D. dung dch Cu(NO3)2 d. Cu 16. Ag c ln tp cht l Fe, Cu. Ha cht no sau y c th dng loi b Fe, Cu thu c Ag tinh khit c khi lng ng bng khi lng Ag c trong hh ban u? A. dung dch Fe(NO3)3 d. B. dung dch HCl d C. dung dch H2SO4 c, nng d. D. dung dch AgNO3 d. Cu 17. C mt hn hp gm Cu v Ag. C th s dng phng php no sau y thu c Ag tinh khit? A. cho hn hp vo dung dch AgNO3 d. B. t hn hp bng oxi d sau ha hn hp vo dung dch HCl. C. Cho hn hp vo dung dch mui ca Fe3+ d. D. C A, B, C u ng. O2 du , t 0 cao CO du , t cao Cu 18. Cho s sau: FeS 2 + Fe. Fe2O3 + sn xut c 56 kg Fe cn bao nhiu qung pirit. Bit hiu sut chung ca qu trnh l 80%. A. 187,5 kg. B. 150 kg C. 120 kg D. 96 kg
0

B. IN PHN Cu 1. Hy cho bit dy cc dung dch no sau y khi in phn, pH ca dd gim i. A. NaCl, NaOH, HCl B. NaCl, NaOH, NaNO3 C. Na2SO4, NaOH, HNO3 D. CuSO4, HNO3, AgNO3 Cu 2. Tnh V kh (ktc) thu c khi in phn ht 0,1 mol NaCl trong dd vi in cc tr, mng ngn xp. A. 0,024 lit B. 4,489 lit C. 2,240 lit D. 1,120 lit Cu 3. Trn V lt dd NaOH 1M vi V lt dd HCl 2M thu c dd Y. Tin hnh in phn dd Y vi in cc tr. Hy cho bit pH ca dd thay i nh th no trong qa trnh in phn? A. ban u gim sau khng i. B. pH tng C. pH ban u tng, sau gim. D. pH gim Cu 4. Hy cho bit dy cc dd no sau y khi in phn pH ca dd tng ln. A. Na2SO4, NaCl, HNO3 B. BaCl2, H2SO4, HCl C. NaCl, NaOH, HCl D. NaCl, NaOH, NaNO3 Cu 5. Tin hnh in phn dd X cha HCl, NaCl v CuCl 2 (in cc tr, c mng ngn). Hy cho bit pH ca dung dch thay i nh th no trong qu trnh in phn. (b qua s thay i v th tch dung dch trong qa trnh in phn). A. pH ban u khng i sau tng. B. pH ban u tng, sau gim C. pH ban u gim sau khng i. D. pH ban u khng i, sau gim. Cu 6. Tin hnh in phn dung dch X cha NaCl a M, CuSO 4 aM, HCl aM c mng ngn. Hy cho bit khi catot bt u c kh thot ra th pH ca dung dch thu c c gi tr trong khong no? B qua s thay i th tch ca dung dch. A. 7 B. <7 C. =7 D. >7 Cu 7. Tin hnh in phn 200 ml dung dch c cha 12,5 gam mui CuSO 4 ngm nc trong bnh in phn vi cc in cc tr vi dng in c cng l I = 9,65A . Khi thi gian in phn c 1000s th catot c kh bay ra. Xc nh cng thc ca mui CuSO4 ngm nc. A. CuSO4. 4H2O B. CuSO4. 5H2O C. CuSO4. 6H2O D. CuSO4. 3H2O Cu 8. Tin hnh mc ni tip 2 bnh in phn: bnh 1: ng 500 ml dung dch CuSO 4 0,1M. bnh 2: ng 500 ml dung dch AgNO3 0,1M. Hy cho bit nu bnh 1 c 1,6 gam Cu thot ra th khi lng dung dch trong bnh 2 gim bao nhiu gam? A. 5,6 gam B. 5,8 gam C. 6,2 gam D. 5,4 gam

Bi tp n thi i hc ha 12- nm hc 2012-2013

Cu 9. Tin hnh in phn 200 ml dd KCl 1M (d=1,15 gam/ml) c mng ngn xp, in cc tr. Tnh C % ca KOH trong dd sau in phn bit rng ti catot thot ra 1,12 lt H2(ktc)? A. 3,658% B. 3,295% C. 2,644% D. 2,474% Cu 10. Tin hnh in phn dung dch Na 2SO4 a M v HCl b M. Hy cho bit pH ca dung dch bin i nh th no trong qu trnh in phn. A. pH ban u tng sau khng i. B. pH ban u tng, sau gim. C. pH ban u gim sau khng i. D. pH ban u khng i, sau gim. Cu 11. Cho cc phng trnh in phn sau, phng trnh no vit sai? A. 4AgNO3 + 2H2O dpdd 4Ag+O2+4HNO3 B. 2MCln dpdd 2M+nCl2 dpdd dpdd C. 4MOHn 4M+2H O D. 2CuSO + 2H O 2Cu+O2+2HNO3 2 4 2 Cu 12. Dung dch X c cha HCl 1,0M; Fe2(SO4)3 0,05M v CuSO4 0,4M. Tin hnh in phn 400 ml dung dch X bng in cc tr vi dng in c cng I = 7,72A n khi catot thu c 5,12 gam kim loi th dng li. a/ Tnh th tch kh thot ra ti anot. A. 2,24 lt B. 3,36 lt C. 2,8 lt D. 4,48 lt a/ Xc nh thi gian in phn. A. 2000s B. 5000s C. 2500s D. 4000s Cu 13. in phn n ht 0,1mol Cu(NO 3)2 trong dung dch vi in cc tr, th sau in phn khi lng dung dch gim bao nhiu gam? A. 6,4gam B. 1,6gam C. 18,8gam D. 8,0 gam Cu 14. Hy cho bit dy cc dd no sau y khi in phn, pH ca dd khng i. A. BaCl2, HCl B. NaCl, NaOH C. H2SO4, CuCl2 D. Na2SO4, NaNO3 Cu 15. Trong cng nghip, ngi ta tin hnh iu ch Cl2 bng phng php in phn dung dch NaCl c mng ngn. Tnh thi gian cn in phn iu ch c 22,4 lt Cl2 bng dng in c cng I= 9,65A. A. 5.000s B. 10.000s C. 40.000s D. 20.000s Cu 16. Phn ng iu ch kim loi no di y khng thuc pp nhit luyn? A. Zn + CuSO4 ZnSO4 + Cu B. HgS + O2 Hg + SO2 C. 2Al + Cr2O3 2Cr + Al2O3 D. 3CO + Fe2O3 2Fe + 3CO2 Cu 17. Cho dng in 3A i qua mt dd ng (II) nitrat trong 1 gi th lng ng kt ta trn catot l bao nhiu gam? A. 9,1gam B. 3,18gam C. 3,58gam D. 7,12gam Cu 18: Dy gm cc kim loi c iu ch trong cng nghip bng phng php in phn nng chy hp cht ca chng l : A. Na, Ca, Zn B. Na, Cu, Al C. Na, Ca, Al D. Fe, Ca, Al Cu 19: Cho kh CO i vo ng s nung nng ng hh X gm Al 2O3, MgO, Fe3O4, CuO thu c cht rn Y. Cho Y vo dd NaOH d thu c phn khng tan Z. Gi s cc jphn ng xy ra hon ton. Phn khng tan Z l: A. MgO, Fe, Cu B. Mg, Fe, Cu C. MgO, Fe 3O4, Cu D. Mg, Al, Fe, Cu Cu 20: kh ion kim loi Cu 2+ trong dd CuSO4 c th dng kim loi A. Fe B. Na C. K D. Ba Cu 21: in phn dd cha a mol CuSO 4 v b mol NaCl vi in cc tr( c mng ngn xp ). dd sau in phn lm phenolphtalein

Nguyn Th Hng- THPT Thnh Long

chuyn sang mu hng th iu kin ca a v b l (bit ion SO 42khng b in phn trong dung dch) A. b<2a B. b=2a C. b>2a D. 2b= a Cu 22 Tin hnh in phn dung dch X cha NaCl a M, CuSO4 0,5aM, HCl aM c mng ngn. Hy cho bit pH ca dung dchqu trnh in phn thay i nh th no? A. ban u gim, sau mt thi gian khng i v sau li tng B. ban u tng, sau mt thi gian khng i v sau li tip tc tng. C. ban u khng i, sau mt thi gian tng v tip tc khng thay i. D. ban u khng i, sau mt thi gian gim v tip tc khng i. Cu 23 in phn dung dch CuCl2 bng in cc tr trong 1 gi vi cng dng in 5 ampe. Khi lng ng gii phng catt l bao nhiu gam? A. 5,97gam B. 7,52gam C. 7,94gam D. 5,56gam Cu 24 in phn (in cc tr) dung dch cha 0,02mol CuSO 4 vi cng dng in 5A trong 6 pht 26 giy. Khi lng catot tng ln bao nhiu gam? A. 2,56gam B. 0,64gam C. 1,28gam D. 0,16gam BT Tng hp 1. in phn dung dch CuSO 4 vi anot bng Cu, nhn thy mu xanh ca dung dch khng thay i l do: A. S in phn khng xy ra B. Thc cht l s in phn nc C. ng va to ra catot li tan ngay D. Lng ng bm vo catot bng lng ng tan ra anot nh in phn 2. in phn dung dch NiSO4 2M trong thi gian v cng dng in nh nhau trong 2 trng hp: (a) Dng hai in cc tr (b) Dng 2 in cc l Niken. Hin tng thu c trong 2 trng hp l: A. Ging nhau v bn cht in cc khng nh hng n sn phm in phn. B. Trng hp (b) anot b ho tan, khi lng ca catot trong trng hp (a) v (b) u tng ln. C. Trng hp (b), catot b ho tan, khi lng ca anot trng hp (a) v (b) u tng. D. Ging nhau. u c kh thot ra anot, khi lng catot u tng. 3. Mun m ng ln mt vt bng st (vt X) chng g v tng v sng p, nn dng phng php: A. Ngm vt trong CuSO4. B. in phn vi catot l X, anot l Cu, dung dch in phn l CuSO4. C. in phn vi catot l Cu, anot l X, dung dch in phn l CuSO4. D. C A v B. 4. in phn dung dch cha HCl a mol/l; CuCl 2 a mol/l; NaCl a mol/l vi in cc tr c mng ngn. Nhn tng qut s thay i pH ca dung dch trong qu trnh in phn l: A. Tng dn. B. Gim dn.

Bi tp n thi i hc ha 12- nm hc 2012-2013

C. Lc u tng, sau gim dn. D. Lc u gim, sau tng dn. 5. in phn dung dch hn hp FeCl 3, CuCl2, CaCl2, NaNO3. Kim loi u tin thot ra catot l:A. Fe B. Cu C. Ca D. Na 6. in phn dd CuSO 4 vi anot l thanh ng cha cc tp cht Fe, Zn, Ag, Au, Pt. 1) Cht thu c anot l: A. Ag, Zn, Fe, Au B. Ag, Zn, Pt C. Ag, Au, Pt D. Au, Fe, Pt 2) Cc na phn ng xy ra anot, catot tng ng ln lt l: A. Anot: Cu Cu2++2e catot: Cu2+ + 2e Cu 2+ 2+ B. Anot: Fe Fe +2e ; Cu Cu +2e ; Au Au3++3e 2+ catot: Cu + 2e Cu C. Anot: Zn Zn2++2e ; Fe Fe2++2e ; Cu Cu2++2e catot: Cu2+ + 2e Cu D. Anot: Zn Zn2++2e ; Cu Cu2++2e; Ag Ag++1e 2+ catot: Cu + 2e Cu 7. Dung dch X cha cc mui NaCl, CuCl2, FeCl3, ZnCl2. Th t in phn catot X l: A. Fe3+, Cu2+, Zn2+, H2O B. Fe3+, Cu2+, Fe2+, Zn2+, H2O 3+ 2+ 2+ 2+ C. Fe , Cu , H2O, Fe , Zn D. Fe3+, Cu2+, Fe2+, Zn2+, H2O, Na+ 8. in phn dd cha a mol CuSO 4 v b mol NaCl vi in cc tr, mng ngn xp. dd thu c sau in phn lm qu tm chuyn mu th iu kin ca a v b l: A. a = 2b B. a > 2b C. a < 2b D. a < 2b hoc a > 2b 9. in phn nng chy hon ton 14,9 gam mui clorua ca kim loi ho tr I thu c 2,24 lt kh (ktc) anot. Kim loi l: A. Li B. Na C. K D. Rb 10. in phn dung dch Cu(NO 3)2 in cc tr, vi cng dng in 9,65A n khi catot bt u c kh thot ra. Thi gian in phn l 40 pht. Khi lng Cu thot ra l: A. 6,68 gam B. 7,68 gam C. 8,68 gam D. 8,86 gam 11. in phn dung dch AgNO3 in cc tr cho n khi dung dch thu c c pH=3 th dng li (khi tin hnh in phn c 80% lng AgNO3 cho). Th tch dung dch coi nh khng thay i ( 1 lt). Nng cc cht trong dung dch thu c sau khi ngng in phn v khi lng AgNO3 ban u l: A. [AgNO3 ] = [HNO3 ] = 10-3M; mAgNO3 = 0,17 gam B. [AgNO3 ] = 2,5.10-3M; [HNO3 ] = 10-3M; mAgNO3 = 0,2125 gam C. [AgNO3 ] = 0,125M ; [HNO3 ] = 10-3M; mAgNO3 = 0,2125 gam D. [AgNO3 ] = 2,5.10-4; [HNO3 ] = 10-3M; mAgNO3 = 0,2125 gam 12. in phn 400 ml dung dch CuSO 4 6% (d=1,02 g/ml) vi in cc tr cho n khi khi lng dung dch gim 10 gam. Khi lng Cu thot ra anot l: A. 10 gam B. 8 gam C. 2 gam D. 0 gam 13. in phn nng chy mui clorua kim loi kim thu c 0,896 lt kh (ktc) anot v 3,12 gam kim loi catot. Cng thc mui l:

A. LiCl B. NaCl C. KCl D. RbCl 14. in phn dung dch Cu(NO3)2 in cc tr, vi cng 9,65A. n khi catot bt u thot kh th dng li, thi gian in phn l 60 pht. Khi lng kim loi sinh ra catot l: A. 11,520 gam B. 13,005 gam C. 9,600 gam D. 4,800 gam 15. in phn dung dch Cu(NO 3)2 in cc tr, trong thi gian 1930 giy, thu c 9,6 gam Cu catot. Cng dng in trong qu trnh in phn l: A. 15A B. 22,5A C. 7,5A D.1,5A 16. in phn in cc tr, mng ngn xp 1 lt dd X cha 0,01 mol CuCl2, 0,01 mol HCl v 0,01 mol NaCl. Khi anot thot ra 0,336 lt kh (ktc) th ngng in phn. dd trong bnh in phn c pH l: A. 2,0 B. 2,3 C. 7,0 D. 12,0 17. in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,64 gam kim loi catot v mt lng kh X anot. Hp th hon ton lng kh trn vo 200 ml dung dch NaOH nhit thng. Sau phn ng nng NaOH cn li l 0,05M. Gi thit th tch dung dch khng thay i. Nng ban u ca NaOH l: A. 0,15M B. 0,2M C. 0,1M D. 0,05M 18. in phn dung dch cha m gam hn hp CuSO 4, NaCl vi in cc tr,mng ngn xp cho n khi nc bt u in phn c 2 in cc th dng li anot thu c 0,672 lt kh (ktc). Dung dch thu c sau in phn ho tan ti a c 1,02 gam Al2O3. Gi tr ca m l:A. 6,710 hoc 8,955 B. 5,710 hoc 7,955 C. 4,710 hoc 6,955 D. 3,710 hoc 5,955 19. in phn dung dch cha 0,02 mol FeSO4 v 0,06 mol HCl vi I=1,34A trong 2 gi(in cc tr, mng ngn). B qua s ho tan ca clo trong nc, coi hiu sut in phn 100%. Khi lng kim loi thot ra catot v th tch kh (ktc) thot ra anot l: A. 11,2 g v 8,96 lt B. 1,12 g v 0,896 lt C. 5,6 g v 4,48 lt D. 0,56 g v 0,448 lt 20. Dung dch X cha HCl, CuSO4, Fe2(SO4)3. Ly 400 ml dung dch X em in phn in cc tr vi I = 7,72A n khi catot c 0,08 mol Cu th dng li. Khi anot c 0,1 mol mt cht kh bay ra. Thi gian in phn v nng mol/l ca Fe 2+ ln lt l (coi th tch dung dch thay i khng ng k): A. 2.300 s v 0,1M B. 2.500s v 0,1M C. 2.300s v 0,15M D. 2.500s v 0,15M 21. in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,32 gam Cu catot v mt lng kh X anot. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH nhit thng. Sau phn ng nng NaOH cn li l 0,05 mol. Gi thit th tch dung dch khng thay i. Nng ban u ca NaOH l: A. 0,15M B. 0,2M C. 0,1M D. 0,05M

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Bi tp n thi i hc ha 12- nm hc 2012-2013

22. in phn 100 ml dung dch cha NaCl vi in cc tr, c mng ngn vi cng dng in l 1,93A. Th tch dung dch in phn coi nh khng i, hiu sut in phn = 100%. Thi gian in phn l bao nhiu thu c dung dch c pH = 12 l: A. 100s B. 50s C. 150s D. 200s 23. H khi A 2012 in phn 150 ml dung dch AgNO 3 1M vi in cc tr trong t gi, cng dng in khng i 2,68A (hiu sut qu trnh in phn l 100%), thu c cht rn X, dung dch Y v kh Z. Cho 12,6 gam Fe vo Y, sau khi cc phn ng kt thc thu c 14,5 gam hn hp kim loi v kh NO (sn phm kh duy nht ca N+5). Gi tr ca t l: A. 0,8. B. 0,3. C. 1,0. D. 1,2. 24. H khi B 2012 in phn dung dch hn hp gm 0,1 mol FeCl 3, 0,2 mol CuCl2 v 0,1 mol HCl (in cc tr). Khi catot bt u thot kh th anot thu c V lt kh (ktc). Bit hiu sut ca qu trnh in phn l 100%. Gi tr ca V l: A. 5,60. B. 11,20. C. 22,40. D. 4,48. 25. C 2012 Tin hnh in phn (vi in cc tr) V lt dung dch CuCl2 0,5M. Khi dng in phn thu c dung dch X v 1,68 lt kh Cl2 (ktc) duy nht anot. Ton b dung dch X tc dng va vi 12,6 gam Fe. Gi tr ca V l : A. 0,15. B. 0,60. C. 0,45. D. 0,80. 26. H Khi A nm 2010 in phn vi in cc tr mt dung dch gm NaCl v CuSO4 c cng s mol n khi catot xut hin bt kh th dng in phn. Trong c qu trnh in phn trn, sn phm thu c anot l: A. Kh Cl2 v H2 B. Kh Cl2 v O2 C. Ch c kh Cl2 D. Kh H2 v O2 27. H Khi A nm 2010 in phn vi in cc tr mt dung dch X cha 0,2 mol CuSO 4 v 0,12 mol NaCl bng dng in c cng 2A. Th tch kh (ktc) thot ra anot sau 9650 giy in phn l: A. 1,344 lt B. 2,240 lt C. 1,792 lt D. 2,912 lt 28. H Khi B nm 2010 in phn (vi in cc tr) 200 ml dung dch CuSO4 nng x mol/l, sau mt thi gian thu c dung dch Y vn cn mu xanh, c khi lng gim 8 gam so vi dung dch ban u. Cho 16,8 gam bt Fe vo Y, sau khi cc phn ng xy ra hon ton thu c 12,4 gam kim loi. Gi tr ca x l: A. 2,25 B. 1,50 C. 1,25 D. 3,25 29. H khi B nm 2009 in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl 2 0,1M v NaCl 0,5M(in cc tr, hiu sut 100%) vi cng dng in 5A trong 3860 giy. Dung dch thu c sau in phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l:

A. 4,05

B. 2,70 C. 1,35 D. 5,40 30. H khi A-2007 Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, ZnO, MgO nung nhit cao.Sau phn ng hn hp rn cn li l: A. Cu, FeO, ZnO, MgO. B. Cu, Fe, Zn, Mg. C. Cu, Fe, Zn, MgO. D. Cu, Fe, ZnO, MgO. 31. Kh ht 6,4 gam MxOy , thy cn 2,688 lt CO (kc. Cng thc ca oxit l A. CuO B. FeO C. Fe2O3 D. Cr2O3 32. Dn CO d qua ng s nung nng cha 21,6 g hn hp: MgO, Fe 3O4 . Sau p thu c m gam rn v hh kh. Dn ht kh vo dd Ca(OH) 2 d , thy c 14 gam kt ta. Tnh m? A. 19,36g B. 10,80g C. 13,48g D. 13,96g 33. Dn CO d qua ng s nung nng cha 21,6 g hn hp: CuO, Fe 2O3 . Sau mt thi gian thu c m gam rn v hh kh. Dn ht kh vo dd Ca(OH)2 d , thy c 14 gam kt ta. Tnh m? A. 19,36g B. 10,80g C. 13,48g D. 13,96g 34. Trn 2,7 gam Al vi 2,4 gam Fe 2O3 ri nung nng thc hin phn ng nhit nhm. Sau phn ng ta thu c m gam hn hp cht rn. Gi tr ca m l A. 1,12g B. 2,04g C. 5,1g D. 10,2g 35. Cho 12,8 gam hn hp bt Fe v oxit st ha tan vo dung dch axit HCl thy c 0,224 lt H2 (ktc) thot ra. Mt khc ly 6,4 gam hn hp trn em kh bng H 2 thy c 5,6 gam cht rn. CT ca oxit st l: A. Fe2O3 B. FeO C. Fe3O4 D. FexOy 36. H khi B-2007 Nung hn hp bt gm 15,2 gam Cr2O3 v m gam Al nhit cao. Sau khi phn ng hon ton thu c 13,3 gam hn hp rn X. Cho ton b hn hp X phn ng vi dung dch HCl d thy thot ra V lt H2 (ktc). Gi tr ca V l: A. 4,48 lt B. 3,36 lt C. 7,84 lt D. 10,08 lt 37. H khi B-2007 Thc hin phn ng nhit nhm vi hn hp X cha Al v Fe2O3 (hai cht ny phn ng vi nhau va ) ta thu c mt cht rn B nng 214 gam. B tc dng vi dung dch NaOH d li mt cht rn duy nht nng 112gam. Khi lng Al ban u c trong hn hp X l A. 54g B. 42g C. 27g D. 48g 38 H khi A-2008 Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c khng kh) n khi phn ng xy ra hon ton , thu c hn hp rn Y. Chia Y ta thnh hai phn bng nhau: - Phn 1 tc dng vi dd H2SO4 long ( d) sinh ra 3,08 lt kh H2 ( ktc). - Phn 2 tc dng vi dd NaOH (d) , sinh ra 0,84 lt kh H 2 ( ktc). Gi tr ca m l

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Bi tp n thi i hc ha 12- nm hc 2012-2013

A. 22,75 B. 21,40 C. 29,40 D. 29,43 39.H khi A-2008 Cho V lt hn hp kh ( ktc) gm CO v H 2 phn ng vi mt lng d hn hp rn gm CuO v Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr ca V l: A. 0,448. B. 0,112. C. 0,224. D. 0,560. 40C-2007 Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit st n khi phn ng xy ra hon ton. Kh thu c sau phn ng c t khi so vi hiro bng 20. Cng thc ca oxit st v phn trm th tch ca kh CO 2 trong hn hp kh sau phn ng l A. FeO; 75%. B. Fe2O3; 75%. C. Fe2O3; 65%. D. Fe3O4; 75%. 41. -2007 Khi cho 41,4 gam hn hp X gm Fe 2O3, Cr2O3 v Al2O3 tc dng vi dd NaOH c (d), sau phn ng thu c cht rn c khi lng 16 gam. kh hon ton 41,4 gam X bng phn ng nhit nhm, phi dng 10,8 gam Al. Thnh phn phn trm theo khi lng ca Cr2O3 trong hn hp X l (Cho: H cc phn ng l 100%) A. 50,67%. B. 20,33%. C. 66,67%. D. 36,71%. 42. CD-2008 Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn hp rn gm CuO, Fe 2O3 ( nhit cao). Sau khi cc phn ng xy ra hon ton, thu c kh X. Dn ton b kh X trn vo lng d dung dch Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l A. 1,120 B. 0,896 C. 0,448 D. 0,224 43. C-2007 t nng mt hn hp gm Al v 16 gam Fe 2O3 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng va vi V ml dung dch NaOH 1M sinh ra 3,36 lt H2 ( ktc). Gi tr ca V l A. 100 B. 150 C. 200 D. 300 44. H khi B 2012 Dn lung kh CO i qua hn hp gm CuO v Fe2O3 nung nng, sau mt thi gian thu c cht rn X v kh Y. Cho Y hp th hon ton vo dung dch Ba(OH) 2 d, thu c 29,55 gam kt ta. Cht rn X phn ng vi dung dch HNO3 d thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 2,24. B. 4,48. C. 6,72. D. 3,36. 45. H Khi B nm 2010 Kh hon ton m gam oxit MxOy cn va 17,92 lt kh CO (ktc) thu c a gam kim loi M. Ho tan a gam M bng dung dch H2SO4 c nng d thu c 20,16 lt SO2 (sn phm kh duy nht, ktc). Oxit M xOy l: A. Cr2O3 B. FeO C. Fe3O4 D. CrO

Nguyn Th Hng- THPT Thnh Long