Solutions Manual to Accompany Basic Principles and Calculations _ in Chemical Engineering SIXTH EDITION David M. Himmelblau University of Texas ay vukh Noe VY O82 Poly. lOr4 Prentice Hall PTR: Upper Saddle River, New Jersey 07458», TYPICAI, ASSIGNMENTS FOR ONE SEI Problem A: ments First Class meeting. No assignments UNIT AND DIMENSIONS 14, 1.6, 1,7, 1.8 DIMENSIONAL CONSISTENCY: MOLE HIS. 1.20, 1.21, 1.31. 1.43 METHODS OF ANALYSIS AND MEASUREMENT. 1.39, 1.43, 1.47, 1.52 : ‘ BASIS: TEMPERATURE 1.60. 1.62. 1.63) 1.68, 1.70 PRESSURE 1.90, 1.91, 1.93,.1,94 | STOICHIOMETRY 1.1060. e: 1.112, 1,122, 1.125 PROBLEM SOLVING 2.1, 2.4, 2.8 COMPUTER USAGE. Sart on Pl, P2, and P3 Exam No.1. | No formal class meeting - Work on computer assignments: No class meeting, - continue working on computer assignments. Class meets turn in computer problems plus the eval ion form. ANALYSIS OF MATERIAL BALANCE PROBLEMS 3.12, 3.13, 3.19, 3.20 MATERIAL BALANCE PROBLEMS (NO REACTION) 3.21, 3.23, 3.24 NO a eae NES oa | A RR re ER All_assignmen the 6th cd dy S 1.6 18, 1.9 Handouts outs 31 32 3324, 25. 26. a7 28, 29. 31. Problem Assignments MATERIAL BALANCE PROBLEMS (NO REACTION) 3.27, 3.36, 3.37 MATERIAL BALANCE PROBLEMS (WITH REACTION) 3.56, 3.57, 3.58 MAT IAL BALANCE PROBLEMS (WITH REACTION) 3.60, 3.63 Exam No. 2 MAT UNITS, 3.71, 3.72 AL BALANCE PROBLEMS WITH MULTIPLE MATERIAL BALANCE PROBLEMS WITH RECYCLE, (NO REACTION) 3.86, 3.87 MATERIAL BALANCE PROBLEMS WITH RECYCLE (WITH REACTION) fy OS ae: | IDEAL GAS AND PARTIAL PRESSURE, 4.1, 4.2, 4.9, 4.18¢, 4.25 | MATERIAL BALANCES WITH IDEAL GASES 4.27, 4.28, 4.37 COMPRESSIBILITY 4,39, 4.40, 4.41, 4.45 EQUATIONS OF STATE. fl Ss GAS MIXTURES; VAPOR PRESSURE 4.50, 4.08, 4.70, 4.730 Exam No. 3. SATURATION 4.83, 4.84, 4,86 EQUILIBRIA 4.88, 4.90, 4.93signmen the 6th edi nid nents : : Problem Assig 7 PARTIAL SATURATION AND HUMIDITY 4.106, 4.110 16 u MATERIAL BALANCES INVOLVING PARTIAL SATURATION ALIG, 4.117, 4.118 47 M Exam Nod. : a5. ENERGY; CONCEPTS, JARGON, AND UNITS e Se 57312) 516, Sale 36. THE ENERGY BALANCE, 5.13 ab; 5:29 a,b; 571 5.12 v ENTHALPY CHANGE! 5.30, 5.34, 5.36, 5.40, 5.43 52 38 SOLVING ENERGY BALANCE PROBLEMS WITHOUT REACTIONS-CLOS| s 5 5.63, 5.64, 5.67 5.3 39, Exam No. § 40. SOLVING ENERGY BALANCE PROBLEMS WITHOUT REACTIONS-OPEN SYSTEMS i 5.74, 5.75, 5.78 $s ae 41 OLVING ENERGY BALANCE PROBLEMS WITH REACTIONS 5.92, 5.96b, 5.97, 5.104 (do (1) only) 54-1 42. CONTINUED 5.109, 5,123 54-2 43 ADIABATIC FLAME TEMPERATURE 5.4 Exinple 5.25 44, FINAL EXAM IS ON CHAPTER 5 ONLY[Exar No. 1 (Open Book, 1 1/2 hours) PROBLEM 1 (5%) Hydrogen can be separated from natural gas by diffusion through a round tube. The : i rale of separation is given by | : N=2ndDpR where = rate of transport of Hp from the tube, ¢ moles/(sec)(cm of length of tube) ' D = diffusion coefficient p = molar density of Ha, g moles /cm3 \ R= log mean radius of tube, ro -r1/ én | with r in cm, What are the units of D? PROBLEM 2 (10%) | A pallet of boxes weighing 10 tons is dropped from a lift truck from a height of 10 fect. The maximum velocity the pallet attains before hitting the ground is 6 ft/sec. How much kinetic energy does the pallet have in (ft)(Ibp at this velocity? PROBLEM 3 (5%) The specific gravity of a fuel oil is 0,82. What is the density of the oil in Ib/ {82 Show all units. PROBLEM 4 (10%) Sulfur trioxide (SO3) can be absorbed in sulfuric acid solution to form more concentrated sulfuric acid. If the gas to be absorbed contains 55% SO, 41% Nz, 3% $02, and 1% Oz, how many parts per million of O2 are there in the gas? (b) What is the composition of the gas on a No free basis? PROBLEM 5 (15%) You have 100 kilograms of gas of the following composition: Cl, 30% i ‘ Hz 10% | Nz 60% What is the average molecular weight of this gas?PROBLEM 6 (15%) \ the heat capacity of a stibstance is $37 JABICC) and its molecular weight is 47 4, what is its heat capacity in ) J/@ eR) ©) J/Ab)(eR) © — J/gmonky ss, PROBLEM 7 (20%) A tock containing 100% BaSO4 is burned with coke (04% 6% ash) and the composition of the produet is BaSO, (11.1%) Bos (72.9%), CU13.9%, Ash (2.2%). The teadtion is | | BASO, +40 massac Caleulate the percent exce: IN Od The Beaiec i cauyplenun ie the reaction PROBLEM 8 (20%) A gas cylinder to which is attached an Bourden gage appears to he ata Pressure of 27.38'in. Hg at 70°F. the Barometer needs 101.8 kPa. A student claime that the Procure th the tank 1511.3 bsia, bul another Student points out that this i¢ impossible + the pressure is really 28.2 Psia. Can 1.3 psia bo correct? Explain and show calculations to back Up your explanation. EXAM No, 2 (Open Book, 2 hours) A chemist attempts to Prepare some very pure crystals of Na2504-101420 hy Missolving 200 of NagSO4 (MolWt=142.05) in 400 g of boiling water. He then Gelully cools the solution slowly unit Some Na2804-10H120 crystallizes out Calculate the g of Na2SO4-10Hoq Hee Gar 1 MS cesta por 100-6 or initia folution, if the residual solution afier the crystals are removed coniaing 28% Nayso, Right answer but: —10 if answer is in B -10 if answer not of Na2S04 and not p per 100 g of ini of NazSO41011.0 solnPROBLEM 2 (25%) | a Water pollution in the Hudson River has claimed considerable recent attention, especially pollution from sewage outlets and industrial wastes. To determine accurately how much effluent enters the river is quite difficult because to catch and weigh the material is impossible, weirs are hard to construct, ele. One suggestion which had been offered is to add a trace Br ion to a given sewage stream, let it mix well, and sample the sewage stream after it mixes well. On one test of the propsal you add ten pounds of NaBr per hour for 24 hours to a scwage stream with essentially no Bro in it. Somewhat downstream of the introduction point a.sampling of the sewage stream shows 0.012% Nabr. The sewage density is 60.3 Ib/{O and river water densily is 62.4 Ib/ its. What is the flow rate of the sewage in Ib/min? ~10 if answer based ~15 if 24 hr basis on 0.012 fractin and was used and not 0.00012. then not converted back to per hour basis PROBLEM 3 (25%) Ss < ; In preparing 5.00 moles of a mixture of three gases (SOr, H2S, and C32), gases from three tanks are combined into a fourth tank. The tanks have the following, compositions (mole fractions): Gas Tank 1 Tank2 Tank3 Tank 4 SQ 0.10 0.20 0.25 0.20 125 0.40 0.20 0.25 0.26 CS 0.50 0.60 0.50 han 0.94 How much of Tanks 1, 2, and 3 must be mixed lo give a product with composition of Tank4? =10 for correct answer but ~15 A lot of people said no wrong basis soln. They used wrong, basis, etc. No soln but correct mat'l balance |PROBLEMA4(25%) 10% a) For the given a the bottoms stream, 15% b) If stenm leaked into the column at 1000 mole/sec and all else was Scents What would the new baltoms composition be? “3 Ghoul be g-mole), iF assumed to k-mole and not sted Carling Wafer Distillate = 7 CON EtOH Feed= 100 ky fore 40% Hoo eco h Hy 10% E40H Whe Yo of bead. o% Ho TO" Hy ee Steam am No. 3 (Open Book Exam, 2 hours) 11 (35%) ‘A company burns an intermediate product £25 having the composition 4.39 $02 27% CO,10% Hz, 1.0% CHa, and the tesidual No together with a waste ail having the composition 87% C, 13% Hp Analysis of the stack gas gives an Orsat Eile of 14.6% COs, 0.76% CO, and 7.65 Oy and the Test N2. Calculate the fraction ofthe total carbon burned that comes from the product gas,PROBLEM 2 (35%) Benzene, toluene and other aromatic compounds can be recovered by solvent extraction with sulfur dioxide. As an example, a catalytic reformate stream containing 70% by weight benzene and 30% non-benzene material is passed through the counter-current extractive recovery scheme shown in the diagram below. One thousand pounds of the reformate stream and 3000 pounds of sulfur dioxide are fed to the system per hour. The benzene product stream (the extract) contains 0.15 pound of sulfur dioxide per pound of benzene. ‘The raffinate stream contains all the initially charged non-benzene material as well as 0.25 pound of benzene pet pound ofthe non-benzene material. The remaining component in the raffinate stream is the sulfur dioxide (a). How many pounds of benzene are extracted per hour, i.e. are in the extract? (&) If 800 pounds of benzene containing in addition 0.25 pound of the non penzene material per pound of benzene are flowing per hour at point A and 700 pounds of benzene containing 0.07 pound of the non-benzene material per pound of eeazene are flowing at point B, how many pounds (exclusive of the sulfur dioxide) are flowing, at points C and D? : : 0.15 tb SO, Extract benzene plus pe — Raffinate 0.25 1b Be Sulfur dioxide . 1000 apy 000 Ibi ae eaves retormate z i 10% Bo