Bi 1

A B C D

So snh nhit nng chy v tan trong nc ca etylamin v glixin NH2-CH2-COOH Glixin c nhit nng chy cao hn nhiu so vi etylamin. c hai u tan nhiu trong nc. C hai cht c nhit nng chy gn ngang nhau v u c 2 C v c hai u tan nhiu trong nc. Glixin c nhit nng chy thp hn etylamin. Glixin tan t cn etylamin tan nhiu trong nc. C hai cht c nhit nng chy thp v u t tan trong nc. Hp cht hu c X mch h, trong phn t ch cha C, H, N, trong N chim 23,73% khi lng phn t X. X tham gia phn ng vi HCl theo t l 1:1 v s mol. X c cng thc phn t v s ng phn l C2H7N vi 2 ng phn. C3H9N vi 4 ng phn. C3H7N vi 4 ng phn. C4H11N vi 8 ng phn. A l -amino axit (c cha 1 nhm - NH2).t chy 8,9 gam A bng Oxi va c 13,2 g CO2;6,3 gam nc v 1,12 lt N2 (ktc) A c cng thc phn t l: C2H5NO2 C3H7NO2 C4H9NO2 C5H9NO2 Cho hn hp gm 3 amino axit no,mi cht ch cha mt nhm amin v 1 nhm axit tham gia phn ng to lin kt peptit th s hp cht ch c 1 lin kt peptit l: 3 4 9 6 Chn trnh t tin hnh no trong cc trnh t sau phn bit dung dch cc cht : CH3NH2, H2NCH2COOH, CH3COONH4, anbumin. Dng qu tm, dng dung dch HNO3 c, dng dung dch NaOH. Dng qu tm, dng Cu(OH)2. Dng Cu(OH)2, dng phenolphtalein, dng dung dch NaOH. Dng qu tm, dng dung dch CuSO4, dng dung dch NaOH. Sp xp cc hp cht sau theo th t gim dn tnh baz. (1) C6H5NH2 (2) C2H5NH2 (3) (C6H5)2NH (4) (C2H5)2NH (5) NaOH (6) NH3 Dy no sau y c th t sp xp ng? 1> (3) > (5) > (4) > (2) > (6) (6) > (4) > (3) > (5) > (1) > (2) (5) > (4) > (2) > (1) > (3) > (6) (5) > (4) > (2) > (6) > (1) > (3) Cho s chuyn ha: Alanin X Y Vy cht Y l:

Bi 2
A B C D

Bi 3
A B C D

Bi 4
A B C D

Bi 5
A B C D

Bi 6

A B C D

Bi 7

A B C D

CH3CH(NH2)COOCH3 CH3CH(OH)COOCH3 CH3CH(NH2)COONa CH3CH(OH)COONa X l mt amino axit t nhin. Bit 0,01 mol X tc dng va vi 0,01 mol HCl to mui Y. Lng Y sinh ra tc dng va vi 0,02 mol NaOH to 1,39 gam mui hu c Z. Vy X l: Axit aminoaxetic Axit -aminopropionic Axit -aminoisovaleric Axit -aminoglutaric Chn phng n tt nht phn bit cc dd glixerol, glucoz, anilin, alanin, anbumin. Dng Cu(OH)2 ri un nng nh, sau dng dd Br2 Dng ln lt cc dung dch CuSO4, H2SO4, I2 Dng ln lt cc dung dch AgNO3, NH3, CuSO4, NaOH Dng ln lt cc dung dch HNO3, NaOH, H2SO4 t chy hon ton hn hp hai amin bc mt, mch h, no, n chc, k tip nhau trong cng dy ng ng thu c CO2 v H2O vi t l s mol 1 : 2 . Hai amin c cng thc phn t ln lt l CH3NH2 v C2H5NH2. C2H5NH2 v C3H7NH2. C3H7NH2 v C4H9NH2. C4H9NH2 v C5H11NH2 t chy mt amin n chc no thu c t l s mol nCO2 : nH2O = 4/7. Amin cho c tn gi no di y? Metylamin Etylamin Trimetylamin Isopropylamin C bao nhiu ng phn cu to ca amin c cng thc phn t C3H9N? 2 3 4 5 trung ha hon ton 0,90 gam hn hp 2 amin no, n chc bc mt c t l s mol l 1 : 1 cn dng 2 lt hn hp dung dch axit HCl v H2SO4 c pH = 2. Vy cng thc ca 2 amin l: CH3NH2 v C2H5NH2 CH3NH2 v C3H7NH2 C2H5NH2 v C3H7NH2 C2H5NH2 v C4H9NH2 t chy hon ton m gam mt amin X bng lng khng kh va thu c 17,6 gam CO2,

Bi 8
A B C D

Bi 9
A B C D

Bi 10
A B C D

Bi 11
A B C D

Bi 12
A B C D

Bi 13
A B C D

Bi 14

A B C D

12,6 gam H2O v 69,44 lt kh nit. Gi thit khng kh ch gm nit v oxi trong oxi chim 20% th tch. Cc kh o iu kin tiu chun. Amin X c cng thc phn t l: C4H9NH2 C3H7NH2 CH3NH2 C2H5NH2 Aminoaxit X cha mt nhm chc Amin bc 1 trong phn t. t chy hon ton mt lng X thu c CO2 v N2 theo t l th tch l 4:1. X l hp cht no sau y: H2NCH(NH2) COOH H2NCH2COOH H2N CH2 CH2 COOH Tt c u sai Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l: H2NC4H8COOH H2NC3H6COOH H2NC2H4COOH H2NCH2COOH Bc ca amin c xc nh bng s nguyn t H ca phn t NH3 b thay th. s gc hidrccbon lin kt vi nguyn t nit. bc ca nguyn t ccbon lin kt vi chc amin. s nguyn t nit c trong phn t. C th phn bit cc bc ca amin bng thuc th: o CuO, t KMnO4/H2SO4 NaNO2/HCl K2Cr2O7/H2SO4 Cho 41,5 gam hn hp gm 3 amin no, n chc l ng ng k tip nhau tc dng va vi dung dch HCl 1,0 M. C cn dung dch sau phn ng thu c 78 gam hn hp mui. Cng thc phn t ba amin l: CH5N, C2H7N, C3H9N C2H7N, C3H9N, C4H11N C2H5N, C3H7N, C4H9N C6H7N, C7H9N, C8H11N Cho X l cht hu c. Kh X bng hiro nguyn t mi sinh th thu c cht hu c Y. Y l hp cht cha mt nhm chc, c tnh baz, c t khi so vi hiro bng 29,5. Cng thc phn t ca X l: C6H5NO2 CH3NO2

Bi 15
A B C D

Bi 16
A B C D

Bi 17
A B C D

Bi 18
A B C D

Bi 19
A B C D

Bi 20
A B

C D

C2H5NO2 C3H7NO2 Cho anilin tc dng vi dung dch nc brom 3% (khi lng ring l 1,3 g.ml ). Th tch nc brom ti thiu cn iu ch 33 gam 2,4,6-tribromanilin l: 1,32 lt 1,03 lt 1,23 lt 1,30 lt Trong cc protein sau y, protein no tn ti dng hnh cu: Anbumin Miozin Fibroin Keratin Cho s chuyn ha sau: CH3CH(NH2)COOH X Y X, Y, Z l cc cht hu c. Cng thc cu to ca Z l: CH3CH2COOCH3 CH3COOCH=CH2 CH2=CHCOOCH3 CH3COOCH2CH3 Cho cc cht sau: (1) H2NCH2COOH ; (2) H2NCH2CH2COOH ; (3) C6H5CH2CH(NH2)COOH ; (4) HOOCCH2CH(NH2)CH2COOH ; (5) H2N[CH2]4CH(NH2)COOH. Nhng cht thuc loi amino axit l: (1) ; (3) ; (4) ; (5) (1) ; (2) ; (3) (1) ; (3) ; (5) (1) ; (2) ; (3) ; (4) Cho s chuyn ha sau: X (C3H7O2N) + Fe + HCl X1 X1 + HCl X2 X2 + NaOH X1 Bit X1 mch thng. Cng thc cu to ca X l: CH2=CHCOONH4 CH3CH2CH2NO2 H2NCH2COOCH3 CH3CH(NH2)COOH Cho 1 mol amino axit X phn ng vi dung dch HCl d, thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH d, thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l: C5H9O4N C4H10O2N2 Z.
-1

Bi 21
A B C D

Bi 22
A B C D

Bi 23

A B C D

Bi 24
A B C D

Bi 25

A B C D

Bi 26
A B

C D

C5H11O2N C4H8O4N2 Pht biu no sau y khng ng l: + Trong dung dch, H2NCH2COOH cn tn ti dng ion lng cc H3N CH2COO Aminoaxit l hp cht hu c tp chc,phn t cha ng thi nhm amino v nhm cacboxyl Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt Hp cht H2NCH2COOH3NCH3 l este ca glyxin (Gly) un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l: H2N-CH2-COOH, H2H-CH2-CH2-COOH H3N -CH2-COOHCl , H3N -CH2-CH2-COOHCl H3N -CH2-COOHCl , H3N -CH(CH3)-COOHCl H2N-CH2-COOH, H2N-CH(CH3)-COOH X l mt -amino axit c cha vng thm v mt nhm NH2 trong phn t. Bit 50 ml dung dch X phn ng va vi 80 ml dung dch HCl 0,5M, dung dch thu c phn ng va vi 50 ml dung dch NaOH 1,6M. Mt khc nu trung ha 250 ml dung dch X bng lng va KOH ri em c cn thu c 40,6 gam mui. CTCT ca X l: C6H5-CH(CH3)-CH(NH2)COOH. C6H5-CH(NH2)-CH2COOH. C6H5-CH(NH2)-COOH. C6H5-CH2CH(NH2)COOH. Hin tng no sau y m t khng chnh xc ? Phn ng gia metylamin v kh Hidroclorua xut hin khi trng Nhng qu tm vo dd etylamin thy qu tm chuyn mu xanh. Nh vi git nc brom vo ng nghim ng dd anilin thy c kt ta trng Thm vi git Phenolphtalein vo dd imetylamin thy xut hin mu xanh Hp cht no sau y khng phi l hp cht lng tnh ? Amoni axetic Axit -amino propionic Alanin Glixerin Cng thc tng qut ca cc amino axit l cng thc no sau y ? NH2 - CxHy - COOH (NH2) - R - (COOH) (NH2)x (COOH)y (NH2)x - R - (COOH)y Hn hp M gm hai cht CH3COOH v NH2CH2COOH. trung ho m gam hn hp M cn 100ml dung dch HCl 1M. Ton b sn phm thu c sau phn ng li tc dng va vi 300ml dung dch NaOH 1M. Thnh phn phn trm theo khi lng ca cc cht CH3COOH v NH2CH2COOH trong hn hp M ln lt l (%)
+ + + + -

Bi 27
A B C D

Bi 28
A B C D

Bi 29

A B C D

Bi 30
A B C D

Bi 31
A B C D

Bi 32
A B C D

Bi 33

A B C D

72,80 v 27,20. 40,00 v 60,00. 44,44 v 55,56. 61,54 v 38,46. Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung dch Y cha (m + 30,8) gam mui . Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha (m + 36,5) gam mui. Gi tr ca m l: 112,2 171,0 165,6 123,8 Trong cc cht etyl axetat, anilin, ancol etylic, axit acrylic, phenylamoni clorua, ancol benzylic, pcresol, phenol. S cht tc dng c vi KOH l: 3 4 5 6 Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin; 1 mol alanin v 1mol valin. Khi thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly; GlyAla v tripeptit Gly-Gly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l Ala, Gly. Ala, Val Gly, Gly. Gly, Val Mui A c cng thc l C3H10O3N2, ly 7,32 gam A phn ng ht vi 150ml dd KOH 0,5M. C cn dd sau phn ng th c phn hi v phn cht rn, trong phn hi c 1 cht hu c bc 3, trong phn rn ch l cht v c. Khi lng cht rn l: 11,52 g 6,90 g 6,06 g 9,42 g Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l: 0,50 0,65 0,70 0,55 Cho 0,1 mol cht X c cng thc phn t C2H8O3N2 tc dng vi dung dch cha 0,2 mol NaOH un nng thu c kh lm xanh qu m v dung dch Y. C cn dung dch Y thu c m gam cht rn khan. Gi tr ca m l: 12,5

Bi 34
A B C D

Bi 35
A B C D

Bi 36
A B C D

Bi 37
A B C D

Bi 38
A B C D

Bi 39
A

B C D

15 5,7 21,8 Cho cc dung dch ring bit cha cc cht: anilin (1), metylamin (2), glixin (3), axit glutamic (4), axit 2,6- iaminohexanoic (5), H2NCH2COONa (6). Cc dung dch lm qu tm ho xanh l: (1), (2). (2), (5), (6). (2), (5). (2), (3), (6).

Bi 40
A B C D

1 A 21 C

2 B 22 A

3 B 23 C

4 C 24 C

5 A 25 B

6 D 26 A

7 B 27 D

8 C 28 C

9 A 29 D

10 A 30 D

11 B 31 D

12 C 32 D

13 B 33 C

14 D 34 A

15 B 35 C

16 D 36 D

17 A 37 B

18 C 38 B

19 A 39 A

20 D 40 B