1

GII CHI TIT MT S CU 591

Cu 24. Chn B
2 3
Na CO
n = 0,1 (mol) 0,2 mol Na
Gi CT chung ca CH
3
COOH; C
6
H
5
OH; C
2
H
5
OH l ROH
ROH + Na RONa +
2
1
H
2
|
mol 0,2 0,1
KL: 15,2 4,6 19,6 0,2
15,2 gam hn hp phn ng cho 0,1 mol H
2

30,4 gam hn hp phn ng cho 0,2 mol H
2

2
H
V = 22,4 . 0,2 = 4,48 lt
Cu 28. Chn D
Hn hp Y c: N
2
; H
2
; NH
3
cho hn hp Y tc dng vi CuO
H
2
+ CuO
o
t
H
2
O + Cu
2NH
3
+ 3CuO
o
t
N
2
+ 3H
2
O + 3Cu
Coi nh H
2
phn ng vi CuO
2
Cu H
32,64
n = = 0,51 (mol) n = 0,51 (mol)
64

N
2

2
N
n 28 5,2
7,2
H
2

2
H
n 2 20,8

2 2
2
N N
H
n n
5,2 5,2
= =
n 20,8 0,51 20,8

2
N
n = 0,1275 (mol)
2
N
n +
2
H
n = 0,51 + 0,1275 = 0,6375 (mol)
V
X
= 22,4 . 0,6375 = 14,28 (lt)
Cu 29. Chn D
Gi a, b ln lt l s mol FeCO
3
v Fe
3
O
4

Theo th n
NO
=
2
CO
n = 0,15 mol, do t 2 phn ng sau:
3FeCO
3
+ 10HNO
3
3Fe(NO
3
)
3
+ 3CO
2
+ NO + 5H
2
O
3Fe
3
O
4
+ 28HNO
3
9Fe(NO
3
)
3
+ NO + 14H
2
O
a b
a = +
3 3
a = 0,15 v b = 0,3
a b
a + + = 0,3
3 3

Vy m = 116a + 232b = 87 gam
Cu 30. Chn B
Theo cng thc gii nhanh l
A A
b - a
m = M
m

Ta c
0,13 - 0,03
m = 147 = 7,35 gam
2

Cu 31. Chn B
COOH + NaOH COONa + H
2
O
1 mol 1 mol. Khi lng tng = 22 gam

a - m
22
Khi lng tng = (a - m) gam



2
2COOH + Ca(OH)
2
(COO)
2
Ca + H
2
O
2 mol 1 mol. Khi lng tng = 38 gam

b - m
19
Khi lng tng = (b - m) gam
Ta c:
a - m
22
=
b - m
19
3m = 22b - 19a
Cu 34. Chn C
Xc nh c aminoaxit l Glyxin (Gly)
45 gam Gly
Gly
45
n = = 0,6 (mol)
75

39,6 gam Gly-Gly
Gly
39,6
n = = 0,6 (mol)
75 . 2 - 18

37,8 gam Tri-Gly
Gly
37,8
n = = 0,2 (mol)
75 . 3 - 36

147,6 gam Tetra-Gly
Gly
147, 6
n = = 0,6 (mol)
75 . 4 - 54

90,9 gam Penta-Gly
Gly
90, 9
n = = 0,3 (mol)
75 . 5 - 72

n
Gly
= 0,6 . 1 + 0,6 . 2 + 0,2 . 3 + 0,6 . 4 + 0,3 . 5 = 6,3 (mol)
n
hexapeptit
=
6, 3
1, 05
6
= (mol)
m = 1,05 . (75 . 6 - 18 . 5) = 378 (gam)
Cu 35. Chn C.
Trc ht xy ra phn ng:
Cu(NO
3
)
2
+ 2NaCl Cu + Cl
2
+ 2NaNO
3

mol 0,018 0,036
Sau phn ng ny vn cha c kh thot ra c hai in cc nn phn ng in phn xy ra tip l.
2NaCl + 2H
2
O 2NaOH + H
2
+ Cl
2

mol 0,004 0,004
Sau phn ng ny nu tip tc in phn s l in phn H
2
O c hai in cc. Do ta kt thc in phn

-
0,004
[OH ] = = 0,02M
0,2

Vy pOH = -log0,02 = 1,7 nn pH = 12,3
Cu 36. Chn D
Gi a v b l s mol Ca v CaC
2
ta c h
40a + 64b = 10 a = 0,09
a + b = 0,19 b = 0,1

Y gm 0,09 mol H
2
v 0,1 mol C
2
H
2

M m
Y
= m
Z
= m
bnh brom tng
+ m
kh thot ra

Nn m
bnh brom tng
= m
Y
- m
kh thot ra

= (0,09 . 2 + 0,1 . 26) -
3,08.12 1,62.2
44 18
| |
+
|
\ .
= 1,76 gam
Cu 44. Chn B
Theo cng thc gii nhanh th
Fe
56
m = (18 + 24 . 0,15) = 15,12 gam
80

Cu 49. Chn D
V
2 2 2
O CO H O
n : n : n = 1 : 1 : 1 nn X c cng thc C
n
H
2n
O
n

Cng thc ny cho bit X c tng s v vng l 1
Theo , X c cha 1 nhm COOH nn X phi cha 1
Vy X phi l hp cht no, mch h

3
Cng thc C
n
H
2n
O
n
khng ph hp vi axit fomic nn p n ph hp l D
Cu 55. Chn C
Rn Z gm Fe v Cu
Cu 56. Chn D
Ta phi c
1,8
0,04 < < 0,06 30 < M < 45 M = 39(K)
M

K KOH
OH
1,8
n = n = n = mol
39

-
1,8
[OH ]= = 0,1M
39 . 0,46
. Vy pOH = 1 tc pH = 13
Cu 57. Chn A.
Dung dch Y cha
3+
3
+
Fe : 0,05 mol
NO : 0,15 mol
H : d

Cc phn ng xy ra:
3Cu + 8H
+
+ 2NO
3

3Cu
2+
+ 2NO + 4H
2
O
mol 0,225 0,15 0,15
Cu + 2Fe
3+
Cu
2+
+ 2Fe
2+

mol 0,025 0,05
Vy m
Cu (max)
= 64 (0,225 + 0,025) = 16 gam; V
NO
= 22,4 . 0,15 = 3,36 lt
Cu 58. Chn B
Cu 59. Chn A
Xt 4 phn ng nhit phn:
+ 4Fe(NO
3
)
3

o
t
2Fe
2
O
3
+ 12NO
2
+ 3O
2

mol 1 0,5
Nh vy nu dng 242 gam Fe(NO
3
)
3
s c 80 gam rn Fe
2
O
3

8
242
9
= = 214 gam (loi)
+ 2Fe(OH)
3

o
t
Fe
2
O
3
+ 3H
2
O
mol 1 0,5
Nh vy nu dng 107 gam Fe(NO
3
)
3
s c 80 gam rn Fe
2
O
3

8
107
9
= = 95 gam (loi)
+ 4FeCO
3
+ O
2

o
t
2Fe
2
O
3
+ 4CO
2

mol 1 0,5
Nh vy nu dng 116 gam FeCO
3
s c 80 gam rn Fe
2
O
3

8
116
9
= = 103 gam (loi)
+ 4Fe(OH)
2
+ O
2

o
t
2Fe
2
O
3
+ 4H
2
O
mol 1 0,5
Nh vy nu dng 90 gam FeCO
3
s c 80 gam rn Fe
2
O
3

8
= 90
9
= 80 gam (nhn)