Uploads - Toan - Hoa-Hoc-12 - 20 Bo de Thi Thu DH DH Duy Tan

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TRNG AI HOC DUY TAN A NANG
20 B THI TH I hc MN: HO hc
(Lu hnh ni b 20102010-2011)
Sinh Vin : PHAN S TN Lp : K16KKT3
( Bin Son +Su Tm )
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
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S : 01
1. Nguyen t- Bang HTTH Lien ket hoa hoc: (2) Cau 1. Ion AB2- co tong so hat mang ien tch am la 30. Trong o so hat mang ien tch cua A nhieu hn cua B la 10. V tr cua A, B trong bang he thong tuan hoan: a. Ck 2, nhom IIIA va ck 2, nhom VIA. b. Ck 3, nhom IIIA va ck 2, nhom VIA. c. CK3, nhom IIIA va ck 3, nhom VIA. d. CK2, nhom IIA va ck 3, nhom VIA. Cau 2. X la nguyen t cha 12 proton, Y la nguyen t cha 17 proton. Cong thc cua hp chat va lien ket hnh thanh gia X va Y la: a. X2Y : lien ket cong hoa tr. b. XY : Lien ket ion. c. XY2 : Lien ket ion. d. X2Y3: Lien ket cong hoa tr. 2. P. oxi hoa kh, can bang hoa hoc: (2) Cau 3. Hoa tan 2,4 gam FeS2 bang H2SO4 ac, nong. Kh thoat ra la SO2. The tch cua H2SO4 5M can e hoa tan va u lng FeS2 tren la: a. 28ml. b. 56 ml c. 72 ml d. 14 ml Cau 4. Cho biet p. hoa hoc sau:
H2 (k) + CO2 (k) H2O (k) + CO (k)
k cb = 0,167 ( 200oC)
Nong o H2 va CO trang thai can bang ?, biet rang hon hp ban au gom 3 mol H2O va 4 mol CO trong bnh V= 10 lt 200oC. a. 0.02M , 0,03M b. 0.03M ; 0,02M C. 0.2M ; 0,3M d. 0.1M; 0,2M 3. S ien li (2). Cau 5. Lng SO3 can them vao 100 gam d.d H2SO4 10% e c d.d H2SO4 20% la: a. 9,756g b. 5,675g c. 3,14g d. 3,4g Cau 6. Xet cac d.d: (1). CH3COONa; (2). NH4Cl ; (3): Na2CO3 ; (4): NaHSO4 (5)NaCl.Cac d.d co pH >7 la: a. (2), (4), (5). b. (1),(3),(4) c. (2),(3),(4),(5) d. (1),(3). 4. Phi kim: (2) Cau 7. Kh Clo tac dung c vi: (1). H2S trong d.d. (2). SO2 trong d.d. (3). NH3. a. (1),(2). b. (2), (3). c. (1), (3) d. (1), (2),(3). Cau 8. T 0,4 mol HCl .che va u 280ml kh Cl2 (dktc) bang p. nao? to to a. MnO + HCl c. KClO3 + HCl to d. (a,b,c) eu ung. b. KMnO4 + HCl 5. ai cng KL: (2) Cau 9. Xet 3 nguyen to co cau hnh electron lan lt la: (X). 1s22s22p63s1. (Y). 1s22s22p63s2 ( Z). 1s22s22p63s23p1. Hiroxit cua X,Y,Z xep theo th t tnh baz tang dan. a. XOH < Y(OH)2 < Z(OH)3. c. Z(OH)3 <Y(OH)2 < XOH. b. Y(OH)2 < Z(OH)2 < XOH. d. Z(OH)3 < XOH < Y(OH)2. Cau 10. Cho dong ien 10A qua 400cm3 d.d H2SO4 0,5M( ien cc tr). T.gian ien phan e thu c d.d H2SO4 0,6M la: a. 5676 giay b. 11258 giay c. 71410 giay d. 83260 giay. 6. KL PNC IA, IIA, Nhom, Sat.(6) Cau 11. Tap hp nhng chat ran nao sau ay tan c trong d.d kiem: a. Al, Al2O3, Al(OH)3, Cr2O3, MgO. c. Al, Zn, Al2O3, ZnO, Cr(OH)3, NaCl. b. ZnO, Be, Ba(OH)2, Mg(OH)2, Al(OH)3. d. Na2O, NaNO3, Al2O3, ZnCl2, CaCO3. Cau 12. D.d AlCl3 trong nc b thuy phan, neu them vao d.d chat sau ay, chat nao lam tang cng qua trnh thuy phan cua AlCl3. a. NH4Cl. b. Na2CO3. c. ZnSO4 d. HCl. Cau 13. Co 3 d.d NaOH , HCl , H2SO4. Thuoc th duy nhat e phan biet 3 d.d o la: a. Na2CO3. b. Al c. CaCO3 d. Quy tm.
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Cau 14. D.d A cha NaOH 1M va Ca(OH)2 0,01M. Suc 2,24 lt kh CO2 vao 400 ml d.d A thu c mot ket tua co khoi lng a. 2 g b. 3 g c. 0,4g d. 1,5g. Cau 15. Hoa tan hoan toan Al va Mg bang d.d HCl d thu c 8,96 lt kh ( ktc). mac khac khi cho mot lng hon hp nh tren vao d.d KOH d thu c 6.72 lt kh ktc. Phan tram khoi lng cua Al trong hon hp au la: a. 30,77% b. 34,62% c, 69,23% d. 53,34% Cau 16.100 ml d.d Al2(SO4)3 tac dung vi 100 ml d.d Ba(OH)2, Nong o mol cua d.d Ba(OH)2 bang 3,0 lan nong o cua Al2(SO4)3 thu c ket tua A. Nung A en khoi lng khong oi th thu c chat ran B ( mA - mB = 5,4), Nong o mol/lit cua Al2(SO4)3 va Ba(OH)2 la: e 4 a. 0,5M va 1,5M b. 1M va 3,0M c. 0,6M va 2,1M d. 0,4M va 1,4M. 7. ai cng ve hp chat hu c va hirocacbon: (2) Cau 17. Trong cac hirocacbon : (1). n butan. (2). buten -2. (3). Propan. (4). Butin -2. (5). Xiclobutan. Nhng chat la ong phan cua nhau: a. 1 va 4 b. 1 va 3 c. 2 va 4 d. 2 va 5 Cau 18.Hon hp X ban au gom 9 lt H2, 4 lt etylen va 1 lt propin, 1 lt propan un nong hon hp X vi bot niken lam chat xuc tac thu c h.hp Y. % The tch hiro trong hon hp Y ( o dung ieu kien) la: a).33,33% b).40% c).50,27% d). 35% 8. Ru phenol (3). Cau 19. Khi cong nc vao buten -1 ( xuc tac H2SO4 loang) san pham chnh la chat nao? a. n-butanol. b. iso butylic. c. sec butylic. d. tert butylic. Cau 20. Chon s o tach phenol va benzen ung. Phenol phenol phenol benzen benzen H2O chie t chiet (1). Benzen Tach lp (2). benzen +KOH (3). benzen + ddBr2
phenol phenol phenolatkali benzen
20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
C6H6 chiet C6H5OK +CO2 Phenol. H + H O C 6 6 2 benzen loc C6H2Br3OH phenol C6H2Br3OH + HCl
a.(1), (2). b. (2). c. (2),(3) d. (1), (2), (3). Cau 21. un nong hon hp hai ru n, n chc vi H2SO4 ac nhiet o 140oC, thu c 21,6 gam H2O va 72 gam hon hp 3 ete. Biet 3 ete co so mol bang nhau va p. xay ra hoan toan. CTCT cua hai ru. a. C3H7OH va CH3OH. c. CH3OH va C2H5OH. b. C2H5OH va C3H7OH. d. C2H5OH va C4H9OH. 9. Anehit axit propionic. (3) Cau 22. Hai chat hu c A va B. Cho 0,1 mol moi chat tac dung vi NaOH d lan lt thu c cac muoi Natri co khoi lng tng ng la 9,4 gam va 6,8 gam. Vay cong thc tng ng cua A va B la: b. CH2=CH-COOH va HCOOCH=CH2. a. CH3COOCH3 va HCOOCH3. c. C2H5COOH va CH3COOCH3. d. HCOOCH3 va CH3COOCH3. Cau 23. ot chay hoan toan 0,1 mol hp chat X la muoi Natri cua axit hu c thu c 0,15 mol CO2. CTCT cua muoi la: a. C2H5COONa. b. C3H7COONa. c. HCOONa. d. CH3COONa. Cau 24. Hon hp gom Anehit fomic, axit fomic, axit axetic co khoi lng 3,78 gam. Hon hp p. vi lng d d.d AgNO3 th thu c 15,12 gam Ag. Mac khac mot na hon hp p. va u vi d.d cha 1.2 gam NaOH. % Khoi lng cua anehit fomic, axit fomic, axit axetic lan lng la: a. 15,87% - 36,5% - 47,63%. b. 25,17% - 32,25% - 42,58% c. 18,26% - 37,86% - 43,88%. d. 15,87% , 36,4%; 47,73%. 10. Este Lipit. (3). Cau 25. Khi un nong este CH3COOCH2CH3. vi xuc tac la H2SO4 loang ( qua trnh 1). Va un nong CH3COOCH=CH2 trong moi trng kiem.( qua trnh 2) . ac iem nao sau ay ung: a. (1) Mot chieu, (2) mot chieu. c. (1) thuan ngch, (2) mot chieu. b. (1) mot chieu, (2) thuan ngch. d. (1) thuan ngich, (2) thuan nghich. Cau 26. Thuy phan hoan toan m gam lipit c hnh thanh 1 axit panmitic va 2 axit eloic bang d.d KOH. ( ch so axit cua lipit = 0). Lng Glixetin va tao ra p. vi Na d thu c 67,2 lt kh H2 ( ktc). Vay khoi lng cua lipit ban au la ( gia s cac p. xay ra hoan toan). a. 1,716kg. b. 1,704kg c. 1,76kg d. 1,762kg. Cau 27. Este co Phan t lng la 88. Cho 17.6 gam A tac dung vi 300 mld.d NaOH 1M un nong. Sau o em co can hon hp sau p. thu c 23.2 gam ba ran khan. CTCT cua A la: a. HCOOCH2CH2CH3. b. C2H5COOCH3. c. CH3COOC2H5. d. HCOOCH CH = CH2
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11. Amin- aminoaxit protein. (2) Cau 28. Axit Aminoaxetic khong co tnh chat nao sau ay: (1). Tac dung vi Na. (3). Trung ngng. (5). lam quy tm hoa o. (2). Tac dung vi ru. (4) Tac dung vi HCl. (6). Tac dung vi muoi Na2CO3. a. (3). b. (4),(5) c. (6) d. (5). Cau 29. S ket tua protit khi un nong c goi la: e 4 a. S trung ngng. b. S ngng tu. c. S phan huy. d. S ong tu. 12. Gluxit. (2). Cau 30. e nhan biet c Saccaroz va Fructoz ta dung nhng thuoc th nao sau ay. a. Cu(OH)2/OHbAgNO3/NH3. c. Cu(OH)2. c. H2SO4 loang, AgNO3/NH3 Cau 31. Len men Glucoz thu c m gam ru etylic ( Hieu suat 50%). Lng Glucoz con lai tiep tuc len men thu c m gam ru etylic (Hieu suat at 50%). Lng ru va ieu che c co the pha thanh 50 lt ru 40o ( Biet khoi lng rieng cua ru nguyen chat la 0,8g/ml). Vay khoi lng cua glucoz ban au em len men la: a. 31,3kg b. 41,74 kg c. 62,6kg d. 23,5kg. 13. Polime va vat lieu polime: (1) Cau 32. Trong cac polime sau. Polime nao la polime thien nhien: (1). Tinh bot. (3). Xenluloz. (5). Caosu isopren. (7). T Capron. (2). Caosubuna. (4). P.V.C (6). Nilon 6-6. a. (1), (2), (3). b. ( 1), (4), (6), (7). c. (1), (3), (5). d. (1), (3), (7). 14. Tong hp hoa vo c(6). Cau 33. Cho mot d.d gom NaNO3, KNO3, Ba(NO3)2. Cho t t bot Al vao, sau o nho tiep tuc d.d X vao th thay co kh Y bay ra. D.d X va kh Y la: (1). NaOH, NH3 (2). H2SO4 loang, NO (3). HCl, H2. (4). KOH va H2. a. (1), (3). b. (3), (4). c. (1), (2). d. (2). Cau 34. Hoa tan 1,44 gam kim loai hoa tr II trong 150 mld.d H2SO4 0,5M. Muon trung hoa axit d trung d.d thu c phai dung het 30ml d.d xut co nong o 1M. Kim loai tren la: a. Ca b. Mg c. Zn d. Cu Cau 35. ot chay hoan toan 8.96 lt kh SO2 ( ktc ) roi dan tat ca san pham chay cho vao 50 ml d.d NaOH 25% ( d = 1,28g/ml). Nong o C% cua muoi trong trong d.d. a. 42,97% va 25,5% b. 35,28% c. 27,18% va 35% d. 50%. Cau 36. Khi in phan hn hp dung dch NaCl va CuSO4, nu dung dch sau khi in phan hoa tan Al2O3 thng xy ra trng hp nao sau ay d. NaCl va CuSO4 b .phan ht. a.NaCl d b. NaCl d hoc CuSO4 d c. CuSO4 d Cau 37. Ngm mt vt bng Cu co khi lng 20g trong 100g dung dch AgNO3 4%. Khi ly vt ra th khi lng AgNO3 trong dung dch gim 17%. Khi lng vt sau phn ng la bao nhhiu: a.10,76g b. 21,52g c 20,304g d. 20,608 g Cau 38. Cho 2a mol NO2 vao dd cha a mol Ba(OH )2 . Them tiep vai giot dd phenolphthalein vao bnh p se thay: b. Luon khong mau a. Khong mau o c. Luon co mau o d. o Khong mau .
20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
15. Tong hp hu c: (6).

Cu 39: Trong s cc tn gi sau ten goi nao ung. 3 metyl butan (1); 3,3 dimetylbutan (3) 2,3 dimetyl butan (2); 2,3,3 trimetyl butan (4), a.(1) b. (2) c. (1) (2) v (4) d. (1),(2),(3),(4) Cau 40. Hon hp kh nao sau ay co the c tach cac chat kh hoan toan bang phng phap hoa hoc pho bien. A. C2H6, SO2, C2H2, C2H4. B. C2H6, C2H4, CO2, C3H8. C. C2H4, C3H6, SO2, C2H2. D. C2H2, CO2, CH4, C3H4. Cau 41. Cho hn hp co khoi lng m gam gom 2 ankin la ong ang lien tiep nhau. Chia hon hp thanh 2 phan bang nhau. Phan 1: Cho suc qua d.d nc brom lay d, thay k.lng brom a tham gia p.ng la 22,4 gam. Phan 2: ot chay hoan toan, san pham chay cho qua d.d nc voi trong lay d th thay khoi lng cua bnh tang 14,24 gam. CTPT va m la: a. C2H2, C3H4 va 6,72gam. c. C3H4 , C4H6 va 6,72 gam. b. C2H2, C3H4 va 3,36gam. d. C3H4 , C4H6 va 3,36gam. Cau 42. Day xap xep s tang dan nhiet o soi ung la: a. HCHO < CH3OH < HCOOH< C3H7OH. C.CH3OCH3 < CH3OH < CH3CHO < CH3COOH. CH3OH < CH3COOH < C2H5OH < C3H7OH. D.CH3OCH3<CH3CHO < CH3OH < CH3COOH.
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Cau 43. Cho 10,8 gam hn hp 2 ru A ,B tc dng Na va , thu c 17,4 gam mui Na.S mol kh H2 thot ra l: a.0,15 mol b. 1,5 mol c. 3 mol d. 3,2 mol + NaOH CuO , t o +O Cau 44. Ru X nao sau ay thoa man s o: X T. Y Z ( Mn ,t )
2+ 2 0
20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
(1) CH3CH2OH. (2) (CH3)2CH-OH. (3) CH3 C(CH3)2OH. A. (1),(2). B. (1), C. (2),(3). D. (1),(2),(3). 15. Phan t chon cua th sinh: ( 6 ) Nhom , sat(2) Cau 45. Nung nong hon hp gom Al va Fe2O3 co khoi lng la 3.01 gam cho p. xay ra hoan toan. Chat ran sau p. hoa tan trong NaOH d thay thoat ra 1,008 lit H2 ( ktc). % khoi lng cua Al va Fe2O3 trong hon hp ban au: a . %Al 45%, %Fe2O3 55% b . %Al 37%, % Fe2O3 63% c . %Al 29%, %Fe2O3 71% d . %Al 42%, %Fe2O3 58%. Cau 46. Co ba lo ng ba hon hp Fe, FeO ; Fe + Fe2O3; FeO va Fe2O3. Giai phap lan lt dung cac thuoc th nao di ay e nhan biet c ca 3 hon hp tren: a. Dung dd HCl sau o them NaOH vao dd thu c. b. Dung H2SO4 am ac, sau o them NaOH vao dd thu c. c. Dd HNO3 loang, sau o them NaOH vao dd thu c. d. Them dd NaOH, sau o them tiep H2SO4 ac. Day ien hoa cua KL (1) Cau 47.Nhung mot thanh Zn vao dung dch Co2+, nhan thay co mot lp Co phu ben ngoai. Khi nhung la Pb vao dung dch muoi tren khong thay co hien tng g? Vat trat t cua day ien hoa la: c. Zn2+/Zn < Co2+/Co<Pb2+/Pb. a. Zn2+/Zn < Pb2+/Pb < Co2+/Co. 2+ 2+ 2+ D. Co2+/Co < Pb2+/Pb< Zn2+/Zn. b. Co /Co < Zn /Zn < Pb /Pb. Hirocacbon va dan xuat hirocacbon(3). Cau 48. ot hoan toan hon hp X gom: etan, propan thu c san pham gom CO2 va hi nc co the tch la 33 lt. Thanh phan % theo so mol tng ng cua etan va propan tng ng la: a. 20 va 80 b. 50 va 50 c. 25 va 75 d.75 va 25. Cau 49. un nong 21.8gam chat A vi 1 lt dung dch NaOH 0.5M thu c 24.8 gam muoi cua axit mot lan axit va mot lng ru B. Neu cho lng ru o bay hi chiem the tch la 2.24 lt. Lng NaOH d c trung hoa bi 2 lt dung dch HCl 0.1M. Cong thc cau tao cua A la: c. (CH3COO)3C3H5. a. (HCOO)3C3H5. b. (C2H5COO)3C3H5. d. (CH3COO)2C2H4. Cau 50. e ra sach bnh ng anilin ta co the dung d.d nao sau ay? a. Dung dch NaOH, sau o ra sach bang nc lanh. b. Dung dch HCl, sau o ra sach bang nc lanh. c. Dung dch Na2CO3. sau o ra sach bang nc nong. d. Dung dch H2O co hoa tan CO2. Sau o ra sach bang nc nong. P N 1. B 2. C 3. A 4. C 5. A 6. D 7. D 8. B 9. C 10. C 11. C 12. B 13. C 14. C 15. C 16. B 17. D 18. A 19. C 20. A 21. C 22. B 23. D 24. A 25. C 26. A 27. B 28. D 29. D 30. D 31. B 32. C 33. A 34. B 35. D 36. B 37. C 38. A 39. B 40. A 41. C 42. D 43. A 44. A 45. A 46. A 47. C 48. A 49. C 50. B
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Cau 1: Hoa tan mot lng oxit Fe trong d.d H2SO4 loang, d. Chia d.d thu c sau phan ng thanh hai phan. Nho d.d KMnO4 vao phan 1 thay mau tm bien mat. Cho bot ong kim loai vao phan 2 thay bot ong tan, d.d co mau xanh. Cong thc cua oxit Fe a dung la: A. FeO B. Fe2O3 C. Fe3O4 D. FeO hoac Fe3O4. Cau 2: Cho phan ng sau ay: N2 + 3H2 2NH + Q 3 Khi tang ap suat, can bang chuyen dch theo chieu nao? A. Chieu nghch B. Chieu giam nong o NH3
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C. Chieu toa nhiet. D. Chieu tang so phan t kh. Cau 3. Cho 2 d.d H2SO4 co pH =1 va pH =2. Them 100 ml d.d NaOH 0,1M vao 100 ml moi d.d tren. Nong o mol/lt cua muoi trong d.d sau phan ng la: A. 0,025M va 0,0025M. B. 0,25M va 0,025M. C. 0,25M va 0,0025M. D. 0,025M va 0,25M. Cau 4. Nhom cac d.d nao sau ay eu co chung mot moi trng : ( axit, baz hay trung tnh). A. Na2CO3, KOH, KNO3. B. HCl, NH4Cl, K2SO4. C. H2CO3, (NH4)2SO4, FeCl3. D. KMnO4, HCl, KAlO2. Cau 5. Phat bieu nao sau ay ung? A. Axit la nhng chat co kha nang nhan proton. B. D.d CH3COOH nong o 0,01M co pH =2. C. Chat ien li nguyen chat khong dan c ien. D. D.d muoi se co moi trng trung tnh. Cau 6. Hoa tan 5,6 gam Fe bang d.d H2SO4 loang (d) thu c d.d X. D.d X phan ng va u vi V ml d.d KMnO4 0,5M. Gia tr V la: A. 20ml B. 80 ml C. 40 ml D. 60 ml. Cau 7. Trong phong th nghiem ngi ta ieu che kh Cl2 bang cach: A. Cho F2 ay Cl2 ra khoi muoi NaCl. B. Cho dd HCl ac tac dung vi MnO2 , un nong. C. ien phan NaCl nong chay. D. ien phan d.d NaCl co man ngan. Cau 8. Nung 15,4g hon hp gom kim loai M va hoa tr II va muoi nitrat cua no en ket thuc phan ng. Chat ran con lai co khoi lng 4,6g cho tac dung vi d.dch HCl thu c 0,56 lt H2 (ktc). M la kim loai nao?. A. Mg B. Cu C. Zn D. Fe Cau 9. Cho a mol Al vao d.d cha b mol Cu2+ va c mol Ag+. Ket thuc phan ng thu c d.d cha 2 loai ion kim loai. Ket luan nao sau ay la ung: A. c/3 a 2b/3. B. c/3 a c/3 + 2b/3 C. c/3 a < c/3 + 2b/3 D. 3c a 2b/3. Cau 10. Cho p gam Fe vao Vml d.d HNO3 1M thay Fe tan het, thu c 0,672 lt kh NO (ktc). Co can d.d sau phan ng thu c 7,82 gam muoi Fe. Gia tr cua p va V la: A. 2,24 gam va 120 ml. B. 1,68 gam va 120 ml. C. 1,8 gam va 129 ml. C. 2,43 gam va 116 ml Cau 11. ien phan d.d CuCl2 vi ien cc tr, sau mot thi gian thu c 0,32 gam Cu catot va mot lng kh X anot. Hap thu hoan toan lng kh X tren vao 200 ml d.d NaOH ( nhiet o thng). Sau phan ng nong o NaOH con lai la 0,05M ( gia thiet coi the tch cua d.d khong thay oi). Nong o ban au cua d.d NaOH la: A. 0,15M B. 0,1M. C. 0,05M. D. 0,2M. Cau 12. Cho 14,6 gam hon hp Fe va Zn tac dung vi d.d HCl d thu c 5,264 lt kh H2 (ktc). Cung lng hon hp nh vay cho tac dung vi 200 ml d.d CuSO4 a mol/lt thu c 14,72 gam chat ran. Gia tr cua a la: A. 0,3M. B. 0,975M. C. 0,25M. D. 0,75M. Cau 13. Hon hp gom FeS2 va CuS2. Cho hon hp tren phan ng vi d.d HNO3, sau phan ng ch thu c 2 muoi sunfat va kh NO. Hoi phng trnh hoa hoc nao sau ay bieu dien ung: A. 2FeS2 + 10HNO3 Fe2(SO4)3 + H2SO4 + 10NO + H2O. Cu2S + 4HNO3 + H2SO4 2CuSO4 + 4NO + 3H2O. B. 2FeS2 + 10HNO3 Fe2(SO4)3 + H2SO4 + 10NO + H2O. 3Cu2S + 10HNO3 6CuSO4 + NO + 5H2O. C. FeS2 + HNO3 Fe(NO3)3 + H2SO4 + NO + H2O. Cu2S + 4HNO3 + H2SO4 2CuSO4 + 4NO + 3H2O. D. FeS2 + HNO3 Fe(NO3)3 + H2SO4 + NO + H2O. 3Cu2S + 10HNO3 6CuSO4 + NO + 5H2O. Cau 14. Cho FeS2 + HNO3 Fe2(SO4)3 + NO2 + Chat nao c bo sung trong dau A.H2O. B.Fe(NO3)3 va H2O. C. H2SO4 va H2O. D.Fe(NO3)3, H2SO4 va H2O. Cau 15. Cho 13,5 gam bot Al tac dung vi het vi d.d HNO3 d thu c hon hp kh X gom NO va N2O. T khoi hi cua X so vi H2 la 19,2. The tch hon hp o 27,3oC va 1atm la: A. 5,6 lt. B. 6,16 lt. C. 7,142 lt D. 8,4 lt. Cau 16. Cation R+ co phan lp ngoai cung la 3p6. Trong bang he thong tuan hoan R v tr nao? A. O th 18, chu k 3, PNC nhom VIII. B. O th 17, chu k 3, PNC nhom VII. C. O th 19, chu k 3, PNC nhom I. D. O th 19, Chu k 4, PNC nhom I.
20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
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Cau 17. Mot hon hp gom 2 mol N2 va 8 mol H2 c dan vao mot bnh kn co xuc tac thch hp. Khi phan ng vi at ti trang thai can bang thu c 9,04 mol hon hp kh. Hieu suat tong hp NH3 la: A. 20% B. 24% C. 25% D. 18%. Cau 18. Cho tng chat : C, Fe, BaCl2, Fe3O4, Fe2O3, FeCO3, Al2O3, H2S, HI, HCl, AgNO3, Na2SO3 lan lt phan ng vi H2SO4 ac, nong. So phan ng thuoc loai phan ng oxi hoa kh la: A. 5 B. 6 C. 7 D. 9 Cau 19. Chon menh e khong ung: A. Fe kh c Cu2+ trong d.d. B. Fe3+ co tnh oxi hoa manh hn Cu2+. 2+ D.Tnh OXH cua cac ion tang theo th t Fe2+, H+, Cu2+, Ag+ C. Fe oxi hoa c Cu. Cau 20. Co 4 d.d muoi rieng biet: CuCl2, ZnCl2, FeCl3, AlCl3. Neu them d.d KOH (d) roi them tiep d.d NH3 (d) vao 4 d.d tren th so ket tua thu c la: A. 1 B. 2 C. 3 D. 4 Cau 21. e thu lay Ag tinh khiet t hon hp X ( gom a mol Al2O3, b mol CuO, c mol Ag2O). Ngi ta hoa tan X bi d.d cha (6a + 2b+2c) mol HNO3 c d.d Y, sau o them tiep: ( biet hieu suat phan ng la 100%). A. 2c mol bot Cu vao Y. B.2 c mol bot Al vao Y. C. c mol bot Al vao Y. D. c mol bot Cu vao Y. Cau 22. Dan kh CO qua ong ng 5 gam Fe2O3 nung nong thu c 4,2 gam hon hp gom Fe, FeO, Fe3O4 va Fe2O3. Dan khi ra khoi ong qua d.d CaOH)2 d thu c a gam ket tua. Gia tr cua a la: A. 4 gam. B. 5 gam C. 6 gam. D. 7,5 gam. Cau 23. Nung nong mg bot Fe trong O2, sau phan ng thu c 3 gam hon hp chat ran X. Hoa tan het hon hp X trong d.d HNO3 (d), thoat ra 0,56 lt kh NO (ktc) la san pham kh duy nhat. Gia tr cua m la: A. 2,52 gam B. 2,22 gam. C. 2,32 gam D. 2,62 gam. Cau 24. Trong hp chat XY ( X la kim loai va Y la phi kim), so electron cua cation bang so electron cua anion va tong so electron trong XY la 20. Biet trong moi hp chat Y ch co mot mc OXH duy nhat. Cong thc XY la: A. MgO B. AlN. C. NaF D. LiF. Cau 25. Suc V lt kh CO2 ( ktc) vao 250 ml d.d Ba(OH)2 1M thu c 19.7 gam ket tua. Gia tr ln nhat cua V la: A. 2.24 lt B. 11,2 lt C. 6.72 lt D. 8.96 lt. Cau 26. A la mot axit no 2 chc mach h. B la mot ru n chc mach h cha mot noi oi. E la este khong cha nhom chc khac tao bi A va B. E co cong thc nao sau ay: A. CnH2n-6O4 B. CnH2n-4O4 C. CnH2n-2O4 D. CnH2n+1COOCmH2m-1. Cau 27. Cho 4,48 lt hon hp X (ktc) gom 2 hirocacbon mach h loi t t qua bnh 2 cha 2 lt d.d brom 0,35M. Sau khi phan ng xay ra hoan toan, so mol brom giam i mot na va khoi lng bnh tang them 6,0 gam. Cong thc phan t cua hai hirocacbon la: A. C2H2 va C4H10. B. C3H4 va C4H8. C. C2H2 va C3H6. D. C2H2 va C4H6. Cau 28. Thuy phan hoan toan 3,96 gam vinyl fomiat trong d.d H2SO4 loang. Trung hoa hoan toan d.d sau phan ng roi cho tac dung tiep vi d.d AgNO3/NH3 d thu c m gam Ag. Gia tr cua m la: A. 23,76gam. B. 11,88 gam C. 21,6 gam. D. 15,12 gam. Cau 29. Cho chuoi phan ng: CH4 A C2H6. Chat A la: (1). Axetylen. (2). Metyl clorua. (3). Metanal. (4). Etylen. A. (1) hoac (2) B. (1) hoac (3). C. (1) hoac (4). D. ch co (1). Cau 30. Len men 1 lt ru etylic 9,2oC. Biet hieu suat cua qua trnh len men la 80% va khoi lng rieng cua ru etylic nguyen chat la 0,8g/ml. Khoi lng cua san pham hu c thu c la: A. 88,7 gam B. 76,8 gam. C. 75,8 gam D. 74,2 gam. Cau 31. Chon menh e khong ung: A. CH3CH2COOCH=CH2 cung day ong ang vi CH2=CHCOOCH3. B. CH3CH2COOCH=CH2 co the trung hp tao polime. C. CH3CH2COOCH=CH2 tac dung c vi d.d brom. D. CH3CH2COOCH=CH2 tac dung c vi d.d NaOH thu c anehit va muoi. Cau 32. A,B,C co cong thc phan t tng ng la : CH2O2, C2H4O2, C3H4O2. Phat bieu ung ve A, B,C la: (1). A,B,C eu la axit. (2). A la axit, B la este, C la anehit co 2 chc. (3). A,B,C eu la ancol co hai chc. (4). ot chay a mol moi chat eu thu c 2a mol H2O. A. (1,3) B. (2,4) C. (1,2) D. (1,2,3,4). Cau 33. Cho 1,8 gam mot axit n chc A phan ng het vi 40 ml d.d KOH 1M thu c d.d X. Co can d.d X c 3,59 gam chat ran. A la: A. Axit acrylic. B. Axit fomic. C. Axit propionic. D. Axit axetic. Cau 34. Hp chat X mach h, co cong thc la C5H8O2. un nong X vi d.d NaOH thu c muoi Y va ru Z, Y tac dung vi H2SO4 tao ra axit T mach phan nhanh. Ten cua X la:
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A. metyl acrylat. B. Metyl metacrylat. C. metyl isobutyrat. D. etyl isobutyrat. Cau 35. Hon hp X gom CH3OH , axit n no A va este B tao bi A va CH3OH. ot chay hoan toan 0,13 mol hon hp X ( so mol CH3OH trong X la 0,08 mol) thu c 0,25 mol CO2. A,B lan lt la: A. HCOOH va HCOOCH3. B. CH3COOH va CH3COOCH3. C. C2H5COOH va C2H5COOCH3. D. C3H7COOH va C3H7COOCH3. Cau 36. Cho s o chuyen hoa sau ay: A + Br2 X B + H 2 / Ni CH3CHO C X Chat X la chat nao trong cac chat cho di ay: B. C2H4 C. C3H6 D. C4H8. A. C2H2 Cau 37. Cho 6,6 gam mot anehit X n chc X, mach h phan ng vi lng d d.d AgNO3/ NH3, un nong. Lng Ag sinh ra cho phan ng het vi HNO3 loang, thoat ra 2,24 lt NO duy nhat (ktc), Cong thc cau tao thu gon cua X la: A. CH3CHO. B. HCHO. C. CH3CH2CHO. D. CH2=CH-CHO. Cau 38. Cho bay hi 2,38 gam hon hp X gom 2 ru n chc 136,5oC va 1 atm thu c 1,68 lt hi. Oxi hoa 4,76 gam hon hp X bi CuO thu c hon hp 2 andehit. Hon hp anehit tac dung vi d.d AgNO3/NH3 d thu c 30,24 gam Ag. Phan tram khoi lng moi ru trong X. A. 56,33% va 43,67%. B. 45,28% va 54,72%. C. 66,67% va 33,33% D. 26,89% va 73,11%. Cau 39. Cho hp chat hu c X co thanh phan % ve khoi lng la : 53,33%C ; 15,56%H; 31,11%N. Cong thc phan t cua X la: A. C2H7N. B. C6H7N. C. C3H9N. D. C4H11N. Cau 40. -aminoaxit X cha mot nhom NH2. Cho 10,3 gam chat X tac dung vi axit HCl ( d) thu c 13,95 gam muoi khan. Cong thc cau tao thu gon cua X la: A. H2NCH2COOH. B. CH3CH2CH(NH2)COOH. C. CH3CH(NH2)COOH. D. CH3CH(NH2)COOH. Cau 41. The tch H2 ( ktc) Can e hiro hoa hoan toan 1 tan olein ( glixerin trioleat) nh chat xuc tac Niken la bao nhieu lt? A. 76018 lt B. 760.18 lt C. 7.6018 lt D. 7601.8 lt. Cau 42. Cho 4 hp cht thm sau :
OH NH2 CHO COOH
20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
(1 )
(2 )
(3 )
(4 )
Cho 4 cht trn tham gia phn ng th th cht no s nh hng v tr mta: A. 1 ,3 ,4 B. 1, 2 , 3 C. 2 ,3 ,4 D. 3 ,4 Cau 43. Thy phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v hai loi axit bo l A. C15H31COOH v C17H35COOH. B. C17H31COOH v C17H33COOH. C. C17H33COOH v C15H31COOH. D. C17H33COOH v C17H35COOH. Cau 44 ot chay hoan toan a mol axit hu c Y c 2a mol CO2.Mac khac e trung hoa a mol Y can dung va u 2a mol NaOH. Cong thc cau tao thu gon cua Y la: A. HOOC-COOH. B. HOOC-CH2-CH2-COOH. C. CH3COOH. D. C2H5COOH. Cau 45. Glixerin co the phan ng vi bao nhieu chat sau ay. (1). HCl. (3). NaOH (5). Cu(OH)2 (7). C6H5NH2 (2). Na (4). CH3COOH (6). Mg(OH)2 (8). H2 A. 5 B.4 C.3 D.6 Cau 46. Hon hp gom ru etylic , phenol va anehit axetic co khoi lng la: 55gam. Chia hon hp thanh hai phan nh nhau.Phan 1 tac dung vi Na d thay thoat ra 2.8 lt kh H2 ( ktc). Phan 2 cho tac dung vi d.d AgNO3 th thay tao thanh 43.2 gam Ag. % theo so mol cua ru trong hon hp au la: A. 25,35% B 25,27% C. 44,44% D. 22,22%.
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Nm hc 2010-2011
Cau 47. Trong cac loai t sau: T tam, t vico, t nilon, t axetat, t capron, t enang: Nhng loai t nao thuoc t nhan tao: A. T visco va t axetat. B. T visco va t nilon 6-6. C. Tnilon -6,6 va t capron. D. T tam va t enang. Cau 48. Khi dan tang nhiet o: S nao sau ay la ung ve bien oi trang thai vat l cua lu huynh: A. S (ran) S ( long, linh ong) S ( long, quanh) S( hi dang phan t ) S ( hi dang n.t). B. S ( ran) S ( long quanh) S ( long, linh ong) S ( hi dang phan t ) S ( hi dang n.t). C. S ( ran) S ( long, linh ong) S ( long, quanh) S ( hi dang n.t). S( hi dang phan t ) D. S ( ran) S (long, quanh ) S (long, quanh) S ( hi dang n.t) S ( hi dang phan t). Cau 49. e trung hoa 25 gam d.d cua mot amin n chc X nong o 12,4% can dung 100 ml d.d HCl 1M. Cong thc phan t cua X la: A. CH5N. B. C2H7N. C. C3H7N. D. C3H5N. Cau 50. Cho cac chat sau: Phenol, etanol, axit axetic, natri axetat, natriphenolat, natri hidroxit. So cap chat tac dung c vi nhau la: A. 2 B. 3 C. 1 D. 4 ap so : 1. C 6. C 2. C 7. B 3. A 8. A 4. C 9. C 5. C 10. A
11. B 12. B 13. A 14. D 15. B
16. D 17. B 18. B 19. C 20. A
21. D 22. B 23. A 24. C 25. D
26. A 27. C 28. A 29. A 30. B
31. A 32. C 33. A 34. B 35. C
36. B 37. A 38. D 39. A 40. B
41. A 42. D 43. D 44. A 45. B
46. D 47. A 48. A 49. A 50. D
Cu 1.Trong cc kim loi Cu, Al, Fe, Ag, Au. dn in ca kim loi c xp theo th t A. Au, Al, Fe, Cu, Ag. B. Au, Ag, Al, Cu, Fe. C. Ag, Cu, Au, Al, Fe. D Al, Ag, Au, Cu, Fe Cu 2.Dng phng php in phn nng chy iu ch c A. tt c cc kim loi vi tinh khit cao. B. cc kim loi hot ng trung bnh v yu. C. ch cc kim loi hot ng mnh. D. ch cc kim loi hot ng trung bnh. Cu 3. loi b tp cht km, ch, ng c ln trong bc ( dng bt) m khng lm thay i khi lng bc ngi ta dng mt lng d dung dch A. AgNO3. B. Pb(NO3)2. C. Cu(NO3)2. D. Fe(NO3)3. Cu 4. Ngi ta iu ch Ba t dung dch BaCl2 bng cch A.in phn dung dch BaCl2. B. C cn dung dch v in phn nng chy . C. dng kim loi K y Ba ra khi dung dch D. c cn dung dch v nhit phn BaCl2 Cu 5. Trong mt cc nc c ho tan a mol Ca(HCO3)2 v b mol Mg(HCO3)2. kh cng ca nc trong cc cn dng V lt nc vi trong, nng p mol/lit. Biu thc lin h gia V vi a, b, p l A. V = (a + b)/p. B. V = 2(a + b)/p. C. V = (a + b)/2p. D. V = (a + b) p. Cu 6. C 5 cht bt mu trng NaCl, Na2CO3, CaCO3, Na2SO4, BaSO4 ng trong cc l ring bit khng ghi nhn. phn bit tng cht ch cn dng A. dung dich MgCl2. B. nc v kh CO2. C. axit H2SO4 long D. dung dch BaCl2. Cu 7. Cc kim loi phn nhm chnh nhm II tan trong nc to dung dch kim gm A. Be, Mg, Ca. B. Be, Ca, Ba. C. Ca, Sr, Ba. D. Ca, Mg, Ba. Cu 8. Nhm khng tan trong nc v A. nhm khng kh c nc nhit thng. B. nhm l kim loi lng tnh. C. trn b mt nhm lun c lp nhm oxit bo v. D. mt l do khc. Cu 9. Nguyn liu sn xut nhm l qung boxit Al2O3.nH2O, thng c ln tp cht Fe2O3 v SiO2. lm sch nguyn liu, ho cht cn dng l A. dung dch NaOH c. B. dung dch NaOH long. C. dung dch HCl v kh CO2. D. dung dch NaOH c v kh CO2. Cu 10. Cc dung dch FeSO4 (1), Fe2(SO4)3 (2), Fe(NO3)3 (3), Fe(NO3)2 (4) c axit ho bng H2SO4 long. Dung dch thuc tm khng b mt mu trong nhm dung dch no sau y :A. (2) v (3) B. (3) v (4). C. (2) v (4). D. (1) v (2) Cu 11. 8,4 gam bt st trong khng kh sau mt thi gian thu c m gam hn hp E gm 4 cht. Ho tan ht hn hp E bng dung dch HNO3 long, d thu c 1,12 lit kh NO duy nht (ktc). Gi tr ca m A. 9,8 gam. B. 15,6 gam. C. 10,8 gam. D. 10,08 gam. Cu 12. Cho t t dung dch NH3 vo dung dch ZnSO4 cho ti d NH3 thy
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A. khng c hin tng g xy ra. B. xut hin kt ta v tan ngay. C. xut hin kt ta trng khng tan. D. c kt ta trng tng dn, sau li tan ra. Cu 13. Kh X khng mu, mi xc, c iu ch bng phn ng ca ng vi axit sunfuric c, nng. Cho X li chm qua nc brm mu vng ( bnh1) v nc hiro sunfua ( bnh 2), hin tng quan st c cc bnh 1 v bnh 2 tng ng l A. (1) dung dch khng i mu ; (2) c kh thot ra mi trng thi. B. (1) dung dch mt mu ; (2) c kt ta mu vng. C. (1) dung dch mt mu ; (2) khng c hin tng g. D. (1) dung dch khng i mu ; (2) c kt ta mu vng. Cu 14. Hai hirocacbon X, Y c cng cng thc phn t C4H8. Khi phn ng vi brom t X thu c mt dn xut 1,2 i brom 2-metyl propan ; t Y thu c mt dn xut 2,3 i brom butan . Tn ca X v Y l A. 2-metyl propen v buten-2. B. 2-metyl propen v metyl xiclo propan C. buten-1 v buten-2. D. buten-2 v xiclo butan. Cu 15. Hn hp kh X gm hai hirocacbon mch h, k tip nhau trong dy ng ng. t chy hon ton 4,48 lt (ktc) kh X thu c 10,752 lt kh CO2 (ktc) v 8,64 gam H2O.Cng thc ca hai hirocacbon v phn trm th tch ca chng trong X tng ng l A. C2H4 (60 %) v C3H6 (40 %). B. C3H6 (60 %) v C4H8 (40 %). C. C2H4 (40 %) v C3H6 (60 %). D. C3H6 (40 %) v C4H8 (60 %). Cu 16. un nng dung dch mantoz c axit v c lm xc tc, thu c dung dch cha A. glucoz. B. fructoz. C. sacaroz. D. glucz v fructoz. Cu 17. Cho cc cht sau: (1) Cu(OH)2, (2) Ag2O/NH3, (3) H2/Ni, t0, (4) H2SO4 long nng. Dung dch mantoz tc dng c vi cc cht A. (2), (3), (4). B. (2), (4). C. (1), (2), (4). D. (3), (4). Cu 18. Ngi ta sn xut xenluloz trinitrat t xenluloz v axit nitric ( s hao ht trong sn xut l 12 %). Khi lng xenluloz cn dng sn xut ra 1 tn xenluloz trinitrat l A. 609,83 kg. B. 619,83 kg. C. 629,83 kg. D. 639,83 kg. Cu 19. T s phn ng : C6H6 X Y 2,4,6 tribrom anilin. Cht X v Y l A. clobenzen v anilin. B. nitrobenzen v phenol. C. nitrobenzen v anilin. D. clobenzen v phenol. Cu 20. t chy hon ton 8,9 gam hp cht hu c E thu c 13,2 gam CO2, 6,3 gam H2O v 1,12 lt N2 (ktc). T khi hi ca E so vi hiro bng 44,5. Khi E phn ng vi dung dch NaOH un nng, sn phm thu c c metanol. Cng thc cu to ca E l A. CH3COOCH2NH2. B. H2NCH2COOCH3. C. CH3CH(NH2)COOCH3 D. H2NCH2CH2COOCH3 Cu 21. Cho 1,47 gam -aminoaxit Y tc dng vi NaOH d to ra 1,91 gam mui natri. Mt khc, 1,47 gam Y tc dng vi HCl d to ra 1,835 gam mui clorua. Cng thc cu to ca Y l A. H2NCH2COOH. B. CH3CH(NH2)COOH. C. CH3(CH2)4CH(NH2)COOH. D. HOOCCH2CH2CH(NH2)COOH. Cu 22. Trong cc cht sau: CH3-CH=CH2, CH2(OH)CH2(OH), NH2-CH2-COOH, CH2=CHCl, nhng cht tham gia c phn ng trng ngng gm A. HO-CH2-CH2-OH v NH2-CH2-COOH. B. HO-CH2-CH2-OH v CH3-CH=CH2. C. CH2=CHCl v CH3-CH=CH2. D. CH3-CH=CH2 v NH2-CH2-COOH. Cu 23. Trong s cc polime sau: si bng (1), t tm (2), len (3), t visco (4), t enang (5), t axetat (6), t nilon-6,6 (7). T thuc loi poliamit gm A.(2), (3), (4), (6). B. (1), (2), (5). C. (1), (4), (6). D. (2), (3), (5), (7). Cu 24. Tch nc t ru (CH3)2CHCH(OH)CH3 trong iu kin thch hp thu c anken. Sn phm tri qui tc Zai xep l sn phm no sau y A. 2-metylbuten-1. B. 2-metylbuten-2. C. 3-metylbuten-1. D. penten-1. Cu 25. Cho 2,325 gam ru X tc dng ht vi Na thu c 0,84 lt kh H2 (ktc).Bit MX 92. Ru X l A. etylen glycol. B. glyxerin. C. etanol. D. propanol. Cu 26. Trong cc ng phn cha vng benzen c cng thc C7H8O s ng phn phn ng c c vi Na v NaOH l A. 2. B. 3. C. 4. D. 5. Cu 27. Dn lung kh CO d i qua ng s cha 17,1 gam hn hp X gm Fe2O3, Al2O3, MgO n khi phn ng hon ton c cht rn Y. Ho tan Y trong dung dch NaOH d thy khi lng cht rn Z thu c bng 65,306% khi lng Y. Ho tan Z bng lng d dung dch HCl thot ra 2,24 lt kh (ktc). Khi lng cc cht trong Z ln lt l (gam) A. 5,6g Fe ; 4,0g Mg. B. 2,8g Fe ; 6,8g MgO C. 5,6g Fe ; 4,0g MgO D. 2,8g Fe ; 6,8g Mg Cu 28. Axit cacboxilic n chc mch h G c cng thc phn t dng CnH2n -2O2. Bit rng 3,6 gam cht G phn ng va vi 8 gam brom trong dung dch. Vy cht G l A. axit acrylic. B. axit metacrilic. C. axit oleic. D. axit linoleic.
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Mn: ho hc
Nm hc 2010-2011
Cu 29. Trung ho dung dch c ho tan 3,8 gam hn hp hai axit cacboxylic no, n chc k tip nhau trong dy ng ng cn dng 150 ml dung dch NaOH 0,5M. Cng thc ca hai axit l B. CH3COOH v C2H5COOH. A. HCOOH v CH3COOH. C. C2H5COOH v C3H7COOH. D. C3H7COOH v C4H9COOH. Cu 30. Bn este c CTPT: C3H4O2, C3H6O2, C4H6O2, C4H8O2. Cng thc phn t ng vi 2 este khi b thu phn cho ra hai cht hu c u khng c kh nng tham gia phn ng trng gng : A C3H4O2 v C4H8O2. B. C3H4O2 v C4H6O2. D. C3H6O2 v C4H8O2. C. C3H4O2 v C3H6O2. Cu 31. X phng ho hon ton 0,01 mol este E (c khi lng 8,9 gam) cn dng va lng NaOH c trong 300 ml dung dch NaOH 0,1 M thu c mt ru v 9,18 gam mui ca mt axit hu c n chc, mch h, c mch cacbon khng phn nhnh. Cng thc ca E A. C3H5(OOCC17H35)3. B. C3H5(OOCC17H33)3. D. C3H5(OOCC15H31)3. C. C3H5(OOCC17H31)3. Cu 32. Ho tan hn hp ng v oxit st t ( dng bt) theo t l mol 2 : 1 bng dung dch HCl d, phn ng xong thu c dung dch X v cht rn Y. Cht tan c trong dung dch X gm A. FeCl2 v FeCl3 B. FeCl3 C. FeCl2 D. FeCl2 v CuCl2 Cu 33. Ho tan 3,84 gam mui sunfat ca hai kim loi kim X, Y (MX < MY) thuc hai chu k k tip vo nc c dung dch E. Dung dch E phn ng va vi 40 ml dung dch BaCl2 0,75 M. Hai kim loi X v Y tng ng l A. Li v Na. B. Na v K. C. K v Rb. D. Rb v Cs. Cu 34. in phn nng chy a gam mui halogenua ca kim loi M, thu c 1,6 gam M Catot v 0,896 lt kh (ktc) Anot. Mt khc dung dch cha a gam mui halogenua ni trn tc dng vi AgNO3 d thu c 11,48 gam kt ta. Cng thc mui halogenua l A. Canxi florua. B. Magie clorua. C. Canxi clorua. D. Magie bromua. Cu 35. Trn 200 ml dung dch gm HCl 0,1 mol/l v H2SO4 0,05 mol/l vi 300 ml dung dch Ba(OH)2 nng x mol/l thu c m gam kt ta v 500 ml dung dch c pH = 13,gi tr ca x v m ln lt l A. x = 0,015 ; m = 2,33. B. x = 0,150 ; m = 2,33. C. x = 0,200 ; m = 3,23. D. x = 0,020 ; m = 3,23. Cu 36. Ho tan ht hn hp FeS2, FeCO3 bng dung dch HNO3 c, nng c dung dch X v 4,48 lt (ktc) hn hp kh Y c t khi so vi hiro bng 22,75. Hp th ton b kh Y vo 300 ml dung dch NaOH 1 M c dung dch Z. Cc cht tan trong Z gm A. NaHCO3, Na2CO3, NaNO3, NaNO2. B. Na2CO3, NaNO3, NaNO2, NaOH. C. NaHCO3, NaNO3, Na2CO3. D. Na2CO3, NaNO3, NaOH. Cu 37. Cho cc dung dch sau: NaHCO3 (X1) ; CuSO4 (X2) ; (NH4)2CO3 (X3) ; NaNO3 (X4) ; MgCl2 (X5) ; KCl (X6). Nhng dung dch khng to kt ta khi cho Ba vo l:A. X1, X4, X5 B. X1, X4, X6 C. X1, X3, X6 D. X4, X6. Cu 38. Hirocacbon F tc dng vi brom trong iu kin thch hp, thu c ch mt dn xut brom c t khi hi so vi hiro bng 75,5. Cht F l A. pentan. B. xiclopentan. C. 2- metylbutan. D. 2,2-i metylpropan. Cu 39. linh ng ca nguyn t H trong nhm OH ca cc cht: ru etylic, axit axetic, axit propionic, axit phenic, axit picric c sp xp theo th t tng dn A. ru etylic, axit axetic, axit propionic, axit phenic, axit picric. B. ru etylic, axit axetic, axit propionic, axit picric, axit phenic. C. ru etylic, axit phenic, axit propionic, axit axetic, axit picric. D. ru etylic, axit phenic, axit picric, axit axetic, axit propionic. Cu 40. Hp cht hu c E mch h, ch cha mt loi nhm chc,c cng thc phn t C8H14O4. Cho E tc dng vi dung dch NaOH thu c mt ru duy nht l CH3OH v mt mui natri ca axit hu c F c mch cacbon khng phn nhnh. E c cng thc cu to l A. CH3OCOCH2CH(CH3)CH2COOCH3. B. CH3OCOCH(CH3)CH(CH3)COOCH3. C. CH3OCOCH2C(CH3)2COOCH3. D. CH3OCOCH2CH2CH2CH2COOCH3. Cu 41. Cht hu c X (cha C, H, N, O) c cng thc phn t trng vi cng thc n gin nht. Trong X, cha 40,45% C, 7,86% H, 15,73% N, cn li l oxi. Khi cho 4,45 gam X tc dng vi NaOH va thu c 4,7 gam mui khan. Cng B. CH3-CH(NH2)-COOH thc cu to ca X lA. H2N-CH2-CH2-COOH C. H2N-CH2-COO-CH3 D. CH2=CH-COO-NH4 Cu 42. Cht hu c X c t khi hi so vi metan bng 4,625. Khi t chy X thu c s mol H2O bng s mol X chy, cn s mol CO2 bng 2 ln s mol nc. X tc dng c vi Na, NaOH v Ag2O trong dung dch NH3 sinh ra Ag. Cng thc cu to ca X lA. HCOOCH2CH3 B. C2H5COOH C. HOOC-CHO D. HOCH2CH2CHO Cu. 43. Hp cht hu c E c cng thc phn t C4H6O2, tho mn iu kin sau: 1) cng H2 (xc tc Ni, to) theo t l mol 1:1.
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20 B THI TH I HC
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Nm hc 2010-2011
2) phn ng chm vi dung dch NaOH nhit thng, ch phn ng mnh khi un nng. 3) sn phm thu c trong phn ng vi dung dch NaOH cho phn ng trng gng. B. CH2=CH-CH2-COOH. Cng thc cu to ca E l: A. CH3-COO-CH=CH2. C. CH2=CH-O-CH2-CHO. D. CH3-CH=CH-COOH. Cu 44. Trong mt bnh kn dung tch khng i 5 lt cha 12,8g SO2 v 3,2g O2 (c mt t xc tc V2O5) nung nng. Khi phn ng t ti cn bng, phn trm th tch oxi trong bnh cn l 20%. Nng mol SO2 v O2 trng thi cn bng tng ng l A. 0,03M v 0,02M B. 0,015M v 0,01M C. 0,02M v 0,02M D. 0,02M v 0,01M ti cn bng, nng mol ca cc cht nh sau : [N2 ] = 0,5 mol/l ; [NH3 ] = 0,8 mol/l ; [H2 ] = 0,8 mol/l. Hng s cn bng v nng mol ca N2, H2 ban u tng ng bng A. 2,5 ; 0,9 ; 2,0 B. 25 ; 1,5 ; 2,0 C. 25 ; 0,9 ; 1,0 D. 2,5 ; 0,9 ; 1,0 Cu 46. Thc hin phn ng nhit nhm 13,4 gam hn hp bt nhm v st(III) oxit c hn hp G. Ho tan G trong dung dch NaOH d, thot ra 3,36 lt kh H2 (cc p/ xy ra hon ton, th tch kh o ktc). Khi lng st(III) oxit c trong hn hp ban u bng A. 6,8 gam. B. 5,4 gam. C. 12 gam D. 8 gam. Cu 47. C 5 mu kim loi Ba, Mg, Ag, Al, Fe. Ngi ta c th nhn bit c tng kim loi m ch cn dng mt dung dch cha mt ho cht lm thuc th l A. HCl. B. HNO3. C. NaOH. D. Fe(NO3)3. Cu 48. Pht biu no sau y khng ng: A. Mt cht c tnh oxi ho gp mt cht c tnh kh, c th xy ra phn ng oxi ho - kh. B. Mt cht hoc ch c tnh oxi ho hoc ch c tnh kh. C. Phn ng c kim loi tham gia l phn ng oxi ho - kh. D. Phi kim l cht oxi ho trong phn ng vi kim loi v hiro. Cu 49. Ru X c cng thc phn t CnHmOz ( z n ). X l ru no, mch h th gi tr thch hp ca m v n l A. m = 2n + 2. B. m = 2n + 1. C. m = 2n z. D. m = 2n + z. Cu 50. T cc s phn ng sau : a) X1 + X2 b)X3 + X4 Ca(OH)2 + H2 CaCO3 + Na2CO3 + H2O b) X3 + X5 Fe(OH)3 + NaCl + CO2 d)X6 + X7 + X2 Al(OH)3 + NH3 + NaCl Cc cht thch hp vi X2, X3, X4, X5 tng ng l: A. Ca ; NaOH ; Ca(HCO3)2 ; FeCl3 B. H2O ; Ca(HCO3)2 ; NaOH ; FeCl3 C. H2O ; NaHCO3 ; Ca(OH)2 ; FeCl3 D. Ca ; Ca(OH)2 ; NaHCO3 ; FeCl3 p n 1 C 21 D 41 D 2 C 22 A 42 C 3 D 23 D 43 A 4 B 24 C 44 D 5 A 25 A 45 A 6 B 26 B 46 D 7 C 27 C 47 D 8 C 28 A 48 B 9 D 29 A 49 A 10 A 30 D 50 C 11 C 31 A 18 B 12 D 32 D 19 C 13 B 33 A 20 B 14 A 34 C 38 D 15 A 35 B 39 C 16 A 36 B 40 D 17 C 37 C
S : 03
Cu 1 t chy hon ton m gam hn hp gm C2H4, C3H6, C4H8 thu c 1,68 lt kh CO2 (ktc). Gi tr ca m bng A. 1,25g B. 1,15g C. 1,05g D. 0,95g Cu 2 Khi lng axit CH3COOH cn ly tc dng va vi 10,65 gam C3H7OH (phn ng c H2SO4 xc tc, un nng, gi thit hiu sut phn ng 100% ) l A. 9,90g B. 10,12g C.12,65g D. 10,65g Cu 3 Cho 5,7 gam hn hp bt P gm Mg, Al, Zn, Cu tc dng hon ton vi oxi d thu c hn hp rn Q c khi lng l 8,1 gam. Th tch ti thiu dung dch HCl 1M cn dng ho tan hon ton Q l A. 180 ml B. 270 ml C. 300 ml D. 360 ml Cu. 4 Cho mt lng bt CaCO3 tc dng hon ton vi dung dch HCl 32,85% sau phn ng thu c dung dch X trong nng HCl cn li l 24,20%. Nng % CaCl2 trong dung dch sau phn ng A.10,35% B.12,35% C.11,35% D. 8,54% Cu 5 Hn hp Z gm 2 axit cacboxylic no, n chc k tip nhau trong dy ng ng. t chy hon ton hn hp Z thu c khi lng H2O t hn khi lng CO2 l 5,46 gam. Nu ly 1/2 lng hn hp Z trn cho tc dng vi dung dch NaOH va th sau phn ng thu c 3,9 gam hn hp mui khan. Cng thc 2 axit trong Z l A. CH3COOH v C2H5COOH B. C2H3COOH v C3H5COOH
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20 B THI TH I HC
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Nm hc 2010-2011
C. C2H5COOH v C3H7COOH D. HCOOH v CH3COOH Cu 6 Cho mt lng ru E i vo bnh ng Na (d), sau khi phn ng xy ra hon ton thy khi lng bnh tng thm 6,3 gam v c 1,568 lt kh H2 (ktc) thot ra. Cng thc ru E l A. C3H5(OH)3 B. C3H7OH C. C2H4(OH)2 D. C2H5OH Cu 7 t chy hon ton m gam mt ru no X thu c cng m gam H2O. Bit khi lng phn t ca X nh hn 100 vC. S ng phn cu to ca ru X l A. 4 B. 6 C. 5 D. 3 Cu 8 Cho cc s phn ng sau : xt xt xt b) X + O2 c) E + H2O a) 6X Y Z G
H xt d) E + Z e) F + H2O Z + G. F iu khng nh no sau y ng A. Cc cht X, Y, Z, E, F, G u c cng s C trong phn t. B. Ch c X v E l hirocacbon C. Cc cht X, Y, Z, E, F, G u phn ng c vi dung dch Ag2O trong NH3. D. Cc cht X, Y, Z, E, F, G u c nhm chc CHO trong phn t. Cu 9 Ho tan hn hp X gm Cu v Fe2O3 trong 400 ml dung dch HCl a mol/lt c dung dch Y v cn li 1 gam ng khng tan. Nhng thanh Mg vo dung dch Y, sau khi phn ng xong, nhc thanh Mg ra thy khi lng tng 4 gam so vi ban u v c 1,12 lt kh H2 (ktc) bay ra.(Gi thit ton b lng kim loi thot ra u bm vo thanh Mg). Khi lng ca Cu trong X v gi tr ca a l A. 1,0g v a = 1M B. 4,2g v a = 1M. C. 3,2g v 2M. D. 4,8g v 2M. Cu 10. Ho tan 14,2 gam hn hp X gm MgCO3 v mt mui cacbonat ca kim loi M vo mt lng va axit HCl 7,3% thu c dung dch Y v 3,36 lt kh CO2 (ktc). Nng MgCl2 trong Y l 6,028%. Cho dung dch NaOH d vo dung dch Y, lc ly kt ta em nung ngoi khng kh n khi lng khng i th thu c m gam chy rn. Gi tr ca m bng A. 12,0g B. 10,4g C. 8,0g D. 7,6g
+
D.Phi kim lun l cht oxi ho trong phn ng oxi ho - kh. Cu 11 Ho tan hon ton 5,94g Al vo dung dch NaOH d thu c kh X. Cho 1,896g KMnO4 tc dng ht vi axit HCl c kh Y. Nhit phn hon ton 12,25g KClO3 c xc tc thu c kh Z. Cho ton b 3 kh Z, Y, Z trn vo bnh kn ri t chy phn ng xy ra hon ton, sau a bnh v nhit thng, thu c dung dch T. Nng phn trm cht tan trong T l A. 18,85% B. 28,85% C. 24,24% D. 31,65% Cu 12 S ng phn mch h c cng thc phn t C4H9NO2 khi phn ng vi dung dch NaOH iu kin thng to ra amoniac l A. 2 B. 3 C. 4 D. 5 Cu 13 t chy hon ton 1,1g hn hp F gm metan, etin, propen thu c 3,52g CO2. Mt khc, khi cho 448 ml hn hp kh F (ktc) i qua dung dch nc brom d th ch c 4g brom phn ng. Phn trm th tch metan, etin, propen trong hn hp F ln lt l (%) : A. 30 ; 40 ; 30 B. 25 ; 50 ; 25 C. 50 ; 25 ; 25 D. 25 ; 25 ; 50 Cu 14 Ho tan hon ton m gam kim loi M bng dung dch HCl d thu c V lit H2 (ktc). Mt khc ho tan hon ton m gam kim loi M bng dung dch HNO3 long, d thu c mui nitrat ca M, H2O v cng V lit kh NO (ktc) duy nht. Bit khi lng mui nitrat to thnh gp 1,905 ln khi lng mui clorua. Kim loi M l A. Mg B. Al C. Cu D. Fe Cu 15. C 50 ml dung dch cha hn hp KOH 0,05M v Ba(OH)2 0,025M ngi ta thm V ml dung dch HCl 0,16M vo 50 ml dung dch trn thu c dung dch mi c pH = 2. Vy gi tr ca V l A. 36,67 ml B. 30,33 ml C. 40,45 ml D. 45,67 ml. Cu 16. t chy hon ton 1,35 gam mt ru no Y c mch cacbon khng phn nhnh ri cho ton b sn phm chy hp th ht vo bnh ng lng d dung dch Ba(OH)2 thy khi lng bnh tng thm a gam v c 11,82 gam kt ta trng. Cng thc phn t ru Y l A. C4H9OH B. C3H6(OH)2 C. C4H8(OH)2 D. C3H5(OH)3 Cu 17. T cc s phn ng sau : a)X1 + X2 b) X3 + X4 Ca(OH)2 + H2 CaCO3 + Na2CO3 + H2O c) X3 + X5 d) X6 + X7 + X2 Fe(OH)3 + NaCl + CO2 Al(OH)3 + NH3 + NaCl Cc cht thch hp vi X2, X3, X4, X5 tng ng l A. Ca ; NaOH ; Ca(HCO3)2 ; FeCl3 B. H2O ; Ca(HCO3)2 ; NaOH ; FeCl3 C. H2O ; NaHCO3 ; Ca(OH)2 ; FeCl3 D. Ca ; Ca(OH)2 ; NaHCO3 ; FeCl3 Cu 18. Mt hn hp gm 2 este n chc X, Y c khi lng 32,6 gam. Chia hn hp trn thnh 2 phn u nhau. X phng ho hon ton phn 1 bng mt lng va 125 ml dung dch NaOH 2M un nng, thu c 1 ru v 2 mui.Cho
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20 B THI TH I HC
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Nm hc 2010-2011
phn 2 tc dng vi lng d dung dch Ag2O trong NH3 thu c 43,2 gam Ag. Khi lng v cng thc ca cc este X, Y c trong hn hp ban u ln lt l: A.24gamHCOOCH3 v 8,6 gamC2H3COOCH3 B. 24gam HCOOCH3 v 8,6 gam C2H5COOCH3 C.12 gamHCOOCH3v20,6gamC2H3COOCH3 D.12gam HCOOCH3 v 20,6 gam CH3COOCH3 Cu 19. iu khng nh no sau y ng ? A. Cacbon ch c tnh kh. B. Cacbon ioxit khng th b oxi ho. C. Cacbon oxit l cht kh khng th t chy. D. Khng th t chy kim cng. Cu 20 Pht biu no sau y lun ng: A.Mt cht c tnh oxi ho gp mt cht c tnh kh, nht thit xy ra phn ng oxi ho - kh. B.Mt cht hoc ch c tnh oxi ho hoc ch c tnh kh. C.Phn ng c kim loi tham gia l phn ng oxi ho - kh. D.Phi kim lun l cht oxi ho trong phn ng oxi ho - kh. Cu 21. X v Y l 2 nguyn t nm trong 2 phn nhm chnh k tip nhau trong bng tun hon dng ngn, X thuc nhm VI. Tng s ht proton trong 2 ht nhn ca X v Y l 25 ( ZX < ZY ) . Bit n cht X tc dng c vi n cht Y. Vy X, Y tng ng l A. Ne v P. B. O v Cl C. F v S D. N v Ar
2NH3 . Khi cn bng c thit lp, ta c nng cn bng ca cc cht nh Cu 22. Cho phn ng N2 + 3H2 sau : [N2] = 3 mol/l, [H2] = 9 mol/l, [NH3] = 4 mol/l. Vy nng ban u ca N2 v H2 l A. [N2] = 7 mol/l, [H2] = 12 mol/l B. [N2] = 5 mol/l, [H2] = 15 mol/l C. [N2] = 5 mol/l, [H2] = 12 mol/l D. [N2] = 9 mol/l, [H2] = 15 mol/l Cu 23. Cho 200 ml dung dch X cha cc ion NH4+ , K+ , SO42- , Cl- vi nng tng ng l 0,5M , 0,1M , 0,25M , 0,1M. Bit rng dung dch X c iu ch bng cch ho tan 2 mui vo nc. Khi lng ca 2 mui c ly l A. 6,6g (NH4)2SO4 v 7,45g KCl. B. 6,6g (NH4)2SO4 v 1,49g KCl. C. 8,7g K2SO4 v 5,35g NH4Cl. D. 3,48g K2SO4 v 1,07g NH4Cl. Cu 24. Nung 44 gam hn hp X gm Cu v Cu(NO3)2 trong bnh kn cho n khi cc phn ng xy ra hon ton thu c cht rn Y. Cht rn Y phn ng va vi 600 ml dung dch H2SO4 0,5 M (Y tan ht). Khi lng Cu v Cu(NO3)2 c trong hn hp X l ( Cu = 64, N = 14, O = 16, S = 32, H = 1) : A. 6,4 g Cu; 37,6 g Cu(NO3)2 B. 9,6 g Cu; 34,4 g Cu(NO3)2 C. 8,8 g Cu; 35,2 g Cu(NO3)2 D. 12,4 g Cu; 31,6 g Cu(NO3)2 Cu 25. t chy 1,12 lit (ktc) hn hp hai hirocacbon X,Y ng ng lin tip (MX < MY), ta thu c 2,88 gam nc v 4,84 gam CO2. Thnh phn % theo th tch ca hai hirocacbon X,Y trong hn hp l: A. 50; 50 B. 20; 80 C. 33,33 ; 66,67 D. 80 , 20. Cu 26. tch butin-1 ra khi hn hp vi butin-2 , nn A. dng phng php chng ct phn on. B. dng dung dch brom. C. dng dung dch AgNO3/NH3, sau dng dung dch HCl. D. dng dung dch KMnO4.
t o , xt
Cu 27. Hirocacbon X tc dng vi brom trong iu kin thch hp, thu c ch mt dn xut brom c t khi hi so vi hiro bng 75,5 ( Br = 80). Cht X l
A. pentan. B. xiclopentan. C. 2- metylbutan. D. 2,2-imetylpropan. Cu 28. Dn hai lung kh clo i qua hai dung dch KOH: dung dch I long v ngui, dung dch II m c, un nng ti 80oC. Nu lng mui KCl sinh ra trong hai dung dch bng nhau th t l th tch kh clo i qua hai dung dch KOH ( I ) v ( II ) l : (Cho : K = 39, Cl = 35,5) A. 5/6 B. 6/3 C. 10/3 D. 5/3 Cu 29. Hai bnh A, B c th tch bng nhau. Bnh A cha 1 mol kh Cl2, bnh B cha 1 mol kh O2. Cho vo mi bnh 2,4 gam bt kim loi M c ho tr khng i. un nng 2 bnh cc phn ng xy ra hon ton ri a 2 bnh v nhit ban u, nhn thy p sut kh trong 2 bnh PA : PB = 1,8 : 1,9. Kim loi M l A. Zn B. Ca C. Mg D. Ba Cu 30. Cho cc cht Cu, FeO, Fe3O4, C, FeCO3, Fe(OH)2, Fe tc dng ln lt vi H2SO4 c, nng u gii phng kh SO2. Nhm cc cht m khi tc dng vi 1 mol H2SO4 u gii phng ra 1/ 4 mol SO2 gm A. Cu, FeO, Fe3O4 B. FeO, Fe3O4, C. Fe3O4, FeCO3, Fe D. FeO, FeCO3, Fe(OH)2 Cu 31. Cc kim loi phn nhm chnh nhm I, II khc cc kim loi cn li ch A. ch c chng l kim loi nh. B. chng u phn ng vi nc to dung dch kim. C. chng c ho tr khng i khi tham gia phn ng ho hc. D. kh nng dn in ca chng tt hn nhm. Cu 32. C V1 ml dung dch H2SO4 pH = 2. Trn thm V2 ml H2O vo dung dch trn c (V1+V2) ml dung dch mi c pH = 3. Vy t l V1 : V2 c gi tr bng A. 1 : 3 B. 1 : 5 C. 1 : 9 D. 1 : 10
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Mn: ho hc
Nm hc 2010-2011
Cu 33. Ho tan 17 gam hn hp NaOH, KOH, Ca(OH)2 vo nc c 500 gam dung dch X. trung ho 50 gam dung dch X cn dng 40 gam dung dch HCl 3,65%. C cn dung dch sau khi trung ho thu c khi lng mui khan l A. 3,16 gam. B. 2,44 gam. C. 1,58 gam. D. 1,22 gam. Cu 34. in phn dung dch cha hn hp 2 mui CuCl2 v Cu(NO3)3 mt thi gian, anot ca bnh in phn thot ra 448 ml hn hp kh (ktc) c t khi so vi H2 bng 25,75 v c m gam kim loi Cu bm trn catot. Gi tr ca m bng A. 0,64 gam B. 1,28 gam C. 1,92 gam. D. 2,56 gam Cu 35. Hp cht hu c n chc X cha C, H, O. Trong phn trm khi lng ca C, H tng ng l 55,81 % v 6,98 %. Y l ng phn ca X v hu nh khng tan trong nc. C X v Y u c ng phn cis trans. Cng thc cu to ca X v Y l cng thc no sau y: A. CH2=CHCOOH v HCOOCH=CH2. B. B. HCOOCH=CHCH3 v CH3CH=CHCOOH C.CH3CH=CHCOOH v HCOOCH=CHCH3 D. CH2=CHCH2COOH v CH3COOCH=CH2 Cu 36. Ru no X l ng ng ca etylen glicol, c phn trm khi lng oxi bng 35,55%. X ho tan c Cu(OH)2 to dung dch mu xanh lam. S ng phn cu to tho mn tnh cht trn ca X l A. 2 B. 3 C.4 D.5 Cu 37. t chy hon ton 1,3g cht hu c X thu c 2,24 lit CO2 (ktc) v 0,9g H2O. Bit X l cht lng v l monome dng trong tng hp cao su, iu ch polime khc X l A. Axetilen B. Butaien C. Isopren D. Stiren Cu 38. Trung ho 0,1 mol amino axit X cn 200g dung dch NaOH 4%. C cn dung dch thu c 16,3gam mui khan. Cng thc phn t ca X l A. H2NCH2COOH B.H2NCH(COOH)2 C. H2NCH2CH2COOH D. H2NCH2CH(COOH)2 Cu 39. X l cht lng khng mu, khng lm i mu phenolphtalein. X tc dng c vi dung dch Na2CO3 v dung dch AgNO3/NH3. Vy X l A. HCOOH B. HCOOCH3 C. HCHO D. CH3COOH Cu 40. Cho m gam hn hp 2 amino axit (trong phn t ch cha 1 nhm amino v 1 nhm cacboxyl) tc dng vi 110 ml dung dch HCl 2M c dung dch X. phn ng ht vi cc cht trong X cn dng 200 gam dung dch NaOH 8,4% c dung dch Y. C cn Y c 34,37 gam cht rn khan. Gi tr ca m l A. 15,1 gam. B. 16,1 gam. C. 17,1 gam. D. 18,1 gam. Cu 41. Cht hu c X c t khi hi so vi metan bng 4,625. Khi t chy X thu c s mol H2O bng s mol X chy, cn s mol CO2 bng 2 ln s mol nc. X tc dng c vi Na, NaOH v Ag2O trong dung dch NH3 sinh ra Ag. Cng thc cu to ca X l A. HCOOC2H5 B. C2H5COOH C. HOOC-CHO D. HOCH2CH2CHO Cu 42. phn bit ru bc 1 vi ru bc 2 ngi ta ln lt dng ho cht sau A. CuO(to) ; Ag2O/NH3 B. CH3COOH ; NaOH C. H2SO4c (170oC) D. O2 (men gim) Cu 43. im ging nhau khi sc kh CO2 ln lt vo cc dung dch nc vi trong (I), natri phenolat (II), natri aluminat (III) ; sc kh ozon vo dung dch KI (IV) ; sc kh sunfur vo dung dch H2S (V) l hin tng dung dch b vn c, nhng bn cht ca cc phn ng khc nhau nh sau : A. (II), (III) khc vi (I), (IV), (V) B. (I), (II), (III) khc vi (IV), (V) C. (I), (II), khc vi (III), (IV), (V) D. (III), (IV) khc vi (I), (II), (V) Cu 44. Cho H2SO4 c vo saccaroz iu kin thng thu c mt cht kh bay ra c kh nng lm mt mu dung dch thuc tm .Cht l : A. Hi H2SO4 . B. Kh CO2. C. Kh SO2 . D. Kh H2S Cu 45. Trong cc cht: glucoz, fructoz, saccaroz, mantoz th nhng cht khng c kh nng tham gia phn ng trng gng l: A. Glucoz v saccaroz. B. Glucoz v mantoz. C. Saccaroz v fructoz. D. Saccaroz v mantoz. Cu 46. Khi thu phn du thc vt xy ra phn ng mt chiu, ngoi glyxerin ta thu c ch yu : A. Axit no. B. Axit khng no . C. Mui ca axit no D. Mui ca axit khng no. Cu 47. Xc tc dng trong phn ng este ho ca amino axit l : B. H2SO4 c. C. HCl bo ho. D. HCl long . A. H2SO4 long. Cu 48. Cc nhm cht sau y, nhm cht no thuc loi t tng hp ? A. T nilon , t capron , t lapxan. B. T vissco , t axetat . C. T tm , len , bng . D. T vissco , t nilon , t capron. Cu 49. Oxi ho 4 gam ru n chc Z bng O2 (xt Cu) thu c 5,6 gam hn hp kh v hi X. Tn ca ru Z v hiu sut phn ng oxi ho l A. C2H5OH ; 60% B. CH3OH ; 80% C. C3H7OH ; 40% D. C4H9OH ; 90%.
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Cu 50. Ru bc hai X c cng thc phn t C6H14O. un X vi H2SO4 c 170oC ch to ra 1 anken duy nht, tn X l A. 2,3-imetyl butanol-2. B. 2,3-imetyl butanol-1.
20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
C. 2-metyl pentanol-3. p n
1 C 21 C 41 C 2 D 22 B 42 A 3 C 23 B 43 B 4 A 24 A 44 C 5 A 25 D 45 C 6 D 26 C 46 D 7 B 27 D 47 A 8 C 28 D 48 A 9 B 29 C 49 B 10 C 30 D 50 D 11 B 31 C 18 A
D. 3,3-imetyl butanol-2.
12 C 32 C 19 B
13 B 33 B 20 C
14 D 34 C 38 B
15 A 35 C 39 A
16 C 36 B 40 C
17 C 37 D
S : 04
Cu 1.Trong cc kim loi Cu, Al, Fe, Ag, Au. dn in ca kim loi c xp theo th t A. Au, Al, Fe, Cu, Ag. B. Au, Ag, Al, Cu, Fe. C. Ag, Cu, Au, Al, Fe. D Al, Ag, Au, Cu, Fe Cu 2.Dng phng php in phn nng chy iu ch c A. tt c cc kim loi vi tinh khit cao. B. cc kim loi hot ng trung bnh v yu. C. ch cc kim loi hot ng mnh. D. ch cc kim loi hot ng trung bnh. Cu 3. loi b tp cht km, ch, ng c ln trong bc ( dng bt) m khng lm thay i khi lng bc ngi ta dng mt lng d dung dch A. AgNO3. B. Pb(NO3)2. C. Cu(NO3)2. D. Fe(NO3)3. Cu 4. Ngi ta iu ch Ba t dung dch BaCl2 bng cch A.in phn dung dch BaCl2. B. C cn dung dch v in phn nng chy . C. dng kim loi K y Ba ra khi dung dch D. c cn dung dch v nhit phn BaCl2 Cu 5. Trong mt cc nc c ho tan a mol Ca(HCO3)2 v b mol Mg(HCO3)2. kh cng ca nc trong cc cn dng V lt nc vi trong, nng p mol/lit. Biu thc lin h gia V vi a, b, p l A. V = (a + b)/p. B. V = 2(a + b)/p. C. V = (a + b)/2p. D. V = (a + b) p. Cu 6. C 5 cht bt mu trng NaCl, Na2CO3, CaCO3, Na2SO4, BaSO4 ng trong cc l ring bit khng ghi nhn. phn bit tng cht ch cn dng A. dung dich MgCl2. B. nc v kh CO2. C. axit H2SO4 long D. dung dch BaCl2. Cu 7. Cc kim loi phn nhm chnh nhm II tan trong nc to dung dch kim gm A. Be, Mg, Ca. B. Be, Ca, Ba. C. Ca, Sr, Ba. D. Ca, Mg, Ba. Cu 8. Nhm khng tan trong nc v A. nhm khng kh c nc nhit thng. B. nhm l kim loi lng tnh. C. trn b mt nhm lun c lp nhm oxit bo v. D. mt l do khc. Cu 9. Nguyn liu sn xut nhm l qung boxit Al2O3.nH2O, thng c ln tp cht Fe2O3 v SiO2. lm sch nguyn liu, ho cht cn dng l A. dung dch NaOH c. B. dung dch NaOH long. C. dung dch HCl v kh CO2. D. dung dch NaOH c v kh CO2. Cu 10. Cc dung dch FeSO4 (1), Fe2(SO4)3 (2), Fe(NO3)3 (3), Fe(NO3)2 (4) c axit ho bng H2SO4 long. Dung dch thuc tm khng b mt mu trong nhm dung dch no sau y :A. (2) v (3) B. (3) v (4). C. (2) v (4). D. (1) v (2) Cu 11. 8,4 gam bt st trong khng kh sau mt thi gian thu c m gam hn hp E gm 4 cht. Ho tan ht hn hp E bng dung dch HNO3 long, d thu c 1,12 lit kh NO duy nht (ktc). Gi tr ca m A. 9,8 gam. B. 15,6 gam. C. 10,8 gam. D. 10,08 gam. Cu 12. Cho t t dung dch NH3 vo dung dch ZnSO4 cho ti d NH3 thy A. khng c hin tng g xy ra. B. xut hin kt ta v tan ngay. C. xut hin kt ta trng khng tan. D. c kt ta trng tng dn, sau li tan ra. Cu 13. Kh X khng mu, mi xc, c iu ch bng phn ng ca ng vi axit sunfuric c, nng. Cho X li chm qua nc brm mu vng ( bnh1) v nc hiro sunfua ( bnh 2), hin tng quan st c cc bnh 1 v bnh 2 tng ng l A. (1) dung dch khng i mu ; (2) c kh thot ra mi trng thi. B. (1) dung dch mt mu ; (2) c kt ta mu vng. C. (1) dung dch mt mu ; (2) khng c hin tng g. D. (1) dung dch khng i mu ; (2) c kt ta mu vng.
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 14. Hai hirocacbon X, Y c cng cng thc phn t C4H8. Khi phn ng vi brom t X thu c mt dn xut 1,2 i brom 2-metyl propan ; t Y thu c mt dn xut 2,3 i brom butan . Tn ca X v Y l A. 2-metyl propen v buten-2. B. 2-metyl propen v metyl xiclo propan C. buten-1 v buten-2. D. buten-2 v xiclo butan. Cu 15. Hn hp kh X gm hai hirocacbon mch h, k tip nhau trong dy ng ng. t chy hon ton 4,48 lt (ktc) kh X thu c 10,752 lt kh CO2 (ktc) v 8,64 gam H2O.Cng thc ca hai hirocacbon v phn trm th tch ca chng trong X tng ng l B. C3H6 (60 %) v C4H8 (40 %). A. C2H4 (60 %) v C3H6 (40 %). C. C2H4 (40 %) v C3H6 (60 %). D. C3H6 (40 %) v C4H8 (60 %). Cu 16. un nng dung dch mantoz c axit v c lm xc tc, thu c dung dch cha A. glucoz. B. fructoz. C. sacaroz. D. glucz v fructoz. Cu 17. Cho cc cht sau: (1) Cu(OH)2, (2) Ag2O/NH3, (3) H2/Ni, t0, (4) H2SO4 long nng. Dung dch mantoz tc dng c vi cc cht A. (2), (3), (4). B. (2), (4). C. (1), (2), (4). D. (3), (4). Cu 18. Ngi ta sn xut xenluloz trinitrat t xenluloz v axit nitric ( s hao ht trong sn xut l 12 %). Khi lng xenluloz cn dng sn xut ra 1 tn xenluloz trinitrat l A. 609,83 kg. B. 619,83 kg. C. 629,83 kg. D. 639,83 kg. Cu 19. T s phn ng : C6H6 X Y 2,4,6 tribrom anilin. Cht X v Y l A. clobenzen v anilin. B. nitrobenzen v phenol. C. nitrobenzen v anilin. D. clobenzen v phenol. Cu 20. t chy hon ton 8,9 gam hp cht hu c E thu c 13,2 gam CO2, 6,3 gam H2O v 1,12 lt N2 (ktc). T khi hi ca E so vi hiro bng 44,5. Khi E phn ng vi dung dch NaOH un nng, sn phm thu c c metanol. Cng thc cu to ca E l A. CH3COOCH2NH2. B. H2NCH2COOCH3. D. H2NCH2CH2COOCH3 C. CH3CH(NH2)COOCH3 Cu 21. Cho 1,47 gam -aminoaxit Y tc dng vi NaOH d to ra 1,91 gam mui natri. Mt khc, 1,47 gam Y tc dng vi HCl d to ra 1,835 gam mui clorua. B. CH3CH(NH2)COOH. Cng thc cu to ca Y l A. H2NCH2COOH. C. CH3(CH2)4CH(NH2)COOH. D. HOOCCH2CH2CH(NH2)COOH. Cu 22. Trong cc cht sau: CH3-CH=CH2, CH2(OH)CH2(OH), NH2-CH2-COOH, CH2=CHCl, nhng cht tham gia c phn ng trng ngng gm A. HO-CH2-CH2-OH v NH2-CH2-COOH. B. HO-CH2-CH2-OH v CH3-CH=CH2. C. CH2=CHCl v CH3-CH=CH2. D. CH3-CH=CH2 v NH2-CH2-COOH. Cu 23. Trong s cc polime sau: si bng (1), t tm (2), len (3), t visco (4), t enang (5), t axetat (6), t nilon-6,6 (7). T thuc loi poliamit gm A.(2), (3), (4), (6). B. (1), (2), (5). C. (1), (4), (6). D. (2), (3), (5), (7). Cu 24. Tch nc t ru (CH3)2CHCH(OH)CH3 trong iu kin thch hp thu c anken. Sn phm tri qui tc Zai xep l sn phm no sau y A. 2-metylbuten-1. B. 2-metylbuten-2. C. 3-metylbuten-1. D. penten-1. Cu 25. Cho 2,325 gam ru X tc dng ht vi Na thu c 0,84 lt kh H2 (ktc).Bit MX 92. Ru X l A. etylen glycol. B. glyxerin. C. etanol. D. propanol. Cu 26. Trong cc ng phn cha vng benzen c cng thc C7H8O s ng phn phn ng c c vi Na v NaOH l A. 2. B. 3. C. 4. D. 5. Cu 27. Dn lung kh CO d i qua ng s cha 17,1 gam hn hp X gm Fe2O3, Al2O3, MgO n khi phn ng hon ton c cht rn Y. Ho tan Y trong dung dch NaOH d thy khi lng cht rn Z thu c bng 65,306% khi lng Y. Ho tan Z bng lng d dung dch HCl thot ra 2,24 lt kh (ktc). Khi lng cc cht trong Z ln lt l (gam) A. 5,6g Fe ; 4,0g Mg. B. 2,8g Fe ; 6,8g MgO C. 5,6g Fe ; 4,0g MgO D. 2,8g Fe ; 6,8g Mg Cu 28. Axit cacboxilic n chc mch h G c cng thc phn t dng CnH2n -2O2. Bit rng 3,6 gam cht G phn ng va vi 8 gam brom trong dung dch. Vy cht G l A. axit acrylic. B. axit metacrilic. C. axit oleic. D. axit linoleic. Cu 29. Trung ho dung dch c ho tan 3,8 gam hn hp hai axit cacboxylic no, n chc k tip nhau trong dy ng ng cn dng 150 ml dung dch NaOH 0,5M. Cng thc ca hai axit l A. HCOOH v CH3COOH. B. CH3COOH v C2H5COOH. C. C2H5COOH v C3H7COOH. D. C3H7COOH v C4H9COOH. Cu 30. Bn este c CTPT: C3H4O2, C3H6O2, C4H6O2, C4H8O2. Cng thc phn t ng vi 2 este khi b thu phn cho ra hai cht hu c u khng c kh nng tham gia phn ng trng gng : A C3H4O2 v C4H8O2. B. C3H4O2 v C4H6O2. C. C3H4O2 v C3H6O2. D. C3H6O2 v C4H8O2.
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 31. X phng ho hon ton 0,01 mol este E (c khi lng 8,9 gam) cn dng va lng NaOH c trong 300 ml dung dch NaOH 0,1 M thu c mt ru v 9,18 gam mui ca mt axit hu c n chc, mch h, c mch cacbon khng phn nhnh. Cng thc ca E A. C3H5(OOCC17H35)3. B. C3H5(OOCC17H33)3. C. C3H5(OOCC17H31)3. D. C3H5(OOCC15H31)3. Cu 32. Ho tan hn hp ng v oxit st t ( dng bt) theo t l mol 2 : 1 bng dung dch HCl d, phn ng xong thu c dung dch X v cht rn Y. Cht tan c trong dung dch X gm B. FeCl3 C. FeCl2 D. FeCl2 v CuCl2 A. FeCl2 v FeCl3 Cu 33. Ho tan 3,84 gam mui sunfat ca hai kim loi kim X, Y (MX < MY) thuc hai chu k k tip vo nc c dung dch E. Dung dch E phn ng va vi 40 ml dung dch BaCl2 0,75 M. Hai kim loi X v Y tng ng l A. Li v Na. B. Na v K. C. K v Rb. D. Rb v Cs. Cu 34. in phn nng chy a gam mui halogenua ca kim loi M, thu c 1,6 gam M Catot v 0,896 lt kh (ktc) Anot. Mt khc dung dch cha a gam mui halogenua ni trn tc dng vi AgNO3 d thu c 11,48 gam kt ta. Cng thc mui halogenua l A. Canxi florua. B. Magie clorua. C. Canxi clorua. D. Magie bromua. Cu 35. Trn 200 ml dung dch gm HCl 0,1 mol/l v H2SO4 0,05 mol/l vi 300 ml dung dch Ba(OH)2 nng x mol/l thu c m gam kt ta v 500 ml dung dch c pH = 13,gi tr ca x v m ln lt l A. x = 0,015 ; m = 2,33. B. x = 0,150 ; m = 2,33. C. x = 0,200 ; m = 3,23. D. x = 0,020 ; m = 3,23. Cu 36. Ho tan ht hn hp FeS2, FeCO3 bng dung dch HNO3 c, nng c dung dch X v 4,48 lt (ktc) hn hp kh Y c t khi so vi hiro bng 22,75. Hp th ton b kh Y vo 300 ml dung dch NaOH 1 M c dung dch Z. Cc cht tan trong Z gm A. NaHCO3, Na2CO3, NaNO3, NaNO2. B. Na2CO3, NaNO3, NaNO2, NaOH. C. NaHCO3, NaNO3, Na2CO3. D. Na2CO3, NaNO3, NaOH. Cu 37. Cho cc dung dch sau: NaHCO3 (X1) ; CuSO4 (X2) ; (NH4)2CO3 (X3) ; NaNO3 (X4) ; MgCl2 (X5) ; KCl (X6). B. X1, X4, X6 C. X1, X3, X6 D. X4, X6. Nhng dung dch khng to kt ta khi cho Ba vo l:A. X1, X4, X5 Cu 38. Hirocacbon F tc dng vi brom trong iu kin thch hp, thu c ch mt dn xut brom c t khi hi so vi hiro bng 75,5. Cht F l A. pentan. B. xiclopentan. C. 2- metylbutan. D. 2,2-i metylpropan. Cu 39. linh ng ca nguyn t H trong nhm OH ca cc cht: ru etylic, axit axetic, axit propionic, axit phenic, axit picric c sp xp theo th t tng dn A. ru etylic, axit axetic, axit propionic, axit phenic, axit picric. B. ru etylic, axit axetic, axit propionic, axit picric, axit phenic. C. ru etylic, axit phenic, axit propionic, axit axetic, axit picric. D. ru etylic, axit phenic, axit picric, axit axetic, axit propionic. Cu 40. Hp cht hu c E mch h, ch cha mt loi nhm chc,c cng thc phn t C8H14O4. Cho E tc dng vi dung dch NaOH thu c mt ru duy nht l CH3OH v mt mui natri ca axit hu c F c mch cacbon khng phn nhnh. E c cng thc cu to l A. CH3OCOCH2CH(CH3)CH2COOCH3. B. CH3OCOCH(CH3)CH(CH3)COOCH3. C. CH3OCOCH2C(CH3)2COOCH3. D. CH3OCOCH2CH2CH2CH2COOCH3. Cu 41. Cht hu c X (cha C, H, N, O) c cng thc phn t trng vi cng thc n gin nht. Trong X, cha 40,45% C, 7,86% H, 15,73% N, cn li l oxi. Khi cho 4,45 gam X tc dng vi NaOH va thu c 4,7 gam mui khan. Cng thc cu to ca X lA. H2N-CH2-CH2-COOH B. CH3-CH(NH2)-COOH C. H2N-CH2-COO-CH3 D. CH2=CH-COO-NH4 Cu 42. Cht hu c X c t khi hi so vi metan bng 4,625. Khi t chy X thu c s mol H2O bng s mol X chy, cn s mol CO2 bng 2 ln s mol nc. X tc dng c vi Na, NaOH v Ag2O trong dung dch NH3 sinh ra Ag. Cng thc cu to ca X lA. HCOOCH2CH3 B. C2H5COOH C. HOOC-CHO D. HOCH2CH2CHO Cu. 43. Hp cht hu c E c cng thc phn t C4H6O2, tho mn iu kin sau: 1) cng H2 (xc tc Ni, to) theo t l mol 1:1. 2) phn ng chm vi dung dch NaOH nhit thng, ch phn ng mnh khi un nng. 3) sn phm thu c trong phn ng vi dung dch NaOH cho phn ng trng gng. Cng thc cu to ca E l: A. CH3-COO-CH=CH2. B. CH2=CH-CH2-COOH. C. CH2=CH-O-CH2-CHO. D. CH3-CH=CH-COOH. Cu 44. Trong mt bnh kn dung tch khng i 5 lt cha 12,8g SO2 v 3,2g O2 (c mt t xc tc V2O5) nung nng. Khi phn ng t ti cn bng, phn trm th tch oxi trong bnh cn l 20%. Nng mol SO2 v O2 trng thi cn bng tng ng l A. 0,03M v 0,02M B. 0,015M v 0,01M C. 0,02M v 0,02M D. 0,02M v 0,01M
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
ti cn bng, nng mol ca cc cht nh sau : [N2 ] = 0,5 mol/l ; [NH3 ] = 0,8 mol/l ; [H2 ] = 0,8 mol/l. Hng s cn bng v nng mol ca N2, H2 ban u tng ng bng A. 2,5 ; 0,9 ; 2,0 B. 25 ; 1,5 ; 2,0 C. 25 ; 0,9 ; 1,0 D. 2,5 ; 0,9 ; 1,0 Cu 46. Thc hin phn ng nhit nhm 13,4 gam hn hp bt nhm v st(III) oxit c hn hp G. Ho tan G trong dung dch NaOH d, thot ra 3,36 lt kh H2 (cc p/ xy ra hon ton, th tch kh o ktc). Khi lng st(III) oxit c trong hn hp ban u bng A. 6,8 gam. B. 5,4 gam. C. 12 gam D. 8 gam. Cu 47. C 5 mu kim loi Ba, Mg, Ag, Al, Fe. Ngi ta c th nhn bit c tng kim loi m ch cn dng mt dung dch cha mt ho cht lm thuc th l A. HCl. B. HNO3. C. NaOH. D. Fe(NO3)3. Cu 48. Pht biu no sau y khng ng: E. Mt cht c tnh oxi ho gp mt cht c tnh kh, c th xy ra phn ng oxi ho - kh. F. Mt cht hoc ch c tnh oxi ho hoc ch c tnh kh. G. Phn ng c kim loi tham gia l phn ng oxi ho - kh. H. Phi kim l cht oxi ho trong phn ng vi kim loi v hiro. Cu 49. Ru X c cng thc phn t CnHmOz ( z n ). X l ru no, mch h th gi tr thch hp ca m v n l A. m = 2n + 2. B. m = 2n + 1. C. m = 2n z. D. m = 2n + z. Cu 50. T cc s phn ng sau : c) X1 + X2 b)X3 + X4 Ca(OH)2 + H2 CaCO3 + Na2CO3 + H2O d) X3 + X5 Fe(OH)3 + NaCl + CO2 d)X6 + X7 + X2 Al(OH)3 + NH3 + NaCl Cc cht thch hp vi X2, X3, X4, X5 tng ng l: A. Ca ; NaOH ; Ca(HCO3)2 ; FeCl3 B. H2O ; Ca(HCO3)2 ; NaOH ; FeCl3 C. H2O ; NaHCO3 ; Ca(OH)2 ; FeCl3 D. Ca ; Ca(OH)2 ; NaHCO3 ; FeCl3 p n 1 C 21 D 41 D 2 C 22 A 42 C 3 D 23 D 43 A 4 B 24 C 44 D 5 A 25 A 45 A 6 B 26 B 46 D 7 C 27 C 47 D 8 C 28 A 48 B 9 D 29 A 49 A 10 A 30 D 50 C 11 C 31 A 18 B 12 D 32 D 19 C 13 B 33 A 20 B 14 A 34 C 38 D 15 A 35 B 39 C 16 A 36 B 40 D 17 C 37 C
S : 05
Cu 1. Nhm cc phn t, nguyn t v ion c tng s electron bng nhau : A. Na, Al3+, CH4, H2S, NH3, Mg. B. Na+, Al3+, CH4, H2O, NH3, Mg2+ 3+ D. Na, Al3+, SiH4, H2O, NH3, Mg2+ C. Na, Al , CH4, H2S, NH3, HF Cu 2. Hai nguyn t X, Y thuc 2 phn nhm chnh lin tip trong bng tun hon. Tng s electron trong 2 nguyn t X, Y bng 19. Phn t hp cht XxYy c tng s proton bng 70. Cng thc phn t hp cht l A. Mg3N2 B. CaC2 C. Al4C3 D. Na2O Cu 3. Phn ng este ho gia ru etylic v axit axetic nhit th nghim c hng s cn bng Kcb = 4. Thc hin phn ng este ho 1 mol axit axetic v 2 mol ru etylic nhit trn th s mol este thu c l A. 0,155 mol B. 0,55 mol C. 0,645 mol D. 0,845 mol
Cu 4. t chy m gam ng (II) sunfua trong kh oxi d thu c cht rn X c khi lng
bng (m 4,8) g Nung X trong kh NH3 d ti khi lng khng i c cht rn Y. Ho tan Y trong dung dch HNO3 long d, thu c V lt kh Z (ktc) khng mu, nng hn oxi. Gi tr ca m (gam) v V (lt) l A. 19,2g v 1,12 lit B. 28,8g v 1,68 lit C. 24,0g v 1,68 lit D. 28,8g v 1,12 lit Cu 5. Cho 4,48 lt kh CO (ktc) i t t qua ng s nung nng ng 23,2 gam Fe3O4. Sau khi dng phn ng, thu c cht rn X v kh Y c t khi so vi hiro bng 18. Ho tan X trong dung dch HNO3 long d thu c V lt kh NO (ktc). Khi lng cht rn X v th tch kh NO thu c l A. 21,6g v 2,24 lit B.20,0g v 3,36 lit C.20,8g v 2,8 lit D.21,6g v 3,36 lit Cu 6. Trn 250 ml dung dch gm HCl v H2SO4 c pH = 2 vo 250 ml dung dch Ba(OH)2 c pH = 13 thy c 0,1165 gam kt ta. Nng mol ca HCl v H2SO4 ban u ln lt l A. 0,003M v 0,002M B. 0,003M v 0,003M C. 0,006M v 0,002M D. 0,006M v 0,003M
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 7. Mt hn hp gm axit no n chc X v ru no n chc Y c khi lng phn t bng nhau. Chia hn hp ra 2 phn bng nhau : Phn 1 tc dng vi Na d thu c 0,56 lt H2. t chy hon ton phn 2 sinh ra 2,688 lt kh CO2. Cng thc phn t v phn trm khi lng X, Y trong hn hp l (cc th tch kh o ktc) A. HCOOH 60% ; C2H5OH 40% B. CH3COOH 60% ; C3H7OH 40% C. HCOOH 40% ; C2H5OH 60% D. CH3COOH 40% ; C3H7OH 60% Cu 8. un nng hn hp 3 ru no n chc X, Y, Z vi H2SO4 c 170oC ch thu c 2 anken l ng ng k tip nhau. Mt khc, khi un nng hn hp 2 trong 3 ru trn vi H2SO4 c 140oC th thu c 1,32 gam hn hp 3 ete c s mol bng nhau. T khi hi ca hn hp ete so vi hiro bng 44. Bit Y, Z c cng s nguyn t C v Y l ru bc1. Cng thc cu to ca X, Y, Z v % khi lng ca X trong hn hp A. X: CH3CH2OH 43,39%; Y: CH3CH2CH2OH ; Z: CH3CHOHCH3 B. X: CH3CH2OH 33,39%; Y: CH3CH2CH2OH Z: CH3CHOHCH3 C. X: CH3CH2CH2OH 43,39%; Y: CH3CH2CH2CH2OH Z: CH3CH2CHOHCH3 Z: CH3CH2CHOHCH3 D. X: CH3CH2CH2OH 33,39%; Y: CH3CH2CH2CH2OH Cu 9. Th tch hi ca 6,84 gam hn hp 2 cht X, Y l ng ng k tip nhau bng th tch ca 3,2 gam kh oxi o cng iu kin. t chy hon ton 3,42 gam hn hp trn cn dng 6,045 lt O2 (ktc) thu c 7,92 gam CO2. Oxi ho khng hon ton X hoc Y u thu c sn phm c phn ng trng gng v u c mch cacbon khng phn nhnh. Cng thc cu to ca X, Y tng ng l A. CH3OH v CH3CH2OH. B. CH3CH2OH v CH3CH2CH2OH C. CH3CH2CH2OH v CH3CH2CH2CH2OH D. CH3CH2CH2CH2OH v CH3CH2CH2CH2CH2OH Cu 10. 109,2oC v 1 atm, th tch ca 1,08 gam hn hp 2 cht hu c cng chc X, Y bng 627,2 ml. Nu cho 1,08 gam hn hp trn tc dng vi Na d th c 336 ml kh thot ra (ktc) ; cn nu t chy hon ton 1,08 gam hn hp ny th thu c 896 ml kh CO2 (ktc) v 1,08 gam H2O. Cng thc phn t X, Y l A. CH3OH v C2H5OH. B. C2H5OH v C2H4(OH)2 C. C2H4(OH)2 v C3H5(OH)3 D. C3H7OH v C2H4(OH)2 Cu 11. Ho hi 1,4 gam mt anehit X thu c th tch hi ng bng th tch ca 0,64 gam oxi cng iu kin nhit v p sut. Mt khc, hiro ho hon ton X (xt Ni, to ) thu c ru iso butylic. Cng thc cu to ca X l B. CH2=CHCH2CHO A. CH3CH2CH2CHO C. CH3CH(CH3)CHO D. CH2=C(CH3)CHO Cu 12. Ho tan cng mt lng oxit ca kim loi M (c ho tr khng i) trong dung dch HCl v dung dch HNO3. C cn 2 dung dch thu c 2 mui khan, thy khi lng mui nitrat nhiu hn khi lng mui clorua mt lng bng 99,38 % khi lng oxit em ho tan. Cng thc oxit l A. MgO B. Al2O3 C. CuO D. Fe2O3 Cu 13. Hoat tan hon ton 12 gam hn hp X gm CuO, Fe2O3, MgO cn dng va 225 ml dung dch HCl 2M. Mt khc, nu t nng 12 gam X trong kh CO d phn ng xy ra hon ton th thu c 10 gam cht rn Y. Phn trm khi lng Fe2O3 trong hn hp X bng A. 33,33 % B. 40,00 % C. 66,67 %. D. 50,00 % Cu 14. Kh m gam Fe2O3 bng CO mt thi gian c cht rn X. Ho tan ht cht rn X trong dung dch HNO3 long, thu c 0,224 lt kh NO (l sn phm kh duy nht ktc). C cn dung dch sau phn ng c 18,15 gam mui khan. Hiu sut ca phn ng kh oxit st bng A. 26,67 % B. 30,25 % C. 13,33 % D. 25,00 % Cu 15. ho tan hon ton mt hiroxit ca kim loi M (c ho tr khng i) cn mt lng axit H2SO4 ng bng khi lng hiroxit em ho tan. Cng thc phn t hiroxit kim loi l A. Al(OH)3 B. Fe(OH)3 C. Mg(OH)2 D. Cu(OH)2. Cu 16. Nh t t 3 V1 ml dung dch Ba(OH)2 (d.d X) vo V1 ml dung dch Al2(SO4)3 (d.d Y) th phn ng va v ta thu c kt ta ln nht l m gam.. Nu trn V2 ml dung dch X trn vo V1 ml dung dch Y th kt ta thu c c khi lng bng 0,9m gam. So snh t l V2 / V1 thy A. V2 / V1 = 2,7 hoc V2 / V1 = 3,55 B. V2 / V1 = 2,5 hoc V2 / V1 = 3,25 C. V2 / V1 = 1,7 hoc V2 / V1 = 3,75 D. V2 / V1 = 2,5 hoc V2 / V1 = 3,55 Cu 17. Hai cc ng axit H2SO4 long t trn 2 a cn A v B, cn v tr thng bng. Cho 5 gam CaCO3 vo cc a A ; 4,8 gam M2CO3 (M l kim loi kim). Sau khi phn ng xong, cn tr li v tr thng bng. Kim loi M l A. Li B. Na C. K D. Rb Cu 18. Ho tan 19,5 gam hn hp X gm Na2O v Al2O3 vo nc c 500 ml dung dch Y. Dn t t kh CO2 vo dung dch Y ng thi khuy u cho n khi bt u xut hin kt ta th dng li, thy th tch kh CO2 (ktc) dng ht 2,24 lt. Khi lng Na2O v Al2O3 trong hn hp X ln lt bng A. 6,2g v 13,3g B. 12,4g v 7,1g C. 9,3g v 10,2g D. 10,85g v 8,65g Cu 19. Cho 7 gam hn hp Cu, Fe (trong Fe chim 40 % khi lng) tc dng vi V ml dung dch HNO3 long, sau khi phn ng xy ra hon ton, thu c kh NO (sn phm kh duy nht) v cn li 4,76 gam kim loi khng tan v dung dch X ch cha mui nitrat kim loi. Khi lng mui c trong dung dch X bng A. 9,68 gam. B. 7,58 gam C. 7,20 gam D. 6,58 gam
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 20. Mnh no sau y khng ng ? A. S thay i nng cht phn ng lm chuyn dch cn bng. B. S thay i nng cht phn ng lm thay i hng s cn bng. C. S thay i nhit phn ng lm thay i hng s cn bng. D. S thay i nhit phn ng lm thay chuyn dch cn bng khi phn ng thu hoc to nhit. Cu 21. iu ch SO2 trong phng th nghim bng cch cho dung dch H2SO4 tc dng vi mui sunfit. Mui no sau y c chn iu ch SO2 l thun li nht ? B. CaSO3 v BaSO3 A. Na2SO3 v CaSO3. C. BaSO3 v CuSO3 D. CuSO3 v Na2SO3 Cu 22. M t hin tng th nghim no sau y khng ng ? A un nng dung dch lng trng trng, xut hin kt ta trng. B Nh vi git dung dch HNO3 vo dung dch lng trng trng thy xut hin kt ta mu vng. C. t chy mt mu lng trng trng xut hin mi kht nh mi tc chy. D.Nh vi git dung dch NaOH v dung dch CuSO4 vo dung dch lng trng trng, trn u thy xut hin mu vng. Cu 23. Polime no di y thc t khng s dng sn xut cht do ? A. Poli(vinyl clorua) B. Poliacrilonitrin C. Polimetylmetacrylat D. Poliphenol fomanehit Cu 24. Cho hn hp X gm 11,6 gam oxit st t v 3,2 gam Cu tc dng vi 400 ml dung dch HCl 1M. Kt thc phn ng, cho dung dch thu c tc dng vi dung dch AgNO3 d th khi lng kt ta thu c l A. 28,7 gam. B. 57,4 gam. C. 73,6 gam. D. 114,8 gam. Cu 25. thu c kt ta hon ton Al(OH)3 t dung dch mui c th thc hin phn ng: A. Cho dung dch AlCl3 tc dung vi dung dch NaOH d B. Cho dung dch Al2(SO4)3 tc dng vi dung dch Ba(OH)2 va C. Cho dung dch AlCl3 vi dung dch NH3 d. D. Cho dung dch NaAlO2 tc dng vi dung dch HCl d Cu 26. Na, K, Ca c sn xut trong cng nghip bng cch : A. Dng phng php nhit luyn B. in phn hp cht nng chy C. Dng phng php thu luyn D. in phn dung dich mui Cu 27. C hai cht bt ring bit Fe3O4 v Fe2O3, phn bit hai cht bt c th dng ho cht l: A. Dung dch HNO3 B. Dung dich HCl C. Dung dch HCl v Cu D. Dung dch H2SO4 long v Al Cu 28: Cho t t lung kh CO2 sc vo dung dch NaAlO2 cho n d hin tng xy ra l: A. Dung dch vn c sau trong tr li B. Dung dch b vn c C. Thi gian u khng c hin tng g, sau dung dch vn c D. Khng c hin tng g. Cu 29. Nhng thanh kim loi R (ho tr II)c khi lng 9,6g vo dung dch cha 0,24 mol Fe(NO3)3. Sau mt thi gian ly thanh kim loi ra, dung dch thu c c khi lng bng khi lng dung dch ban u, thanh kim loi sau em ho tan B. Mg. C. Ni. D. Cd. bng dd HCl d th thu c 6,272 lit H2(ktc). Kim loi R l A. Zn. Cu 30. iu khng nh no sau y khng ng ? A. un nng ru metylic vi axit H2SO4 c 170oC khng thu c anken. B. Anilin khng lm nc qu tm ho xanh. C. Phenol tc dng vi dung dch nc brom to kt ta trng. D. Tt c cc ru no a chc u ho tan c Cu(OH)2 to dung dch mu xanh lam. Cu 31. Cho a mol AlCl3 tc dng vi dung dch cha b mol NaOH. sau phn ng thu c kt ta th t l a : b bng A. a/b = 1/5 B. a/b = 1/4 C . a/b > 1/4 D . a/b < 1/4 Cu 32. Cho 6,94 gam hn hp gm FexOy v Al ho tan hon ton trong 100 ml dung dch H2SO4 1,8 M, to ra 0,672 lt H2 (ktc). Bit khi lng H2SO4 ly d 20% so vi lng cn thit cho phn ng . FexOy l A. FeO B. Fe2O3 Fe3O4 D. Bi ton khng gii c. Cu 33. nhn bit cc cht etanol, propenol, etylenglycol, phenol c th dng cp cht: A. nc brom v dung dch NaOH B. nc brom v Cu(OH)2 C. dung dch NaOH v Cu(OH)2 D. dung dch KMnO4 v Cu(OH)2 Cu 34. Cho Na d vo m gam dung dch ru etylic trong nc, thy lng hiro bay ra bng 0,03m gam. Nng phn trm C2H5OH trong dung dch bng A. 75,57 % B. 72,57 % C. 70,57 % D. 68,57 % Cu 35. Cc dung dch sau c cng nng mol/lit : NH3, Na2CO3, NaOH, NH4Cl. pH ca chng tng dn theo th t A. NH3, Na2CO3, NaOH, NH4Cl B. NH4Cl, Na2CO3, NaOH, NH3 C. NH3, NH4Cl, NaOH, Na2CO3 D. NH4Cl, Na2CO3, NH3, NaOH Cu 36. Kt lun no sau y khng ng ?
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
A. Hn hp Na2O + Al2O3 c th tan ht trong nc. B. Hn hp Fe2O3 + Cu c th tan ht trong dung dch HCl. C. Hn hp KNO3 + Cu c th tan ht trong dung dch NaHSO4. D. Hn hp FeS + CuS c th tan ht trong dung dch HCl. Cu 37. Cho s phn ng : X + HNO3 long Fe(NO3)3 + NO + H2O. S cht X c th thc hin phn ng trn l A. 3 B. 4 C. 5 D. 6. Cu 38. Trong s phn ng : a) Cu + X Y + Z ; b) Fe + Y Z + Cu c) Fe + X Z. d) Z + Cl2 X. Cc cht X,Y, Z ln lt l B. FeCl3 ; CuCl2 ; FeCl2 A. FeCl3 ; FeCl2 ; CuCl2 C. AgNO3 ; Fe(NO3)2 ; Cu(NO3)2 D. HNO3 ; Cu(NO3)2 ; Fe(NO3)3 Cu 39. X l mt anehit mch h, mt th tch hi ca X kt hp c vi ti a 3 th tch H2, sinh ra ancol Y. Y tc dng vi Na d c th tch H2 ng bng th tch hi ca X ban u ( cc th tch kh v hi o cng iu kin). X c cng thc tng qut l A. CnH2n 1CHO B. CnH2n (CHO)2 C. CnH2n + 1CHO D. CnH2n 2 (CHO)2. Cu 40. Pht biu no sau y l ng A. Cc axit hu c u tan trong nc . B. Cc axit hu c u lm qu tm. C. Cc axit hu c u th lng. D. Axit fomic mnh nht trong dy ng ng. Cu 41. Trong dy bin ho sau C2H6 C2H5Cl C2H5OH CH3CHO CH3COOH CH3COOC2H5 C2H5OH S phn ng oxi ho kh l A. 2 B. 3 C. 4 D. 6 Cu 42. C 2 axit cacboxylic X v Y. Trn 1 mol X vi 2 mol Y ri cho tc dng vi Na d c 2 mol H2 . Trn 2 mol X vi 1 mol Y ri cho tc dng vi Na d c 2,5 mol H2. S nhm chc trong X v Y l A. X, Y u n chc. B. X n chc, Y 2 chc C. X 2 chc, Y n chc. D. X, Y u 2 chc Cu 43. Khi t chy cc ng ng ca mt loi ancol th t l nCO2 : nH2O tng dn khi s nguyn t C trong ancol tng dn. Cng thc ca dy ng ng ancol l B. CnH2n + 2O, n 1 CnH2n 6O, n 7 D. CnH2n 2O, n 3 A. CnH2nO, n 3 Cu 44. t chy hon ton mt hirocacbon X thu c s mol CO2 bng s mol H2O. iu khng nh no sau y lun ng. A. X l mt anken B. X l mt xicloankan C. Phn t X cha mt lin kt D. T l s H : s C trong X lun bng 2:1 Cu 45. T capron l mt loi A. t axetat B. t visco C. t poliamit D. t polieste. Cu 46. Dy gm cc cht u tc dng vi dung dch Ag2O/NH3 l A. axetandehit, butin -1, eten B. axetandehit, butin -2, etin C. natri fomiat, vinylaxetilen, etin D. natri fomiat, vinylaxetilen, eten. Cu 47. in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,32 gam Cu catot v mt lng kh X anot. Hp th ton b lng kh x trn vo 200 ml dung dch NaOH ( nhit thng ). Sau phn ng, nng NaOH cn li l 0,05M (gi thit th tch dung dch khng thay i). Nng ban u ca dung dch NaOH l (Cu = 64) A. 0,15M B. 0,2M C. 0,1M D. 0,05M.
Cu 48. -aminoaxit X cha mt nhm NH2. Cho 10,3 gam X tc dng vi axit HCl(d) , thu c 13,95 gam mui khan. cng thc cu to thu gn ca X l(cho H = 1, C = 12, O = 16, N =
A. H2NCH2COOH B. H2NCH2CH2COOH C. CH3CH2CH(NH2)COOH D. CH3CH(NH2)COOH Cu 49. Cho dy cc cht : Ca(HCO3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong dy c tnh cht lng tnh l A. 3 B. 5 C. 4 D. 2 Cu 50. t chy hon ton a mol axit hu c Y c 2a mol CO2. Mt khc trung ho a mol Y cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l A. HOOC-CH2CH2-COOH B. C2H5COOH
C. CH3-COOH
D. HOOC-COOH.
p n 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17
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20 B THI TH I HC
B 21 D 41 B C 22 D 42 C D 23 B 43 B B 24 B 44 D A 25 C 45 C C 26 B 46 C B 27 A 47 C A 28 B 48 C C 29 B 49 C B 30 D 50 D D 31 C 18 C
Mn: ho hc
D 32 B 19 C A 33 B 20 B C 34 A 38 B D 35 D 39 D A B 36 37 D C 40 D
Nm hc 2010-2011
S : 06
Cu 1: Hn hp X cha K2O, NH4Cl, KHCO3 v BaCl2 c s mol bng nhau. Cho hn hp X vo nc (d), un nng, dung dch thu c cha A. KCl, KOH. B. KCl. C. KCl, KHCO3, BaCl2. D. KCl, KOH, BaCl2. Cu 2: Cho hp cht hu c X c cng thc phn t C6H6O2. Bit X tc ng vi dung dch KOH theo t l mol l 1 : 2. S ng phn cu to ca X l A. 3. B. 4. C. 1. D. 2. Cu 3: Cho Ba kim loi ln lt vo cc dung dch sau: NaHCO3, CuSO4, (NH4)2CO3, NaNO3, MgCl2. S dung dch to kt ta lA. 1. B. 2. C. 3. D. 4. Cu 4: Ho tan ht cng mt lng Fe trong dung dch H2SO4 long (1) v H2SO4 c nng (2) th th tch kh sinh ra trong cng iu kin l A. (1) bng (2). B. (1) gp i (2). C. (2) gp ri (1). D. (2) gp ba (1). Cu 5: C bao nhiu hp cht hu c (cha C, H, O) phn t khi l 60 v tc dng c vi Na kim loI A. 5. B. 4. C. 3. D. 2. Cu 6: Hn hp gm C2H5OH, CH3CHO, CH3COOH. Ngi ta thu hi CH3COOH bng cch dng ho cht A. Na, dung dch H2SO4. B. Ag2O/NH3, dung dch H2SO4. C. Cu(OH)2, dung dch NaOH. D. dung dch NaOH, dung dch H2SO4. Cu 7: Cho s : Ru anken polime. C bao nhiu polime to thnh t ru c cng thc phn t C5H12O c mch cacbon phn nhnh: A. 3. B. 4. C. 5. D. 6. Cu 8: Cho cc cht: C2H6, C2H4, CH3CHO, CH3COOCH=CH2. S cht ph hp vi cht X theo s sau C2H2 X Y CH3COOH. A. 4. B. 3. C. 2. D. 1. Cu 9: C4H8O2 l hp cht tp chc ru - anehit. S ng phn ca n l A. 3. B. 4. C. 5. D. 6. Cu 10: Cho s : + O2 + CH3OH trng hp X Y D E thu tinh plecxiglat. X c cng thc l: A. CH3CH(CH3)CH2OH. B. CH2=C(CH3)CH2OH. C. CH2=C(CH3)CH2CH2OH. D. CH3CH(CH3)CH2CH2OH. Cu 11: t chy hon ton 10 ml mt este cn 45 ml O2 thu c V CO2 : V H2O = 4 : 3. Ngng t sn phm chy thy th tch gim 30 ml. Cc th tch o cng iu kn. Cng thc ca este l A. C4H6O2. B. C4H6O4. C. C4H8O2 D. C8H6O4. Cu 12: Cho mt t bt st vo dung dch AgNO3 d, sau khi kt thc th nghim thu c dung dch X gm B. Fe(NO3)2 , AgNO3 d, H2O. A. Fe(NO3)2 , H2O. C. Fe(NO3)3 , AgNO3 d, H2O. D. Fe(NO3)2 , Fe(NO3)3 , AgNO3 d, H2O. Cu 13: Dung dch cha cc ion Na+, Ca2+, Mg2+, Ba2+, H+, Cl. Phi dng dung dch cht no sau y loi b ht cc ion Ca2+, Mg2+, Ba2+, H+ ra khi dung dch ban u? A. K2CO3. B. NaOH. C. Na2SO4. D. AgNO3. Cu 14: Mt hn hp X c khi lng m gam gm Ba v Al. Cho m gam X tc dng vi nc d, thu c 8,96 lt kh H2.Cho m gam X tc dng vi dung dch Ba(OH)2 d thu c 22,4 lt kh H2. (Cc phn ng u xy ra hon ton, cc th tch kh o iu kin tiu chun, cho Al = 27, Ba = 137). m c gi tr l: A. 29,9 gam. B. 27,2 gam. C. 16,8 gam. D. 24,6 gam. Cu 15: Cho cc cu sau: 1- Cht bo thuc loi cht este. 2- T nilon, t capron, t enang u iu ch bng phn ng trng ngng.
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
3- Vinyl axetat khng iu ch c trc tip t axit v ru tng ng. 4- Nitro benzen phn ng vi HNO3 c (xc tc H2SO4 c) to thnh m-initrobenzen. 5- Anilin phn ng vi nc brom to thnh p-bromanilin. Nhng cu ng l: A. 1, 2, 4. B. 2, 3, 4. C. 1, 4, 5. D. 1, 3, 4. Cu 16: Cho hn hp hai aminoaxit u cha 1 nhm amino v 1 nhm cacboxyl vo 440 ml dung dch HCl 1M c dung dch X. tc dng ht vi dung dch X cn 840 ml dung dch NaOH 1M. Vy khi to thnh dung dch X th A. aminoaxit v HCl cng ht. B. d aminoaxit. C. d HCl. D. khng xc nh c. Cu 17: Hn hp X gm hai axit cacboxylic u no, mch h. Trung ho 0,3 mol X cn 500 ml dung dch NaOH 1M. Khi t chy hon ton 0,3 mol X thu c 11,2 lt CO2 ( ktc). Cng thc ca hai axit l: A. HCOOH; C2H5COOH. B. CH3COOH; C2H5COOH. C. HCOOH; (COOH)2. D. CH3COOH; CH2(COOH)2. Cu 18: un 9,2 gam glixerin v 9 gam CH3COOH c xc tc thu c m gam sn phm hu c E cha mt loi nhm chc. Bit hiu sut phn ng bng 60%. Gi tr ca m l: A. 8,76. B. 9,64. C. 7,54. D. 6,54. Cu 19: t chy hon ton 1,44 gam hp cht thm X thu c 2,86 gam CO2, 0,45 gam H2O v 0,53 gam Na2CO3. X c cng thc phn t trng vi cng thc n gin nht. Cng thc ca X l A. C6H5COONa. B. C6H5ONa. C. C6H5CH2ONa. D. C6H5CH2CH2ONa. Cu 20: Bt nhm dng ch to hn hp tec mit hn kim loi. Thnh phn ca hn hp tec mit gm A. Al2O3 v Fe3O4. B. Al v Fe2O3. C. Al v FeO. D. Al v Fe3O4. Cu 21: Cho V lt kh CO2 ( ktc) hp th hon ton vo 200 ml dung dch hn hp KOH 1M v Ba(OH)2 0,75M thu c 27,58 gam kt ta. Gi tr ln nht ca V l (cho C = 12, O =16, Ba = 137) A. 6,272 lt. B. 8,064 lt. C. 8,512 lt. D. 2,688 lt. Cu 22: Cho 10 gam hn hp Fe, Cu (cha 40% Fe) vo mt lng H2SO4 c, un nng. Kt thc phn ng, thu c dung dch X, kh Y v cn li 6,64 gam cht rn. Khi lng mui to thnh trong dung dch X l (cho O = 16; S = 32; Fe = 56; Cu = 64) A. 9,12 gam. B. 12,5 gam. C. 14,52 gam. D. 11,24 gam. Cu 23: Cho 3,04 gam hn hp X gm FeO, Fe3O4, Fe2O3. kh hon ton hn hp X th cn 0,1 gam hiro. Mt khc, ho tan hn hp X trong H2SO4 c, nng th th tch kh SO2 (l sn phm kh duy nht ktc) l (cho H = 1; O = 16; Fe = 56) A. 112 ml. B. 224 ml. C. 336 ml. D. 448 ml. Cu 24: Mt este ca ru metylic tc dung vi nc brom theo t l s mol l 1 : 1. Sau phn ng thu c sn phm trong brom chim 35,1% theo khi lng. Este l: A. metyl propionat.B. metyl panmitat. C. metyl oleat. D. metyl acrylat. Cu 25: Trn dung dch cha a mol NaAlO2 vi dung dch cha b mol HCl. thu c kt ta th cn c t l : A. a : b = 1 : 4. B. a : b < 1 : 4. C. a : b = 1 : 5. D. a : b > 1 : 4. Cu 26: Cho mt axit cacboxylic n chc tc dng vi etylenglicol thu c mt este duy nht. Cho 0,2 mol este ny tc dng va vi dung dch NaOH thu c 16,4 gam mui. Axit l: D. C2H3COOH. A. HCOOH. B. CH3COOH. C. C2H5COOH. Cu 27: t chy hon ton 1,18 gam mt hp hp cht amin n chc Y bng mt lng khng kh va . Dn ton b kh sau phn ng vo bnh ng dung dch Ca(OH)2 d thu c 6 gam kt ta v 9,632 lt kh ( ktc) duy nht thot ra khi bnh. Tm cng thc phn t ca Y. A. CH5N. B. C2H7N. C. C3H9N. D. C4H11N. Cu 28: Kh 1,6 gam hn hp hai anehit no bng kh H2 thu c hn hp hai ru. un hai ru ny vi H2SO4 c c hn hp hai olefin l ng ng k tip. t hai olefin ny c 3,52 gam CO2. Bit cc phn ng xy ra hon ton. Cng thc ca hai anehit l (cho H = 1; C =12; O = 16) A. HCHO, CH3CHO. B. CH3CHO, C2H5CHO. C. C2H5CHO, C3H7CHO. D. Khng xc nh c. Cu 29: Trong qu trnh in phn dung dch KCl, qu trnh no sau y xy ra cc dng (anot) A. ion Cl b oxi ho. B. ion Cl b kh. C. ion K+ b kh. D. ion K+ b oxi ho. Cu 30: lm mm mt loi nc cng c cha CaCl2 v Mg(HCO3)2 ta c th dng A. Na3PO4. B. NaOH. C. NaCl. D. Ca(OH)2.
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 31: Hn hp hai cht hu c tc dng vi dung dch NaOH thu c hai mui ca hai axit n chc v mt ru. Hai cht hu c l 1) X, Y l hai este ca cng mt ru. 2) X, Y l hai este ca cng mt axit. 3) X, Y l mt este v mt axit. 4) X, Y l mt este v mt ru. Nhng cu ng l A. (1), (2). B. (2), (3). C. (3), (4). D. (1), (3). Cu 32: un hn hp gm metanol, etanol v propanol-1 vi H2SO4 c nhit thch hp t 140o n 180oC th thu c bao nhiu sn phm l hp cht hu c? A. 5. B. 6. C. 8. D. 9. Cu 33: Cho cc cht: C4H10O, C4H9Cl, C4H10, C4H11N. S ng phn ca cc cht gim theo th t B. C4H11N, C4H9Cl, C4H10O, C4H10. A. C4H9Cl, C4H10, C4H10O, C4H11N. C. C4H11N, C4H10O, C4H9Cl, C4H10. D. C4H11N, C4H10O, C4H10, C4H9Cl. Cu 34: Khi vt bng gang, thp b n mn in ho trong khng kh m, nhn nh no sau y ng? A. Tinh th st l cc dng, xy ra qu trnh kh. B. Tinh th st l cc m, xy ra qu trnh oxi ho. C. Tinh th cacbon l cc dng, xy ra qu trnh oxi ho. D. Tinh th cacbon l cc m, xy ra qu trnh oxi ho. Cu 35: t chy hon ton a gam mt ru thu c 33a/23 gam CO2 v 18a/23 gam H2O. Ru l: A. C2H5OH. B. C2H4(OH)2. C. C3H7OH. D. C3H5(OH)3. Cu 36: X phng ho hon ton 0,1 mol mt este n chc bng 180 ml dung dch MOH 1 mol/lt (M l kim loi kim). C cn dung dch thu c cht rn A. t ht cht rn A thu c 12,42 gam M2CO3. Kim loi M l A. Li. B. Na C. K. D. Rb. Cu 37: Xt phn ng: 2Al + 2NaOH + 2H2O 2NaAlO2 + 3H2. Vai tr ca cc cht l: A. Al l cht kh, nguyn t H trong NaOH ng vai tr l cht oxi ho. B. Al l cht kh, nguyn t O trong NaOH ng vai tr l cht oxi ho. C. Al l cht kh, nguyn t H trong H2O ng vai tr l cht oxi ha. D. Al l cht kh, nguyn t H trong c NaOH v H2O ng vai tr l cht oxi ho. Cu 38: Cho 20 gam S vo mt bnh c dung tch bng 44,8 lt cha O2 ( ktc), th tch cht rn khng ng k. Nung bnh cho n khi phn ng hon ton, p sut trong bnh khi tr v 0oC l (cho S = 32) A. 2atm. B. 2,1atm. C. 1atm. D. 1,2atm. Cu 39: Dung dch mui no di no di y c pH > 7 ? A. NaHSO4. B. NaNO3. C. NaHCO3. D. (NH4)2SO4. Cu 40: Ho tan hon ton 16 gam hn hp Mg v Fe bng dung dch H2SO4 long va . Sau phn ng thy khi lng dung dch tng thm 15,2 gam so vi ban u. Khi lng mui khan thu c khi c cn dung dch sau phn ng l (cho H = 1; O = 16; Mg = 24; S = 32; Fe = 56) A. 53,6 gam. B. 54,4 gam. C. 92 gam D. 92,8 gam. Cu 41: Ch dng thm dung dch H2SO4 long, c th nhn bit c bao nhiu kim loi trong s cc kim loi: Mg, Al, Fe, Cu, Ba? A. 2. B. 3. C. 4. D. 5. Cu 42: Cho s phn ng: CH2=CH2 + KMnO4 + H2SO4 (COOH)2 + MnSO4 + K2SO4 + H2O T l v h s gia cht kh v cht oxi ho tng ng l: A. 5 : 2. B. 2 : 5. C. 2 : 1. D. 1 : 2. Cu 43: Cho 11,6 gam mui FeCO3 tc dng va vi dung dch HNO3, c hn hp kh CO2, NO v dung dch X. Khi thm dung dch HCl (d) vo dung dch X, th dung dch thu c ho tan ti a bao nhiu gam bt ng kim loi, bit rng c kh NO bay ra. (Cho C = 12; O = 16; Fe = 56; Cu = 64). A. 14,4 gam B. 7,2 gam. C. 16 gam. D. 32 gam. Cu 44: Dy no sau y xp theo chiu tng dn bn knh ca cc ion? A. Al3+ ; Mg2+; Na+ ; F ; O2. B. Na+; O2; Al3+ ; F; Mg2+. C. O2; F; Na+; Mg2+; Al3+. D. F; Na+; O2; Mg2+; Al3+. Cu 45: Nhit phn hon ton Fe(NO3)2 trong khng kh thu c sn phm gm: A. FeO, NO2, O2. B. Fe2O3, NO2. C. Fe, NO2, O2. D. Fe2O3, NO2, O2.
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 46: C bn hp cht hu c cng thc phn t ln lt l: CH2O, CH2O2, C2H2O3 v C3H4O3. S cht va tc dng vi Na, va tc dng vi dung dch NaOH, va c phn ng trng gng l: A. 1. B. 2. C. 3. D. 4. Cu 47: Nhit phn hon ton m gam hn hp X gm CaCO3 v Na2CO3 thu c 11,6 gam cht rn v 2,24 lt kh (ktc). Khi lng CaCO3 v Na2CO3 trong hn hp X ln lt l (cho C = 12; O = 16; Na = 23; Ca = 40) A. 10,0 gam v 6,0 gam. B. 11,0 v 6,0 gam. C. 5,6 gam v 6,0 gam. D. 5,4 gam v 10,6 gam. Cu 48: X phng ho este C5H10O2 thu c mt ru. un ru ny vi H2SO4 c 170oC c hn hp hai olefin. Este l: B. CH3COOCH(CH3)2. A. CH3COOCH2CH2CH3. C. HCOOCH(CH3)C2H5. D. HCOO(CH2)3CH3. Cu 49: Cho hai mui X, Y tho mn iu kin sau: X + Y khng xy ra phn ng. X + Cu khng xy ra phn ng. Y + Cu khng xy ra phn ng. X + Y + Cu xy ra phn ng. X v Y l mui no di y? A. NaNO3 v NaHSO4. B. NaNO3 v NaHCO3. C. Fe(NO3)3 v NaHSO4. D. Mg(NO3)2 v KNO3. Cu 50: Cho dung dch cha a mol Ca(HCO3)2 vo dung dch cha a mol Ca(HSO4)2. Hin tng quan st c l A. si bt kh v vn c. B. vn c. C. si bt kh. D. vn c, sau trong sut tr li.
P N 1 B 21 B 41 D 2 A 22 A 42 D 3 D 23 B 43 D 4 C 24 C 44 A 5 B 25 D 45 D 6 D 26 B 46 C 7 A 27 C 47 C 8 B 28 B 48 C 9 C 29 A 49 A 10 B 30 A 50 A 11 A 31 D 18 D 12 C 32 C 19 A 13 A 33 C 20 D 14 A 34 B 38 C 15 D 35 D 39 C 16 C 36 C 40 B 17 C 37 C
S : 07
Cu 1. Thc hin p/ nhit nhm m gam hn hp A gm Al, Fe2O3 c hn hp B ( H = 100%). Chia B thnh 2 phn bng nhau. Ho tan phn 1 trong H2SO4 long d, thu c 1,12 lt kh (ktc). Ho tan phn 2 trong dung dch NaOH d th khi lng cht khng tan l 4,4 gam. Gi tr ca m bng: A. 6,95g. B. 13,9g. C. 8,42g. D. 15,64g. Cu 2. Ly 13,4gam hn hp Al v Fe2O3 thc hin hon ton p/ nhit nhm, thu c cht rn X. Ho tan hon ton X trong dung dch H2SO4 long d thy thot ra 5,6 lt kh H2 (ktc). Khi lng Al v Fe2O3 trong hn hp ban u ln lt l (cho Al = 27, Fe = 56): A. 5,4g v 8,0g. B. 2,7g v 10,7g. C. 8,1g v 5,3g. D. 10,8g v 2,6g Cu 3. Ly 11 gam hn hp gm Al v Fe cho tc dng hon ton vi dung dch HCl long thu c 8,96 lit kh H2 (ktc). Phn trm khi lng ca Al v Fe trong hn hp ban u tng ng l: A. 49,09% v 50,91%. B. 36,82% v 63,18%. C. 61,36% v 38,64%. D. 73,64% v 26,36%. Cu 4. Cho 2,2 gam hn hp Al v Fe trong s nguyn t Al gp i s nguyn t Fe, tc dng vi lng d dung dch mui clorua ca kim loi M ( M c ho tr II trong mui v ng sau Al, Fe trong dy in ho) thu c 5,12 gam cht rn. Cng thc mui ca kim loi M l: A. Ni. B. Pb. C. Cu. D. Hg Cu 5. X l mt hirocacbon th kh. t chy hon ton X thu c th tch kh CO2 gp hai ln th tch hi nc. Nu t chy hon ton X bng mt th tch kh oxi dng d 20% th hn hp kh thu c sau khi lm ngng t hi nc s bng 2,5 ln th tch ca X em t.( cc th tch kh v hi o cng iu kin to, p) Cng thc ca X l cht no sau y: A. C2H4. B. C4H4. C. C3H4. D. C2H2.
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 6. Ho tan 10 gam hn hp Cu2S v CuS bng 200 ml dung dch KMnO4 0,75M trong mi trng axit H2SO4. Sau khi un si ui ht kh SO2 sinh ra, lng KMnO4 cn d phn ng va ht vi 175 ml dung dch FeSO4 1M. Khi lng CuS trong hn hp ban u l: A. 4 gam. B. 5 gam. C. 6 gam. D. 7 gam. Cu 7. C cc dung dch sau ng trong cc l mt nhn : NaHSO4, Na2CO3, AlCl3, FeCl3, NaNO3, Ca(NO3)2 Ch cn dng thm mt ho cht lm thuc th, c th nhn bit c tng dung dch trn. Ho cht l ho cht no sau y ? A. dung dch Ba(OH)2 B. dung dch MgCl2 C. dung dch KOH D. phenolphtalein. Cu 8. Ho tan ht 2,2 gam hn hp Al v Fe bng dung dch HNO3 long thu c dung dch Y v 448 ml kh (ktc) gm N2O v N2 c t khi so vi hiro bng 18. Khi lng Fe c trong hn hp l: A. 0,56g B. 1,12g C. 0,84g D.1,68g Cu 9. Cho 3,584 lt (ktc) hn hp gm mt ankan (X), mt anken (Y), mt ankin (Z). Ly hn hp cho tc dng vi dung dch AgNO3 d trong amoniac thy th tch hn hp gim 12,5% v thu c 1,47 gam kt ta. Cho hn hp cn li i qua dung dch brom d thy khi lng bnh brom tng 2,22 gam v c 13,6 gam brom phn ng. t chy hon ton lng kh i ra khi bnh brom ri hp th ton b sn phm chy vo dung dch Ba(OH)2 d th thu c 2,955 gam kt ta. Cc cht X, Y, Z ln lt l: A. CH4, C2H4, C2H2. B. C3H8, C2H4, C3H4. C. C3H8, C2H4, C2H2. D. CH4, C2H4, C3H4. Cu 10. Cho hn hp kh X (ktc) gm 2 anken l ng ng k tip nhau tc dng vi H2O (xt, to) ri tch ly ton b ru to thnh. Chia hn hp ru thnh 2 phn bng nhau. Phn 1 tc dng ht vi Na to ra 420 ml kh H2 (ktc). t chy hon ton phn 2 thu c CO2 c khi lng nhiu hn khi lng H2O l 1,925 gam. Cng thc cc ru l: A. C2H5OH v C3H7OH B. C3H7OH v C4H9OH D. CH3OH v C2H5OH C. C4H9OH v C5H11OH Cu 11. Trn ln 30 ml dung dch HCl a mol/l vi 50 ml dung dch Ba(OH)2 c pH = 12,5 c dung dch X c pH = 10. Nng mol ca dung dch HCl : a c gi tr bng: A. 0,0524M. B. 0,5240M C. 0,2524M D. 0,0254M. Cu 12. Cho cc cht sau : CH2=CH-Cl (1) ; CH3-CH2-Cl (2) ; CH2=CH-CH=O (3) ; CH3-CH=O (4). phn cc phn t c sp xp theo chiu gim dn nh sau : A. 1, 2, 3, 4 B.3, 4, 2, 1 C. 3, 4, 1, 2 D. 4, 3, 2, 1. Cu 13. t chy hn hp kh X gm H2S v 6,72 lt kh O2. Lm lnh hn hp sau phn ng ngng t ht hi nc thy cn li 5,6 lt kh Y. Th tch kh SO2 trong Y l (bit phn ng xy ra hon ton, cc th tch kh o ktc ; S = 32 ; O = 16 ; H = 1): A. 4,48 lit B. 3,36 lt C. 3,36 lt hoc 2,24 lt D. 4,48 lit hoc 2,24 lt Cu 14. Ho cht T l mt cht bt mu trng, bit rng T ch c th l mt trong cc ho cht sau : MgCl2, CaCO3, BaCl2, CaSO4. xc nh T l ho cht no c th dng thuc th no sau y ? C. H2O v HNO3. D. H2O v H2SO4. A. H2O v HCl. B. H2O v NaOH. Cu 15. Ho tan 14,3 gam Na2CO3.10H2O vo 85,7 gam nc c dung dch X. Cho rng khi lng ring ca nc l 1g/ml v th tch ca nc l th tch dung dch. Nng % v khi lng ring ca dung dch X ln lt bng : A. 5,3 % v 1,06 g/ml. B. 5,3 % v 1,17 g/ml. C. 14,3 % v 1,06 g/ml. D. 14,3 % v 1,17 g/ml. Cu 16. Mt hn hp kh gm CO2 v kh X, trong CO2 chim 82,5% khi lng cn X chim 25% th tch. Bit hn hp kh ny c kh nng lm mt mu dung dch brom v dung dch thuc tm. Kh X l cht kh no sau y ? A. CO. B. NO C. C2H2. D. C2H4. Cu 17. Mt hn hp gm Al2(SO4)3 v K2SO4, trong s nguyn t oxi chim 20/31 tng s nguyn t c trong hn hp. Ho tan hn hp trn vo nc ri cho tc dng vi dung dch BaCl2 d, hi khi lng kt ta thu c gp bao nhiu ln khi lng hn hp ban u: A. 1,488 ln B. 1,588 ln C. 1,688 ln D. 1,788 ln Cu 18. Ho tan hon ton FeS2 vo cc cha dung dch HNO3 long c dung dch X v kh NO thot ra. Thm bt Cu d v axit sunfuric vo dung dch X, c dung dch Y c mu xanh, nhng khng c kh thot ra. Cc cht tan c trong dung dch Y l: A. Cu(NO3)2 ; Fe(NO3)3 ; H2SO4. B. Cu(NO3)2 ; Fe(NO3)2 ; H2SO4. C. CuSO4 ; Fe2(SO4)3 ; H2SO4. D. CuSO4 ; FeSO4 ; H2SO4. Cu 19. C 3 gi bt trng khng ghi nhn, mi gi cha ring r hn hp 2 cht sau : NaCl v KCl ; Na2CO3 v K2CO3 ; MgSO4 v BaCl2. Ngi ta ch dng 1 ho cht l c th nhn ra c 3 gi bt trng trn. Ho cht no trong cc ho cht sau khng dng phn bit c 3 gi bt trng trn: A. dung dch HCl B. dung dch Ba(OH)2 C. dung dch H2SO4 D. H2O.
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 20. Cho 3,8 gam hn hp gm cc kim loi Mg, Al, Zn, Cu tc dng hon ton vi oxi d thu c hn hp X c khi lng 5,24 gam. Th tch (ti thiu) dung dch HCl 0,5M cn dng ho tan hon ton X l: A. 180 ml B. 360 ml C. 240 ml D. 480 ml. Cu 21. Cho mt lng bt CaCO3 tc dng hon ton vi dung dch HCl 32,85%, sau phn ng thu c dung dch X trong nng HCl cn li l 24,2% v CaCl2 l a%. Gi tr ph hp ca a l: A. 10,51% B.11,51% C. 11,09% D. 10,09% Cu 22. Hn hp Z gm 2 axit no n chc k tip nhau trong dy ng ng. t chy hon ton mt lng hn hp Z thu c CO2 c khi lng ln hn khi lng H2O l 2,73 gam. Nu ly cng mt lng hn hp Z nh trn cho tc dng vi NaOH va th sau phn ng thu c lng mui khan l 3,9 gam. Cng thc 2 axit l: A. HCOOH v CH3COOH B. CH3COOH v C2H5COOH C. C2H5COOH v C3H7COOH D. C3H7COOH v C4H9COOH Cu 23. Cho mt lng ru Y i vo bnh ng Na d, sau khi phn ng hon ton, thy khi lng bnh tng 6,0 gam v c 2,24 lt kh H2 (ktc) thot ra. Ru Y l ru no sau y ? A. C2H5OH B. C3H5(OH)3 C. C2H4(OH)2 D. C3H7OH Cu 24. t chy hon ton 1,8 gam ru no Z thu c 1,8 gam nc. Bit MZ < 100. S cng thc cu to c th c ca Z l: A. 3. B. 6. C. 5. D. 7. Cu 25. Cho 3,1 gam ancol(ru) X tc dng vi Na d, sinh ra 5,3 gam ancolat. Cng thc ru X l: A. C2H5OH B. C3H5(OH)3 C. C2H4(OH)2 D. C3H7OH Cu 26. Cho s sau: X + H2 Y ; X + O2 Z ; Y + Z C4H4O4 + 2H2O. Cc cht Y, Z l A. Y : CH3OH ; Z : C2H2O4 B. Y : C2H4(OH)2 ; Z : H2CO2 C. Y : C2H5OH ; Z : C2H2O4 D. Y : C2H4(OH)2 ; Z : C2H2O4 Cu 27. Cho mt lung kh CO i qua ng s ng 0,04 mol hn hp X gm FeO v Fe2O3 t nng. Kt thc th nghim, thu c hn hp Y gm 4 cht, nng 4,784 gam. Kh i ra khi ng s c hp th vo dung dch Ca(OH)2 d th thu c 4,6 gam kt ta. Phn trm khi lng ca FeO trong X l: A. 10,40% B. 13,04% C. 89,60% D. 86,96% Cu 28. Chia 22 gam hn hp 2 ru no n chc l ng ng k tip thnh 2 phn bng nhau : Cho phn 1 tc dng ht vi Na thu c 3,36 lt kh H2(ktc). t chy hon ton phn 2 to ra V lt kh CO2 v m gam H2O. Vy gi tr ca V v m tng ng vi gi tr no sau y: A. 8,96 lit ; 12,6 g B. 6,72 lit ; 10,8 g C. 11,2 lit ; 12,6 g D. 8,96 lit ; 10,8 g Cu 29. Cho 13,92 gam oxit st t tc dng vi dung dch HNO3 thu c 0,448 lt kh NxOy (ktc). Khi lng HNO3 tham gia phn ng l: A. 34,02 gam B. 35,28 gam C. 11,34 gam D. 31,50 gam. Cu 30. Cho 18,56 gam mt oxit st tc dng ht vi dung dch HNO3 to ra 0,224 lt kh(ktc) mt oxit ca nit. Cng thc ca oxit st v oxit nit ln lt l: A. Fe2O3 v N2O B. Fe3O4 v NO2 C. Fe2O3 v NO D. Fe3O4 v N2O Cu 31. X v Y c cng cng thc phn t C3H8O v cng phn ng c vi Na. Oxi ho nh X v Y bi CuO un nng, thu c X1 v Y1 tng ng trong Y1 cho phn ng trng gng cn X1 khng c phn ng ny. Tn ca X v Y tng ng l: A. propanol-1 v propanol-2 B. propanol-2 v propanol-1 C. propanol-1 v propanal D. etylmetylete v propanol-1 Cu 32. Chia dung dch c ho tan 4,14 gam mui R2CO3 (R l mt kim loi kim) thnh 2 phn bng nhau. Cho 160 ml dung dch HCl 0,2M vo phn 1 th sau phn ng axit vn cn d. Cho dung dch BaCl2 vo phn 2, lc c 2,561 gam kt ta. R2CO3 l mui no sau y, bit cc phn ng xy ra hon ton ? (cho Ba = 137, Li = 7, Na = 23, K = 39, Rb = 85, Cs = 133, C = 12, O = 16): A. Rb2CO3 B. Cs2CO3 C. Na2CO3 D. K2CO3 Cu 33. Cho 20,7 gam hn hp CaCO3 v K2CO3 phn ng ht vi dung dch HCl d, thu c kh Y. Sc ton b kh Y t t vo dung dch ch cha 0,18 mol Ba(OH)2, thu c m gam kt ta. Hi m c gi tr trong khong no: A. 35,46 m 29,55 B. 35,46 m > 29,55 C. 35,46 m 30,14 D. 35,46 m > 0 Cu 34. Cht hu c Y1 trong phn t ch cha mt loi nhm chc, c phn trm khi lng C v H tng ng bng 49,315% v 6,85%, cn li l oxi. T khi hi ca Y1 so vi khng kh xp x bng 5,034. Cho Y1 tc dng vi dung dch NaOH, sinh ra mt mui (Y2) v mt ru (Y3). Nung mui Y2 vi hn hp vi ti xt thu c mt hirocacbon n gin nht. Cng thc Y2 v Y3 ln lt l: A. HCOONa v HOCH2CH2CH2CH2OH B. CH3CH2COONa v CH3CH2CH2OH C. CH3COONa v HOCH2CH2OH D. NaOOCCH2COONa v CH3OH. Cu 35. Thc hin phn ng x phng ho hn hp vinyl axetat v phenyl axetat bng dung dch NaOH d, un nng. Sn phm thu c ngoi natri axetat cn c: A. ru vinylic v ru benzylic. B. axetandehit v natri phenolat.
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
C. axetandehit v phenol. D. ru vinylic v phenol. Cu 36. t chy hon ton 7,7 gam cht hu c Z (c cng thc phn t trng vi cng thc n gin nht) bng oxi, thu c 6,3 gam H2O, 4,48 lt CO2, 1,12 lt N2 (cc kh o ktc). Cho Z phn ng vi dung dch NaOH un nng, c kh Z1. Kh Z1 lm xanh giy qu tm m v khi t chy Z1 thu c sn phm lm c nc vi trong. Cng thc cu to ca Z l cng thc no sau y: A. HCOOH3NCH3 B. CH3COONH4 C. CH3CH2COONH4 D. CH3COOH3NCH3 Cu 37. Hn hp R gm Fe2O3, CuO, CaO c t l s mol tng ng l 1:2:3. Dn 14 lt kh CO (ktc) i vo ng s ng R nung nng n phn ng hon ton, c kh T c t khi so vi hiro bng 20,4 v cht rn X. Phn trm khi lng cc cht rn trong X: A. 27,45% Fe ; 31,37% Cu ; 41,18% CaO B. 41,18% Fe ; 31,37% Cu ; 27,45% CaO C. 35,56% Fe ; 31,11% Cu ; 33,33% Ca D. 31,11% Fe ; 35,56% Cu ; 33,33% Ca Cu 38. Z l este to bi ru metylic v axit cacboxylic Y n chc, mch h, c mch cacbon phn nhnh. X phng ho hon ton 0,6 mol Z trong 300 ml dung dch KOH 2,5M un nng, c dung dch E. C cn dung dch E c cht rn khan F. t chy hon ton F bng oxi d, thu c 45,36 lt kh CO2 (ktc), 28,35 gam H2O v m gam K2CO3. Cng thc cu to ca Y v gi tr ca m l: A. CH3CH(CH3)COOH ; m = 51,75g B. CH2=C(CH3)COOH ; m = 51,75g. C. CH3CH(CH3)COOH ; m = 41,40g D. CH2=C(CH3)COOH ; m = 41,40g. Cu 39. Cho cht v c X tc dng vi mt lng va KOH, un nng, thu c kh X1 v dung dch X2. Kh X1 tc dng vi mt lng va CuO nung nng, thu c kh X3, H2O, Cu. C cn dung dch X2 c cht rn khan X4 (khng cha clo). Nung X4 thy sinh ra kh X5 ( M=32vC). Nhit phn X thu c kh X6 (M= 44vC) v nc. Cc cht X1, X3, X4, X5, X6 ln lt l: A. NH3 ; NO ; KNO3 ; O2 ; CO2 B. NH3 ; N2 ; KNO3 ; O2 ; N2O C. NH3 ; N2 ; KNO3 ; O2 ; CO2 D. NH3 ; NO ; K2CO3 ; CO2 ; O2. Cu 40. iu khng nh no sau y khng ng:
t A. Phn ng NH4NO3 + KOH KNO3 + NH3 + H2O dng iu ch NH3 trong PTN t B. Phn ng 2NH3 + 3CuO 3Cu + N2 + 3H2O dng minh ho tnh kh ca NH3 t C. Phn ng 2KNO3 2KNO2+ O2 dng iu ch O2 trong PTN t D. Phn ng NH4NO3 2H2O + N2O dng iu ch N2O trong cng nghip. Cu 41. Cht X (C8H14O4) tho mn s cc phn ng sau: b) X1 + H2SO4 X3 + Na2SO4 a) C8H14O4 + 2NaOH X1 + X2 + H2O. c) nX3 + nX4 Nilon-6,6 + nH2O d) 2X2 + X3 X5 + 2H2O Cng thc cu to ca X (C8H14O4 ) l A. HCOO(CH2)6 OOCH B. CH3OOC(CH2)4COOCH3 C. CH3OOC(CH2)5COOH D. CH3CH2OOC(CH2)4COOH Cu 42. t chy hon ton 0,1 mol ru no, mch h X cn va 5,6 lt oxi (ktc). X cng vi axit HOOCC6H4COOH l 2 monome c dng iu ch polime, lm nguyn liu sn xut t: A. Nilon-6,6 B. Capron C. Lapsan D. Enang. Cu 43. Nung 6,58 gam Cu(NO3)2 trong bnh kn, sau mt thi gian thu c 4,96 gam cht rn v hn hp kh X. Hp th hon ton hn hp X vo nc, c 300 ml dung dch Y. Dung dch Y c pH l: A. pH = 1 B. pH = 2 C. pH = 3 D. pH = 4 Cu 43. Cho 3,84 gam hn hp oxit st vo bnh kn cha 2,912 lt kh CO ( ktc) nung nng n phn ng hon ton c Fe v kh A c t khi so vi H2 bng 18. Mt khc, ho tan hon ton 3,84 gam hn hp trn bng H2SO4 c nng, d th thu c V ml kh SO2 ( ktc). V c gi tr l: A. 112 ml. B. 224 ml. C. 336 ml. D. 448 ml. Cu 44. Phn ng Cu + 2FeCl3 CuCl2 + 2FeCl2 cho thy: A. ng kim loi c tnh kh mnh hn st kim loi. B. ng c th kh Fe3+ thnh Fe2+. C. ng kim loi c tnh oxi ho km st kim loi. D. St kim loi b ng y ra khi dung dch mui. Cu 45. Hp cht X to bi 3 nguyn t. Nhit phn X thu c hn hp 2 cht kh v hi c t khi so vi nhau bng 0,642. Cng thc phn t no sau y c coi l hp l i vi X: B. NH4NO2. C. NH4NO3 D. Cu(NO3)2 . A. NH4Cl Cu 46. Bn hirocacbon u l cht kh iu kin thng. Khi phn hu hon ton mi cht trn thnh cacbon v hiro, th tch kh thu c u gp i th tch hirocacbon ban u. Vy bn cht trn: A. u l ankan. B. u l anken. C. u l ankin. D. u c 4H trong phn t. Cu 47. Hn hp X gm K v Zn c khi lng 14,3 gam, tan ht trong mt lng nc d to ra dung dch Y ch cha mt cht tan duy nht v kh H2 (ktc). Khi lng K v th tch H2 to ra l: A. 3,9g v 2,24lt B. 7,8g v 2,24lt C. 7,8g v 4,48lt D. 7,8g v 1,12lt.
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 48. Ho tan hon ton 9,94 gam hn hp Al, Fe, Cu trong dung dch HNO3 long d, thy thot ra 3,584 lt kh NO ( ktc ; l sn phm kh duy nht). Tng khi lng mui to thnh l: A. 39,7g. B. 37,3g C. 29,7g D.27,3g Cu 49. t chy hon ton mt hirocacbon X thu c nH 2O < nCO2 . iu khng nh no sau y ng ? A. X ch c th l ankin hoc ankaien B. X ch c th l ankin hoc xicloankan C. X c th l ankin, xicloanken, ankaien D. X ch c th l ankin hoc xicloanken Cu 50. Ho tan 10,8 gam Al trong mt lng axit H2SO4 va thu c dung dch X. Thm V lt dung dch NaOH 0,5M vo dung dch X c kt ta m sau khi nung n khi lng khng i cho ra mt cht rn c khi lng 10,2 gam. Gi tr ca V l: A. 1,2 lt B. 1,2 hoc 1,6 lt C. 1,2 hoc 2,8 lt D. 1,2 hoc 2,4 lt P N 1 2 3 B A A 21 22 23 A B C 41 42 43 D C A 4 C 24 B 44 B 5 D 25 C 45 B 6 C 26 D 46 D 7 D 27 B 47 C 8 B 28 A 48 A 9 B 29 B 49 C 10 A 30 D 50 C 11 A 31 B 18 12 B 32 D 19 13 D 33 B 20 14 D 34 C 38 15 A 35 B 39 16 D 36 A 40 17 C 37 A
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Cu 1: Nhn nh no sau y v HNO3 l khng ng? A. Axit nitric l cht lng d tan trong nc v d bay hi. B. Axit nitric th hin tnh axit mnh khi tc dng vi baz, oxit baz, kim loi C. Axit nitric c tnh oxihoa mnh, l tnh cht ca NO3- trong dung dch axit. D. Axit nitric c thng c mu vng l do HNO3 km bn, phn hu to thnh NO2. Cu 2: Cu no sau y sai ? A. Lin kt trong a s tinh th hp kim vn l lin kt kim lai B. Kim lai c tnh cht vt l chung: tnh do, tnh dn in, dn nhit, c nh kim C. iu ch Mg, Al ngi ta dng kh H2 hoc CO kh oxit kim loi tng ng nhit cao D. Cc thit b my mc bng st tip xc vi hi nc nhit cao c kh nng b n Mn ha hc. Cu 3: Cho hn hp X gm oxi v clo tc dng ht vi hn hp Y gm 4,80 g magie v 8,10 g nhm to thnh 37,05 g hn hp cc oxit v mui clorua ca hai kim loi. Phn trm th tch ca oxi trong X l: (Bit: O=16; Cl=35,5; Mg=24; Al=27) A. 44,44%. B. 55,56%. C. 56,55%. D. 43,45%. Cu 4: Gi s H c 3 ng v, S c 1 ng v, O c 3 ng v. S phn t H2SO3 c th c l: A. 72 B. 90 C. 60 D. 36 Cu 5: Cho CO2 li t t vo dung dch cha KOH v Ca(OH)2, c th xy ra cc phn ng sau: 1. CO2 + 2KOH K2CO3 + H2O 2. CO2 + Ca(OH)2 CaCO3 + H2O 3. CO2 + K2CO3 + H2O 2KHCO3 4. CO2 + CaCO3 + H2O Ca(HCO3)2 Th t cc phn ng xy ra l: A. 1, 2, 3, 4 . B. 1, 2, 4, 3. C. 1, 4, 2, 3 D. 2, 1, 3, 4. Cu 6: Cu hnh electron ng ca nguyn t nguyn t Cu (Z = 29) l: A. 1s22s22p63s23p63d94s2. B. 1s22s22p63s23p63d104s1 2 2 6 2 6 6 2 3 C. 1s 2s 2p 3s 3p 3d 4s 4p D. 1s22s22p63s23p64s33d8. Cu 7: Supephtphat kp c thnh phn chnh l: A. Ca3(PO4)2. B. CaHPO4 . C. Ca(H2PO4)2. D. Ca(H2PO4)2; CaSO4 Cu 8: Sau khi cn bng phng trnh phn ng: FexOy + HNO3 Fe(NO3)3 + NO + H2O, theo t l h s nguyn, n gin nht, th tng h s ca HNO3 v NO l: A. 15x - 4y. B. 12x- 3y. C. 9x-3y. D. 18x- 5y. Cu 9: Trong cng nghip HCl c th iu ch bng phng php sulfat theo phng trnh phn ng: 2NaCl (tinh th) +
t H2SO4 (c) 2HCl + Na2SO4 Ti sao phng php ny khng c dng iu ch HBr v HI ? A. Do tnh axit ca H2SO4 yu hn HBr v HI. B. Do NaBr v NaI t tin, kh kim
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C. Do HBr v HI sinh ra l cht c. D. Do Br-, I- c phn ng vi H2SO4 c, nng. Cu 10: Ho tan hon ton 12 gam hn hp X gm Fe v Cu bng dung dch HNO3 d, kt thc th nghim thu c 6,72 lt (ktc) hn hp kh Y gm NO v NO2 c khi lng 12,2 gam. Khi lng mui nitrat sinh ra l: (Bit: Fe=56; Cu=64; H=1; O=16; N=14) A. 30,6 gam. B. 39,9 gam. C. 43,0 gam. D. 55,4 gam. Cu 11: Ngm mt thanh kim loi M c khi lng 50 gam trong dung dch HCl. Sau phn ng thu c 336 ml H2 (ktc) v thy khi lng l kim loi gim 1,68% so vi ban u. Kim loi M l: (Bit: H=1; Fe=56; Mg=24; Al=27; Zn=65; Cl=35,5). A. Mg. B. Al. C. Zn. D. Fe Cu 12: Khi in phn dung dch mui trong nc tr s pH khu vc gn mt in cc tng ln, th dung dch mui em in phn l: A. K2SO4. B. KCl C. CuSO4 D. AgNO3. Cu 13: Hp cht no sau y trong phn t ch c lin kt cng ha tr ? A. H2SO4 . B. KNO3 . C. NH4Cl . D. CaO. Cu 14: ng vi cng thc phn t C5H8, s cht ng phn mch h ti a c th c l: A. 10. B. 11. C. 9. D. 8. Cu 15: Hn hp X gm H2 v mt an ken i xng. T khi hi ca X so vi H2 bng 9,1. un nng X c xc tc Ni thu c hn hp Y khng lm mt mu dd brm, t khi hi ca Y so vi H2 l 13. Cng thc cu to ca X l: (Bit: H=1; C=12) B. CH2=CH-CH2-CH3. A. CH2=CH2. C. CH3-C(CH3)=C(CH3)-CH3. D. CH3 -CH=CH-CH3. Cu 16: Cc loi t c ngun gc xenluloz l: A. Si bng, t tm, t nilon 6,6. B. T tm, len, t visco. C. Si bng, t visco, t capron. D. T axetat, si bng, t visco. A. 5. B. Cu 17: Khi un nng hn hp gm cc ng phn aminoaxit ca C3H7O2N, s tripeptit c th to thnh l: 8. C. 7. D. 6. Cu 18: Cc gluxit va to c kt ta vi dd Ag2O/NH3, va ho tan c Cu(OH)2, va cng hp vi H2 xc tc Ni v un nng l: A. Saccaroz v fructz . B. Saccaroz v mantoz . C. Amilz v glucoz. D. Glucoz v fructoz . Cu 19: un nng hn hp xenluloz vi HNO3 c v H2SO4 c, thu c hn hp sn phm gm hai cht hu c c s mol bng nhau, c % khi lng ca N trong bng 9,15%. Cng thc ca hai cht trong sn phm l: (Bit: H=1; N=14; O=16; C=12) A. [C6H7(OH)3]n , [C6H7(OH)2NO3]n B. [C6H7(OH)2NO3]n, [C6H7OH(NO3)2]n. C. [C6H7OH(NO3)2]n, [C6H7(NO3)3]n. D. [C6H7(OH)2NO3]n, [C6H7(NO3)3]n. Cu 20: Cho cc cht sau: C2H5O-H (1), CH3CO(O-H) (2), HCO(O-H) (3), C6H5O-H (4), R-C=CH-H (5), R-CC-H (6) Chiu tng dn linh ng ca cc nguyn t H trong cc nhm chc ca cc cht trn l: A. 1 < 4 < 3 < 2 < 5 < 6. B. 5 < 6 < 1 < 4 < 2 < 3. C. 4 < 1 < 3 < 2 < 6 < 5. D. 6 < 5 < 4 < 1< 2 < 3. Cu 21: t chy hon ton mt lng cht hu c X thu c sn phm ch gm 3,15g nc; 6,60g ccbnc v 0,56 lit nit. Lng oxi cn dng t chy X bng 4,2 lit (kh o ktc). Khi tc dng vi dd NaOH thu c sn phm c mui H2N-CH2-COONa. Cng thc ca X l: (Bit: C=12; H=1; O=16; Na=23; N=14) A. H2N- CH2-COOH. B. CH3-CH(NH2)-COOH. C. H2N -CH2-COO-C2H5. D. H2N-CH2-COO-CH3. Cu 22: Tin hnh trng hp butadien-1,3 c th th c bao nhiu loi polime ? A. 1. B. 2. C. 3. D. 4. Cu 23: Trong cc phn t polime: polivinylclorua, xenluloz, tinh bt (amilopectin), cao su lu ha, nha phenolfomandehit, polistiren, nhng phn t polime c cu to mch nhnh v mng l A. Xenluloz, amilopectin, polistiren B. Amilopectin, cao su lu ha, nha phenolfomandehit. C. Polistiren, polivinyl clorua, xenluloz. D. Xenluloz, polivinyl clorua, nha phenolfomandehit. Cu 24: Trong s cc ru cng thc phn t C6H14O, s ru c th loi nc ni phn t to ra sn phm ti a ch cha hai an ken ng phn l: A. 2. B. 3. C. 4. D. 5.
20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 25: Phenol khng tc dng vi cht no sau y? A. Na. B. HCl. C. NaOH. D. dung dch Br2. Cu 26: Tm kt lun khng ng cu sau y: Do trong phn t axit focmic va c chc axit, va c chc andehit nn axit focmic tham gia phn ng vi: A. H2 xt Ni, t0. B. K2ZnO2. C. Ag2O/NH3. D. Zn. Cu 27: Cho hn hp hai ru no, n chc mch h k tip nhau trong dy ng ng tc dng vi Na d thu c 14,65g hn hp mui khan v 2 lit H2 270C, 1,23 atm. Hai ru c tn l: (Bit:H=1; C=12; O=16; Na=23) A. ru amylc v butylc. B. ru prpylic v butylc. C. ru etylc v prpylc. D. ru metylc v etylc. Cu 28: Hn hp X gm metanal v etanal. Khi oxi ha (H = 100%) m gam hn hp X thu c hn hp Y gm hai axit hu c tng ng c d Y/X = x. Gi tr ca x trong khong no sau y ? (Bit: O=16; H=1; C=12 ) A. 1 < x < 1,36. B. 1,36 < x < 1,53. C. 1,53 < x < 1,62. D. 1,62 < x < 1,75. Cu 29: un nng 0,1 mol X vi lng va dung dch NaOH thu c 13,4 gam mui ca axit hu c a chc Y v 9,2 gam ru n chc Z. Cho ru Z bay hi th thu c th tch l 4,48 lt (qui v ktc). Cng thc ca X l: (Bit: O=16; H=1; C=12; Na=23) A. CH(COOCH3)3 .B. CH3CH2OOC COOCH2CH3 C. C2H5OOC CH2 COOC2H5 . D. C2H5OOC CH2 CH2 COOC2H5. Cu 30: phn bit du thc vt v du bi trn my ngi ta c th dng thuc th l: A. Cu(OH)2. B. Kim loi Na v Cu(OH)2. C. DD CuSO4 v DD NaOH. D. DD NaOH v CuO. Cu 31: un nng axit axetic vi ru iso-amylic (CH3)2CHCH2CH2OH c H2SO4 c xc tc thu c iso-amyl axetat (du chui). Bit hiu sut phn ng t 68%. Lng du chui thu c t 132,35 gam axit axetic un nng vi 200 gam ru iso-amylic l: (Bit: O=16; H=1; C=12 ) A. 295,5 gam. B. 286,7 gam. C. 200,9 gam. D. 195,0 gam. Cu 32: Amoniac phn ng vi tt c cc cht trong dy sau: A. H2SO4, PbO, FeO, NaOH . B. HCl, KOH, FeCl3, Cl2 C. NaHSO4, O2, Cl2, ZnCl2 . D. KNO3, CuCl2, H2S, Al(OH)3 Cu 33: nhn bit c 4 kim loi: Ag, Na, Mg v Al. ch cn dng ha cht no sau y? A. H2O. B. dd NaOH long. C. dd HCl long Cu 34: Cho t t kim loi M vo dd (NH4)2SO4 n d, thy c hn hp kh bay ra v thu c dd trong sut . Kim loi M l: A. Ba B. Fe. C. Na. D. Mg. Cu 35: Trong cc cp cht cho di y, cp cht no c th cng tn ti trong mt dung dch? A. AlCl3 v CuSO4 . B. NaHSO4 v NaHCO3 .C. Na2ZnO2 v HCl. D. NH3 v AgNO3. Cu 36: T cc cht ban u l KMnO4, CuS, Zn, dd HCl c th iu ch trc tip c bao nhiu cht trng thi kh iu kin thng? A. 3. B. 4. C. 5. D. 6. Cu 37: Cho 6,72 lt kh CO2 ktc hp th han tan vo V ml dd Ba(OH)2 0,9M, thu c m gam kt ta v dd cha 19,425 g mt mui ccbonat. Gi tr V l: (Bit: O=16; H=1; Ba=137; C=12) A. 255ml. B. 250ml. C. 252ml. D. 522ml. Cu 38: C cc dd cha cc cht HCOOH, C2H3COOH, HCOOCH3, C2H3COOCH3 ring bit. Dng cp cht no sau y nhn bit c chng? A. CaCO3, qu tm . B. dd Br2, dd Ag2O/NH3. C. dd Ag2O/NH3, Zn. D. dd NaOH, dd Br2. Cu 39: thc hin bin ha: toluen X Y p-crezol , ta phi dng thm nhng ha cht thuc nhm no sau y (k c cht lm xc tc)? A. HNO3 c, H2SO4 c, NaOH. B. Fe, CO2, dd KOH c, Br2. C. Cl2, HCl, NH3, dd NaOH. D. Fe, HCl, NaOH, HNO3 c. Cu 40: X l hp cht hu c thun chc c t khi hi so vi oxi bng 4,125. Trong X, oxi chim 48,48% v khi lng. Bit X khng tc dng vi Na, nhng tc dng vi dd NaOH sinh ra ch mt ru v hn hp hai mui. Cng thc ca X l: (Bit: O=16; H=1; C=12 ) A. HCOO-CH2-CH2-COO-CH3. B. HCOO-CH2-CH2-OOC-CH3. C. HCOO-CH2-CH2-OOC-C2H5. D. CH3-COO-CH2-CH(OOCH)-CH2-OOC-CH3. Cu 41: Trong phn ng thu phn este xc tc axit, tng hiu sut ca phn ng thu phn th dng xc tc l: A. dd NH3. B. dd H2S. C. dd H2SO4 long. D. dd H2SO4 c.
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 42: Hn hp M gm axit X, ru Y v este Z c to ra t X v Y, tt c u n chc; trong s mol X gp hai ln s mol Y. Bit 17,35 g M tc dng va vi dd cha 0,2 mol NaOH, ng thi thu c 16,4 g mui khan v 8,05 g ru . Cng thc X, Y, Z l: (Bit: O=16; H=1; C=12;Na=23) A. HCOOH, CH3OH, HCOOCH3. B. CH3COOH, CH3OH, CH3COOCH3. C. CH3COOH, C2H5OH, CH3COOC2H5. D. HCOOH, C3H7OH, HCOOC3H7. Cu 43: C 4 dung dch: lng trng trng, glixerin, glucoz, h tinh bt c th dng thuc th duy nht no sau y phn bit c cc dung dch ? A. AgNO3/NH3. B. HNO3/H2SO4 C. Cu(OH)2/OH .D. I2/CCl4. Cu 44: S ph hy kim loi theo c ch n mn in ha xy ra nhanh hn n mn ha hc l do A. n mn in ha khng phi l phn ng oxihoa - kh cn n mn ha hc l phn ng oxihoa-kh . B. n mn in ha tiu thu nng lng in cn n mn ha hc khng pht sinh dng in . C. cc qu trnh oxihoa - kh ca n mn in ha xy ra hai in cc cn ca n mn ha hc xy ra cng mt thi im D. n mn in ha xy ra trong dung dch in li cn n mn ha hc ch xy ra vi cc cht kh hoc hi nc nhit cao Cu 45: Gii thch ng v y nht v nguyn nhn ti sao cc kim loi kim c nhit nng chy, cng thp nht so vi tng chu k l A. Kim lai kim c m in nh nht tng chu k, c kiu mng tinh th lng tr lc gic u. B. Chng c bn knh ion ln nht, in tch ion nh nht, d b ion ha nht so tng chu k; c mng tinh th lp phng tm din . C. Chng c bn knh ion ln nht, in tch ion v s electron ha tr t do nh nht so tng chu k; c cu to tinh th rng nht. D. Chng c bn knh ion nh nht, in tch ion v s electron ha tr t do nh nht so tng chu k; c mng tinh th lp phng tm khi. Cu 46: Khi tch nc n phn t ru no n chc k tip nhau, thu c hn hp gm x phn t ete khc nhau. Bit tng khi lng mol phn t ca x ete l 612 g; khi lng mol ca tng ru nh hn 102. Cng thc ca cc ru l: (Bit: O=16; H=1; C=12) A. CH3OH; C2H5OH. B. C2H5OH; C3H7OH, C4H9OH. C. C3H7OH; C4H9OH. D. C4H9OH; C5H11OH; C6H13OH. Cu 47: tch loi cc cht kh: propin, etylen, metan ra khi hn hp ca chng, c th dng nhng ha cht thuc nhm no sau y: (cc phng tin khc coi nh c ) A. dd Br2, dd KOH/ ru v dd KMnO4. B. dd Br2, Zn v dd Ag2O/NH3. C. dd HNO3 c v dd KOH. D. dd HCl, dd KOH/Ru v dd Ag2O/NH3. Cu 48: Cht hu c X c 1 nhm amino, 1 chc este. Hm lng nit trong X l 15,73%. X phng ha m gam cht X, hi ru bay ra cho i qua CuO nung nng c andhit Y. Cho Y thc hin phn ng trng bc thy c 16,2 gam Ag kt ta. Gi tr ca m l: (Bit: O=16; H=1; C=12; Ag=108; N=14) A. 7,725 gam. B. 3,3375 gam. C. 6,675 gam. D. 5,625 gam. Cu 49: ng vi cng thc phn t C4H8O2, c a hp cht hu c n chc mch h v b hp cht c th tc dng c vi Ag2O/NH3 to thnh Ag. Gi tr ca a v b ln lt l: A. 5; 1. B. 6; 2. C. 4; 1. D. 7; 2. Cu 50: Cho 21,30 g P2O5 vo V lit dung dch NaOH 1M, thu c dung dch trong cha 38,20 g hn hp mui pht pht. Gi tr V l: (H=1, Na=23, O=16, P=31) A. 0,40 lit . B. 1,00 lit . C. 0,60 lit . D. 0,44 lit . 1. B 2. C 3. A 4. C 5. D 6. B 7. C 8. A 9. D 10. C 11. D 12. B 13. A 14. A 15. D 16. D 17. B 18. 19. 20. 21. D 22. C 23. B 24. A 25. B 26. A 27. C 28. B 29. B 30. C 31. D 32. C 33. C 34. C 35. A 36. A 37. B 38. 39. 40. 41. D 42. C 43. C 44. C 45. C 46. B 47. D 48. B 49. B 50. A
S : 09
1: Cho cc nguyn t M (Z = 11), X (Z = 17), Y (Z = 9) v R (Z = 19). m in ca cc nguyn t tng dn theo th t A. M < X < Y < R. B. M < X < R < Y. C. Y < M < X < R. D. R < M < X < Y.
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20 B THI TH I HC
2: Trong t nhin, nguyn t ng c hai ng v l
63 29
Mn: ho hc
63 29
Nm hc 2010-2011
Cu v
65 29
Cu. Nguyn t khi trung bnh ca ng l 63,54. Thnh
phn phn trm tng s nguyn t ca ng v Cu l A. 73%. B. 50%. C. 54%. D. 27%. 3: Lu hunh trong SO2 lun th hin tnh kh trong cc phn ng vi : A. H2S, O2, nc Br2. B. dung dch NaOH, O2, dung dch KMnO4.
C. O2, nc Br2, dung dch KMnO4.
D. dung dch KOH, CaO, nc
4: nhn ra cc kh CO2, SO2, H2S, N2 cn dng cc dung dch: A. Nc brom v NaOH. B. NaOH v Ca(OH)2. C. Nc brom v Ca(OH)2 . D. KMnO4 v NaOH. 5: Trong s cc dung dch: Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa, nhng dung dch c pH > 7 l: B. Na2CO3, NH4Cl, KCl. A. KCl, C6H5ONa, CH3COONa. C. NH4Cl, CH3COONa, NaHSO4. D. Na2CO3, C6H5ONa, CH3COONa. 6: Khi cho 100ml dung dch KOH 1M vo 100ml dung dch HCl thu c dung dch c cha 6,525 gam cht tan. Nng mol (hoc mol/l) ca HCl trong dung dch dng l (Cho H = 1; O = 16; Cl = 35,5; K = 39) A. 0,75M. B. 0,5M. C. 0,25M. D. 1M. 7: C th dng NaOH ( th rn) lm kh cc cht kh A. NH3, SO2, CO, Cl2. B. N2, NO2, CO2, CH4, H2. B. C. NH3, O2, N2, CH4, H2. D. N2, Cl2, O2 , CO2, H2. 8: Ha tan hon ton 3,22 gam hn hp X gm Fe, Mg v Zn bng mt lng va dung dch H2SO4 long, thu c 1,344 lt hiro ( ktc) v dung dch cha m gam mui. Gi tr ca m l (Cho H = 1; O = 16; Mg = 24; S = 32; Fe = 56; Zn = 65) A. 9,52. B. 7,25. C. 8,98. D. 10,27. 9: C phn ng: X + HNO3 Fe(NO?3)3 + NO + H?2O S cht X c th thc hin phn ng trn l: A. 3. B. 4. C. 5. D. 6 10: Nung hn hp A gm CaCO3 v CaSO3 ti phn ng hon ton c cht rn B c khi lng bng 50,4% khi lng ca hn hp A. Phn trm khi lng hai cht trn trong hn hp ln lt l: A. 40% v 60%. B. 30% v 70%. C. 25% v 75%. D. 20% v 80%. 11: C 2 cht A v B ch cha chc axit cacboxylic: +) Ly 1 mol A trn vi 2 mol B ri cho tc dng vi Na d, thu c 2 mol H2 +) Ly 2 mol A trn vi 1 mol B ri cho tc dng vi Na d, thu c a mol H2 Gi tr a l: A. 1mol. B. 1,5mol. C. 2,5mol. D. 3mol. 12: Hidro ha cht A (C4H6O) c ru n-butilic.S cng thc cu to mch h c th c ca A l: A. 3. B. 4. C. 5. D. 6. 13: Trong dy bin ha: C2H6 C2H5Cl C2H5OH CH3CHO CH3COOH CH3COOC2H5 C2H5OH S phn ng oxi ha kh l: A. 2. B. 3. C. 4. D. 5. 14: Hn hp X gm N2 v H2 c M = 7,2 vC . Sau khi tin hnh phn ng tng hp NH3, c hn hp Y c M = 8 vC . Hiu sut phn ng tng hp l: A. 10% B. 15% C. 20%. D. 25%. 15: Khi ha tan hiroxit kim loi M(OH)2 bng mt lng va dung dch H2SO4 20% thu c dung dch mui trung ho c nng 27,21%. Kim loi M l (Cho H = 1; O = 16; Mg = 24; S = 32; Fe = 56; Cu = 64; Zn = 65) A. Mg. B. Zn. C. Cu. D. Fe. 16: Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%) tc dng vi clo theo t l s mol 1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng phn ca nhau. Tn ca X l (Cho H = 1; C = 12; Cl = 35,5) A. butan. B. 2-metylpropan. C. 3-metylpentan. D. 2,3-imetylbutan 17: t chy hon ton mt ru (ancol) X thu c CO2 v H2O c t l s mol tng ng l 3 : 4. Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO2 thu c ( cng iu kin). Cng thc phn t ca X l A. C3H8O2. B. C3H8O3. C. C3H8O. D. C3H4O. 18: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (Cho: H = 1; C = 12; O = 16; th tch dung dch thay i khng ng k)
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
A. C2H5OH v C4H9OH. B. C2H5OH v C3H7OH. D. C4H9OH v C5H11OH. C. C3H7OH v C4H9OH. 19: C bao nhiu ru (ancol) bc 2, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18%? (Cho H = 1; C = 12; O = 16) A. 3. B. 5. C. 2. D. 4. 20: Cho 2,9 gam mt anehit phn ng hon ton vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 21,6 gam Ag. Cng thc cu to thu gn ca anehit l (Cho H = 1; C = 12; O = 16; Ag = 108) A. HCHO. B. CH3CHO. C. CH2=CH-CHO. D. OHC-CHO. 21: Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam mui ca axit hu c. Cng thc cu to thu gn ca X l (Cho H = 1; C = 12; O = 16; Ca = 40) A. HCC-COOH. B. CH3COOH. C. CH2=CH-COOH. D. CH3-CH2-COOH. 22: Dn V lt ( ktc) hn hp X gm axetilen v hiro i qua ng s ng bt niken nung nng, n phn ng xong thu c kh Y. Dn Y vo lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 12 gam kt ta. Kh i ra khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z thu c 2,24 lt kh CO2 ( ktc) v 4,5 gam nc. Gi tr ca V bng (Cho H = 1; C = 12; O = 16; Br = 80; Ag = 108) A. 13,44. B. 5,60. C. 11,2. D. 8,96. 23: Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x phng ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X? (Cho H = 1; C = 12; O =16) A. 2. B. 4. C. 3. D. 5. 24: un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l (Cho H = 1; C = 12; O = 16) A. 50%. B. 62,5%. C. 75%. D. 55%. 25: Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3 thu c cht hu c T. Cho cht T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l A. HCOOCH=CH2. B. CH3COOCH=CH-CH3. C. CH3COOCH=CH2. D. HCOOCH3. 26: trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l (Cho H = 1; C = 12; N = 14) A. CH5N. B. C2H7N. C. C3H7N. D. C3H5N. 27: C th dng cht no sau y phn bit 3 cht lng khng mu l benzen, toluen, stiren ? A. Dung dch Brom. B. Dung dch NaOH. C. Dung dch KMnO4. D. Dung dch H2SO4 28: Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l (Cho H = 1; C = 12; N = 14; O =16; Na = 23) A. H2NCH2COO-CH3. B. H2NCOO-CH2CH3. C. CH2=CHCOONH4. D. H2NC2H4COOH. 29: Cho 50ml dung dch glucoz cha r nng tc dng vi mt lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 2,16 gam bc kt ta. Nng mol (hoc mol/l) ca dung dch glucoz dng l (Cho H = 1; C = 12; O = 16; Ag = 108) A. 0,10M. B. 0,20M. C. 0,01M. D. 0,02M. 30: Polivinyl axetat (hoc poli(vinyl axetat)) l polime c iu ch bng phn ng trng hp A. CH2=CH-COO-CH3. B. CH2=CH-COO-C2H5. C. C2H5COO-CH=CH2. D. CH3COO-CH=CH2. 31: Mt dung dch cha 0,02 mol Cu2+, 0,03 mol K+, x mol Cl v y mol SO42. Tng khi lng cc mui tan c trong dung dch l 5,435 gam. Gi tr ca x v y ln lt l (Cho O = 16; S = 32; Cl = 35,5; K = 39; Cu = 64) A. 0,05 v 0,01. B. 0,01 v 0,03. C. 0,03 v 0,02. D. 0,02 v 0,05. 32: Nhit phn hon ton hn hp gm x mol AgNO3 v y mol Cu(NO3)2 c hn hp kh c M = 42,5 vC.T s x/y l: A. 1. B. 2. C. 3. D. 4. 33: Cc kh c th cng tn ti trong mt hn hp l A. H2S v Cl2. B. HI v O3. C. NH3 v HCl. D. Cl2 v O2. 34: Ho tan hon ton hn hp X gm Fe v Mg bng mt lng va dung dch HCl 20%, thu c dung dch Y. Nng ca FeCl2 trong dung dch Y l 15,76%. Nng phn trm ca MgCl2 trong dung dch Y l (Cho H = 1; Mg = 24; Cl = 35,5; Fe = 56) A. 11,79%. B. 24,24%. C. 28,21%. D. 15,76%. 35: Cho s phn ng: KCl (X) (Y) O2. X v Y c th l: A. Cl2 v KClO3. B. KClO3 v KClO. C. HCl v KClO. D. KOH v K2CO3.
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
36: Cho hn hp Fe + Cu tc dng vi dung dch HNO3, phn ng xong, thu c dung dch A ch cha mt cht tan. Cht tan l: A. Fe(NO3)3. B. Cu(NO3)2. C. Fe(NO3)2 . D. HNO3. 37: S hp cht n chc, ng phn cu to ca nhau c cng cng thc phn t C4H8O2, u tc dng c vi dung dch NaOH l A. 4. B. 6. C. 3. D. 5. 38: Cho s chuyn ho: Glucoz X Y CH3COOH. Hai cht X, Y ln lt l A. CH3CHO v CH3CH2OH. B. CH3CH2OH v CH3CHO. C. CH3CH(OH)COOH v CH3CHO. D. CH3CH2OH v CH2=CH2. 39: Cho cc cht sau: phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc dng c vi nhau l A. 4. B. 1. C. 3. D. 2. 40: Ch dng Cu(OH)2 c th phn bit c tt c cc dung dch ring bit sau: A. saccaroz, glixerin (glixerol), anehit axetic, ru (ancol) etylic. B. glucoz, mantoz, glixerin (glixerol), anehit axetic. C. glucoz, lng trng trng, glixerin (glixerol), ru (ancol) etylic. D. lng trng trng, glucoz, fructoz, glixerin (glixerol).
41: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s
mol X tham gia phn ng v X ch tc dng c vi NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l D. CH3OC6H4OH. A. CH3C6H3(OH)2. B. HOC6H4CH2OH. C. C6H5CH(OH)2. 42: Cho glixerin tc dng vi hn hp 3 axit C17H35COOH, C17H33COOH v C15H31COOH. S este ba chc ti a c th to thnh l: A. 9. B. 12. C. 15. D. 18. 43: t chy hn hplu hunh v cacbon (th tch khng ng k) trong bnh kn ng oxi d, sau a bnh v nhit ban u th p sut trong bnh so vi trc khi t s: A. tng ln mt t. B. gim xung mt t. C. khng thay i so ban u. D. c th tng hoc gim, ty lng C, S. 44: Trong s cc cht kh NH3; H2S; CO2; SO2; NO2 , s kh m trong nguyn t c ha tr cao hn va c tnh oxi ha, va c tnh kh l: A. 1. B. 2. C. 3. D. 4. 45: thu c CO2 tinh khit t phn ng ca CaCO3 vi dung dch HCl ngi ta cho sn phm kh i qua ln lt cc bnh no sau y? A. NaOH v H2SO4 c. B. H2SO4 c v NaHCO3. C. NaHCO3 v H2SO4 c. D. H2SO4 c v NaOH . 46: Cho hn hp X gm Mg v Fe vo dung dch axit H2SO4 c, nng n khi cc phn ng xy ra hon ton, thu c dung dch Y v mt phn Fe khng tan. Cht tan c trong dung dch Y l A. MgSO4. B. MgSO4 v Fe2(SO4)3. C. MgSO4 v FeSO4. D. MgSO4, Fe2(SO4)3 v FeSO4. 47: Cho cc cht c cng thc cu to nh sau: HOCH2-CH2OH (X); HOCH2-CH2-CH2OH (Y); HOCH2-CHOH-CH2OH (Z); CH3-CH2-O-CH2-CH3 (R); CH3-CHOH-CH2OH (T). Nhng cht tc dng c vi Cu(OH)2 to thnh dung dch mu xanh lam l A. X, Y, Z, T. B. X, Y, R, T. C. Z, R, T. D. X, Z, T. 48: Khi thc hin phn ng tch nc i vi ru (ancol) X, ch thu c mt anken duy nht. Oxi ho hon ton mt lng cht X thu c 5,6 lt CO2 ( ktc) v 5,4 gam nc. C bao nhiu cng thc cu to ph hp vi X? (Cho H = 1; C = 12; O = 16) A. 2. B. 4. C. 3. D. 5. 49: Trong s cc loi t sau: t tm, t visco, t nilon-6,6, t axetat, t capron, t enang, nhng loi t no thuc loi t nhn to? A. T visco v t axetat. B. T nilon-6,6 v t capron. C. T tm v t enang. D. T visco v t nilon-6,6. 50: Polime dng ch to thu tinh hu c (plexiglas) c iu ch bng phn ng trng hp B. CH2=C(CH3)COOCH3. C. C6H5CH=CH2. D. CH3COOCH=CH2. A. CH2 =CHCOOCH3.
P N
Cch hc tt mn Ho l phi lm Sytan1992@gmail.com Bai tap nhiu , bn cnh ( hehe... ) Trang36/77-LTH-2010
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1. D 2. A 3. C 4. C 5. D 6. B 7. C 8. C 9. C 10. A 11. C 12. D 13. B 14. D 15. C 16. D 17. C 18. 19. 20.
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21. C 22. C 23. B 24. B 25. C 26. A 27. A 28. A 29. B 30. D 31.C 32. A 33. D 34. A 35. A 36. C 37. B 38. 39. 40.
Nm hc 2010-2011
41. B 42. D 43. C 44. B 45. C 46. C 47. D 48. B 49. A 50. B
S : 10 Cho bit khi lng nguyn t (theo vC) ca cc nguyn t : H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Fe = 56; Cu = 64; Zn = 65; As = 75 ; Br = 80; Rb = 85,5; Ag = 108; Ba = 137. 1. Mt nguyn t X c tng s ht proton, ntron v electron l 155 ht trong s ht mang in nhiu hn s ht khng mang in l 33. Nguyn t c s proton, ntron tng ng l A. 47 v 61. B. 35 v 45. C. 26 v 30. D. 20 v 20. 2. Nguyn t X c phn lp ngoi cng trong cu hnh eletron l 4s1. in tch ht nhn ca nguyn t X l A. 19. B. 24. C. 29. D. A, B, C u ng. 3. Ha tan hn hp X gm Al v Fe vo dung dch HNO3 d sau phn ng hon ton thu c dung dch A v 4,44 gam hn hp kh Y c th tch 2,688 lt ( ktc) gm hai kh khng mu, trong c mt kh t ha nu ngoi khng kh. S mol hn hp X l A. 0,32 mol. B. 0,22 mol. C. 0,45 mol. D. 0,12 mol. 4. Trong cc oxit FeO, Fe2O3, Fe3O4 nhng cht c kh nng tc dng vi H2SO4 c nng c kh SO2 bay ra l A. ch c FeO v Fe3O4. B. ch c Fe3O4. C. ch c FeO. D. ch c FeO v Fe2O3. 5. Th tch dung dch KOH 0,001M cn ly pha vo nc c 1,5 lt dung dch c pH = 9 l A. 30 ml. B. 25 ml. C. 20 ml. D. 15 ml. Tng khi lng cc mui khan 6. Dung dch A cha cc ion SO42; 0,2 mol Ca2+; 0,1 mol NH4+ v 0,2 mol NO3. c trong dung dch A l A. 36,2 gam. B. 36,6 gam. C. 36,3 gam. D. 36,4 gam. 7. Dung dch nc clo c tnh ty mu, st trng l do A. clo tc dng vi nc to ra HClO c tnh oxi ha mnh. B. clo c tnh oxi ha mnh. C. clo tc dng vi nc to ra HCl c tnh axit mnh. D. lin kt gia 2 nguyn t clo trong phn t l lin kt yu. 8. Khi oxi ha 11,2 lt NH3 ( ktc) iu ch HNO3 vi hiu sut ca c qu trnh l 80% th thu c khi lng dung dch HNO3 6,3% l A. 300 gam. B. 500 gam. C. 250 gam. D. 400 gam. 9. Mt thanh Zn ang tc dng vi dung dch HCl, nu cho thm vi git dung dch CuSO4 vo th A. lng bt kh H2 bay ra vi tc khng i. B. lng bt kh H2 bay ra chm hn. C. bt kh H2 ngng bay ra. D. lng bt kh H2 bay ra nhanh hn. 10. Tnh oxi ha ca cc ion kim loi: Fe3+, Fe2+, Mg2+, Zn2+, Cu2+, Ag+ bin i theo quy lut no sau y? A. Fe3+ > Fe2+ > Mg2+ > Zn2+ > Cu2+ > Ag+. B. Ag+ > Fe3+ > Cu2+ > Fe2+ > Zn2+ > Mg2+. C. Mg2+ > Zn2+ > Cu2+ > Ag+ > Fe3+ > Fe2+. D. Fe3+ > Ag+ > Cu2+ > Fe2+ > Zn2 > Mg2+. 11. Cho a gam Na ha tan ht vo 86,8 gam dung dch c cha 13,35 gam AlCl3, sau phn ng hon ton thu c m gam dung dch X v 3,36 lt kh H2 ( 0oC, 2atm). Hy chn cu tr li ng trong cc cu sau: A. m = 100,6 gam v dung dch X c 3 cht tan. B. m = 100,6 gam v dung dch X c 2 cht tan. C. m = 100 gam v dung dch X c 3 cht tan. D. m = 100 gam v dung dch X c 2 cht tan.
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12. Nc t nhin thng c ln lng nh cc mui Ca(NO3)2, Mg(NO3)2, Ca(HCO3)2, Mg(HCO3)2. C th dng mt ha cht no sau y loi ht cc cation trong mu nc trn? A. NaOH. B. K2SO4. C. NaHCO3. D. Na2CO3. 13. S phng trnh ha hc ti thiu cn dng iu ch K kim loi t dung dch K2CO3 l A. 1. B. 2. C. 3. D. 4. 14. Nung 8,4 gam Fe trong khng kh sau phn ng thu c m gam cht rn X gm Fe, Fe2O3, Fe3O4, FeO. Ha tan ht m gam X vo dung dch HNO3 d thu c 2,24 lt kh NO2 ( ktc) l sn phm kh duy nht. Gi tr ca m l A. 11,2 gam. B. 10,2 gam. C. 7,2 gam. D. 6,9 gam. 15. Nguyn liu ch yu c dng sn xut Al trong cng nghip l A. qung olomit B. qung mahetit. C. t st. D. qung boxit. 16. Cho 200 ml dung dch AlCl3 0,5M tc dng vi 500 ml dung dch NaOH 1M c dung dch X. Trong dung dch X cha cc cht tan A. NaAlO2, NaCl, NaOH. B. NaAlO2, AlCl3. C. NaAlO2, NaCl. D. AlCl3, AlCl3. 17. Ha tan ht 5,6 gam Fe bng mt lng va dung dch HNO3 c nng thu c V lt NO2 l sn phm kh duy nht (ti ktc). V nhn gi tr nh nht l A. 1,12 lt. B. 2,24 lt. C. 4,48 lt. D. 6,72 lt. 18. Fe(NO3)2 l sn phm ca phn ng A. FeO + dd HNO3. B. dd FeSO4 + dd Ba(NO3)2. D. A hoc B u ng. C. Ag + dd Fe(NO3)3. 19. Dung dch A cha 0,01 mol Fe(NO3)3 v 0,13 mol HCl c kh nng ha tan ti a bao nhiu gam Cu kim loi? (bit NO l sn phm kh duy nht) A. 2,88 gam. B. 3,92 gam. C. 3,2 gam. D. 5,12 gam. 20. Khi cho C6H14 tc dng vi clo (chiu sng) to ra ti a 5 sn phm ng phn cha mt nguyn t clo. Tn gi ca C6H14 l A. 2,3-imetylbutan. B. 2-metylpentan. C. n-hexan. D. 3-metylpentan. 21. C bao nhiu ng phn ankin c cng thc phn t C5H8? A. 2. B. 3. C. 4. D. 5. o 22. Cho 3,548 lt hi hn hp X ( 0 C, 1,25 atm) gm 2 anken l ng ng lin tip vo dung dch nc brom d thy khi lng bnh ng dung dch brom tng 10,5 gam. Cng thc phn t ca 2 anken l A. C3H6 v C4H8. B. C2H4 v C3H6. C. C4H8 v C5H10. D. C5H10 v C6H12. 23. Isopren c th to ra bao nhiu gc hirocacbon ha tr mt? A. 2. B. 3. C. 4. D. 5. 24. Cho hirocacbon X c cng thc phn t C7H8. Cho 4,6 gam X tc dng vi lng d AgNO3 trong dung dch NH3 thu c 15,3 gam kt ta. X c ti a bao nhiu cng thc cu to? A. 3. B. 4. C. 5. D. 6. 25. linh ng ca nguyn t hiro trong nhm OH ca cc cht: H2O, C2H5OH, C6H5OH bin i theo quy lut no sau y? A. H2O > C2H5OH > C6H5OH. B. C2H5OH > H2O > C6H5OH. C. C6H5OH > H2O > C2H5OH. D. C2H5OH > C6H5OH > H2O. 26. Cho 15,2 gam hn hp gm glixerin v ancol n chc X vo Na d thu c 4,48 lt H2 (ktc). Lng H2 do X sinh ra bng 1/3 lng H2 do glixerin sinh ra. X c cng thc l A. C3H7OH. B. C2H5OH. C. C3H5OH. D. C4H9OH. 27. t chy hon ton m gam hn hp X gm 2 ru k tip nhau trong dy ng ng thu c 6,72 lt CO2 ( ktc) v 7,65 gam H2O. Mt khc nu cho m gam X tc dng ht vi Na th thu c 2,8 lt H2 ( ktc). Cng thc ca 2 ru l A. C2H5OH v C3H7OH. B. C3H5(OH)3 v C4H7(OH)3. C. C2H4(OH)2 v C3H6(OH)2. D. C3H6(OH)2 v C4H8(OH)2. 28. Ru X c cng thc phn t l C5H12O. un X vi H2SO4 c 170oC khng thu c anken. Tn gi ca X l
20 B THI TH I HC
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A. pentanol. B. pentanol-2. C. 2,2-imetylpropanol-1. D. 2-metylbutanol-2. 29. Hp cht hu c X tc dng vi AgNO3 trong NH3 d thu c sn phm Y. Cho Y tc dng vi dung dch H2SO4 long hoc dung dch NaOH u thu c kh v c. X l cht no trong cc cht sau y? A. HCHO. B. HCOOH. C. HCOONH4. D. A, B, C u ng. 30. Cho 2,32 gam mt anehit tham gia phn ng trng gng hon ton vi dung dch AgNO3 (trong NH3) d thu c 17,28 gam Ag. Vy th tch kh H2 ( ktct) ti a cn dng phn ng ht vi 2,9 gam X l A. 1,12 lt. B. 3,36 lt. C. 2,24 lt. D. 6,72 lt. 31. T kh thin nhin, cc cht v c v iu kin cn thit iu ch nha phenolfomanehit cn dng ti thiu bao nhiu phng trnh phn ng? A. 4. B. 5. C. 6. D. 7. 32. Cng thc phn t C9H8O2 c bao nhiu ng phn axit l dn xut ca benzen, lm mt mu dung dch nc brom (k c ng phn hnh hc)? A. 5. B. 6. C. 7. D. 8. 33. t chy hon ton m gam mt axit no, mch h, hai ln axit X thu c 6,72 lt CO2 ( ktc) v 4,5 gam H2O. Cng thc ca X l A. C2H4(COOH)2. B. C4H8(COOH)2. C. C3H6(COOH)2. D. C5H10(COOH)2. 34. Mt este X mch h to bi ancol no n chc v axit khng no (c mt ni i C=C) n chc. t chy a mol X thu c 6,72 lt kh CO2 ( ktc) v 4,05 gam nc. Gi tr ca a l A. 0,025 mol. B. 0,05 mol. C. 0,06 mol. D. 0,075 mol. 35. Thy phn este C4H6O2 trong mi trng axit thu c mt hn hp gm cc sn phm u c kh nng phn ng trng gng. Cng thc cu to ca este l A. HCOOCH=CHCH3. B. HCOOCH2CH=CH2. C. CH3COOCH=CH2. D. c A, B, C u ng. 36. Du thc vt l A. hn hp cc hirocacbon trng thi rn. B. hn hp cc hirocacbon trng thi lng. C. este 3 ln este ca ru glixerin vi axit bo ch yu l axit bo khng no. D. este 3 ln este ca ru glixerin vi axit bo ch yu l axit bo no. 37. X phng ha 10 gam este X cng thc phn t l C5H8O2 bng 75 ml dung dch NaOH 2M. C cn dung dch sau phn ng c 11,4 gam cht rn khan. Tn gi ca X l A. etylacrylat. B. vinylpropyonat. C. metylmetacrylat. D. alylaxetat. 38. S ng phn mch h c cng thc phn t C2H4O2 l A. 1. B. 2. C. 3. D. 4. 39. Cho 100 ml dung dch aminoaxit X nng 0,3M phn ng va vi 48 ml dung dch NaOH 1,25M, sau c cn th thu c 5,31 gam mui khan. X c cng thc no sau y? B. H2NC2H4COOH. A. H2NCH(COOH)2. D. H2NC2H3(COOH)2. C. (H2N)2CHCOOH. 40. Cho cc hp cht: 1. C6H5NH2; 2. C2H5NH2; 3. (C6H5)2NH; 4. (C2H5)2NH; 5. NH3. Tnh baz ca chng bin i theo quy lut no sau y? A. 1 > 3 > 5 > 4 > 2. B. 2 > 1 > 5 > 3 > 4. C. 4 > 2 > 5 > 1 > 3. D. 5 > 2 > 4 > 1 > 3. 41. Cho cc cht lng: axit axetic, axit acrylic, etylaxetat, vinylpropionat, alylfomiat ng trong cc l khc nhau. Dng cc ha cht no sau y nhn bit c tt c cc cht trn? A. dd AgNO3/NH3; dd Br2. B. dd AgNO3/NH3; qu tm, dd Br2. C. dd AgNO3/NH3; qu tm; Cu(OH)2. D. qu tm; Cu(OH)2. 42. Ln men 22,5 gam glucoz lm ru etylic, hiu qu qu trnh ln men l 80%. Khi lng ru thu c l A. 4,6 gam. B. 9,2 gam. C. 2,3 gam. D. 6,9 gam. 43. Da nhn to (PVC) c iu ch t kh thin nhin theo s :
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CH4 C2H2 CH2=CHCl [CH2CHCl]n. Nu hiu sut ca ton b qu trnh iu ch l 20%, mun iu ch c 1 tn PVC th th tch kh thin nhin (cha 80% metan) iu kin tiu chun cn dng l A. 4375 m3. B. 4450 m3. C. 4480 m3. D. 6875 m3. 44. V tu thy lm bng thp, bo v tu khi b n mn khi i trn bin ngi ta gn vo y tu kim loi no sau y? A. Mg. B. Sn. C. Pb. D. Cu. 45. Hp cht hu c X c cng thc phn t l C4H7O2Cl khi thy phn trong mi trng kim c cc sn phm, trong c 2 hp cht c kh nng tham gia phn ng trng gng. Cng thc cu to ng ca X l A. HCOOCH2CHClCH3. B. C2H5COOCH2Cl. C. CH3COOCHClCH3. D. HCOOCHClCH2CH3. 46. Cho 1 mol KOH vo dung dch cha m gam HNO3 v 0,2 mol Al(NO3)3. thu c 7,8 gam kt ta th gi tr ca m l A. 18,9 gam. B. 44,1 gam. C. 19,8 gam. D. A hoc B u ng. 47. Cho 12,8 gam dung dch ru glixerin trong nc c nng 71,875% tc dng ht vi mt lng d Na thu c V lt kh H2 ( ktc). Gi tr ca V l A. 5,6 lt. B. 3,36 lt. C. 4,48 lt. D. 11,2 lt. 48. Dy cc cht no sau y u c kh nng tham gia phn ng trng gng (to kt ta Ag)? A. axetilen, anehit axetic, metylfomiat. B. metanal, etanal, axit axetic. C. metanal, etanal, axit foocmic, metylfomiat. D. axetilen, axit axetic, axit foocmic. 49. kh hon ton 13,2 gam hn hp gm Fe, FeO, Fe2O3, Fe3O4 th cn va 4,48 lt CO ( ktc). Khi lng ca Fe thu c l A. 8,4 gam. B. 10 gam. C. 11,2 gam. D. 11,6 gam. 50. C 5 cht lng ng trong 5 l mt nhn: 1. benzen, 2. axit axetic, 3. axit acrylic, 4. ru etylic, glixerin. Nu ch dng cc ha cht sau y: qu tm, nc brom, Cu(OH)2 iu kin thng th c th nhn bit c nhng cht no? A. Tt c. B. 3, 4, 5. C. 1, 3, 4. D. 2, 3 5. P N 1. A 6. B 11. C 16. A 21. B 26. A 31. C 36. C 41. B 46. D 2. D 7. A 12. D 17. C 22. A 27. C 32. B 37. A 42. B 47. A 3. B 8. D 13. B 18. B 23. C 28. C 33. B 38. C 43. C 48. C 4. A 9. D 14. A 19. C 24. B 29. D 34. D 39. D 44. A 49. B 5. D 10. B 15. D 20. B 25. C 30. C 35. A 40. C 45. D 50. A
S : 11
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t : H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Fe = 56; Cu = 64; Zn = 65; As = 75 ; Br = 80; Rb = 85,5; Ag = 108; Ba = 137. S 24 1. Kt lun no biu th ng v kch thc ca nguyn t v ion? A. Na < Na+, F > F. B. Na < Na+, F < F. + C. Na > Na , F > F . D. Na > Na+, F < F. 2. Cho 0,54 gam Al vo 40 ml dung dch NaOH 1M, sau phn ng hon ton thu c dung dch X. Cho t t dung dch HCl 0,5M vo dung dch X thu c kt ta. thu c lng kt ta ln nht cn th tch dung dch HCl 0,5M l A. 110 ml. B. 90 ml. C. 70 ml. D. 80 ml. 3. Mi cht v ion trong dy no sau va c tnh kh, va c tnh oxi ho? A. SO2, S, Fe3+. B. Fe2+, Fe, Ca, KMnO4. 2+ C. SO2, Fe , S, Cl2. D. SO2, S, Fe2+, F2. 4. Kim loi nhm b oxi ho trong dung dch kim (dung dch NaOH). Trong qu trnh cht oxi ho l A. Al. B. H2O. C. NaOH. D. H2O v NaOH.
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5. Mi phn t v ion trong dy no sau va c tnh axit, va c tnh baz?
A. HSO4, ZnO, Al2O3, HCO3, H2O, CaO. B. NH4+, HCO3, CH3COO. C. ZnO, Al2O3, HCO3, H2O. D. HCO3, Al2O3, Al3+, BaO. 6. Dung dch Y cha Ca2+ 0,1 mol, Mg2+ 0,3 mol, Cl 0,4 mol, HCO3 y mol. Khi c cn dung dch Y ta thu c mui khan c khi lng l A. 37,4 gam. B. 49,8 gam. C. 25,4 gam. D. 30,5 gam. 7. Mi cht trong dy no sau ch phn ng vi dung dch axit sunfuric c, nng m khng phn ng vi dung dch axit sunfuric long? B. Cu, S. A. Al, Fe, FeS2, CuO. C. Al, Fe, FeS2, Cu. D. S, BaCl2. 8. Cho s phn ng:
H2O HCl NaOH t 3 X dd X Y Kh X Z T + H2O, HNO
o
trong X l A. NH3. B. CO2. C. SO2. D. NO2. 9. Cho 8 gam canxi tan hon ton trong 200 ml dung dch hn hp HCl 2M v H2SO4 0,75M thu c kh H2 v dung dch X. C cn dung dch X thu c lng mui khan l A. 22,2 gam. B. 25,95 gam. C. 22,2 gam m 25,95 gam. D. 22,2gam m 27,2gam. 10. Cho 1,04 gam hn hp 2 kim loi tan hon ton trong H2SO4 long d thy c 0,672 lt kh thot ra iu kin tiu chun. Khi lng hn hp mui sunfat khan thu c l A. 3,92 gam. B. 1,68 gam. C. 0,46 gam. D. 2,08 gam. 11. lm sch mui n c ln tp cht CaCl2, MgCl2, BaCl2 cn dng 2 ho cht l A. dd Na2CO3, dd HCl. B. dd NaOH, dd H2SO4. D. dd AgNO3, dd NaOH. C. dd Na2SO4, dd HCl. 12. phn bit 3 dung dch NaOH, HCl, H2SO4 ch cn dng mt thuc th l A. Na2CO3. B. Al. C. BaCO3. D. qu tm. 13. Mt dung dch hn hp cha a mol NaAlO2 v a mol NaOH tc dng vi mt dung dch cha b mol HCl. iu kin thu c kt ta sau phn ng l A. a = b. B. a = 2b. C. b = 5a. D. a < b < 5a. 14. Cho 11,1 gam hn hp hai mui sunft trung ho ca 2 kim loi kim hai chu k lin tip tan hon ton trong dung dch HCl d thu c 2,24 lt kh SO2 (ktc). Hai kim loi l A. Li, Na. B. Na, K. C. K, Cs. D. Na, Cs. 15. Khi phn ng vi Fe2+ trong mi trng axit, l do no sau y khin MnO4 mt mu? A. MnO4 to phc vi Fe2+. B. MnO4 b kh cho ti Mn2+ khng mu. C. MnO4- b oxi ho. D. MnO4 khng mu trong dung dch axit. 16. Cho mt gam bt st tip xc vi oxi mt thi gian thu c 1,24 gam hn hp Fe2O3 v Fe d. Lng Fe d l A. 0,036 gam. B. 0,44 gam. C. 0,87 gam. D. 1,62 gam. 17. kh hon ton 6,4 gam mt oxt kim loi cn 0,12 mol kh H2. Mt khc ly lng kim loi to thnh cho tan hon ton trong dung dch H2SO4 long th thu c 0,08 mol H2. Cng thc oxit kim loi l A. CuO. B. Al2O3. C. Fe3O4. D. Fe2O3. 18. t chy hon ton 8,8 gam FeS v 12 gam FeS2 thu c kh. Cho kh ny sc vo V ml dung dch NaOH 25% (d=1,28 g/ml) c mui trung ha. Gi tr ti thiu ca V l A. 50 ml. B. 75 ml. C. 100 ml. D. 120 ml. 19. Dung dch X cha NaOH 0,2M v Ca(OH)2 0,1M. Sc 7,84 lt kh CO2 (ktc) vo 1 lt dung dch X th khi lng kt ta thu c l A. 15 gam. B. 5 gam. C. 10 gam. D. 0 gam. 20. Cho cc phn ng: C6H5NH3Cl + (CH3)2NH (CH3)2NH2Cl + C6H5NH2 (I) (CH3)2NH2Cl + NH3 NH4Cl + (CH3)2NH (II) Trong phn ng t xy ra l A. (I). B. (II). C. (I), (II). D. khng c. 21. Cho a mol Cu kim loi tan hon ton trong 120 ml dung dch X gm HNO3 1M v H2SO4 0,5M (long) thu c V lt kh NO duy nht (ktc). Tnh V? A. 14,933a lt. B. 12,32a lt. C. 18,02a lt. D. kt qu khc. 22. Ho tan ht m gam hn hp gm FeO, Fe2O3 v Fe3O4 bng HNO3 c, nng thu c 4,48 lt kh NO2 (ktc). C cn dung dch sau phn ng c 145,2 gam mui khan. Gi tr ca m l
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
A. 35,7 gam. B. 46,4 gam. C. 15,8 gam. D. 77,7 gam. 23. S ng phn c cng thc phn t C4H10O l A. 5. B. 6. C. 7. D. 8. 24. Hai anken c cng thc phn t C3H6 v C4H8 khi phn ng vi HBr thu c 3 sn phm, vy 2 anken l A. xiclopropan v but-1-en. B. propen v but-1-en. C. propen v but-2-en. D. propen v metyl propen. 25. un nng mt ru X vi H2SO4 c lm xc tc nhit thch hp thu c mt olefin duy nht. Cng thc tng qut ca X l (vi n > 0, nguyn) A. CnH2n+1OH. B. ROH. C. CnH2n+1CH2OH. D. CnH2n+2O. 26. un nng hn hp etanol v propanol-2 vi axit oxalic c xc tc H2SO4 m c c th thu c ti a bao nhiu este hu c a chc? A. 2. B. 3. C. 4. D. 5. 27. Khi t chy mt ru n chc (X) thu c CO2 v hi nc theo t l th tch VCO2 : VH2O = 4 : 5. Cng thc phn t ca X l A. C4H10O2. B. C3H6O. C. C4H10O. D. C5H12O. 28. Cng thc n gin nht ca anehit no, mch h X l C2H3O. X c cng thc phn t l A. C2H3O. B. C4H6O2. C. C8H12O4. D. C12H18O6. 29. Cho s phn ng sau:
+ Cl 2 , 500 C + NaOH + CuO, t Propilen Y X propenal.
o o
Tn gi ca Y l A. propanol. B. propenol. C. axeton. D. axit propionic. 30. Trong phn ng este ho gia ru v axit hu c, yu t khng lm cn bng ca phn ng este ho chuyn dch theo chiu thun l A. cho ru d hay axit d. B. dng cht ht nc tch nc. C. chng ct ngay tch este ra. D. s dng axit mnh lm xc tc. 31. Cho cht Y (C4H6O2) tc dng vi dung dch NaOH thu c 2 sn phm u c kh nng phn ng trng gng. Cng thc cu to ca Y l A. CH3COOCH=CH2. B. HCOOCH2CH=CH2. C. HCOOCH=CHCH3. D. HCOOC(CH3)=CH2. 32. t chy hp cht hu c X thu c CO2 v H2O. Khi lng phn t ca X l 74 vC. X tc dng c vi Na, dung dch NaOH, dung dch AgNO3/NH3. Cng thc phn t ca X l A. C4H10O. B. C3H6O2. C. C2H2O3. D. C6H6. 33. Cho s bin ho (gi s cc phn ng u hon ton):
+ NaOH , t + HCl + H 2 , Ni, t Triolein X2. X X1
o o
Tn ca X2 l A. axit oleic. 34. Cho phn ng:
B. axit panmitic.
C. axit stearic.
D. axit linoleic.
CH2CH2Br + NaOH (lo ng) Br

Cng thc cu to ca Y l:
H2O to
Y + NaBr
CH2CH2OH A. B.
CH2CH2Br C.
CH2CH2OH
CH2CH2OH
D.
Br OH OH ONa 35. 1 mol aminoaxit Y tc dng va vi 1 mol HCl. 0,5 mol Y tc dng va vi 1 mol NaOH. Phn t khi ca Y l
147 vC. Cng thc phn t ca Y l A. C5H9NO4. B. C4H7N2O4. C. C5H7NO4. 36. Tnh cht c trng ca saccaroz l 1. tham gia phn ng hiro ho; 2. cht rn kt tinh, khng mu; 3. khi thu phn to ra glucoz v fructoz; 4. tham gia phn ng trng gng; D. C7H10O4N2.
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
5. phn ng vi ng (II) hiroxit. Nhng tnh cht no ng? A. 3, 4, 5. B. 1, 2, 3, 5. C. 1, 2, 3, 4. D. 2, 3, 5. 37. Fructoz khng phn ng vi cht no sau y? A. Dung dch Br2. B. H2 / Ni, to. C. Cu(OH)2 trong dung dch NaOH. D. Dung dch AgNO3 trong NH3. 38. Khi clo ho PVC thu c mt loi t clorin cha 66,6% clo theo khi lng. S mt xch trung bnh ca PVC tc dng vi mt phn t clo l A. 1, 5. B. 3. C. 2. D. 2,5. 39. Chn phn ng sai? A. Phenol + dung dch brom Axit picric + axit bromhiric.
t B. Ru benzylic + ng (II) oxit Anehit benzoic + ng + nc. t C. Propanol-2 + ng (II) oxit Axeton + ng + nc. D. Etilen glycol + ng (II) hiroxit Dung dch mu xanh thm + nc. 40. t chy hon ton 2,6 gam hn hp (X) gm 2 anehit no, mch h c cng s nguyn t ccbon trong phn t thu c 0,12 mol CO2 v 0,1 mol H2O. Cng thc phn t ca 2 anehit l A. C4H8O, C4H6O2. B. C3H6O, C3H4O2. C. C5H10O, C5H8O2. D. C4H6O2, C4H4O3. 41. nhn bit 3 l mt nhn: phenol, stiren, ru benzylic, ngi ta dng mt thuc th duy nht l A. natri. B. nc brom. C. dd NaOH. D. Ca(OH)2. 42. t chy hon ton m gam hn hp X gm hai anehit no, n chc, mch h c 0,4 mol CO2. Mt khc hiro ho hon ton cng lng hn hp X trn cn 0,2 mol H2 thu c hn hp hai ru. t chy hon ton lng hn hp hai ru trn th s mol H2O thu c l A. 0,4 mol. B. 0,6 mol. C. 0,8 mol. D. 0,3 mol. 43. t chy hon ton hn hp gm 1 ankan v 1 anken. Cho sn phm chy ln lt i qua bnh 1 ng P2O5 d v bnh 2 ng KOH rn, d, sau th nghim thy khi lng bnh 1 tng 4,14 gam bnh 2 tng 6,16 gam. S mol ankan c trong hn hp l A. 0,06 mol. B. 0,09 mol. C. 0,03 mol. D. 0,045 mol. 44. t chy hon ton m gam hn hp 2 ru ng ng lin tip thu c 0,66 gam CO2 v 0,45 gam H2O. Nu tin hnh oxi ha m gam hn hp ru trn bng CuO, sn phm to thnh cho tc dng vi AgNO3 / NH3 d s thu c lng kt ta Ag l A. 10,8 gam. B. 3,24 gam. C. 2,16 gam. D. 1,62 gam.
o o
Kt lun no sau y khng ng?

A. Cc thit b my mc bng kim loi tip xc vi hi nc nhit cao c kh nng b n mn ho hc. B. p tm km vo mn tu thu lm bng thp (phn ngm di nc) th v tu thu c bo v. C. vt bng thp ra ngoi khng kh m th vt b n mn in ho. D. hp lm bng st ty (st trng thic) b xy xt, trong khng kh m b n mn in ho th thic s b n mn trc. 45. lm sch CO2 b ln tp kh HCl v hi nc th cho hn hp ln lt i qua cc bnh ng (lng d) A. dd NaOH v dd H2SO4. B. dd Na2CO3 v P2O5. C. dd H2SO4 v dd KOH. D. dd NaHCO3 v P2O5. 46. kh hon ton 3,04 gam hn hp Y (gm FeO, Fe3O4, Fe2O3) th cn 0,05 mol H2. Mt khc ho tan hon ton 3,04 gam hn hp Y trong dung dch H2SO4 c th thu c th tch kh SO2 (sn phm kh duy nht) iu kin tiu chun l A. 224 ml. B. 448 ml. C. 336 ml. D. 112 ml. 47. t chy hon ton 5,8 gam mt axit cacboxylic mch thng thu c 0,2 mol CO2 v 0,1mol H2O. Cng thc phn t ca axit l A. C2H4O2. B. C3H4O4. C. C4H4O4. D. C6H6O6. 48. Mi ankan c cng thc trong dy sau s tn ti mt ng phn tc dng vi clo theo t l 1 : 1 to ra monocloroankan duy nht? A. C2H6; C3H8; C4H10; C6H14. B. C2H6; C5H12; C8H18. C. C3H8; C6H14; C4H10. D. C2H6; C5H12; C6H14. 49. Cho s chuyn ho sau: Br2 + NaOH CuO Cu(OH )2 + 2 NaOH C2H4 X1 X2 X3 X4
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20 B THI TH I HC
X3, X4 ln lt l A. OHCCH2OH, NaOOCCH2OH. B. OHCCHO, CuC2O4. C. OHCCHO, NaOOCCOONa. C. HOCH2CH2OH, OHCCHO.
Mn: ho hc
HOOCCOOH
+ H 2SO4
Nm hc 2010-2011
50: Cho m gam Fe vo 100 ml dung dch Cu(NO3)2 th nng ca Cu2+ cn li trong dung dch bng 1/2 nng ca Cu2+ ban u v thu c mt cht rn A c khi lng bng m+0,16 gam. Bit cc phn ng xy ra hon ton. Khi lng Fe v nng (mol/l) ban u ca Cu(NO3)2 : A. 1,12 gam v 0,3M B. 2,24 gam v 0,2 M C.1,12gam v 0,4M D. 2,24 gam v 0,3 M.
P N : 1. D 2. D 3. C 4. B 5. C 6. A 7. B 8. A 9. B 10. A 11. A 12. C 13. D 14. A 15. B 16. B 17. D 18. B 19. B 20. A 21. A 22. B 23. C 24. C 25. C 26. B 27. C 28. B 29. B 30. D 31. C 32. C 33. C 34. A 35. A 36. D 37. A 38. C 39. A 40. B 41. B 42. B 43. B 44. B 45. D 46. D 47. A 48. C 49. B 50. C
S : 12
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t : H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Fe = 56; Cu = 64; Zn = 65; As = 75 ; Br = 80; Rb = 85,5; Ag = 108; Ba = 137. Cu 1: Ancol C5H12O c s ng phn bc 2 l: A. 5 B. 3 C. 4 D.2 Cu 2: Cracking hon ton 2,8 lt C5H12 thu hh B . t chy hn hp B thu tng lng CO2, H2O l: A. 27g B.41g C. 82g D. 62g Cu 3: Cho 2,24 lt CO2 ktc vo 20 lt dung dch Ca(OH)2, thu c 6 gam kt ta. Nng ca dung dch Ca(OH)2 dng l: A. 0,003M. B. 0,0035M. C.0,004M D.0,003M hoc 0,004M. Cu 4: Khuy u mt lng bt Fe, Fe3O4 vo dung dch HNO3 long. Chm dt phn ng, thu c dung dch X v kh NO v cn li mt t kim loi. Vy dung dch X cha cht tan: A. Fe(NO3)3, Fe(NO3)2 B. Fe(NO3)3, HNO3 C.Fe(NO3)2duy nht D. Fe(NO3)3, Fe(NO3)2, HNO3 Cu 5: C mt hp cht hu c n chc Y, khi t chy Y ta ch thu c CO2 v H2O vi s mol nh nhau v s mol oxi tiu tn gp 4 ln s mol ca Y. Bit rng: Y lm mt mu dung dch brom v khi Y cng hp hiro th c ru n chc. Cng thc cu to mch h ca Y l: B. CH2=CH-CH2-CH2-OH A. CH3-CH2-OH C. CH3-CH=CH-CH2-OH D..CH2=CH-CH2-OH Cu 6: Mt cht hu c X cha C, H, O ch cha mt loi chc cho 2,9g X phn ng vi dung dch AgNO3/NH3 d thu c 21,6g Ag. Vy X c th l: A. HCHO B.OHC-CHO C. CH2(CHO)2 D. CH3 CHO Cu 7: Cho 3g hn hp gm 3 kim loi ng trc H2 trong dy hot ng ha hc phn ng ht vi H2SO4 d, thu c 1,008 lt H2 (kc). C cn dung dch thu c mg rn. Vy m c th bng: A.7,32g B. 5,016g C. 2,98g D. Kt qu khc Cu 8: So snh tnh axit ca cc cht sau y: CH2Cl-CH2COOH (1), HCOOH (3), A. (3) > (2) > (1 ) > (4) CH3COOH (2), CH3-CHCl-COOH (4) B. (4) > (2) > (1 ) > (3)
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20 B THI TH I HC
C.(4)>(1)>(3)>(2) D. Kt qu khc
Mn: ho hc
Nm hc 2010-2011
Cu 9: Hai cht hu c X v Y u n chc l ng phn ca nhau. t chy hon ton 5,8 gam hn hp X v Y cn 8,96 lt oxi (ktc) thu c kh CO2 v hi nc theo t l VCO2 : Vhi H2O = 1 : 1 (o cng iu kin). Cng thc n D. C5H10O gin ca X v Y l: A. C2H4O B.C3H6O C. C4H8O Cu 10: Ha tan hon ton 2,81 (g) hn hp mt oxit Kim loi kim v mt oxit kim loi kim th vo V ml ddH2SO4 0,1M ri c cn dd sau p thu c 6,81g hh mui khan. Gi tr V: A.500ml B. 625 ml C. 725 ml D. 425 ml Cu 11: t ancol A. Dn ht sm phm chy vo bnh ng ddCa(OH)2 d; thy c 3 gam kt ta v khi lng bnh tng 2,04 gam. Vy A l: A. CH3OH B. C2H5 OH B.C3H7H D. C4H9OH Cu 12: Ha tan ht 1,62g bc bng axit nng 21% ( d=1,2 g/ml) ; thu oc NO.Th tch dung dch axitnitric ti thiu cn phn ng l: A. 4ml B.5ml C. 7,5ml D. Gi tr khc Cu 13: Mt oxit kim loi: M x Oy trong M chim 72,41% v khi lng. Kh hon ton oxit ny bng CO, thu c 16,8 gam M. Ha tan hon ton lng M ny bng HNO3 c nng thu c 1 mui v x mol NO2. Gi tr x l: A. 0,45 B. 0,6 C. 0,75 D.O,9 Cu 14: Hn hp X gm 2 axit no: A1 v A2. t chy hon ton 0,3mol X thu c 11,2 lt kh CO2 (ktc). Trung ha 0,3 mol X cn 500ml dung dch NaOH 1M. Cng thc cu to ca 2 axit l: A. CH3COOH v C2H5COOH B.HCOOH v HOOC-COOH C. HCOOH v C2H5COOH D. CH3COOH v HOOC-CH2-COOH Cu 15: Khi th 1 ln vi Br2 to 4 sn phm. Vy tn gi l: A. 2 metyl pentan. B.2-metyl butan C. 2,3 imetylbutan. D. 2,3 dimetyl butan Cu 16: t chy hn hp 2 ru ng ng c s mol bng nhau, ta thu c khi CO2 v hi nc c t l s mol: nCO2 : nH2O = 2 : 3. Cng thc phn t 2 ru ln lt l: A.CH4O v C3H8O B. C2H6O v C3H8O C. CH4O v C2H6O D. C2H6O v C4H10O Cu 17: Cho phn ng: C4H6O2 + NaOH B + D; D + Z E + Ag. B c th iu ch trc tip c t CH4 v C2H6. Vy B c th l: A. CH3COONa B. C2H5COONa C.A,B u ng D. A, B u sai Cu 18: t chy hn hp A gm c nhiu hidrcacbon thu c 6,72 lt CO2 (kc) v 3,6g H2O. Vy V lt O2 cn t l: A.8,96lt B. 2,24 lt C. 6,72lt D. 4,48lt Cu 19 Cho th t cc cp oxi ha- kh sau: Fe2+/Fe; Cu2+/Cu; Fe3+/Fe2+; Ag+/Ag. Trong cc dung dch mui v kim loi sau: Fe(NO3)2, Cu(NO3)2, Fe(NO3)3, Fe, Cu, Ag th dung dch AgNO3 c th tc dng vi: A. Fe, Cu, dung dch Fe(NO3)2. B. Fe, Cu. C. Fe, Cu, dung dch CuSO4. D. Fe, dung dch Fe(NO3)2. Cu 20: Cu hnh electron ca ion Cl- l: A. 1s22s22p6 B.1s22s22p63s23p6 2 2 6 2 5 C. 1s 2s 2p 3s 3p D. 1s22s22p63s23p4 Cu 21: Dung dch c pH=7: A. NH4Cl B. CH3COONa C. C6H5ONa D.KClO3 Cu 22: Vi cng thc C3H8Ox c nhiu nht bao nhiu CTCT cha nhm chc phn ng c vi Na. A. 2 B. 3 C. 4 D.5 Cu 23: Chn pht biu sai: A. t chy 1 ankan cho s mol H2O > s mol CO2 B. Phn ng c trng ca ankan l phn ng th. C. Ankan ch c lin kt xch ma trong phn t. D.Clo ho ankan theo t l 1:1 ch tao 1 sn phm ho duy nht
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Cu 24: Cho m gam Fe vo 100 ml dung dch Cu(NO3)2 th nng ca Cu2+ cn li trong dung dch bng 1/2 nng ca Cu2+ ban u v thu c mt cht rn A c khi lng bng m+0,16 gam. Bit cc phn ng xy ra hon ton. Khi lng Fe v nng (mol/l) ban u ca Cu(NO3)2 : A. 1,12 gam v 0,3M B. 2,24 gam v 0,2 M C.1,12gam v 0,4M D. 2,24 gam v 0,3 M. Cu 25: Ho tan 45,9 gam kim loi M bng dung dch HNO3 long thu c hn hp kh gm 0,3 mol N2O v 0,9 mol NO. Kim loi M l: A. Mg
20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 26: Sp xp cc cht sau: H2, H2O, CH4, C2H6 theo th t nhit si tng dn
A.H2 < CH4 <C2H6< H2O B. H2 < CH4 < H2O < C2H6 C. H2 < H2O < CH4 < C2H6 D. CH4 < H2 < C2H6 < H2O
B. Fe
C.Al
D. Zn
Cu 27: Ly 9,1gam hp cht A c CTPT l C3H9O2N tc dng vi dung dch NaOH d, un nng, c 2,24 lt (o ktc) kh B thot ra lm xanh giy qu tm m. t chy ht lng kh B ni trn, thu c 4,4gam CO2. CTCT ca A v B l: A.HCOONH3C2H5; C2H5NH2 B.CH3COONH3CH3;CH3NH2 C. HCOONH3C2H3; C2H3NH2 D. CH2=CHCOONH4; NH3 Cu 28: Cho cc dung dch ca cc hp cht sau: NH2-CH2-COOH (1) ; ClH3N-CH2-COOH (2) ; NH2-CH2-COONa (3) ; NH2-(CH2)2CH(NH2)-COOH (4) ; HOOC-(CH2)2CH(NH2)-COOH (5). Cc dung dch lm qu tm ho l: A. (3) B. (2) C.(2),(5) D. (1), (4). Cu 29: nhn bit dung dch cc cht glixerin, h tinh bt, lng trng trng g, ta c th dng mt thuc th duy nht thuc th l: A. Dung dch H2SO4 B.Cu(OH)2 C. Dung dch I2 D. Dung dch HNO3 Cu 30: Trong s cc polime tng hp sau y: nha PVC (1), caosu isopren (2), nha bakelit (3), thu tinh hu c (4), t nilon 6,6 (5).Cc polime l sn phm trng ngng gm: A. (1) v (5) B. (1) v (2) C. (3) v (4) D.(3) v (5) Cu 31: Cho 360 gam glucoz ln men thnh ru etylic (gi s ch c phn ng to thnh ruetylic). Cho tt c kh CO2 hp th vo dung dch NaOH th thu c 212 gam Na2CO3 v 84 gam NaHCO3. Hiu sut ca phn ng ln men ru l: A. 50% B. 62,5% C.75% D. 80% Cu 32: Cht hu c (A) cha C, H, O. Bit rng (A) tc dng c vi dung dch NaOH, c cn c cht rn (B) v hn hp hi (C), t (C) chng ct c (D), (D) tham gia phn ng trng gng cho sn phm (E), (E) tc dng vi NaOH li thu c (B). Cng thc cu to ca (A) l: B. HCOOCH=CH-CH3 A. HCOOCH2-CH=CH2 C. HCOOC(CH3)=CH2 D.CH3COOCH=CH2 Cu 33: Dung dch X cha axit HCl a mol/l v HNO3 b mol/l. trung ho 20 ml dung dch X cn dng 300 ml dung dch NaOH 0,1 M. Mt khc ly 20 ml dung dch X cho tc dng vi dung dch AgNO3 d thy to thnh 2,87 gam kt ta. ( Ag = 108, Cl = 35,5 ). Gi tr ca a, b ln lt l: A.1,0 v 0,5 B. 1,0 v 1,5 C. 0,5 v 1,7 D. 2,0 v 1,0 Cu 34: Ion CO32- cng tn ti vi cc ion sau trong mt dung dch: A.NH4+ ,Na+ ,K+ B. Cu2+, Mg2+, Al3+ C. Fe2+, Zn2+, Al3+ D. Fe3+, HSO4Cu 35. Dung dch E cha cc ion Mg2+, SO42-, NH4+, Cl-. Chia dung dch E ra 2 phn bng nhau: Cho phn I tc dng vi dung dch NaOH d, un nng, c 0,58 gam kt ta v 0,672 lit kh (ktc). Phn II tc dng vi dung dch BaCl2 d, c 4,66 gam kt ta. Tng khi lng cc cht tan trong dung dch E bng (Mg = 24, Ba = 137, S = 32, O = 16, Na = 23,H = 1, Cl = 35,5) A.6,11g B. 3,055g. C. 5,35g. D. 9,165g. Cu 36: Hp cht hu c C4H7O2Cl khi thu phn trong mi trng kim c cc sn phm trong c hai cht c kh nng tham gia phn ng trng gng. Cng thc cu to ca cht hu c l: A. HCOO-CH2- CHCl-CH3 B. CH3-COO-CH2-CH2Cl C.HCOOCHCl-CH2- CH3 D. HCOOC(CH3)Cl-CH3 Cu 37: Ha tan 2,49 gam hh 3 kim loi ( Mg, Fe, Zn) bng lng va dd H2SO4 1M, thu c1,344 lt H2 (kc) Th tch dung dch H2SO4 cn dng l: A. 1,2 lt B. 0,24 lt C. 0,06lt D. 0,12 lt
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Cu 38: un hn hp X gm 2 cht hu c A, B vi H2SO4 c 140OC; thu c 3,6 gam hn hp B gm 3 te C s mol bng nhau v 1,08 gam nc. Hai cht hu c l: A. CH3OH v C3H7OH B.CH3OH v C2H5OH C. C3H7OH v CH2=CH-CH2OH D. C2H5OH v CH2=CH-CH2OH Cu 39: Cho 31,9 gam hn hp Al2O3, ZnO, FeO, CaO tc dng ht vi CO d nung nng thu c 28,7 gam hn hp Y. Cho Y tc dng vi dung dch HCl d thu c V lt H2 (ktc). Th tch H2 l: A. 6,72 lt B. 11,2 lt C.5,6lt D.4.48 lt Cu 40: X l ru bc II c CTPT C6H14O. un nng X vi H2SO4 c 1700C ch to mt anken duy nht. Tn ca (X) l : A.2,2-imetylbutan-3-ol B. 2,3-imetylbutan-3-ol C. 3,3-imetylbutan-2- ol D. 2,3-imetylbutan-2-ol Cu 41: Cho bt Al vo dung dch hn hp:NaNO3 ; NaNO2; NaOH s c s phn ng nhiu nht bng: A.1 B. 2 C.3 D. Gi tr khc Cu 42: t chy a mol mt este no ; thu c x mol CO2 v y mol H2O. Bit x y = a. Cng thc chung ca este: A. CnH2n-2O2 B. CnH2n-4O6 C.CnH2n-2O4 D. CnH2nO2 D. Butanal
20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 43: Mt anhit n no c %O=36,36 v khi lng. Tn gi ca anhit ny l: A. Propanal B. 2-metyl propanal C.Etanal
Cu 44: Dung dch A: 0,1mol M2+ ; 0,2 mol Al3+; 0,3 molSO42- v cn li l Cl-. Khi c cn ddA thu c 47,7 gam rn. Vy M s l: A. Mg B. Fe C.Cu D. Al D.CH3COOCH3 B. Cu 45: Este X phn ng vi dung dch NaOH, un nng to ra ru metylic v natri axetat. Cng thc cu to ca X l: A. HCOOCH3 B. C2H5COOCH3 C. CH3COOC2H5 Cu 46: (A) l este n chc, mch C h v c mC : mO = 9 : 8 . C tt c bao nhiu CTCT ca (A) c th c: A. 3 4 C.5 D. 6
Cu 47: t ru A. Dn ht sm phm chy vo bnh ng dung dch Ca(OH)2 d; thy c 3 gam kt ta v khi lng bnh tng 2,04 gam. Vy A l: A. CH4O B. C2H6 O C.C3H8O D. C4H10O Cu 48: Trong cng nghip, natri hiroxit c sn xut bng phng php: A. in phn dung dch NaCl, khng c mng ngn in cc. B.in phn dung dich NaCl , c mng ngn in cc C. in phn dung dch NaNO3 , khng c mn ngn in cc. D. in phn NaCl nng chy. Cu 49: Cho hh bt KL: a mol Mg, b mol Al, p vi dd hh cha c mol Cu(NO3)2 , d mol AgNO3 Sau p thu c rn cha 2kim loi. Biu thc lin h a,b,c,d: A. 2a + 3b = 2c + d B. 2a + 3b 2c d C. 2a + 3b 2c d D. 2a + 3b 2c + d Cu 50: 1,68 lt hn hp A: CH4, C2H4 (kc) c KLPTTB bng 20. t chy hon ton hhA; thu x gam CO2. Vy x bng: A.3,3g B.4,4g C . 6,6g D. 5,6 g
P N 1D 11C 21D 31C 41C 2B 12B 22D 32D 42C 3C 13D 23D 33 43C 4C 14B 24C 3 44C 5D 15B 25C 35A 45D 6B 16A 26A 36C 46C 7A 17C 27B 37B 47C 8C 1 28C 38D 48B 9B 19A 29B 39A 49D 10A 20B 30D 40C 50B
S : 13
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t :
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Fe = 56; Cu = 64; Zn = 65; As = 75 ; Br = 80; Rb = 85,5; Ag = 108; Ba = 137. 49. Ion HS c tnh cht A. A. axit. B. trung tnh. C. lng tnh. D. baz. 50. Ion Al(H2O)3+ c tnh cht B. A. axit. B. trung tnh. C. lng tnh. D. baz. 51. Mui axit l C. mui c kh nng phn ng vi baz. D. mui vn cn hiro trong phn t. E. mui to bi baz yu v axit mnh. F. mui vn cn hiro c kh nng thay th bi kim loi. 52. Ha tan hon ton 10 gam hn hp hai mui XCO3 v Y2(CO3)3 bng dung dch HCl ta thu c dung dch A v 0,672 lt kh bay ra ktc. C cn dung dch A th thu c m gam mui khan. Gi tr ca m l G. A. 1,033 gam. B. 10,33 gam. C. 9,265 gam. D. 92,65 gam. 53. Magie c th chy trong kh cacbonioxit to ra mt cht bt X mu en. Cng thc ha hc ca X l H. A. Mg2C. B. MgO. C. Mg(OH)2. D. C (cacbon). 54. Cho 3,78 gam bt Al phn ng va vi dung dch mui XCl3 to thnh dung dch Y. Khi lng cht tan trong dung dch Y gim 1,06 gam so vi dung dch XCl3. Cng thc ca mui XCl3 l I. A. AuCl3. B. CrCl3. C. NiCl3. D. FeCl3. 55. Nung 100 gam hn hp gm Na2CO3 v NaHCO3 cho n khi khi lng hn hp khng i c 69 gam cht rn. Phn trm khi lng ca mi cht trong hn hp ln lt l J. A. 74% v 26%. B. 84% v 16%. C. 26% v 74%. D. 16% v 84%. 56. Trong mt cc nc cng cha a mol Ca2+, b mol Mg2+ v c mol HCO3. Nu ch dng nc vi trong, nng d Ca(OH)2 pM lm gim cng ca cc th ngi ta thy khi thm V lt nc vi trong vo cc, cng trong cc l nh nht. Biu thc tnh V theo a, b, p l K. A.
a + 2b a+b . B. p p .
C.
2a + b p .
D.
a+b 2p .
57. in phn nng chy hon ton 1,9 gam mui clorua ca mt kim loi ha tr (II) thu c 0,48 kim loi catot.
Kim loi cho l L. A. Zn. B. Mg. C. Ca. D. Ba. 58. in phn hon ton mt lt dung dch AgNO3 vi hai in cc tr thu c mt dung dch c pH = 2. Xem th tch dung dch khng thay i th lng bm catot l M. A. 0,216 gam. B. 0,108 gam. C. 0,54 gam. D. 1,08 gam. 59. Ni cc phn ng nhit phn u l phn ng oxi ha - kh l N. A. ng. B. ng nu phn ng c thay i s oxi ha. O. C. sai. D. c th th ng. 60. Trong phn ng oxi ha - kh H2O c th ng vai tr l P. A. cht kh. B. cht oxi ha. C. mi trng. D. c A, B, C. 61. H2O2 l cht c th cho, c th nhn in t v trong oxi c Q. A. mc oxi ha trung gian. B. mc oxi ha 1. R. C. ha tr (II). D. ha tr (I). 62. Trong phng trnh: Cu2S + HNO3 Cu(NO3)2 + H2SO4 + NO + H2O, h s ca HNO3 l S. A. 18. B. 22. C. 12. D. 10. 63. Trn 50 ml dung dch HCl 0,104M so vi 50 ml dung dch Ag2SO4 0,125M s thu c lng kt ta l T. A. 0,7624 gam. B. 0,7426 gam. C. 0,7175. D. 0,7462. 64. Trn 50 ml dung dch BaCl2 2,08% (d = 1,15 g/ml) vi 75 ml dung dch Ag2SO4 0,05M s thu c lng kt ta l U. A. 2,29 gam. B. 2,1577 gam. C. 1,775 gam. D. 1,95 gam. 65. trung ha ht 200 ml dung dch Ba(OH)2 0,15M v KOH 0,25M th th tch dung dch HClO4 10,05% (d = 1,1 g/ml) cn dng l V. A. 100 ml. B. 72 ml. C. 50 ml. D. 25 ml. 66. Cho 4,9 gam hn hp A gm K2SO4, Na2SO4 vo 100 ml dung dch Ba(OH)2 0,5M c 6,99 gam kt ta trng. Phn trm khi lng K2SO4 trong A l W. A. 71,0204%. B. 69,0124%. C. 35,5102%. D. 28,9796%. 67. Ha tan a gam M2(CO3)n bng lng va dung dch H2SO4 10% c dung dch mui 15,09%. Cng thc mui l
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20 B THI TH I HC
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Nm hc 2010-2011
X. A. FeCO3. B. MgCO3. C. CuCO3. D. CaCO3. 68. Sc ht 1,568 lt kh CO2 (ktc) vo 500 ml dung dch NaOH 0,16M. Sau th nghim c dung dch A. Rt 250 ml dung dch B gm BaCl2 0,16M v Ba(OH)2 xM vo dung dch A c 3,94 gam kt ta v dung dch C. Nng xM ca Ba(OH)2 bng Y. A. 0,02M. B. 0,025M. C. 0,03M. D. 0,015M. 69. Khi lng hn hp A gm K2O v BaO (t l s mol 2 : 3) cn dng trung ha ht 1,5 lt dung dch hn hp B gm HCl 0,005M v H2SO4 0,0025M l Z. A. 0,0489 gam. B. 0,9705 gam. C. 0,7783 gam. D. 0,1604 gam. 70. in li ca mt cht in li ph thuc AA. A. nng v nhit . B. bn cht cht in li. BB. C. bn cht dung mi. D. c A, B, C. 71. Cht in li mnh l CC. A. cht in li 100%. B. cht in li hu nh hon ton. DD. C. cht in phn. D. cht khng b thy phn. X, Y l hai axit cacboxylic n chc. Trn 1,2 gam X vi 5,18 gam Y c hn hp Z. trung ha ht Z cn 90 ml dung dch NaOH 1M. Trn 7,8 gam X vi 1,48 gam Y c hn hp Z. trung ha ht Z cn 77 ml dung dch NaOH 2M. 2. Tm cng thc tng ng ca X, Y. A. A. CH3 COOH v C3H5COOH. B. CH3COOH v C2H5COOH. B. C. C2H5COOH v C3H7COOH. D. C2H5COOH v C4H9COOH. 72. pH c trng cho C. tnh axit ca dung dch. D. tnh axit - baz ca cc cht. E. tnh axit, tnh baz ca dung dch. F. nng ion H3O+ ca dung dch. 73. t chy ht m gam mt axit no, n chc, mch h c (m + 2,8) gam CO2 v (m 2,4) gam nc. Axit ny l G. A. HCOOH. B. CH3COOH. C. C2H5 COOH. D. C3H7 COOH. 74. t chy 7,3 gam mt axit no, mch h c 0,3 mol CO2 v 0,25 mol H2O cho cng thc phn t H. A. CH3COOH. B. COOHCOOH. D. C4H8(COOH)2. I. C. C2H5COOH. 75. Ha hi hon ton mt axit hu co A c mt th tch hi bng th tch hiro thu c khi cng cho lng axit nh trn tc dng ht vi natri (o cng iu kin). Mt khc trung ha 9 gam A cn 100 gam dung dch NaOH 8%. A l J. A. CH3COOH. B. HOOCCOOH. K. C. CH2(COOH)2. D. C3H7COOH. 76. t chy 14,4 gam cht hu c A c 28,6 gam CO2; 4,5 gam H2O v 5,3 gam Na2CO3. Bit phn t A cha 2 nguyn t oxi. A c cng thc phn t L. A. C3H5O2Na. B. C4H7O2Na. C. C4H5O2Na.D. C7H5O2Na. 77. Du n l hn hp cc triglixerit. C bao nhiu loi triglixerit trong mt mu du n m thnh phn phn t gm glixerin kt hp vi hai axit C17H35COOH v C17H34COOH? M. A. 6 triglixerit. B. 9 triglixerit. C. 12 triglixerit. D. 18 triglixerit. 78. Hp cht hu c X cha mt loi nhm chc, c cng thc phn t C6H10O4. Khi thy phn X trong NaOH thu c mt mui v hai ru c s cacbon gp i nhau. X c cu to N. A. HOOCCH2CH2CH2CH2COOH. B. CH3OOCCH2COOC2H5. O. C. HOOCCH2CH2CH2COOCH3. D. C2H5COOCH2CH2COOH. 79. Thy phn hon ton 4,4 gam este n chc E bng 22,75 ml dung dch NaOH 10% (d = 1,1 g/ml). Bit lng NaOH ny d 25% so vi l thuyt. E l P. A. este cha no. B. C4H8O2. C. C5H8O2. D. C4H6O2. 80. X l mt aminoaxit no ch cha mt nhm NH2 v mt nhm COOH. Cho 0,89 gam X tc dng vi HCl va to ra 1,255 gam mui. Cng thc cu to ca X l Q. A. H2NCH2COOH. B. CH3CH(NH2)COOH. R. C. CH3CH(NH2)CH2COOH. D. C3H7CH(NH2)COOH. 81. X l mt -aminoaxit no ch cha mt nhm NH2 v mt nhm COOH. Cho 15,1 gam X tc dng vi HCl d thu c 18,75 gam mui. Cng thc cu to ca X l S. A. H2NCH2COOH. B. CH3CH(NH2)CH2COOH. T. C. C3H7CH(NH2)COOH. D. C6H5CH(NH2)COOH. 82. Dng lng trng trng g lm trong mi trng (aga, nc ng), ta ng dng tnh cht no sau y? U. Tnh baz ca protit. V. Tnh axit ca protit.
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20 B THI TH I HC
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Nm hc 2010-2011
W. Tnh lng tnh ca protit. X. Tnh ng t nhit cao v ng t khng thun nghch ca abumin. 83. Tm nh ngha ng v nhm chc? Y. L cc hp cht hu c c nhng tnh cht ha hc nht nh. Z. L cc nhm OH, COOH, CHO. AA. L nhm cc nguyn t gy ra cc phn ng ha hc c trng cho mt hp cht hu c. BB. L nhm cc cht hu c quyt nh tnh cht c trng cho hp cht . 84. Ru etylic c nhit si cao hn hn so vi cc anehit v dn xut halogen c khi lng phn t xp x vi n v CC. trong cc hp cht nu, ch c ru etylic cho phn ng vi natri. DD. trong cc hp cht nu, ch c ru etylic to c lin kt hiro vi nc. EE. trong cc hp cht nu, ch c ru etylic c kh nng loi nc to olefin. FF. trong cc hp cht nu, ch c ru etylic c lin kt hiro lin phn t. 85. t chy hon ton 1 mol ru no, mch h A cn 2,5 mol kh oxi. A l GG. A. CH3OH. B. C2H4(OH)2. C. C2H5OH. D. C3H7OH. 86. Benzen khng phn ng vi Br2 trong dung dch nhng phenol li lm mt mu dung dch brom nhanh chng v HH. phenol c tnh axit. II. tnh axit ca phenol yu hn c axit cacbonic. JJ. do nh hng ca nhm OH, cc v tr ortho v para trong phenol giu in tch m, to iu kin d dng cho tc nhn Br+ tn cng. KK. phenol khng phi l mt dung mi hu c tt hn nh benzen. 87. S d anilin c tnh baz yu hn NH3 l do LL. nhm NH2 cn mt cp electron cha lin kt. MM. phn t khi ca anilin ln hn so vi NH3. NN. nhm NH2 c tc dng y electron v pha vng benzen lm gim mt electron ca N. OO. gc phenyl c nh hng lm gim mt electron ca nguyn t N. 88. Chn cu sai trong s cc cu sau y? PP. Etylamin d tan trong nc do c lin kt hiro. QQ. Tnh cht ha hc ca etylamin l phn ng to mui vi baz mnh. RR. Etylamin tan trong nc to dung dch c kh nng sinh ra kt ta vi dung dch FeCl3. SS. Etylamin c tnh baz do nguyn t nit cn cp electron cha lin kt c kh nng nhn proton. 89. Cng thc ca amin cha 15,05% khi lng nit l TT. A. C2H5NH2. B. (CH3)2NH. C. C6H5NH2. D. (CH3)3N. 90. Cho 20 gam hn hp gm 3 amin no, n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M ri c cn dung dch th thu c 31,68 gam hn hp mui. Th tch dung dch HCl dng l UU. A. 100 ml. B. 50 ml. C. 200 ml. D. 320 ml. 91. Cho 20 gam hn hp gm 3 amin no, n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M ri c cn dung dch th thu c 31,68 gam hn hp mui. Nu trn 3 amin trn theo t l mol (v th t phn t khi tng dn) = 1 : 10 : 5 th cng thc phn t ca 3 amin l VV. A. CH3NH2, C2H5NH2, C3H7NH2. B. C2H7N, C3H9N, C4H11N. WW. C. C3H9N, C4H11N, C5H14N. D. C3H7N, C4H9N, C5H11N. 92. t chy hon ton 6,2 gam mt amin no, n chc phi dng ht 10,08 lt kh oxi (ktc). Cng thc ca amin l XX. A. C2H5NH2. B. CH3NH2. C. C4H9NH2. D. C3H7NH2. 93. iu no sau y lun ng? YY. Cng thc tng qut ca mt anehit no mch h bt k l CnH2n+22kOk (k l s nhm CHO). ZZ. Mt anehit n chc, mch h bt k chy cho s mol H2O nh hn s mol CO2 phi l anehit no. AAA. Bt c anehit n chc no khi tc dng vi lng d dung dch AgNO3/NH3 cng u to ra s mol Ag gp i s mol anehit dng. BBB. Ch c anehit no c 2 nhm chc cacbonyl tc dng vi dung dch AgNO3 trong NH3 d mi to ra s mol Ag gp 4 ln s mol anehit dng. 94. t chy a mol anehit A to ra 2a mol CO2. Mt khc a mol A tc dng vi lng d dung dch AgNO3/NH3 to ra 4a mol Ag. A l CCC. A. anehit cha no. B. HCHO. DDD. C. CHOCHO. D. CH2=CHCHO. 95. Cng thc n gin nht ca anehit A cha no, mch h cha mt lin kt ba trong phn t l C2HO. A c cng thc phn t l EEE. A. C2HO. B. C6H3O3. C. C8H4O4. D. C4H2O2. 96. Trung ha a mol axit hu c A cn 2a mol NaOH. t chy ht a mol axit A c 2a mol CO2. A l
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
FFF. A. axit no n chc. B. CH3COOH. GGG. C. HOOCCOOH. D. COOHCH2COOH. 97. Trung ha hon ton 1,8 gam mt axit hu c n chc bng dung dch NaOH va ri c cn dung dch sau phn ng c 2,46 gam mui khan. Axit ni trn l HHH. A. HCOOH. B. CH3COOH. III. C. CH2=CHCOOH. D. C2H5COOH. P N 1. C 2. A 3. D 4. B 5. D 6. D 7. D 8. B 9. B 10. D 11. B 12. D 13. B 14. B 15. D 16. D 17. A 18. A 19. C 20. A 21. B 22. B 23. B 24. B 25. C 26. B 27. D 28. B 29. D 30. A 31. B 32. B 33. B 34. D 35. D 36. C 37. B 38. B 39. C 40. D 41. B 42. C 43. D 44. B 45. B 46. A 47. C 48. D 49. C 50. B
S : 14
Cho bit khi lng nguyn t ca cc nguyn t : H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Fe = 56; Cu = 64; Zn = 65; As = 75 ; Br = 80; Rb = 85,5; Ag = 108; Ba = 137; Be = 9. Cu 1: nh hng ca gc C6H5- n nhm -OH trong phn t phenol th hin qua phn ng gia phenol vi: D. Na kim loi A. Dung dch NaOH B. Nc Br2 C. H2 (Ni, t0) Cu 2: Qu trnh sn xut amoniac trong cng nghip da trn phn ng thun nghch sau y. N2 (k) + 3 H2 (k) 2 NH3 (k) ; = - 92 KJ Khi phn ng t ti trng thi cn bng, nhng thay i no di y lm cho cn bng dch chuyn theo chiu thun to ra nhiu amoniac: (1) Tng nhit ; (2) Tng p sut ; (3) Cho cht xc tc ; (4) Gim nhit ; (5) Ly NH3 ra khi h. A. (1), (2), (3), (5) B. (2), (3), (5) C. (2), (4), (5) D. (2), (3), (4), (5) Cu 3: Cho d y bin ho: CH CH CH3CHO CH3CH2OH CH3COOH CH3COOCH5 CH3COONa CH4. S phn ng oxi ho kh trong d y bin ho trn l: A. 2 B. 3 C. 4 D. 5 Cu 4: t chy hn hp m gam hn hp hai ancol ng ng lin tip thu c 0,66 gam CO2 & 0,45 gam H2O. Nu tin hnh oxi ho hon ton m gam hn hp hai ancol trn bng CuO, sn phm to thnh cho tc dng vi AgNO3/NH3 d s thu c lng kt ta bc l:A. 1,08 g B. 3,24 g C. 1,62 g D. 2,16 g Cu 5: Cho 3,2 gam Cu vo 100ml dung dch hn hp HNO3 0,8M v H2SO4 0,2M, sn phm kh duy nht sinh ra l NO. S gam mui sinh ra trong dung dch thu c l: A. 9,21 g. B. 5,64 g. C. 8,84 g. D. 7,90 g. Cu 6: Trong cc dung dch: HNO3, NaCl, K2SO4, Ca(OH)2, NaHSO4, Mg(NO3)2. D y gm cc cht u tc dng c vi dung dch Ba(HCO3)2 l: A. HNO3, Ca(OH)2, NaHSO4, Mg(NO3)2 B. HNO3, NaCl, K2SO4 C. HNO3, Ca(OH)2, NaHSO4, K2SO4 D. NaCl, K2SO4, Ca(OH)2
Cu 7: Cho hn hp 2 axitn chc, ng ng k tip tc dng ht vi dung dch NaOH. Lng mui sinh ra cho tc dng vi vi ti xt hon ton c hn hp kh
c t khi i vi H2 bng 6,25. Phn trm v s mol 2 axit trong hn hp cho l:' A. 25% v 75% B. 40% v 60% C. 30% v 70% D. 20% v 80% Cu 8: Cho 24,12 gam hn hp X gm CuO, Fe2O3, Al2O3 tc dng va vi 350ml dung dch HNO3 4M. C cn dung dch sau phn ng c m gam hn hp mui khan. Gi tr ca m l: A. 99,72 g B. 86,8 g C. 77,92 g D. 76,34 g Cu 9: Dd A cha 0,02mol Fe(NO3)3 v 0,3mol HCl c kh nng ha tan c Cu vi khi lng ti a l: A. 5,76 g. B. 0,64 g. C. 6,4 g. D. 0,576 g. Cu 10: Trong mt cc nc c cha 0,01 mol Na+ ; 0,02 mol Ca2+ ; 0,01 mol Mg2+ ; 0,05 mol HCO3- v 0,02 mol Cl-. Nc trong cc thuc loi no ? A. Nc cng vnh cu B. Nc cng tm thi C. Nc cng ton phn D. Nc mm Cu 11: Khi ly 2,85 gam mui clorua ca mt kim loi M ch c ho tr II v mt lng mui nitrat ca kim loi c s mol bng s mol mui clorua th thy khi lng ca chng khc nhau 1,59 gam. M l kim loi no sau y ? A. Cu B. Zn C. Mg D. Ca
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 12: Trong s cc hp cht n chc mch h c cng thc phn t CH2O, H2CO2, H4C3O2. S cht c th tc dng vi hiro (xt,t0), natrihiroxit, phn ng trng gng vi AgNO3/NH3 ln lt l: A. 1, 2, 4. B. 3, 3, 3. C. 2, 2, 2. D. 2, 2, 3. Cu 13: D y cht no sau y c th trc tip chuyn ho thnh axit axetic: A. C2H5OH ; CH3CHO ; CH3COONa ; CH3COOCH3 B. CH3CHO ; C2H5Cl ; CH3COCH3 ; CH3COONa C. C2H5OH; CH3COOCH3 ; CH2 = CH-COOH ; C2H6 D. C2H5OH ; CH3CHO ; C2H4 ; C2H5Cl Cu 14: Ho tan hon ton 1,5 gam hn hp Fe v mt kim loi ho tr II trong dung dch HCl thu c 3,36 lt H2 ktc, Kim loi ho tr II l: A. Ca B. Be C. Zn D. Mg Cu 15: Hn hp X gm 2 anehit cacboxylic u no, mch h. Cho 0,1 mol X phn ng trng gng hon ton thu c 0,3 mol Ag. Khi t chy hon ton 0,3 mol X thu c 16,8 lt CO2 ( ktc). Cng thc ca 2 anehit l: A. CH3CHO; CH2(CHO)2. B. CH3CHO; (CHO)2. B. C. HCHO; CH3CHO. D. CH3CHO; C2H5CHO. Cu 16: Trng hp ht 6,25 gam vinyl clorua c m gam PVC. S mt xch -CH2-CHCl- c trong m gam PVC ni trn l: A. 6,02. 1023. B. 6,02. 1021. C. 6,02. 1022. D. 6,01. 1020 Cu 17: Hn hp A gm Na2O, NH4Cl, NaHCO3, BaCl2. Cho hn hp A vo nc d, un nng sau cc phn ng xy ra hon ton thu c dung dch cha: A. NaCl B. NaCl, NaOH, BaCl2 C. NaCl, NaHCO3, BaCl2 D. NaCl, NaOH Cu 18: Cho dung dch X cha 0,1 mol FeCl2, 0,2 mol FeSO4. Th tch dung dch KMnO4 0,8M trong H2SO4 lang va oxi ha ht cc cht trong X l: A. 0,125 lit. B. 0,075 lit. C. 0,03 lit. D. 0,3 lit. Cu 19: 100ml dd A cha NaOH 0,1M v NaAlO2 0,3M. Thm t t dd HCl 0,1M vo dd A cho n khi kt ta tan tr li 1 phn. em nung kt ta n khi lng k0 i th c 1,02g cht rn. Th tch dd HCl 0,1M dng l: A. 0,7 lit B. 0,5 lit C. 0,6 lit D. 0,55 lit Cu 20: t chy hon ton 1,12 lt (ktc) hn hp X gm C2H4 v C4H4 th th tch kh CO2 (ktc) v khi lng hi H2O thu c ln lt l: A. 3,36 lt v 1,8 gam. B. 1,68 lt v 1,8 gam. C. 4,48 lt v 1,8 gam. D. 2,8 lt v 1,35 gam. Cu 21: Ho tan 0,24 mol FeCl3 v 0,16 mol Al2(SO4)3 vo dung dch cha 0,4 mol H2SO4 c dung dch X. Thm 1,3 mol Ba(OH)2 nguyn cht vo dung dch X thy xut hin kt ta Y. Khi lng ta Y l: A. 344,18 g. B. 0,64 g. C. 41,28 g. D. 246,32 g. Cu 22: Nguyn t ca nguyn t X c cu hnh eletron ho tr: (n-1)d5 ns1 (n 4). V tr ca nguyn t X trong bng tun hon l: A. Chu k n, nhm VI A B. Chu k n, nhm IA C. Chu k n, nhm IB D. Chu k n, nhm VI B Cu 23: Kt lun no sau y l sai ? (1) Cc axitcacboxilic u khng tham gia phn ng trng gng ; (2) Ancol etylic tc dng c vi natri nhng khng tc dng c vi CuO un nng ; (3) Tt c cc ng phn ancol ca C4H9OH u b oxi ho thnh anehit hoc xeton tng ng ; (4) Phenol c tnh axit mnh hn ancol ; (5) Cc este n chc (ch cha cc nguyn t C, H, O) khi thu phn trong mi trng kim u cho sn phm hu c l mui v ancol. A. (1), (2), (3), (5) B. (1), (2), (3) C. (3), (5) D. (1), (3), (5), 37 Cu 24: Trong t nhin ng v 17Cl chim 24,23 % v s nguyn t clo. H y cho bit phn trm v khi lng ca 37 1 17Cl trong HClO4 l bao nhiu ? (Cho nguyn t khi trung bnh ca clo bng 35,5 v vi H l ng v 1H ; O l ng v 16 8O). A. 9,204 % B. 26,39 % C. 8,56 % D. 8,92 % Cu 25: Hn hp X gm 2 cht hu c. Hn hp X phn ng va vi 100ml dd KOH 5M, sau phn ng thu c hn hp hai mui ca 2 axit no n chc v mt ancol no n chc Y. Cho ton b Y ac dng ht vi Na thu c 3,36 lt H2 (ktc). Hn hp X gm: A. 1 este v 1 axit. B. 1 este v 1 ancol C. Hai este D. 1 axit v 1 ancol Cu 26: Cho 19,2 gam hn hp mui cacbonat ca mt kim loi ho tr I v mui cacbonat ca mt kim loi ho tr II tc dng vi dung dch HCl d, thu c 4,48 lit mt cht kh (ktc). Khi lng mui to thnh trong dd l: A. 23,4 g. B. 22,2 g. C. 25,2 g. D. 21,4 g Cu 27: X l mt amino axit. Khi cho 0,2 mol X tc dng va vi HCl thu c 33,9 gam mui. Mt khc cho 0,2 mol X tc dng va vi NaOH thu c 35,4 gam mui. Cng thc phn t ca X l: A. C3H7NO2 B. C4H7NO4 C. C4H6N2O2 D. C5H7NO2 Cu 28: Ha cht no di y thng dng kh kh Cl2 lm nhim bn kk trong phng th nghim ?
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
A. dd Ca(OH)2 B. NH3 C. H2 D. O2 Cu 29: Cho bn l khng nh n cha mt trong cc dung dch sau: NaOH, Ba(OH)2, HCl, NaCl c cng nng mol 0,1M. Ch dng dung dch phenolphtalein nhn bit c my dung dch trong s cc dd trn ? A. 5 B. 1 C. 3 D. 4 Cu 30: Phn ng no di y khng dng chng minh c im cu to phn t glucoz ? A. Phn ng trng gng chng t trong phn t glucoz c nhm CH=O. B. Tc dng vi Na chng minh phn t c 5 nhm OH. C. Phn ng to este cha 5 gc axit CH3COO chng t c phn t c 5 nhmOH. D. Ha tan Cu(OH)2 cho dung dch mu xanh lam chng minh phn t c nhiu nhm chc OH. Cu 31: Khi cho Cu vo dung dch FeCl3 ; H2S vo dung dch CuSO4 ; HI vo dung dch FeCl3 ; dung dch AgNO3 vo dung dch FeCl3 ; dd HCl vo dd Fe(NO3)2 S cp cht phn ng c vi nhau l: A. 3 B. 2 C. 4 D. 5 Cu 32: Mun tng hp 60 kg thu tinh hu c poli (metylmetacrylat) th khi lng axit v ancol phi dng l bao nhiu ? (Bit hiu sut qu rnh ete hoa v qu trnh trng hp ln lt l 60% v 80%) A. 32,5 kg v 20 kg B. 107,5 kg v 40 kg C. 85,5 kg v 41kg D. 85 kg v 40 kg Cu 33: Cho 0,0 1 mol mt este X phn ng va ht vi 100 ml dung dch NaOH 0,2M, sn phm to ra ch gm mt mui v mt ancol u c s mol bng s mol este, u c cu to mch cacbon khng phn nhnh. Mt khc x phng ho hon ton mt lng este X bng dung dch KOH va , th va ht 200 ml KOH 0,15M v thu c 3,33 gam mui. X l: A. imetyl aipat. B. Etylenglycol oxalat. C. ietyl oxalat D. Etylenglicol aipat. Cu 34: Trn ln 100 ml dd NaHSO41M vi 100 ml dd KOH 2M c dung dch D, C cn dung dch D thu c nhng cht no sau y ? B. Na2SO4, KOH A. Na2SO4, K2SO4, KOH C. Na2SO4, K2SO4. NaOH, KOH D. Na2SO4, NaOH, KOH Cu 35: C th nh bit 3 cht: C2H5OH, CH2=CH-CH2OH, C6H5OH bng mt ho cht l: A. CuO B. Dung dch nc Br2 C. Dung dch KMnO4 D. Na Cu 36: Cracking hon ton 2,8 lt C5H12 (ktc) thu c hn hp kh B, t chy hon ton hn hp kh B thu c tng lng CO2 v H2O l: A. 41 g B. 82g C. 27g D. 62g Cu 37: in phn nng chy mui MX (M l kim loi kim, X l Cl, Br) c cht rn M v kh X. cho M vo nc d c dung dch A v kh Y. Cho kh X tc dng hon ton vi kh Y c kh Z. Hp th ht lng kh Z vo dung dch A c dung dch B, Gi tr pH ca dung dch B l: A. pH > 7 B. pH < 7 C. pH = 7 D. pH 7 Cu 38: Pht biu no sau y khng ng ? A. Anilin khng lm i mu giy qu tm m. B. Anilin l baz yu hn NH3 v nh hng ht electron ca gc C6H5- n nhm - NH2. C. nh hng ca nhm - NH2 n gc C6H5- lm cho phn t anilin t/d vi dd Br2 to kt ta trng. D. Tt c cc peptit u c phn ng mu biure. Cu 39: Cho s phn ng: NaX(r) + H2SO4() NaHSO4 + HX (X l gc axt). Phn ng trn dng iu ch cc axt: A. HBr, HI, HF B. HF, HCl, HBr C. HNO3, HCl, HF D. HNO3, HI, HBr Cu 40: Chia m gam mt este E thnh 2 phn bng nhau Phn 1 t chy hon ton thu c 1,12 lt khCO2 (ktc) v 0,9 gamH2O. Phn 2 cho tc dng vi dd NaOH 0,125M th va ht 100ml. Gi tr ca m l: A. 2,2 g B. 1,1 g C. 0,9 g. D. 1,8 g----------------Cu 41: Cho 4,5 gam hn hp X gm Fe3O4 v Cu vo dung dch HCl d, sau phn ng xy ra hon ton, thy cn 0,8 gam cht rn khng tan. Lng Fe3O4 trong hn hp l: A. 1,16 g B. 2,9 g C. 1,74 g D. 3,7 g Cu 42: Phn ng no sau y chng t glucoz c cu to mch vng ? A. Phn ng vi CH3OH / HCl B. Phn ng vi [Ag(NH3)2]OH. C. Phn ng vi Cu(OH)2. D. Phn ng vi H2 / Ni, t0. Cu 43: Pht biu no l ng trong cc pht biu sau: A. Xeton no khng tham gia phn ng cng . B. Anehit khng phn ng vi nc. C. Nh dung dch KMnO4 vo dung dch axeton, mu tm khng b mt. D. Cng thc phn t chung ca cc anehit no l CnH2nO. Cu 44: Cho cc cht v ion sau: HCO3-, K2CO3, H2O, Ca(OH)2, Al2O3, (NH4)2CO3, HS -. Theo Bronstet s cht v ion c tnh cht lng tnh l:
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20 B THI TH I HC
Mn: ho hc
2
Nm hc 2010-2011
A. 5 B. 3 C. 4 D. 1 0 Cu 45: Cho th in cc chun: E Ag + / Ag = +0,080 V, E 0 = +0,34V, E 0 = 0,00V, E 0 = - 0,76V. Cu 2 + / Cu Zn 2+ / Zn 2H+ / H Sut in ng chun ca pin in ha no sau y l ln nht ? B. E0Pin (Cu-Ag) C. E0Pin (Zn-Cu) D. E0 Pin (H2-Ag) A. E0 Pin (H2-Cu) Cu 46: Cho ln l]t cc cht C2H5Cl, C2H5OH, C6H5OH, C6H5Cl vo dung dch NaOH long un nng. S cht phn ng c vi dung dch NaOH l: A. 3 B. 4 C. 2 D. 1 Cu 47: Trng hp no sau y khng xy ra phn ng ? A. CuO + NH3, un nng B. CrO3 + NH3 C. Fe(NO3)2 + AgNO3 D. CuS + H2SO4 long Cu 48: H y sp xp cc cht sau y theo th t tnh baz tng dn: amoniac (1), anilin (2), p-nitroanilin (3), p-metylanilin (4), metylamin (5), imetylamin (6). A. (3) < (2) < (4) < (5) < (6) < (1) B. (3) < (4) < (2) < (1) < (5) < (6) C. (3) < (2) < (1) < (4) < (5) < (6) D. (3) < (2) < (4) < (1) < (5) < (6) Cu 49: phn bit ion CO32- v ion SO32- c th dng: A. Qu tm B. dd HCl C. dd CaCl2 D. dd Br2 Cu 50: Axit cacboxylic A vi mch cacbon khng phn nhnh, c cng thc nguyn l CHO. C 0,5 mol A tc dng ht vi NaHCO3 gii phng ra 1 mol CO2. Dng P2O5 tch loi nc ra khi A ta thu ]c cht B c cu to mch vng. Tn gi ca A l: A. Axit oleic B. Axit fumalic C. Axit maleic D. Axit aipic
P N
1A 11C 21D 31C 41B 2C 12B 22D 32B 42A 3C 13A 23A 33D 43C 4B 14B 23D 34C 44A 5D 15A 25A 35B 45C 6C 16C 26D 36A 46C 7A 17A 27B 37C 47D 8A 18B 28B 38D 48D 9C 19A 29D 39C 48D 10C 2 30B 40A 50C
S : 15
1. Cp cht no sau y khng xy ra phn ng?
A. Fe2+ v Cr2+ B. Fe3+ v Cu C. Mg v Ni2+ D. Zn v Cr3+ 2. Cho 5,6 g bt Fe phn ng hon ton vi dung dch H2SO4 m c, nng ngi ta thu c 9,6g sn phm kh cha lu hunh. Sn phm cha lu hunh l: A. H2S B. SO2 C. S D. Fe2(SO4)3 3. Khi vt bng thp b n mn in ha trong khng kh m, nhn nh no sau y khng ng ? A. cc dng xy ra qu trnh kh : 2H+ + 2e H2 B. cc dng xy ra qu trnh kh : O2 + 2H2O 4OH C. cc m xy ra qu trnh oxi ha : Fe Fe2+ + 2e D. cc m xy ra qu trnh oxi ha : Fe Fe3+ + 3e 4. Cho 0,1 mol Fe phn ng hon ton vi dung dch HNO3 d ngi ta thu c mui. Bit s mol Fe phn ng gn bng 27,78% s mol HNO3. Vy th tch kh thot ra ktc l: A. 0,672 L B. 0,84 L C. 6,72 L D. 2,24 L 5. Cho kh H2 qua ng s cha a gam Fe2O3 un nng, sau mt thi gian thu c 5,200g hn hp X gm 4 cht rn. Ha tan ht hn hp X bng HNO3 c nng thu c 0,785 mol kh NO2. Vy a l: A. 11,480g B. 24,040g C. 17,760g. D. 8,340g 6. Al c th phn ng vi tt c cc cht trong dy no sau y iu kin thch hp ? A. CuO, Cr2O3, dung dch K2SO4 B. dung dch CuSO4, dung dch CaCl2, CO C. dung dch FeCl2, FeO, dung dch SrCl2 D. Ca(OH)2, CuSO4, Cr2O3 7. Ha tan hon ton hn hp 3 kim loi : K, Sr, Ba vo nc ta c 0,448 lt kh (ktc) v dung dch X. Th tch dung dch HCl 0,5M cn dng trung ha dung dch X l : A. 80 ml. B. 40 ml. C. 20 ml. D. 125 ml. 8. C bao nhiu cht to kt ta vi kh H2S trong cc cht sau: FeCl2 , FeCl3 , ZnCl2, CuSO4?
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20 B THI TH I HC
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Nm hc 2010-2011
A. 1 B. 2 C.3 D. 4 9. Phn ng no sau y xy ra c iu kin thch hp ? A. 2Fe + 3S (d) Fe2S3 B. 2FeCl3 + 3H2S Fe2S3 + 6HCl C. Fe2O3 + CO 2FeO + CO2 D. 2FeS + 10H2SO4 Fe2(SO4)3 + 9SO2 + 10H2O 10. Cho 3,36 gam bt Mg vo dung dch cha hn hp gm CuCl2 0,12 mol v FeCl3 0,02 mol. Sau khi phn ng xy ra hon ton c cht rn A. Khi lng cht rn A l : A. 8,24 g. B. 8,16 g. C. 8,46 g. D. 7,92g 11. Fe c ln Al, Be, Cr2O3 dng bt. tinh ch Fe, ta c th dng : A. Dung dch H2SO4 long B. Dung dch Ba(OH)2 C. Dung dch FeCl2 D. HNO3 c ngui. 12. Dy cc cht no sau y u phn ng c vi dung dch NH3 ? A. dung dch FeCl3, dung dch HCOOH, dung dch BaCl2 B. kh clo, kh oxi, kh sunfur C. AgCl, CuO, Zn(OH)2 D. CuSO4, Be(OH)2, Al(OH)3 13. Th nghim no sau y khng to ra H2SO4 A. Sc kh SO2 vo dung dch brom B. un nng lu hunh bt vi H3PO4 c, nng C. Sc kh clo vo dung dch H2S D. Pha long oleum bng nc 14. Cho 1 ml dung dch brom mu vng vo ng nghim, thm vo 1 ml benzen ri lc tht k. Sau yn ta c 2 lp cht lng khng tan vo nhau. Quan st 2 lp cht lng ta thy : A. Lp trn c mu vng, lp di khng mu. B. Lp di c mu vng, lp trn khng mu. B. C 2 lp u khng mu. D. C 2 lp u c mu vng nhng nht hn. 15. C bao nhiu cht thuc loi aren trong cc C2H5 CH=CH2 cht sau ?
CH2
A. 2
B. 3
C. 4
D. 5
16. Pht biu no sau y khng ng ?
A. nhit thng glucoz, fructoz, saccaroz u ho tan Cu(OH)2 to dung dch xanh lam B. Glucoz, fructoz u tc dng vi H2 (xc tc Ni, t) cho poliancol C. Glucoz, fructoz, saccaroz u tham gia phn ng trng gng D. Glucoz, fructoz, mantoz u b oxi ho bi Cu(OH)2 khi un nng cho kt ta gch 17. Cho xenluloz phn ng hon ton vi anhiric axetic th sn phm to thnh gm 6,6 g CH3COOH v 11,1 g hn hp X gm xeluloz triaxetat v xenluloz iaxetat. Thnh phn phn trm v khi lng ca xenluloz triaxetat trong hn hp X l : A. 77,84%. B. 22,16%. C. 75%. D. 25% 18. S ng phn cu to ca amin bc nht ng vi cng thc phn t C4H11N l : A. 3 B. 4 C. 5 D. 6 19. Hin tng no sau y khng ng ? A. Protein u d tan trong nc to thnh dung dch keo B. Lp vng ni ln khi nu tht c l hin tng ng t protein C. Lng trng trng gp Cu(OH)2 to thnh mu tm D. Lng trng trng gp HNO3 to thnh hp cht c mu vng. 20. C bao nhiu cht trong dy : CH3NH2, CH3CH(NH2)COOH, HI, C2H5OH, Na2CO3, CH3NH3Cl phn ng vi axit 2aminopropanioic ? B. 3 B. 4 C. 5 D. 6 21. Dy chuyn ha no sau y khng ng ? A. CH4C2H2C4H4C4H6Cao su buna B. CH4C2H2CH3CHOC2H5OHC4H6Cao su buna C. CH4C2H2C2H3OHC2H5OHC4H6Cao su buna D. CH4C2H2C2H6C2H5ClC2H5OHC4H6Cao su buna 22. T cht u l vi v cc nguyn liu v c khc c th iu ch PVC vi s phng trnh ha hc ti thiu l : A. 4 B. 5 C. 6 D. 7 23. t chy ht hn hp A gm 0,1 mol etilenglicol (etylen glicol) v 0,2 mol ancol X thu c 35,2 gam CO2. Nu cho hn hp A tc dng ht vi natri th thu c 0,4 mol H2. Vy X l : A. CH3CH2CH2OH B. CH2 CH2 CH2 C. CH2 CH CH2 D. CH2 CH CH CH2
OH
OH
OH
OH
OH
OH
OH
OH
OH
24. Trong cc cht sau : HCHO, CH3Cl, CO, CH3COOCH3, CH3ONa, CH3OCH3, CH2Cl2 c bao nhiu cht to ra metanol bng 1 phn ng ? A. 3 B. 4 C. 5 D. 6
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
D. 43,2 g
25. Cho 12 g hn hp anehit fomic v metyl fomiat c khi lng bng nhau tc dng vi mt lng tha dung dch
AgNO3/NH3 . Khi lng Ag sinh ra l : A. 108,0 g B. 64,8 g C. 86,4 g 26. Pht biu no sau y khng ng v dy ng ng axit ankanoic ? A. Mch C cng di nhit si cc axit cng tng B. Khi lng phn t cng ln mnh tnh axit cng gim C. Mch C cng di cc axit cng kh tan trong nc [H 3O + ][ROO ] D. Cng thc tnh hng s in li axit l : Ka = [RCOOH][H O]
2
27. C bao nhiu ng phn cu to thuc loi anehit thm ng vi cng thc phn t C8H8O ? A. 2 B. 3 C. 4 D. 5 28. Cho cc cht phn ng vi nhau theo t l mol 1 : 1 trong s chuyn ha sau :
A B CH4 Cng thc khng ph hp vi cht A l : A. CH3OOCCH3. B. CH3COOH. C. CH3COONH4. D. HCOOCH3 29. Cn bng ha hc ca phn ng este ha gia ancol v axit hu c s dch chuyn theo chiu thun khi : A. pha long hn hp bng nc. B. thm dung dch NaOH vo hn hp. C. chng ct tch este ra khi hn hp. D. un nng hn hp. 30. S phn ng no sau y khng to ra HBr ? A. PBr3 + H2O B. Zn3P2 + H2O PH3 + Zn(OH)2 nhsng B. NaBr (rn) + H2SO4 c D. C6H5-CH3 + Br2 o-BrC6H4-CH3 + HBr 31. nhn bit hai bnh kh CO2 v SO2, cch no sau y khng ng ? A. Thi t t n d mi kh vo dung dch Ca(OH)2 B. Cho mi kh vo dung dch KMnO4 C. Cho mi kh vo dung dch Br2 D. Cho mi kh vo dung dch H2S 32. Cc dung dch (dung mi l nc) trong dy no sau y u c th lm qu tm ha xanh ? A. AlCl3, NH4Cl, C2H5ONa B. NH4Cl, C2H5ONa, Mg(OH)2 C. NaF, C6H5ONa, Na2CO3 D. Na3PO4, NH3, BaI2 33. Phn ng no sau y khng ng ? A. CaCl2 + CO2 + H2O CaCO3 + 2HCl B. CuCl2 + H2S CuS + 2HCl C. NaHSO4 + Na2CO3 Na2SO4 + NaHCO3 D. BaSO3 + 2HCl BaCl2 + SO2 + H2O 34. Nhn xt no ng khi in phn dung dch cha hn hp HCl v H2SO4? A. pH dung dch gim dn trong sut qu trnh in phn. B. pH dung dch tng ln n gi tr nht nh ri khng thay i na. C. pH dung dch gim xung n gi tr nht nh ri tng ln D. pH dung dch tng dn n gi tr nht nh ri gim xung 35. Thy phn hon ton hp cht 13,75 g PCl3 thu c dung dch X cha hn hp 2 axit. Th tch dung dch NaOH 0,1M trung ha dung dch X l : A. 300 ml B. 400 ml C. 500 ml D. 600 ml 36. Cc hp cht trong dy no sau y u c tnh axit ? B. H2SO4, Na2HPO3, CH3COOH. A. AlCl3, Ca(HCO3)2, NaHSO4 C. HClO, CO2, C6H5ONa D. NH4Cl, SO2, Na2ZnO2 (hay Na2[Zn(OH)4] ) 37. Dy no sau y gm cc cht u tc dng c vi ru (ancol) etylic iu kin thch hp ? A. CuO, CH3COOH, NaOH. B. Ca, CaO, CH3COOH. C. CuO, CH3OH, HCl. D. CuSO4, CH3COOH, HCl. 38. Phng php nhn bit no khng ng ? A. phn bit c ru (ancol) isopropylic v n- propylic ta oxi ha nh mi cht ri cho tc dng vi dung dch AgNO3/NH3 . B. phn bit metanol, metanal, axetilen ta cho cc cht phn ng vi dung dch AgNO3/NH3 C. phn bit benzen v toluen ta dng dung dch brom. D. phn bit axit metanoic v axit etanoic ta cho phn ng vi Cu(OH)2/NaOH 39. Chuyn ha hon ton 4,6 g hn hp cha cng s mol 2 ankanol bc nht thnh ankanal cn dng 0,1 mol CuO. Cho ton b ankanal thu c cho phn ng trng gng thu c 0,3 mol Ag. Hai ankanol l : A. CH3OH v C2H5OH. B. CH3OH v C3H7OH. C. C2H5OH v C3H7OH. D. C2H5OH v C4H9OH. Tnh cht no sau y khng ng vi cht NH3 CH COOH A. Phn ng vi NaOH v HCl B. Phn ng vi ancol COO C. Phn ng vi NaOH, khng phn ng vi HCl D. Cho phn ng trng ngng 40. Nhn xt no di y khng ng ? A. Phenol cho phn ng th d hn toluen. B. Toluen cho phn ng th d hn benzen C. Benzen cho phn ng th d hn anilin D. Anilin cho phn ng th d hn axit benzoic
+ NaOH + NaOH
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20 B THI TH I HC
chnh. Hnh v no di y khng ng? A. (I) B. (I), (II) C. (III) D. (III), (IV)
OCH3
Mn: ho hc
COOH CH2CH3
Nm hc 2010-2011
CH3 NO2
42. Khi cho cc cht sau phn ng vi clo c xc tc bt st, chiu mi tn ch v tr nguyn t clo gn vo to sn phm
(I)
(II)
(III)
(IV)
43. t chy a gam hn hp 3 kim loi Mg, Zn, Cu thu c 34,5 gam hn hp rn X gm 4 oxit kim loi. ha tan ht
hn hp X cn dng va dung dch cha 0,8 mol HCl. Vy gi tr ca a l: B. 21,7g C. 31,3g D. 24,9g 44. Hai ng phn X v Y c cng thc phn t C3H8O2. Tnh cht ca X v Y th hin trong bng sau: dung dch NaOH Na AgNO3/NH3 X c phn ng c phn ng khng phn ng Y c phn ng khng phn ng c phn ng Cng thc cu to ca X v Y ln lt l: A. CH3CH2COOH v HCOOCH2CH3 B. CH3CH2COOH v HOCH2CH2CHO C. CH3COOCH3 v HOCH2CH2CHO D. CH3COOCH3 v HCOOCH2CH3) 45. Phn ng no di y c dng sn xut axeton trong cng nghip ?
A. 28,1g
A. B. C.
(CH3COO)2Ca CH3COCH3 + CaCO3 CH3CHOHCH3 + CuO CH3COCH3 + Cu + H2O

2 2 4 C H OH + CH COCH C6H5CH(CH3)2 6 5 3 3 1.O kk, 2.H SO
D. CH3CCl2CH3 + 2KOH CH3COCH3 + 2KCl + 2H2O 46: dung dch CuSO4 vi anot bng ng, cng dng l 5 A, trong thi gian 9650 giy. iu no sau y ng ? A. Khi lng ng thu c catot l 16 g. B. Khi lng kh oxi thu c anot l 4 g. C. Nng CuSO4 gim dn trong qu trnh in phn. D. Phng trnh in phn l : 2CuSO4 + 2H2O 2Cu + 2H2SO4 + O2 47Cho 0,10 mol Fe v 0,10 mol FeO phn ng vi dung dch cha 0,15 mol AgNO3. Sau khi phn ng xy ra hon ton th khi lng cht rn thu c l : A. 21,6 g B. 23,4 g C. 24,8 g D.26,0g 48. Nu ch xt sn phm chnh th s chuyn ha no sau y KHNG ng ?
2 2 A. CH3CHOHCH3 CH3CH=CH2 CH3CH2CH2OH H O +H O
2 2 B. CH3CH2CH2OH CH3CH=CH2 CH3CHOHCH3

2 C. CH3CH2CH2OH CH3CH=CH2 CH3CHClCH3 CH3CHOHCH3 H O + HCl + NaOH
H O
+H O
D. CH3CH2CH2OH CH3CH2CH2Cl CH3CH2CHOH

49. Cc cht trong dy no sau y u to kt ta vi dung dch AgNO3/NH3 ? A. vinylaxetilen, glucoz, metyl fomiat, anehit axetic B. glucoz, metyl fomiat, imetylaxetilen, anehit axetic C. vinylaxetilen, glucoz, metyl fomiat, axit propionic
+ HCl
+ NaOH
D.vinylaxetilen, glucoz, metyl fomiat, imetylaxetilen

50. Cho 0,10 mol Fe v 0,10 mol FeO phn ng vi dung dch cha 0,15 mol AgNO3. Sau khi phn ng xy ra hon ton th khi lng cht rn thu c l : B. 21,6 g B. 23,4 g C. 24,8 g D.26,0g 1. A 2. B 3. D 4. A 5. A 6. D 7. A 8. B 9. D 10. A 11. B 12. B 13. B 14. A 15. C p n 16. C 17. A 18. B 19. A 20. C 21. C 22. B 23. C 24. C 25. A 26. D 27. C 28. D 29. C 30. B 31. A 32. C 33. A 34. D 35. C 36. A 37. C 38. C 39. B 40. C 41. C 42. C 43. A 44. A 45. C 46. C 47. C 48. C 49. A 50. C
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20 B THI TH I HC
Mn: ho hc
S : 16
Nm hc 2010-2011
Cu 1: Ancol C5H12O c s ng phn bc 2 l:
A. 5
B. 3
C. 4
D. 2
Cu 2: Cracking hon ton 2,8 lt C5H12 thu hh B. t chy hn hp B thu tng lng CO2, H2O l: A. 27g B. 41g C. 82g D. 62g Cu 3: Thuc th duy nht dng nhn bit cc cht sau: Ba(OH)2, NH4HSO4, BaCl2, HCl, NaCl, H2SO4 dng trong 6 l b mt nhn. A. dd Na2CO3 B. dd AgNO3 C. dd NaOH D. qu tm Cu 4: Khuy u mt lng bt Fe, Fe3O4 vo dung dch HNO3 long. Chm dt phn ng, thu c dung dch X v kh NO v cn li mt t kim loi. Vy dung dch X cha cht tan: B. Fe(NO3)3, HNO3 A. Fe(NO3)3, Fe(NO3)2 C. Fe(NO3)2 duy nht D. Fe(NO3)3, Fe(NO3)2, HNO3 Cu 5: C mt hp cht hu c n chc Y, khi t chy Y ta ch thu c CO2 v H2O vi s mol nh nhau v s mol oxi tiu tn gp 4 ln s mol ca Y. Bit rng: Y lm mt mu dung dch brom v khi Y cng hp hiro th c ru n chc. Cng thc cu to mch h ca Y l: A. CH3-CH2-OH B. CH2=CH-CH2-CH2-OH C. CH3-CH=CH-CH2-OH D. CH2=CH-CH2-OH . Cu 6: Mt cht hu c X cha C, H, O ch cha mt loi chc cho 2,9g X phn ng vi dung dch AgNO3/NH3 d thu c 21,6g Ag. Vy X c th l: A. HCHO B. OHC CHO C. CH2(CHO)2 D. CH3 CHO Cu 7: Cho 3g hn hp gm 3 kim loi ng trc H2 trong dy hot ng ha hc phn ng ht vi H2SO4 d, thu c 1,008 lt H2 (kc). C cn dung dch thu c mg rn. Vy m c th bng: A. 7,32g B. 5,016g C. 2,98g D. Kt qu khc Cu 8: So snh tnh axit ca cc cht sau y: CH2Cl-CH2COOH (1), CH3COOH (2), HCOOH (3), CH3-CHCl-COOH (4) A. (3) > (2) > (1 ) > (4) B. (4) > (2) > (1 ) > (3) C. (4) > (1) > (3). > (2) D. Kt qu khc
Cu 9: Hai cht hu c X v Y u n chc l ng phn ca nhau. t chy hon ton 5,8 gam hn hp X v Y cn 8,96 lt oxi (ktc) thu c kh CO2 v hi nc theo t l VCO2 : Vhi H2O = 1 : 1 (o cng iu kin). Cng thc n gin ca X v Y l: A. C2H4O B. C3H6O C. C4H8O D. C5H10O Cu 10: Ha tan hon ton 2,81 (g) hn hp mt oxit Kim loi kim v mt oxit kim loi kim th vo V ml ddH2SO4 0,1M ri c cn dd sau p thu c 6,81g hh mui khan. Gi tr V: A. 500 ml B. 625 ml C. 725 ml D. 425 ml Cu 11: t ru A. Dn ht sm phm chy vo bnh ng ddCa(OH)2 d; thy c 3 gam kt ta v khi lng bnh tng 2,04 gam. Vy A l: A. CH3OH B. C2H5 OH C. C3H7OH D. C4H9OH Cu 12: Ha tan ht 1,62g bc bng axit nng 21% ( d=1,2 g/ml) ; thu oc NO.Th tch dung dch axitnitric ti thiu cn phn ng l: A. 4ml B. 5ml C. 7,5ml D. Gi tr khc Cu 13: Mt oxit kim loi: M x Oy trong M chim 72,41% v khi lng. Kh hon ton oxit ny bng CO, thu c 16,8 gam M. Ha tan hon ton lng M ny bng HNO3 c nng thu c 1 mui v x mol NO2. Gi tr x l: A. 0,45 B. 0,6 C. 0,75 D. 0,9 Cu 14: Hn hp X gm 2 axit no: A1 v A2. t chy hon ton 0,3mol X thu c 11,2 lt kh CO2 (ktc). Trung ha 0,3 mol X cn 500ml dung dch NaOH 1M. Cng thc cu to ca 2 axit l: A. CH3COOH v C2H5COOH B. HCOOH v HOOC-COOH C. HCOOH v C2H5COOH D. CH3COOH v HOOC-CH2-COOH Cu 15: Khi th 1 ln vi Br2 to 4 sn phm. Vy tn gi l: A. 2 metyl pentan. B. 2metyl butan. C. 2,3 imetylbutan. D. 2,3 dimetyl butan
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 16: t chy hn hp 2 ru ng ng c s mol bng nhau, ta thu c khi CO2 v hi nc c t l s mol: nCO2 : nH2O = 2 : 3. Cng thc phn t 2 ru ln lt l: A. CH4O v C3H8O B. C2H6O v C3H8O C. CH4O v C2H6O D. C2H6O v C4H10O Cu 17: Cho phn ng: C4H6O2 + NaOH B + D; D + Z E + Ag. B c th iu ch trc tip c t CH4 v C2H6. Vy B c th l: A. CH3COONa B. C2H5COONa C. A, B u ng D. A, B u sai Cu 18: t chy hn hp A gm c nhiu hidrcacbon thu c 6,72 lt CO2 (kc) v 3,6g H2O. Vy V lt O2 cn t l: A. 8,96lt B. 2,24 lt C. 6,72lt D. 4,48lt Cu 19 Cho th t cc cp oxi ha- kh sau: Fe2+/Fe; Cu2+/Cu; Fe3+/Fe2+; Ag+/Ag. Trong cc dung dch mui v kim loi sau:Fe(NO3)2, Cu(NO3)2, Fe(NO3)3, Fe, Cu, Ag th dung dch AgNO3 c th tc dng vi: A. Fe, Cu, dung dch Fe(NO3)2. B. Fe, Cu. C. Fe, Cu, dung dch CuSO4. D. Fe, dung dch Fe(NO3)2. Cu 20: Cu hnh electron ca ion Cl- l: B. 1s22s22p63s23p6 A. 1s22s22p6 Cu 21: Dung dch c pH=7: A. NH4Cl B. CH3COONa C. 1s22s22p63s23p5 C. C6H5ONa D. 1s22s22p63s23p4 D. KClO3
Cu 22: Vi cng thc C3H8Ox c nhiu nht bao nhiu CTCT cha nhm chc phn ng c vi Na. A. 2 B. 3 C. 4 D. 5 Cu 23: Chn pht biu sai: A. t chy 1 ankan cho s mol H2O > s mol CO2 B. Phn ng c trng ca ankan l phn ng th. C. Ankan ch c lin kt xch ma trong phn t. D. Clo ha ankan theo t l 1:1 ch to mt sn phm th duy nht. Cu 24: Cho m gam Fe vo 100 ml dung dch Cu(NO3)2 th nng ca Cu2+ cn li trong dung dch bng 1/2 nng ca Cu2+ ban u v thu c mt cht rn A c khi lng bng m+0,16 gam. Bit cc phn ng xy ra hon ton. Khi lng Fe v nng (mol/l) ban u ca Cu(NO3)2 : A. 1,12 gam v 0,3M B. 2,24 gam v 0,2 M C. 1,12 gam v 0,4 M D. 2,24 gam v 0,3 M. Cu 25: Ho tan 45,9 gam kim loi M bng dung dch HNO3 long thu c hn hp kh gm 0,3 mol N2O v 0,9 mol NO. Kim loi M l: A. Mg B. Fe C. Al D. Zn Cu 26: Sp xp cc cht sau: H2, H2O, CH4, C2H6 theo th t nhit si tng dn: A. H2 < CH4 < C2H6 < H2O B. H2 < CH4 < H2O < C2H6 C. H2 < H2O < CH4 < C2H6 D. CH4 < H2 < C2H6 < H2O Cu 27:: Ly 9,1gam hp cht A c CTPT l C3H9O2N tc dng vi dung dch NaOH d, un nng, c 2,24 lt (o ktc) kh B thot ra lm xanh giy qu tm m. t chy ht lng kh B ni trn, thu c 4,4gam CO2. CTCT ca A v B l: A. HCOONH3C2H5 ; C2H5NH2 B. CH3COONH3CH3; CH3NH2 C. HCOONH3C2H3 ; C2H3NH2 D. CH2=CHCOONH4; NH3 Cu 28: Cho cc dung dch ca cc hp cht sau: NH2-CH2-COOH (1) ; ClH3N-CH2-COOH (2) ; NH2-CH2-COONa (3) ; NH2-(CH2)2CH(NH2)-COOH (4) ; HOOC-(CH2)2CH(NH2)-COOH (5). Cc dung dch lm qu tm ho l: A. (3) B. (2) C. (2), (5) D. (1), (4). Cu 29: nhn bit dung dch cc cht glixerin, h tinh bt, lng trng trng g, ta c th dng mt thuc th duy nht thuc th l: A. Dung dch H2SO4 B. Cu(OH)2 C. Dung dch I2 D. Dung dch HNO3 Cu 30: Trong s cc polime tng hp sau y: nha PVC (1), caosu isopren (2), nha bakelit (3), thu tinh hu c (4), t nilon 6,6 (5). Cc polime l sn phm trng ngng gm: A. (1) v (5). B. (1) v (2) C. (3) v (4) D. (3) v (5). Cu 31: Cho 360 gam glucoz ln men thnh ru etylic (gi s ch c phn ng to thnh ruetylic). Cho tt c kh CO2 hp th vo dung dch NaOH th thu c 212 gam Na2CO3 v 84 gam NaHCO3. Hiu sut ca phn ng ln men ru l:
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20 B THI TH I HC
A. 50% B. 62,5%
Mn: ho hc
C. 75% D. 80%
Nm hc 2010-2011
Cu 32: Cht hu c (A) cha C, H, O. Bit rng (A) tc dng c vi dung dch NaOH, c cn c cht rn (B) v hn hp hi (C), t (C) chng ct c (D), (D) tham gia phn ng trng gng cho sn phm (E), (E) tc dng vi NaOH li thu c (B). Cng thc cu to ca (A) l: A. HCOOCH2-CH=CH2 B. HCOOCH=CH-CH3 C. HCOOC(CH3)=CH2 D. CH3COOCH=CH2 Cu 33: Dung dch X cha axit HCl a mol/l v HNO3 b mol/l. trung ho 20 ml dung dch X cn dng 300 ml dung dch NaOH 0,1 M. Mt khc ly 20 ml dung dch X cho tc dng vi dung dch AgNO3 d thy to thnh 2,87 gam kt ta. ( Ag = 108, Cl = 35,5 ). Gi tr ca a, b ln lt l: A. 1,0 v 0,5 B. 1,0 v 1,5 C. 0,5 v 1,7 D. 2,0 v 1,0 Cu 34: Ion CO32- cng tn ti vi cc ion sau trong mt dung dch: A. NH4+, Na+, K+ B. Cu2+, Mg2+, Al3+ C. Fe2+, Zn2+, Al3+ D. Fe3+, HSO4-
Cu 35. Dung dch E cha cc ion Mg2+, SO42-, NH4+, Cl-. Chia dung dch E ra 2 phn bng nhau: Cho phn I tc dng vi dung dch NaOH d, un nng, c 0,58 gam kt ta v 0,672 lit kh (ktc). Phn II tc dng vi dung dch BaCl2 d, c 4,66 gam kt ta. Tng khi lng cc cht tan trong dung dch E bng (Mg = 24, Ba = 137, S = 32, O = 16, Na = 23,H = 1, Cl = 35,5) A. 6,11g. B. 3,055g. C. 5,35g. D. 9,165g. Cu 36: Hp cht hu c C4H7O2Cl khi thu phn trong mi trng kim c cc sn phm trong c hai cht c kh nng tham gia phn ng trng gng. Cng thc cu to ca cht hu c l: A. HCOO-CH2- CHCl-CH3 B. CH3-COO-CH2-CH2Cl C. HCOOCHCl-CH2-CH3 D. HCOOC(CH3)Cl-CH3 Cu 37: Ha tan 2,49 gam hh 3 kim loi ( Mg, Fe, Zn) bng lng va dd H2SO4 1M, thu c1,344 lt H2 (kc) Th tch dung dch H2SO4 cn dng l: A. 1,2 lt B. 0,24 lt C. 0,06 lt D. 0,12 lt
Cu 38: un hn hp X gm 2 cht hu c A, B vi H2SO4 c 140OC; thu c 3,6 gam hn hp B gm 3 te C s mol bng nhau v 1,08 gam nc. Hai cht hu c l:
A. CH3OH v C3H7OH C. C3H7OH v CH2=CH-CH2OH B. CH3OH v C2H5OH D. C2H5OH v CH2=CH-CH2OH Cu 39: Cho 31,9 gam hn hp Al2O3, ZnO, FeO, CaO tc dng ht vi CO d nung nng thu c 28,7 gam hn hp Y. Cho Y tc dng vi dung dch HCl d thu c V lt H2 (ktc). Th tch H2 l: A. 6,72 lt B. 11,2 lt C. 5,6 lt D. 4,48 lt
Cu 40: X l ru bc II c CTPT C6H14O. un nng X vi H2SO4 c 1700C ch to mt anken nht. Tn ca (X) l :

A. 2,2-imetylbutan-3-ol B. 2,3-imetylbutan-3-ol C. 3,3-imetylbutan-2- ol D. 2,3-imetylbutan-2-ol Cu 41: Cho bt Al vo dung dch hn hp:NaNO3 ; NaNO2; NaOH s c s phn ng nhiu nht bng: A.1 B. 2 C. 3 D. Gi tr khc Cu 42: t chy a mol mt este no ; thu c x mol CO2 v y mol H2O. Bit x y = a. Cng thc chung ca este: A. CnH2n-2O2 B. CnH2n-4O6 C. CnH2n-2O4 D. CnH2nO2 Cu 43: Mt anhit n no c %O=36,36 v khi lng. Tn gi ca anhit ny l: A. Propanal B. 2-metyl propanal C. Etanal D. Butanal
duy
Cu 44: Dung dch A: 0,1mol M2+ ; 0,2 mol Al3+; 0,3 molSO42- v cn li l Cl-. Khi c cn ddA thu c 47,7 gam rn. Vy M s l: A. Mg B. Fe C. Cu D. Al Cu 45: CTTQ ca Este sinh bi axit n no v ng ng benzen l: A. CnH2n - 6O2 B. CnH2n 8O2 C. CnH2n - 4 O2 D. CnH2n -2O2. B.
Cu 46: (A) l este n chc, mch C h v c mC : mO = 9 : 8 . C tt c bao nhiu CTCT ca (A) c th c: A. 3 4 C. 5 D. 6
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20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cu 47: t ru A. Dn ht sm phm chy vo bnh ng dung dch Ca(OH)2 d; thy c 3 gam kt ta v khi lng bnh tng 2,04 gam. Vy A l: B. C2H6 O A. CH4O C. C3H8O D. C4H10O Cu 48: Trong cng nghip, natri hiroxit c sn xut bng phng php: A. in phn dung dch NaCl, khng c mng ngn in cc. B. in phn dung dch NaCl, c mng ngn in cc. C. in phn dung dch NaNO3 , khng c mn ngn in cc. D. in phn NaCl nng chy. Cu 49: Cho hh bt KL: a mol Mg, b mol Al, p vi dd hh cha c mol Cu(NO3)2 , d mol AgNO3 Sau p thu c rn cha 2kim loi. Biu thc lin h a,b,c,d: A. 2a + 3b = 2c + d B. 2a + 3b 2c d C. 2a + 3b 2c d D. 2a + 3b 2c + d Cu 50: 1,68 lt hn hp A: CH4, C2H4 (kc) c KLPTTB bng 20. t chy hon ton hhA; thu x gam CO2. Vy x bng: A.3,3g B. 4,4g C . 6,6g D. 5,6 g P N 1. D 6. C 11. A 16. A 21. A 26. B 31. A 36. A 41. B 46. B 2. B 7. B 12. B 17. B 22. A 27. C 32. A 37. B 42. A 47. D 3. D 8. C 13. B 18. B 23. C 28. D 33. D 38. A 43. A 48. D 4. C 9. C 14. C 19. D 24. B 29. C 34. C 39. B 44. A 49. D 5. D 10. A 15. B 20. B 25. D 30. C 35. A 40. D 45. B 50. C
S : 17
1 mt anken (c 6 nguyn t C), phn ng vi dung dch KMnO4, trong mi trng axit, ch cho mt sn phm oxi ha l
CH3COCH3, anken l A. 2,3-imetyl-2-buten. C. isopren. 2.Cho phn ng sau: B. 3-metyl-2-penten. D. trans-3-hexen.
Mg + HNO3 Mg(NO3)2 + NO + NO2 + H2O Nu t l s mol gia NO v NO2 l 2:1, th h s cn bng ti gin ca HNO3 trong phng trnh ho hc l A. 12. B. 30. C. 18. D. 20. 3.in phn dung dch CuSO4 nng 0,5M vi in cc tr trong th thu c 1 gam ng. in lng tiu tn ti thiu l A. 3015 C. B.2870 C. C.1212 C. D.2550 C. 4.C th iu ch bc kim loi t dung dch AgNO3 bng cch A. in phn vi in cc than ch. B. nhit phn. C. in phn vi in cc Au. D. cho tc dng vi kim loi mnh nh canxi. 5.in phn dung dch CuSO4 nng 0,5M vi in cc tr trong th thu c 1gam Cu. Nu dng dng in mt chiu c cng 1A, th thi gian in phn ti thiu l A. 50 pht 15 giy.B. 40 pht 15 giy. C. 0,45 gi. D. 0,65 gi. 6.Phng php thy luyn dng iu ch A. kim loi c tnh kh yu. B. kim loi m ion dng ca n c tnh oxy ha yu. C. kim loi hot ng mnh. D. kim loi c cp oxi ha-kh ng trc Zn2+/Zn. 7.Ha tan m gam hn hp 2 mui cacbonat kim loi ha tr (I) v (II) bng dung dch HCl d thu c dung dch A v V lt kh CO2 (ktc). C cn dung dch A thu c (m+3,3) gam mui khan. Tnh V? A. 2,24 lt. B. 3,72 lt. C. 6,72 lt. D. 8,96 lt. 8.Cho cc cht A (C4H10), B (C4H9Cl), C (C4H10O), D (C4H11N). Nguyn nhn gy ra s tng s lng cc ng phn t A n D l do A. ha tr ca cc nguyn t th tng lm tng th t lin kt trong phn t. B. m in khc nhau ca cc nguyn t.
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C. cc bon c th to nhiu kiu lin kt khc nhau. D. khi lng phn t khc nhau. 9.A v B l 2 axit cacboxylic n chc. Trn 1,2 gam A vi 5,18 gam B c hn hp X. trung ha ht X cn 90 ml dung dch NaOH 1M. Trn 7,8 gam A vi 1,48 gam B c hn hp Y. trung ha ht Y cn 75 ml dung dch NaOH 2M. Cng thc ca A, B ln lt l A. CH3COOH v C2H3COOH. B. C2H3COOH v C2H5COOH. D. CH3COOH v C2H5COOH. C. C2H5COOH v CH3COOH. 10.S ng phn cu to ca C5H10 l A. 11. B. 10. C. 9. D.8. 11. lm thay i pH ca dung dch (dung mi nc) t 4 thnh 6, th cn pha dung dch vi nc theo t l th tch l A. 1:99. B. 99:1. C. 2:3. D. 3:2. 12.Dung dch c pH = 4 s c nng ion OH bng A. 104. B. 4. C. 1010. D. 104. 13.Khi trn nhng th tch bng nhau ca dung dch HNO3 0,01M v dung dch NaOH 0,03M th thu c dung dch c pH bng A. 9. B. 12,3. C. 13. D.12. 14.Cho cc cht A (C4H10), B (C4H9Cl), C (C4H10O), D (C4H11N). S lng cc ng phn ca A, B, C, D tng ng l A. 2; 4; 6; 8. B. 2; 3 ; 5; 7. C. 2; 4; 7; 8. D. 2; 4; 5; 7. 15.S cp ng phn cis-trans ca C5H10 l A. 1. B. 2. C. 3. D. 4. 16.Phng php no di y thng dng iu ch kim loi phn nhm ph nh Crom, Mangan, St... A. in phn mui nng chy, hoc phn hy nhit hoc khai thc dng kim loi t do. B. Kh bng cc cht kh ha hc hoc kh cc qung sunfua bng Cacbon nhit cao C. Dng kim loi mnh y kim loi yu ra khi dung dch mui. D. in phn dung dch mui. 17.Hn hp X gm hai hirocacbon A, B thuc loi ankan, anken, ankin. t chy hon ton 6,72 lt (ktc) X ri cho tt c sn phm chy hp th hon ton vo bnh ng nc vi trong d, thy khi lng bnh tng thm 46,5 gam v c 75 gam kt ta. X c th gm A. 2 ankan. B. 1 ankin +1 anken. C. 1 ankan +1 anken. D. 1 ankan +1 ankin. 18.Hn hp X gm hai hirocacbon A, B thuc loi ankan, anken, ankin. t chy hon ton 6,72 lt (ktc) kh X c khi lng l m gam, v cho tt c sn phm chy hp th hon ton vo bnh ng nc vi trong d, thy khi lng bnh tng thm 46,5 gam v c 75 gam kt ta. Nu t l khi lng ca A v B l 22:13, th khi lng m (gam) X ly A. 10. B. 9,5. C. 10,5. D.11. 19.Hn hp X gm hai hirocacbon A, B thuc loi ankan, anken, ankin. t chy hon ton 6,72 lt (ktc) kh X c khi lng l m gam, v cho tt c sn phm chy hp th hon ton vo bnh ng nc vi trong d, thy khi lng bnh tng thm 46,5 gam v c 75 gam kt ta. Nu t l khi lng ca A v B l 22:13, th s gam cht A trong m gam X l A. 4,4. B. 4,5. C. 5,6. D.6,6. 20.Nitro ha benzen thu c 2 hp cht nitro X, Y hn km nhau mt nhm NO2. t chy hon ton 2,3 gam hn hp X, Y thu c CO2, H2O v 0,224 lt N2 (ktc). Cng thc phn t ca X, Y l A. C6H5NO2 v C6H4(NO2)2. B. C6H4(NO2)2 v C6H3(NO2)3. C. C6H5NO2 v C6H3(NO2)3. D. khng xc nh c. 21.Aminoaxit iu kin thng l cht rn, kt tinh, tan tt trong nc v A. aminoaxit c nhm chc axit. B. aminoaxit c nhm chc baz. C. aminoaxit c cu to tinh th ion lng cc. D. aminoaxit va c tnh axit va c tnh baz. 22.Este A c iu ch t aminoaxit B v ru etilic. 2,06 gam A ha hi hon ton chim th tch bng th tch ca 0,56 gam nit cng iu kin. A c cng thc cu to l A. NH2CH2CH2COOCH2CH3. B. NH2CH2COOCH2CH3. C. CH3NHCOOCH2CH3. D. CH3COONHCH2CH3. 23.Khi lng phn t ca mt loi t capron bng 16950 vC, ca t enang bng 21590 vC. S mt xch trong cng thc phn t ca mi loi t trn ln lt l A. 120 v 160. B.200 v 150. C.150 v 170. D.170 v 180. 24.Khi lng phn t trung bnh ca xenluloz tnh theo .v.C trong si bng l 1750000, trong si gai l 5900000. S mt xch trung bnh trong cng thc phn t xenluloz ca mi loi si tng ng l A. 10802 v 36420. B. 12500 v 32640. C.32450 v 38740. D.16780 v 27900.
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25.Cn bao nhiu lt axit H2SO4 (d = 1,84 g/ml) v bao nhiu lt nc ct pha thnh 9 lt dung dch H2SO4 c d = 1,28 g/ml. A. 3 lt v 6 lt. B. 2 lt v 7 lt. C. 6 lt v 3 lt. D. 4 lt v 5 lt. 26.Hin tng quan st c khi cho dung dch nc iot ln lt vo ming chui cn xanh v ming chui chn l A. c hai cho mu xanh lam. B. c hai khng i mu. C. ming chui cn xanh cho mu xanh tm, ming chn khng nh vy. D. ming chui chn cho mu xanh lam, ming xanh khng nh vy. 27.Cho s phn ng sau: H 2SO4 HBr NaOH But-1-en X Y Z. H O 180 oC
2
Bit X, Y, Z u l cc hp cht hu c v l nhng sn phm chnh. Cng thc ca X, Y, Z ln lt l A. CH3CH(Br)CH2CH3, CH3CH(OH)CH2CH3 , CH3CH=CHCH3. B. CH2BrCH2CH2CH3 , CH2(OH)CH2CH2CH3, CH2=CHCH2CH3. C. CH3CH(Br)CH2CH3, CH3CH(OH)CH2CH3 , CH2=CHCH2CH3. D. CH3CH(Br)CH2CH3, CH3CH2CH2CH2(OH), CH2=CHCH2CH3. 28.Cho s phn ng: + H 2O / H men ru men gim + Y, xt Xenluloz X Y Z T. Cng thc cu to ca T l A. C2H5COOCH3. B. CH3COOH. C. C2H5COOH. D. CH3COOC2H5. 29.Cn trn theo t l th tch no 2 dung dch NaOH 0,1M vi dung dch NaOH 0,2M c dung dch NaOH 0,15M. Cho rng s trn ln khng thay i th tch. A. 1 : 1. B. 1 : 2. C. 2 : 1. D. 2 : 3. 30.Tin hnh th nghim sau: Cho mt t bt ng kim loi vo ng nghim cha dung dch FeCl3, lc nh ng nghim s quan st thy hin tng no sau y? A. Kt ta St xut hin v dung dch c mu xanh. B. Khng c hin tng g xy ra. C. ng tan v dung dch c mu xanh. D. C kh mu vng lc ca Cl2 thot ra. 31.Cho vo ng nghim 1ml dung dch protit (lng trng trng), tip theo cho 1ml dung dch NaOH c v 1 git dung dch CuSO4 2%, lc nh ng nghim. mu ca dung dch quan st c l A. xanh tm. B. vng. C. en. D. khng c s thay i mu. 32.Cho 3,2 gam Cu tc dng vi 100ml dung dch hn hp HNO3 0,8M + H2SO4 0,2M, sn phm kh duy nht ca HNO3 l kh NO. S gam mui khan thu c l A. 5,64. B. 7,9. C. 8,84. D. ba kt qu trn u sai. 33.Cho 3,2 gam Cu tc dng vi 100ml dung dch hn hp HNO3 0,8M + H2SO4 0,2M, sn phm kh duy nht ca HNO3 l kh NO. Th tch (tnh bng lt) kh NO ( ktc) l A. 0,672. B. 0,448. C. 0,224. D. 0,336. 34.Ht nhn nguyn t R c in tch bng +32.1019C. Nguyn t R thuc A. chu k 3 nhm IIB. B. chu k 3 nhm IIA. C. chu k 4 nhm IIA. D. chu k 4 nhm IIIA. 35.17,7 gam mt ankylamin cho tc dng vi dung dch FeCl3 d thu c 10,7 gam kt ta. Cng thc ca ankylamin l A. CH3NH2. B. C4H9NH2. C. C3H9N. D. C2H5NH2. 36.Dung dch AlCl3 trong nc b thy phn nu thm vo dung dch cc cht sau y, cht no lm tng cng qu trnh thy phn AlCl3? A. NH4Cl. B. Na2CO3. C. ZnSO4. D. Khng c cht no c. 37.Khi t chy ng ng ca ru n chc ta thy t l s mol n CO2 : n H 2O tng dn theo s mol cacbon, ru trn thuc dy ng ng A. ru thm. B. ru khng no. C. ru no. D. khng xc nh c. 38.Khi nung nng mnh 25,4 gam hn hp gm kim loi M v mt oxit st phn ng xy ra hon ton, th thu c11,2 gam st v 14,2 gam mt xt ca kim loi M. Hi M l kim loi no? A. Al. B. Cr. C. Mn. D. Zn. 39.Dng giy rp nh sch mnh nhm ri nh mt git dung dch HgCl2 ln b mt sch mnh nhm. Sau 2 pht, lau kh v mnh nhm trong khng kh. Hin tng quan st c sau cng l A. nhng ht nh li ti mu trng bc ca thy ngn ln trn mnh nhm. B. b mt nhm c mu en. C. nhng si nh nh si ch mu trng xut hin trng nh lng t. D. si bt trn b mt mnh nhm do AlCl3 b thy phn.
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40.Cho hi nc i qua than nng c hn hp kh A gm CO2,CO, H2. Ton b lng kh A va kh ht 48 gam Fe2O3 thnh Fe v thu c 10,8 gam H2O. Phn trm th tch CO2 trong hn hp kh A l A. 28,571. B. 14,289. C. 13,235. D. 16,135. 41.C th dng ha cht no di y phn bit ba oxit mu en Cr2O3, FeO, MnO2? A. Dung dch HNO3. B. Dung dch Fe2(SO4)3. C. Dung dch HCl. D. Dung dch NaOH. 42.Ha tan hon ton 11,9 gam hn hp 2 kim loi (Zn, Al) bng dung dch H2SO4 c nng thu c 7,616 lt SO2 (ktc), 0,64 gam S v dung dch X. Tnh khi lng mui trong X. A. 60,3 gam. B. 50,3 gam. C. 72,5 gam. D. 30,3 gam. 43.Tin hnh th nghim sau: nh vi git dung dch H2S vo ng nghim cha dung dch FeCl3 thy xut hin kt ta. Kt ta l A. Fe. B. S. C. FeS. D. c FeS v S. 44.Trn b mt ca cc h nc vi, hay cc thng nc vi ngoi khng kh, thng c mt lp vng mng. Lp vng ny ch yu l A. canxi. B. canxi hiroxit. C. canxi cacbonat. D. canxi oxit. 45.Trong cc cht sau, cht no khng to lin kt hiro vi nc? A. CH3CH3. B. CH3CH2OH. C. NH3. D. HF. 46.C bao nhiu kiu lin kt hiro gia cc phn t H2O? A. 1. B. 2. C. 3. D. 4. 47.Lin kt hiro gia cc phn t no sau y l bn vng nht? D. CH3COOH. A. CH3CH2OH. B. CH3CH2NH2. C. H2O. 48.Axit flo hiric yu hn axit clohiric v A. flo m in hn clo. B. HF nh hn HCl. C. lin kt hiro ca HF bn hn ca HCl. D. HF phn cc mnh hn HCl. 98. Cc cht H2O, CH3OH, HCHO, HCOOH, C2H5OH. CH3COOH c nhit si tng ng k hiu l s1, s2, s3, s4, s5, s6. Nu xp nhit si tng dn t u n cui th c trt t sau A. s2, s4, s3, s1, s6, s5. B. s3, s2, s5, s1, s4, s6. C. s1, s2, s3, s4, s5, s6. D. s3, s2, s4, s1, s6, s5. 99. Hp kim no di y ca nhm tan hon ton trong dung dch axit clohiric? A. uyra. B. Silumin. C. Almelec. D. Eletron. P N 1. A 2. D 3. A 4. A 5. A 6. A 7. C 8. A 9. D 10. A 11. A 12. C 13. D 14. C 15. A 16. B 17. D 18. C 19. D 20. A 21. C 22. B 23. C 24. A 25. C 26. D 27. A 28. D 29. A 30. C 31. A 32. B 33. A 34. C 35. C 36. B 37. C 38. C 39. C 40. B 41. C 42. B 43. B 44. C 45. A 46. A 47. D 48. C 49. B 50. D
S : 18
Cau 1. Ion M2+ co tong so hat la 34. Vay so khoi cua M co gia tr: a. 11 b. 23 c. 24 d. 25 Cau 2. X+ co tong so hat la 57, Y la nguyen to thuoc chu k nho ke can lien tiep vi X, cung nhom vi X, vay Y la: a. ong b. Clo c. Natri d. Flo Cau 3.Cho ptp Mg + HNO3 Mg(NO3)2 + NH4NO3 + H2O. Tong he so (cac so nguyen nho nhat) cua cac chat trong ph. ng la a. 20 b. 22 c. 24 d. 26
2NH3 H < 0 Cau 4 Cho ptp tong hp NH3 sau: 2N2 + 3 H2

e tang hieu suat phan ng ta phai: (1) Tang nong o cua N2, H2. (2) Giam nong o cua NH3. (3) Bo sung chat xuc tac (4) Tang ap suat. a. (1), (3),(4), (6) b. (1), (2), (4), (6). (5). Giam ap suat. (6). Tang nhiet o. (7). Giam nhiet o c. (1), (3), (4), (7). d. ( 1), (2), (4) (7).
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Cau 5. Cho 400 ml dung dch HCl (pH = a) phan ng vi 500 ml dung dch NaOH co pH = 13. Co can dung dch thu c chat ran co khoi lng 2,37 gam. Gia tr a nhan la: a. 1,3. b. 1 c. 0,994. d. 0,996. Cau 6. Trong dung dch co the ton tai ong thi cac ion sau: a. NH4+, Cl-, Na+, OH-, NO3-. b. CH3COO-, K+, NO3--, OH--, NH4+. 2-+ -c. CO3 , Na , OH , HS d. Na+, Ca2+, Fe3+, NO3--, Cl-. Cau 7. Bon bnh cha cac dd HF, HBr, HCl, HI co the dung thuoc th nao sau ay e phan biet : a. Giay quy. b. Ho tinh bot. c. Dung dch AgNO3. d. Dung dch phenol phtalein. Cau 8. Cho mot kimloai M tac dung vi dung dch HNO3 sinh ra hon hp hai kh ( NO va kh A) co t khoi so vi Hiro la : 14.75. Vay kh A la: b . N2 c. NH3 d. NO2 a. H2 Cau 9. Cho Fe vao dung dch AgNO3. Sau phan ng chat ran con lai ch co 1 kim loai duy nhat M va dung dch A. Cho axit HCl (d) tiep tuc vao th thay co kh B thoat ra, thu c ket tua C va dung dch D. Vay kim loai M , va kh B, ket tua C va muoi trong dung dch D la: thoat ra la: a. (Fe), ( H2), (AgCl), (FeCl3). b. (Ag), (NO), (AgCl),(FeCl3) c. (Ag), (H2,NO), (AgCl),(FeCl2) d. (Fe), (NO),(Fe(OH)2),(AgNO3 va Fe(NO3)2). Cau 10. Mang tinh the kim loai gom: a. Cac nguyen t kim loai nut mang, gia cac nut mang la am may electron t do. b. Cac ion dng co nh cac nut mang va cac electron t do chuyen ong xung quanh ion dng. c. Cac ion dng dao ong lien tuc nut mang va cac electron t do chuyen ong hon loan gia cac ion dng. d. Cac nguyen t kim loai va cac electron lien ket vi nhau bang lien ket kim loai. Cau 11. Hon hp A nang 14,3g gom K va Zn tan het trong nc d cho ra dung dch ch cha mot chat duy nhat la muoi. Xac nh khoi lng cua moi kim loai trong hon hp (K = 39, Zn =65). a. 7,8gK ; 6,5g Zn. b. 6,5gK va 7,8gZn. c. 4,2gK ; 10,1g Zn. d. 5,8gK va 8,5gZn. Cau 12. Cho t t 200 ml dung dch HCl 3M that cham vao 400 ml dung dch gom Na2CO3 1M va NaHCO3 1M. va khoay eu. The tch kh thoat ra ktc la: a. 4,48lt. b. 13.44 lt c. 8,96 lt d. 2,24 lt Cau 13. Cac chat nao sau ay co the lam mem nc cng vnh cu. b. HCl, CaCl2. a. Ca(OH)2 va u, Na2CO3. c. K2CO3 ; Na3PO4. d, HCl va Na2CO3. Cau 14. Cho 4,48 gam Fe phan ng vi dung dch H2SO4 ac, nong thay thoat ra 672cm3 kh ( ktc). Vay khoi lng chat ran con lai sau phan ng. a. 3,36g b. 1.68g c.2,8 g. d. 3,92g. e 3 Cau 15. Cho m gam hon hp gom: Mg, Fe, Al phan ng het vi HCl; thu c 0,896 lt H2 (kc) va 5,856 gam hh muoi . Vay m co the bang a.3,012 b.3,016 c.3,018 d. 3,102 Cau 16. Tm nhan nh ung: a. Al tac dung c vi dung dch axit va dung dch baz nen Al la kim loai lng tnh. b. Khi cho Al tac dung vi dung dch NaOH , Al la chat kh, NaOH la chat oxi hoa. c. Al(OH)3 co tnh baz. d. Khi suc kh NH3 vao dung dch AlCl3 th thu c ket tua, sau o ket tua tan ra. Cau 17. Phan tch mot hp chat hu c thay co 0,72gam Cacbon; 0,2 gam Hiro ; 0,56 gam Nit. Cong thc Phan t trung vi cong thc n gian nhat cua hp chat hu c la: a . C 3 H5 N b. C3H10N2. c. C4H5N. d.C2H7N2. Cau 18. Tm phat bieu sai a. Xycloankan la hydrocacbon no b. ankin la hydrocacbon co hai lien ket c. Ch co anken ot chay th mol CO2 = mol H2O d. Trung hp isopren cho caosu t nhien. Cau 19. Tach nc hai ru lien tiep ch thu c mot anken duy nhat, vay A va B la: a. CH3OH ,C2H5OH. b.ru etylic ruu n-propylic. c .Ru n propylic va ru butylic d. ru tert-butylic , n-propylic Cau 20. ot chay hoan toan 0.5 mol ru no th can ung 40 gam O2. Ru o la: a. C2H5OH. b. C2H4(OH)2. c. C3H5(OH)3 d. C3H7OH. Cau 21. Mot dan xuat hirocac bon thm co CTPT C7H8O. So ong phan cua hp chat nay co the la: a. 3 b. 4 c. 5 d. 6
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Cau 22. Tnh chat nao sau ay khong phai cua axit fomic. (1). Chat long khong mau. (5). P vi oxit kim loai. (2). Co mui ac trng. (6). The hien tc cua este. (3). t tan trong nc. (7). P vi Cu(OH)2, to tao tua o gach. (4). p vi ru. (8) co tnh chat cua anehit. a. 3,6. b. 2, 3, 6,8 c. 3,5,6,7 d. 1,2,4,5. Cau 23. Hon hp 23.8 gam hai ru A, B n chc tac dung vi Na d giai phong 5,6 lt kh (ktc). Oxi hoa 23,8 gam 2 ru tren thu c mgam 2 anehit. m/2 gam anehit nay co kha nang tao c toi a 75,6g Ag khi p vi AgNO3/NH3 d. Cong thc phan t cua hai ru. a. CH3OH va C3H7OH. b. C3H5OH va CH3OH d. C2H5OH va CH3OH. c. C2H5OH va C3H7OH. Cau 24. ieu che 300 gam dung dch CH3COOH 25% th phai can bao nhieu gam gao ( cha 80% tinh bot). Biet hieu suat cua moi phan ng at 75%. a. 135gam b. 150 gam. c. 240g d. 300g Cau 25. Este nao sau ay sau khi thuy phan trong dung dch NaOH cho 3 muoi. b. C2H5COOC6H5. a. CH3COOCCl2CH3. c. CH3COOCH2C6H5. d. C2H5COOCCl(OH)CH3. Cau 26. Thuy phan hoan toan 1 mol este n chc X trong NaOH. San pham cua phan ng tham gia phan ng vi dung dch Cu(OH)2 khi un nong thay tao c 288 gam ket tua. Vay este X la: a. CH3COOCH=CH2. b. HCOOCH=CH2-CH3. d. HCOOC(Cl)=CH-CH3. c. HCOOCH2CH3. Cau 27. Khi un nong lipit vi dung dch H2SO4 loang thu c: a. Glixerin va axit beo. b. H2O,etylen glicol va axit beo. c. Glixetin va xa phong. d. Etylen glicol va axit beo. Cau 28. Dung dch nao sau ay khong lam oi mau quy tm: a. Axit - amino petandioic. b. axit - diamino propionic. c. axit lactic. d. axit - amino iso valeric. Cau 29. Co cac phat bieu sau ve protit: Phat bieu ung la: (1) Protit la hp chat cao phan t thien nhien co cau truc phc tap. (2) Protit co trong c the ngi va ong vat. (3) C the ngi va ong vat khong the tong hp c protit t nhng chat hu c ma ch tong hp c t cac aminoaxit. (4) Protit ben oi vi nhiet, axit va kiem. a. (1) , (2). b. (2), (3). c. (1), (3). d. (3), (4). Cau 30. Nhan xet nao sau ay la ung ve s giong nhau gia Glucoz va saccarozo. (1). eu hoa tan c Cu(OH)2 nhiet o thng. (2). eu co trong cu cai ng, va ma. (3). eu tham gia phan ng trang gng. (4). eu c s dung trong y hoc lam huyet thanh ngot. a. (1). b. (1), (2) c. (1), (2), (3). d. (1), (2), (4). Cau 31. Kh Glucoz e tao thanh sorbitol. Khoi lng cua glucoz e tao ra 1.82 gam socbitol vi hieu suat 80% la bao nhieu gam? a. 2,25 gam. b. 1.14gam c. 22.5 gam d. 14.4 gam. Cau 32. Phan ng hoa hoc nao sau ay ieu che t capron. to a. nH2N-CH2-COOH (-HN-CH2 C - )n + nH2O. O CH3 CH3 xt , t o b. nCH2=C (-CH2-C - )n COOCH3 COOCH3. to c. nH2N-(CH2)6-NH2 + nHOOC- (CH2)4-COOH [-HN-(CH2)6-NH-C (CH2)4 C - ]n + 2nH2O. O O d. CH2 CH2 CH2 to , p n C = O [-C (CH2)5-NH-]n CH2 CH2 NH O Cau 33. Cho m gam Cu vao 500 ml dung dch Cu(NO3)2 0,3M va HCl 0,5M th thay tan bt 40% so vi khoi lng cua Cu ban au. Khoi lng cua m la:
20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
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Cau 35.Cap chat nao sau ay co the cung ton tai ieu kien thng: 1. Cl2 va H2S. 2. Na2CO3 + H2SO4. a. ( 2, 3, 4, 5).
a. 15 gam b. 36gam c. 24,4gam d. 8gam. Cau 34. Cho cac dung dch sau ay: Na2CO3, BaCl2, H2SO4, AlCl3, FeCl3 Ch bang mot thuoc th duy nhat nao sau ay co the nhan biet c tat ca cac chat tren. (1) Quy tm. (2) NaOH. (3). Ba(OH)2 a. (1) hoac (2). b. (1) hoac (3). C. (2) hoac (3). d. (1) hoac (2) hoac 3.
20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
Cau 36. Cho phan ng sau: A + B AB . Hoi neu tang nong o cua A, B len hai lan th toc o phan ng tang len 32 lan. Vay bang: a. 2 b. 3 c. 4 d. 5
3. SO2 va O2 5. Fe + H2SO4 ac. 4. SO2 va O3 6. FeO + H2SO4 ac. b. ( 3, 5). c. ( 1, 2, 3, 6)
d. ( 2, 4, 5).
Cau 37. Hoa tan 10,8 gam Al trong H2SO4 va u thu c dung dch A. Tnh the tch cua dung dch NaOH 0,5M phai them vao dung dch A e co c ket tua sau khi nung en khoi lng khong oi cho ra mot chat ran co khoi lng 10,2 gam. a. 1.2 lt va 2,8 lt b. 1,2 lt c. 0.6 lt va 1.6 lt
o
d. 1,2 lt va 1,4 lt.
Cau 38. e ieu che HI ngi ta dung phan ng nao trong cac phan ng hoa hoc sau: 1. HCl + KI HI + KCl. t (3). H3PO4 + 3KI 3HI + K3PO4.
o
t (2)H2 + I2 2HI. t (4) H2SO4 ac + 2 KI 2HI + K2SO4.

o
a. 1,2
b. 2, 4
c. 2.
d. 3,4
Cau 39. e ieu che ra chat sinh han ( Freon) th tien hanh : a. The Metan. b. Phan huy Benzen. c. Crackinh propan. d.Thuy phan Canxicacbua. Cau 40. e ieu che T.N.T th : a. Nitro hoa sau o metyl hoa. b. Metyl hoa sau o trinitro hoa. c. Metyl hoa sau o nitro hoa. d. Ankyl hoa sau o nitro hoa. Cau 41. Mot lt con 92o tac dung vi Na d. Biet dR = 0,8g/ml. The tch cua H2 tao ra la: a. 224lt b. 224,24 lt c. 228,98 lt d. 179,2lt. Cau 42. Bon ong nghiem ng cac hon hp sau: (1). Benzen + phenol. (3). Anilin + dung dch NaOH, (2). Anilin + ddH2SO4 lay d. (4). Anilin + H2O. Cho biet trong ong nghiem nao co s tach lp. a. 1,2,3. b. 4 c. 3,4 d. 1.3,4 Cau 43. Hon hp gom 2 amin no n chc ong ang lien tiep phan ng va u vi 0,1 lt dung dch H2SO4 1M cho ra mot hon hp 2 muoi co kl17,4g. Xac nh CTPT va khoi lng moi amin. a. 4,5g C2H5-NH2 va 2,8g C3H7-NH2. b. 3,1 gam CH3-NH2 va 4,5 g C2H5-NH2. c. 1,55g CH3-NH2 va 4,5g C2H5-NH2. d. 3,1g CH3-NH2 va 2,25g C2H5-NH2.
CH3COOH + C2H5OH. e thu c nhieu ancol ta Cau 44. Trong phan ng thuy phan sau:CH3COOC2H5 + H2O
nen:(1) them H2SO4. (2). Them HCl (3). Them NaOH. (4) Them H2O. Ta thc hien phng phap nao? a. (1,2) b. (3,4) c.(3) d. (4). Cau 45. Tron 6,48g Al vi 16 gam Fe2O3 . Thc hien phan ng nhiet nhom c chat ran A. Cho A tac dung vi dung dch NaOH d co 2,688 lt kh H2 ( ktc) thoat ra. Vay H.suat cua phan ng la: a. 100% b. 85% c. 80% d. 75% Cau 46. Hon hp X gom Fe2O3 va FeO va MgO co khoi lng 4,24 gam trong o co 1,2gam MgO. Khi cho X phan ng vi CO d ( phan ng xay ra hoan toan) ta c chat ran A va hon hp CO va CO2. Hon hp kh nay qua 350ml dd nc voi trong 0,1M tao ra 2 gam ket tua. Khoi lng cua Fe2O3 va FeO trong hon hp la: a. 0,8g Fe2O3 va 1,44g FeO. b. 1,6g Fe2O3 va 0,72g FeO. c. 1,6g Fe2O3 va 1,44 g FeO. d. 0,8g Fe2O3 va 0,72g FeO. Cau 47. Cho cac phan ng sau: 1. Zn + Cu2+ Zn2+ + Cu. 3. Cu + Fe2+ Cu2+ + Fe. 2+ 2+ + 2. Cu + Pt Cu + Pt. 4. Pt + 2H Pt2+ + H2. Phan ng nao co the xay ra theo chieu thuan.
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a. (1), (2). b. (3), (4) c. (1),(2),(3). d. (2), (3). Cau 48. Xicloankan co cong thc phan t la C6H12. Khi cho A the mono Clo 2 san pham the khac nhau. CTCT cua A la: CH3 a. b. c. d. CH3 CH3 CH3 CH3 CH3 Cau 49. Khi cac chat cho cot (1 ) cho tien hanh the mono clo trong k kien anh sang va sp chnh cho cot (2). Hay ghep ung chat ban au va san pham tng ng. (1). n butan. (a). 3 clo pentan. (2). iso butan. (b). 2 clo 2 metyl butan. (3). iso pentan. (c). 2 clo butan. (d). 1- clo butan. (e). 2- clo-2-metyl propan. a. . (1-c; 2-e; 3-b). b. ( 1 c; 2-d; 3-a). c. (1-d; 2-c; 3-a). d.(1-c; 2-e, 3 a). Cau 50. ot chay hoan toan hon hp X gom hai hirocacbon mach h cung day ong ang hap thu hoan toan san pham vao 1,8 lt dung dch Ca(OH)2 0,05M thu c ket tua va khoi lng cua dung dch tang 3.78 gam. Cho Ba(OH)2 d vao dug dch thu c ket tua va tong khoi lng ket tua cua hai lan la 18.85 gam. Hay ong ang cua hai hirocacbon co the la day nao sau ay: (1). Ankan. (2). Anken. (3). Ankin (4). Ankaien. (5). Hirocacbon thm. (6). Xicloankan. a. 1 b. (2,3). c.(3), (4), (5) d. (3, 4).
20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
ap so : 1. C 2. C 3. B 4. D 5. A 6. D 7. C 8. B 9. B 10. C 11. A 12. A 13. C 14. C 15. B 16. C 17. B 18. C 19. A 20. B 21. C 22. A 23. B 24. D 25. D 26. C 27. A 28. D 29. A 30. B 31. A 32. D 33. A 34. D 35. B 36. C 37. A 38. C 39. D 40. B 41. C 42. D 43. B 44. C 45. C 46. C 47. A 48. D 49. A 50. C
S : 19
100.
Ha tan 9,14 gam hp kim Cu, Mg, Al bng mt lng va dung dch HCl thu c 7,84 lt kh X (ktc) v 2,54 gam cht rn Y v dung dch Z. Lc b cht rn Y, c cn cn thn dung dch Z thu c lng mui khan l A. 31,45 gam. B. 33,99 gam. C. 19,025 gam. D. 56,3 gam. 101. Ho tan hon ton m gam Al vo dung dch HNO3 rt long th thu c hn hp gm 0,015 mol kh N2O v 0,01mol kh NO (phn ng khng to NH4NO3). Gi tr ca m l A. 13,5 gam. B. 1,35 gam. C. 0,81 gam. D. 8,1 gam 102. Hp cht hu c X, mch h (cha C, H, N), trong nit chim 23,73% v khi lng. Bit X tc dng vi HCl vi t l s mol nX : nHCl = 1: 1. Cng thc phn t ca X l A. C2H7N. B. C3H7N. C. C3H9N. D. C4H11N. 103. t chy 6 gam este X thu c 4,48 lt CO2 (ktc) v 3,6 gam H2O. X c cng thc phn t no di y? A. C5H10O2. B. C4H8O2. C. C3H6O2. D. C2H4O2. 104. Cho hai mui X, Y tha mn iu kin sau: X + Y khng xy ra phn ng X + Cu khng xy ra phn ng
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Y + Cu khng xy ra phn ng X + Y + Cu xy ra phn ng X, Y l mui no di y? A. NaNO3 v NaHCO3. B. NaNO3 v NaHSO4. D. Mg(NO3)2 v KNO3. C. Fe(NO3)3 v NaHSO4. 105. Cho hn hp gm Fe v FeS tc dng vi dung dch HCl d thu c 2,24 lt hn hp kh iu kin tiu chun. Hn hp kh ny c t khi so vi hiro l 9. Thnh phn % theo s mol ca hn hp Fe v FeS ban u ln lt l A. 40% v 60%. B. 50% v 50%. C. 35% v 65%. D. 45% v 55%. 106. Cho m gam Cu phn ng ht vi dung dch HNO3 thu c 8,96 lt (ktc) hn hp kh NO v NO2 c khi lng l 15,2 gam. Gi tr ca m l A. 25,6 gam. B. 16 gam. C. 2,56 gam. D. 8 gam. 107. Pht biu no di y khng ng v bn cht qu trnh ho hc in cc trong khi in phn? A. Anion nhng electron anot. B. Cation nhn electron catot. C. S oxi ho xy ra anot. D. S oxi ha xy ra catot. 108. Hai este A, B l dn xut ca benzen c cng thc phn t l C9H8O2. A v B u cng hp vi brom theo t l mol l 1 : 1. A tc dng vi dung dch NaOH cho mt mui v mt anehit. B tc dng vi dung dch NaOH d cho 2 mui v nc, cc mui u c phn t khi ln hn phn t khi ca CH3COONa. Cng thc cu to ca A v B ln lt l cc cht no di y? A. HOOCC6H4CH=CH2 v CH2=CHCOOC6H5 B. C6H5COOCH=CH2 v C6H5CH=CHCOOH C. HCOOC6H4CH=CH2 v HCOOCH=CHC6H5 D. C6H5COOCH=CH2 v CH2=CHCOOC6H5 109. Hn hp X gm hai kim loi A v B ng trc H trong dy in ha v c ha tr khng i trong cc hp cht. Chia m gam X thnh hai phn bng nhau: - Phn 1: Ha tan hon ton trong dung dch cha axit HCl v H2SO4 long to ra 3,36 lt kh H2. - Phn 2: Tc dng hon ton vi dung dch HNO3 thu c V lt kh NO (sn phm kh duy nht). Bit cc th tch kh o ktc. Gi tr ca V l A. 2,24 lt. B. 3,36 lt. C. 4,48 lt. D. 6,72 lt. 110. Ha tan hon ton hn hp X gm 0,4 mol FeO v 0,1mol Fe2O3 vo dung dch HNO3 long, d thu c dung dch A v kh B khng mu, ha nu trong khng kh. Dung dch A cho tc dng vi dung dch NaOH d thu c kt ta. Ly ton b kt ta nung trong khng kh n khi lng khng i thu c cht rn c khi lng l A. 23,0 gam. B. 32,0 gam. C. 16,0 gam. D. 48,0 gam. 111. Cho cc cht: CH3NH2, C6H5NH2, (CH3)2NH, (C6H5)2NH v NH3. Trt t tng dn tnh baz (theo chiu t tri qua phi) ca 5 cht trn l A. (C6H5)2NH, NH3, (CH3)2NH, C6H5NH2, CH3NH2 B. (C6H5)2NH, C6H5NH2, NH3, CH3NH2, (CH3)2NH C. (C6H5)2NH, NH3, C6H5NH2, CH3NH2, (CH3)2NH D. C6H5NH2, (C6H5)2NH, NH3, CH3NH2, (CH3)2NH. 112. Ho tan hon ton 19,2 gam Cu bng dung dch HNO3, ton b lng kh NO thu c em oxi ho thnh NO2 ri chuyn ht thnh HNO3. Th tch kh oxi (ktc) tham gia vo qu trnh trn l gi tr no di y? A. 1,68 lt. B. 2,24 lt. C. 3,36 lt. D. 4,48 lt. 113. Cho kh CO i qua ng s cha 16 gam Fe2O3 un nng, sau phn ng thu c hn hp rn X gm Fe, FeO, Fe3O4, Fe2O3. Ha tan hon ton X bng H2SO4 c, nng thu c dung dch Y. C cn dung dch Y, lng mui khan thu c l A. 20 gam. B. 32 gam. C. 40 gam. D. 48 gam. 114. Thu phn C4H6O2 trong mi trng axit thu c hn hp hai cht u c phn ng trng gng. Cng thc cu to ca C4H6O2 l
A. H3C C O CH CH2 O C. H C O CH CH CH3 O
B. H C O CH2 CH CH2 O D. H2C HC C O CH3 O
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115.
Mn: ho hc
Nm hc 2010-2011
C 4 dung dch khng mu ng trong 4 l mt nhn: NaCl, MgCl2, AlCl3, FeCl2. C th dng kim loi no di y phn bit 4 dung dch trn (khng c s dng thm thuc th khc)? A. Na. B. Al. C. Fe. D. Ag. 116. Trong phng th nghim, kh CO2 c iu ch t CaCO3 v dung dch HCl thng b ln kh hiro clorua v hi nc. thu c CO2 gn nh tinh khit ngi ta dn hn hp kh ln lt qua hai bnh ng cc dung dch no trong cc dung dch di y. A. NaOH, H2SO4 c. B. NaHCO3, H2SO4 c. D. H2SO4 c, Na2CO3. C. Na2CO3, NaCl . 117. un nng 0,1 mol cht X vi lng va dung dch NaOH thu c 13,4 gam mui ca axit hu c a chc B v 9,2 gam ancol n chc D. Cho ton b lng ancol D bay hi 127oC v 600 mmHg s chim th tch 8,32 lt. Cng thc ca cht X l A. CH(COOCH3)3 B. H3COOCCH2CH2COOCH3 C. C2H5OOCCOOC2H5 D. C3H5OOCCOOC3H5 118. Cho s phn ng sau:
+ dd AgNO3 / NH 3 + Cl 2 , as + NaOH, t + CuO, t Toluen X Y Z T 1 :1
o o
Bit X, Y, Z, T l cc hp cht hu c v l nhng sn phm chnh. Cng thc cu to ng ca T l A. C6H5COOH. B. CH3C6H4COONH4. C. C6H5COONH4. D. pHOOCC6H4COONH4. 119. Theo nh ngha axit-baz ca Bronstet, cc cht v ion thuc dy no di y l lng tnh? A. CO32, CH3COO. B. ZnO, Al2O3, HSO4, NH4+. + C. NH4 , HCO3 , CH3COO . D. ZnO, Al2O3, HCO3, H2O. 120. t chy hon ton 0,1 mol hn hp hai axit cacboxylic l ng ng k tip thu c 3,36 lt CO2 (ktc) v 2,7 gam H2O. S mol ca mi axit ln lt l A. 0,05 mol v 0,05 mol. B. 0,045 mol v 0,055 mol. C. 0,04 mol v 0,06 mol. D. 0,06 mol v 0,04 mol. 121. Cho cc ion kim loi sau: Fe3+, Fe2+, Zn2+, Ni2+, H+, Ag+. Chiu tng dn tnh oxi ha ca cc ion l A. Zn2+, Fe2+, H+, Ni2+, Fe3+, Ag+. B. Zn2+, Fe2+, Ni2+, H+, Fe3+, Ag+. C. Zn2+, Fe2+, Ni2+, H+, Ag+, Fe3+. D. Fe2+, Zn2+, Ni2+, H+, Fe3+, Ag+. 122. Ho tan 25 gam CuSO4.5H2O vo nc ct c 500ml dung dch A. Gi tr gn ng pH v nng mol ca dung dch A l B. pH > 7; [CuSO4] = 0,3125M. A. pH = 7; [CuSO4] = 0,20M. C. pH < 7; [CuSO4] = 0,20M. D. pH > 7; [CuSO4] = 0,20M. 123. T l v s nguyn t ca 2 ng v A v B trong t nhin ca mt nguyn t X l 27 : 23. Trong ng v A c 35 proton v 44 ntron, ng v B c nhiu hn ng v A l 2 ntron. Nguyn t khi trung bnh ca nguyn t X l gi tr no di y? A. 79,92. B. 81,86. C. 80,01. D. 76,35. 124. Cht hu c X mch h, tn ti dng trans c cng thc phn t C4H8O, X lm mt mu dung dch Br2 v tc dng vi Na gii phng kh H2. X ng vi cng thc phn t no sau y? A. CH2=CHCH2CH2OH. B. CH3CH=CHCH2OH. C. CH2=C(CH3)CH2OH. D. CH3CH2CH=CHOH. 125. Khi pha long dung dch CH3COOH 1M thnh dung dch CH3COOH 0,5M th A. in li tng. B. in li gim. C. in li khng i. D. in li tng 2 ln. 126. Anion X2 c cu hnh electron lp ngoi cng l 3s23p6. Tng s electron lp v ca X2 l bao nhiu? A. 18. B. 16. C. 9. D. 20. 127. Cho 7,28 gam kim loi M tc dng hon ton vi dung dch HCl, sau phn ng thu c 2,912 lt kh H2 27,3oC; 1,1 atm. M l kim loi no di y? A. Zn. B. Mg. C. Fe. D. Al. 128. Khi t chy polime X ch thu c kh CO2 v hi nc vi t l s mol tng ng l 1 : 1. X l polime no di y?
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Mn: ho hc
Nm hc 2010-2011
A. Polipropilen (PP). B. Tinh bt. C. Poli(vinyl clorua) (PVC). D. Polistiren (PS). 129. Ancol X mch h c s nguyn t cacbon bng s nhm chc. Cho 9,3 gam ancol X tc dng vi Na d thu c 3,36 lt kh. Cng thc cu to ca X l A. CH3OH. B. CH2OHCHOHCH2OH. C. CH2OHCH2OH D. C2H5OH. 130. Trong mt chu k, theo chiu tng dn ca in tch ht nhn A. bn knh nguyn t gim dn, tnh kim loi tng dn. B. bn knh nguyn t gim dn, tnh phi kim tng dn. C. bn knh nguyn t tng dn, tnh phi kim tng dn. D. bn knh nguyn t tng dn, tnh phi kim gim dn. 131. t chy hai hirocacbon l ng ng lin tip ca nhau ta thu c 6,3 gam nc v 9,68 gam CO2. Cng thc phn t ca hai hirocacbon l A. C2H4 v C3H6. B. CH4 v C2H6. C. C2H6 v C3H8. D. Tt c u sai. 132. Ch dng mt thuc th no di y phn bit c etanal (anehit axetic), propan-2-on (axeton) v pent-1-in (pentin-1)? A. Dung dch brom. B. Dung dch AgNO3/NH3 d. C. Dung dch Na2CO3. D. H2 (Ni, to). 133. Cho phn ng sau: FeS + H2SO4 Fe2(SO4)3 + SO2 + H2O H s cn bng ca H2SO4 trong phng trnh ha hc l A. 8. B. 10. C. 12. D. 4. 134. Trong cc phng php lm mm nc, phng php ch kh c cng tm thi ca nc l A. phng php ha hc (s dng Na2CO3, Na3PO4). B. un nng nc cng. C. phng php lc. D. phng php trao i ion. 135. t chy hon ton hn hp hai amin bc mt, mch h, no, n chc, k tip nhau trong cng dy ng ng thu c CO2 v H2O vi t l s mol n CO2 : n H 2O = 1: 2 . Hai amin c cng thc phn t ln lt l B. C2H5NH2 v C3H7NH2. A. CH3NH2 v C2H5NH2. C. C3H7NH2 v C4H9NH2. D. C4H9NH2 v C5H11NH2. 136. in phn 1 lt dung dch NaCl d vi in cc tr, mng ngn xp ti khi dung dch thu c c c pH = 12 (coi lng Cl2 tan v tc dng vi H2O khng ng k, th tch dung dch thay i khng ng k), th th tch kh thot ra anot (ktc) l bao nhiu? A. 1,12 lt. B. 0,224 lt. C. 0,112 lt. D. 0,336 lt. 137. Khi t chy hon ton mt este X cho n CO2 = n H 2O . Thy phn hon ton 6,0 gam este X cn va dung dch cha 0,1 mol NaOH. Cng thc phn t ca este l A. C2H4O2. B. C3H6O2. C. C4H8O2. D. C5H10O2. 138. un nng 27,40 gam CH3CHBrCH2CH3 vi KOH d trong C2H5OH, sau khi phn ng xy ra hon ton thu c hn hp kh X gm hai olefin trong sn phm chnh chim 80%, sn phm ph chim 20%. t chy hon ton X thu c bao nhiu lt CO2 (ktc)? A. 4,48 lt. B. 8,96 lt. C. 11,20 lt. D. 17,92 lt. 139. C bao nhiu ng phn cu to ca amin c cng thc phn t C3H9N? A. 2. B. 3. C. 4. D. 5. 140. Cho dy chuyn ha sau:
Br2 (dd ) 2 4 CH 3CH 2CHOHCH 3 E F H SO , 170oC
Bit E, F l sn phm chnh, cc cht phn ng vi nhau theo t l 1:1 v s mol. Cng thc cu to ca E v F ln lt l cp cht trong dy no sau y? A. CH3CH2CH=CH2, CH3CH2CHBrCH2Br. B. CH3CH=CHCH3, CH3CHBrCHBrCH3. C. CH3CH=CHCH3, CH3CH2CBr2CH3. D. CH3CH2CH=CH2, CH2BrCH2CH=CH2. 141. Phn t khi trung bnh ca PVC l 750.000. H s polime ha ca PVC l
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20 B THI TH I HC
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Nm hc 2010-2011
A. 12.000. B. 15.000. C. 24.000. D. 25.000. 142. Oxi ho 2,2 gam mt anehit n chc X thu c 3 gam axit tng ng (hiu sut phn ng bng 100%). X c cng thc cu to no di y? A. CH3CHO. B. C2H5CHO. D. CH3CH2CH2CHO. C. CH3CH(CH3)CHO. 143. Cho dung dch cha a mol Ca(HCO3)2 vo dung dch cha a mol Ca(HSO4)2. Hin tng quan st c l A. si bt kh. B. vn c. C. si bt kh v vn c. D. vn c, sau trong tr li. 144. Th tch dung dch HCl 0,3M cn trung ho 100ml dung dch hn hp NaOH 0,1M v Ba(OH)2 0,1M l A. 100 ml. B. 150 ml. C. 200 ml. D. 250 ml. 145. Hp th hon ton 4,48 lt SO2 (ktc) bng 0,3 mol NaOH. Khi lng mui khan thu c l A. 20,8 gam. B. 23,0 gam. C. 31,2 gam. D. 18,9 gam. 146. Kh hon ton 17,6 gam hn hp X gm Fe, FeO, Fe2O3 cn 2,24 lt CO ( ktc). Khi lng st thu c l A. 5,6 gam. B. 6,72 gam. C. 16,0 gam. D. 11,2 gam. 147. Cho hn hp X gm hai anehit l ng ng k tip tc dng ht vi H2 d (Ni, to) thu c hn hp hai ancol n chc. t chy hon ton hn hp hai ancol ny thu c 11 gam CO2 v 6,3 gam H2O. Cng thc ca hai anehit l A. C2H3CHO, C3H5CHO. B. C2H5CHO, C3H7CHO. C. C3H5CHO, C4H7CHO. D. CH3CHO, C2H5CHO. 148. Etilen c ln cc tp cht SO2, CO2, hi nc. C th loi b tp cht bng cch no di y? A. Dn hn hp i qua bnh ng dung dch brom d. B. Dn hn hp qua bnh ng dung dch natri clorua d. C. Dn hn hp ln lt qua bnh ng dung dch NaOH d v bnh ng CaO. D. Dn hn hp ln lt qua bnh ng dung dch brom d v bnh ng dung dch H2SO4 c. 149. Cho 2,84 gam hn hp X gm hai ancol n chc, l ng ng k tip nhau tc dng va vi Na to ra 4,6 gam cht rn v V lt kh H2 (ktc). V c gi tr l A. 2,24 lt. P N 19: 1. A 2. B 3. C 4. D 5. B B. 1,12 lt. 6. B 7. A 8. D 9. D 10. A C. 1,792 lt. 11. D 12. B 13. C 14. C 15. C 16. A 17. B 18. C 19. C 20. D D. 0,896 lt. 21. A 22. B 23. C 24. A 25. B 26. A 27. A 28. C 29. A 30. C 31. B 32. C 33. B 34. B 35. B 36. A 37. C 38. A 39. D 40. C 41. B 42. A 43. A 44. C 45. A 46. B 47. C 48. D 49. C 50. D
S : 20
150.
Trong mt cc nc c cha a mol Ca , b mol Mg2+, c mol Cl, d mol HCO3. Biu thc lin h gia a, b, c, d l A. a + b = c + d. B. 3a + 3b = c + d.
2+
C. 2a + 2b = c + d.
D.
1 (a + b) = c + d. 2
Cho cc ion v nguyn t: Ne (Z=10), Na+ (Z=11), F (Z=9) c c im no sau y l chung A. s khi. B. s proton. C. s electron. D. s ntron. 152. Dung dch dm n thng l A. Dung dch axit axetic 0, 1% n 0, 3%. B. Dung dch axitmetanoic 2% n 4%. C. Dung dch axit acrylic 2% n 3%. D. Dung dch axit etanoic 2% n 5%. 153. A, B l cc kim loi hot ng ha tr (II), thuc hai chu k lin tip trong bng tun hon. Ha tan hn hp gm 23, 5 gam mui ccbonat ca A v 8, 4 gam mui cacbonat ca B bng dung dch HCl d sau c cn v in phn nng chy hon ton th thu c 11,8 gam hn hp kim loi catot v V lt kh anot. Hai kim loi A, B l A. Be v Mg. B. Mg v Ca. C. Sr v Ba. D. Ba v Ra. 154. Hy sp xp cc cp xi ha kh sau y theo th t tng dn tnh oxi ha ca cc ion kim loi: (1): Fe2+/Fe; (2): Pb2+ /Pb; (3): 2H+/ H2; (4): Ag+/Ag;
151.
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(5): Na+/Na; (6): Fe3+/Fe2+; (7): Cu2+/Cu. A. (5) < (1) < (2) < (3) < (7) < (6) < (4). B. (4) < (6) < (7) < (3) < (2) < (1) < (5). C. (5) < (1) < (6) < (2) < (3) < (4) < (7). D. (5) < (1) < (2) < (6) < (3) < (7) < (4). 155. Mt anehit c cng thc thc nghim l (C4H4O3)n. Cng thc phn t ca anehit l A. C2H2O3. B. C4H4O3. C. C8H8O6. D. C12H12O9. 156. Cho s chuyn ha sau: A + HCl B + D B + Cl2 F E + NaOH H + NaNO3 A + HNO3 E + NO + D B + NaOH G + NaCl G + I + D H Cc cht A, G, H l B. FeO, Fe(OH)2 v Fe(OH)3. A. CuO, CuOH v Cu(OH)2. C. PbO, PbCl2 v Pb(OH)4. D. Cu, Cu(OH)2 v CuOH. 157. Khi cho 17, 4 gam hp kim Y gm st, ng, nhm phn ng ht vi H2SO4 long d ta thu c dung dch A; 6, 4 gam cht rn; 9, 856 lt kh B 27, 3C v 1 atm. Phn trm khi lng mi kim loi trong hp kim Y l A. Al 30%, Fe 50% v Cu 20%. B. Al 30%, Fe 32% v Cu 38%. C. Al : 31,03%, Fe 32,18% v Cu 36,78%. D. Al 25%, Fe 50% v Cu 25%. 158. Cho hn hp Y gm 2,8 gam Fe v 0,81 gam Al vo 200 ml dung dch C cha AgNO3 v Cu(NO3)2. Khi phn ng kt thc, thu c dung dch D v 8,12 gam cht rn E gm 3 kim loi. Cho bit cht rn E tc dng vi dung dch HCl d th thu c 0,672 lt kh H2 ktc. Nng mol ca AgNO3 v Cu(NO3)2 trong dung dch C l A. 0,075M v 0,0125M. B. 0,3M v 0,5M. C. 0,15M v 0,25M. D. kt qu khc. 159. C 100 ml dung dch hn hp 2 axit H2SO4 v HCl c nng tng ng l 0,8M v1,2M. Thm vo 10 gam bt hn hp Fe, Mg, Zn. Sau phn ng xong, ly 1/2 lng kh sinh ra cho i qua ng s ng a gam CuO nung nng. Sau phn ng xong hon ton, trong ng cn li 14,08 gam cht rn. Khi lng a l A. 14,2 gam. B. 16,32 gam. C. 15,2 gam. D. 25,2 gam. 160. Nguyn t X thuc chu k 4 nhm VI, phn nhm ph c cu hnh e l B. 1s22s22p63s23p63d104s24p4. A. 1s22s22p63s23p63d64s2. C. 1s22s22p63s23p63d104s24d4. D. 1s22s22p63s23p63d54s1. 161. Cho bit sn phm chnh ca phn ng kh nc ca (CH3)2CHCH(OH)CH3? A. 2-metylbuten-1. B. 3-metyl buten-1. C. 2-metylbuten-2. D. 3-metyl buten-2. 162. Cho bit s ng phn no ca ru no, n chc t C3 n C5 khi tch nc khng to ra cc anken ng phn: A. C3H7OH : 2 ng phn; C4H9OH : 3 ng phn; C5H11OH : 3 ng phn. B. C3H7OH : 1 ng phn; C4H9OH : 4 ng phn; C5H11OH : 4 ng phn. C. C3H7OH : 3 ng phn; C4H9OH : 4 ng phn; C5H11OH : 3 ng phn. D. C3H7OH : 2 ng phn; C4H9OH : 3 ng phn; C5H11OH : 4 ng phn. 163. Trong dy ng ng ca ru n chc no, khi mch cacbon tng, ni chung A. si tng, kh nng tan trong nc tng. B. si tng, kh nng tan trong nc gim. C. si gim, kh nng tan trong nc tng. D. si gim, kh nng tan trong nc gim. 164. Hy sp xp cc cht sau y theo trt t tng dn tnh baz: p-X-C6H5-NH2 (cc dn xut ca anilin) vi X l (I)NO2, (II)CH3, (III)CH=O, (IV)H. A. I < II < III < IV.B. II < III < IV < I. C. I < III < IV < II. D. IV < III < I < II. 165. Nhit phn 1,88 gam Cu(NO3)2 ri hp th ton b lng kh sinh ra bng H2O thu c 2 lt dung dchA. Tip tc thm vo 100 ml dung dch X : 0,023 gam Na c dung dch B. pH ca dung dch A v B ln lt l A. 7-12,7. B. 2-7. C. 3-11. D. 2,2-12.
20 B THI TH I HC
Mn: ho hc
Nm hc 2010-2011
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Nm hc 2010-2011
Xt cc loi hp cht hu c mch h sau: Ru n chc, no (A); anehit n chc, no (B); ru n chc khng no 1 ni i (C), anehit n chc, khng no 1 ni i (D). ng vi cng thc tng qut CnH2nO ch c 2 cht sau: A. A, B. B. B, C. C. C, D. D. A, D. 167. t chy mt hn hp cc cht thuc dy ng ng anehit thu c s mol CO2 bng s mol H2O th l dy ng ng A. Anehit n chc no, mch h. B. Anehit vng no. C. Anehit hai chc no. D. Anehit khng no n chc 1 lin kt i. 168. Hp cht hu c X khi un nh vi dung dch AgNO3/NH3 (d) thu c sn phm Y, Y tc dng vi dung dch HCl cho kh v c A, vi dung dch NaOH ho kh v c B. X l A. HCHO. B. HCOOH. C. HCOONH4. D. C A, B, C u ng. 169. Cho 13,6 gam mt hp cht hu c X (C,H,O) tc dng va vi 300 ml dung dch AgNO3 2M trong NH4OH thu c 43,2 gam bc. Bit t khi hi ca X i vi oxi bng 2,125. Xc nh cng thc cu to ca X. A. CH3CH2CHO. B. CH2=CHCH2CHO. C. HCCCH2CHO. D. HCCCHO. 170. B tc phn ng sau: FeO + H+ + SO42 SO2 + A. FeSO4 + H2O. B. Fe2(SO4)3 + H2O. C. FeSO4 + Fe2(SO4)3 + H2O. D. Fe3+ + H2O. 171. Phn ng gia dung dch Kali pemanganat trong mi trng axit vi ion iodua c biu din bng phng trnh no di y? A. 2MnO4 + 5I +16H+ 2Mn2+ + 8H2O + 5I2 B. MnO4 + 10I +2H+ Mn2+ + H2O + 5I2 + 11e C. 2MnO4 + 10I- +16H+ 2Mn2+ + 8H2O + 5I2 D. MnO4 + 2I +8H+ Mn2+ + 4H2O + I2 172. Sp xp cc cht sau y theo trnh t gim dn nhit si: CH3COOH (1), HCOOCH3 (2), CH3CH2COOH (3), CH3COOCH3 (4), CH3CH2CH2OH (5). A. (3) > (5) > (1) > (2) > (4). B. (1) > (3) > (4) > (5) > (2). C. (3) > (1) > (4) > (5) > (2). D. (3) > (1) > (5) > (4) > (2). 173. C 4 l ng 4 dung dch mt nhn l AlCl3, NaNO3, K2CO3, NH4NO3. Nu ch c php dng mt dung dch mt cht lm thuc th nhn bit th c th chn A. dd NaOH. B. dd H2SO4. C. dd Ba(OH)2. D. dd AgNO3. 174. Hai cht A v B cng c CTPT C9H8O2, cng l dn xut ca benzen, u lm mt mu dung dch nc Br2. A tc dng vi dung dch NaOH cho 1 mui v 1 anehit, B tc dng vi dung dch NaOH cho 2 mui v nc. Cc mui sinh ra u c khi lng phn t ln hn M ca CH3COONa. A v B tng ng l A. CH2=CHCOOC6H5 ; HCOOC6H4CH=CH2. B. C6H5COOCH=CH2 ; CH2=CHCOOC6H5. C. HCOOCH=CHC6H5 ; HCOOC6H4CH=CH2. D. C6H5COOCH=CH2 ; HCOOC6H4CH = CH2. 175. Hn hp X gm 0,01 mol HCOONa v a mol mui natri ca hai axit no n chc l ng ng k tip. t chy hn hp X v cho sn phm (CO2, H2O)ln lt qua bnh 1 ng H2SO4c, bnh 2 ng KOH d, thy khi lng bnh 2 tng nhiu hn bnh 1 nhiu hn bnh mt l 3,51 gam. Phn cht rn Y cn li sau khi t l Na2CO3 cn nng 2,65 gam. Cng thc phn t ca hai mui natri l A. CH3COONa, C2H5COONa. B. C3H7COONa, C4H9COONa. C. C2H5COONa, C3H7COONa. D. kt qu khc. 176. T bo quang in c ch to t kim loi no trong cc kim loi sau: A. Na. B. Ca. C. Cs. D. Li. 177. Thy phn este E c cng thc phn t C4H8O2 vi xc tc axit v c long, thu c 2 sn phm hu c X, Y(ch cha nguyn t C, H, O). T X c th diu ch trc tip ra Y bng mt phn ng duy nht. Cht X l A. axit axetic. B. Ru etylic. C. Etyl axetat. D. Axit fomic.
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20 B THI TH I HC
178.
Mn: ho hc
Nm hc 2010-2011
C 2 hp cht hu c X, Y cha cc nguyn t C, H, O khi lng phn t u bng 74. Bit X tc dng c vi Na, c X, Y u tc dng c vi dung dch NaOH v dung dch AgNO3 trong NH3. Vy X, Y c th l A. C4H9OH v HCOOC2H5. B. CH3COOCH3 v HOC2H4CHO. C. OHCCOOH v C2H5COOH. D. OHCCOOH v HCOOC2H5. 179. Cht no khng phn ng c vi Cu(OH)2: B. HOCH2CH2OH. A. CH3COOH. C. HOCH2CH2CH2OH. D. CH3CHO. 180. Cho s chuyn ha sau: 1. C3H4O2 + NaOH (A) + (B) 2. (A) + H2SO4 long (C) + (D) 3. (C) + AgNO3 + NH3 + H2O (E) + Ag +NH4NO3 4. (B) + AgNO3 + NH3 + H2O (F) + Ag +NH4NO3 Cc cht (B) v (C) theo th t c th l A. CH3CHO v HCOONa. B. CH3CHO v HCOOH. C. HCHO v HCOOH. D. HCHO v CH3CHO. 181. Hon thnh s phn ng sau: CH2 = CH2 + KMnO4 + H2O A. C2H4(OH)2 + MnO2 + KOH. B. CH3CHO + MnO2 + KOH. C. CH3COOK + MnO2 + KOH. D. C2H5OH + MnO2 + KOH. 182. So snh nhit si ca cc cht sau: Ru etylic (1), etylclorua (2), etan(3), axit axetic (4) A. (1) > (2) > (3) > (4). B. (4) > (3) > (2) > (1). C. (4) > (1) > (2) > (3). D. (1) > (2) > (3) > (4). 183. Cho cc dung dch: X1: dung dch HCl, X2: dung dch KNO3, X3: dung dch HCl + KNO3, X4: dung dch Fe2(SO4)3. Dung dch no c th ha tan c bt Cu? A. X1, X4, X2. B. X3, X4. C. X1, X2, X3, X4. D. X3, X2. 184. Crckinh 5,8 gam C4H10 thu c hn hp sn phm X gm H2 v 6 hirocacbon. t chy 1/2 hn hp X th lng H2O thu c l A. 13, 5 gam. B. 9 gam. C. 6,3 gam. D. 4,5 gam. 185. Theo nh ngha v axit-baz cc nhm phn t sau y c xc nh ng: A. Nhm phn t NH4+, SO42, NO3 c tnh axit. B. Nhm phn t HCO3, S2, Al3+ c tnh baz. C. Nhm phn t HCO3, Cl, K+ c tnh trung tnh. D. Nhm phn t HCO3, H2O, HS, Al(OH)3 c tnh lng tnh. 186. Ngi ta c th dng thuc th theo th t nh th no d nhn bit 3 kh : N2, SO2, CO2? A. Ch dng dung dch Ca(OH)2. B. Dng dung dch nc vi trong sau dng dung dch KMnO4. C. Dng dung dch Br2 sau dng dung dch NaHCO3. D. C B v C. 187. Cho Fe c Z = 26. Hi Fe2+ c cu hnh nh th no? A. 1s22s22p63s23p63d44s2. B. 1s22s22p43s23p63d6. 2 2 6 2 6 5 1 C. 1s 2s 2p 3s 3p 3d 4s . D. p n khc. 188. A l mt este to bi ankanol v mt axit n chc, khng no mch h cha mt lin kt i. Cng thc phn t tng qut ca A phi l A. CxH2x-4O2 (x4). B. CxH2x-2O2 (x4). C. CxH2xO2(x4). D. CxH2x-4O2 (x3). 189. Hp cht A n chc c cng thc phn t l C4H8O2. S ng phn ca A l A. 5. B. 7. C. 4. D. 6. 190. Trn 3 dung dch H2SO4 0,1M; HCl 0,2 M; HNO3 0,3M vi th tch bng nhau c dung dch A. Cho 300 ml dung dch A tc dng vi V ml dung dch B cha NaOH 0,2 M v Ba(OH)2 0,1M c dung dch C c pH=1. Gi tr ca V l A. 0,24 lt. B. 0,08 lt. C. 0,16 lt. D. 0,32 lt.
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191.
Mn: ho hc
Nm hc 2010-2011
t chy hon ton 2,22 gam mt hp cht hu c X thu c 5,28 gam CO2 v 2,7 gam H2O. X phn ng c vi Na, khng phn ng vi dung dch NaOH. Tm Cng thc phn t ca X v cho bit tt c cc ng phn cng nhm chc v khc nhm chc ca X ng vi cng thc trn? A. C3H8O, c 4 ng phn. B. C4H10O v 6 ng phn. C. C2H4(OH)2, khng c ng phn. D. C4H10O c 7 ng phn. 192. Hon thnh phng trnh phn ng h hc sau: SO2 + KMnO4 + H2O Sn phm l A. K2SO4, MnSO4. B. MnSO4, KHSO4. C. MnSO4, KHSO4, H2SO4. D. MnSO4, K2SO4, H2SO4. 193. Cho 1,365 gam mt kim loi kim M tan hon ton vo nc thu c mt dung dch ln hn khi lng nc ban u l 1,33 gam. Kim loi M dng l A. Na. B. K. C. Cs. D. Rb. 194. Ha tan hon ton 2,175 gam hn hp 3 kim loi Zn, Mg, Fe vo dung dch HCl d thy thot ra 1,344 lt H2 (ktc). Khi c cn dung dch ta thu c bao nhiu gam mui khan? A. 6,555. B. 6,435. C. 4,305. D. 4,365. 195. trung ha 200 ml dung dch aminoaxit M 0,5M cn 100 gam dung dch NaOH 8%, c cn dung dch sau phn ng c 16, 3 gam mui khan. M c cng thc cu to l A. H2NCH2COOH. B. H2NCH(COOH)2. C. H2NCH2CH(COOH)2. D. (H2N)2CHCOOH. + 196. Cho dung dch cha cc ion sau (Na , Ca2+, Mg2+, Ba2+, H+, Cl). Mun tch c nhiu cation ra khi dung dch m khng a ion l vo dung dch, ta c th cho dung dch tc dng vi cht no trong cc dung dch sau: A. Dung dch KHCO3 va . B. Dung dch Na2SO4 va . C. Dung dch NaOH va . D. Dung dch Na2CO3 va . 197. Hp cht hu c C4H7O2Cl khi thy phn trong mi trng kim c cc sn phm trong c hai cht c kh nng trng gng. Cng thc cu to ng l A. HCOOCH2CHClCH3. B. CH3COOCH2Cl. C. C2H5COOCHClCH3. D. HCOOCHClCH2CH3. 198. Trong qu trnh in phn, cc ion m di chuyn v A. cc m v b in cc kh. B. cc dng v b in cc kh. C. cc dng v b in cc oxi ha. D. cc m v b in cc oxi ha. 199. Cho 2, 24 lt CO2 vo 20 lt dung dch Ca(OH)2, thu c 6 gam kt ta. Nng ca dung dch Ca(OH)2 dng l A. 0,003M. B. 0,0035M. C. 0,004M. D. 0,003M hoc 0,004M.Cho hn hp X gm hai anehit l ng ng k o tip tc dng ht vi H2 d (Ni, t ) thu c hn hp hai ancol n chc. t chy hon ton hn hp hai ancol ny thu c 11 gam CO2 v 6,3 gam H2O. Cng thc ca hai anehit l A. C2H3CHO, C3H5CHO. B. C2H5CHO, C3H7CHO. D. CH3CHO, C2H5CHO. C. C3H5CHO, C4H7CHO. 200. Etilen c ln cc tp cht SO2, CO2, hi nc. C th loi b tp cht bng cch no di y? A. Dn hn hp i qua bnh ng dung dch brom d. B. Dn hn hp qua bnh ng dung dch natri clorua d. C. Dn hn hp ln lt qua bnh ng dung dch NaOH d v bnh ng CaO. D. Dn hn hp ln lt qua bnh ng dung dch brom d v bnh ng dung dch H2SO4 c. 201. Cho 2,84 gam hn hp X gm hai ancol n chc, l ng ng k tip nhau tc dng va vi Na to ra 4,6 gam cht rn v V lt kh H2 (ktc). V c gi tr l A. 2,24 lt. P N 20: 1. C 2. C 3. D 4. B 5. A B. 1,12 lt. 6. B 7. B 8. C 9. C 10. B 11. D 12. C 13. A 14. B 15. C C. 1,792 lt. 16. B 17. B 18. A 19. D 20. C 21. D 22. A 23. D 24. C 25. B D. 0,896 lt. 26. C 27. C 28. B 29. D 30. C 31. B 32. A 33. C 34. B 35. D 36. D 37. B 38. B 39. B 40. D 41. B 42. D 43. D 44. B 45. B 46. B 47. D 48. D 49. C 50. C
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TRNG AI HOC DUY TAN A NANG

(Lu hnh ni b 20102010-2011)

Sinh Vin : PHAN S TN Lp : K16KKT3

( Bin Son +Su Tm )

H2 (k) + CO2 (k) H2O (k) + CO (k)

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15. Tong hp hu c: (6).

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11. B 12. B 13. A 14. D 15. B

16. D 17. B 18. B 19. C 20. A

21. D 22. B 23. A 24. C 25. D

26. A 27. C 28. A 29. A 30. B

31. A 32. C 33. A 34. B 35. C

36. B 37. A 38. D 39. A 40. B

41. A 42. D 43. D 44. A 45. B

46. D 47. A 48. A 49. A 50. D

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