8 Cu 1: (2 im) Vit phng trnh phn ng thc hin cc bit ha sau:

(1) (2) (2) CH4 C2H2 C2H4 PE

(4)

C6H6 Cu 2: (2 im) Bng phng php ha hc hy phn bit 4 l kh mt nhn sau: C2H2, CO2, SO2, CH4. Cu 3: (4 im) Mt hn hp gm Cu v Fe c tng khi lng 12g cho vo 400 ml dung dch HCl 1M (d). Sau phn ng thu c 6,4g cht rn, dung dch A v V lt kh (ktc). a) Vit phng trnh phn ng. Tnh V ? b) Ly 400 ml dung dch NaOH c nng a mol/l phn ng va vi dung dch A, thu c kt ta B. - Tnh a ? - Lc ly kt ta B , nung trong khng kh n khi lng khng i thu c m gam cht rn. Tnh m ? Cu 4: (2 im) Ha tan m gam mt oxit st cn 150 ml dung dch HCl 3M. Nu kh hon ton m gam oxit st trn bng CO nhit cao th thu c 8,4g st. Xc nh cng thc phn t oxit st ?

Cho bit: Fe = 56; Cu = 64 ; O = 16) 9

Cu 1: (2,0 im) Vit cc phng trnh ho hc thc hin nhng chuyn i sau:

Al2O3
Cu 2: (2,0 im)

(1)

NaAlO2

(2)

Al(OH)3

(3)

AlCl3

(4)

Al

Tch 3 cht rn FeCl2, CaCO3, AgCl ra khi hn hp ca chng bng phng php ho hc.

Cu 3: (3,0 im) Ho tan hon ton 3,45 gam kim loi A ho tr (I) vo 102,7 gam nc thu c 106 gam dung dch B a. Xc nh kim loi A. b. Tnh nng phn trm ca dung dch B. c. Cho ton b dung dch B trn vo 50 gam dung dch AlCl3 10,68%. Tnh khi lng kt ta. Cu 4: (3,0 im) Hn hp A gm hircacbon X v H2, un nng hn hp A c Ni xc tc thu kh Y duy nht. T khi hi Y so vi H2 gp 3 ln t khi hi ca A so vi H2. t chy mt lng khc ca Y thu c 22 gam CO2 v 13,5 gam H2O. a. Y l hircacbon loi no? Xc nh cng thc phn t ca Y? b. Xc nh cng thc phn t ca X Bit X, Y l ankan, anken hoc ankin (Cho bit: H = 1; O = 16; C = 12; Cl = 35,5; Al = 27; Li = 7; Na = 23; K = 39)

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Cu 1. ( 2,0 im) 1. Xc nh cc cht c trong s sau v vit phng trnh ho hc (ghi r iu kin):
(1) ( 2) ( 3) ( 4) Al4C3 A B C 6,6,6 ( 5) (6) (7) (8) D E F G (Etylaxetat)

Bit E, F l nhng hp cht hu c c cha cc nguyn t C, H, O. 2. T qung pirit st, mui n, khng kh, nc (c cht xc tc v thit b cn thit khc). Hy vit cc phng trnh ho hc iu ch: Fe2(SO4)3 , Na2SO4, Na2SO3, nc Giaven. Cu 2. (2,0 im) 1. Nu hin tng v vit phng trnh ho hc (nu c) cho cc th nghim sau: a) Sc kh CO2 t t vo dung dch nc vi trong. b) Cho t t dung dch HCl vo dung dch Na2CO3. c) Cho kim loi Na vo dung dch CuSO4. d) Nhng inh st co sch g vo dung dch CuSO4. 2. Cho hai n cht X, Y tc dng vi nhau thu c kh A c mi trng thi. t chy A trong kh oxi d thu c kh B c mi hc. A li tc dng vi B to ra n cht X, v khi cho X tc dng vi st nhit cao thu c cht C. Cho C tc dng vi dung dch HCl li c kh A. Gi tn X, Y, A, B, C. Cu 3. (2,5 im)

1. Mt hp cht hu c B cha c cha cc nguyn t (C, H, O) c cng thc phn t trng vi cng thc n gin nht. t chy hon ton B bng mt lng oxi va thu c:

m H2O

9 8 m B v VCO 2 VO2 . Tm cng thc phn t ca B. 15, 4 9

2. Hn hp X gm Mg v kim loi M. Ho tan hon ton 8,0 gam hn hp X cn va 200 gam dung dch HCl 7,3%. Mt khc, 8,0 gam hn hp X tc dng va vi 5,6 lt kh Cl2 ( ktc) to ra hai mui clorua. Xc nh kim loi M v % khi lng ca M trong hn hp X. Cu 4. (3,5 im) 1. Hirocacbon A c khi lng phn t bng 68 vC. A phn ng hon ton vi H2 to B. C A v B u c mch cacbon phn nhnh. Xc nh cng thc cu to ca A v B. 2. Cho 0,51 gam hn hp A gm Fe v Mg vo 100 ml dung dch CuSO4 aM. Sau khi cc phn ng xy ra hon ton, lc thu c 0,69 gam rn B v dung dch C. Thm NaOH d vo dung dch C, ly kt ta em nung ngoi khng kh n khi lng khng i c 0,45 gam cht rn D. Tnh a.

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Bi I: (2,5 im) 1. Ch dng mt thuc th duy nht hy phn bit cc cht bt c mu tng t nhau, cha trong cc l mt nhn sau: CuO, Fe3O4, Ag2O, MnO2, (Fe + FeO). Vit cc phng trnh phn ng ha hc xy ra. 2. Cho hn hp cht rn gm FeS2, CuS, Na2O. Ch c dng thm nc v cc iu kin cn thit (nhit , xc tc, ...). Hy trnh by phng php v vit cc phng trnh phn ng ha hc xy ra iu ch FeSO4, Cu(OH)2. Bi II: (1,5 im) Cho s chuyn ha sau:

Tm cc cht hu c ng vi cc ch ci A, B, C, ... . Vit cc phng trnh phn ng ha hc xy ra, ghi r cc iu kin. Bit A l mt loi gluxit, khi t chy hon ton A thu c khi lng H2O v CO2 theo t l 33: 88 v C, D, E l cc hp cht c cng s nguyn t cacbon. Bi III: (2 im) 1. Cho mt lng kim loi M phn ng hon ton vi dung dch CuSO4, sau phn ng khi lng cht rn thu c gp 3,555 ln khi lng M em dng. Mt khc, nu dng 0,02 mol kim loi M tc dng H2SO4 long ly d th thu c 0,672 lt kh (ktc). Xc nh kim loi M. 2. Khi thc hin phn ng chuyn ha metan thnh axetilen ( 15000C v iu kin thch hp) thu c hn hp kh X gm metan, axetilen v hidro. t chy hon ton hn hp X thu c 26,4 gam CO2. Tnh khi lng hn hp X em t. Bi IV: (1,5 im)

t chy hon ton mt hidrocacbon A mch thng thu c VH 2O : VCO2 1: 2 . Mt khc, nu ly 0,2mol A tc dng ht vi dung dch AgNO3 trong NH3 (d) thu c 58,4 gam cht kt ta. Xc nh cng thc cu to, cng thc phn t ca A. Bi V: (2,5 im) Hn hp X gm 2 cht hu c CH3COOH (A) v RCOOC2H5 (B) (c t l s mol 1:1). Cho X tc dng ht vi 200ml dung dch NaOH, sau phn ng thu c dung dch Y. C cn Y thu c hi ru v 36,6gam cht rn Z (trong Z c 2 cht vi s mol bng nhau). Ngng t ht hi ru, cho tc dng ht vi Na thy gii phng 1,68 lt H2 (ktc). 1. Vit PTHH ca phn ng. Xc nh cng thc cu to ca B. Bit phn t khi ca B < 168. 2. Xc nh nng mol ca dung dch NaOH ban u.

Cho: Ag = 108 ; Na = 23; K = 39 ; Mg = 24 ; Fe = 56 ; Cu = 64 Zn = 65 ; Al = 27 ; Mn = 55 ; O = 16 ; Cl = 35,5 ; S = 32 ; N = 14 ; C = 12 ; H = 1. H t - Th sinh khng c s dng bng tnh tan v bng HTTH cc nguyn t ha hc. - Gim th coi thi khng gii thch g thm.

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Cu 1: (4 im) 1. Vit phng trnh phn ng thc hin dy chuyn ha sau:
(1) (2) (3) (4) (5) (6) MnO2 Cl2 HCl FeCl2 Fe(OH)2 FeSO4 Fe(NO3)2

(7)
(8) (9) (10) Ca(NO3)2 CaCO3 CaCl2 Ca(HCO3)2

2. C 5 dung dch cha trong 5 l ring bit gm cc cht : Na2CO3, BaCl2, MgCl2, H2SO4, NaOH c nh s bt k 1,2,3,4,5 . Thc hin cc th nghim c kt qu nh sau: - Cht l 1 tc dng vi cht l 2 cho kh bay ln, v tc dng vi cht l 4 to thnh kt ta. - Cht l 2 cho kt ta trng vi cht l 4 v l 5. Hy cho bit tn cht c trong tng l 1,2,3,4,5.Gii thch v vit phng trnh phn ng minh ho. Cu 2: (2 im): Trn 2 a cn v tr thng bng c 2 cc h trong khng kh,mi cc u ng 100g dung dch HCl c nng 3,65%.Thm vo cc th nht 8,4g MgCO3 ,thm vo cc th hai 8,4g NaHCO3. a)Sau khi p kt thc,cn cn gi v tr thng bng khng? Nu khng th lch v bn no?Gii thch. b)Nu mi bn a cn cng ly 100g dung dch HCl nhng nng l 10% v cng lm th nghim nh trn vi khi lng MgCO3 v NaHCO3 u bng 8,4g. Phn ng kt thc,cn cn gi v tr thng bng khng ? Gii thch.

Cu 3: (2 im) Ngi ta dng kh CO d nhit cao kh hon ton 53,5g hn hp X cha CuO, Fe2O3, PbO, FeO thu c hn hp kim loi Y v hn hp kh Z. Cho Z tc dng ht vi dung dch Ca(OH)2 d, phn ng xong ngi ta thu c 60 gam kt ta trng. a)Vit phng trnh ha hc ca cc phn ng. b)Xc nh khi lng ca hn hp kim loi Y. Cu 4: (4 im) Ho tan hon ton hn hp X gm Fe v Mg bng mt lng va dd HCl 20% thu c dung dch Y. Bit nng ca MgCl2 trong dung dch Y l 11,787%. a) Vit phng trnh phn ng. b) Tnh nng % ca mui st trong dung dch Y. c) Nu thm vo dung dch Y ni trn mt lng dung dch NaOH 10% va tc dng th nng % ca cht c trong dung dch sau phn ng l bao nhiu ? Cu 5: ( 4 im) t chy hon ton mt hn hp kh A gm C2H2, C2H4, CH4, C3H4, C2H6 th thu c 8,96 lt CO2 ktc) v 9 gam nc. a) Vit phng trnh phn ng t chy. b) Tnh th tch kh Oxi cn dng ( o ktc) c) Tnh tng khi lng ca hn hp A. Cu 6: (4 im) t chy hon ton m gam mt hyrocacbon X, dn ton b sn phm chy ln lt qua bnh 1 ng H2SO4 c d, bnh 2 ng dung dch Ca(OH)2 d. Sau khi phn ng xy ra hon ton ,ngi ta thy: - Bnh 1: c khi lng tng thm 21,6 gam. - Bnh 2: c 100 gam cht kt ta trng. a) Vit cc phng trnh phn ng xy ra. b) Tnh m. c) Xc nh cng thc phn t ca X bit rng t khi hi ca X so vi oxi l 2,25. d) Vit cng thc cu to c th c ng vi cng thc phn t ni trn. 13 (

CuI: (2,5 im) 1/ Cho cc dung dch mui A, B, C, D cha cc gc axit khc nhau.Cc mui B, C t trn ngn la v sc pht ra nh sng mu vng.

A tc dng vi B thu -c dung dch mui tan, kt ta trng E khng tan trong n-c v axit mnh, gii phng kh F khng mu, khng mi, nng hn khng kh. T khi hi ca F so vi H2 bng 22. - C tc dng vi B cho dung dch mui tan khng mu v kh G khng mu, mi hc, gy ngt, nng hn khng kh, lm nht mu dung dch n-c Brm. - D tc dng vi B thu -c kt ta trng E. Mt khc D tc dng vi dung dch AgNO3 to kt ta trng. Hy tm A, B, C, D, E, F, G v vit cc ph-ng trnh phn ng xy ra. 2/ Vit cc ph-ng trnh phn ng xy ra khi dng n-c vi loi b mi kh c sau y ra khi khng kh b nhim : Cl2 , SO2 , H2S , NO2 . 3/ Hn hp X gm 4 cht kh sau : CO2, SO3, SO2 v H2. Trnh by ph-ng php ho hc nhn ra s c mt ca cc kh trong hn hp X. Vit cc ph-ng trnh phn ng xy ra. Cu II: ( 2,5 im) 1/ Cho A, B, C, D, X, Y, Z u l cc hp cht hu c; A, B, C l nhng hirocacbon, C l cht kh c kh nng kch thch qu mau chn v phn t cha mt lin kt km bn; X,Y,Z l nhng mui ca axit hu c. Hy xc nh cng thc cu to thch hp ca A,B,C,D, X,Y,Z v vit ph-ng trnh ha hc theo s sau ( ghi r iu kin nu c): C CH3COOH
(9) (1)

(2)

(5) (8)

B Y
(7) (6)

(4)

(3)

2/ Hp cht hu c A c cng thc cu to thu gn: CH2 = CH CH2 - OH. Hi A c th c nhng tnh cht ha hc no? Hy vit ph-ng trnh phn ng minh ha cho nhng tnh cht . 3/ T vi, than , cc cht v c v cc iu kin cn thit vit cc ph-ng trnh ho hc (ghi r iu kin) iu ch Benzen, Caosubuna. Cu III: ( 3,0 im) 1/ A l hn hp gm M2CO3, MHCO3, MCl (M l kim loi trong hp cht). Cho 43,71 gam hn hp A tc dng ml dung dch HCl 10,52% (D = 1,05 g/ml) ly d- thu dch B v 17,6 gam kh C. Chia dung dch B thnh 2 nhau: ha tr I ht vi V -c dung phn bng

- Phn 1: Phn ng va vi 125 ml dung dch KOH 0,8M. C cn dung dch thu -c m gam mui khan. - Phn 2: Tc dng hon ton vi dung dch AgNO3 d- thu -c 68,88 gam kt ta trng. a/ Xc nh tn kim loi M v phn trm khi l-ng mi cht trong A. b/ Tm m v V.

2/ Ho tan 16,8 (gam) mt kim loi M vo dung dch HCl d- thu -c 6,72 lit kh H2 (ktc). a. Tm kim loi M. b. Ho tan 25,2 (gam) kim loi M vo dung dch H 2SO4 10% ( long), va . Sau khi kt thc phn ng thu -c dung dch A. Lm lnh dung dch A thu -c 55,6 (gam) mui sunfat kt tinh ngm n-c ca kim loi M tch ra v cn li dung dch mui sunfat bo ho c nng 9,275%. Tm cng thc ca mui sunfat ngm n-c ca kim loi M. Cu IV: ( 2 im) 1/ Hn hp kh X gm C2H6 , C3H6 , C4H6. T khi hi ca X so vi H2 bng 21.t chy hon ton 2,24 lt hn hp X ( ktc) ri dn ton b sn phm thu -c ln l-t qua bnh 1 ng H2SO4c v bnh 2 ng dung dch KOH d- th khi l-ng tng ln bnh 1 v bnh 2 l m1(gam), m2(gam).Tnh cc gi tr m1 , m2

2/ Este E to bi mt axit X n chc, mch h, khng no (cha 1 lin kt i C=C ) v mt ancol Y no, ba chc, mch h. Trong phn t ca E nguyn t Cacbon chim 56,69% khi l-ng. Tm cng thc phn t v vit cng thc cu to ca E. (Bit E ch cha mt loi nhm chc duy nht).

14

Cu 1 (2 im) 1/ 3 hp cht ca natri l X, Y, Z c mi quan h sau:

t 2 CO2 Y X
0

CO

dung dich Z X Y Z

Xc nh cng thc ha hc ca X, Y, Z v vit cc phng trnh phn ng theo s trn. 2/ Vit phng trnh phn ng nhit phn n khi lng khng i ca: KMnO4, KClO3, Mg(HCO3)2. Cu 2 (2 im) C 4 ng nghim, mi ng cha mt dung dch mui ( khng trng kim loi cng nh gc axit ) l clorua, sunfat, nitrat, cacbonat ca cc kim loi Ba, Mg, K, Ag. 1/ Hi mi ng nghim cha dung dch mui no? 2/ Trnh by phng php ha hc phn bit 4 dung dch mui trn. Cu 3 (2 im) T C, H2O, khng kh, cht v c, iu kin v xc tc cn thit coi nh c . Hy vit cc phng trnh phn ng ho hc to ra axit gluconic, natri etylat, etyl axetat. Cu 4 (2 im) - Cho 41,175 gam hn hp hai kim loi Na, Ba tc dng vi 59,725 gam nc thu c dung dch X v c 10,08 lt kh thot ra (ktc). - Trn 400 ml dung dch A (cha HCl) vi 100 ml dung dch B (cha H2SO4) c dung dch C. Ly 10 ml dung dch C trn vi 90 ml nc c dung dch D. - Dng 1 gam dung dch X trung ho va dung dch D trn, thu c kt ta Y. C cn phn dung dch th thu c mt lng mui khan Z. Tng khi lng Y v Z l 0,83125 gam. a/ Tnh nng phn trm cc cht c trong dung dch X. b/ Tnh nng mol ca cc cht c trong dung dch A, B, C, D. Cho rng th tch ca dung dch thay i khng ng k. Cu 5 (2 im)

t chy hon ton 0,2 mol mt hp cht hu c A c cng thc phn t dng CnH2n, ton b sn phm chy c hp thu ht vo 295,2 gam dung dch NaOH 20%. Sau khi hp thu xong, nng ca NaOH cn li trong dung dch l 8,45%. Cc phn ng xy ra hon ton. 1/ Xc nh cng thc phn t ca A. 2/ Hn hp kh X gm A v H2 c t khi so vi hiro l 10,75. un nng X vi bt Ni lm xc tc n khi phn ng hon ton thu c hn hp Y. a/ Chng minh rng hn hp Y lm mt mu dung dch brom. b/ Tnh thnh phn phn trm th tch mi kh trong hn hp X; hn hp Y.

15