(a)

(b)

(d)

(e)

(c)

(f)

(b)

(a)

(c)

(d)

(e)

101
101

3000

100
100

2500

103
103

102
102

1500

1000
500C
calcined
500 ?C calcined

200
200
112
112
201
201

110
110

002
002

Intensity (AU)

2000

500
As-synthesized
As-synthesized
0
110
0

20
20

30
30

40
40

50
50

60
60

70
70

80
80

20

22

300C
300 ?C

350

1.88

400C
400?C

351
351

1.66

500?C

351
351

500C

350

Absorbance

1.4
1.4
354
354

1.22
200C
200?
C
11
0.88
0.66
0.44
0.2
0.2
00
250

As-synthesized
As-synthesized
100 ?C

350

450

550

Wavelength (nm)

650

750