S GIO DC & O TO TRNG THPT LNG 2 ( c 6 trang)

THI TH I HC LN I NM 2012-2013 MN HA HC Thi gian lm bi: 90 pht, khng k thi gian pht (60 cu trc nghim) M thi 132

Cho bit khi lng nguyn t (theo vC) ca cc nguyn t: H = 1; C = 12; N = 14; O = 16;Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39;Ca = 40; Cr = 52; Fe = 56;Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137

H, tn th sinh:....................................................................................... S bo danh .............................phng thi

I. PHN CHUNG DNH CHO TT C TH SINH (t cu 1 n cu 40) Cu 1: t chy hon ton 0,03 mol hn hp X gm HCOOH, C 2H5OH v CH3COOH, sau phn ng thu c 2,20 gam CO2 v 1,08 gam H2O. Nu nh t t dung dch Na 2CO3 0,50M vo 0,30 mol hn hp X, n khi khng c kh thot ra th thu c V lt kh CO2 (ktc). Gi tr V l A. 4,48. B. 2,24. C. 0,448. D. 0,224. Cu 2: Cho m gam Mg vo dung dch c cha 0,8 mol Fe(NO 3)3 v 0,05 mol Cu(NO3)2 , n phn ng hon ton thu c 14,4 gam cht rn.Gi tr ca m l A. 15,6 gam. B. 8,4 gam. C. 6 gam. D. 24 gam Cu 3: t chy hon ton m gam hn hp X gm hai ancol thu c 0,35 mol CO 2 v 0,6 mol H2O. Mt khc, nu cho m gam X tc dng ht vi 10,35 gam Na thu c (10+m) gam cht rn. Cng thc phn t ca hai ancol trong X l. A. C2H5OH v C3H6(OH)2 B. CH3OH v C2H4(OH)2 C. C2H5OH v C3H5(OH)3 D. CH3OH v C3H6(OH)2 Cu 4: Hn hp X gm hai anhit. t chy hon ton 0,25 mol X thu c 0,3 mol CO2. Mt khc, nu cho 0,25 mol X tc dng ht vi dung dch AgNO 3/NH3 d, thu c 0,9 mol Ag. Cng thc cu to thu gn ca hai anhit trong X l. A. HCHO v CH3-CHO B. HCHO v CH3 -CH2-CHO C. CH3CHO v OHC-CHO D. HCHO v HOC-CHO Cu 5: Cho 0,5 gam hn hp X gm Li, Na, K vo nc thu c 2 lt dung dch c pH = 12. Trn 8 gam hn hp X v 5,4 gam bt Al ri cho vo nc n phn ng hon ton c V lt kh thot ra(ktc).Gi tr ca V l: A. 8,064 B. 10,304 C. 11,648 D. 8,160 Cu 6: Cho 4,48 gam hn hp gm CH 3COOC2H5 v CH3COOC6H5 (c t l mol l 1:1) tc dng vi 800 ml dung dch NaOH 0,1 M thu c dung dch X. C cn dung dch X th khi lng cht rn thu c l A. 4,88 gam. B. 6,4 gam C. 5,6 gam. D. 3,28 gam Cu 7: R l nguyn t m nguyn t c phn lp electron ngoi cng l np 2n+1 (n l s th t ca lp electron). C cc nhn xt sau v R: (I) Tng s ht mang in ca nguyn t R l 18. (II) S electron lp ngoi cng trong nguyn t R l 7. (III) Cng thc ca oxit cao nht to ra t R l R2O7. (IV) Dung dch NaR tc dng vi dung dch AgNO3 to kt ta. S nhn xt ng l: A. 4 B. 3 C. 2 D. 1 Cu 8: Khi cho Cu vo dung dch FeCl3; H2S vo dung dch CuSO4; HI vo dung dch FeCl3; dung dch AgNO3 vo dung dch FeCl3; dd HCl vo dung dch Fe(NO3)2. s cc cht phn ng c vi nhau l: A. 4 B. 2 C. 5 D. 3
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Cu 9: Cho dy cc cht: andehit fomic, axit axetic, etyl axetat, axit fomic, ancol etylic, metyl fomiat, axetilen, vinyl axetilen, etylen, glucozo, saccarozo. S cht trong dy tham gia phn ng c vi dung dch AgNO3/NH3 l A. 3 B. 6 C. 7 D. 5. Cu 10: Cho V lt hn hp kh X gm H2, C2H2, C2H4 , trong s mol ca C2H2 bng s mol ca C2H4 i qua Ni nung nng (hiu sut t 100%) thu c 11,2 lt hn hp kh Y ( ktc), bit t khi hi ca hn hp Y i vi H2 l 6,6. Nu cho V lt hn hp X i qua dung dch Brom d th khi lng bnh Brom tng A. 5,4 gam. B. 4,4 gam. C. 2,7 gam. D. 6,6 gam. Cu 11: Pht biu no sau y l ng? A. Nhng nguyn t c cng s khi thuc cng mt nguyn t ho hc. B. Trong tt c cc nguyn t, s proton bng s ntron. C. Ht nhn ca tt c cc nguyn t u c proton v ntron. D. Nguyn t M c Z = 11 thuc chu k 3 nhm IA. Cu 12: Cho cc cht: C2H4(OH)2, CH2OH-CH2-CH2OH, CH3CH2CH2OH, C3H5(OH)3, (COOH)2, CH3COCH3, CH2(OH)CHO. C bao nhiu cht u phn ng c vi Na v Cu(OH)2 nhit thng ? A. 3. B. 2. C. 5. D. 4. Cu 13: Thc hin cc th nghim sau: (1) Ni mt thanh Zn vi mt thanh Fe ri trong khng kh m. (2) Th mt vin Fe vo dung dch CuSO4. (3) Th mt vin Fe vo dung dch cha ng thi ZnSO4 v H2SO4 long. (4) Th mt vin Fe vo dung dch H2SO4 long. (5) Th mt vin Fe vo dung dch cha ng thi CuSO4 v H2SO4 long. Trong cc th nghim trn nhng th nghim Fe b n mn in ha hc l A. (2) v (5). B. (1) v (3). C. (1), (2), (3), (4), (5). D. (3) v (5). Cu 14: Ly 0,3 mol hn hp X gm H 2NC3H5(COOH)2 v H2NCH2COOH cho vo 400ml dung dch HCl 1M th thu c dung dch Y. Y tc dng va vi 800ml dung dch NaOH 1M thu c dung dch Z. Lm bay hi Z thu c m gam cht rn khan, gi tr ca m l A. 38,5 gam B. 71,3 gam C. 47,9 gam D. 61,9 gam Cu 15: Cho m gam Na vo 160 ml dung dch gm Fe 2(SO4)3 0,125M v Al2(SO4)3 0,25M, sau khi cc phn ng kt thc, lc kt ta ri nung n khi lng khng i, thu c 4,73 gam cht rn. Gi tr ln nht ca m l A. 10,35. B. 9,43. C. 11,50. D. 9,20. Cu 16: Cho phng trinh phan ng aFe(NO3)2 + bKHSO4 xFe(NO3)3 + yFe2(SO4)3 + zK2SO4 + tNO + uH2O Trong a, b, x, y, z, t, u l b h s nguyn dng, ti gin ca phng trnh. Tng a + b la A. 43. B. 21. C. 27. D. 9. Cu 17: Cho cc pht biu sau v phenol (C6H5OH): (a) Phenol va tc dng vi dung dch NaOH va tc dng c vi Na. (b) Phenol tan c trong dung dch KOH. (c) Nhit nng chy ca phenol ln hn nhit nng chy ca ancol etylic. (d) Dung dch natriphenolat tc dng vi CO2 to thnh Na2CO3. (e) Phenol l mt ancol thm. S pht biu ng l A. 4. B. 3. C. 5. D. 2.

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Cu 18: trung ho lng axit t do c trong 14 gam mt mu cht bo cn 15 ml dung dch KOH 0,1M. Ch s axit ca mu cht bo trn l A. 5,5. B. 4,8. C. 7,2. D. 6,0. Cu 19: A l hn hp kh gm SO2 v CO2 c t khi hi so vi H2 l 27. Dn a mol hn hp kh A qua bnh ng 1 lt dd NaOH 1,5a M, sau phn ng c cn dung dch thu c m gam mui. Biu thc lin h gia m v a l A. m=103.5a B. m=105a C. m=141a D. m=116a Cu 20: Cho dy cc cht: Cu, CuO, Fe3O4, C, FeCO3, Fe(OH)3. S cht trong dy tc dng vi H2SO4 c, nng, d khng to kh SO2 l A. 3. B. 4. C. 2. D. 1. Cu 21: Qu trnh sn xut amoniac trong cng nghip da trn phn ng thun nghch sau: 2NH3(k). N2(k) + 3H2(k) H = -92 kJ Khi phn ng t ti trng thi cn bng, nhng thay i no di y lm cho cn bng chuyn dch theo chiu thun to ra nhiu amoniac: (1) Tng nhit ; (2) Tng p sut; (3) Thm cht xc tc; (4) Gim nhit ; (5) Ly NH3 ra khi h A. (1), (2), (3), (5). B. (2), (4), (5). C. (2), (3), (4), (5). D. (2), (3), (5). 2Cu 22: Phn ng c phng trnh ion rt gn: HCO3 + OH CO3 + H2O l A. NaHCO3 + HCl NaCl + CO2 + H2O. B. Ca(HCO3) + 2NaOH CaCO3 + Na2CO3 + 2H2O. C. 2NaHCO3 + Ca(OH)2 CaCO3 + Na2CO3 + 2H2O.D. 2NaHCO3 + 2KOH Na2CO3 + K2CO3 + 2H2O Cu 23: Cho t t 150 ml dd HCl 1M vo 500 ml dd A gm Na 2CO3 v NaHCO3 th thu c 1,008 lt kh (ktc) v dd B. Cho dd B tc dng vi dd Ba(OH) 2 d th thu c 29,55 g kt ta. Nng mol ca Na2CO3 v NaHCO3 trong dd A ln lt l: A. 0,2M v 0,4M B. 0,18M v 0,26M C. 0,21M v 0,32M D. 0,21M v 0,18M Cu 24: Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO3 th u sinh ra a mol kh. Cht X l A. ancol o-hiroxibenzylic. B. axit aipic. C. etylen glicol D. axit 3-hiroxipropanoic. Cu 25: Trong cc cht: xiclopropan, xiclohexan, benzen, stiren, axit axetic, axit acrylic, anehit axetic, anehit acrylic, axeton, etyl axetat, vinyl axetat, imetyl ete. S cht c kh nng lm mt mu nc brom l: A. 6. B. 7. C. 4. D. 5. Cu 26: Cho cc phn ng: K2Cr2O7 + 14HBr 3Br2 + 2KBr + 2CrBr3 + 7H2O Br2 +2NaI 2NaBr + I2 Khng nh no sau y l ng? 3+ A. Tnh kh: Cr > I B. Tnh oxi ho: I2 > Br2 C. Tnh kh: Br > Cr3+ D. Tnh oxi ho: I2 > Cr2O7 Cu 27: Ho tan ht m gam Fe bng 400 ml dung dch HNO 3 1M. Sau khi phn ng xy ra hon ton thu c dung dch cha 26,44 gam cht tan v kh NO (sn phm kh duy nht). Gi tr ca m l A. 12,24. B. 5,60. C. 6,12. D. 7,84. Cu 28: Ha tan ht 15,55 gam hn hp X gm Fe, Mg, Al v Zn vo dung dch HCl d, sau phn ng thu c 0,4 mol H2 . Mt khc, nu oxi ha hon ton hn hp X trn trong O 2 d, thu c 23,15 gam cht rn Y. Phn trm khi lng ca Fe trong X l. A. 81,03 B. 36,01 C. 64,82 D. 54,02 Cu 29: t chy hon ton mt hn hp X (gm glucoz, anehit fomic, axit axetic) cn 2,24 lt O 2 (ktc). Dn sn phm chy qua bnh ng dung dch Ca(OH)2 (d), thy khi lng bnh tng m gam. Gi tr ca m l A. 12,4 B. 3,1 C. 6,2 D. 4,4
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Cu 30: in phn (in cc tr, mng ngn xp) dung dch X thy pH tng, dung dch Y thy pH gim. Vy dung dch X v dung dch Y no sau y ng: A. (X) KBr, (Y) Na2SO4 B. (X) BaCl2, (Y) CuSO4 C. (X) NaCl, (Y) HCl D. (X) AgNO3, (Y) BaCl2 Cu 31: Cho cc cht: Al, Al2O3, Al2(SO4)3, Zn(OH)2, NaHS, K2SO3, (NH4)2CO3. S cht u phn ng c vi dung dch HCl, dung dch NaOH l A. 5. B. 4. C. 7. D. 6 Cu 32: un nng cht H2N-CH2 -CONH-CH(CH3)-CONH-CH2 -COOH trong dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l: A. H2N-CH2-COOH, H2N-CH2-CH2-COOH. B. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl-. C. H2N-CH2-COOH, H2N-CH(CH3)-COOH. D. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl-. Cu 33: Nhit phn cc mui sau: NH 4NO2, NaHCO3, CaCO3, KMnO4, NaNO3, Cu(NO3)2. S phn ng nhit phn thuc loi phn ng oxi ho - kh l A. 3. B. 4. C. 5. D. 6. Cu 34: Thu phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32gam Ala-Ala v 27,72 gam Ala-Ala-Ala .Gi tr m l A. 88,2 B. 90,6 C. 81,54 D. 111,74 Cu 35: Cho hn hp gm 3,36 gam Mg v 0,4 gam MgO tc dng vi dung dch HNO 3 long d thu c 0,448 lt kh X duy nht (ktc). C cn dung dch sau phn ng thu c 23 gam cht rn khan. S mol HNO 3 phn ng l: A. 0,32 mol B. 0,28 mol C. 0,34 mol D. 0,36 mol Cu 36: S ng phn ca C3H9O2N khi tc dng vi NaOH un nng cho sn phm kh c th lm xanh qu tm m . A. 4 B. 3 C. 2 D. 1 Cu 37: Cho cc cp cht sau: (a) Kh Cl2 v kh O2. (b) Kh H2S v kh SO2. (c) Kh H2S v dung dch Pb(NO3)2. (d) CuS v dung dch HCl. (e) Kh Cl2 v dung dch NaOH. S cp cht xy ra phn ng ho hc nhit thng l A. 3. B. 1. C. 4. D. 2. Cu 38: T m (kg) khoai c cha 25% tinh bt, bng phng php ln men ngi ta iu ch c 100 lt dung dch ancol etylic 600. Bit khi lng ring ca C2H5OH l 0,8 g/ml, hiu sut chung ca c qu trnh l 90%. Gi tr ca m l A. 338,09kg B. 375,65kg C. 93,91kg D. 676,2kg. Cu 39: Cho 17,80 gam bt Fe vo 400 ml dung dch gm Cu(NO 3)2 0,40M v H2SO4 0,50M. Sau phn ng thu c m gam hn hp kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr m v V l A. 11,20 v 3,36. B. 11,20 v 2,24. C. 10,68 v 3,36. D. 10,68 v 2,24. Cu 40: Hn hp X gm: Na, Ca, Na2O v CaO. Ha tan ht 5,13 gam hn hp X vo nc thu c 0,56 lt H2 (ktc) v dung dch kimY trong c 2,8 gam NaOH. Hp th 1,792 lt kh SO 2 (ktc) vo dung dch Y thu c m gam kt ta. Gi tr ca m l A. 5,4. B. 6,0. C. 7,2. D. 4,8.

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II. PHN RING. Th sinh ch c lm mt trong hai phn: phn 1 hoc phn 2 1.PHN 1: DNH CHO TH SINH THEO CHNG TRNH CHUN (10 cu, t cu 41 n cu 50) Cu 41: So snh no di y khng ng? A. Al(OH)3 v Cr(OH)3 u l cht lng tnh v va c tnh oxi ha va c tnh kh. B. BaSO4 v BaCrO4 u l nhng cht khng tan trong nc. C. Fe(OH)2 v Cr(OH)2 u l baz v l cht kh. D. H2SO4 v H2CrO4 u l axit c tnh oxi ha mnh. Cu 42: Ch dng thm mt thuc th trnh by cch nhn bit cc cht rn sau. NaOH, Al, ZnO, CaCO 3 A. Qu tm B. Dung dch kim C. Nc D. Dung dch axit Cu 43: Dn khi CO d qua hn hp nung nong Al, Al 2O3, MgO, FeO. Sau khi phan ng hoan toan thu c hn hp rn gm A. Al, Al2O3, MgO, Fe. B. Al, MgO, Fe C. Al, Mg, Fe D. Fe Cu 44: Cho 6,9 gam hn hp X gm 2 ancol no, n chc (Y v Z) tc dng vi Na d thu c 1,68 lt H2(ktc). Cn khi oxi ho 6,9 gam hn hp X bi CuO d, nung nng thu c hn hp T gm 2 sn phm hu c tng ng vi Y v Z. Cho T tc dng vi lng d dung dch AgNO 3 trong NH3 th thu c 43,2 gam Ag. Cng thc hai ancol trong axit l: A. CH3OH v CH3CH(CH3)CH2OH B. CH3OH v CH3CH(OH)CH3 C. CH3OH v CH3CH(OH)CH2CH3 D. CH3CH2OH v CH3CH2CH3OH Cu 45: Cho dy cc cht: but-2-en, axit acrylic, propilen, ancol anlylic, 2-metylhex-3-en, axit oleic, hexa1,4-ien, stiren. S cht trong dy c ng phn hnh hc l A. 5. B. 6. C. 4. D. 7. Cu 46: S ng phn ca dn xut halogen c cng thc phn t C4H9Br l: A. 5 B. 2 C. 4 D. 3 Cu 47: Hn hp gm hai anhit n chc X v Y c chia thnh hai phn bng nhau: - Phn 1: un nng vi dd AgNO3/NH3 d th to ra 10,8 gam Ag. - Phn 2: oxi ha to thnh hai axit tng ng, sau cho hai axit ny phn ng vi 250 ml dung dch NaOH 0,26M c dung dch Z. trung ha lng NaOH d trong dung dch Z cn dng ng 100 ml dung dch HCl 0,25M. C cn dung dch Z ri em t chy cht rn thu c sau khi c cn, c 3,52 gam CO 2 v 0,9 gam H2O. Cng thc phn t ca hai anhit X v Y l: A. HCHO v C2H5CHO. B. HCHO v C2H3CHO C. HCHO v CH3CHO D. CH3CHO v C2H5CHO. Cu 48: Cho 0,1 mol hp cht ha c c CTPT CH6O3N2 tc dng vi dd cha 0,2 mol NaOH un nng, sau khi phn ng xy ra hon ton thu c cht kh lm xanh giy qu tm m v dung dch Y. C cn dung dch Y thu c m gam rn khan. Gi tr ca m l A. 12,5 B. 21,8 C. 8,5 D. 15 Cu 49: Cho dng H2 i qua ng s ng 0,2 mol hn hp FeO v Fe 2O3 nung nng sau mt thi gian thu c 1,89 gam H2O v 22,4 gam hn hp cht rn X. Ho tan hon ton cht rn X trong dung dch HNO 3 thu c V lit kh NO (ktc) l sn phm kh duy nht. Gi tr ca V l A. 0,75 B. 2,24 C. 3,73 D. 4,48 Cu 50: Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na 2O v Al2O3; Cu v Fe2(SO4)3; BaCl2 v CuCl2 ; Ba v NaHSO4. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l A. 2. B. 4. C. 1. D. 3.

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2. PHN 2. DNH CHO TH SINH THEO CHNG TRNH NNG CAO (t cu 51 n cu 60) Cu 51: Dung dch Y gm CH3COOH 0,1M v HCl 0,005M. Bit 25 oC Ka ca CH3COOH l 1,75.10-5. Gi tr pH ca dung dch Y 25oC l A. 1,77. B. 2,30. C. 2,33. D. 2,27. Cu 52: Hp cht X c cng thc phn t C 4H8O3. Cho 10,4 gam X tc dng vi dung dch NaOH (va ) thu c 9,8 gam mui. cng thc cu to ng ca X l A. CH3COOCH2CH2OH B. HOCH2COOC2H5. C. HCOOCH2CH2CHO D. CH3CH(OH)-COOCH3 Cu 53: X l mt tripeptit c to thnh t 1 aminoaxit no, mch h c 1 nhm -COOH v 1 nhm -NH 2 .t chy hon ton 0,3 mol X cn 2,025 mol O 2 thu c sn phm gm CO2 ,H2O , N2. Vy cng thc ca amino axit to nn X l A. H2NCH2COOH B. H2NC3H6COOH C. H2NC4H8COOH D. H2NC2H4COOH Cu 54: Hn hp kh A gm CO v H 2 c t khi i vi hiro bng 4,25, hn hp kh B gm O 2 v O3 c t khi i vi H2 l 20. t chy hon ton 10V lt kh A cn lng th tch hn hp kh B l: (cc kh o cng iu kin nhit , p sut) A. 10V B. 6V C. 4V D. 8V Cu 55: Ancol bc ba, mch h X c cng thc phn t C5H10O. T X ngi ta thc hin s bin ho sau: +Br +NaOH X C5H10OBr2 C5H12O3 (cht Y). Dy cc cht u c th tc dng c vi Y l: A. Na2O, NaHCO3, v CH3OH (xc tc H2SO4 c, to). B. Na, NaOH, v CH3COOH (xc tc H2SO4 o c, t ). C. NaHCO3, NaOH v Cu(OH)2. D. Na, Cu(OH)2, v C2H5OH (xc tc H2SO4 c, to). Cu 56: Cp dung dch no sau y u c pH nh hn 7? A. Dung dch AlCl3 v dung dch NaHSO4. B. Dung dch NH3 v dung dch NH4Cl. C. Dung dch Na2SO4 v dung dch NaHSO4. D. Dung dch NaOH v dung dch Na2CO3. Cu 57: Cho 3 kim loi X,Y,Z bit E o ca 2 cp oxihoa - kh X2+/X = -0,76V v Y2+/Y = +0,34V. Khi cho Z vo dung dch mui ca Y th c phn ng xy ra cn khi cho Z vo dung dch mui X th khng xy ra phn ng. Bit Eo ca pin X-Z = +0,63V. Tnh Eo ca pin to bi hai in cc kim loi Y v Z A. +1,73V B. +0,47 V C. +2,49V D. +0,21V Cu 58: C 6 gi bt ring bit c mu tng t nhau: CuO, FeO, Fe 3O4, MnO2, Ag2O v hn hp Fe + FeO. Thuc th phn bit c 6 gi bt trn l: A. dd HNO3 c B. dd H2O2 C. dd H2SO4 long D. dd HCl Cu 59: Nhng mt l st nh vo dung dch cha mt trong cc cht sau: FeCl 3, ZnCl2, CuSO4, Pb(NO3)2, HCl, NaCl, HNO3, H2SO4 c nng, NH4NO3 (cc dung dch cho u d). S trng hp phn ng to mui Fe(II) l A. 3. B. 5. C. 4. D. 6. Cu 60: in phn 500 ml dung dch hn hp CuSO 4 a mol/l v NaCl 1 mol/l vi in cc tr, mng ngn xp, cng dng in khng i 5A trong thi gian 96,5 pht (hiu sut qu trnh in phn l 100%, nc bay hi khng ng k) thu c dung dch c khi lng gim so vi ban u l 17,15 gam. Gi tr ca a l A. 0,4. B. 0,5. C. 0,2. D. 0,3.
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