3 :

3 :

04/03/2009 :

05
:
H 2O 2
. .
. =120 C S v = 500ml 0.08 mol .L 1
O 2 5 :
40
300

30
35
270 288

25
252

20
228

15
192

10
138

5
72

0
0

/1 .
/2 v m = 24 L / mol
/3 .
/4 - .
- t 1 =15mn : t 2 = 25 mn
- . .
/5 .
/6 . = 500 C
.
:

PO

min

) ( ml
) ] ( mol / L

04
210
84

/1

/2 PO

210

. j 138.3

/3
/4 222.2 g 210
.
/5 .
/6 . .
210

/7 . PO
m (X ) = 206.0385u
et
m (PO ) = 210.0482u :
z ( Bi ) = 83 et
z ( pb ) = 82
et
m (He ) = 4.0039u
z ( Rn ) = 86 . z ( At ) = 85 . m p = 1.00728u . m n = 1.00867u

 04
:
) ( L . r = 25 R
(K .
E = 6 v L(H
/1
/2 t = 0
-1
) L = f (
r.R
-1 L 0.1.
) ( ms
0 1
-2 .
(R
-3 i(A
-2
. (i = f(t :
0.015
.
-1

2
L .
-2
(t (ms
04
:
n 100g (n(g .

1
. ) ( S
10

) (

VS = 20 ml ) ( S Cb = 0.1 mol/l
PH
(PH = f(Vb : Vb .
/1 - S
- .
8.6
/2
.
4.7
/3 -
3.2
- Qr .
)vb(ml
20
10
0
/4 -
) ( S C .
- 100g
- .
+3
=1.02 10 g / l :
03
:
. r T
:
/1 . r , T G :
/2 . T r :
/3 . m r T :
/ 4 ) ( ) (
- . G M r :