BQ GIAO DUC VA DAO TAO DAIHQCHUE

Hp vd ftn th{ sinh: So bdodanh:.....

n / , ,

Aeq6

(Dqtt) ri rnr rwBN srNHsAUDArnec uAivr 2012

M6n thi: Co s& lf thuy6t h,ia hgc vir c6u t4o ch6t (ddnh cho: Cao hgc) Thdi gian ldm bdi: lB0 philt CAU1 Choc6cphanimg sau,xdy ra d 25oC: 2H2S(r) + Fe(r) : FeS2(r) + 2H2&) LLl2ss:-137,9*t^tt'

H2S(r) + =Oz&) = HrO(D + SO2(it) LHz*:-562,0k1/mol; el6t nirigt tao thdnh ti6u chu6n cria SO2(l) vn HzO(| Hn tuqt beng -296,81 kl/mot vit, -285,83 kl/mol.Hdy tinhnhiCt t4o thdnhti6u chu6ncriaHzS(,t)vd FeSz(r). Ciu2. I) So sdnhnhiQt.dQ s6i cuadungm6i nguy6n chAtvd dungdich chrtach6ttan kh6ngbay hoi, kh6ng tliQnly 6 cimg 6p su6tngoai. 2) M6.tdungdich nu6c chua ch6ttan khdng bay hoi k6t tinh d 271,5K. X6c dlnh nhiQtdQs6i cuadung dich bi6t hdngs6nghiQm lantrvd hZngs6nghiQm s6i crianu6c16n luqt ld 1,86vd 0,513. Ciu 3. + CIO--* IO- + Cf h0,0606mofl.l.s{.NundngdQ ,625oc,hangs5t5cdQcriaphanimg:f ban dAu cria cric chdt phan img <lubdng 3,5.10- M, sau 300 gi6y n6ng tlQ cta ciic chdt d6 cdn l4i bao nhiu? Ciu 4.

cho'nu#u*"" "' HIY ;:":u";13; HzOz+ 2H-+ 2e Iz + 2e SzOs2-+ 2e

Fe3* + e

2HzO

go: 0,69v qo: 7,77 v qo: 0,535 V, : eo 2rov, qo:0,771V.

HzOzsOd6ng vai trd ld ch6t oxi ho6 hay ch6t khu v<ri citcc{p sau ddy o diAu kien tiOuchuAn:

1) 2)
3)

_ fe-

: 2I_ 2SOo,2^'

Ciu 5. tu hiclro,khi chuachri j dtin spin diQntrl, rmg vdi bu6c nhiy t& . Trong quangph6 ptllt xa nguyGn n" v nt ta chi thu duo. c mQtvachph6. 1) Tinh budc s6ng(nm) cta brlc x4 ph6t ra rlng voi bu6c nhiy cua ilign tu t& mrlc n" = 3 vAnt = 2. \,HAy giin thich sUt6ch vpch fL rinCvo! bu6c nhdy cua tliQntir trl mric n" = 3 vA n1:2 trong quangph6 ph6t x4 nguy6ntu hitho khi c6 chu f diin spincua<liQn tr?. Choh[ng sd Rydberg: 109678 crr'. Ciu 6. Hfly cho bitit danghinh hgc, tr4ng thrii lai ho6 crianguy6ntr?trung tdm vd so siinhg6c li6n kilt cua c6c phAntu trong m6i day sau: 1) PH:, PCI: vd PF:. 2) OFz,OClzvd SFz. CAq 7. l) HAy giai thich t4i saophric chtit [Co(NH3)6]3* nghichtt trong khi phfc chdt 1Cof4] thuantuZ 2) T4i saocdcphric ch6tcua Zn" thudngkh6ngmdu? Cho<tin tich hat nhdncuaCo : 27, Zn: 30.
Ghi chr[: Cdn b0 coi thi kh6ng gidi thich gi thAm.