Tuyn tp Bo co Hi ngh Sinh vin Nghin cu Khoa hc ln th 8 i hc Nng nm 2012

KHO ST S PHT QUANG T PHT V PHT QUANG CNG BC

CA NHM VT LIU PHT QUANG S DNG TRONG VIC CH TO
LED TRNG
STUDING THE PHOTOLUMINESCENT SPECTRAL AND THE
THERMOLUMINESCENCE STUMILATE IN MAKING THE WHILTE LED OF
MATERIAL
SVTH: Phm Hoi Chu, H Th Phng Thanh, Nguyn Th Hng Nhung,
Nguyn Th Thu Li, Ng Th Thy Trang

Lp 08SVL, Khoa Vt l, Trng i hc S Phm i hc Nng

GVHD: Nguyn Vn Cng, L Vn Thanh Sn

Khoa Vt l, Trng i hc S Phm i hc Nng

TM TT
Bi bo a ra mt s kt qu kho st s pht quang cng bc nhit v o ph pht quang
t pht ca tm quang Mn trong trng Silicat v Aluminat. T kt qu thu c tc gi i n mt s
kt lun v s nh hng ca ch nung vt liu silicat v nng ion Mn n cng nhit pht
quang v ph pht quang t pht ca ion Mn trong vt liu nn Silicate v Aluminat ng dng trong
ch to LED trng.
T kha: pht quang t pht(PL), pht quang cng bc(TL), LED trng
ABSTRACT
This paper displays some results on themorluminescence phenomeum and the
photoluminescence of the activator Mn in the silica and alumina host lattice. By experimental result, the
author abstracts some conclusion about the effects of heating mode silicat material and ion Mn in
thermoluminescence (TL) intensity and the photoluminescence (PL) spectral of this activator of some
silica-based material and its applications in manufacturing white LED.
Keywords: photoluminescent spectral (PL), thermoluminescence stumilate (TL), white LED.

1. t vn
Cc cht pht quang ni chung v cht ln quang di ni ring c pht hin v ch
nghin cu t hng trm nm nay vi nhiu cng trnh nghin cu ca cc nh khoa hc nh
Antonop, Clemen, LepsinHin tng pht quang t pht cng nh pht quang cng bc
ca cc cht ny c rt nhiu ng dng trong khoa hc-k thut, i sng c bit to bc
t ph trong cng nghip chiu sng v in t vin thng t khi LED trng xut hin.
nh sng trng ca LED c to ra da trn nguyn l trn 3 mu c bn (, xanh lc,
xanh lam). Trn chip LED loi xanh lam, ngi ta ph mt lp cht pht quang ln b mt ca
chip gi l lp chuyn i. Khi chip LED hot ng, tia sng xanh pht ra kch thch cc
nguyn t ca cht pht quang s pht ra tia v xanh lc. L sinh vin vt l vi iu kin
hin c ca phng th nghim i Hc S Phm Nng nhm mun tm hiu v vic ch to
vt liu pht quang mu v mu xanh ca trng tinh th Aluminate, Silicate pha tp ion
Mn. T a ra mt s nhn xt cn thit t vic ch to vt liu ny. cng chnh l l do

Tuyn tp Bo co Hi ngh Sinh vin Nghin cu Khoa hc ln th 8 i hc Nng nm 2012

nhm chn ti Kho st s pht quang t pht v pht quang cng bc ca nhm vt
liu pht quang s dng trong vic ch to LED trng.
2. Thc nghim
2.1. Ch to mu
Nhm tin hnh nghin trn hn hp gm cc mui cacbonat ca cc ion kim loi
(Mg, Ca, Sr, Ba, Zn ), xit nhm (Al 2 O 3 ), silic ixit (SiO2), MnCO 3 vi cc liu lng
thch hp, sau mu ngui t nhin, lm sch, sau cho nhiu x tia X, chiu x bng
tia v tin hnh o TL v ph PL. Sau , vn dng cng thc tnh ton tm su by Et.
2.2. Kt qu v tho lun :
2.2.1.i vi ph TL:
45000

Hnh 2.2.1.1 ng cong TL ca mu (Mg.Ba).SiO3 :

0,5% Mn

(Mg.Ba).SiO3, 0,5% Mn

40000

cuong do TL (a.u.)

35000

Nhn xt: ng cong TL xut hin mt nh di nhit

1000C, mt nh vng nhit trn 1700C nhng
cng thp v mt nh TL 1430C c cng ln
nht.

30000
25000
20000
15000
10000
5000

30000

(Mg.Ba).SiO3 , 0,24% Mn

0
50

100

150

200

250

25000

300

nhiet do ( C)
cuong do TL (a.u.)

20000

Hnh 2.2.1.2 ng cong TL ca mu (Mg.Ba).SiO3 :0,24% Mn

15000

10000

5000

Nhn xt: ng cong TL xut hin vng nhit di

1000C, nh nhit pht quang mnh nht 1450C, khng khc so vi mu pha tp 0,5%Mn.
Nng Mn cng ln th cng TL cng cao.
50

100

150

200

250

nhiet do ( C)

Hnh 2.2.1.3 ng cong TL ca mu (Ca.Zn).SiO3 : 0,7% Mn

nung 10000C/ 2gi + 12000C/4 gi.

250000

(Ca.Zn).SiO3, 0,7% Mn
1 : 1 : 2,5

cuong do TL (a.u.)

200000

150000

Nhn xt: Dng ng cong TL gm 2 nh nhit 1210C v

1760C c cng cao v mt nh ngoi 2400C c cng rt
b.

100000

50000

50

100

150

200

250

300

(Ca.Zn).SiO3 0,7 Mn
1 : 1 : 2,5

100000

nhiet do ( C)

Hnh 2.2.1.4 ng cong TL ca mu (Ca.Zn).SiO3 :

0,7% Mn iu kin nung 12000C/ 6 gi.

cuong do TL (a.u.)

80000

60000

40000

20000

Nhn xt: ng cong TL gm 2 nh nhit

1380C v 1940C c cng cao. Nh vy, ch
nung cng nh hng n nhit pht quang.

50

100

150

200
0

nhiet do ( C)

250

300

Tuyn tp Bo co Hi ngh Sinh vin Nghin cu Khoa hc ln th 8 i hc Nng nm 2012

Bng 2.2 Gi tr su by ca cc ng cong TL

Tn mu

STT
nh

Nhit nh
TL (0C)

Gi tr su by

(Mg.Ba).SiO3 : 0,5%Mn

143

1,08

(Mg.Ba).SiO3:0,24%Mn

145

1,09

(Ca.Zn).SiO3 : 0,7% Mn

121

0,6

176

1,5

138

0,74

194

1,63

(Ca.Zn).SiO3 : 0,7% Mn

E (eV)

2.2.2. i vi ph PL:
25000

cuong do PL (a.u)

Hnh2.2.2.1 ng cong PL
(CaO)0,4.(ZnO)0,4.(SiO3)1,2 : 0,3% Mn

(Ca.Zn).SiO3:0,3% Mn
0,4 :0,4 :1,2

20000

15000

10000

5000

0
500

550

600

650

buoc song(nm)

700

750

ca

mu

Nhn xt: Tm quang Mn nng 0,3% trong trng

tinh th CaO.ZnO.SiO2 t l 0,4:0,4:1,2 pht quang
bc sng 525nm_ mu xanh.

Hnh2.2.2.2 ng cong PL ca (CaO)0,4.(ZnO)0,6.(SiO2)1,0 : 0,3%

Mn

(Ca.Zn).SiO3:0,3% Mn
0,4 :0,6 :1

16000
14000

cuong do PL (a.u)

Nhn xt: Tm quang Mn nng 0,3% trong trng tinh th

(Ca.Zn).SiO3 t l 0,4:0,6:1 pht quang bc sng 525nm _ mu
xanh.

18000

12000
10000
8000
6000
4000
2000
500

550

600

650

700

750

buoc song(nm)
b)

Hnh2.2.2.3 ng cong PL ca mu (CaO)0,55.(ZnO)0,4.(SiO2)1,05

: 0,3% Mn

30000

CaO:ZnO:SiO2:0,3%
0,55 :0,4 :1,05

cuong do PL (a.u)

25000

20000

Nhn xt: Tm quang Mn nng 0,3% trong trng tinh th

(Ca.Zn).SiO3 t l 0,55:0,4:1,05 pht quang bc sng 525nm_
mu xanh.

15000

10000

5000

0
500

550

600

650

700

buoc song(nm)
c)

32000
30000

Nhn xt: Vi cng mt nng 0,3%Mn trong trng tinh th

polysilicat (Ca.Zn).SiO3 vi cc t l nng khc nhau th u pht
quang bc sng 525nm _mu xanh nhng cng pht quang
i vi vt liu c t l cht nn khc nhau l khc nhau.

(Ca.Zn).SiO3: 0,3% Mn
0,4 :0,6 : 1
0,4 :0,4 : 1,2
0,55 :0,4 : 1,05

28000
26000
24000
22000

cuong do PL (a.u)

Hnh2.2.2.4 ng cong PL ca mu (Ca.Zn).SiO3: 0,3% Mn

iu kin nung 12000C/6gi vi cc t l v cht nn khc nhau.

20000
18000
16000
14000
12000
10000
8000
6000
4000
2000
0
500

550

600

650

buoc song(nm)

700

750

Tuyn tp Bo co Hi ngh Sinh vin Nghin cu Khoa hc ln th 8 i hc Nng nm 2012

(Mg.Ca)Al2O4 : Mn c chat chay

0,5:0,5:1
(Mg.Ca)Al2O4 : Mn khng c chat chay
0,4:0,4:1,2

70000

cuong do phat quang

60000

50000

Hnh 2.2.2.5 So snh ph pht quang ca (Mg,Ca)Al2O4 : Mn khi

c v khng c cht chy

40000

Nhn xt :Dng ph pht quang ca vt liu khi nung c cht chy

gm 3 nh ph c tnh i xng ng vi cc bc sng 640 nm,
655 nm v 665 nm. Trong nh 655 nm c cng pht
quang ln nht .Ph pht quang ca vt liu khi nung khng c
cht chy ch xut hin mt nh bc sng 640 nm nhng c
cng

yu
hn
rt
nhiu.

30000

20000

10000

0
520

540

560

580

600

620

640

660

680

700

buoc song (nm )

MgO.CaO.Al2O3: Mn 0,2%
( 0,4 : 0,4 : 1,2)
MgO.CaO.Al2O3: Mn 0,2%
( 0,5 : 0,5 : 1)

60000

Nhn xt: - Vt liu (Mg.Ca)Al2O4 : 0,2% Mn vi t l

cht nn (1:1:3) cho ph pht quang 3 bc sng 640 nm,
655 nm , 665 nm v c cng mnh. Ph pht quang
ca vt liu (Mg.Ca)Al2O4:0,2%Mn vi t l cht nn ( 1:
1: 2 ) ch c nh bc sng 650 nm vi cng yu

60000

30000

20000

10000

0
630

640

650

660

670

680

690

700

buoc song (nm)

Nhn xt: - ng cong pht quang ca vt liu SrAl2O4:Mn

0,2% Mn cho 3 nh chnh bc sng 642 nm, 657 nm , 667
nm v bc sng 657 nm c cng pht quang ln nht.

50000

cuong do phat quang

40000

Hnh 2.2.2.7 Ph pht quang ca SrAl2O4:0,2% Mn

SrAl2O4: Mn 0,2 %
0,8:1,2

70000

50000

cuong do phat quang

Hnh 2.2.2.6 . So snh ph pht quang ca (Mg.Ca)Al2O4 :

Mn khi thay i t l cht nn

40000

30000

20000

10000

0
600

620

640

660

680

700

720

740

buoc song (nm )

BaAl2O4 : Mn 0,2 %
0,8:1,2

Hnh 2.2.2.8. Ph pht quang ca BaAl2O4: Mn

Nhn xt: - Ph pht quang cho nh bc sng 635 nm
v c ng cong pht quang c cng yu cng
yu hn so vi vt liu SrO.Al 2 O 3 :Mn 0,2%.

10500

10000

9500

9000
610

620

630

640

650

660

670

680

buoc song (nm)

Hnh 2.2.2.9. So snh ph pht quang ca (Ba.Zn)Al2O4: Mn

khi nung c v khng c cht chy

(Ba.Zn)Al2O4 : Mn c chat chay

0,4:0,4:1,2
(Ba.Zn)Al2O4 : Mn khng c chat chay
0,4:0,4:1,2

22000
20000
18000

Cuong do phat quang

cuong do phat quang

11000

16000
14000
12000
10000
8000
6000
640

660

Buoc song (nm)

680

700

Nhn xt: Cng vt liu (Ba.Zn)Al2O4 : Mn( 0,2 % ) vi t l

cht nn ( 1: 1: 3) nhng ph pht quang ca vt liu khi nung
c cht chy th cng pht quang ln hn so vi ph pht
quang ca vt liu khi nung khng c cht chy. nh pht
quang cao nht bc sng 662 nm v c cng mnh hn
ca vt liu BaAl2O4 : Mn c nh bc sng 635 nm
hnh 2.2.b.6.

Tuyn tp Bo co Hi ngh Sinh vin Nghin cu Khoa hc ln th 8 i hc Nng nm 2012

3. Kt lun
Qua kho st hin tng pht quang cng bc (nhit) v pht quang t pht ca
nhm vt liu silicat, aluminat c pha tp ion Mn, tc gi a ra mt s kt lun sau:
* V pht quang cng bc (nhit):
- Nhm vt liu nn (Mg.Ba)SiO3 c nh TL cc i nhit t 1430C- 1450C.
- Nhm vt liu nn (Ca.Zn)SiO3 c nh TL cc i nhit t 1760C- 1940C
- Vi cc cht nn khc nhau th cng TL c gi tr khc nhau, s by v su
by c gi tr khc nhau.
- Nng Mn cng ln th cng TL cng cao.
- Ch nung nh hng n cng TL.
* V pht quang t pht:
- Tm quang Mn vi cng mt nng trong cc trng tinh th polysilicat
(Ca.Zn)SiO3 khc nhau th u pht quang bc sng 525nm _mu xanh.
- Cng pht quang ca tm quang Mn i vi mt loi vt liu vi t l cht nn
khc nhau l khc nhau.
- Ph pht quang ca cc vt liu (Mg.Ca)Al2O4 ; SrAl2O4; BaAl2O4; (Ba.Zn)Al2O4
pha tp Mn c dng ph khc nhau.
- Qua kho st ta thy rng ion Mn ph hp vi vt liu nn (Mg.Ca)Al2O4 nn cho
pht quang cng cc i bc sng c 655nm .
- Cc nh ph u nm trong khong bc sng ( 635 nm - 670 nm ), ph hp vi
cc s liu v nh ph pht quang ca Mn 4 trong cc mng ch Aluminate ng vi s
dch chuyn t 2E v 4A2 cho pht quang mu . [1],[5]
- Khi pha thm cht chy vo vt liu c mng ch l Aluminate th phn ng pha
rn xy ra tt hn nn cng pht quang tng ln.
- T l cht nn l ( 1 : 1 : 3 ) cho kt qu pht quang tt hn t l cht nn l ( 1: 1 :
2)
TI LIU THAM KHO
[1] Phan Vn Thch , Hin tng hunh quang v k thut phn tch hunh quang, i
hc tng hp H Ni.
[2] Nguyn Mnh Sn, L Vn Tut (2007), Cc nghin cu pht quang ca vt liu
aluminate pha tp nguyn t t him, i hc Hu.
[3] V Xun Quang (1999), Quang ph ca cc tm in t trong vt rn, Vin khoa hc
vt liu.
[4] inh Thanh Khn, Ch to vt liu CaAl2O4. Kho st nh hng ca ion Mn2+ ln
ph pht quang cu vt liu ny, Khoa Vt l, Trng i hc S Phm - i hc
Nng (2008).
Ting Anh
5

Tuyn tp Bo co Hi ngh Sinh vin Nghin cu Khoa hc ln th 8 i hc Nng nm 2012

[5] G.Blasse.B.C.Grabmaier, Luminescent Materialslag

Heidelberg 1994

springer, Verlag Berlin

[6] Role of SiO2 in Zn2SiO4 : Mn2+ phosphor used in optoelectronic materials , Indian
Journal of Engineering & Materials Sciences, (6/2009) Vol 6, tr 185 - 187
[7] S.W.S Mc KEEVER, The Thermoluminescence of solids, Deparment of physic,
Oklahoma State University (1985).